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Thomas F. Spilker, Ph.D.

Affiliations: 
2014 Chemistry Ohio State University, Columbus, Columbus, OH 
Area:
inorganic, organometallic and materials chemistry
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Malcolm H. Chisholm grad student 2014 Ohio State
 (Development of metal-metal quadruply bonded complexes with pi-extended structures: Synthesis, characterization, photophysical properties and applications as molecular synthons.)

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Publications

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Jiang C, Young PJ, Durr CB, et al. (2016) Synthesis, Structure, and Photophysical Properties of Mo2(NN)4 and Mo2(NN)2(T(i)PB)2, Where NN = N,N'-Diphenylphenylpropiolamidinate and T(i)PB = 2,4,6-Triisopropylbenzoate. Inorganic Chemistry
Brown-Xu SE, Chisholm MH, Durr CB, et al. (2015) MM Quadruply Bonded Complexes Supported by Vinylbenzoate Ligands: Synthesis, Characterization, Photophysical Properties and Application as Synthons. Chemical Science (Royal Society of Chemistry : 2010). 6: 1780-1791
Chisholm MH, Gustafson TL, Kender WT, et al. (2015) Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Ditungsten Quadruple Bonds. Inorganic Chemistry. 54: 9438-46
Chisholm MH, Durr CB, Gustafson TL, et al. (2015) Electronic and Spectroscopic Properties of Avobenzone Derivatives Attached to Mo₂ Quadruple Bonds: Suppression of the Photochemical Enol-to-Keto Transformation. Journal of the American Chemical Society. 137: 5155-62
Chisholm MH, Brown-Xu SE, Spilker TF. (2015) Photophysical studies of metal to ligand charge transfer involving quadruply bonded complexes of molybdenum and tungsten. Accounts of Chemical Research. 48: 877-85
Brown-Xu SE, Chisholm MH, Durr CB, et al. (2015) MM quadruply bonded complexes supported by vinylbenzoate ligands: Synthesis, characterization, photophysical properties and application as synthons Chemical Science. 6: 1780-1791
Chisholm MH, Brown-Xu SE, Spilker TF. (2015) Photophysical Studies of Metal to Ligand Charge Transfer Involving Quadruply Bonded Complexes of Molybdenum and Tungsten Accounts of Chemical Research. 48: 877-885
Brown-Xu SE, Chisholm MH, Durr CB, et al. (2014) Photophysical properties of cis-Mo2 quadruply bonded complexes and observation of photoinduced electron transfer to titanium dioxide. Journal of the American Chemical Society. 136: 11428-35
Alberding BG, Chisholm MH, Durr CB, et al. (2014) 4-Nitrophenyl- and 4'-nitro-1,1'-biphenyl-4-carboxylates attached to Mo2 quadruple bonds: ground versus excited state M2δ-ligand conjugation. Dalton Transactions (Cambridge, England : 2003). 43: 11397-403
Brown-Xu SE, Chisholm MH, Durr CB, et al. (2014) Mo2 paddlewheel complexes functionalized with a single MLCT, S1 infrared-active carboxylate reporter ligand: preparation and studies of ground and photoexcited states. Inorganic Chemistry. 53: 637-44
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