Ernest Grunwald - Publications

Affiliations: 
Brandeis University, Waltham, MA, United States 
Area:
physical organic chemistry
Website:
http://www.nap.edu/openbook.php?record_id=10992&page=146

81 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
1989 Grunwald E. Application of Kirkwood's Theory of the Dielectric Constant to Solutes Hydrogen-Bonded in the Water Network Journal of Solution Chemistry. 18: 331-353. DOI: 10.1007/Bf00656772  0.308
1977 Chang KC, Grunwald E, Robinson LR. Bifunctional proton transfer and acid-base properties of 1,4,7,10-tetraazacyclododecane (cyclen) Journal of the American Chemical Society. 99: 3794-3796. DOI: 10.1021/Ja00453A045  0.333
1977 Chang KC, Grunwald E, Robinson LR. Bifunctional Proton Transfer And Acid-Base Properties Of 1,4,7,10-Tetraazacyclododecane (Cyclen) Cheminform. 8. DOI: 10.1002/Chin.197734096  0.333
1976 Chang K, Grunwald E. Bifunctional proton transfer of the conjugate base of uracil compared with that of imidazole in aqueous solution Journal of the American Chemical Society. 98: 3737-3738. DOI: 10.1021/Ja00428A074  0.329
1976 Grunwald E, Crampton MR, Effio A, I T. Molecular structure of ion pairs from electric dipole moments. IV. Ion-pair solvation in acetic acid Journal of the American Chemical Society. 98: 1716-1720. DOI: 10.1021/Ja00423A014  0.317
1976 I T, Grunwald E. Molecular structure of ion pairs from electric dipole moments. III. Substituted anilinium chlorides and p-toluenesulfonates in octanoic acid Journal of the American Chemical Society. 98: 1351-1354. DOI: 10.1021/Ja00422A011  0.325
1976 Grunwald E, Chang KC, Skipper PL, Anderson VK. Kinetics of bifunctional proton transfer. 2. Lysine and cysteine in aqueous solutions The Journal of Physical Chemistry. 80: 1425-1431. DOI: 10.1021/J100554A008  0.339
1976 Chang KC, Grunwald E. Water participation in proton-transfer reactions of glycine and glycine methyl ester The Journal of Physical Chemistry. 80: 1422-1425. DOI: 10.1021/J100554A007  0.326
1976 Chang K, Grunwald E. Bifunctional proton transfer of the conjugate base of uracil compared with that of imidazole in aqueous solution Cheminform. 7. DOI: 10.1002/Chin.197636124  0.329
1975 Bell JA, Grunwald E, Hayon E. Kinetics of deprotonation of organic free radicals in water. Reaction of glycolate (HOCHCO2-), (HOCHCONH2), and (HOCCH3CONH2) with various bases Journal of the American Chemical Society. 97: 2995-3000. DOI: 10.1021/Ja00844A014  0.309
1975 Highsmith S, Grunwald E. Proton Exchange Of Carboxylic Acids In 1-Octanol Cheminform. 6. DOI: 10.1002/Chin.197503149  0.358
1974 Eustace D, Grunwald E. Ionization of anilines in carboxylic acid solvents. Equilibrium constants, stoichiometry, solvent and substituent effects, electric dipole moments, and proton exchange Journal of the American Chemical Society. 96: 7171-7176. DOI: 10.1021/Ja00830A001  0.386
1974 I T, Grunwald E. Molecular structure of ion pairs from electric dipole moments. II. Complexing of potassium p-toluenesulfonate and lithium chloride with macrocyclic polyethers in octanoic acid Journal of the American Chemical Society. 96: 2879-2884. DOI: 10.1021/Ja00816A035  0.311
1974 I T, Grunwald E. Molecular structure of ion pairs from electric dipole moments. I. Potassium p-toluenesulfonate and lithium chloride in octanoic acid Journal of the American Chemical Society. 96: 2387-2392. DOI: 10.1021/Ja00815A014  0.318
1974 Highsmith S, Grunwald E. Proton Exchange of Carboxylic Acids in 1-Octanol The Journal of Physical Chemistry. 78: 2339-2340. DOI: 10.1021/J150671A008  0.358
1974 I T, Grunwald E. Molecular Structure Of Ion Pairs From Electric Dipole Moments Part 1, Potassium P-Toluenesulfonate And Lithium Chloride In Octanoic Acid Cheminform. 5. DOI: 10.1002/Chin.197426094  0.318
1973 Hendrickson JB, Boeckman RK, Glickson JD, Grunwald E. Molecular geometry. VIII. Proton magnetic resonance studies of gycloheptane conformations Journal of the American Chemical Society. 95: 494-505. DOI: 10.1021/Ja00783A032  0.533
1973 Grunwald E, Effio A. Electric dipole moments in polar solvents. I. Audiofrequency measurement with slightly conducting solutions Journal of Solution Chemistry. 2: 373-392. DOI: 10.1007/Bf00713251  0.326
1973 HENDRICKSON JB, BOECKMAN RKJ, GLICKSON JD, GRUNWALD E. ChemInform Abstract: MOLEKUELGEOMETRIE 8. MITT. (1)H-NMR-UNTERSUCHUNGEN VON CYCLOHEPTAN-KONFORM. Chemischer Informationsdienst. 4. DOI: 10.1002/Chin.197329080  0.504
1972 Jones FM, Eustace D, Grunwald E. Rates of exchange of acetic acid molecules at the amide hydrogen-bond acceptor site of aniline bases Journal of the American Chemical Society. 94: 8941-8942. DOI: 10.1021/Ja00780A069  0.317
1972 Grunwald E, Fong D. Solvation and bifunctional proton transfer of (NH3)5PtNH23+ in aqueous solution Journal of the American Chemical Society. 94: 7371-7377. DOI: 10.1021/Ja00776A018  0.334
1972 Rosenthal D, Grunwald E. Quatermolecular Proton Transfer Of 2,4-Lutidine And Its Conjugate Acid In Aqueous Solution. Journal of the American Chemical Society. 94: 5956-5961. DOI: 10.1021/Ja00772A004  0.361
1971 Grunwald E, Crampton MR. Kinetics of ion-pair exchange in acetic acid. II. Effect of the cation on reaction rate Journal of the American Chemical Society. 93: 2990-2994. DOI: 10.1021/Ja00741A029  0.38
1971 Grunwald E, Crampton MR. Kinetics of ion-pair exchange in acetic acid. I. Rate constants deduced from proton exchange of anilinium salts Journal of the American Chemical Society. 93: 2987-2990. DOI: 10.1021/Ja00741A028  0.385
1971 Grunwald E, Ralph EK. Kinetic studies of hydrogen-bonded solvation complexes of amines in water and hydroxylic solvents Accounts of Chemical Research. 4: 107-113. DOI: 10.1021/Ar50039A005  0.303
1970 Crampton MR, Grunwald E. Kinetics of ion-pair exchange in acetic acid Journal of the Chemical Society D: Chemical Communications. 983-984. DOI: 10.1039/C29700000983  0.311
1970 Leung CS, Grunwald E. Temperature dependence of .DELTA.-Cp.deg. for the self-ionization of methanol and for the acid dissociation of benzoic acid in methanol The Journal of Physical Chemistry. 74: 696-701. DOI: 10.1021/J100699A002  0.301
1970 Leung CS, Grunwald E. Temperature dependence of .DELTA.-Cp.deg. for the self-ionization of water and for the acid dissociation of acetic acid and benzoic acid in water The Journal of Physical Chemistry. 74: 687-696. DOI: 10.1021/J100699A001  0.315
1969 Marshall TH, Grunwald E. NH-proton exchange of purine in aqueous solution. Effect of molecular complexing on reaction rate Journal of the American Chemical Society. 91: 4541-4544. DOI: 10.1021/Ja01044A039  0.362
1969 Ralph EK, Grunwald E. Hydrogen-ion-catalyzed proton exchange in tert-butyl alcohol-water mixtures Journal of the American Chemical Society. 91: 2426-2429. DOI: 10.1021/Ja01038A003  0.324
1969 Ralph EK, Grunwald E. Kinetics of proton exchange in the ionization and acid dissociation of imidazole in aqueous acid Journal of the American Chemical Society. 91: 2422-2425. DOI: 10.1021/Ja01038A002  0.373
1969 Fong D, Grunwald E. Kinetic study of proton exchange between the Al(OH2)63+ ion and water in dilute acid. Participation of water molecules in proton transfer Journal of the American Chemical Society. 91: 2413-2422. DOI: 10.1021/Ja01038A001  0.361
1969 Leung CS, Grunwald E. Substituent effects in the ion-pair dissociation of anilinium acetate and anilinium p-toluenesulfonate in acetic acid The Journal of Physical Chemistry. 73: 1822-1830. DOI: 10.1021/J100726A031  0.344
1969 Grunwald E, Fong D. Acidity and association of aluminum ion in dilute aqueous acid The Journal of Physical Chemistry. 73: 650-653. DOI: 10.1021/J100723A028  0.339
1968 Ralph EK, Grunwald E. Higher-than-termolecular proton transfer in aqueous solutions of imidazole Journal of the American Chemical Society. 90: 517-517. DOI: 10.1021/Ja01004A069  0.325
1968 Grunwald E, Ku AY. Proton exchange between ammonium ion, trimethyl-ammonium ion, and water. Speed of the dehydration step that precedes bimolecular proton transfer Journal of the American Chemical Society. 90: 29-31. DOI: 10.1021/Ja01003A006  0.338
1968 Grunwald E, Haley JF. Acid dissociation constant of trifluoroacetic acid in water measured by differential refractometry The Journal of Physical Chemistry. 72: 1944-1948. DOI: 10.1021/J100852A015  0.327
1967 Grunwald E, Ralph EK. Rate constants for the dissociation of amine-water hydrogen bonds and the effect of nonpolar groups in aqueous solution Journal of the American Chemical Society. 89: 4405-4411. DOI: 10.1021/Ja00993A028  0.337
1967 Puar MS, Grunwald E. Proton exchange and hydrogen bonding of salicyclic acid in methanol Journal of the American Chemical Society. 89: 4403-4405. DOI: 10.1021/Ja00993A027  0.324
1967 Ralph EK, Grunwald E. Proton Exchange Of Triethylammonium Ion In Aqueous Solution. Journal of the American Chemical Society. 89: 2963-2967. DOI: 10.1021/Ja00988A028  0.343
1967 Ceska GW, Grunwald E. Equilibrium Constants and Substituent Effects in the Ionization of Aniline as a Base and the Ion-Pair Dissociation of Anilinium Acetate in Glacial Acetic Acid Journal of the American Chemical Society. 89: 1371-1376. DOI: 10.1021/Ja00982A016  0.365
1967 Grunwald E. A nuclear magnetic resonance study of acid dissociation and proton exchange of trimethylammonium ion in methanol The Journal of Physical Chemistry. 71: 1846-1850. DOI: 10.1021/J100865A048  0.345
1967 Grunwald E, Puar MS. Proton exchange of phenol in aqueous acid The Journal of Physical Chemistry. 71: 1842-1845. DOI: 10.1021/J100865A047  0.372
1967 Grunwald E, Jumper CF, Puar MS. Rates and solvent participation in acid-base reactions of substituted phenols and phenoxides in methanol The Journal of Physical Chemistry. 71: 492-499. DOI: 10.1021/J100862A006  0.362
1965 Grunwald E, Cocivera M. Solvent participation in proton transfer reactions of amines and their conjugate acids Discussions of the Faraday Society. 39: 105-111. DOI: 10.1039/Df9653900105  0.383
1965 Cocivera M, Grunwald E. Hydrogen-Bonded Structure of Ion Pairs of Ammonium Salts as Deduced from Proton-Exchange Rates Journal of the American Chemical Society. 87: 2070-2071. DOI: 10.1021/Ja01087A054  0.327
1965 Winters LJ, Grunwald E. Organic Reactions Occurring in or on Micelles. III. Reaction of Methyl Bromide with Cyanide Ion1,2 Journal of the American Chemical Society. 87: 4608-4611. DOI: 10.1021/Ja00948A037  0.321
1964 Grunwald E, Price E. Relative Strength of Picric, Acetic, and Trichloroacetic Acids in Various Environments. Dispersion Effects in Acid-Base Equilibria Journal of the American Chemical Society. 86: 4517-4525. DOI: 10.1021/Ja01075A001  0.303
1964 Grunwald E, Price E. Ionization and Proton Exchange of Amines in Acetic Acid. II. Effect of Structure on Reactivity and the Reaction Mechanism Journal of the American Chemical Society. 86: 2970-2977. DOI: 10.1021/Ja01069A002  0.366
1964 Grunwald E, Price E. Ionization and Proton Exchange of Amines in Acetic Acid. I. Kinetic and Equilibrium Properties for Solutions of Methylamine Journal of the American Chemical Society. 86: 2965-2970. DOI: 10.1021/Ja01069A001  0.387
1964 Price E, Grunwald E. Metathetical Reactions of Ion Pairs in Acetic Acid The Journal of Physical Chemistry. 68: 3876-3878. DOI: 10.1021/J100794A503  0.369
1964 Cocivera M, Grunwald E, Jumper CF. Acid Dissociation and Proton Transfer of p-Toluidinium Ion and Dimethylphenylphosphonium Ion in Methanol The Journal of Physical Chemistry. 68: 3234-3239. DOI: 10.1021/J100793A026  0.346
1963 Grunwald E, Jumper CF. Kinetics and Mechanism of the Proton Transfer between Methyloxonium Ion and Benzoic Acid in Methanol Solution Journal of the American Chemical Society. 85: 2051-2052. DOI: 10.1021/Ja00897A004  0.393
1963 Grunwald E, Meiboom S. Kinetics of proton transfer in methanol for a series of carboxylic acids of varying strength Journal of the American Chemical Society. 85: 2047-2050. DOI: 10.1021/Ja00897A003  0.655
1963 Grunwald E, Jumper CF, Meiboom S. Kinetics of proton transfer in methanol solutions of benzoic acid and sodium benzoate Journal of the American Chemical Society. 85: 522-528. DOI: 10.1021/Ja00888A008  0.662
1962 Grunwald E, Jumper CF, Meiboom S. Kinetics of Proton Transfer in Methanol and the Mechanism of the Abnormal Conductance of the Hydrogen Ion Journal of the American Chemical Society. 84: 4664-4671. DOI: 10.1021/Ja00883A011  0.342
1961 Berkowitz BJ, Grunwald E. MOLAR REFRACTION AS AN INDEX OF PROTON TRANSFER: AN ESTIMATE OF THE ACID STRENGTH OF p-TOLUENESULFONIC ACID Journal of the American Chemical Society. 83: 2956-2956. DOI: 10.1021/Ja01474A041  0.323
1960 Grunwald E, Karabatsos PJ, Kromhout RA, Purlee EL. Proton‐Transfer Studies by Nuclear Magnetic Resonance. II. Rate Constants and Mechanism for the Reaction CH3NH3++OH2+NH2CH3 in Aqueous Acid Journal of Chemical Physics. 33: 556-563. DOI: 10.1063/1.1731183  0.317
1960 Emerson MT, Grunwald E, Kromhout RA. Proton‐Transfer Studies by Nuclear Magnetic Resonance. I. Diffusion Control in the Reaction of Ammonium Ion in Aqueous Acid Journal of Chemical Physics. 33: 547-555. DOI: 10.1063/1.1731182  0.343
1960 Emerson MT, Grunwald E, Kaplan ML, Kromhout RA. Proton Transfer Studies by Nuclear Magnetic Resonance. III. The Mean Life of the Amine-Water Hydrogen Bond in Aqueous Solution1a Journal of the American Chemical Society. 82: 6307-6314. DOI: 10.1021/Ja01509A030  0.317
1959 Duynstee EFJ, Grunwald E. Organic Reactions Occurring in or on Micelles. I. Reaction Rate Studies of the Alkaline Fading of Triphenylmethane Dyes and Sulfonphthalein Indicators in the Presence of Detergent Salts1 Journal of the American Chemical Society. 81: 4540-4542. DOI: 10.1021/Ja01526A025  0.302
1957 Grunwald E, Loewenstein A, Meiboom S. Application of nuclear magnetic resonance to the study of acid-base equilibria The Journal of Chemical Physics. 27: 641-642. DOI: 10.1063/1.1743803  0.646
1957 Grunwald E, Loewenstein A, Meiboom S. Rates and Mechanisms of Protolysis of Methylammonium Ion in Aqueous Solution Studied by Proton Magnetic Resonance Journal of Chemical Physics. 27: 630-640. DOI: 10.1063/1.1743802  0.387
1957 Heck R, Corse J, Grunwald E, Winstein S. The Role of Neighboring Groups in Replacement Reactions. XXII. Competition between o-MeO-5 and Ar1-3 Participation in Solvolysis of o-Methoxyneophyl Tolunesulfonate1,2 Journal of the American Chemical Society. 79: 3278-3284. DOI: 10.1021/Ja01569A076  0.446
1957 Purlee EL, Grunwald E. The Measurement of Acid Dissociation Constants and Ion-pair Dissociation Constants in Solvents of Intermediate Dielectric Constant. Carboxylic Acids and their Sodium and Potassium Salts in 70% Dioxane-30% Water1 Journal of the American Chemical Society. 79: 1372-1376. DOI: 10.1021/Ja01563A030  0.385
1957 Purlee EL, Grunwald E. The Potentiometric Measurement of Ion-pair Dissociation Constants. HCl, NaCl and KCl in 70% Dioxane-30% Water1 Journal of the American Chemical Society. 79: 1366-1372. DOI: 10.1021/Ja01563A029  0.321
1956 Grunwald E, Lowenstein A, Meiboom S. Study of the Protolysis of Methylammonium Ion in Water by Proton Magnetic Resonance Journal of Chemical Physics. 25: 382-383. DOI: 10.1063/1.1742924  0.308
1955 Bacarella AL, Grunwald E, Marshall HP, Purlee EL. THE POTENTIOMETRIC MEASUREMENT OF ACID DISSOCIATION CONSTANTS AND pH IN THE SYSTEM METHANOL-WATER. pKA VALUES FOR CARBOXYLIC ACIDS AND ANILINIUM IONS Journal of Organic Chemistry. 20: 747-762. DOI: 10.1021/Jo01124A007  0.349
1955 Grunwald E, Cristol SJ. Mechanisms of Elimination Reactions. XIV. Solvent and Salt Effects in the Alkaline Dehydrohalogenation of Chloro- and Bromomaleate and -Fumarate1a Journal of the American Chemical Society. 77: 2891-2892. DOI: 10.1021/Ja01615A067  0.329
1954 Marshall HP, Grunwald E. The Measurement and Correlation of Acid Dissociation Constants for Ammonium and Anilinium Salts in the System Dioxane-Water1 Journal of the American Chemical Society. 76: 2000-2004. DOI: 10.1021/Ja01636A090  0.335
1953 Gutbezahl B, Grunwald E. The Effect of Solvent on Equilibrium and Rate Constants. II. The Measurement and Correlation of Acid Dissociation Constants of Anilinium and Ammonium Salts in the System Ethanol—Water1,2a Journal of the American Chemical Society. 75: 559-565. DOI: 10.1021/Ja01099A014  0.314
1951 Grunwald E, Berkowitz BJ. The Measurement and Correlation of Acid Dissociation Constants for Carboxylic Acids in the System Ethanol-Water. Activity Coefficients and Empirical Activity Functions1a Journal of the American Chemical Society. 73: 4939-4944. DOI: 10.1021/Ja01154A139  0.314
1951 Winstein S, Grunwald E, Jones HW. The Correlation of Solvolysis Rates and the Classification of Solvolysis Reactions into Mechanistic Categories Journal of the American Chemical Society. 73: 2700-2707. DOI: 10.1021/Ja01150A078  0.483
1948 Grunwald E, Winstein S. The Correlation of Solvolysis Rates Journal of the American Chemical Society. 70: 846-854. DOI: 10.1021/Ja01182A117  0.447
1948 Grunwald E, Winstein S. The Role of Neighboring Groups in Replacement Reactions. XV. Rates and Medium Effects in the Alcoholysis and Hydrolysis of α-Bromopropionate Ion. The Carboxylate Ion Group Journal of the American Chemical Society. 70: 841-846. DOI: 10.1021/Ja01182A116  0.514
1948 Winstein S, Grunwald E. The Role of Neighboring Groups in Replacement Reactions. XIII.1General Theory of Neighboring Groups and Reactivity Journal of the American Chemical Society. 70: 828-837. DOI: 10.1021/Ja01182A114  0.466
1948 Winstein S, Grunwald E, Ingraham LL. The Role of Neighboring Groups in Replacement Reactions. XII. Rates of Acetolysis of 2-Substituted Cyclohexyl Benzenesulfonates1 Journal of the American Chemical Society. 70: 821-828. DOI: 10.1021/Ja01182A113  0.499
1948 Winstein S, Grunwald E, Buckles RE, Hanson C. The Role of Neighboring Groups in Replacement Reactions. XI. Some Reactivities Involving Neighboring Groups1 Journal of the American Chemical Society. 70: 816-821. DOI: 10.1021/Ja01182A112  0.612
1948 Winstein S, Hanson C, Grunwald E. The Role of Neighboring Groups in Replacement Reactions. X.1Kinetics of Solvolysis of trans-2-Acetoxycyclohexyl p-Toluenesulfonate2 Journal of the American Chemical Society. 70: 812-816. DOI: 10.1021/Ja01182A111  0.481
1947 Grunwald E, Winstein S. Kinetics and Mechanism of the Reaction of Hydrogen Bromide with Ethanol Journal of the American Chemical Society. 69: 2051-2053. DOI: 10.1021/Ja01200A068  0.489
1946 Winstein S, Grunwald E. NEIGHBORING GROUPS AND REACTIVITY Journal of the American Chemical Society. 68: 536-537. DOI: 10.1021/Ja01207A521  0.44
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