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Darcy A. Culkin, Ph.D.

Affiliations: 
2004 Yale University, New Haven, CT 
Area:
reactions catalyzed by transition metal complexes
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"Darcy Culkin"
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John F. Hartwig grad student 2004 Yale
 (Synthesis and reactivity of palladium complexes of functionalized alkyls. Selection of catalysts for the alpha-arylation of nitriles and amides.)

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Dove AP, Li H, Pratt RC, et al. (2006) Stereoselective polymerization of rac- and meso-lactide catalyzed by sterically encumbered N-heterocyclic carbenes. Chemical Communications (Cambridge, England). 2881-3
Hama T, Culkin DA, Hartwig JF. (2006) Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. Journal of the American Chemical Society. 128: 4976-85
Hartwig J, Hama T, Culkin D. (2006) Pd-Catalyzed α-Arylation of Zinc Amide Enolates Synfacts. 2006: 0714-0714
Culkin DA, Hartwig JF. (2004) Carbon-carbon bond-forming reductive elimination from arylpalladium complexes containing functionalized alkyl groups. Influence of ligand steric and electronic properties on structure, stability, and reactivity Organometallics. 23: 3398-3416
Hama T, Liu X, Culkin DA, et al. (2003) Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. Journal of the American Chemical Society. 125: 11176-7
Culkin DA, Hartwig JF. (2003) Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research. 36: 234-45
Culkin DA, Hartwig JF. (2003) Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles Cheminform. 34
Culkin DA, Hartwig JF. (2002) Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. Journal of the American Chemical Society. 124: 9330-1
Culkin DA, Hartwig JF. (2001) C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. Journal of the American Chemical Society. 123: 5816-7
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