Paul G. Williard
Affiliations: | Chemistry | Brown University, Providence, RI |
Area:
total synthesis of several marine natural products as well as vitamin D derivatives, characterization of reactive intermediates such as enolate anions and amide basesWebsite:
http://research.brown.edu/research/profile.php?id=1106970163&r=1Google:
"Paul Williard"Parents
Sign in to add mentor| Harold W. Heine | grad student | 1972 | Bucknell University | |
| (BS/MS at Bucknell) | ||||
| Gilbert Stork | grad student | 1976 | Columbia | |
| (Investigation of a Novel Carbon-Carbon Bond Forming Reaction) | ||||
| George H. Büchi | post-doc | 1976-1979 | MIT | |
Children
Sign in to add trainee| Nancy E. Lee | grad student | 1994 | Brown |
| Chengzao Sun | grad student | 2001 | Brown |
| Madeleine A. Jacobson | grad student | 2002 | Brown |
| Ivan Keresztes | grad student | 2002 | Brown |
| Joanna L. Turteltaub | grad student | 2007 | Brown |
| Maria R. Rella | grad student | 2008 | Brown |
| Deyu Li | grad student | 2009 | Brown |
| Chi Cheung Su | grad student | 2010-2015 | Brown |
| Onkei Tai | grad student | 2017 | Brown |
| Kenneth W. Henderson | post-doc | Brown |
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Publications
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| Pang H, Williard PG. (2020) Solid state aldol reactions of solvated and unsolvated lithium pinacolone enolate aggregates Tetrahedron. 76: 130913 |
| Seo J, Shearer J, Williard PG, et al. (2019) Reactivity of a biomimetic W(iv) bis-dithiolene complex with CO leading to formate production and structural rearrangement. Dalton Transactions (Cambridge, England : 2003) |
| Berton M, Mello R, Williard PG, et al. (2017) On the Reactivity of Lithium β-ketocarboxylates: the Role of Lithium salts. Journal of the American Chemical Society |
| Tai O, Hopson R, Williard PG. (2017) Aggregation and Solvation of n-Butyllithium. Organic Letters |
| Tai O, Hopson R, Williard PG. (2017) Ligand Binding Constants to Lithium Hexamethyldisilazide (LiHMDS) Determined by Diffusion-ordered NMR Spectroscopy (DOSY). The Journal of Organic Chemistry |
| Guang J, Liu QP, Hopson R, et al. (2016) Conformational Polymorphism of Lithium Pinacolone Enolate. Journal of the American Chemical Society |
| Guang J, Hopson R, Williard PG, et al. (2016) Perfluoroalkyl Grignard Reagents: NMR Study of 1-Heptafluoropropylmagnesium Chloride in Solution. The Journal of Organic Chemistry |
| Zhang Y, Williard PG, Bernskoetter WH. (2016) Synthesis and Characterization of Pincer-Molybdenum Precatalysts for CO2 Hydrogenation Organometallics. 35: 860-865 |
| Zhang Y, MacIntosh AD, Wong JL, et al. (2015) Iron catalyzed CO2 hydrogenation to formate enhanced by Lewis acid co-catalysts. Chemical Science. 6: 4291-4299 |
| Fujiu M, Negishi K, Guang J, et al. (2015) Chemo-, regio-, and stereo-selective perfluoroalkylations by a Grignard complex with zirconocene. Dalton Transactions (Cambridge, England : 2003). 44: 19464-8 |