| Year |
Citation |
Score |
| 2017 |
Adams CJ, Lusi M, Mutambi EM, Orpen AG. Two-Step Mechanochemical Synthesis of Carbene Complexes of Palladium(II) and Platinum(II) Crystal Growth & Design. 17: 3151-3155. DOI: 10.1021/Acs.Cgd.7B00106 |
0.368 |
|
| 2014 |
Lister JM, Carreira M, Haddow MF, Hamilton A, McMullin CL, Orpen AG, Pringle PG, Stennett TE. Unexpectedly high barriers to M-P rotation in tertiary phobane complexes: Phobpr behavior that is commensurate with tBu2PR Organometallics. 33: 702-714. DOI: 10.1021/Om400980E |
0.75 |
|
| 2013 |
Natarajan R, Bridgland L, Sirikulkajorn A, Lee JH, Haddow MF, Magro G, Ali B, Narayanan S, Strickland P, Charmant JP, Orpen AG, McKeown NB, Bezzu CG, Davis AP. Tunable porous organic crystals: structural scope and adsorption properties of nanoporous steroidal ureas. Journal of the American Chemical Society. 135: 16912-25. PMID 24147834 DOI: 10.1021/Ja405701U |
0.301 |
|
| 2013 |
Fanjul T, Eastham G, Floure J, Forrest SJ, Haddow MF, Hamilton A, Pringle PG, Orpen AG, Waugh M. Interplay of bite angle and cone angle effects. A comparison between o-C6H4(CH2PR2)(PR'2) and o-C6H4(CH2PR2)(CH2PR'2) as ligands for Pd-catalysed ethene hydromethoxycarbonylation. Dalton Transactions (Cambridge, England : 2003). 42: 100-15. PMID 23080322 DOI: 10.1039/C2Dt31913F |
0.438 |
|
| 2013 |
Tsoureas N, Hamilton A, Haddow MF, Harvey JN, Orpen AG, Owen GR. Insight into the hydrogen migration processes involved in the formation of metal-borane complexes: Importance of the third arm of the scorpionate ligand Organometallics. 32: 2840-2856. DOI: 10.1021/Om4002389 |
0.612 |
|
| 2012 |
Jover J, Fey N, Harvey JN, Lloyd-Jones GC, Orpen AG, Owen-Smith GJ, Murray P, Hose DR, Osborne R, Purdie M. Expansion of the Ligand Knowledge Base for Chelating P,P-Donor Ligands (LKB-PP). Organometallics. 31: 5302-5306. PMID 24882917 DOI: 10.1021/Om300312T |
0.805 |
|
| 2012 |
Fey N, Garland M, Hopewell JP, McMullin CL, Mastroianni S, Orpen AG, Pringle PG. Stable fluorophosphines: predicted and realized ligands for catalysis. Angewandte Chemie (International Ed. in English). 51: 118-22. PMID 22076744 DOI: 10.1002/Anie.201105954 |
0.794 |
|
| 2012 |
James SL, Adams CJ, Bolm C, Braga D, Collier P, Friš?i? T, Grepioni F, Harris KD, Hyett G, Jones W, Krebs A, Mack J, Maini L, Orpen AG, Parkin IP, et al. Mechanochemistry: opportunities for new and cleaner synthesis. Chemical Society Reviews. 41: 413-47. PMID 21892512 DOI: 10.1039/C1Cs15171A |
0.474 |
|
| 2012 |
Fanjul T, Eastham G, Haddow MF, Hamilton A, Pringle PG, Orpen AG, Turner TPW, Waugh M. Efficient and chemoselective ethene hydromethoxycarbonylation catalysts based on Pd-complexes of heterodiphosphines o-C 6H 4(CH 2P tBu 2)(CH 2PR 2) Catalysis Science and Technology. 2: 937-950. DOI: 10.1039/C1Cy00409C |
0.438 |
|
| 2012 |
Fey N, Haddow MF, Mistry R, Norman NC, Orpen AG, Reynolds TJ, Pringle PG. Regioselective B-cyclometalation of a bulky o-carboranyl phosphine and the unexpected formation of a dirhodium(II) complex Organometallics. 31: 2907-2913. DOI: 10.1021/Om201198S |
0.8 |
|
| 2011 |
Blagg RJ, López-Gómez MJ, Charmant JP, Connelly NG, Cowell JJ, Haddow MF, Hamilton A, Orpen AG, Riis-Johannessen T, Saithong S. The oxidative conversion of the N,S-bridged complexes [{RhLL'(μ-X)}2] to [(RhLL')3)(μ-X)2]+ (X = mt or taz): a comparison with the oxidation of N,N-bridged analogues. Dalton Transactions (Cambridge, England : 2003). 40: 11497-510. PMID 21952645 DOI: 10.1039/C1Dt10930H |
0.614 |
|
| 2011 |
Hallett AJ, Baber RA, Orpen AG, Ward BD. The co-ordination chemistry of tris(3,5-dimethylpyrazolyl)methane manganese carbonyl complexes: synthetic, electrochemical and DFT studies. Dalton Transactions (Cambridge, England : 2003). 40: 9276-83. PMID 21837321 DOI: 10.1039/C1Dt10828J |
0.485 |
|
| 2011 |
Dodds DL, Floure J, Garland M, Haddow MF, Leonard TR, McMullin CL, Orpen AG, Pringle PG. Diphosphanes derived from phobane and phosphatrioxa-adamantane: similarities, differences and anomalies. Dalton Transactions (Cambridge, England : 2003). 40: 7137-46. PMID 21643610 DOI: 10.1039/C1Dt10335K |
0.755 |
|
| 2011 |
Chotima R, Dale T, Green M, Hey TW, McMullin CL, Nunns A, Orpen AG, Shishkov IV, Wass DF, Wingad RL. Cyclopropenylidene carbene ligands in palladium catalysed coupling reactions: carbene ligand rotation and application to the Stille reaction. Dalton Transactions (Cambridge, England : 2003). 40: 5316-23. PMID 21475742 DOI: 10.1039/C1Dt10109A |
0.795 |
|
| 2011 |
López-Gómez MJ, Connelly NG, Haddow MF, Hamilton A, Lusi M, Baisch U, Orpen AG. Potassium S2N-heteroscorpionates: structure and iridaboratrane formation. Dalton Transactions (Cambridge, England : 2003). 40: 4647-59. PMID 21423986 DOI: 10.1039/C0Dt01718C |
0.779 |
|
| 2011 |
Kara H, Adams CJ, Schwarz B, Orpen AG. The use of [Fe(dithiooxalate)2(NO)]2- as a tecton in crystal engineering Crystengcomm. 13: 5082-5087. DOI: 10.1039/C1Ce05309D |
0.332 |
|
| 2011 |
Adams CJ, Haddow MF, Lusi M, Orpen AG. Crystal synthesis of 1,4-phenylenediamine salts and coordination networks Crystengcomm. 13: 4324-4331. DOI: 10.1039/C0Ce00020E |
0.319 |
|
| 2011 |
Mikhel IS, Garland M, Hopewell J, Mastroianni S, McMullin CL, Orpen AG, Pringle PG. Cage phosphinites: Ligands for efficient nickel-catalyzed hydrocyanation of 3-pentenenitrile Organometallics. 30: 974-985. DOI: 10.1021/Om101023E |
0.79 |
|
| 2010 |
Blagg RJ, Connelly NG, Haddow MF, Hamilton A, Lusi M, Orpen AG, Ridgway BM. Isomerism in rhodium(I) N,S-donor heteroscorpionates: ring substituent and ancillary ligand effects. Dalton Transactions (Cambridge, England : 2003). 39: 11616-27. PMID 21038065 DOI: 10.1039/C0Dt00774A |
0.659 |
|
| 2010 |
Adams CJ, Kurawa MA, Orpen AG. Coordination chemistry in the solid state: reactivity of manganese and cadmium chlorides with imidazole and pyrazole and their hydrochlorides. Inorganic Chemistry. 49: 10475-85. PMID 20945835 DOI: 10.1021/Ic101403J |
0.399 |
|
| 2010 |
Adams CJ, Haddow MF, Lusi M, Orpen AG. Crystal engineering of lattice metrics of perhalometallate salts and MOFs. Proceedings of the National Academy of Sciences of the United States of America. 107: 16033-8. PMID 20798344 DOI: 10.1073/Pnas.0910146107 |
0.312 |
|
| 2010 |
Adams CJ, Kurawa MA, Orpen AG. Coordination chemistry in the solid state: Synthesis and interconversion of pyrazolium salts, pyrazole complexes, and pyrazolate MOFs Dalton Transactions. 39: 6974-6984. PMID 20556305 DOI: 10.1039/C0Dt00195C |
0.336 |
|
| 2010 |
López-Gómez MJ, Connelly NG, Haddow MF, Hamilton A, Orpen AG. Fluxional rhodium scorpionate complexes of the hydrotris(methimazolyl)borate (Tm) ligand and their static boratrane derivatives. Dalton Transactions (Cambridge, England : 2003). 39: 5221-30. PMID 20379586 DOI: 10.1039/C000651C |
0.65 |
|
| 2010 |
Adams CJ, Haddow MF, Hughes RJ, Kurawa MA, Orpen AG. Coordination chemistry of platinum and palladium in the solid-state: synthesis of imidazole and pyrazole complexes. Dalton Transactions (Cambridge, England : 2003). 39: 3714-24. PMID 20354624 DOI: 10.1039/B919665J |
0.39 |
|
| 2010 |
Hopewell J, Jankowski P, McMullin CL, Orpen AG, Pringle PG. Subtleties in asymmetric catalyst structure: the resolution of a 6-phospha-2,4,8-trioxa-adamantane and its applications in asymmetric hydrogenation catalysis. Chemical Communications (Cambridge, England). 46: 100-2. PMID 20024306 DOI: 10.1039/B916359J |
0.737 |
|
| 2010 |
Bowen LE, Charernsuk M, Hey TW, McMullin CL, Orpen AG, Wass DF. Ligand effects in chromium diphosphine catalysed olefin co-trimerisation and diene trimerisation. Dalton Transactions (Cambridge, England : 2003). 560-7. PMID 20023994 DOI: 10.1039/B913302J |
0.763 |
|
| 2010 |
Adams CJ, Gillon AL, Lusi M, Orpen AG. Towards polymorphism control in coordination networks and metallo-organic salts Crystengcomm. 12: 4403-4409. DOI: 10.1039/C0Ce00230E |
0.326 |
|
| 2010 |
Jover J, Fey N, Harvey JN, Lloyd-Jones GC, Orpen AG, Owen-Smith GJJ, Murray P, Hose DRJ, Osborne R, Purdie M. Expansion of the ligand knowledge base for monodentate P-donor ligands (LKB-P) Organometallics. 29: 6245-6258. DOI: 10.1021/Om100648V |
0.808 |
|
| 2010 |
Fanjul T, Eastham G, Fey N, Hamilton A, Orpen AG, Pringle PG, Waugh M. Palladium complexes of the heterodiphosphine o- C6H 4(CH2PtBu2)(CH2PPh 2) are highly selective and robust catalysts for the hydromethoxycarbonylation of ethene Organometallics. 29: 2292-2305. DOI: 10.1021/Om100049N |
0.764 |
|
| 2010 |
Jankowski P, McMullin CL, Gridnev ID, Orpen AG, Pringle PG. Is restricted M-P rotation a common feature of enantioselective monophos catalysts? An example of restricted Rh-P rotation in a secondary phosphine complex Tetrahedron Asymmetry. 21: 1206-1209. DOI: 10.1016/J.Tetasy.2010.06.005 |
0.749 |
|
| 2010 |
McMullin CL, Rühle B, Besora M, Orpen AG, Harvey JN, Fey N. Computational study of PtBu3 as ligand in the palladium-catalysed amination of phenylbromide with morpholine Journal of Molecular Catalysis a: Chemical. 324: 48-55. DOI: 10.1016/J.Molcata.2010.02.030 |
0.805 |
|
| 2009 |
Adams CJ, Baber A, Boonyuen S, Connelly NG, Diosdado BE, Kantacha A, Orpen AG, Patrón E. Thiolates vs. halides as pi-donors: the redox-active alkyne complexes [M(SR)L(eta-R'C[triple bond]CR')L'] {M = Mo or W, L = CO or P(OMe)(3), L' = eta-C(5)H(5) and Tp'}. Dalton Transactions (Cambridge, England : 2003). 9746-58. PMID 19885520 DOI: 10.1039/B912986C |
0.579 |
|
| 2009 |
Blagg RJ, Adams CJ, Charmant JP, Connelly NG, Haddow MF, Hamilton A, Knight J, Orpen AG, Ridgway BM. A novel route to rhodaboratranes [Rh(CO)(PR3){B(taz)3}]+ via the redox activation of scorpionate complexes [RhLL'Tt]. Dalton Transactions (Cambridge, England : 2003). 8724-36. PMID 19809748 DOI: 10.1039/B910108J |
0.621 |
|
| 2009 |
Fey N, Haddow MF, Harvey JN, McMullin CL, Orpen AG. A ligand knowledge base for carbenes (LKB-C): maps of ligand space. Dalton Transactions (Cambridge, England : 2003). 8183-96. PMID 19789771 DOI: 10.1039/B909229C |
0.808 |
|
| 2009 |
Bedford RB, Dumycz H, Haddow MF, Pilarski LT, Orpen AG, Pringle PG, Wingad RL. Chiral triaryl phosphite-based palladacycles and platinacycles: synthesis and application to asymmetric Lewis acid catalysis. Dalton Transactions (Cambridge, England : 2003). 7796-804. PMID 19759955 DOI: 10.1039/B907333G |
0.388 |
|
| 2009 |
Cushion M, Ebrahimpour P, Haddow MF, Hallett AJ, Mansell SM, Orpen AG, Wass DF. Copper(i) complexes of cis,cis-1,3,5-tris(mesitylideneamino)cyclohexane ligands: Synthesis, structure and substrate selectivity Dalton Transactions. 1632-1635. PMID 19421608 DOI: 10.1039/B818827K |
0.376 |
|
| 2009 |
Rudolf GC, Hamilton A, Orpen AG, Owen GR. A 'sting' on Grubbs' catalyst: an insight into hydride migration between boron and a transition metal. Chemical Communications (Cambridge, England). 553-5. PMID 19283288 DOI: 10.1039/B816036H |
0.336 |
|
| 2009 |
Carreira M, Charernsuk M, Eberhard M, Fey N, van Ginkel R, Hamilton A, Mul WP, Orpen AG, Phetmung H, Pringle PG. Anatomy of phobanes. diastereoselective synthesis of the three isomers of n-butylphobane and a comparison of their donor properties. Journal of the American Chemical Society. 131: 3078-92. PMID 19183007 DOI: 10.1021/Ja808807S |
0.759 |
|
| 2009 |
Adams CJ, Anderson KM, Connelly NG, Harding DJ, Hayward OD, Orpen AG, Patrón E, Rieger PH. The d3/d2 alkyne complexes [MX2(eta-RC[triple bond, length as m-dash]CR)Tp']z (X = halide, z = 0 and 1+): final links in a d6-d2 redox family tree. Dalton Transactions (Cambridge, England : 2003). 530-43. PMID 19122911 DOI: 10.1039/B813642D |
0.571 |
|
| 2009 |
Haddow MF, Middleton AJ, Orpen AG, Pringle PG, Papp R. Stereoelectronic effects in a homologous series of bidentate cyclic phosphines. A clear correlation of hydroformylation catalyst activity with ring size. Dalton Transactions (Cambridge, England : 2003). 202-9. PMID 19081990 DOI: 10.1039/B815056G |
0.37 |
|
| 2009 |
McMullin CL, Fey N, Orpen AG. Conformational analysis of bidentate tetra-aryl diphosphines Acta Crystallographica Section a Foundations of Crystallography. 65: s307-s308. DOI: 10.1107/S0108767309093453 |
0.775 |
|
| 2009 |
Lloyd-Jones G, Evans L, Fey N, Harvey J, Hose D, Murray P, Orpen A, Osborne R, Owen-Smith G, Purdie M. Kinetic Studies of Palladium-Catalyzed Tsuji-Trost Allylations Synfacts. 2009: 0292-0292. DOI: 10.1055/S-0028-1087759 |
0.779 |
|
| 2009 |
Green M, McMullin CL, Morton GJP, Orpen AG, Wass DF, Wingad RL. Rhodium complexes of cyclopropenylidene carbene ligands: Synthesis, structure, and hydroformylation catalysis Organometallics. 28: 1476-1479. DOI: 10.1021/Om801031A |
0.813 |
|
| 2009 |
Carreira M, Charernsuk M, Eberhard M, Fey N, Van Ginkel R, Hamilton A, Mul WP, Orpen AG, Phetmung H, Pringle PG. Anatomy of phobanes. Diastereoselective synthesis of the three isomers of n-butylphobane and a comparison of their donor properties Journal of the American Chemical Society. 131: 3078-3092. DOI: 10.1021/ja808807s |
0.692 |
|
| 2009 |
Fey N, Orpen AG, Harvey JN. Building ligand knowledge bases for organometallic chemistry: Computational description of phosphorus(III)-donor ligands and the metal-phosphorus bond Coordination Chemistry Reviews. 253: 704-722. DOI: 10.1016/J.Ccr.2008.04.017 |
0.811 |
|
| 2008 |
Kurawa MA, Adams CJ, Orpen AG. cis-Aqua-dichlorido[pyrimidin-2(1H)-one-κN]copper(II). Acta Crystallographica. Section E, Structure Reports Online. 64: m969. PMID 21202815 DOI: 10.1107/S1600536808018771 |
0.348 |
|
| 2008 |
Kurawa MA, Adams CJ, Orpen AG. 2-Oxo-1,2-dihydro-pyrimidin-3-ium di-μ-chlorido-bis-{dichloridobis[pyrimidin-2(1H)-one-κN]cuprate(II)} dihydrate. Acta Crystallographica. Section E, Structure Reports Online. 64: m924-5. PMID 21202780 DOI: 10.1107/S1600536808017455 |
0.369 |
|
| 2008 |
Kurawa MA, Adams CJ, Orpen AG. A tetra-nuclear chlorido-bridged manganese(II) cluster with imidazole ligands. Acta Crystallographica. Section E, Structure Reports Online. 64: m1276-7. PMID 21201026 DOI: 10.1107/S1600536808029139 |
0.407 |
|
| 2008 |
Tsoureas N, Owen GR, Hamilton A, Orpen AG. Flexible scorpionates for transfer hydrogenation: The first example of their catalytic application Dalton Transactions. 6039-6044. PMID 19082061 DOI: 10.1039/B809247H |
0.433 |
|
| 2008 |
Evans LA, Fey N, Harvey JN, Hose D, Lloyd-Jones GC, Murray P, Orpen AG, Osborne R, Owen-Smith GJJ, Purdie M. Counterintuitive kinetics in Tsuji-Trost allylation: Ion-pair partitioning and implications for asymmetric catalysis Journal of the American Chemical Society. 130: 14471-14473. PMID 18839958 DOI: 10.1021/Ja806278E |
0.796 |
|
| 2008 |
Casas JM, Diosdado BE, Forniés J, Martín A, Rueda AJ, Orpen AG. Synthesis of binuclear platinum complexes containing the ligands 8-naphthyridine, 2-aminopyridine, and 7-azaindolate. An experimental study of the steric hindrance of the bulky pentafluorophenyl ligands in the synthesis of binuclear complexes. Inorganic Chemistry. 47: 8767-75. PMID 18767797 DOI: 10.1021/Ic8006475 |
0.489 |
|
| 2008 |
Baya M, Houghton J, Konya D, Champouret Y, Daran JC, Almeida Leñero KQ, Schoon L, Mul WP, van Oort AB, Meijboom N, Drent E, Orpen AG, Poli R. Pd(I) phosphine carbonyl and hydride complexes implicated in the palladium-catalyzed oxo process. Journal of the American Chemical Society. 130: 10612-24. PMID 18630871 DOI: 10.1021/Ja8012903 |
0.549 |
|
| 2008 |
Norman DW, Carraz CA, Hyett DJ, Pringle PG, Sweeney JB, Orpen AG, Phetmung H, Wingad RL. Bidentates versus monodentates in asymmetric hydrogenation catalysis: synergic effects on rate and allosteric effects on enantioselectivity. Journal of the American Chemical Society. 130: 6840-7. PMID 18454526 DOI: 10.1021/Ja800858X |
0.355 |
|
| 2008 |
Charmant JP, Haddow MF, Mistry R, Norman NC, Orpen AG, Pringle PG. A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C-C bond in ortho-carboranyl diphosphines. Dalton Transactions (Cambridge, England : 2003). 1409-11. PMID 18322616 DOI: 10.1039/B719404H |
0.525 |
|
| 2008 |
Hamilton A, Orpen A, Harvey J. Studying conformational preferences for mechanistic purposes: using database mining and computation Acta Crystallographica Section a Foundations of Crystallography. 64: C628-C628. DOI: 10.1107/S0108767308079786 |
0.379 |
|
| 2008 |
Adams CJ, Kurawa MA, Lusi M, Orpen AG. Solid state synthesis of coordination compounds from basic metal salts Crystengcomm. 10: 1790-1795. DOI: 10.1039/B809950B |
0.354 |
|
| 2008 |
Charmant JPH, Haddow MF, Mistry R, Norman NC, Orpen AG, Pringle PG. A simple entry into nido-C2B10 clusters: HCl promoted cleavage of the C-C bond in ortho-carboranyl diphosphines Dalton Transactions. 1409-1411. DOI: 10.1039/b719404h |
0.442 |
|
| 2008 |
Baber A, Fan C, Norman DW, Orpen AG, Pringle PG, Wingad RL. Oxidative dehydrogenation of tris(o-isopropylphenyl)phosphines by platinum complexes Organometallics. 27: 5906-5910. DOI: 10.1021/Om800382M |
0.369 |
|
| 2008 |
Downing JH, Roure J, Heslop K, Haddow MF, Hopewell J, Lusi M, Phetmung H, Orpen AG, Pringle PG, Pugh RI, Zambrano-Williams D. General routes to alkyl phosphatrioxaadamantane ligands Organometallics. 27: 3216-3224. DOI: 10.1021/Om800141Y |
0.356 |
|
| 2008 |
Daly S, Haddow MF, Orpen AG, Rolls GTA, Wass DF, Wingad RL. Copper(I) Diphosphine Catalysts for C−N Bond Formation: Synthesis, Structure, and Ligand Effects Organometallics. 27: 3196-3202. DOI: 10.1021/Om800139V |
0.501 |
|
| 2008 |
Fey N, Harvey JN, Lloyd-Jones GC, Murray P, Orpen AG, Osborne R, Purdie M. Computational descriptors for chelating P,P- And P,N-donor ligands Organometallics. 27: 1372-1383. DOI: 10.1021/Om700840H |
0.822 |
|
| 2008 |
Casas JM, Diosdado BE, Forniés J, Martín A, Rueda AJ, Orpen AG. Synthesis of binuclear platinum complexes containing the ligands 8-naphthyridine, 2-aminopyridine, and 7-azaindolate. An experimental study of the steric hindrance of the bulky pentafluorophenyl ligands in the synthesis of binuclear complexes Inorganic Chemistry. 47: 8767-8775. DOI: 10.1021/ic8006475 |
0.335 |
|
| 2007 |
Adams CJ, Anderson KM, Connelly NG, Llamas-Rey E, Orpen AG, Paul RL. The effect of micro-CN linkage isomerism and ancillary ligand set on directional metal-metal charge-transfer in cyanide-bridged dimanganese complexes. Dalton Transactions (Cambridge, England : 2003). 3609-22. PMID 17700823 DOI: 10.1039/B705975B |
0.603 |
|
| 2007 |
Wass DF, Haddow MF, Hey TW, Orpen AG, Russell CA, Wingad RL, Green M. Cyclopropenylidene carbene ligands in palladium C-C coupling catalysis. Chemical Communications (Cambridge, England). 2704-6. PMID 17594026 DOI: 10.1039/B702827J |
0.41 |
|
| 2007 |
Adams CJ, Charmant JP, Connelly NG, Gill M, Kantacha A, Onganusorn S, Orpen AG. Homobinuclear cyanide-bridged linkage isomers containing the redox-active unit [(micro-XY)Ru(CO)2L(o-O2C6Cl4)] (XY=CN or NC). Dalton Transactions (Cambridge, England : 2003). 2283-94. PMID 17534489 DOI: 10.1039/b700648a |
0.513 |
|
| 2007 |
Adams CJ, Baber RA, Connelly NG, Harding P, Hayward OD, Kandiah M, Orpen AG. Iodination of triazenide-bridged rhodium and iridium complexes: oxidative addition vs. one-electron oxidation. Dalton Transactions (Cambridge, England : 2003). 1325-33. PMID 17372648 DOI: 10.1039/B700736A |
0.573 |
|
| 2007 |
Bowen LE, Haddow MF, Orpen AG, Wass DF. One electron oxidation of chromium N,N-bis(diarylphosphino)amine and bis(diarylphosphino)methane complexes relevant to ethene trimerisation and tetramerisation. Dalton Transactions (Cambridge, England : 2003). 1160-8. PMID 17339999 DOI: 10.1039/B700559H |
0.426 |
|
| 2007 |
Adams CJ, Colquhoun HM, Crawford PC, Lusi M, Orpen AG. Solid-state interconversions of coordination networks and hydrogen-bonded salts. Angewandte Chemie (International Ed. in English). 46: 1124-8. PMID 17191295 DOI: 10.1002/Anie.200603593 |
0.346 |
|
| 2007 |
Adams CJ, Bartlett IM, Carlton S, Connelly NG, Harding DJ, Hayward OD, Orpen AG, Patron E, Ray CD, Rieger PH. The d4/d3 redox pairs [MX(CO)(eta-RC[triple bond, length as m-dash]CR)Tp']z (z=0 and 1): structural consequences of electron transfer and implications for the inverse halide order. Dalton Transactions (Cambridge, England : 2003). 62-72. PMID 17160175 DOI: 10.1039/B611472E |
0.581 |
|
| 2007 |
Leyssens T, Peeters D, Orpen AG, Harvey JN. How important is metal - Ligand back-bonding toward YX3 ligands (Y = N, P, C, Si)? An NBO analysis Organometallics. 26: 2637-2645. DOI: 10.1021/Om061151Z |
0.621 |
|
| 2007 |
Baber RA, Haddow MF, Middleton AJ, Orpen AG, Pringle PG, Haynes A, Williams GL, Papp R. Ligand stereoelectronic effects in complexes of phospholanes, phosphinanes, and phosphepanes and their implications for hydroformylation catalysis Organometallics. 26: 713-725. DOI: 10.1021/Om060912V |
0.32 |
|
| 2006 |
Baber RA, Bedford RB, Betham M, Blake ME, Coles SJ, Haddow MF, Hursthouse MB, Orpen AG, Pilarski LT, Pringle PG, Wingad RL. Chiral palladium bis(phosphite)PCP-pincer complexes via ligand C-H activation. Chemical Communications (Cambridge, England). 3880-2. PMID 17268657 DOI: 10.1039/B609704A |
0.427 |
|
| 2006 |
Mansson RA, Welsh AH, Fey N, Orpen AG. Statistical modeling of a ligand knowledge base Journal of Chemical Information and Modeling. 46: 2591-2600. PMID 17125199 DOI: 10.1021/Ci600212T |
0.708 |
|
| 2006 |
Baber A, de Vries JG, Orpen AG, Pringle PG, von der Luehe K. Allosteric effects in asymmetric hydrogenation catalysis? Asymmetric induction as a function of the substrate and the backbone flexibility of C1-symmetric diphosphines in rhodium-catalysed hydrogenations. Dalton Transactions (Cambridge, England : 2003). 4821-8. PMID 17033707 DOI: 10.1039/B607479K |
0.323 |
|
| 2006 |
Doherty R, Haddow MF, Harrison ZA, Orpen AG, Pringle PG, Turner A, Wingad RL. Bulky 4-phosphacyclohexanones: diastereoselective complexations, orthometallations and unprecedented [3.1.1]metallabicycles. Dalton Transactions (Cambridge, England : 2003). 4310-20. PMID 16967114 DOI: 10.1039/B607490A |
0.415 |
|
| 2006 |
Adams CJ, Connelly NG, Goodwin NJ, Hayward OD, Orpen AG, Wood AJ. Metal-metal charge transfer and solvatochromism in cyanomanganese carbonyl complexes of ruthenium and osmium. Dalton Transactions (Cambridge, England : 2003). 3584-96. PMID 16855759 DOI: 10.1039/B602334G |
0.63 |
|
| 2006 |
Adams CJ, Bartlett IM, Boonyuen S, Connelly NG, Harding DJ, Hayward OD, McInnes EJ, Orpen AG, Quayle MJ, Rieger PH. Structural consequences of the one-electron reduction of d4 [Mo(CO)2(eta-PhC[triple bond]CPh)Tp']+ and the electronic structure of the d5 radicals [M(CO)L(eta-MeC[triple bond]CMe)Tp'] {L = CO and P(OCH2)3CEt}. Dalton Transactions (Cambridge, England : 2003). 3466-77. PMID 16832497 DOI: 10.1039/B514951G |
0.61 |
|
| 2006 |
Blagg RJ, Charmant JP, Connelly NG, Haddow MF, Orpen AG. Redox activation of a B-H bond: a new route to metallaboratrane complexes. Chemical Communications (Cambridge, England). 2350-2. PMID 16733576 DOI: 10.1039/B604954K |
0.592 |
|
| 2006 |
Adams CJ, Baber RA, Connelly NG, Harding P, Hayward OD, Kandiah M, Orpen AG. Triazenide-bridged rhodium-palladium complexes: [I2Rh(mu-p-MeC6H4NNNC6H4Me-p)2Pd(eta(3)-C3H5)]-, a stable paramagnetic [RhPd]4+ species with a localised Rh(II) centre. Dalton Transactions (Cambridge, England : 2003). 1749-57. PMID 16568184 DOI: 10.1039/B514513A |
0.62 |
|
| 2006 |
Fey N, Harris SE, Harvey JN, Orpen AG. Adding value to crystallographically-derived knowledge bases Journal of Chemical Information and Modeling. 46: 912-929. PMID 16563023 DOI: 10.1021/Ci0504768 |
0.784 |
|
| 2006 |
Adams CJ, Baber RA, Batsanov AS, Bramham G, Charmant JP, Haddow MF, Howard JA, Lam WH, Lin Z, Marder TB, Norman NC, Orpen AG. Synthesis and reactivity of cobalt boryl complexes. Dalton Transactions (Cambridge, England : 2003). 1370-3. PMID 16518504 DOI: 10.1039/B516594F |
0.64 |
|
| 2006 |
Kara H, Adams CJ, Orpen AG, Podesta TJ. Pyridinium boronic acid salts in crystal synthesis New Journal of Chemistry. 30: 1461-1469. DOI: 10.1039/B604729G |
0.357 |
|
| 2006 |
Adams CJ, Baber RA, Batsanov AS, Bramham G, Charmant JPH, Haddow MF, Howard JAK, Lam WH, Lin Z, Marder TB, Norman NC, Orpen AG. Synthesis and reactivity of cobalt boryl complexes Dalton Transactions. 6: 1370-1373. DOI: 10.1039/b516594f |
0.624 |
|
| 2005 |
Harris SE, Orpen AG, Bruno IJ, Taylor R. Factors affecting d-block metal-ligand bond lengths: toward an automated library of molecular geometry for metal complexes. Journal of Chemical Information and Modeling. 45: 1727-48. PMID 16309280 DOI: 10.1021/Ci0500785 |
0.411 |
|
| 2005 |
Fey N, Tsipis AC, Harris SE, Harvey JN, Orpen AG, Mansson RA. Development of a ligand knowledge base, part 1: computational descriptors for phosphorus donor ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 291-302. PMID 16278917 DOI: 10.1002/Chem.200500891 |
0.805 |
|
| 2005 |
Baber RA, Charmant JP, Cook AJ, Farthing NE, Haddow MF, Norman NC, Orpen AG, Russell CA, Slattery JM. Primary amido substituted diborane4 compounds and imidodiborate4 anions. Dalton Transactions (Cambridge, England : 2003). 3137-9. PMID 16172634 DOI: 10.1039/B509653G |
0.542 |
|
| 2005 |
Tsipis AC, Orpen AG, Harvey JN. Substituent effects and the mechanism of alkene metathesis catalyzed by ruthenium dichloride catalysts. Dalton Transactions (Cambridge, England : 2003). 2849-58. PMID 16094473 DOI: 10.1039/B506929G |
0.584 |
|
| 2005 |
Adams CJ, Crawford PC, Orpen AG, Podesta TJ, Salt B. Thermal solid state synthesis of coordination complexes from hydrogen bonded precursors. Chemical Communications (Cambridge, England). 2457-8. PMID 15886769 DOI: 10.1039/B501555C |
0.359 |
|
| 2005 |
Baber RA, Collard S, Hooper M, Orpen AG, Pringle PG, Wilkinson MJ, Wingad RL. Bulky triarylarsines are effective ligands for palladium catalysed Heck olefination. Dalton Transactions (Cambridge, England : 2003). 1491-8. PMID 15824787 DOI: 10.1039/B417910B |
0.494 |
|
| 2005 |
Clarke ML, Ellis D, Mason KL, Orpen AG, Pringle PG, Wingad RL, Zaher DA, Baker RT. The electron-poor phosphines P{C6H3(CF3)2-3,5}3 and P(C6F5)3 do not mimic phosphites as ligands for hydroformylation. A comparison of the coordination chemistry of P{C6H3(CF3)2-3,5}3 and P(C6F5)3 and the unexpectedly low hydroformylation activity of their rhodium complexes. Dalton Transactions (Cambridge, England : 2003). 1294-300. PMID 15782267 DOI: 10.1039/B418193J |
0.456 |
|
| 2005 |
Baber RA, Clarke ML, Heslop KM, Marr AC, Orpen AG, Pringle PG, Ward A, Zambrano-Williams DE. Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium(I) hydroformylation catalysts. Dalton Transactions (Cambridge, England : 2003). 1079-85. PMID 15739010 DOI: 10.1039/B418259F |
0.317 |
|
| 2005 |
Baber RA, Orpen AG, Pringle PG, Wilkinson MJ, Wingad RL. Special effects of ortho-isopropylphenyl groups. Diastereoisomerism in platinum(II) and palladium(II) complexes of helically chiral PAr3 ligands. Dalton Transactions (Cambridge, England : 2003). 659-67. PMID 15702175 DOI: 10.1039/B416525J |
0.471 |
|
| 2005 |
Dennett JN, Knox SA, Anderson KM, Charmant JP, Orpen AG. The synthesis of [FeRu(CO)2(mu-CO)2(eta-C5H5)(eta-C5Me5)] and convenient entries to its organometallic chemistry. Dalton Transactions (Cambridge, England : 2003). 63-73. PMID 15605148 DOI: 10.1039/B414412K |
0.444 |
|
| 2005 |
Angharad Baber R, Bull AEA, Charmant JPH, Norman NC, Orpen AG. N-imidazole-boron trichloride adduct Acta Crystallographica Section E: Structure Reports Online. 61: o553-o554. DOI: 10.1107/S1600536805002631 |
0.465 |
|
| 2005 |
Baber RA, Charmant JPH, Cook AJR, Farthing NE, Haddow MF, Norman NC, Orpen AG, Russell CA, Slattery JM. Primary amido substituted diborane(4) compounds and imidodiborate(4) anions Dalton Transactions. 3137-3139. DOI: 10.1039/b509653g |
0.429 |
|
| 2005 |
Tsipis AC, Orpen AG, Harvey JN. Substituent effects and the mechanism of alkene metathesis catalyzed by ruthenium dichloride catalysts Dalton Transactions. 2849-2858. DOI: 10.1039/b506929g |
0.427 |
|
| 2005 |
Baber RA, Collard S, Hooper M, Orpen AG, Pringle PG, Wilkinson MJ, Wingad RL. Bulky triarylarsines are effective ligands for palladium catalysed Heck olefination Dalton Transactions. 1491-1498. DOI: 10.1039/b417910b |
0.304 |
|
| 2005 |
Podesta TJ, Orpen AG. Tris(Pyridinium)Triazine in Crystal Synthesis of 3-Fold Symmetric Structures Crystal Growth & Design. 5: 681-693. DOI: 10.1021/Cg049783G |
0.381 |
|
| 2005 |
Charmant JPH, Monowar Jahan AHM, Norman NC, Orpen AG. The preparation and structural characterisation of thiolato anions of bismuth(III) Inorganica Chimica Acta. 358: 1358-1364. DOI: 10.1016/J.Ica.2004.03.025 |
0.569 |
|
| 2005 |
Fey N, Tsipis AC, Harris SE, Harvey JN, Orpen AG, Mansson RA. Development of a ligand knowledge base, Part 1: Computational descriptors for phosphorus donor ligands Chemistry - a European Journal. 12: 291-302. DOI: 10.1002/chem.200500891 |
0.777 |
|
| 2004 |
Adams CJ, Anderson KM, Baber RA, Connelly NG, Kandiah M, Orpen AG. M...HNR interactions in imino-bound diaryltriazene complexes: structure and fluxionality. Dalton Transactions (Cambridge, England : 2003). 3353-9. PMID 15483722 DOI: 10.1039/B408410A |
0.565 |
|
| 2004 |
Basra S, De Vries JG, Hyett DJ, Harrison G, Heslop KM, Orpen AG, Pringle PG, Von Der Luehe K. Efficient asymmetric hydrogenation with rhodium complexes of C(1)-symmetric 2,5-dimethylphospholane-diphenylphosphines. Dalton Transactions (Cambridge, England : 2003). 1901-5. PMID 15381999 DOI: 10.1039/B404827J |
0.387 |
|
| 2004 |
Angeloni A, Crawford PC, Orpen AG, Podesta TJ, Shore BJ. Does hydrogen bonding matter in crystal engineering? Crystal structures of salts of isomeric ions. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 3783-91. PMID 15281163 DOI: 10.1002/Chem.200400165 |
0.339 |
|
| 2004 |
Adams CJ, Anderson KM, Bardaji M, Connelly NG, Goodwin NJ, Llamas-Rey E, Orpen AG, Rieger PH. Bi- and poly-metallic cyanide-bridged complexes of the redox-active cyanomanganese nitrosyl unit [Mn(CN)(PR3)(NO)(eta-C5H4Me)]. Dalton Transactions (Cambridge, England : 2003). 683-94. PMID 15252534 DOI: 10.1039/B313654J |
0.607 |
|
| 2004 |
Baber RA, Charmant JPH, Moore JD, Norman NC, Orpen AG. 4-Methylpyridinium bis(pyrocatecholato-k2O,O′)borate catechol solvate Acta Crystallographica Section E: Structure Reports Online. 60: o1140-o1142. DOI: 10.1107/S1600536804013108 |
0.484 |
|
| 2004 |
Baber RA, Charmant JPH, Norman NC, Orpen AG, Rossi J. Dimethylammonium tetrahydropentaborate Acta Crystallographica Section E: Structure Reports Online. 60: o1086-o1088. DOI: 10.1107/S1600536804012371 |
0.495 |
|
| 2004 |
Charmant JPH, Norman NC, Orpen AG, Whittell GR. Carbonyldichlorohydridobis(trimethylphosphine)iridium(III) Acta Crystallographica Section E: Structure Reports Online. 60: m164-m165. DOI: 10.1107/S1600536804000480 |
0.427 |
|
| 2004 |
Charmant JPH, Norman NC, Orpen AG, Whittell GR. Carbonyldichlorohydridobis(triphenyl-phosphine)iridium(III) Acta Crystallographica Section E: Structure Reports Online. 60: m162-m163. DOI: 10.1107/S1600536804000479 |
0.601 |
|
| 2004 |
Crawford PC, Gillon AL, Green J, Orpen AG, Podesta TJ, Pritchard SV. Synthetic crystallography: Synthon mimicry and tecton elaboration in metallate anion salts Crystengcomm. 6: 419-428. DOI: 10.1039/B407722A |
0.364 |
|
| 2004 |
Charmant JPH, Jahan AHMM, Norman NC, Orpen AG, Podesta TJ. Coordination polymers formed by Bi(SC6F5)3 with multidentate polypyridyl ligands Crystengcomm. 6: 29-33. DOI: 10.1039/B315176J |
0.637 |
|
| 2004 |
Dennett JNL, Gillon AL, Heslop K, Hyett DJ, Fleming JS, Lloyd-Jones CE, Orpen AG, Pringle PG, Wass DF, Scutt JN, Weatherhead RH. Diphosphine Complexes of Nickel(II) Are Efficient Catalysts for the Polymerization and Oligomerization of Ethylene: Steric Activation and Ligand Backbone Effects Organometallics. 23: 6077-6079. DOI: 10.1021/Om0494014 |
0.393 |
|
| 2004 |
Higham LJ, Heslop K, Pringle PG, Orpen AG. 2,2′-Bis((di-tert-butylphosphino)methyl)-1,1′-biphenyl (ditbi): A bulky analogue of bisbi. The crystal structure of [Rh2Cl2(1,5-cod)2(μ-ditbi)] Journal of Organometallic Chemistry. 689: 2975-2978. DOI: 10.1016/J.Jorganchem.2004.06.029 |
0.429 |
|
| 2003 |
Alonso MA, Casares JA, Espinet P, Soulantica K, Orpen AG, Phetmung H. Conformational preferences driven by the C-methyl substituent in chelated o-diphenylphosphino-alpha-methyl-N,N-dimethylbenzylamine rhodium complexes. Inorganic Chemistry. 42: 3856-64. PMID 12793823 DOI: 10.1021/Ic034117A |
0.39 |
|
| 2003 |
Harvey JN, Heslop KM, Orpen AG, Pringle PG. Factors controlling the relative stabilities of cis- and trans-[PtX2L2] isomers: Chatt and Wilkins--50 years on. Chemical Communications (Cambridge, England). 278-9. PMID 12585429 DOI: 10.1039/B210939E |
0.481 |
|
| 2003 |
Charmant JPH, Norman NC, Orpen AG, Starbuck J. 4,4′-Bipyridyl adduct of an iodoantimonate anion linked by a 4,4′-bipyridinium cation Acta Crystallographica Section E: Structure Reports Online. 59: m997-m999. DOI: 10.1107/S1600536803022347 |
0.54 |
|
| 2003 |
Clarke ML, Orpen AG, Pringle PG, Turley E. Organometallic chemistry of bromodifluoromethyl substituted phosphines. The development of a novel nickel catalysed P-C bond forming reaction Dalton Transactions. 4393-4394. DOI: 10.1039/B311799E |
0.355 |
|
| 2003 |
Anderson KM, Baylies CJ, Monowar Jahan AHM, Norman NC, Orpen AG, Starbuck J. Coordination complexes of the bismuth(III) thiolates Bi(SC6F5)3 and Bi(SC6Cl5)3 with pyridine ligands Dalton Transactions. 3270-3277. DOI: 10.1039/B305711A |
0.651 |
|
| 2003 |
Baber RA, Norman NC, Orpen AG, Rossi J. The solid-state structure of diboronic acid, B2(OH)4 New Journal of Chemistry. 27: 773-775. DOI: 10.1039/B302496M |
0.525 |
|
| 2003 |
Adams CJ, Connelly NG, Emslie DJH, Hayward OD, Manson T, Orpen AG, Rieger PH. The substitution chemistry of the tris(3,5-dimethylpyrazolyl)-methanerhodium complex [Rh(CO)2{HC(pz′)3}]+ Dalton Transactions. 2835-2845. DOI: 10.1039/B302440G |
0.644 |
|
| 2003 |
Alonso E, Forniés J, Fortuñe C, Martín A, Orpen AG. Reactivity of [NBu4][(C6F5) 2M(μ-PPh2)2M′(acac-O,O′)] (M, M′ = Pt, Pd) toward Silver Centers. Synthesis of Polynuclear Complexes Containing M-Ag Bonds (M = Pd, Pt) Organometallics. 22: 5011-5019. DOI: 10.1021/Om034047F |
0.364 |
|
| 2003 |
Alonso E, Forniés J, Fortuño C, Martín A, Orpen AG. Synthesis of neutral and anionic tetranuclear clusters [Pt4(μ2-PPh2)3 {μ3-PPh(1,2-η2-Ph)-κ3P} (C6F5)4L] containing five coordinate P atoms and two Pt-Pt bonds Organometallics. 22: 2723-2728. DOI: 10.1021/Om030100O |
0.396 |
|
| 2003 |
Charmant JPH, Forniés J, Gómez J, Lalinde E, Merino RI, Moreno MT, Orpen AG. Synthesis and electrical and optical properties of [PtTl2-xLix(C6F5)2 (C≡CPh)2] (x = 0, 1) Organometallics. 22: 652-656. DOI: 10.1021/Om020972A |
0.368 |
|
| 2003 |
Baber RA, Clarke ML, Orpen AG, Ratcliffe DA. Synthesis and transition metal chemistry of 'phosphomide' ligands: A comparison of the reactivity and electronic properties of diphenyl-P-perfluoro-octanoyl-phosphine, P-acetyl-dyphenylphophine and P-anisoyl-diphenylphosphine. X-ray crystal structure of [RhCp*(Ph2PC(O)CH3)Cl2] Journal of Organometallic Chemistry. 667: 112-119. DOI: 10.1016/S0022-328X(02)02152-6 |
0.51 |
|
| 2003 |
Dennett JNL, Knox SAR, Charmant JPH, Gillon AL, Orpen AG. Synthesis and reactivity of μ-butadienyl diruthenium cations Inorganica Chimica Acta. 354: 29-40. DOI: 10.1016/S0020-1693(03)00391-8 |
0.419 |
|
| 2002 |
Adams CJ, Anderson KM, Connelly NG, Harding DJ, Orpen AG, Patron E, Rieger PH. The d2/d3 alkyne redox pair [WF2(PhC identical to CPh)Tp']z (z = +1 or 0): missing links in a 'redox family tree'. Chemical Communications (Cambridge, England). 130-1. PMID 12120337 DOI: 10.1039/B109535H |
0.526 |
|
| 2002 |
Norman NC, Orpen AG, Quayle MJ, Whittell GR. Chlorobis(triphenylphosphine)nickel(I). Acta Crystallographica. Section C, Crystal Structure Communications. 58: m160-1. PMID 11870288 DOI: 10.1107/S010827010200032X |
0.5 |
|
| 2002 |
Braga D, Desiraju GR, Miller JS, Orpen AG, Price SL. Innovation in crystal engineering Crystengcomm. 4: 500-509. DOI: 10.1039/B207466B |
0.449 |
|
| 2002 |
Adams CJ, Bartlett IM, Connelly NG, Harding DJ, Hayward OD, Martín AJ, Orpen AG, Quayle MJ, Rieger PH. Redox routes to arenechromium complexes of two-, three- and four-electron alkynes; structure and bonding in paramagnetic [Cr(CO)L(η-RC≡CR)(η-arene)]+ Journal of the Chemical Society, Dalton Transactions. 4281-4288. DOI: 10.1039/B206177P |
0.615 |
|
| 2002 |
Podesta TJ, Orpen AG. Use of the Ni(dithiooxalate)2 2- unit as a molecular tecton in crystal engineering Crystengcomm. 4: 336-342. DOI: 10.1039/B203138H |
0.376 |
|
| 2002 |
Hernández-Molina M, Lorenzo-Luis P, Ruiz-Pérez C, López T, Martín IR, Anderson KM, Orpen AG, Bocanegra EH, Lloret F, Julve M. A phase transition in the novel three-dimensional compound [Eu2(mal)3(H2O)6] (H2mal = malonic acid) Journal of the Chemical Society, Dalton Transactions. 3462-3470. DOI: 10.1039/B202649J |
0.338 |
|
| 2002 |
Pérez J, García L, Orpen AG, Santana MD, Saezc P, García G. Conformational analysis of complexes of 2,4,4-trimethyl-1,5,9-triazacyclododec-1-ene and its 9-methyl derivative New Journal of Chemistry. 26: 726-731. DOI: 10.1039/B200164K |
0.461 |
|
| 2002 |
Bellamy D, Connelly NG, Lewis GR, Orpen AG. Metallocenium salts of perhalophenylplatinate anions: Ion shape, charge and solvation effects on crystal structure Crystengcomm. 4: 68-79. DOI: 10.1039/B111164G |
0.592 |
|
| 2002 |
Connelly NG, Hayward OD, Klangsinsirikul P, Orpen AG. Novel dicarbonyl and carbonylnitrosyl tris(μ-triazenide) dirhodium complexes Journal of the Chemical Society, Dalton Transactions. 305-306. DOI: 10.1039/B109972H |
0.617 |
|
| 2002 |
Adams CJ, Anderson KM, Bartlett IM, Connelly NG, Orpen AG, Paget TJ. Ligand-induced and reductively induced alkyne-isocyanide coupling reactions of Mo(CnBut)3(PhC≡CPh)(η5-C5M e55)][BF4] Organometallics. 21: 3454-3463. DOI: 10.1021/Om020313Y |
0.568 |
|
| 2002 |
Bartolomé C, Espinet P, Vicente L, Villafañe F, Charmant JPH, Orpen AG. Neutral organometallic palladium(II) aquo complexes Organometallics. 21: 3536-3543. DOI: 10.1021/Om020198R |
0.439 |
|
| 2002 |
Serrano JL, Garcı́a L, Pérez J, Pérez E, Vives J, Sánchez G, López G, Molins E, Orpen A. Synthesis and characterization of new cyclometallated Pd(II) complexes with bridging or terminal imidato ligands. Crystal structures of [{Pd(μ-succinimide)(phpy)}2] and [Pd(azb)(succinimide)(PPh3)] (phpy = 2-phenylpyridine; azb=azobenzene) Polyhedron. 21: 1589-1596. DOI: 10.1016/S0277-5387(02)01041-0 |
0.342 |
|
| 2002 |
Adams CJ, Anderson KM, Connelly NG, Harding DJ, Orpen AG, Patron E, Rieger PH. The d2/d3 alkyne redox pair [WF2(PhC≡CPh)tp′]z (z = +1 or 0): Missing links in a 'redox family tree' Chemical Communications. 130-131. |
0.414 |
|
| 2001 |
Anderson KM, Connelly NG, Llamas-Rey E, Orpen AG, Paul RL. Control over directional metal-metal charge transfer in cyanide-bridged dimanganese complexes: effects of mu-CN linkage isomerism and ancillary ligand set. Chemical Communications (Cambridge, England). 1734-5. PMID 12240289 DOI: 10.1039/B104998B |
0.553 |
|
| 2001 |
Anderson KM, Kündig EP, Norman NC, Orpen AG, Pardoe JAJ, Smith DW, Timms PL. Dicarbonylbis(1,4-difluoro-2,3,5,6-tetramethyl-1,4-diboracyclohexa-2,5-diene)molybdenum Acta Crystallographica Section E Structure Reports Online. 57: m419-m420. DOI: 10.1107/S1600536801014167 |
0.509 |
|
| 2001 |
Anderson KM, Orpen AG. On the relative magnitudes of cis and trans influences in metal complexes Chemical Communications. 2682-2683. DOI: 10.1039/B108517B |
0.321 |
|
| 2001 |
Anderson KM, Connelly NG, Goodwin NJ, Lewis GR, Moreno MT, Orpen AG, Wood AJ. Cyanide-bridged complexes with Sn(II)Mn(I), Sn(II)Mn(II), Sn(IV)Mn(I) and Sn(IV)Mn(II) oxidation states Journal of the Chemical Society, Dalton Transactions. 1421-1427. DOI: 10.1039/B100721L |
0.615 |
|
| 2001 |
Orpen AG, Quayle MJ. Geometry variation of complex ions in crystals Journal of the Chemical Society, Dalton Transactions. 1601-1610. DOI: 10.1039/B100108F |
0.351 |
|
| 2001 |
Dossett SJ, Gillon A, Orpen AG, Fleming JS, Pringle PG, Wass DF, Jones MD. Steric activation of chelate catalysts: Efficient polyketone catalysts based on four-membered palladium(II) diphosphine chelates Chemical Communications. 699-700. DOI: 10.1039/B010063N |
0.364 |
|
| 2001 |
Connelly NG, Emslie DJH, Hayward OD, Orpen AG, Quayle MJ. Redox-active catecholate complexes of rhodium hydrotris(pyrazolyl)-borates Journal of the Chemical Society, Dalton Transactions. 875-880. DOI: 10.1039/B010061G |
0.59 |
|
| 2001 |
Adams CJ, Anderson KM, Bartlett IM, Connelly NG, Orpen AG, Paget TJ, Phetmung H, Smith DW. Molybdenum-based alkyne-isocyanide coupling reactions: Synthesis of a reactive diiminometallacyclopentene complex Journal of the Chemical Society, Dalton Transactions. 1284-1292. DOI: 10.1039/B010018H |
0.619 |
|
| 2001 |
Dolling B, Gillon AL, Orpen AG, Starbuck J, Wang XM. Homologous families of chloride-rich 4,4′-bipyridinium salt structures Chemical Communications. 567-568. DOI: 10.1039/B009467F |
0.32 |
|
| 2001 |
Connelly NG, Emslie DJH, Geiger WE, Hayward OD, Linehan EB, Orpen AG, Quayle MJ, Rieger PH. Redox-induced κ2-κ3 isomerisation in hydrotris(pyrazolyl)-boratorhodium complexes: Synthesis, structure and ESR spectroscopy of stabilised rhodium(II) species Journal of the Chemical Society, Dalton Transactions. 512-514. DOI: 10.1039/B008131K |
0.651 |
|
| 2001 |
Alonso E, Casas JM, Forniés J, Fortuño C, Martín A, Orpen AG, Tsipis CA, Tsipis AC. Synthesis of homo- or hetero-trinuclear palladium(II)/platinum(II) compounds with bridging phosphido ligands. Crystal and electronic structures (DFT) of [N(PPh3)2]2 [Pt3(μPPh2)4 (C6F5)4] and of its oxidation product [Pt3(C(6)F(5))4 (μ-PPh2)4] Organometallics. 20: 5571-5582. DOI: 10.1021/Om010407S |
0.403 |
|
| 2001 |
García-Herbosa G, Connelly NG, Muñoz A, Cuevas JV, Orpen AG, Politzer SD. Synthesis, structure, and electrochemistry of mononuclear and face-to-face binuclear orthometalated complexes of palladium(II) with N-monodentate or N(1),N(3)-bridging 1,3-di-p-tolyltriazenido ligands. Dependence on geometrical arrangement of the electronic communication between two equivalent redox sites Organometallics. 20: 3223-3229. DOI: 10.1021/Om010075R |
0.604 |
|
| 2001 |
Alonso E, Forniés J, Fortuño C, Martín A, Orpen AG. Reactivity of a secondary phosphine platinum(II) complex with [Pt(norbornene)3] and PPh3. Synthesis of new single phosphido-bridged derivatives of platinum(I) and phosphido-bridged platinum(II) hydrides Organometallics. 20: 850-859. DOI: 10.1021/Om0007973 |
0.358 |
|
| 2001 |
Anderson KM, Lesley MJG, Norman NC, Orpen AG, Quayle MJ, Rice CR, Starbuck J, Timms PL, Whittell GR. ChemInform Abstract: Recent Advances in Diborane(4) Chemistry Cheminform. 32: no-no. DOI: 10.1002/chin.200105271 |
0.407 |
|
| 2000 |
Alonso MA, Casares JA, Espinet P, Soulantica K, Charmant JP, Orpen AG. Rhodium complexes with the chelating and binucleating ligands P(CH2CH2Py)nPh3-n (Py = 2-pyridyl; n = 1,2): structures and fluxional behavior. Inorganic Chemistry. 39: 705-11. PMID 11272564 |
0.317 |
|
| 2000 |
Norman NC, Orpen AG, Quayle MJ, Rice CR. Three sulfur-containing diborane(4) compounds Acta Crystallographica. Section C, Crystal Structure Communications. 56: 440-4. PMID 10815202 DOI: 10.1107/S0108270199014778 |
0.528 |
|
| 2000 |
Norman NC, Orpen AG, Quayle MJ, Robins EG. Compositional disorder in trans- Acta Crystallographica. Section C, Crystal Structure Communications. 56: 50-2. PMID 10710666 DOI: 10.1107/S0108270199013554 |
0.503 |
|
| 2000 |
Gillon AL, Lewis GR, Orpen AG, Rotter S, Starbuck J, Wang X, Rodríguez-Martín Y, Ruiz-Pérez C. Organic–inorganic hybrid solids: control of perhalometallate solid state structures Journal of the Chemical Society-Dalton Transactions. 3897-3905. DOI: 10.1039/B005036I |
0.329 |
|
| 2000 |
Norman NC, Orpen AG, Quayle MJ, Rice CR. Diborane(4) compounds incorporating thio- and seleno-carboranyl groups New Journal of Chemistry. 24: 837-839. DOI: 10.1039/B004942P |
0.476 |
|
| 2000 |
Fernandez E, Gillon A, Heslop K, Horwood E, Hyett DJ, Orpen AG, Pringle PG. Rationally designed improvement of the bis(phospholano)ethane ligand for asymmetric hydrogenation leads to a reappraisal of the factors governing the enantioselectivity of Duphos catalysts Chemical Communications. 1663-1664. DOI: 10.1039/B002994G |
0.411 |
|
| 2000 |
Carraz CA, Ditzel EJ, Orpen AG, Ellis DD, Pringle PG, Sunley GJ. Rhodium(I) complexes of unsymmetrical diphosphines: Efficient and stable methanol carbonylation catalysts Chemical Communications. 1277-1278. DOI: 10.1039/B002802I |
0.308 |
|
| 2000 |
James SC, Norman NC, Orpen AG, Starbuck J. Crystal synthesis using secondary and dative coordinate bonding: 4,4'-bipyridyl adducts of arylbismuth dihalides Crystengcomm. 2: 67-72. DOI: 10.1039/B001874K |
0.615 |
|
| 2000 |
Connelly NG, Hayward OD, Klangsinsirikul P, Orpen AG, Rieger PH. Redox-active heterobinuclear triazenide-bridged complexes; Ancillary ligand control of electron distribution in a three-electron metal-metal bond Chemical Communications. 963-964. DOI: 10.1039/B001764G |
0.596 |
|
| 2000 |
King PJ, Knox SAR, Leggc MS, Orpen AG, Wilkinson JN, Hill EA. Transformation of dimethyl acetylenedicarboxylate to bis(methylcarboxylate)vinylidene at a diruthenium centre: Unprecedented 1,2-migration of a CO2Me group Journal of the Chemical Society, Dalton Transactions. 1547-1548. DOI: 10.1039/B001666G |
0.383 |
|
| 2000 |
Espinet P, Soulantica K, Charmant JPH, Orpen AG. 1,2-phenylene diisocyanide for metallotriangles Chemical Communications. 915-916. DOI: 10.1039/B001027H |
0.342 |
|
| 2000 |
Lesley MJG, Norman NC, Orpen AG, Starbuck J. Synthetic routes to cyclic and unsymmetric diborane(4) compounds New Journal of Chemistry. 24: 115-117. DOI: 10.1039/A909645K |
0.458 |
|
| 2000 |
Ellis DD, Harrison G, Orpen AG, Phetmung H, Pringle PG, deVries JG, Oevering H. Platinum(II), palladium(II) and rhodium(I) complexes of o-, m- and p-Ph2PC6H4PO(OEt)2. PtCl2–SnCl2 Hydroformylation catalysts modified with phosphonated triarylphosphines Journal of the Chemical Society-Dalton Transactions. 671-675. DOI: 10.1039/A908963B |
0.362 |
|
| 2000 |
Cobley CJ, Ellis DD, Orpen AG, Pringle PG. Rhodium(I) complexes of robust phosphites derived from calix[4]arenes and their application in the hydroformylation of 1-hexene Journal of the Chemical Society-Dalton Transactions. 7: 1109-1112. DOI: 10.1039/A908961F |
0.483 |
|
| 2000 |
Cobley CJ, Ellis DD, Orpen AG, Pringle PG. Calix[4]arene derived phosphites: their hydrolytic stability and complexes with gold(I), platinum(II,0), palladium(II) and iridium(I) Journal of the Chemical Society-Dalton Transactions. 1101-1107. DOI: 10.1039/A908960H |
0.504 |
|
| 2000 |
Alonso E, Forniés J, Fortuño C, Martín A, Orpen AG. Polynuclear Homo- or Heterometallic Palladium(II)−Platinum(II) Pentafluorophenyl Complexes Containing Bridging Diphenylphosphido Ligands. 8.†Syntheses and Reactivity of the Tetranuclear [Pt4(μ2-PPh2)3{μ3-PPh(1,2-η2-Ph)-κ3P}(C6F5)4] Cluster Organometallics. 19: 2690-2697. DOI: 10.1021/Om000140H |
0.445 |
|
| 2000 |
Deeming AJ, Hogarth G, Lee M(, Saha M, Redmond SP, Phetmung H(, Orpen A. para-Ethynyl aniline as a building block for fully π-conjugated ligands and acetylide complexes: crystal structures of trans-[Pt(PPh3)2(CCC6H4NH2)2] and [(μ-H)Ru3(CO)9(μ3-CCC6H4NH2)] Inorganica Chimica Acta. 309: 109-122. DOI: 10.1016/S0020-1693(00)00254-1 |
0.473 |
|
| 2000 |
Espinet P, Hernando R, Iturbe G, Villafañe F, Orpen AG, Pascual I. Structure and dynamic behavior of (η3- allyl)bromodicarbonylmolybdenum(II) complexes containing polydentate 2- pyridylphosphanes or their oxides as chelating ligands: Occurrence of three fluxional processes European Journal of Inorganic Chemistry. 1031-1038. DOI: 10.1002/(Sici)1099-0682(200005)2000:5<1031::Aid-Ejic1031>3.0.Co;2-D |
0.467 |
|
| 1999 |
Charmant JP, Forniés J, Gómez J, Lalinde E, Moreno MT, Orpen AG, Solano S. Double Insertion of Coordinated Phosphanylalkyne Ligands into a Pt-C(6)F(5) Bond. Angewandte Chemie (International Ed. in English). 38: 3058-3061. PMID 10540421 DOI: 10.1002/(Sici)1521-3773(19991018)38:20<3058::Aid-Anie3058>3.0.Co;2-7 |
0.453 |
|
| 1999 |
Chui SS, Lo SM, Charmant JP, Orpen AG, Williams ID. A chemically functionalizable nanoporous material Science (New York, N.Y.). 283: 1148-50. PMID 10024237 DOI: 10.1126/Science.283.5405.1148 |
0.672 |
|
| 1999 |
Chui SSY, Lo SMF, Charmant JPH, Orpen AG, Williams ID. A chemically functionalizable nanoporous material [Cu3(TMA)2 (H2O)3](n) Science. 283: 1148-1150. DOI: 10.1126/science.283.5405.1148 |
0.317 |
|
| 1999 |
Bartlett IM, Carlton S, Connelly NG, Harding DJ, Hayward OD, Orpen AG, Ray CD, Rieger PH. Structure and bonding in the d4/d3 alkyne redox pairs [WX(CO)(MEC≡CMe)Tp'](z) (X = F, Cl, Br and I; z = 0 and 1): Halide stabilisation of electron deficient metal alkyne complexes Chemical Communications. 2403-2404. DOI: 10.1039/A907912B |
0.585 |
|
| 1999 |
Gillon AL, Orpen AG, Starbuck J, Wang XM, Rodríguez-Martín Y, Ruiz-Pérez C. Cation-controlled formation of [{MCl4}(n)](2n-) chains in [4,4'- H2bipy][MCl4] (M = Mn, Cd): An alternative to the A2MCl4 <100> layer perovskite structure Chemical Communications. 2287-2288. DOI: 10.1039/A907681F |
0.307 |
|
| 1999 |
Anderson KM, Lesley MJG, Norman NC, Orpen AG, Starbuck J. The platinum catalysed diboration of alkynes using 1,2- B2Cl2(NMe2)2: Formation of 1-azonia-2-borata-5-borole derivatives New Journal of Chemistry. 23: 1053-1055. DOI: 10.1039/A907255A |
0.465 |
|
| 1999 |
Starbuck J, Norman NC, Orpen AG. Secondary bonding as a potential design element for crystal engineering New Journal of Chemistry. 23: 969-972. DOI: 10.1039/A906352H |
0.525 |
|
| 1999 |
Crocker M, Herold RHM, Orpen AG, Overgaag MTA. Synthesis and characterisation of titanium silasesquioxane complexes: Soluble models for the active site in titanium silicate epoxidation catalysts Journal of the Chemical Society - Dalton Transactions. 3791-3804. DOI: 10.1039/A905887G |
0.485 |
|
| 1999 |
Bellamy D, Brown NC, Connelly NG, Orpen AG. The synthesis and structure of a paramagnetic Lewis base adduct of antimony pentachloride, trans-[MnII(CNSbCl5)(CO)2{P(OEt) 3}-(dppm)][SbCl6] Journal of the Chemical Society - Dalton Transactions. 3191-3195. DOI: 10.1039/A902481F |
0.631 |
|
| 1999 |
Bellamy D, Connelly NG, Hicks OM, Orpen AG. Triphenylboron adducts of redox-active cyanomanganese ligands Journal of the Chemical Society - Dalton Transactions. 3185-3190. DOI: 10.1039/A902478F |
0.664 |
|
| 1999 |
Marder TB, Norman NC, Orpen AG, Quayle MJ, Rice CR. Crystalline TCNQ and TCNE adducts of the diborane(4) compounds B2(1,2-E2C6H4)2 (E = O or S) Journal of the Chemical Society - Dalton Transactions. 2127-2132. DOI: 10.1039/A901169B |
0.603 |
|
| 1999 |
James SC, Norman NC, Orpen AG. Pyridine adducts of arylbismuth(III) halides Journal of the Chemical Society - Dalton Transactions. 2837-2843. DOI: 10.1039/A900823C |
0.596 |
|
| 1999 |
Curtis D, Lesley MJG, Norman NC, Orpen AG, Starbuck J. Phosphine exchange reactions involving cis-[Pt(PPh3)2(Bcat)2] (cat = 1,2-O2C6H4) and the oxidative addition of 1,2-B2Cl2(NMe2)2 to Pt0 Journal of the Chemical Society - Dalton Transactions. 1687-1694. DOI: 10.1039/A810006C |
0.591 |
|
| 1999 |
Bartlett IM, Connelly NG, Martín AJ, Orpen AG, Paget TJ, Rieger AL, Rieger PH. Oxidatively induced isomerisation of vinylidene ligands to alkynes: ESR spectra of paramagnetic vinylidene and alkyne arene metal complexes Journal of the Chemical Society - Dalton Transactions. 691-698. DOI: 10.1039/A809451I |
0.643 |
|
| 1999 |
Alder RW, Carniero TMG, Mowlam RW, Orpen AG, Petillo PA, Vachon DJ, Weisman GR, White JM. Evidence for hydrogen-bond enhanced structural anomeric effects from the protonation of two aminals, 5-methyl-1,5,9-triazabicyclo-[7.3.1]tridecane and 1,4,8,11-tetraazatricyclo[9.3.1.14,8]hexadecane Journal of the Chemical Society. Perkin Transactions 2. 589-599. DOI: 10.1039/A807954D |
0.324 |
|
| 1999 |
Lesley MJG, Mock U, Norman NC, Orpen AG, Rice CR, Starbuck J. Synthesis and X-ray structure of a [4]ferrocenophane containing a boron-boron bond Journal of Organometallic Chemistry. 582: 116-118. DOI: 10.1016/S0022-328X(98)01194-2 |
0.578 |
|
| 1999 |
Lesley MJG, Clegg W, Marder TB, Norman NC, Orpen AG, Scott AJ, Starbuck J. Three PtII catecholate and 1,2-dithio-catecholate complexes Acta Crystallographica Section C: Crystal Structure Communications. 55: 1272-1275. |
0.622 |
|
| 1998 |
James SC, Norman NC, Orpen AG. [Ti2(O-2,4,6-Me3C6H2)2(OiPr)4(μ-OiPr)2] Acta Crystallographica Section C Crystal Structure Communications. 54: 1261-1263. DOI: 10.1107/S0108270198003461 |
0.456 |
|
| 1998 |
Hodge P, James SC, Norman NC, Orpen AG. Neutral and anionic aryloxy halides of bismuth(III) Journal of the Chemical Society - Dalton Transactions. 4049-4054. DOI: 10.1039/A806647G |
0.605 |
|
| 1998 |
Bois H, Connelly NG, Crossley JG, Guillorit JC, Lewis GR, Orpen AG, Thornton P. Structural studies of [Pt(CNMe)4][M(mnt)2]n {M = Pd or Pt, mnt = [S2C2(CN)2]2-, n = 1 or 2}: Structure-dependent paramagnetism of three crystal forms of [Pt(CNMe)4][Pt(mnt)2]2 Journal of the Chemical Society - Dalton Transactions. 2833-2838. DOI: 10.1039/A803456G |
0.532 |
|
| 1998 |
Alder RW, Allen PR, Anderson KR, Butts CP, Khosravi E, Martín A, Maunder CM, Orpen AG, St. Pourçain CB. Conformational control by quaternary centres: Theory, database evidence and application to polymers Journal of the Chemical Society. Perkin Transactions 2. 2083-2107. DOI: 10.1039/A802623H |
0.337 |
|
| 1998 |
Connelly NG, Hicks OM, Lewis GR, Moreno MT, Orpen AG. Novel N-bound thallium(I) complexes of redox-active cyanomanganese carbonyl ligands: cyanide as a µ3-κC∶κN∶κN triply bridging ligand Journal of the Chemical Society-Dalton Transactions. 1913-1918. DOI: 10.1039/A800765I |
0.642 |
|
| 1998 |
Connelly NG, Lewis GR, Moreno MT, Orpen AG. Zinc, cadmium and mercury complexes of redox-active cyanomanganese carbonyl ligands: intramolecular electron transfer through tetrahedral d10 metal centres Journal of the Chemical Society-Dalton Transactions. 1905-1912. DOI: 10.1039/A800762D |
0.662 |
|
| 1998 |
Clegg W, Johann TRF, Marder TB, Norman NC, Orpen AG, Peakman TM, Quayle MJ, Rice CR, Scott AJ. Platinum-catalysed 1,4-diboration of 1,3-dienes Journal of the Chemical Society-Dalton Transactions. 1431-1438. DOI: 10.1039/A800108A |
0.568 |
|
| 1998 |
Aullón G, Bellamy D, Orpen AG, Brammer L, Bruton EA. Metal-bound chlorine often accepts hydrogen bonds Chemical Communications. 6: 653-654. DOI: 10.1039/A709014E |
0.772 |
|
| 1998 |
Connelly NG, Orpen AG. Tetrahedral chlorometal derivatives of redox-active cyanomanganese ligands: synthesis, structures and solvatochromic properties of a new class of cyanide-bridged complexes Chemical Communications. 517-518. DOI: 10.1039/A707541C |
0.621 |
|
| 1998 |
Clegg W, Lawlor FJ, Marder TB, Nguyen P, Norman NC, Orpen AG, Quayle MJ, Rice CR, Robins EG, Scott AJ, Souza FES, Stringer G, Whittell GR. Boron–boron bond oxidative addition to rhodium(I) and iridium(I) centres Journal of the Chemical Society-Dalton Transactions. 301-309. DOI: 10.1039/A705374F |
0.568 |
|
| 1998 |
Dai C, Johnson SM, Lawlor FJ, Lightfoot P, Marder TB, Norman NC, Orpen AG, Pickett NL, Quayle MJ, Rice CR. 2,2′-Bipyridyl and 1,10-phenanthroline adducts of the diborane (4) compound B2 (1,2-S2C6H4)2 Polyhedron. 17: 4139-4143. DOI: 10.1016/S0277-5387(98)00221-6 |
0.671 |
|
| 1998 |
Charmant JP, Dickson HA, Grist NJ, Knox SA, Orpen A, Saynor K, Viñas JM. Linking of benzyne and carbon monoxide at a triruthenium centre by migratory insertion Journal of Organometallic Chemistry. 565: 141-151. DOI: 10.1016/S0022-328X(98)00448-3 |
0.471 |
|
| 1998 |
Orpen A, Pringle PG, Smith MB, Worboys K. Synthesis and properties of new tris(cyanoethyl)phosphine complexes of platinum (0,II), palladium (0,II), iridium (I) and rhodium (I). Journal of Organometallic Chemistry. 550: 255-266. DOI: 10.1016/S0022-328X(97)00541-X |
0.455 |
|
| 1998 |
Clegg W, Lawlor FJ, Lesley G, Marder TB, Norman NC, Orpen A, Quayle MJ, Rice CR, Scott AJ, Souza FE. Oxidative addition of boron–boron, boron–chlorine and boron–bromine bonds to platinum(0)1Dedicated to Professor Ken Wade on the occasion of his 65th birthday and in recognition of his outstanding contributions to the understanding of the chemistry of boron.1 Journal of Organometallic Chemistry. 550: 183-192. DOI: 10.1016/S0022-328X(97)00233-7 |
0.683 |
|
| 1998 |
Budzelaar PHM, Van Oort AB, Orpen AG. β-diiminato complexes of VIII and TiIII - Formation and structure of stable paramagnetic dialkylmetal compounds European Journal of Inorganic Chemistry. 1485-1494. DOI: 10.1002/(Sici)1099-0682(199810)1998:10<1485::Aid-Ejic1485>3.0.Co;2-F |
0.363 |
|
| 1997 |
Crocker M, Herold RHM, Orpen AG. Synthesis and structural characterisation of tripodal titanium silsesquioxane complexes: a new class of highly active catalysts for liquid phase alkene epoxidation Chemical Communications. 2411-2412. DOI: 10.1039/A704969B |
0.325 |
|
| 1996 |
James SC, Norman NC, Orpen AG, Quayle MJ, Weckenmann U. Novel structural forms for imidoamides and oxoalkoxides of bismuth Journal of the Chemical Society-Dalton Transactions. 4159-4161. DOI: 10.1039/Dt9960004159 |
0.558 |
|
| 1996 |
Brown NC, Carpenter GB, Connelly NG, Crossley JG, Martín A, Orpen AG, Rieger AL, Rieger PH, Worth GH. Intramolecular electron transfer in linear trinuclear complexes of copper(I), silver(I) and gold(I) bound to redox-active cyanomanganese ligands Journal of the Chemical Society-Dalton Transactions. 3977-3984. DOI: 10.1039/Dt9960003977 |
0.591 |
|
| 1996 |
Atkinson FL, Blackwell HE, Brown NC, Connelly NG, Crossley JG, Orpen AG, Rieger AL, Rieger PH. Synthesis of the 17-electron cations [FeL(L′)(NO)2]+(L, L′= PPh3, OPPh3): structure and bonding in four-co-ordinate metal dinitrosyls, and implications for the identity of paramagnetic iron dinitrosyl complex catalysts Journal of the Chemical Society-Dalton Transactions. 3491-3502. DOI: 10.1039/Dt9960003491 |
0.616 |
|
| 1996 |
Brauers G, Feher FJ, Green M, Hogg JK, Orpen AG. Reaction of the η2(4e)-donor alkyne complexes [Mo{η2(4e)-R1C2R2}{P(OMe)3}2(η-C5H5)](R1= R2= Ph or Me; R1= Me, R2= Ph) with the Grignard reagents MgR3(X)(R3= Me, Et, CH2Ph, CH2CHCH2or CHCH2) and CH2(MgI)2 Journal of the Chemical Society-Dalton Transactions. 3387-3396. DOI: 10.1039/Dt9960003387 |
0.446 |
|
| 1996 |
Mole L, Spencer JL, Litster SA, Redhouse AD, Carr N, Orpen AG. Synthesis and characterization of cationic dinuclear complexes of platinum with bridging hydrides; crystal structures of [Pt2(µ-H)2{But2P(CH2)3PBut2}2][BF4]2 and [Pt2(µ-H)2{(C6H11)2P(CH2)3P(C6H11)2}2][BF4]2 Journal of the Chemical Society-Dalton Transactions. 2315-2321. DOI: 10.1039/Dt9960002315 |
0.448 |
|
| 1996 |
Atkinson FL, Brown NC, Connelly NG, Orpen AG, Rieger AL, Rieger PH, Rosair GM. Paramagnetic Tetrahedral Dinitrosyliron Complexes Containing Redox-Active Cyanomanganese Ligands Journal of the Chemical Society-Dalton Transactions. 1959-1966. DOI: 10.1039/Dt9960001959 |
0.604 |
|
| 1996 |
Adams KJ, Barker JJ, Knox SAR, Orpen AG. Linking And Fragmentation Of Alkynes At A Triruthenium Centre Journal of the Chemical Society-Dalton Transactions. 975-988. DOI: 10.1039/Dt9960000975 |
0.428 |
|
| 1996 |
Farrugia LJ, Senior AM, Braga D, Grepioni F, Orpen AG, Crossley JG. Dynamic disorder in crystalline [Fe2Os(CO)12] and direct evidence for rotation of the Fe2Os triangle in the solid state from variable temperature X-ray diffraction and 13C MAS NMR studies Journal of the Chemical Society-Dalton Transactions. 631-641. DOI: 10.1039/Dt9960000631 |
0.485 |
|
| 1996 |
Bartlett IM, Connelly NG, Orpen AG, Quayle MJ, Rankin JC. Structure and bonding in redox-active d4, d5 and d6 alkyne complexes: metal–alkyne moieties as electron sinks Chemical Communications. 2583-2584. DOI: 10.1039/Cc9960002583 |
0.582 |
|
| 1996 |
Connelly NG, Emslie DJH, Metz B, Orpen AG, Quayle MJ. Redox-induced κ2–κ3 isomerisation in rhodium hydrotris(3,5-dimethylpyrazolyl)borate chemistry: the stabilisation of square-pyramidal rhodium(II) Chemical Communications. 2289-2290. DOI: 10.1039/Cc9960002289 |
0.596 |
|
| 1996 |
Bartlett IM, Connelly NG, Legge MS, Martín AJ, Metz B, Orpen AG. Oxidatively induced carbon chain growth at a ditungsten centre Chemical Communications. 1877-1878. DOI: 10.1039/Cc9960001877 |
0.616 |
|
| 1996 |
Alder RW, Ellis DD, Orpen AG, Taylor PN. Bicyclic medium-ring diphosphines: contrasting behaviour in the bicyclo[3.3.3]undecane and bicyclo[4.4.4]tetradecane series Chemical Communications. 1996: 539-540. DOI: 10.1039/Cc9960000539 |
0.367 |
|
| 1996 |
Alonso E, Forniés J, Fortuño C, Martín A, Orpen AG. Synthesis and characterization of [NBu4][Pt3(µ-PPh2)2(C6F5)5]: an anionic cluster containing an unusual µ3-PPh2 bridging system Chemical Communications. 231-232. DOI: 10.1039/Cc9960000231 |
0.379 |
|
| 1996 |
Albéniz AC, Espinet P, Lin Y, Orpen AG, Martín A. Insertion of Alkenyl Sulfides into a Palladium−Aryl Bond. 1. Synthesis and Evolution of a Three-Membered Thiopalladacycle. X-ray Crystal Structure of a New Tetrameric Palladium Derivative with Bridging (Phenylthio)alkyl Ligands Organometallics. 15: 5003-5009. DOI: 10.1021/om960406d |
0.311 |
|
| 1996 |
Connelly NG, Metz B, Orpen AG, Rieger PH. Synthesis, Reactions, and Molecular and Electronic Structure of the Radical Cation [Mo2(μ-C8Me8)(η-C5H5)2]+: An Intermediate in the Redox Activation of an Alkyl C−H Bond Organometallics. 15: 729-735. DOI: 10.1021/om950529i |
0.307 |
|
| 1996 |
James SL, Orpen A, Pringle PG. Diphosphine analogues of proton sponge: X-ray crystal structure of [Pd(η3-allyl)(dppn)]BF4·CH2Cl2 (dppn = 1,8-bis(diphenylphosphino)naphthalene) Journal of Organometallic Chemistry. 525: 299-301. DOI: 10.1016/S0022-328X(96)06451-0 |
0.384 |
|
| 1996 |
Hogarth G, Knox SA, Lloyd BR, Macpherson KA, Morton DA, Orpen A. Reactivity of bis(diphenylphosphino) methane at a di-iron centre: thermally induced rearrangements of dimetallacyclopentenone complexes [Fe2(CO)5{μ-σ:η3-C(O)CRCr}(μ-dppm)] Inorganica Chimica Acta. 251: 167-176. DOI: 10.1016/S0020-1693(96)05269-3 |
0.412 |
|
| 1996 |
Alder RW, Allen PR, Murray M, Orpen AG. Bis(diisopropylamino)carbene Angewandte Chemie International Edition in English. 35: 1121-1123. DOI: 10.1002/Anie.199611211 |
0.422 |
|
| 1995 |
Cuevas JV, García-Herbosa G, Muñoz MA, Hickman SW, Orpen AG, Connelly NG. Dalton communications: Synthesis, structural characterisation and electrochemistry of the tetranuclear compound [{Pd2(μ-RNNNR)2}2(μ-Cl)4] (R = C6H4Me-p): A precursor to triazenido-bridged palladium(II) complexes Journal of the Chemical Society, Dalton Transactions. 4127-4128. DOI: 10.1039/Dt9950004127 |
0.605 |
|
| 1995 |
Braga D, Grepioni F, Tedesco E, Orpen AG. Crystal construction and molecular recognition for [Cr(CO)6] Journal of the Chemical Society-Dalton Transactions. 1215-1220. DOI: 10.1039/Dt9950001215 |
0.463 |
|
| 1995 |
Baker MJ, Giles MF, Orpen AG, Taylor MJ, Watt RJ. Cis-[RhI(CO)(Ph2PCH2P(S)Ph2)]: A new catalyst for methanol carbonylation Journal of the Chemical Society, Chemical Communications. 197-198. DOI: 10.1039/C39950000197 |
0.327 |
|
| 1995 |
Fornies J, Menjon B, Sanz-Carrillo RM, Tomas M, Connelly NG, Crossley JG, Orpen AG. Synthesis and Structural Characterization of the First Isolated Homoleptic Organoplatinum(IV) Compound: [Pt(C6Cl5)4] Journal of the American Chemical Society. 117: 4295-4304. DOI: 10.1021/Ja00120A011 |
0.53 |
|
| 1995 |
Knox SAR, Lloyd BR, Morton DAV, Orpen AG, Turner ML, Hogarth G. Reactions of [Fe2(CO)6(μ-CO)(μ-dppm)] with alkynes: Stepwise synthesis of tropone at a dinuclear metal centre Polyhedron. 14: 2723-2743. DOI: 10.1016/0277-5387(95)00145-I |
0.347 |
|
| 1995 |
Connelly NG, Escher T, Martin AJ, Metz B, Orpen AG. The reductive dimerization of [W(NCMe)(MeC2Me)2(η-C5H5)]+: Synthesis and X-ray structure of the novel bis(metallacyclopentadiene) complex [W2(μ-σ,σ,η2,η2-C4Me4)2(η-C5H5)2] Journal of Cluster Science. 6: 125-134. DOI: 10.1007/Bf01175840 |
0.571 |
|
| 1994 |
Connelly NG, Einig T, Herbosa GG, Hopkins PM, Mealli C, Orpen AG, Rosair GM, Viguri F. New synthetic routes to face-to-face and open-book triazenide-bridged dirhodium bipyridyl complexes with the [rh2]4+ core Journal of the Chemical Society, Dalton Transactions. 2025-2039. DOI: 10.1039/Dt9940002025 |
0.676 |
|
| 1994 |
Crispini A, Errington RJ, Fisher GA, Funke FJ, Norman NC, Orpen AG, Stratford SE, Struve O. Synthetic and structural studies on bismuth(III) thiocyanate and selenocyanate complexes Journal of the Chemical Society, Dalton Transactions. 1327-1335. DOI: 10.1039/Dt9940001327 |
0.647 |
|
| 1994 |
Atkinson FL, Connelly NG, Crossley JG, Orpen AG. Arenediazonium ion insertion into an iron-phosphine bond; synthesis and crystal structure of [Fe(NO)2{PPh2CH2CH2P(Ph) 2NN(C6H4F-p)}][PF6]·OC 4H8 Journal of the Chemical Society, Dalton Transactions. 1161-1162. DOI: 10.1039/Dt9940001161 |
0.579 |
|
| 1994 |
Adams KJ, Barker JJ, Charmant JPH, Ganter C, Klatt G, Knox SAR, Orpen AG, Ruile S. Tri- and tetra-nuclear μ-alkyne clusters from [Ru2(μ-CO)(μ-C2R2)(η-C 5H5)2] (R = Ph or CF3) Journal of the Chemical Society, Dalton Transactions. 477-484. DOI: 10.1039/Dt9940000477 |
0.409 |
|
| 1994 |
Carmalt CJ, Crossley JG, Knight JG, Lightfoot P, Martín A, Muldowney MP, Norman NC, Orpen AG. An examination of the structures of iodosylbenzene (PhIO) and the related imido compound, PhINSO2-4-Me-C6H4, by X-ray powder diffraction and EXAFS (extended X-ray absorption fine structure) spectroscopy Journal of the Chemical Society, Chemical Communications. 2367-2368. DOI: 10.1039/C39940002367 |
0.56 |
|
| 1994 |
Connelly NG, Metz B, Orpen AG. The stable radical cation [Mo2(μ-C8Me 8)(η-C5H5)2]+: An intermediate in the redox activation of an alkyl C-H bond and a probe of metal-alkene bonding Journal of the Chemical Society, Chemical Communications. 2109-2110. DOI: 10.1039/C39940002109 |
0.619 |
|
| 1994 |
Braga D, Grepioni F, Orpen AG. Ni(CO)4 and Fe(CO)5. A Study of Molecular Recognition and Crystal Construction Organometallics. 13: 3544-3556. DOI: 10.1021/Om00021A030 |
0.379 |
|
| 1994 |
Boyd DC, Connelly NG, Herbosa GG, Hill MG, Mann KR, Mealli C, Orpen AG, Richardson KE, Rieger PH. Electronic Structure of Ligand-Bridged Complexes Containing the [Rh2]3+ Core: ESR Spectroscopy, MO Calculations, and X-ray Structures of the Three Redox Pairs [Rh2(CO)2LL'{.mu.-PhNC(Me)NPh}2]z [z = 0, 1; L = L' = PPh3, P(OPh)3; L = PPh3, L' = P(OPh)3] Inorganic Chemistry. 33: 960-971. DOI: 10.1021/Ic00083A021 |
0.524 |
|
| 1994 |
Bardwell DA, Crossley JG, Jeffery JC, Orpen A, Psillakis E, Tilley EE, Ward MD. A study of crystal packing in a series of closely related square-planar palladium(II) and platinum(II) complexes Polyhedron. 13: 2291-2300. DOI: 10.1016/S0277-5387(00)88139-5 |
0.446 |
|
| 1994 |
Connelly NG, Crossley JG, Orpen AG, Salter H. The co-stacking of a planar metal complex and a novel 1,3-dithiole: The synthesis and crystal structure of [Pt(mnt)(CNMe)2]·(NC)2C2S2 Journal of Organometallic Chemistry. 480: c12-c13. DOI: 10.1016/0022-328X(94)87132-9 |
0.591 |
|
| 1994 |
Hogg JK, James SL, Orpen A, Pringle PG. Chelating diphos ligands with inorganic backbones. Crystal structure of [PtCl2{(PPh2O)2SiPh2}] Journal of Organometallic Chemistry. 480: c1-c3. DOI: 10.1016/0022-328X(94)87128-0 |
0.444 |
|
| 1994 |
Bardaji M, Brown NC, Connelly NG, Davies R, Orpen AG, Rosair GM, Seear NR. Low-valent metal complexes as redoxactive ligands: New heteropolynuclear derivatives of manganese and rhenium cyanides and the crystal structure of [(o-phen) (OC)3Re(μ-CN)-Ru(CO)2(PPh3)(o-O2C6Cl4)] Journal of Organometallic Chemistry. 474: C21-C23. DOI: 10.1016/0022-328X(94)84078-4 |
0.606 |
|
| 1993 |
Harrison CC, Li X, Hopkinson I, Stratford SE, Orpen AG. Ultraviolet–visible–near-infrared and EXAFS study of CoIIcoordination chemistry in post-doped silica sol–gel glasses J. Chem. Soc., Faraday Trans.. 89: 4115-4122. DOI: 10.1039/Ft9938904115 |
0.314 |
|
| 1993 |
Carriedo GA, Connelly NG, Perez-Carreno E, Orpen AG, Rieger AL, Rieger PH, Riera V, Rosair GM. Structure and bonding in low-spin octahedral manganese(II) carbonyls: Ligand-set control of spin delocalisation Journal of the Chemical Society, Dalton Transactions. 3103-3110. DOI: 10.1039/Dt9930003103 |
0.587 |
|
| 1993 |
Barker JJ, Orpen AG, Seeley AJ, Timms PL. Crystal structure of [W(η-C6F6)2] synthesised together with other sandwich complexes of tungsten and molybdenum containing η6-C6F6 or η6-C6H3F3-1,3,5 ligands, from atoms of the metals Journal of the Chemical Society-Dalton Transactions. 3097-3102. DOI: 10.1039/Dt9930003097 |
0.436 |
|
| 1993 |
Clegg W, Farrugia LJ, McCamley A, Norman NC, Orpen AG, Pickett NL, Stratford SE. Structural studies on bismuth–iodide–hexamethyl-phosphoramide complexes by X-ray crystallography and extended X-ray absorption fine structure spectroscopy Journal of the Chemical Society-Dalton Transactions. 2579-2587. DOI: 10.1039/Dt9930002579 |
0.595 |
|
| 1993 |
Brammer L, Dunne BJ, Green M, Moran G, Orpen AG, Reeve C, Schaverien CJ. Reactions of co-ordinated ligands. Part 55. Molybdenummediated addition of alkynes to cyclooctatetraene; one-electron oxidation and protonation of η3-allyl(η4-1,3-diene)(η-cyclopentadienyl or η5-indenyl) molybdenum complexes, and crystal structures of [Mo(η3,η4-C12H13)(η-C5H5)], [Mo(η2,η4-C14H17)(η-C5H5)][BF4] and [Mo(η2,η4-C12H13)(µMo,C-H)(η5-C9H7)][CF3SO3] Journal of the Chemical Society-Dalton Transactions. 1747-1759. DOI: 10.1039/Dt9930001747 |
0.657 |
|
| 1993 |
Atkinson FL, Christofides A, Connelly NG, Lawson HJ, Loyns AC, Orpen AG, Rosair GM, Worth GH. Spin delocalisation and the geometry of redox-active cyanomanganesecarbonyl ligands in heteropolynuclear complexes of rhodium(I) Journal of the Chemical Society, Dalton Transactions. 1441-1450. DOI: 10.1039/Dt9930001441 |
0.626 |
|
| 1993 |
Garner SE, Orpen AG. Structural systematics. Part 5. Conformation and bonding in the chiral metal complexes [M(η5-C5R5)(XO)Z(PPh3)] Journal of the Chemical Society-Dalton Transactions. 533-541. DOI: 10.1039/Dt9930000533 |
0.432 |
|
| 1993 |
Brady LA, Dyke AF, Garner SE, Knox SAR, Irving A, Nicholls SM, Orpen AG. Oligomerisation of alkynes at a diruthenium centre Journal of the Chemical Society, Dalton Transactions. 487-488. DOI: 10.1039/Dt9930000487 |
0.343 |
|
| 1993 |
De With J, Horton AD, Orpen AG. Unusual [2 + 2] cycloaddition adducts of an imidovanadium complex with alkynes and ethene: conversion to .eta.3-1-azaallyl and ethenyl complexes Organometallics. 12: 1493-1496. DOI: 10.1021/Om00029A003 |
0.393 |
|
| 1993 |
Braga D, Grepioni F, Orpen AG. Nickel carbonyl [Ni(CO)4] and iron carbonyl [Fe(CO)5]: molecular structures in the solid state Organometallics. 12: 1481-1483. DOI: 10.1021/Om00028A082 |
0.382 |
|
| 1993 |
Carmalt CJ, Norman NC, Orpen A, Stratford SE. A cationic, four-coordinate, ten-electron bismuth(III) complex: Synthesis and structure of [BiPh2(HMPA)2][BF4] (HMPA = hexamethylphosphoramide) Journal of Organometallic Chemistry. 460: C22-C24. DOI: 10.1016/0022-328X(93)83156-P |
0.699 |
|
| 1993 |
Jackson RD, James S, Orpen A, Pringle PG. 1,8-Bis(diphenylphosphino)naphthalene: A rigid chelating, diphosphine analogue of proton sponge Journal of Organometallic Chemistry. 458: C3-C4. DOI: 10.1016/0022-328X(93)80482-Q |
0.348 |
|
| 1992 |
Connelly NG, Hopkins PM, Orpen AG, Slater J. Addition of cyclopropenylium and tropylium ions to cyclooctatetraene-cobalt and -rhodium cyclopentadienyl complexes Journal of the Chemical Society, Dalton Transactions. 3303-3310. DOI: 10.1039/Dt9920003303 |
0.603 |
|
| 1992 |
Connelly NG, Hopkins PM, Orpen AG, Rosair GM, Viguri F. Redox-catalysed isomerisation of [Rh2(μ-CO)(bipy)(Ph2PCH2CH 2PPh2)(μ-N1,N3-RNNNR) 2]2+ to [Rh2(μ-CO)(bipy)(Ph2PCH2CH 2PPh2)(μ-N1,3,N 3-RNNNR)(μ-N1,N3-RNNNR)]... Journal of the Chemical Society, Dalton Transactions. 2907-2908. DOI: 10.1039/Dt9920002907 |
0.565 |
|
| 1992 |
Carr N, Mole L, Orpen AG, Spencer JL. Platinum ethyl complexes with β-agostic Pt-H-C bonding Journal of the Chemical Society, Dalton Transactions. 2653-2662. DOI: 10.1039/Dt9920002653 |
0.483 |
|
| 1992 |
Baker MJ, Harrison KN, Orpen AG, Pringle PG, Shaw G. 2-Methoxyphenyl phosphite complexes of platinum(0) and nickel(0) Journal of the Chemical Society, Dalton Transactions. 2607-2614. DOI: 10.1039/Dt9920002607 |
0.341 |
|
| 1992 |
Clegg W, Errington RJ, Fisher GA, Hockless DCR, Norman NC, Orpen AG, Stratford SE. Structural studies on phenyl bismuth halides and halogenoanions Journal of the Chemical Society-Dalton Transactions. 1967-1974. DOI: 10.1039/Dt9920001967 |
0.629 |
|
| 1992 |
Aggarwal RP, Connelly NG, Crespo MC, Dunne BJ, Hopkins PM, Orpen AG. Oxidatively induced alkyne rotation in dicobalt complexes: Structural tests of molecular orbital theory Journal of the Chemical Society, Dalton Transactions. 655-662. DOI: 10.1039/Dt9920000655 |
0.622 |
|
| 1992 |
Morton DAV, Orpen AG. Structural systematics. Part 4. Conformations of the diphosphine ligands in M2(µ-Ph2PCH2PPh2) and M(Ph2PCH2CH2PPh2) complexes Journal of the Chemical Society-Dalton Transactions. 641-653. DOI: 10.1039/Dt9920000641 |
0.324 |
|
| 1992 |
Clegg W, Compton NA, Errington RJ, Fisher GA, Hockless DCR, Norman NC, Williams NAL, Stratford SE, Nichols SJ, Jarrett PS, Orpen AG. Structural studies on organotransition-metal-bismuth complexes Journal of the Chemical Society, Dalton Transactions. 193-201. DOI: 10.1039/Dt9920000193 |
0.747 |
|
| 1992 |
Connelly NG, Crossley JG, Orpen AG. Linear chain metal compounds: [M(mnt)(CNMe)2] [M = Ni, Pd, Pt; mnt = 1,2-S2C2(CN)2] Journal of the Chemical Society, Chemical Communications. 1568-1571. DOI: 10.1039/C39920001568 |
0.585 |
|
| 1992 |
Connelly NG, Crossley JG, Orpen AG, Salter H. New linear chain mixed metal compounds: Complex salts of [Pt(CNMe) 4]2+ Journal of the Chemical Society, Chemical Communications. 1564-1568. DOI: 10.1039/C39920001564 |
0.57 |
|
| 1992 |
Dent AJ, Farrugia LJ, Orpen AG, Stratford SE. Kinetic and structural information on metal cluster rearrangement in solution from EXAFS spectra Journal of the Chemical Society, Chemical Communications. 1456-1457. DOI: 10.1039/C39920001456 |
0.334 |
|
| 1992 |
Connelly NG, Orpen AG, Rieger AL, Rieger PH, Scott CJ, Rosair GM. ESR spectroscopic characterisation of a coordinated alkyne radical, and redox-induced vinylidene-alkyne complex isomerisation Journal of the Chemical Society, Chemical Communications. 1293-1295. DOI: 10.1039/C39920001293 |
0.579 |
|
| 1992 |
Alder RW, Ganter C, Harris CJ, Orpen AG. The preparation and reactions of 1,6-diphosphatricyclo[4.4.4.0] tetradecanediium ditrifluoromethanesulfonate Journal of the Chemical Society, Chemical Communications. 1172-1174. DOI: 10.1039/C39920001172 |
0.348 |
|
| 1992 |
Alder RW, Ganter C, Harris CJ, Orpen AG. Synthesis and reactions of 1,6-diphosphabicyclo[4.4.0]decane and related molecules Journal of the Chemical Society, Chemical Communications. 1170-1172. DOI: 10.1039/C39920001170 |
0.304 |
|
| 1992 |
Brady LA, Dyke AF, Garner SE, Guerchais V, Knox SAR, Maher JP, Nicholls SM, Orpen AG. Acid-catalysed C-H activation of ethene and linking of alkynes at a diruthenium centre Journal of the Chemical Society, Chemical Communications. 310-312. DOI: 10.1039/C39920000310 |
0.444 |
|
| 1992 |
Connelly NG, Einig T, Herbosa GG, Hopkins PM, Mealli C, Orpen AG, Rosair GM. Ligand- and oxidation state-dependence of structure of triazenido-bridged complexes with face-to-face and open-book dirhodium cores: MO studies and the crystal structure of [Rh2(μ-CO)(bipy)(dppm)(μ-RNNNR) 2][PF6]2·2CH2Cl2 (R = p-tolyl) Journal of the Chemical Society, Chemical Communications. 143-145. DOI: 10.1039/C39920000143 |
0.625 |
|
| 1992 |
Schaverien CJ, Meijboom N, Orpen AG. A new ligand environment in organolanthanoid chemistry: sterically hindered, chelating diolato ligands and the X-ray structure of [La{CH(SiMe3)2}{1,1′-(2-OC6H2But2-3,5)2}(thf)3](thf = tetrahydrofuran) Journal of the Chemical Society, Chemical Communications. 124-126. DOI: 10.1039/C39920000124 |
0.459 |
|
| 1992 |
Horton AD, Orpen AG. Unprecedented coordination of a silicon-chlorine bond to a transition metal: synthesis and structure of [rac-C2H4(indenyl)2Zr{CH(SiMe2Cl)(SiMe3)}][Al2Cl6.5Me0.5] formed by reversible silicon-carbon bond activation Organometallics. 11: 1193-1201. DOI: 10.1021/Om00039A028 |
0.386 |
|
| 1992 |
Horton AD, Orpen AG. Double-insertion reaction of alkynes with methylzirconocene cation [Cp'2ZrMe]+: formation of an unusual distorted .eta.5-pentadienyl ligand Organometallics. 11: 8-10. DOI: 10.1021/om00037a005 |
0.314 |
|
| 1992 |
Ellis JW, Harrison KN, Hoye PAT, Orpen AG, Pringle PG, Smith MB. Water-soluble tris(hydroxymethyl)phosphine complexes with nickel, palladium, and platinum. Crystal structure of [Pd{P(CH2OH)3}4].cntdot.CH3 Inorganic Chemistry. 31: 3026-3033. DOI: 10.1021/Ic00040A009 |
0.418 |
|
| 1992 |
Doherty NM, Hogarth G, Knox SAR, Macpherson KA, Melchior F, Morton DAV, Orpen AG. Phosphorus-carbon bond cleavage at a di-iron centre: synthesis of μ-phosphidomethyl complexes [Fe2(CO)6(μ-CH2PR2)(μ-PR2)] from [Fe2(CO)6(μ-R2PCH2PR2)] Inorganica Chimica Acta. 198: 257-270. DOI: 10.1016/S0020-1693(00)92368-5 |
0.447 |
|
| 1992 |
Horton AD, Orpen AG. A Structurally Distorted Ligand in an Electron-Deficient Dizirconocene Cation: Unusual 1,2- and 1,1-Dimetallioalkenes Angewandte Chemie International Edition in English. 31: 876-878. DOI: 10.1002/Anie.199208761 |
0.391 |
|
| 1992 |
Horton AD, Orpen AG. Strukturell deformierter Ligand in Dizirconocen-Kationen mit Elektronenmangel - ungewöhnliche 1,2- und 1,1-Dimetallioalken Angewandte Chemie. 104: 912-914. DOI: 10.1002/Ange.19921040733 |
0.4 |
|
| 1991 |
Froom SFT, Green M, Mercer RJ, Nagle KR, Orpen AG, Rodrigues RA. Reactions of co-ordinated ligands. Part 53. Synthesis of dimolybdenum and ditungsten µ-σ,η2-(4e)-vinylidene and -allenylidene complexes; crystal structures of [N(PPh3)2][Mo2{µ-σ:η2-(3e)-C2Ph}(CO)4(η5-C9H7)2], [Mo2{µ-σ:η2-(4e)-CC(Ph)(CH2)4OMe}(CO)4(η-C5H5)2] and [Mo2{µ-σ:η2-(4e)-CCCMe2}(CO)4(η-C5H5)2] Journal of the Chemical Society-Dalton Transactions. 3171-3183. DOI: 10.1039/Dt9910003171 |
0.446 |
|
| 1991 |
Beevor RG, Freeman MJ, Green M, Morton CE, Orpen AG. Reactions of co-ordinated ligands. Part 52. Formation and reactivity of molybdenum vinylidene anions; crystal structures of [Mol(η4-CH2CHCHCHCH2But){P(OMe)3}(η-C5H5)] and [Mo(η3-CButCHCHCMe2CO){P(OMe)3}2(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 3021-3030. DOI: 10.1039/Dt9910003021 |
0.479 |
|
| 1991 |
Connelly NG, Geiger WE, Orpen AG, Orsini JJ, Richardson KE. Synthesis of asymmetric alkyne-bridged dipalladium complexes from the paramagnetic cation [Pd2(μ-PhC2Ph)(η-C5Ph5) 2]+; Crystal structures of [Pd2(bipy)(μ-PhC2Ph)(η-C5Ph 5)][Pd2(NCMe)(bipy)(μ-PhC2Ph)(η-C 5Ph5)].. Journal of the Chemical Society, Dalton Transactions. 2967-2977. DOI: 10.1039/Dt9910002967 |
0.623 |
|
| 1991 |
Connelly NG, Orpen AG, Rosair GM, Worth GH. Allylic alkylation of co-ordinated cyanide; the synthesis and X-ray crystal structure of trans-[Mn(CO)(CNCH2CMe = CH2)(dppm)2][PF6]·thf (dppm = Ph2PCH2PPh2, thf = tetrahydrofuran) Journal of the Chemical Society, Dalton Transactions. 1851-1854. DOI: 10.1039/Dt9910001851 |
0.668 |
|
| 1991 |
Brammer L, Charnock JM, Goggin PL, Goodfellow RJ, Orpen AG, Koetzle TF. The role of transition metal atoms as hydrogen bond acceptors: A neutron diffraction study of [NPrn 4]2[PtCl 4]·cis-[PtCl2(NH2Me)2] at 20 K Journal of the Chemical Society, Dalton Transactions. 1789-1798. DOI: 10.1039/Dt9910001789 |
0.622 |
|
| 1991 |
Christofides A, Connelly NG, Lawson HJ, Loyns AC, Orpen AG, Simmonds MO, Worth GH. Reduction-oxidation properties of organo-transition metal complexes. Part 33. Ligand- vs. metal-based oxidation of cyano-bridged catecholatoruthenium-manganese carbonyl compounds: The X-ray crystal structure of cis-[(dppe)(Et3P)(OC)2Mn(μ-CN)Ru(CO) 2(PPh3)(o-O2C6Cl 4)]·CH2Cl2 Journal of the Chemical Society, Dalton Transactions. 1595-1601. DOI: 10.1039/Dt9910001595 |
0.628 |
|
| 1991 |
Crocker M, Dunne BJ, Green M, Orpen AG. Reactions of co-ordinated ligands. Part 51. The reactions of σ,η3(5e)-butadienylruthenium complexes [Ru{C(Ph)-η3-C(Ph)C(Ph)CR(Ph)}(η-C5H5)](R = H or CHO) with P(OMe)3, PhCCPh, H+ and aryldiazonium cations; crystal structure of [Ru{C(O)C(Ph)C(Ph)-η2-(Z)C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 1589-1594. DOI: 10.1039/Dt9910001589 |
0.378 |
|
| 1991 |
Carr N, Dunne BJ, Mole L, Orpen AG, Spencer JL. Ligand control of agostic M ⋯ H ⋯ C three-centre, two-electron bonding in bicyclo[2.2.1]hept-2-yl complexes of platinum and palladium. X-ray crystal structures of [Pt(η2-C7H 10){But 2P(CH2)2PBu t 2}] and [Pt(C7H11){Bu t 2P.. Journal of the Chemical Society, Dalton Transactions. 863-871. DOI: 10.1039/Dt9910000863 |
0.474 |
|
| 1991 |
Compton NA, Errington RJ, Fisher GA, Norman NC, Webster PM, Jarrett PS, Nicholls SJ, Orpen AG, Stratford SE, Williams NAL. Bismuth complexes containing Mn(CO)5 and Re(CO)5 fragments. Synthetic studies and structural characterisation by solid- and solution-state extended X-ray absorption fine structure spectroscopy Journal of the Chemical Society-Dalton Transactions. 669-676. DOI: 10.1039/Dt9910000669 |
0.749 |
|
| 1991 |
Dunne BJ, Morris RB, Orpen AG. Structural systematics. Part 3. Geometry deformations in triphenylphosphine fragments: A test of bonding theories in phosphine complexes Journal of the Chemical Society, Dalton Transactions. 653-661. DOI: 10.1039/Dt9910000653 |
0.362 |
|
| 1991 |
Aggarwal RP, Connelly NG, Dunne BJ, Gilbert M, Orpen AG. Reduction-oxidation properties of organotransition-metal complexes. Part 32. One-electron oxidation of [Co(η4-cot)-(η-C5Me5)] (cot = cyclooctatetraene): Redox-induced polycyclic ring transformations of the resulting dimer, and crystal structure of [Co2(η4:η′4-C16H 16).. Journal of the Chemical Society, Dalton Transactions. 1-9. DOI: 10.1039/Dt9910000001 |
0.634 |
|
| 1991 |
Baker MJ, Harrison KN, Orpen AG, Pringle PG, Shaw G. Chelating diphosphite complexes of nickel(0) and platinum(0): Their remarkable stability and hydrocyanation activity Journal of the Chemical Society, Chemical Communications. 803-804. DOI: 10.1039/C39910000803 |
0.447 |
|
| 1991 |
Gomes-Carneiro TM, Jackson RD, Downing JH, Orpen AG, Pringle PG. Halocarbon complexes of platinum(II) Journal of the Chemical Society, Chemical Communications. 317-319. DOI: 10.1039/C39910000317 |
0.402 |
|
| 1991 |
Horton AD, Orpen AG. Lewis-base-free cationic zirconocene complexes containing an alkenyl ligand Organometallics. 10: 3910-3918. DOI: 10.1021/Om00057A024 |
0.447 |
|
| 1991 |
Clegg W, Compton NA, Errington R, Fisher GA, Hockless DC, Norman NC, Orpen A. Anionic, four-coordinate, 10-electron bismuth complexes Polyhedron. 10: 123-126. DOI: 10.1016/S0277-5387(00)83559-7 |
0.752 |
|
| 1990 |
Bott SG, Brammer L, Connelly NG, Green M, Orpen AG, Paxton JF, Schaverien CJ, Bristow S, Norman NC. Reactions of co-ordinated ligands. Part 48. Reactivity studies of the octatrienediylidenedimolybdenum complexes [Mo2(μ-C8Me8)(η-C5H 5)2] and [Mo2(μ-C8H4But 4)(η-C5H5)2]. Crystal structures of.. Journal of the Chemical Society, Dalton Transactions. 1957-1969. DOI: 10.1039/Dt9900001957 |
0.808 |
|
| 1990 |
Connelly NG, Gilbert M, Orpen AG, Sheridan JB. Allylic alkylation of complexed cyclo-octatetraene (cot) via the reaction of [Fe{P(OMe)3}(NO)2(η3-allyl)]+ with [M(CO)3(η4-cot)] (M = Fe or Ru) derivatives; X-ray structure of [Ru(CO)2(PPh3)(η2,η3-C 8H8R)][PF6]·0.5CH.. Journal of the Chemical Society, Dalton Transactions. 1291-1300. DOI: 10.1039/Dt9900001291 |
0.626 |
|
| 1990 |
Colborn RE, Dyke AF, Gracey BP, Knox SAR, MacPherson KA, Mead KA, Orpen AG. Organic chemistry of dinuclear metal centres. Part 14. Synthesis, X-ray structure, and reactivity of the ruthenium-ruthenium double-bonded complex [Ru2(μ-CO)(μ-C2Ph2)(η-C 5H5)2] Journal of the Chemical Society, Dalton Transactions. 761-771. DOI: 10.1039/Dt9900000761 |
0.461 |
|
| 1990 |
Carr N, Crossley JG, Dent AJ, Gouge JR, Greaves GN, Jarrett PS, Orpen AG. Linear molecular aggregation in solution: EXAFS studies of ML4 complexes Journal of the Chemical Society, Chemical Communications. 1369-1371. DOI: 10.1039/C39900001369 |
0.304 |
|
| 1990 |
Bruce GC, Gangnus B, Garner SE, Knox SAR, Orpen AG, Phillips AJ. Vinyl homologation via methyl migration to μ-vinyl at a diruthenium centre Journal of the Chemical Society, Chemical Communications. 1360-1362. DOI: 10.1039/C39900001360 |
0.414 |
|
| 1990 |
Alcock NW, Bergamini P, Gomes-Carniero TM, Jackson RD, Nicholls J, Orpen AG, Pringle PG, Sostero S, Traverso O. The flexibility of bridging phosphinoyl ligands: new classes of triplatinum(II) and diplatinum(I) complexes Journal of the Chemical Society, Chemical Communications. 980-982. DOI: 10.1039/C39900000980 |
0.414 |
|
| 1990 |
De With J, Horton AD, Orpen AG. Stable alkylvanadium(V) compounds containing bulky imido and amido ligands Organometallics. 9: 2207-2209. DOI: 10.1021/Om00158A015 |
0.345 |
|
| 1990 |
Van Leeuwen PWNM, Roobeek CF, Orpen AG. Aldehyde insertion into a platinum hydride and subsequent nucleophilic attack of the alkoxide at phosphorus: platinum-alkoxide/phosphorus-aryl metathesis Organometallics. 9: 2179-2181. DOI: 10.1021/Om00158A002 |
0.341 |
|
| 1990 |
Crocker M, Green M, Nagle KR, Orpen AG, Neumann HP, Morton CE, Schaverien CJ. Reactions of coordinated ligands. Part 47. Synthesis, structure, and reactivity of [.eta.4(5e)-butadienyl]ruthenium complexes: crystal structures of CpRu:C(Ph)-.eta.3-[C(Ph)C(Ph)CH(Ph)], CpRuC(Ph):C(Ph)-.eta.2-[C(Ph):CH(Ph)]P(OMe)3, and CpRu2[.mu.-(Z)-C(Ph):CH(Ph)](CO)2(.eta.4-C4Ph4) Organometallics. 9: 1422-1434. DOI: 10.1021/Om00119A012 |
0.347 |
|
| 1990 |
Budzelaar PHM, Frijns JHG, Orpen AG. Synthesis and coordination chemistry of a new class of binucleating ligands: pyridyl-substituted diphosphines Organometallics. 9: 1222-1227. DOI: 10.1021/Om00118A050 |
0.368 |
|
| 1990 |
Van Leeuwen PWNM, Roobeek CF, Frijns JHG, Orpen AG. Characterization of the intermediates in the hydroformylation reaction catalyzed by platinum diphenylphosphinous acid complexes Organometallics. 9: 1211-1222. DOI: 10.1021/Om00118A049 |
0.421 |
|
| 1990 |
Orpen AG, Connelly NG. Structural systematics: the role of P-A .sigma.* orbitals in metal-phosphorus .pi.-bonding in redox-related pairs of M-PA3 complexes (A = R, Ar, OR; R = alkyl) Organometallics. 9: 1206-1210. DOI: 10.1021/Om00118A048 |
0.611 |
|
| 1990 |
Meijboom N, Schaverien CJ, Orpen AG. Organometallic chemistry of chromium(VI): synthesis of chromium(VI) alkyls and their precursors. X-ray crystal structure of the metallacycle Cr(NBu-tert)2{o-(CHSiMe3)2C6H4} Organometallics. 9: 774-782. DOI: 10.1021/Om00117A037 |
0.394 |
|
| 1990 |
Knox SAR, Lloyd BR, Morton DAV, Nicholls SM, Orpen AG, Viñas JM, Weber M, Williams GK. Benzyne complexes of ruthenium: Models for dissociative chemisorption of benzene on a metal surface. Crystal structures of... Journal of Organometallic Chemistry. 394: 385-415. DOI: 10.1016/0022-328X(90)87246-A |
0.464 |
|
| 1990 |
Wahab Al-Saadoon A, Green M, Mercer RJ, Orpen A. Formation of trinuclear metal clusters by reaction of dimolybdenum μ-acetylide anions with electrophilic metal species. Crystal structure of [Mo3(μ3-C2Ph)(CO)5(η-C5H5)3] Journal of Organometallic Chemistry. 384: C12-C16. DOI: 10.1016/0022-328X(90)87075-O |
0.421 |
|
| 1990 |
Fennis PJ, Budzelaar PH, Frijns JH, Orpen A. Dichloromethane addition to rhodium-β-diketonate complexes of diphosphines and pyridyl-substituted diphosphines Journal of Organometallic Chemistry. 393: 287-298. DOI: 10.1016/0022-328X(90)80205-E |
0.44 |
|
| 1990 |
BOTT SG, BRAMMER L, CONNELLY NG, GREEN M, ORPEN AG, PAXTON JF, SCHAVERIEN CJ, BRISTOW S, NORMAN NC. ChemInform Abstract: Reactions of Coordinated Ligands. Part 48. Reactivity Studies of the Octatrienediylidenedimolybdenum Complexes (Mo2(μ-C8Me8)(η-C5H5)2) and (Mo2(μ-C8H4tBu4)(η-C5H5)2). Crystal Structures of (Mo2(μ-C8Me7CH2)(η-C5H5)2)(CF3SO3), (Mo2(μ-C8 Cheminform. 21. DOI: 10.1002/chin.199038280 |
0.723 |
|
| 1990 |
COLBORN RE, DYKE AF, GRACEY BP, KNOX SAR, MACPHERSON KA, MEAD KA, ORPEN AG. ChemInform Abstract: Organic Chemistry of Dinuclear Metal Centers. Part 14. Synthesis, X-Ray Structure, and Reactivity of the Ruthenium-Ruthenium Double-Bonded Complex (Ru2(μ-CO)(μ-C2Ph2)(η-C5H5)2). Cheminform. 21. DOI: 10.1002/chin.199025237 |
0.383 |
|
| 1989 |
Brauns T, Carriedo C, Cockayne JS, Connelly NG, Herbosa GG, Orpen AG. Reduction-oxidation properties of organotransition-metal complexes. Part 30. Triazenido-bridged carbonylrhodium bipyridyl complexes with [rh2]2+, [rh2]3+, and [rh2]4+ cores Journal of the Chemical Society, Dalton Transactions. 2049-2059. DOI: 10.1039/Dt9890002049 |
0.652 |
|
| 1989 |
Knox SAR, MacPherson KA, Orpen AG, Rendle MC. Organic chemistry of dinuclear metal centres. Part 13. Synthesis, structure, and reactivity of [Ru2(CO)4(η5:η 5′-C5H4CH2C5H 4)] Journal of the Chemical Society, Dalton Transactions. 1807-1813. DOI: 10.1039/Dt9890001807 |
0.531 |
|
| 1989 |
Colborn RE, Davies DL, Dyke AF, Knox SAR, Mead KA, Orpen AG, Guerchais JE, Roué J. Organic chemistry of dinuclear metal centres. Part 12. Synthesis, X-ray crystal structure, and reactivity of the di-μ-alkylidene complex [Ru2(CO)2(μ-CHMe)(μ-CMe2)(η-C 5H5)2]: Alkylidene linking Journal of the Chemical Society, Dalton Transactions. 1799-1805. DOI: 10.1039/Dt9890001799 |
0.506 |
|
| 1989 |
Orpen AG, Connelly NG, Whiteley MW, Woodward P. Structural effects of one-electron oxidation on a cyclobutadieneiron derivative: X-ray crystal structures of [Fe(CO){P(OMe)3}2(η-C4Ph4)] and [Fe(CO){P(OMe)3}2(η-C4Ph 4)]BF4 Journal of the Chemical Society, Dalton Transactions. 1751-1757. DOI: 10.1039/Dt9890001751 |
0.605 |
|
| 1989 |
Green M, Orpen AG, Schaverien CJ. Reactions of co-ordinated ligands. Part 46. Formation of [Os3(µ-H)(µ-CCH2CHMe2)(CO)10] and [Os3(µ-H)(µ-CCHCMe2)(CO)10] by carbon–carbon σ-bond and carbon–hydrogen activation of 3,3-dimethylcyclopropene; crystal and molecular structure of [Os3(µ-H)(µ-CCH2CHMe2)(CO)10] and evidence for its facile rearrangement to [Os3(µ-H)(µ-CHCHCHMe2)(CO)10] Journal of the Chemical Society-Dalton Transactions. 1333-1340. DOI: 10.1039/Dt9890001333 |
0.382 |
|
| 1989 |
Baker PK, Barker GK, Gill DS, Green M, Orpen AG, Williams ID, Welch AJ. Reactions of co-ordinated ligands. Part 45. Ligand displacement and oxidative reactions of the carbyne complex [Mo(CCH2But){P(OMe)3}2(η-C5H5)]; crystal and molecular structures of [Mo{η3-RNCC(CH2But)CNR}-(CNR)2(η-C5H5)](R = 2,6-Me2C6H3), [Mo(CCHBut)I{P(OMe)3}2(η-C5H5)], and [M o{C(CH2But)P(O)(OMe)2}{P(OMe)3}(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 1321-1331. DOI: 10.1039/Dt9890001321 |
0.472 |
|
| 1989 |
Brown SSD, Salter ID, Dent AJ, Kitchen GFM, Orpen AG, Bates PA, Hursthouse MB. The heteronuclear cluster chemistry of the Group 1B metals. Part 11. Effect of the nature of the bidentate diphosphine ligand on the metal framework structures of the gold heteronuclear cluster compounds [Au2Ru4(µ3-H)(µ-H){µ-Ph2P(CH2)nPPh2}(CO)12](n= 1–6). X-Ray crystal structures of [Au2Ru4(µ3-H)(µ-H){µ-Ph2P(CH2)nPPh2}(CO)12](n= 1 or 2) Journal of the Chemical Society-Dalton Transactions. 1227-1236. DOI: 10.1039/Dt9890001227 |
0.44 |
|
| 1989 |
Carriedo C, Connelly NG, Hettrich R, Orpen AG, White JM. Notes. Synthesis and X-ray crystal structure of [Rh(NO)(PPh3)2(p-MeC6H4NNNC 6H4Me-p)][BF4]·CH2Cl 2 Journal of the Chemical Society, Dalton Transactions. 745-748. DOI: 10.1039/Dt9890000745 |
0.616 |
|
| 1989 |
Orpen AG, Brammer L, Allen FH, Kennard O, Watson DG, Taylor R. Supplement. Tables of bond lengths determined by X-ray and neutron diffraction. Part 2. Organometallic compounds and co-ordination complexes of the d- and f-block metals Journal of the Chemical Society-Dalton Transactions. DOI: 10.1039/Dt98900000S1 |
0.635 |
|
| 1989 |
Fildes MJ, Knox SAR, Orpen AG, Turner ML, Yates MI. Synthesis of trimethylenemethane by combination of methylene with allene at a diruthenium centre: X-ray structure of [Ru2(CO)(μ-CO){μ- η1,η3-CH2C(CH2) 2}(η-C5H5)2] Journal of the Chemical Society, Chemical Communications. 1680-1682. DOI: 10.1039/C39890001680 |
0.442 |
|
| 1989 |
Harrison KN, Hoye PAT, Orpen AG, Pringle PG, Smith MB. Water soluble, zero-valent, platinum-, palladium-, and nickel-P(CH 2OH)3 complexes: Catalysts for the addition of PH 3 to CH2O Journal of the Chemical Society, Chemical Communications. 1096-1097. DOI: 10.1039/C39890001096 |
0.398 |
|
| 1989 |
Aggarwal RP, Connelly NG, Crespo MC, Dunne BJ, Hopkins PM, Orpen AG. The X-ray structures of the redox-related pair [Co2(CO) 2(μ-MeC2Me)(μ-dppm)2] and [Co 2(CO)2(μ-MeC2Me)(μ-dppm)2] [PF6], CH2Cl2 (dppm = Ph2PCH 2PPh2) Journal of the Chemical Society, Chemical Communications. 33-35. DOI: 10.1039/C39890000033 |
0.584 |
|
| 1989 |
Arif AM, Cowley AH, Nunn CM, Quashie S, Norman NC, Orpen AG. Synthesis and reactivity of a phosphavinylidene complex of molybdenum Organometallics. 8: 1878-1884. DOI: 10.1021/Om00110A009 |
0.569 |
|
| 1989 |
Van der Heijden H, Schaverien CJ, Orpen AG. The first salt- and solvent-free monocyclopentadienyl lanthanide dialkyl complex. X-ray structure determinations of La(.eta.5-C5Me5)[CH(SiMe3)2]2 and of its tetrahydrofuran adduct: compounds containing agostic silicon-carbon bonds Organometallics. 8: 255-258. DOI: 10.1021/Om00103A037 |
0.431 |
|
| 1989 |
Schaverien CJ, van der Heijden H, Orpen A. Monocyclopentadienyl lanthanide chemistry: towards the limits of steric unsaturation Polyhedron. 8: 1850-1852. DOI: 10.1016/S0277-5387(00)80669-5 |
0.481 |
|
| 1989 |
COLBORN RE, DAVIES DL, DYKE AF, KNOX SAR, MEAD KA, ORPEN AG, GUERCHAIS JE, ROUE J. ChemInform Abstract: Organic Chemistry of Dinuclear Metal Centers. Part 12. Synthesis, X-Ray Crystal Structure, and Reactivity of the Di-μ-alkylidene Complex (Ru2(CO)2(μ-CHMe)(μ-CMe2)(η-C5H5)2): Alkylidene Linking. Cheminform. 20. DOI: 10.1002/chin.198949261 |
0.368 |
|
| 1989 |
BAKER PK, BARKER GK, GILL DS, GREEN M, ORPEN AG, WILLIAMS ID, WELCH AJ. ChemInform Abstract: Reactions of Coordinated Ligands. Part 45. Ligand Displacement and Oxidative Reactions of the Carbyne Complex (Mo(CCH2tBu)(P(OMe)3)2(η-C5H5)); Crystal and Molecular Structures of (Mo(η3-RN=C-C(CH2tBu)-C=NR)(CNR)2(η-C5H5))(R: 2,6-Me2C Cheminform. 20. DOI: 10.1002/chin.198949240 |
0.549 |
|
| 1989 |
ARIF AM, COWLEY AH, NUNN CM, QUASHIE S, NORMAN NC, ORPEN AG. ChemInform Abstract: Synthesis and Reactivity of a Phosphavinylidene Complex of Molybdenum. Cheminform. 20. DOI: 10.1002/chin.198944269 |
0.512 |
|
| 1989 |
BOTTRILL M, GREEN M, ORPEN AG, SAUNDERS DR, WILLIAMS ID. ChemInform Abstract: Reactions of Coordinated Ligands. Part 44. The Reactivity of the Carbyne Complex (Mo(CCH2tBu)(P(OMe)3)2(η-C5H5)) Toward Protonic Acids, Diphenylphosphine, and the π-Acid Tetracyanoethylene; Formation and Crystal Structures of (MoH(C Cheminform. 20. DOI: 10.1002/chin.198924237 |
0.54 |
|
| 1989 |
VAN DER HEIJDEN H, SCHAVERIEN CJ, ORPEN AG. ChemInform Abstract: The First Salt- and Solvent-Free Monocyclopentadienyl Lanthanoid Dialkyl Complex. X-Ray Structure Determinations of La(η5-C5Me5)(CH(SiMe3)2)2 and of Its Tetrahydrofuran Adduct: Compounds Containing Agostic Si-C Bonds. Cheminform. 20. DOI: 10.1002/chin.198917264 |
0.341 |
|
| 1989 |
ARIF AM, COWLEY AH, PAKULSKI M, PEARSALL M, CLEGG W, NORMAN NC, ORPEN AG. ChemInform Abstract: Synthesis and Structures of Phosphinidene and Phosphido Complexes of Iron and Cobalt. Cheminform. 20. DOI: 10.1002/chin.198909264 |
0.477 |
|
| 1988 |
Arif AM, Cowley AH, Pakulski M, Pearsall M, Clegg W, Norman NC, Orpen AG. Synthesis and structures of phosphinidene and phosphido complexes of iron and cobalt Journal of the Chemical Society-Dalton Transactions. 2713-2721. DOI: 10.1039/Dt9880002713 |
0.617 |
|
| 1988 |
Green M, Jetha NK, Mercer RJ, Norman NC, Orpen AG. Reactions of co-ordinated ligands. Part 43. Alkyne linking reactions at dimetal centres. Synthesis and structures of [Mo2{µ-(σ,η3:η2:η3,σ-C8H4But4)}(η-C5H5)2], [Mo2{µ-(σ,η3:η3,σ-CHCHButC6H2But3)}(η-C5H5)2], and [FeMo(CO)2(C4Me2Ph2)(η-C5H5)2] Journal of the Chemical Society-Dalton Transactions. 1843-1851. DOI: 10.1039/Dt9880001843 |
0.636 |
|
| 1988 |
Connelly NG, Gilbert M, Orpen AG, White JM. Allylation of cobalt-co-ordinated cyclo-octatetraene by the [fe{P(OMe)3}(NO)2(η3-allyl)]+ cation: Ring closure to 1,2,3,3a-tetrahydropentalenyl derivatives and the X-ray structure of [co(η5-C8H8R)(η-C5Me 5)][PF6] [r = CH2C(Me)=CH2] Journal of the Chemical Society, Dalton Transactions. 1631-1636. DOI: 10.1039/Dt9880001631 |
0.649 |
|
| 1988 |
Connelly NG, Hassard KA, Dunne BJ, Orpen AG, Raven SJ, Carriedo GA, Riera V. The oxidative isomerisation of cis,cis-dicarbonylmanganese(I) derivatives; Isolation of the resulting trans-dicarbonylmanganese(II) complexes and the X-ray structure of cis,cis-[MnBr(CO)2{P(OPh)3}(Ph2PCH 2PPh2)] Journal of the Chemical Society, Dalton Transactions. 1623-1629. DOI: 10.1039/Dt9880001623 |
0.591 |
|
| 1988 |
Carr N, Dunne BJ, Orpen AG, Spencer JL. Co-ordinatively unsaturated diphosphine platinum(II) alkyl cations: A new class of β-agostic complexes Journal of the Chemical Society, Chemical Communications. 926-928. DOI: 10.1039/C39880000926 |
0.468 |
|
| 1988 |
Grist NJ, Hogarth G, Knox SAR, Lloyd BR, Morton DAV, Orpen AG. Generation of a μ3-vinylidene ligand via step-wise cleavage of 1,1-bis(diphenylphosphino)ethylene at di- and tri-iron centres Journal of the Chemical Society, Chemical Communications. 673-675. DOI: 10.1039/C39880000673 |
0.357 |
|
| 1988 |
Hogarth G, Knox SAR, Lloyd BR, Macpherson KA, Morton DAV, Orpen AG. Structural observation of bis(diphenylphosphino)methane reactivity at a di-iron centre Journal of the Chemical Society, Chemical Communications. 360-362. DOI: 10.1039/C39880000360 |
0.403 |
|
| 1988 |
Hogarth G, Kayser F, Knox SAR, Morton DAV, Orpen AG, Turner ML. Stepwise synthesis of tropone from ethyne and carbon monoxide at a di-iron centre: Crystal structure of [Fe2(CO)4(μ-C 6H6CO) (μ-Ph2PCH2PPh 2)] Journal of the Chemical Society, Chemical Communications. 358-359. DOI: 10.1039/C39880000358 |
0.302 |
|
| 1988 |
Brammer L, Connelly NG, Edwin J, Geiger WE, Orpen AG, Sheridan JB. Structural consequences of electron transfer reactions. Pt. 17. One-electron oxidation of (N4-cot)RhCp: rearrangements of the radicalcation and of the resulting dimerization product Organometallics. 7: 1259-1265. DOI: 10.1021/Om00096A004 |
0.576 |
|
| 1988 |
Arif AM, Cowley AH, Norman NC, Orpen AG, Pakulski M. Transition-metal phosphinidene complexes: syntheses, structures, and bonding in dinuclear phosphinidene complexes containing 14- and 15-electron metal fragments Organometallics. 7: 309-318. DOI: 10.1021/Om00092A012 |
0.559 |
|
| 1988 |
Lewandos GS, Doherty NM, Knox SAR, Macpherson KA, Orpen AG. Organic chemistry of dinuclear metal centres-X. Dimerization of allene at a diruthenium centre; X-ray crystal structure of [Ru2(CO)2{ (μ-C(Me)CHCH2CCH2)}(η-C5Me5)2] Polyhedron. 7: 837-845. DOI: 10.1016/S0277-5387(00)86306-8 |
0.471 |
|
| 1988 |
GREEN M, JETHA NK, MERCER RJ, NORMAN NC, ORPEN AG. ChemInform Abstract: Reactions of Coordinated Ligands. Part 43. Alkyne Linking Reactions at Dimetal Centers. Synthesis and Structures of (Mo2(μ-(σ,η3:η2:η3,σ-C8H4tBu4))(η-C5H5)2), (Mo2(μ-(σ,η3:η3,σ-CH=CHtBuC6H2tBu3))(η-C5H5)2), and (FeMo(CO)2(C4Me2Ph2)(η- Cheminform. 19. DOI: 10.1002/chin.198843304 |
0.568 |
|
| 1988 |
CONNELLY NG, GILBERT M, ORPEN AG, WHITE JM. ChemInform Abstract: Allylation of Cobalt-Coordinated Cyclooctatetraene by the (Fe(P(OMe)3)(NO)2(η3-allyl))+ Cation: Ring Closure to 1,2,3,3a-Tetrahydropentalenyl Derivatives and the X-Ray Structure of (Co(η5-C8H8R)(η-C5Me5)) (PF6) (R: CH2C(Me)=CH2). Cheminform. 19. DOI: 10.1002/chin.198839240 |
0.322 |
|
| 1988 |
ARIF AM, COWLEY AH, NORMAN NC, ORPEN AG, PAKULSKI M. ChemInform Abstract: Transition-Metal Phosphinidene Complexes: Syntheses, Structures, and Bonding in Dinuclear Phosphinidene Complexes Containing 14- and 15-Electron Metal Fragments. Cheminform. 19. DOI: 10.1002/chin.198823291 |
0.521 |
|
| 1988 |
CROCKER M, FROOM SFT, GREEN M, NAGLE KR, ORPEN AG, THOMAS DM. ChemInform Abstract: Reactions of Coordinated Ligands. Part 42. The Synthesis and Reactions of Cationic η4-Tetraphenylcyclobutadieneruthenium Complexes: X-Ray Crystal Structures of (Ru(NCMe)(η4-C4Ph4)(η-C5H5))(BF4) and (Ru(η5-CH(Ph)C(Ph)C(Ph)C(Ph)O)(η-C5H Cheminform. 19. DOI: 10.1002/chin.198809323 |
0.329 |
|
| 1988 |
LEWANDOS GS, KNOX SAR, ORPEN AG. ChemInform Abstract: Organic Chemistry of Dinuclear Metal Centres. Part 9. Diruthenium Complexes of Buta-1,3-diene. X-Ray Crystal Structure of (Ru2(CO)2(μ-s-trans-η2:η2′-CH2CHCHCH2)(η-C5H5)2). Cheminform. 19. DOI: 10.1002/chin.198809320 |
0.36 |
|
| 1987 |
Allen FH, Kennard O, Watson DG, Brammer L, Orpen AG, Taylor R. Tables of bond lengths determined by X-ray and neutron diffraction. Part 1. Bond lengths in organic compounds Journal of the Chemical Society-Perkin Transactions 1. DOI: 10.1039/P298700000S1 |
0.615 |
|
| 1987 |
Crocker M, Froom SFT, Green M, Nagle KR, Orpen AG, Thomas DM. Reactions of co-ordinated ligands. Part 42. The synthesis and reactions of cationic η4-tetraphenylcyclobutadieneruthenium complexes; X-ray crystal structures of [Ru(NCMe)(η4-C4Ph4)(η-C5H5)][BF4] and [Ru{η5-CH(Ph)C(Ph)C(Ph)C(Ph)O}(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 2803-2814. DOI: 10.1039/Dt9870002803 |
0.469 |
|
| 1987 |
Lewandos GS, Knox SAR, Orpen AG. Organic chemistry of dinuclear metal centres. Part 9. Diruthenium complexes of buta-1,3-diene. X-Ray crystal structure of [Ru2(CO)2(µ-s-trans-η2:η2′-CH2CHCHCH2)(η-C5H5)2] Journal of the Chemical Society-Dalton Transactions. 2703-2707. DOI: 10.1039/Dt9870002703 |
0.457 |
|
| 1987 |
Beevor RG, Green M, Orpen AG, Williams ID. Reactions of co-ordinated ligands. Part 41. Synthesis and reactions of cationic functionalised alkyne molybdenum complexes; formation of carbyne and vinylidene complexes and crystal structure of [Mo(CCHPh)Br{P(OMe)3}2(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 1319-1328. DOI: 10.1039/Dt9870001319 |
0.455 |
|
| 1987 |
Green M, Orpen AG, Schaverien CJ, Williams ID. Reactions of co-ordinated ligands. Part 40. Synthesis, structure, and reactivity of dirhenium µ-allylidene complexes; crystal structures of[Re2(µ-σ:η3-CHCHCMe2)(CO)8] and [Re2(µ-σ:η3-CHCHCMe2)(CO)9] Journal of the Chemical Society-Dalton Transactions. 1313-1318. DOI: 10.1039/Dt9870001313 |
0.484 |
|
| 1987 |
Freeman MJ, Orpen AG, Salter ID. The heteronuclear cluster chemistry of the Group 1B metals. Part 3. Synthesis, structures, and chemical properties of the trimetallic hexanuclear Group 1B metal cluster compounds [MM′Ru4(µ3-H)2(CO)12(PPh3)2](M = Cu, M′= Ag or Au; M = Ag, M′= Au). X-Ray crystal structure of the complex [AgCuRu4(µ3-H)2(CO)12(PPh3)2]·CH2Cl2 Journal of the Chemical Society-Dalton Transactions. 1001-1008. DOI: 10.1039/Dt9870001001 |
0.356 |
|
| 1987 |
Allen SR, Beevor RG, Green M, Orpen AG, Paddick KE, Williams ID. Reactions of co-ordinated ligands. Part 39. The synthesis of carbyne complexes from alkyne molybdenum and tungsten cations; Formation and crystal structures of [Mo(≡CCH<inf>2</inf>Bu<sup>t</sup>){P(OMe)<inf>3</inf>} <inf>2</inf>(η-C<inf>5</inf>H<inf>5</inf>)] and [Mo{=C(SiMe<inf>3</inf>)CH<inf>2</inf>}{P(OMe)<inf>3</inf>} <inf>2</inf>(η<sup>5</sup>-C<inf>9</inf>H<inf>7</inf>)] Journal of the Chemical Society, Dalton Transactions. 591-604. DOI: 10.1039/Dt9870000591 |
0.598 |
|
| 1987 |
Freeman MJ, Orpen AG, Salter ID. The heteronuclear cluster chemistry of the Group 1B metals. Part 2. Synthesis, X-ray crystal structures, and dynamic behaviour of the bimetallic hexanuclear Group 1B metal cluster compounds [M2Ru4H2(CO)12(PPh3)2](M = Cu, Ag, or Au) Journal of the Chemical Society-Dalton Transactions. 379-390. DOI: 10.1039/Dt9870000379 |
0.382 |
|
| 1987 |
Knox SAR, Lloyd BR, Orpen AG, Viñas JM, Weber M. Co-ordination of benzyne at tetra- and pentra-ruthenium centres: a model for dissociative chemisorption of benzene on a stepped metal (111) surface Journal of the Chemical Society, Chemical Communications. 1498-1500. DOI: 10.1039/C39870001498 |
0.438 |
|
| 1987 |
Brammer L, Charnock JM, Goggin PL, Goodfellow RJ, Koetzle TF, Orpen AG. Hydrogen bonding by cisplatin derivative: Evidence for the formation of N-H ⋯ Cl and N-H ⋯ Pt bonds in [NPrn 4] 2{[PtCl4]·cis-[PtCl2(NH 2Me)2]} Journal of the Chemical Society, Chemical Communications. 443-445. DOI: 10.1039/C39870000443 |
0.634 |
|
| 1987 |
Green M, Greenfield S, Grimshire MJ, Kersting M, Orpen AG, Rodrigues RA. Synthesis, structure, and reactivity of a 4-oxo-η3-cyclohexenyl molybdenum complex; diastereofacial selectivity in the reactions of the derived lithium enolate Journal of the Chemical Society, Chemical Communications. 97-99. DOI: 10.1039/C39870000097 |
0.466 |
|
| 1987 |
Arif AM, Cowley AH, Pakulski M, Norman NC, Orpen AG. Vanadium-phosphinidene complex exhibiting vanadium-phosphorus multiple bonding Organometallics. 6: 189-191. DOI: 10.1021/Om00144A035 |
0.572 |
|
| 1987 |
GREEN M, ORPEN AG, SCHAVERIEN CJ, WILLIAMS ID. ChemInform Abstract: Reactions of Coordinated Ligands. Part 40. Synthesis, Structure, and Reactivity of Dirhenium μ-Allylidene Complexes; Crystal Structures of (Re2(.mu±sigma.:η3-CHCHCMe2)(CO)8) and (Re2(.mu±sigma.:η3-CHCHCMe2)(CO)9). Cheminform. 18. DOI: 10.1002/chin.198740306 |
0.538 |
|
| 1987 |
BEEVOR RG, GREEN M, ORPEN AG, WILLIAMS ID. ChemInform Abstract: Reactions of Coordinated Ligands. Part 41. Synthesis and Reactions of Cationic Functionalized Alkyne Molybdenum Complexes; Formation of Carbyne and Vinylidene Complexes and Crystal Structure of (Mo(C=CHPh)Br(P(OMe)3)2(η-C5H5)). Cheminform. 18. DOI: 10.1002/chin.198740299 |
0.564 |
|
| 1987 |
ALLEN SR, BEEVOR RG, GREEN M, ORPEN AG, PADDICK KE, WILLIAMS ID. ChemInform Abstract: Reactions of Coordinated Ligands. Part 39. Synthesis of Carbyne Complexes from Alkyne Molybdenum and Tungsten Cations; Formation and Crystal Structures of (Mo(CCH2tBu)(P(OMe)3)2(η-C5H5)) and Cyclic (Mo(=C(SiMe3)CH2)(P(OMe)3)2(η5-C9H7 Cheminform. 18. DOI: 10.1002/chin.198729259 |
0.536 |
|
| 1987 |
ARIF AM, COWLEY AH, PAKULSKI M, NORMAN NC, ORPEN AG. ChemInform Abstract: A Vanadium-Phosphinidene Complex Exhibiting Vanadium-Phosphorus Multiple Bonding. Cheminform. 18. DOI: 10.1002/chin.198720267 |
0.526 |
|
| 1987 |
GREEN M, MERCER RJ, ORPEN AG, SCHAVERIEN CJ, WILLIAMS ID. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 38. Reactions of 1,2-Dienes, 1,3-Dienes, and Alkynes with the μ-Allylidene Complex (Mo2(μση3-CHCHCMe2)(CO)4(η-C5H5)2); Molecular Structures of (Mo(CO)2(η-C5H5)(μη3:η3-CH2C(CH2)CHCHCMe2)Mo(CO)2(η Cheminform. 18. DOI: 10.1002/chin.198704246 |
0.511 |
|
| 1986 |
Carroll WE, Green M, Orpen AG, Schaverien CJ, Williams ID, Welch AJ. Reactions of co-ordinated ligands. Part 37. Synthesis and structure of the dimolybdenum µ-allylidene complex [Mo2(µ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; formation and crystal structure of the oxo-µ-allylidene complex [Mo2O(µ-σ:η3-CHCHCMe2)(µ-CO)(CO)(η-C5H5)2]. Thermal rearrangement to alkyne and 1,3-diene dimolybdenum species and structure of [Mo3(µ3-η4-CCHCMeCH)(CO)4(η-C5H5)3] Journal of the Chemical Society-Dalton Transactions. 1021-1030. DOI: 10.1039/Dt9860001021 |
0.493 |
|
| 1986 |
Brammer L, Green M, Orpen AG, Paddick KE, Saunders DR. Reactions of co-ordinated ligands. Part 36. The synthesis, structure, and reactivity of the three-alkyne ‘fly-over’ complex [Mo2{µ-(σ,η3:η3,σ-C6Me6)}(η5-C9H7)2]; formation and structure of [Mo2{µ-(σ,η3:η3,σ-C6Me6)}(CO)2(η5-C9H7)2] Journal of the Chemical Society-Dalton Transactions. 657-667. DOI: 10.1039/Dt9860000657 |
0.696 |
|
| 1986 |
Jeffery JC, Orpen AG, Stone FGA, Went MJ. Chemistry of di- and tri-metal complexes with bridging carbene or carbyne ligands. Part 40. Transformation of terminally bound alkylidyne ligands to μ-alkylidene, μ-vinyl, μ-alkyl, and μ-aryl groups at a bimetal centre; X-ray crystal structures of ... Journal of the Chemical Society, Dalton Transactions. 173-186. DOI: 10.1039/Dt9860000173 |
0.519 |
|
| 1986 |
Froom SFT, Green M, Mercer RJ, Nagle KR, Orpen AG, Schwiegk S. Evidence for a facile switch in the bonding mode of µ-vinylidene ligands from σ, η2 to σ,σ; synthesis and structure of a dinuclear µ-σ,η2-allenylidene complex Journal of the Chemical Society, Chemical Communications. 1666-1668. DOI: 10.1039/C39860001666 |
0.444 |
|
| 1986 |
Doherty NM, Fildes MJ, Forrow NJ, Knox SAR, Macpherson KA, Orpen AG. Transformation of vinylidene to ketene at a diruthenium centre: Crystal structure of [Ru<inf>2</inf>(CO)<inf>2</inf>(μ-CO){μ-C(O)CH <inf>2</inf>}(η-C<inf>5</inf>Me<inf>5</inf>)<inf>2</inf>] Journal of the Chemical Society, Chemical Communications. 1355-1357. DOI: 10.1039/C39860001355 |
0.479 |
|
| 1986 |
Brammer L, Crocker M, Dunne BJ, Green M, Morton CE, Nagle KR, Orpen AG. The reactions of σ,η3-butadienylruthenium complexes with donor ligands and protons: structures of [RuC(Ph)C(Ph)-η2-{(Z)-C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)] and [RuC(O)C(Ph)C(Ph)-η2-{(Z)-C(Ph)CH(Ph)}{P(OMe)3}(η-C5H5)] Journal of the Chemical Society, Chemical Communications. 1226-1228. DOI: 10.1039/C39860001226 |
0.649 |
|
| 1986 |
Cracknell RB, Orpen AG, Spencer JL. Spectroscopic and theoretical studies on [Co(η-C5Me 5)Et(PMe2Ph)]+: Evidence for dynamic inversion of chirality at cobalt Journal of the Chemical Society, Chemical Communications. 1005-1006. DOI: 10.1039/C39860001005 |
0.377 |
|
| 1986 |
Bates PA, Brown SSD, Dent AJ, Hursthouse MB, Kitchen GFM, Orpen AG, Salter ID, Šik V. Control of the metal core geometries and dynamic behaviour of heteronuclear group 1b metal cluster compounds using bidentate phosphine ligands: X-ray crystal structures of [Au2Ru4(µ-H)(µ3-H)(µ-Ph2PCH2PPh2)(CO)12] and [Ag2Ru4(µ3-H)2(µ-Ph2PCH2PPh2)(CO)12] Journal of the Chemical Society, Chemical Communications. 600-602. DOI: 10.1039/C39860000600 |
0.399 |
|
| 1986 |
Mercer RJ, Green M, Orpen AG. The formation and reactivity of dimolybdenum acetylide anions; synthesis, structure, and thermal rearrangement of dimolybdenum η1,η2-(4e)-vinylidene complexes Journal of the Chemical Society, Chemical Communications. 567-569. DOI: 10.1039/C39860000567 |
0.422 |
|
| 1986 |
Doel GR, Feasey ND, Knox SAR, Orpen AG, Webster J. Phosphorus–carbon bond cleavage at a dimolybdenum centre: isomerisation of [Mo2(CO)3(PPh3)(µ-HC2H)(η-C5H5)2] to [Mo2(CO)2(µ-PPh2){µ-η3-HC2(H)C(O)Ph}(η-C5H5)2] Journal of the Chemical Society, Chemical Communications. 542-544. DOI: 10.1039/C39860000542 |
0.44 |
|
| 1986 |
Doherty NM, Hogarth G, Knox SAR, MacPherson KA, Melchior F, Orpen AG. Phosphorus-carbon bond cleavage at a di-iron centre. Conversion of μ-R<inf>2</inf>PCH<inf>2</inf>PR<inf>2</inf> to μ-R<inf>2</inf>PCH <inf>2</inf> and μ-PR<inf>2</inf>: Crystal structures of [Fe <inf>2</inf>(CO)<inf>4</inf>(μ-Ph<inf>2</inf>PCH<inf>2</inf>)(μ-PPh <inf>2</inf>)(μ-Me<inf>2</inf>PCH<inf>2</inf>PMe<inf>2</inf>)] and.. Journal of the Chemical Society, Chemical Communications. 540-542. DOI: 10.1039/C39860000540 |
0.406 |
|
| 1986 |
Feher FJ, Green M, Orpen AG. The role of α-hydrogen elimination reactions in the formation of η3-cyclopropenyl- and η4-cyclopentadiene- molybdenum complexes Journal of the Chemical Society, Chemical Communications. 291-293. DOI: 10.1039/C39860000291 |
0.467 |
|
| 1986 |
Connelly NG, Orpen AG, Quarmby IC, Sheridan JB. Stereo- and regio-specific CC bond formation via the coupling of electrophilic and nucleophilic organotransition-metal complexes: The x-ray crystal structure of [Ru(CO)2(PPh3)(η2,η3-C8H8R)][PF6]·0.5CH2Cl2 (R = CH2C(Me)CH2) Journal of Organometallic Chemistry. 299: C51-C55. DOI: 10.1016/0022-328X(86)84021-9 |
0.631 |
|
| 1986 |
CARROLL WE, GREEN M, ORPEN AG, SCHAVERIEN CJ, WILLIAMS ID, WELCH AJ. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 37. Synthesis and Structure of the Dimolybdenum μ-Allylidene Complex [Mo2(μ-σ:η3-CHCHCMe2)(CO)4(η-C5H5)2]; Formation and Crystal Structure of the Oxo-μ-allylidene Complex[Mo2O(μ-σ:η3-CHCHCMe2)(μ Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198636267 |
0.568 |
|
| 1986 |
BRAMMER L, GREEN M, ORPEN AG, PADDICK KE, SAUNDERS DR. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 36. The Synthesis, Structure, and Reactivity of the Three-alkyne ′Fly-over′ Complex Mo2(μ-(σ,η3:η3,σ-C6Me6))(η5-C9H7)2. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198625272 |
0.665 |
|
| 1986 |
GREEN M, ORPEN AG, SCHAVERIEN CJ, WILLIAMS ID. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 35. Evidence for Carbon - Carbon Double-bond Cleavage of Cyclopropenes in Their Reaction with Dinuclear Cobalt, Rhodium, and Iridium Complexes; Crystal Structure and Protolysis of [Rh2(μ-CO)(μ-C Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198618337 |
0.495 |
|
| 1986 |
FREEMAN MJ, ORPEN AG, CONNELLY NG, MANNERS I, RAVEN SJ. ChemInform Abstract: Stereochemical Consequences of the Two-electron Oxidation of a Dirhodium Fulvalene Complex Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198609066 |
0.483 |
|
| 1986 |
CROCKER M, GREEN M, MORTON CE, NAGLE KR, ORPEN AG. ChemInform Abstract: Reactions of Co-ordinated Ligands. Part 34. Synthesis, Structure, and Reactivity of Cationic Dieneruthenium Complexes. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198602285 |
0.345 |
|
| 1985 |
Green M, Orpen AG, Schaverien CJ, Williams ID. Reactions of co-ordinated ligands. Part 35. Evidence for carbon–carbon double-bond cleavage of cyclopropenes in their reaction with dinuclear cobalt, rhodium, and iridium complexes; crystal structure and protolysis of [Rh2(µ-CO)(µ-COCHCMe2CH)(µ-C5Me5)2] Journal of the Chemical Society-Dalton Transactions. 2483-2491. DOI: 10.1039/Dt9850002483 |
0.478 |
|
| 1985 |
Freeman MJ, Orpen AG, Connelly NG, Manners I, Raven SJ. Stereochemical consequences of the two-electron oxidation of a dirhodium fulvalene complex: the X-ray crystal structures of trans-[Rh2(CO)2(PPh3)2 (η5:η′5-C10H8)] and .. Journal of the Chemical Society, Dalton Transactions. 2283-2289. DOI: 10.1039/Dt9850002283 |
0.678 |
|
| 1985 |
Crocker M, Green M, Morton CE, Nagle KR, Orpen AG. Reactions of co-ordinated ligands. Part 34. Synthesis, structure, and reactivity of cationic dieneruthenium complexes; crystal structures of [Ru(η4-C6H8)(CO)(η-C5H5)][BF4] and [Ru(η3-C6H9)(CO)(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 2145-2153. DOI: 10.1039/Dt9850002145 |
0.479 |
|
| 1985 |
Gracey BP, Knox SAR, Macpherson KA, Orpen AG, Stobart SR. Organic chemistry of dinuclear metal centres. Part 8. Organo-iron-ruthenium chemistry. X-Ray structure of trans-[FeRu(CO)2(μ-CO)2(η-C5H 5)2] Journal of the Chemical Society, Dalton Transactions. 1935-1944. DOI: 10.1039/Dt9850001935 |
0.434 |
|
| 1985 |
Connelly NG, Freeman MJ, Orpen AG, Sheridan JB, Symonds AND, Whiteley MW. Reduction-oxidation properties of organotransition-metal complexes. Part 22. Stereospecific oxidative cyclopropane ring opening and reductive cyclobutane ring formation in polycyclic hydrocarbon complexes of iron; X-ray crystal structures of [Fe2(CO)6(η5:η′ 5-C16H16)][PF6] 2·CH.. Journal of the Chemical Society, Dalton Transactions. 1027-1035. DOI: 10.1039/Dt9850001027 |
0.627 |
|
| 1985 |
Connelly NG, Freeman MJ, Orpen AG, Sheehan AR, Sheridan JB, Sweigart DA. Reduction-oxidation properties of organotransition-metal complexes. Part 21. Synthesis and X-ray structural characterisation of the redox-related pair of cyclohexadienyl complexes [Mn(CO)(dppe)(η5-C6H6Ph)] and [Mn(CO)(dppe)(η5-C6H6Ph)][PF 6]·0.5CH2Cl2 Journal of the Chemical Society, Dalton Transactions. 1019-1026. DOI: 10.1039/Dt9850001019 |
0.639 |
|
| 1985 |
Allen SR, Beevor RG, Green M, Norman NC, Orpen AG, Williams ID. Reactions of co-ordinated ligands. Part 33. Mononuclear η2-vinyl complexes: Synthesis, structure, and reactivity Journal of the Chemical Society, Dalton Transactions. 435-450. DOI: 10.1039/Dt9850000435 |
0.712 |
|
| 1985 |
Farrugia LJ, Green M, Hankey DR, Murray M, Orpen AG, Stone FGA. Chemistry of the unsaturated cluster compound [Os3Pt(µ-H)2(CO)10{P(cyclo-C6H11)3}]; X-ray crystal structures of [Os3Pt(µ-H)2(CO)11{P(cyclo-C6H11)3}], [Os3Pt(µ-H)4(CO)10{P(cyclo-C6H11)3}], and [Os3Pt(µ-H)2(µ-CH2)(CO)10–{P(cyclo-C6H11)3}](two isomers) Journal of the Chemical Society-Dalton Transactions. 177-190. DOI: 10.1039/Dt9850000177 |
0.468 |
|
| 1985 |
Boer EJMd, Orpen AG. [(η5-C5Me5)2Ti]2(µ-OC)2[cpMo(CO)]2(cp =η5-C5H5): A compound with linear co-ordination of titanium to a bridging carbonyl and a d6–d6[cpMo(CO)2]2 fragment Journal of the Chemical Society, Chemical Communications. 1666-1667. DOI: 10.1039/C39850001666 |
0.409 |
|
| 1985 |
Heijden Hvd, Orpen AG, Pasman P. Photochemistry of [(η5-C5Me5)Re(CO)3] in benzene solution structure of [{(η5-C5Me5)Re(CO)2}2(µ-η2,η2′-C6H6) Journal of the Chemical Society, Chemical Communications. 1576-1578. DOI: 10.1039/C39850001576 |
0.476 |
|
| 1985 |
Bourner DG, Brammer L, Green M, Moran G, Orpen AG, Reeve C, Schaverien CJ. A molybdenum-centred (6 + 2)π addition of alkynes to cyclo-octatetraene and cycloheptatriene; structural evidence for an arrested 1,3-hydorgen shift Journal of the Chemical Society, Chemical Communications. 1409-1411. DOI: 10.1039/C39850001409 |
0.703 |
|
| 1985 |
Orpen AG, Connelly NG. Structural evidence for the participation of P–X σ* orbitals in metal–PX3 bonding Journal of the Chemical Society, Chemical Communications. 1310-1311. DOI: 10.1039/C39850001310 |
0.577 |
|
| 1985 |
Arif AM, Cowley AH, Norman NC, Orpen AG, Pakulski M. The question of ‘open’ or ‘closed’ bimetallic phosphinidene (and heavier congeneric) complexes Journal of the Chemical Society, Chemical Communications. 1267-1268. DOI: 10.1039/C39850001267 |
0.426 |
|
| 1985 |
Alder RW, Orpen AG, White JM. Structures of the radical cation and dication from oxidation of 1,6-diazabicyclo[4.4.4]tetradecane Journal of the Chemical Society, Chemical Communications. 949-951. DOI: 10.1039/C39850000949 |
0.313 |
|
| 1985 |
Beevor RG, Freeman MJ, Green M, Morton CE, Orpen AG. The reactions of an ambident lithium molybdenumvinylidene complex with electrophiles; novel formation of a 1,3-diene complex and evidence for intramolecular carbon–hydrogen activation on photolysis of a carbyne complex Journal of the Chemical Society, Chemical Communications. 68-70. DOI: 10.1039/C39850000068 |
0.479 |
|
| 1985 |
Connelly NG, Forrow NJ, Knox SAR, Macpherson KA, Orpen AG. Activation of a µ3-ethylidyne ligand through oxidation–deprotonation: X-ray structure of [Ru3(µ3-CMe)(µ-CO)3(η-C5Me5)3][BF4] Journal of the Chemical Society, Chemical Communications. 16-17. DOI: 10.1039/C39850000016 |
0.658 |
|
| 1985 |
Connelly NG, Forrow NJ, Gracey BP, Knox SAR, Orpen AG. Activation of µ-alkylidene ligands through oxidation–deprotonation: a new synthesis of µ-methyne, and is hydrogenation to µ-methyl Journal of the Chemical Society, Chemical Communications. 14-16. DOI: 10.1039/C39850000014 |
0.611 |
|
| 1985 |
Van der Heijden H, Gal AW, Pasman P, Orpen AG. Reactions of the trimetallic neopentylidyne complex [{Cl2(MeOCH2CH2OMe)Ta(.mu.-CCMe3)}2Zn(.mu.-Cl)2] with alkynes. A structural study of [(.eta.5-C5(t-Bu)(CH2CMe3)2(CH2CMe2CH2)2TaCl2] Organometallics. 4: 1847-1853. DOI: 10.1021/Om00129A027 |
0.399 |
|
| 1985 |
De Boer EJM, De With J, Meijboom N, Orpen AG. Structure and reactivity of bridging dimanganese and -rhenium ethane-1,2-dionyl compounds Organometallics. 4: 259-264. DOI: 10.1021/Om00121A010 |
0.354 |
|
| 1985 |
CONNELLY NG, FREEMAN MJ, ORPEN AG, SHERIDAN JB, SYMONDS AND, WHITELEY MW. ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 22. STEREOSPECIFIC OXIDATIVE CYCLOPROPANE RING OPENING AND REDUCTIVE CYCLOBUTANE RING FORMATION IN POLYCYCLIC HYDROCARBON COMPLEXES OF IRON: X-RAY CRYSTAL STRUCT Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198537262 |
0.523 |
|
| 1985 |
CONNELLY NG, FREEMAN MJ, ORPEN AG, SHEEHAN AR, SHERIDAN JB, SWEIGART DA. ChemInform Abstract: Reduction-Oxidation Properties of Organotransition-metal Complexes. Part 21. Synthesis and X-Ray Structural Characterisation of the Redox-related Pair of Cyclohexadienyl Complexes [Mn(CO)(dppe)(η5-C6H6Ph)] and [Mn(CO)(dppe)(η5- C6H6Ph Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198537259 |
0.565 |
|
| 1985 |
ALLEN SR, BEEVOR RG, GREEN M, NORMAN NC, ORPEN AG, WILLIAMS ID. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 33. MONONUCLEAR η2-VINYL COMPLEXES: SYNTHESIS, STRUCTURE, AND REACTIVITY Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198526304 |
0.668 |
|
| 1985 |
BARR RD, GREEN M, HOWARD JAK, MARDER TB, ORPEN AG, STONE FGA. ChemInform Abstract: THE ANALOGY BETWEEN ALKENES AND THE DINUCLEAR SPECIES (MRH(μ-CO)2(η-C5ME5)2) (M = COBALT OR RHODIUM): DYNAMIC NUCLEAR MAGNETIC RESONANCE, X-RAY CRYSTALLOGRAPHIC, AND EXTENDED-HUECKEL MOLECULAR-ORBITAL STUDIES OF THE BONDING BETWEEN UN Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198515317 |
0.457 |
|
| 1985 |
CONNELLY NG, FREEMAN MJ, MANNERS I, ORPEN AG. ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 18. THE STABILIZATION OF PARAMAGNETIC CYCLOPENTADIENYLRHODIUM COMPOUNDS VIA O-QUINONE COMPLEXATION: X-RAY CRYSTAL STRUCTURE OF (η-CYCLOPENTADIENYL)(TETRACHLORO-2 Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198515316 |
0.56 |
|
| 1985 |
ALLEN SR, GLAUERT TH, GREEN M, MEAD KA, NORMAN NC, ORPEN AG, SCHAVERIEN CJ, WOODWARD P. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 32. THE REACTION OF SULFUR NUCLEOPHILES WITH CATIONIC MOLYBDENUM ALKYNE COMPLEXES: ALKYNE ROTATION AND THE MOLECULAR STRUCTURE OF THE COMPLEXES (MO(SC6H4NO2-P)(P(OME)3)(η2-MEC2ME)(η-C5H5)) AND (M Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198515294 |
0.606 |
|
| 1985 |
GREEN M, NORMAN NC, ORPEN AG, SCHAVERIEN CJ. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 31. THE SYNTHESIS, STRUCTURE, AND PROTONATION OF THE OCTAMETHYLOCTATRIENEDIYLIDENEDIMOLYBDENUM COMPLEX μ-(η-3,4,5,6,7,8-HEXAMETHYLDECA-3,5,7-TRIENE-2,9-DIYLIDENE-C2,5-6,9(MO1)# C2-4,7-9(MO2))-BIS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198509306 |
0.591 |
|
| 1985 |
Green M, Mercer RJ, Morton CE, Orpen AG. Synthesis, Structure, and Reactivity of ?3-1-Azaallylmolybdenum Complexes Angewandte Chemie International Edition in English. 24: 422-424. DOI: 10.1002/Anie.198504221 |
0.376 |
|
| 1985 |
Green M, Mercer RJ, Morton CE, Orpen AG. Synthese, Struktur und Reaktivität von η3-1-Azaallylmolybdän-Komplexen Angewandte Chemie. 97: 422-423. DOI: 10.1002/Ange.19850970526 |
0.326 |
|
| 1984 |
Barr RD, Green M, Howard JAK, Marder TB, Orpen AG, Stone FGA. The analogy between alkenes and the dinuclear species [MRh(µ-CO)2(η-C5Me5)2](M = Co or Rh); dynamic nuclear magnetic resonance, X-ray crystallographic, and extended-Hückel molecular-orbital studies of the bonding between unsaturated CoRh and Rh2 fragments and the pentacarbonylmolybdenum group Journal of the Chemical Society-Dalton Transactions. 2757-2763. DOI: 10.1039/Dt9840002757 |
0.483 |
|
| 1984 |
Allen SR, Glauert TH, Green M, Mead KA, Norman NC, Orpen AG, Schaverien CJ, Woodward P. Reactions of co-ordinated ligands. Part 32. The reaction of sulphur nucleophiles with cationic molybdenum alkyne complexes: Alkyne rotation and the molecular structures of the complexes [Mo(SC6H4NO2-p){P(OMe)3}(η 2-MeC2Me)(η-C5H5)] and.. Journal of the Chemical Society, Dalton Transactions. 2747-2756. DOI: 10.1039/Dt9840002747 |
0.638 |
|
| 1984 |
Connelly NG, Freeman MJ, Manners I, Orpen AG. Reduction-oxidation properties of organotransition-metal complexes. Part 18. The stabilisation of paramagnetic cyclopentadienylrhodium compounds via o-quinone complexation: X-ray crystal structure of [Rh(PPh3){o-C(O)OC6Cl4O}(η-C 5H5)]·0.25CH2Cl2 Journal of the Chemical Society, Dalton Transactions. 2703-2712. DOI: 10.1039/Dt9840002703 |
0.626 |
|
| 1984 |
Green M, Orpen AG, Salter ID, Stone FGA. Hydrido-bridged bimetallic complexes involving gold or silver and chromium, molybdenum, or tungsten: X-ray crystal structure of [AuCr(µ-H)(CO)5(PPh3)] Journal of the Chemical Society-Dalton Transactions. 2497-2503. DOI: 10.1039/Dt9840002497 |
0.434 |
|
| 1984 |
Green M, Norman NC, Orpen AG, Schaverien CJ. Reactions of co-ordinated ligands. Part 31. The synthesis, structure, and protonation of the octamethyloctatrienediylidenedimolybdenum complex [Mo2(µ-C8Me8)(η-C5H5)2], evidence for three-centre carbon–hydrogen–molybdenum interactions Journal of the Chemical Society-Dalton Transactions. 2455-2465. DOI: 10.1039/Dt9840002455 |
0.653 |
|
| 1984 |
Gill DS, Green M, Marsden K, Moore I, Orpen AG, Stone FGA, Williams ID, Woodward P. The reaction of molybdenum and tungsten carbyne complexes with sulphur and selenium; crystal structures of [Mo{η2-(S2CCH2But)}-(CO)2(η-C5H5)] and [W{η2-(S2CC6H4Me-4)}(CO)2(η-C5H5)] Journal of the Chemical Society-Dalton Transactions. 1343-1347. DOI: 10.1039/Dt9840001343 |
0.537 |
|
| 1984 |
Allen SR, Green M, Moran G, Orpen AG, Taylor GE. Reactions of co-ordinated ligands. Part 29. The formation of a 1,3-diene at a molybdenum centre by linking of but-2-yne with an alkene; X-ray crystal structures of [Mo(η2-o-Ph2PC6H4CH=CH 2)(η2-MeC2Me)(η-C5H 5)][BF4] and [Mo(NCMe)(η4-o-MeCH=CMe-CH=CHC.. Journal of the Chemical Society, Dalton Transactions. 441-449. DOI: 10.1039/Dt9840000441 |
0.49 |
|
| 1984 |
Crocker M, Green M, Orpen AG, Neumann H, Schaverien CJ. Reaction of cationic cyclobutadineruthenium complexes with hydride anion donors; evidence for the formation of η4(5e) butadienyl species and fragmentation of the cyclobutadiene ring: crystal structure of [RuC(Ph)–η3-{C(Ph)·CH(Ph)·CH(Ph)}-(η-C5H5)] and [Ru2(µ-CO){µ-(Z)-C(Ph)CH(Ph)}(CO)2(η4-C4Ph4)(η-C5H5)] Journal of the Chemical Society, Chemical Communications. 1351-1353. DOI: 10.1039/C39840001351 |
0.371 |
|
| 1984 |
Crocker M, Green M, Orpen AG, Thomas DM. The synthesis, structure, and reactivity of cationic η<sup>4</sup>-cyclobutadiene-ruthenium complexes; Formation of the trisethylene(η-cyclopentadienyl)ruthenium cation Journal of the Chemical Society - Series Chemical Communications. 1141-1144. DOI: 10.1039/C39840001141 |
0.431 |
|
| 1984 |
Connelly NG, Finn CJ, Freeman MJ, Orpen AG, Stirling J. The synthesis of mixed-valence dirhodium carbonyl complexes, and the X-ray crystal structures of [Rh(CO)(PPh3)(μ-RNNNR)2] and [Rh(CO)(PPh3)- (μ-RNNIMR)2][PF6] (R = p-Tolyl) Journal of the Chemical Society - Series Chemical Communications. 1025-1027. DOI: 10.1039/C39840001025 |
0.634 |
|
| 1984 |
Davies DL, Gracey BP, Guerchais V, Knox SAR, Orpen AG. Methyl group mobility and conversion into methyne at a diruthenium centre Journal of the Chemical Society, Chemical Communications. 841-843. DOI: 10.1039/C39840000841 |
0.39 |
|
| 1984 |
Jeffery JC, Orpen AG, Robinson WT, Stone FGA, Went MJ. Stepwise transformation of a terminally bound alkylidyne ligand to a bridging acyl group at a bimetal centre via an asymmetrically bridging alkyl; X-ray crystal structures of [N(PPh3)2][ReW(µ-CHR)(CO)9](R = C6H4Me-4), [ReW(µ-CH2R)(µ-Me2PCH2PMe2)(CO)7], and [ReW(µ-OCCH2R)(µ-Ph2PCH2PPh2)(CO)6{P(OMe)3}] Journal of the Chemical Society, Chemical Communications. 396-398. DOI: 10.1039/C39840000396 |
0.482 |
|
| 1984 |
Cracknell RB, Orpen AG, Spencer JL. The synthesis and structure of [Co(η-C5Me 5)Et{P(p-tolyl)3}] cation: A model for the β-elimination transition state Journal of the Chemical Society, Chemical Communications. 326-328. DOI: 10.1039/C39840000326 |
0.401 |
|
| 1984 |
Barr RD, Marder TB, Orpen AG, Williams ID. The role of saturated transition metal carbonyl complexes as π-acid ligands; a theoretical investigation of the bonding in [Cr(µ-CO)2(CO)(η-C6H6)Rh(CO)(η-C5Me5)] and (Co)(µ-CO)2(η-C5H5)Rh(PH3)(η-C5H5)] Journal of the Chemical Society, Chemical Communications. 112-114. DOI: 10.1039/C39840000112 |
0.431 |
|
| 1984 |
Green M, Orpen AG, Schaverien CJ. Formation of triosmium µ-carbyne complexes by ring-opening and carbon–hydrogen activation of 3,3-dimethylcyclopropene; rearrangement of an alkyl µ-carbyne to a µ-vinyl complex via a 1,2-hydrogen shift Journal of the Chemical Society, Chemical Communications. 37-39. DOI: 10.1039/C39840000037 |
0.361 |
|
| 1984 |
Gracey BP, Knox SAR, Macpherson KA, Orpen AG, Stobart SR. Organic chemistry of the iron-ruthenium centre Journal of Organometallic Chemistry. 272: C45-C48. DOI: 10.1016/0022-328X(84)80490-8 |
0.399 |
|
| 1984 |
GILL DS, GREEN M, MARSDEN K, MOORE I, ORPEN AG, STONE FGA, WILLIAMS ID, WOODWARD P. ChemInform Abstract: THE REACTION OF MOLYBDENUM AND TUNGSTEN CARBYNE COMPLEXES WITH SULFUR AND SELENIUM: CRYSTAL STRUCTURES OF DICARBONYL(η-CYCLOPENTADIENYL)(3,3-DIMETHYLDITHIOBUTANOATO-S,S′)MOLYBDENUM AND DICARBONYL(η-CYCLOPENTADIENYL)(DITHIO-P-TOLUATO-S Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198441269 |
0.48 |
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| 1984 |
ALLEN SR, GREEN M, MORAN G, ORPEN AG, TAYLOR GE. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 29. THE FORMATION OF A 1,3-DIENE AT THE MOLYBDENUM CENTER BY LINKING 2-BUTYNE WITH AN ALKENE: X-RAY CRYSTAL STRUCTURES OF ((η2-2-BUTYNE)(η-CYCLOPENTADIENYL)(.alpha±beta±eta.-O-DIPHENYLPHOSP# HINO Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198423275 |
0.334 |
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| 1984 |
COLBORN RE, DAVIES DL, DYKE AF, ENDESFELDER A, KNOX SAR, ORPEN AG, PLAAS D. ChemInform Abstract: ORGANIC CHEMISTRY OF DINUCLEAR METAL CENTERS. PART 6. μ-VINYLIDENE- AND μ-ETHYLIDYNEDIRUTHENIUM COMPLEXES: CRYSTAL STRUCTURES OF CIS-(RU2(CO)2(μ-CO)(μ-C:CH2)(η-C5H5)2) AND CIS-(RU2(CO)2(μ-CO)(μ-CME)(η-C5H5)2)(BF4) Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198411311 |
0.325 |
|
| 1983 |
Colborn RE, Davies DL, Dyke AF, Endesfelder A, Knox SAR, Orpen AG, Plaas D. Organic chemistry of dinuclear metal centres. Part 6. μ-vinylidene and μ-ethylidyne diruthenium complexes: Crystal structures of cis-[Ru2(CO)2(μ-CO)(μ-CCH2)(η-C 5H5)2] and cis-[Ru2(CO)2(μ-CO)(μ-CMe)(η-C5H 5)2][BF4] Journal of the Chemical Society, Dalton Transactions. 2661-2668. DOI: 10.1039/Dt9830002661 |
0.482 |
|
| 1983 |
Allen SR, Green M, Norman NC, Paddick KE, Orpen AG. Reactions of co-ordinated ligands. Part 28. The reaction of nucleophilic reagents with the cationic bis(acetylene) molybdenum complexes [Mo(CO)(RC<inf>2</inf>R′)<inf>2</inf>(η-C<inf>5</inf>H <inf>5</inf>)][BF<inf>4</inf>]; X-ray crystal structures of.. Journal of the Chemical Society, Dalton Transactions. 1625-1633. DOI: 10.1039/Dt9830001625 |
0.645 |
|
| 1983 |
Orpen AG. Structural chemistry of binuclear metal centres. Crystal and molecular structures of the µ-vinyl and µ-methylcarbene complexes [Fe2(CO)2(µ-CO)(µ-CHCH2)(η-C5H5)2][BF4] and [Fe2(CO)2(µ-CO)(µ-CHMe)(η-C5H5)2] Journal of the Chemical Society-Dalton Transactions. 1427-1431. DOI: 10.1039/Dt9830001427 |
0.475 |
|
| 1983 |
Allen SR, Baker PK, Barnes SG, Bottrill M, Green M, Orpen AG, Williams ID, Welch AJ. Reactions of co-ordinated ligands. Part 27. Formation of η<sup>3</sup>-allyl and σ-vinyl complexes by nucleophilic attack on cationic molybdenum monoacetylene complexes. Molecular structures of.. Journal of the Chemical Society, Dalton Transactions. 927-939. DOI: 10.1039/Dt9830000927 |
0.617 |
|
| 1983 |
Orpen AG, McMullan RK. X-Ray and neutron diffraction studies on [Ru4(CO)8(μ-H)4{P(OCH3) 3}4] at 293 and 20 K: Characterisation of the vibrational behaviour of two-co-ordinate hydrogen atoms Journal of the Chemical Society, Dalton Transactions. 463-474. DOI: 10.1039/Dt9830000463 |
0.433 |
|
| 1983 |
Green M, Orpen AG, Schaverien CJ, Williams ID. The synthesis, structure, and reactivity of a di-rhenium octacarbonyl µ-carbene complex; molecular structure of [Re2{µ-(η1,η3-CH·CH·CMe2)}(CO)8] Journal of the Chemical Society, Chemical Communications. 1399-1401. DOI: 10.1039/C39830001399 |
0.468 |
|
| 1983 |
Goodfellow RJ, Herbert IR, Orpen AG. Platinum(I) dimer chemistry: Distortion of co-ordination geometry in [Pt2Br2(μ-CO)(PPh3)3] Journal of the Chemical Society - Series Chemical Communications. 1386-1388. DOI: 10.1039/C39830001386 |
0.432 |
|
| 1983 |
Freeman MJ, Green M, Orpen AG, Salter ID, Stone FGA. Cluster complex metathesis: synthesis, structures, and dynamic behaviour of Bi- and tri-metallic hexanuclear cluster complexes [MM′Ru4(µ3-H)2(CO)12(PPh3)2](M = M′= Cu, Ag, or Au; M = Cu, M′= Ag or Au; M = Ag, M′= Au) Journal of the Chemical Society, Chemical Communications. 1332-1334. DOI: 10.1039/C39830001332 |
0.325 |
|
| 1983 |
Beevor RG, Green M, Orpen AG, Williams ID. The formation of vinylidene molybdenum complexes and their transformation into mononuclear carbyne complexes; X-ray crystal structure of [Mo{CCHPh}Br{P(OMe)3}2(η-C5H5)] Journal of the Chemical Society, Chemical Communications. 673-675. DOI: 10.1039/C39830000673 |
0.412 |
|
| 1983 |
Green M, Orpen AG, Schaverien CJ, Williams ID. Formation of an alkyne and a 1,3-diene at a dimolybdenum centre by isomerisation of a µ-allylidene complex; synthesis and X-ray structure of [Mo3(µ3-{η4-C·CH·CMe·CH})(CO)4(η-C5H5)3] Journal of the Chemical Society, Chemical Communications. 583-585. DOI: 10.1039/C39830000583 |
0.425 |
|
| 1983 |
Bott SG, Connelly NG, Green M, Norman NC, Orpen AG, Paxton JF, Schaverien CJ. The activation of a carbon–hydrogen bond in a dimolybdenumcyclononatetraene by oxidation of a metal centre; X-ray crystal structures of [Mo2(µ-C8Me7CH2)(η-C5H5)2][CF3SO3] and [Mo2(µ-C8Me8)(µ-Cl)(η-C5H5)2][SbCl4]·CH2Cl2 Journal of the Chemical Society, Chemical Communications. 378-381. DOI: 10.1039/C39830000378 |
0.702 |
|
| 1983 |
Farrugia LJ, Green M, Hankey DR, Orpen AG, Stone FGA. Reversible addition of hydrogen and carbon monoxide to a closo- triosmiumplatinum cluster: X-ray crystal structures of [Os3Pt(µ-H)4(CO)10{P(C6H11)3}] and [Os3Pt(µ-H)2(CO)11{P(C6H11)3}] Journal of the Chemical Society, Chemical Communications. 310-312. DOI: 10.1039/C39830000310 |
0.429 |
|
| 1983 |
Forrow NJ, Knox SAR, Morris MJ, Orpen AG. Synthesis, X-ray structure, and reactivity of [Ru3H3(CO)3(η-C5H5)3]: an entry into the organic chemistry of the triruthenium centre Journal of the Chemical Society, Chemical Communications. 234-235. DOI: 10.1039/C39830000234 |
0.43 |
|
| 1983 |
Green M, Orpen AG, Schaverien CJ, Williams ID. The formation of a cyclohexadienone at a dimolybdenum centre; X-ray crystal structure of [Mo2(µ-{η4-CMe2·CH·CH·CH·C(But)CO})-(CO)2(η-C5H5)2], and evidence for an unusual bonding mode for a bridging 1,3-diene ligand Journal of the Chemical Society, Chemical Communications. 181-183. DOI: 10.1039/C39830000181 |
0.505 |
|
| 1983 |
Farrugia LJ, Orpen A, Stone FA. A synthetic route to heteronuclear clusters containing iridium and rhodium: X-ray crystal structures of [IrOs3(μ-H)2(μ-Cl)(CO)12] and [Ir2Rh2(μ-CO)(μ3-CO)2(CO)4(η-C5Me5)2] Polyhedron. 2: 171-173. DOI: 10.1016/S0277-5387(00)83953-4 |
0.409 |
|
| 1983 |
Farrugia LJ, Freeman MJ, Green M, Orpen A, Gordon F, Stone A, Salter ID. Metal framework arrangements in pentanuclear gold-ruthenium clusters. Crystal structures of [Au2Ru3(μ3-S)(CO)8(PPh3)3] and [Au2Ru3(μ-H)(μ3-COMe)(CO)9(PPh3)2] Journal of Organometallic Chemistry. 249: 273-288. DOI: 10.1016/S0022-328X(00)98815-6 |
0.42 |
|
| 1983 |
Moran G, Green M, Orpen A. Formation of a fulvene by trimerisation of an alkyne at a rhodium centre; crystal structure of cycloocta-1,5-diene(η5-1,3,6-tri-t-butylfulvene) rhodium hexafluorophosphate Journal of Organometallic Chemistry. 250: c15-c20. DOI: 10.1016/0022-328X(83)85086-4 |
0.396 |
|
| 1983 |
ALLEN SR, GREEN M, NORMAN NC, PADDICK KE, ORPEN AG. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 28. THE REACTION OF NUCLEOPHILIC REAGENTS WITH THE CATIONIC BIS(ACETYLENE)MOLYBDENUM COMPLEXES (MO(CO)(RC2R′)2(η-C5H5))(BF4). X-RAY CRYSTAL STRUCTURES OF DICARBONYL(η-CYCLOPENTADIENYL)(1,2,4-TRIM Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198347254 |
0.61 |
|
| 1983 |
ORPEN AG. ChemInform Abstract: STRUCTURAL CHEMISTRY OF BINUCLEAR METAL CENTERS. CRYSTAL AND MOLECULAR STRUCTURES OF THE μ-VINYL AND μ-METHYLCARBENE COMPLEXES (FE2(CO)2(μ-CO)(μ-CHCH2)(η-C5H5)2)(BF4) AND (FE2(CO)2(μ-CO)(μ-CHME)(η-C5H5)2) Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198342062 |
0.317 |
|
| 1983 |
ALLEN SR, BAKER PK, BARNES SG, BOTTRILL M, GREEN M, ORPEN AG, WILLIAMS ID, WELCH AJ. ChemInform Abstract: REACTIONS OF COORDINATED LIGANDS. PART 27. FORMATION OF η3-ALLYL AND Σ-VINYL COMPLEXES BY NUCLEOPHILIC ATTACK ON CATIONIC MOLYBDENUM MONOACETYLENE COMPLEXES. MOLECULAR STRUCTURES OF CARBONYL(η5-INDENYL)(η3-ANTI-1-METHYLALLYL)(TRIETHYL Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198334276 |
0.554 |
|
| 1982 |
Prest DW, Mays MJ, Raithby PR, Orpen AG. Reaction between [Re3H3(CO)12] and the diphosphine ligands Ph2P-CH2PPh2 and (EtO)2POP(OEt)2 : X-ray crystal structures of [Re2H2-(CO)6(Ph2PCH2PPh2)] and [Re3H3(CO)8{(EtO)2POP(OEt)2}2] Journal of the Chemical Society-Dalton Transactions. 737-745. DOI: 10.1039/Dt9820000737 |
0.496 |
|
| 1982 |
Kergoat R, Kubicki MM, Guerchais JE, Norman NC, Orpen AG. Bis(cyclopentadienyls) with transition metal–mercury bonds. Part 4. Formation of niobium–mercury bonds and X-ray crystal structure of [Nb(η-C5H5)2{HgS2CN(C2H5)2}3] Journal of the Chemical Society-Dalton Transactions. 633-638. DOI: 10.1039/Dt9820000633 |
0.647 |
|
| 1982 |
Boileau AM, Orpen AG, Stansfield RFD, Woodward P. The sequential linking of alkynes at a dimolybdenum centre. Crystal structures of [Mo2{µ-(MeO2CC2CO2Me)(HC2H)(MeO2CC2CO2Me)2}(η-C5H5)2]·2CH2Cl2 and [Mo2{µ-(MeO2CC2CO2Me)4}(η-C5H5)2] Journal of the Chemical Society-Dalton Transactions. 187-193. DOI: 10.1039/Dt9820000187 |
0.431 |
|
| 1982 |
Brun P, Dawkins GM, Green M, Miles AD, Orpen AG, Stone FGA. Bis(ethylene)(η-pentamethylcyclopentadienyl)cobalt as a precursor to heteronuclear metal clusters: X-ray crystal strucutre of [Co2Mo2(µ-CO)3lpar;µ4-CO)(η-C5H5)2(η-C5Me5)2]; a model for CO activation on a stepped metal surface Journal of the Chemical Society, Chemical Communications. 926-927. DOI: 10.1039/C39820000926 |
0.457 |
|
| 1982 |
Schaverien CJ, Green M, Orpen AG, Williams ID. Alkene fragmentation at a dimetal centre; X-ray crystal structure and protonation of the bridged carbene complex [Rh2(µ-CO){µ,µ-(CHCMe2CHCO)}(η-C5Me5)2] Journal of the Chemical Society, Chemical Communications. 912-914. DOI: 10.1039/C39820000912 |
0.445 |
|
| 1982 |
Allen SR, Green M, Orpen AG, Williams ID. The role of metallacyclopropenes in the formation of alkylidyne complexes; evidence for a 1,2-trimethylsilyl shift and the x-ray crystal structure of [Mo=C(SiMe<inf>3</inf>)CH<inf>2</inf>{P(OMe)<inf>3</inf>}<inf>2</inf>(η <sup>5</sup>-C<inf>9</inf>H<inf>7</inf>)] Journal of the Chemical Society, Chemical Communications. 826-828. DOI: 10.1039/C39820000826 |
0.57 |
|
| 1982 |
Green M, Orpen AG, Salter LD, Stone FGA. Hydrido-bridged complexes of gold and silver: X-ray crystal structure of [AuCr(µ-H)(CO)5(PPh3)] Journal of the Chemical Society, Chemical Communications. 813-814. DOI: 10.1039/C39820000813 |
0.372 |
|
| 1982 |
Green M, Orpen AG, Williams ID. The mechanism of protonation of carbyne complexes; X-ray crystal structure of [HMo(CCH2But){P(OMe)3}2(η-C5H5)][BF4] and [Mo(CF3CO2)(CF3CO2H){P(OMe)3}2(η-C5H5)] Journal of the Chemical Society, Chemical Communications. 493-495. DOI: 10.1039/C39820000493 |
0.43 |
|
| 1982 |
Feasey ND, Knox SAR, Orpen AG. A new low co-ordination mode for nitrogen in a nitrido metal cluster: X-ray crystal structure of [Mo3(N)(O)(CO)4(η-C5H5)3] Journal of the Chemical Society, Chemical Communications. 75-76. DOI: 10.1039/C39820000075 |
0.4 |
|
| 1982 |
Dawkins GM, Green M, Orpen AG, Stone FGA. Synthesis and X-ray crystal structure of [Fe2(µ-CH3)(µ-CO)(µ-Ph2PCH2PPh2)(η-C5H5)2][PF6]: a salt with a bridging methyl group having a C---H---Fe interaction Journal of the Chemical Society, Chemical Communications. 41-43. DOI: 10.1039/C39820000041 |
0.391 |
|
| 1982 |
Colborn RE, Dyke AF, Knox SAR, Macpherson KA, Orpen AG. Sequential methylene addition to an alkyne coordinated at a diruthenium centre Journal of Organometallic Chemistry. 239: C15-C18. DOI: 10.1016/S0022-328X(00)95272-0 |
0.441 |
|
| 1982 |
Prest DW, Mays MJ, Orpen AG, McMullan RK. Joint x-ray and neutron diffraction structure analysis of [(μ-H)3Re3(CO)8{(EtO)2POP(OEt)2}2] Journal of Organometallic Chemistry. 240: 395-406. DOI: 10.1016/S0022-328X(00)85141-4 |
0.446 |
|
| 1982 |
KERGOAT R, KUBICKI MM, GUERCHAIS JE, NORMAN NC, ORPEN AG. ChemInform Abstract: BIS(CYCLOPENTADIENYLS) WITH TRANSITION METAL-MERCURY BONDS. PART 4. FORMATION N OF NIOBIUM-MERCURY BONDS AND X-RAY CRYSTAL STRUCTURE OF BIS(CYCLOPENTADIENYL)TRIS((DIETHYLDITHIOCARBAMATO)MERCURIO)NIOBIUM Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198225251 |
0.521 |
|
| 1981 |
Norman NC, Orpen AG, Williams ID. Crystallographic studies of molybdenum to carbon multiple bonds Acta Crystallographica Section a Foundations of Crystallography. 37: C218-C218. DOI: 10.1107/S0108767381093082 |
0.536 |
|
| 1981 |
Johnson BFG, Lewis J, Orpen AG, Raithby PR, Rouse KD. Combined X-ray and neutron diffraction study of [Os4(CO)11H3(CHCHPh)] Journal of the Chemical Society-Dalton Transactions. 788-792. DOI: 10.1039/Dt9810000788 |
0.555 |
|
| 1981 |
Goggin PL, Goodfellow RJ, Herbert IR, Orpen AG. Bridging by carbonyl vs. halide ligands: X-ray crystal structure of [NBu4n]2[Pd2Cl4(µ-CO)2] Journal of the Chemical Society, Chemical Communications. 1077-1079. DOI: 10.1039/C39810001077 |
0.458 |
|
| 1981 |
Green M, Hankey DR, Murray M, Orpen AG, Stone FGA. Synthesis, dynamic behaviour, and molecular structures of µ-methylene platinumtriosmium complexes; X-ray crystal structures of two isomers of [Os3Pt(µ-H)2(µ-CH2)(CO)10{P(C6H11)3}] Journal of the Chemical Society, Chemical Communications. 689-691. DOI: 10.1039/C39810000689 |
0.42 |
|
| 1981 |
Green M, Norman NC, Orpen AG. Linking of four acetylene molecules at a dimolybdenum center and the protonation of the resulting metallacyclononatetraene to form a cation containing a bridging MoHC system Journal of the American Chemical Society. 103: 1269-1271. DOI: 10.1021/Ja00395A070 |
0.521 |
|
| 1981 |
Green M, Norman NC, Orpen AG. Transformation of coordinatively unsaturated .eta.1-vinylmolybdenum complexes into three-electron .eta.2-bonded cyclic alkylidene species Journal of the American Chemical Society. 103: 1267-1269. DOI: 10.1021/Ja00395A069 |
0.567 |
|
| 1981 |
GREEN M, NORMAN NC, ORPEN AG. ChemInform Abstract: LINKING OF FOUR ACETYLENE MOLECULES AT A DIMOLYBDENUM CENTER AND THE PROTONATION OF THE RESULTING METALLACYCLONONATETRAENE TO FORM A CATION CONTAINING A BRIDGING MOHC SYSTEM Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198125289 |
0.463 |
|
| 1980 |
Orpen AG. Indirect location of hydride ligands in metal cluster complexes Journal of the Chemical Society-Dalton Transactions. 2509-2516. DOI: 10.1039/Dt9800002509 |
0.397 |
|
| 1980 |
Dyke AF, Knox SAR, Naish PJ, Orpen AG. Conversion of ethyne into methylcarbene and ethene at a di-metal centre: X-ray structure of [Fe2(CO)2(µ-CO)(µ-CHMe)(η-C5H5)2] Journal of the Chemical Society, Chemical Communications. 441-442. DOI: 10.1039/C39800000441 |
0.425 |
|
| 1980 |
Broadhurst PV, Johnson BF, Lewis J, Orpen A, Raithby PR, Thornback JR. Synthesis and Characterisation of a Thiocarbonyl containing Osmium Cluster Journal of Organometallic Chemistry. 187: 141-145. DOI: 10.1016/S0022-328X(00)90543-6 |
0.62 |
|
| 1979 |
Johnson BF, Lewis J, Orpen A, R. Raithby P, Süss G. HRu3(CO)10(COCH3). A cluster with an oxygen-containing μ2-carbyne ligand; preparation, structure and fluxionality Journal of Organometallic Chemistry. 173: 187-197. DOI: 10.1016/S0022-328X(00)81288-7 |
0.681 |
|
| 1978 |
Orpen AG, Sheldrick GM. Bis(tert-butyl isocyanide)hexadecacarbonylhexaosmium Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 34: 1989-1991. DOI: 10.1107/S0567740878014661 |
0.441 |
|
| 1978 |
Orpen AG, Rivera AV, Bryan EG, Pippard D, Sheldrick GM, Rouse KD. Bridging hydrides in [H2Os3(CO)10] and [(C2H3)HOs3(CO)10]: a combined X-ray–neutron diffraction study Journal of the Chemical Society, Chemical Communications. 723-724. DOI: 10.1039/C39780000723 |
0.487 |
|
| 1978 |
Eady CR, Gavens PD, Johnson BF, Lewis J, Malatesta MC, Mays MJ, Orpen A, Rivera A, Sheldrick GM, Hursthouse MB. Isocyanide substitution in octadecacarbonyl hexaosmium Journal of Organometallic Chemistry. 149: C43-C46. DOI: 10.1016/S0022-328X(00)94131-7 |
0.647 |
|
| 1978 |
Orpen A. The indirect location of hydride ligands in metal carbonyl clusters Journal of Organometallic Chemistry. 159: c1-c4. DOI: 10.1016/S0022-328X(00)82321-9 |
0.362 |
|
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