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Jennifer S. Hirschi, Ph.D. - Publications

Affiliations: 
2007 Texas A & M University, College Station, TX, United States 
Area:
organic, organometallic, and bioorganic reaction mechanisms
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25 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Awasthi A, Mallojjala SC, Kumar R, Eerlapally R, Hirschi JS, Draksharapu A. Altering the Localization of an Unpaired Spin in a Formal Ni(V) Species. Chemistry (Weinheim An Der Bergstrasse, Germany). e202302824. PMID 37903027 DOI: 10.1002/chem.202302824  0.732
2023 Lin PC, Joshi C, McGinnis TM, Mallojjala SC, Sanford AB, Hirschi JS, Jarvo ER. Stereospecific Nickel-Catalyzed Cross-Electrophile Coupling Reaction of Alkyl Mesylates and Allylic Difluorides to Access Enantioenriched Vinyl Fluoride-Substituted Cyclopropanes. Acs Catalysis. 13: 4488-4499. PMID 37066042 DOI: 10.1021/acscatal.3c00257  0.792
2022 Joshi C, Macharia JM, Izzo JA, Wambua V, Kim S, Hirschi JS, Vetticatt MJ. Isotope Effects Reveal the Catalytic Mechanism of the Archetypical Suzuki-Miyaura Reaction. Acs Catalysis. 12: 2959-2966. PMID 37168650 DOI: 10.1021/acscatal.1c05802  0.717
2022 East AK, Lee MC, Smaga LP, Jiang C, Mallojjala SC, Hirschi JS, Chan J. Synthesis of Silicon-Substituted Hemicyanines for Multimodal SWIR Imaging. Organic Letters. PMID 36374323 DOI: 10.1021/acs.orglett.2c03382  0.723
2022 Athavale SV, Gao S, Das A, Mallojjala SC, Alfonzo E, Long Y, Hirschi JS, Arnold FH. Enzymatic Nitrogen Insertion into Unactivated C-H Bonds. Journal of the American Chemical Society. PMID 36194202 DOI: 10.1021/jacs.2c08285  0.768
2022 Mallojjala SC, Nyagilo VO, Corio SA, Adili A, Dagar A, Loyer KA, Seidel D, Hirschi JS. Probing the Free Energy Landscape of Organophotoredox-Catalyzed Anti-Markovnikov Hydrofunctionalization of Alkenes. Journal of the American Chemical Society. 144: 17692-17699. PMID 36112933 DOI: 10.1021/jacs.2c07807  0.801
2022 Chandra Mallojjala S, Sarkar R, Karugu RW, Manna MS, Ray S, Mukherjee S, Hirschi JS. Mechanism and Origin of Remote Stereocontrol in the Organocatalytic Enantioselective Formal C(sp)-H Alkylation Using Nitroalkanes as Alkylating Agents. Journal of the American Chemical Society. 144: 17399-17406. PMID 36108139 DOI: 10.1021/jacs.2c02941  0.364
2021 Wambua V, Hirschi JS, Vetticatt MJ. Rapid Evaluation of the Mechanism of Buchwald-Hartwig Amination and Aldol Reactions Using Intramolecular C Kinetic Isotope Effects. Acs Catalysis. 11: 60-67. PMID 34659873 DOI: 10.1021/acscatal.0c04752  0.763
2021 Athavale S, Gao S, Liu Z, Mallojjala SC, Hirschi J, Arnold FH. Biocatalytic, Intermolecular C-H Bond Functionalization for the Synthesis of Enantioenriched Amides. Angewandte Chemie (International Ed. in English). PMID 34534409 DOI: 10.1002/anie.202110873  0.793
2021 Gardner SH, Brady CJ, Keeton C, Yadav AK, Mallojjala SC, Lucero MY, Su S, Yu Z, Hirschi JS, Mirica LM, Chan J. A General Approach to Convert Hemicyanine Dyes into Highly Optimized Photoacoustic Scaffolds for Analyte Sensing. Angewandte Chemie (International Ed. in English). PMID 34089556 DOI: 10.1002/anie.202105905  0.73
2020 Lin Y, Hirschi WJ, Kunadia A, Paul A, Ghiviriga I, Abboud KA, Karugu R, Vetticatt MJ, Hirschi JS, Seidel D. A Selenourea-Thiourea Brønsted Acid Catalyst Facilitates Asymmetric Conjugate Additions of Amines to α,β-Unsaturated Esters. Journal of the American Chemical Society. PMID 32118419 DOI: 10.1021/Jacs.9B12457  0.739
2019 Izzo JA, Myshchuk Y, Hirschi JS, Vetticatt MJ. Transition state analysis of an enantioselective Michael addition by a bifunctional thiourea organocatalyst. Organic & Biomolecular Chemistry. 17: 3934-3939. PMID 30942247 DOI: 10.1039/C9Ob00072K  0.752
2018 Roytman VA, Karugu RW, Hong Y, Hirschi JS, Vetticatt M. 13C Kinetic Isotope Effects as a Quantitative Probe to Distinguish Between Enol and Enamine Mechanisms in Aminocatalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29654709 DOI: 10.1002/Chem.201801748  0.747
2018 Gheewala C, Hirschi JS, Lee WH, Paley DW, Vetticatt MJ, Lambert TH. Asymmetric Induction via a Helically Chiral Anion: Enantioselective PCCP Brønsted Acid-Catalyzed Inverse Electron-Demand Diels-Alder Cycloaddition of Oxocarbenium Ions. Journal of the American Chemical Society. PMID 29485273 DOI: 10.1021/Jacs.8B00260  0.722
2017 Vetticatt M, Macharia J, Wambua V, Hong Y, Harris L, Hirschi JS, Evans GB. A Designed Approach to Enantiodivergent Enamine Catalysis. Angewandte Chemie (International Ed. in English). PMID 28544165 DOI: 10.1002/Anie.201703919  0.715
2017 Jarvis CL, Hirschi JS, Vetticatt MJ, Seidel D. Catalytic Enantioselective Synthesis of Lactams through Formal [4+2] Cycloaddition of Imines with Homophthalic Anhydride. Angewandte Chemie (International Ed. in English). PMID 28128534 DOI: 10.1002/Anie.201612148  0.726
2016 Ashley MA, Hirschi JS, Izzo JA, Vetticatt MJ. Isotope Effects Reveal Mechanism of Enamine Formation in L-Proline Catalyzed α-Amination of Aldehydes. Journal of the American Chemical Society. PMID 26772311 DOI: 10.1021/Jacs.5B10876  0.752
2011 Silva RG, Hirschi JS, Ghanem M, Murkin AS, Schramm VL. Arsenate and phosphate as nucleophiles at the transition states of human purine nucleoside phosphorylase. Biochemistry. 50: 2701-9. PMID 21348499 DOI: 10.1021/Bi200279S  0.304
2009 Wang Z, Hirschi JS, Singleton DA. Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction. Angewandte Chemie (International Ed. in English). 48: 9156-9. PMID 19876990 DOI: 10.1002/Anie.200903293  0.67
2009 Kelly KK, Hirschi JS, Singleton DA. Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects. Journal of the American Chemical Society. 131: 8382-3. PMID 19485324 DOI: 10.1021/Ja9031083  0.75
2009 Hirschi JS, Takeya T, Hang C, Singleton DA. Transition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines. Journal of the American Chemical Society. 131: 2397-403. PMID 19146405 DOI: 10.1021/Ja8088636  0.712
2007 Soloshonok VA, Ueki H, Yasumoto M, Mekala S, Hirschi JS, Singleton DA. Phenomenon of optical self-purification of chiral non-racemic compounds. Journal of the American Chemical Society. 129: 12112-3. PMID 17850147 DOI: 10.1021/Ja065603A  0.544
2007 Ralph EC, Hirschi JS, Anderson MA, Cleland WW, Singleton DA, Fitzpatrick PF. Insights into the mechanism of flavoprotein-catalyzed amine oxidation from nitrogen isotope effects on the reaction of N-methyltryptophan oxidase. Biochemistry. 46: 7655-64. PMID 17542620 DOI: 10.1021/Bi700482H  0.648
2005 Hirschi J, Singleton DA. The normal range for secondary Swain-Schaad exponents without tunneling or kinetic complexity. Journal of the American Chemical Society. 127: 3294-5. PMID 15755143 DOI: 10.1021/Ja0430752  0.635
2003 Boren B, Hirschi JS, Reibenspies JH, Tallant MD, Singleton DA, Sulikowski GA. Exo-selective Diels-Alder reactions of vinylazepines. Origin of divergent stereoselectivity in Diels-Alder reactions of vinylazepines, vinylpiperideines, and vinylcycloalkenes. The Journal of Organic Chemistry. 68: 8991-5. PMID 14604372 DOI: 10.1021/Jo034462H  0.655
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