James A. Franz

Affiliations: 
Fundamental & Computational Sciences Pacific Northwest National Laboratory, Richland, WA, United States 
Area:
free radical chemistry and homogeneous catalysis
Website:
http://iic.pnnl.gov/staff/Jim_Franz.stm
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"James A. Franz"

Parents

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James Cullen Martin grad student 1974 UIUC
 (Reactions of diaryldialkoxysulfuranes with active hydrogen compounds)

Children

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Thomas W Nalli post-doc 1986-1987 PNNL
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Publications

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Glezakou VA, Rousseau R, Elbert ST, et al. (2017) Trends in Homolytic Bond Dissociation Energies of Five- and Six-Coordinate Hydrides of Group 9 Transition Metals: Co, Rh, Ir. The Journal of Physical Chemistry. A
Norton JR, Spataru T, Camaioni DM, et al. (2014) Kinetics and mechanism of the hydrogenation of the CpCr(CO) 3 •/[CpCr(CO)3]2 equilibrium to CpCr(CO)3H Organometallics. 33: 2496-2502
Franz JA, O'Hagan M, Ho MH, et al. (2013) Conformational dynamics and proton relay positioning in nickel catalysts for hydrogen production and oxidation Organometallics. 32: 7034-7042
Roberts JA, Franz JA, van der Eide EF, et al. (2011) Comproportionation of cationic and anionic tungsten complexes having an N-heterocyclic carbene ligand to give the isolable 17-electron tungsten radical CpW(CO)2(IMes)(•). Journal of the American Chemical Society. 133: 14593-603
Cheng TY, Szalda DJ, Franz JA, et al. (2010) Structural and computational studies of Cp(CO)2(PCy3)MoFBF3, a complex with a bound BF4 - ligand Inorganica Chimica Acta. 363: 581-585
Franz JA, Lee SJ, Bowden TA, et al. (2009) Activation of the S-H group in Fe(mu(2)-SH)Fe clusters: S-H bond strengths and free radical reactivity of the Fe(mu(2)-SH)Fe cluster. Journal of the American Chemical Society. 131: 15212-24
Appel AM, Lee SJ, Franz JA, et al. (2009) Free energy landscapes for S-H bonds in Cp*2Mo2S4 complexes. Journal of the American Chemical Society. 131: 5224-32
Mader EA, Manner VW, Markle TF, et al. (2009) Trends in ground-state entropies for transition metal based hydrogen atom transfer reactions. Journal of the American Chemical Society. 131: 4335-45
Appel AM, Lee SJ, Franz JA, et al. (2009) Determination of S - H bond strengths in dimolybdenum tetrasulfide complexes Organometallics. 28: 749-754
Appel AM, Lee SJ, Franz JA, et al. (2008) Formation and reactivity of a persistent radical in a dinuclear molybdenum complex. Journal of the American Chemical Society. 130: 8940-51
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