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Steven J. Malcolmson, Ph.D. - Publications

Affiliations: 
2010 Graduate School of Arts & Sciences Boston College, Newton, MA, United States 
Area:
catalysts
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39 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Zhu J, Rahim F, Zhou P, Zhang A, Malcolmson SJ. Copper-Catalyzed Diastereo-, Enantio-, and ()-Selective Aminoallylation of Ketones through Reductive Couplings of Azatrienes for the Synthesis of Allylic 1,2-Amino Tertiary Alcohols. Journal of the American Chemical Society. PMID 39011628 DOI: 10.1021/jacs.4c05637  0.315
2023 Ma X, Malcolmson SJ. Palladium-Catalyzed Regiodivergent Three-Component Alkenylamination of 1,3-Dienes with Alkyl and Aryl Amines. Journal of the American Chemical Society. PMID 38054457 DOI: 10.1021/jacs.3c09873  0.385
2021 Zhou P, Shao X, Malcolmson SJ. A Diastereodivergent and Enantioselective Approach to - and -Diamines: Development of 2-Azatrienes for Cu-Catalyzed Reductive Couplings with Imines That Furnish Allylic Amines. Journal of the American Chemical Society. PMID 34424694 DOI: 10.1021/jacs.1c07707  0.353
2020 Onyeagusi CI, Malcolmson SJ. Strategies for the Catalytic Enantioselective Synthesis of -Trifluoromethyl Amines. Acs Catalysis. 10: 12507-12536. PMID 34306806 DOI: 10.1021/acscatal.0c03569  0.383
2020 Colell JFP, Logan AWJ, Zhou Z, Lindale JR, Laasner R, Shchepin RV, Chekmenev EY, Blum V, Warren WS, Malcolmson SJ, Theis T. Rational ligand choice extends the SABRE substrate scope. Chemical Communications (Cambridge, England). PMID 32671356 DOI: 10.1039/D0Cc01330G  0.351
2020 Adamson NJ, Park S, Zhou P, Nguyen AL, Malcolmson SJ. Enantioselective Construction of Quaternary Stereogenic Centers by the Addition of an Acyl Anion Equivalent to 1,3-Dienes. Organic Letters. PMID 32052974 DOI: 10.1021/Acs.Orglett.0C00412  0.443
2020 Onyeagusi CI, Shao X, Malcolmson SJ. Enantio- and Diastereoselective Synthesis of Homoallylic α-Trifluoromethyl Amines by Catalytic Hydroalkylation of Dienes. Organic Letters. PMID 32013445 DOI: 10.1021/Acs.Orglett.0C00342  0.506
2019 Malcolmson SJ, Li K, Shao X. 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 30: 1253-1268. PMID 33731976 DOI: 10.1055/s-0037-1611770  0.383
2019 Shao X, Malcolmson SJ. Catalytic Enantio- and Diastereoselective Cyclopropanation of 2-Azadienes for the Synthesis of Aminocyclopropanes Bearing Quaternary Carbon Stereogenic Centers. Organic Letters. PMID 31465235 DOI: 10.1021/Acs.Orglett.9B02692  0.454
2019 Park S, Adamson NJ, Malcolmson SJ. Brønsted acid and Pd-PHOX dual-catalysed enantioselective addition of activated C-pronucleophiles to internal dienes. Chemical Science. 10: 5176-5182. PMID 31183071 DOI: 10.1039/C9Sc00633H  0.449
2019 Daniel PE, Onyeagusi CI, Ribeiro AA, Li K, Malcolmson SJ. Palladium-Catalyzed Synthesis of -Trifluoromethyl Benzylic Amines via Fluoroarylation of -Difluoro-2-azadienes Enabled by Phosphine-Catalyzed Formation of an Azaallyl-Silver Intermediate. Acs Catalysis. 9: 205-210. PMID 31105988 DOI: 10.1021/Acscatal.8B03999  0.489
2019 Adamson NJ, Jeddi H, Malcolmson SJ. Preparation of Chiral Allenes through Pd-Catalyzed Intermolecular Hydroamination of Conjugated Enynes: Enantioselective Synthesis Enabled by Catalyst Design. Journal of the American Chemical Society. PMID 31070902 DOI: 10.1021/Jacs.9B02637  0.495
2019 Malcolmson SJ, Li K, Shao X. 2-Azadienes as Enamine Umpolung Synthons for the Preparation of Chiral Amines Synlett. 30: 1253-1268. DOI: 10.1055/S-0037-1611770  0.486
2019 Adamson NJ, Malcolmson SJ. Catalytic Enantio- and Regioselective Addition of Nucleophiles in the Intermolecular Hydrofunctionalization of 1,3-Dienes Acs Catalysis. 10: 1060-1076. DOI: 10.1021/Acscatal.9B04712  0.499
2018 Shao X, Li K, Malcolmson SJ. Enantioselective Synthesis of anti-1,2-Diamines by Cu-Catalyzed Reductive Couplings of Azadienes with Aldimines and Ketimines. Journal of the American Chemical Society. PMID 29775301 DOI: 10.1021/Jacs.8B04750  0.427
2018 Adamson NJ, Wilbur KCE, Malcolmson SJ. Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles. Journal of the American Chemical Society. PMID 29446922 DOI: 10.1021/Jacs.7B13300  0.416
2018 Park S, Malcolmson SJ. Development and Mechanistic Investigations of Enantioselective Pd-Catalyzed Intermolecular Hydroaminations of Internal Dienes Acs Catalysis. 8: 8468-8476. DOI: 10.1021/Acscatal.8B01914  0.433
2017 Li K, Shao X, Tseng L, Malcolmson SJ. 2-Azadienes as Reagents for Preparing Chiral Amines: Synthesis of 1,2-Amino Tertiary Alcohols by Cu-Catalyzed Enantioselective Reductive Couplings with Ketones. Journal of the American Chemical Society. PMID 29272124 DOI: 10.1021/Jacs.7B12213  0.448
2017 Li K, Weber AE, Tseng L, Malcolmson SJ. Diastereoselective and Enantiospecific Synthesis of 1,3-Diamines via 2-Azaallyl Anion Benzylic Ring-Opening of Aziridines. Organic Letters. PMID 28771013 DOI: 10.1021/Acs.Orglett.7B01886  0.487
2017 Daniel PE, Weber AE, Malcolmson SJ. Umpolung Synthesis of 1,3-Amino Alcohols: Stereoselective Addition of 2-Azaallyl Anions to Epoxides. Organic Letters. PMID 28656772 DOI: 10.1021/Acs.Orglett.7B01471  0.346
2017 Adamson NJ, Hull E, Malcolmson SJ. Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd-PHOX Catalyst. Journal of the American Chemical Society. PMID 28453290 DOI: 10.1021/Jacs.7B03480  0.456
2013 Malcolmson SJ, Young TS, Ruby JG, Skewes-Cox P, Walsh CT. The posttranslational modification cascade to the thiopeptide berninamycin generates linear forms and altered macrocyclic scaffolds. Proceedings of the National Academy of Sciences of the United States of America. 110: 8483-8. PMID 23650400 DOI: 10.1073/Pnas.1307111110  0.676
2012 Lichtscheidl AG, Ng VW, Müller P, Takase MK, Schrock RR, Malcolmson SJ, Meek SJ, Li B, Kiesewetter ET, Hoveyda AH. Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes. Organometallics. 31: 4558-4564. PMID 22899875 DOI: 10.1021/Om300353E  0.689
2012 Walsh CT, Malcolmson SJ, Young TS. Three ring posttranslational circuses: insertion of oxazoles, thiazoles, and pyridines into protein-derived frameworks. Acs Chemical Biology. 7: 429-42. PMID 22206579 DOI: 10.1021/Cb200518N  0.696
2011 Crawford JM, Mahlstedt SA, Malcolmson SJ, Clardy J, Walsh CT. Dihydrophenylalanine: a prephenate-derived Photorhabdus luminescens antibiotic and intermediate in dihydrostilbene biosynthesis. Chemistry & Biology. 18: 1102-12. PMID 21944749 DOI: 10.1016/J.Chembiol.2011.07.009  0.707
2011 Zhang W, Ntai I, Bolla ML, Malcolmson SJ, Kahne D, Kelleher NL, Walsh CT. Nine enzymes are required for assembly of the pacidamycin group of peptidyl nucleoside antibiotics. Journal of the American Chemical Society. 133: 5240-3. PMID 21417270 DOI: 10.1021/Ja2011109  0.597
2011 Hoveyda AH, Malcolmson SJ, Meek SJ, Zhugralin AR. ChemInform Abstract: Catalytic Enantioselective Olefin Metathesis Reactions Cheminform. 42: no-no. DOI: 10.1002/chin.201118234  0.738
2010 Hoveyda AH, Malcolmson SJ, Meek SJ, Zhugralin AR. Catalytic enantioselective olefin metathesis in natural product synthesis. Chiral metal-based complexes that deliver high enantioselectivity and more. Angewandte Chemie (International Ed. in English). 49: 34-44. PMID 19967680 DOI: 10.1002/Anie.200904491  0.783
2010 Hoveyda AH, Malcolmson SJ, Meek SJ, Zhugralin AR. Catalytic Enantioselective Olefin Metathesis and Natural Product Synthesis Metathesis in Natural Product Synthesis: Strategies, Substrates and Catalysts. 343-348. DOI: 10.1002/9783527629626.ch12  0.766
2010 Ji JX, Chan ASC, Helmchen G, Kazmaier U, Förster S, Ojima I, Kaloko JJ, Chaterpaul SJ, Teng YHG, Lin CF, Mikami K, Aikawa K, Hoveyda AH, Malcolmson SJ, Meek SJ, et al. Asymmetric Carbon-Carbon Bond-Forming Reactions Catalytic Asymmetric Synthesis: Third Edition. 437-770. DOI: 10.1002/9780470584248.ch8  0.671
2009 Meek SJ, Malcolmson SJ, Li B, Schrock RR, Hoveyda AH. The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes. Journal of the American Chemical Society. 131: 16407-9. PMID 19842640 DOI: 10.1021/Ja907805F  0.769
2009 Sattely ES, Meek SJ, Malcolmson SJ, Schrock RR, Hoveyda AH. Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. Journal of the American Chemical Society. 131: 943-53. PMID 19113867 DOI: 10.1021/Ja8084934  0.806
2009 Harvey JS, Malcolmson SJ, Dunne KS, Meek SJ, Thompson AL, Schrock RR, Hoveyda AH, Gouverneur V. Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis. Angewandte Chemie (International Ed. in English). 48: 762-6. PMID 19101976 DOI: 10.1002/Anie.200805066  0.775
2009 Sattely ES, Meek SJ, Malcolmson SJ, Schrock RR, Hoveyda AH. Synthesis of (+)-Quebrachamine Synfacts. 2009: 817-817. DOI: 10.1055/S-0029-1217578  0.77
2009 Harvey JS, Malcolmson SJ, Dunne KS, Meek SJ, Thompson AL, Schrock RR, Hoveyda AH, Gouverneur V. Synthesis of P-Stereogenic Centers Through Ring-Closing Metathesis Synfacts. 2009: 397-397. DOI: 10.1055/S-0028-1087898  0.73
2009 Hoveyda A, Malcolmson S, Meek S, Sattely E, Schrock R. Molybdenum-Catalyzed Enantioselective Alkene Metathesis Synfacts. 2009: 0293-0293. DOI: 10.1055/S-0028-1087747  0.797
2009 Hoveyda A, Malcolmson S, Meek S, Zhugralin A. Katalytische enantioselektive Olefinmetathese in der Naturstoffsynthese: chirale Metallkomplexe für hohe Enantioselektivitäten und vieles mehr Angewandte Chemie. 122: 38-49. DOI: 10.1002/Ange.200904491  0.728
2008 Malcolmson SJ, Meek SJ, Sattely ES, Schrock RR, Hoveyda AH. Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis. Nature. 456: 933-7. PMID 19011612 DOI: 10.1038/Nature07594  0.789
2006 Lee AL, Malcolmson SJ, Puglisi A, Schrock RR, Hoveyda AH. Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis. Journal of the American Chemical Society. 128: 5153-7. PMID 16608351 DOI: 10.1021/Ja058428R  0.661
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