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Stephen L. Buchwald - Publications

Affiliations: 
1984- Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
organometallic chemistry
Website:
http://chemistry.mit.edu/people/buchwald-stephen
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Year Citation  Score
2024 Ai HJ, Kim ST, Liu C, Buchwald SL. Correction to "Copper-Catalyzed Amination of Aryl Chlorides under Mild Reaction Conditions". Journal of the American Chemical Society. PMID 39411914 DOI: 10.1021/jacs.4c13491  0.379
2024 Feng K, Raguram ER, Howard JR, Peters E, Liu C, Sigman MS, Buchwald SL. Development of a Deactivation-Resistant Dialkylbiarylphosphine Ligand for Pd-Catalyzed Arylation of Secondary Amines. Journal of the American Chemical Society. 146: 26609-26615. PMID 39288263 DOI: 10.1021/jacs.4c09667  0.373
2024 Ai HJ, Kim ST, Liu C, Buchwald SL. Copper-Catalyzed Amination of Aryl Chlorides under Mild Reaction Conditions. Journal of the American Chemical Society. PMID 39283164 DOI: 10.1021/jacs.4c10237  0.423
2024 Strauss MJ, Liu KX, Greaves ME, Dahl JC, Kim ST, Wu YJ, Schmidt MA, Scola PM, Buchwald SL. Cu-Catalyzed Amination of Base-Sensitive Aryl Bromides and the Chemoselective N- and O-Arylation of Amino Alcohols. Journal of the American Chemical Society. PMID 38924516 DOI: 10.1021/jacs.4c05246  0.366
2024 Garhwal S, Dong Y, Mai BK, Liu P, Buchwald SL. CuH-Catalyzed Regio- and Enantioselective Formal Hydroformylation of Vinyl Arenes. Journal of the American Chemical Society. PMID 38723265 DOI: 10.1021/jacs.4c04287  0.377
2024 Strauss MJ, Greaves ME, Kim ST, Teijaro CN, Schmidt MA, Scola PM, Buchwald SL. Room-Temperature Copper-Catalyzed Etherification of Aryl Bromides. Angewandte Chemie (International Ed. in English). e202400333. PMID 38359082 DOI: 10.1002/anie.202400333  0.344
2023 Kutateladze DA, Mai BK, Dong Y, Zhang Y, Liu P, Buchwald SL. Stereoselective Synthesis of Trisubstituted Alkenes via Copper Hydride-Catalyzed Alkyne Hydroalkylation. Journal of the American Chemical Society. 145: 17557-17563. PMID 37540777 DOI: 10.1021/jacs.3c06479  0.439
2023 Kim ST, Strauss MJ, Cabré A, Buchwald SL. Room-Temperature Cu-Catalyzed Amination of Aryl Bromides Enabled by DFT-Guided Ligand Design. Journal of the American Chemical Society. PMID 36926889 DOI: 10.1021/jacs.3c00500  0.348
2023 Ye Y, Kim ST, King RP, Baik MH, Buchwald SL. Studying Regioisomer Formation in the Pd-Catalyzed Fluorination of Cyclic Vinyl Triflates: Evidence for in situ Ligand Modification. Angewandte Chemie (International Ed. in English). e202300109. PMID 36775802 DOI: 10.1002/anie.202300109  0.383
2023 Reichert EC, Feng K, Sather AC, Buchwald SL. Pd-Catalyzed Amination of Base-Sensitive Five-Membered Heteroaryl Halides with Aliphatic Amines. Journal of the American Chemical Society. 145: 3323-3329. PMID 36719903 DOI: 10.1021/jacs.2c13520  0.809
2022 Rojas AJ, Wolfe JM, Dhanjee HH, Buslov I, Truex NL, Liu RY, Massefski W, Pentelute BL, Buchwald SL. Palladium-peptide oxidative addition complexes for bioconjugation. Chemical Science. 13: 11891-11895. PMID 36320916 DOI: 10.1039/d2sc04074c  0.61
2022 Knippel JL, Ni AZ, Schuppe AW, Buchwald SL. A General Strategy for the Asymmetric Preparation of α-Stereogenic Allyl Silanes, Germanes, and Boronate Esters via Dual Copper Hydride- and Palladium-Catalysis. Angewandte Chemie (International Ed. in English). PMID 36137941 DOI: 10.1002/anie.202212630  0.36
2022 Feng S, Dong Y, Buchwald SL. Enantioselective Hydrocarbamoylation of Alkenes. Angewandte Chemie (International Ed. in English). e202206692. PMID 35657208 DOI: 10.1002/anie.202206692  0.372
2022 Dong Y, Schuppe AW, Mai BK, Liu P, Buchwald SL. Confronting the Challenging Asymmetric Carbonyl 1,2-Addition Using Vinyl Heteroarene Pronucleophiles: Ligand-Controlled Regiodivergent Processes through a Dearomatized Allyl-Cu Species. Journal of the American Chemical Society. PMID 35341240 DOI: 10.1021/jacs.2c00734  0.358
2021 Hou CJ, Schuppe AW, Knippel JL, Ni AZ, Buchwald SL. A Dual CuH- and Pd-Catalyzed Stereoselective Synthesis of Highly Substituted 1,3-Dienes. Organic Letters. 23: 8816-8821. PMID 34726414 DOI: 10.1021/acs.orglett.1c03324  0.394
2021 King RP, Krska SW, Buchwald SL. A Neophyl Palladacycle as an Air- and Thermally Stable Precursor to Oxidative Addition Complexes. Organic Letters. PMID 34613744 DOI: 10.1021/acs.orglett.1c02307  0.658
2021 King RP, Krska SW, Buchwald SL. A Ligand Exchange Process for the Diversification of Palladium Oxidative Addition Complexes. Organic Letters. PMID 34319123 DOI: 10.1021/acs.orglett.1c02101  0.635
2021 Schuppe AW, Knippel JL, Borrajo-Calleja GM, Buchwald SL. Enantioselective Hydroalkenylation of Olefins with Enol Sulfonates Enabled by Dual Copper Hydride and Palladium Catalysis. Journal of the American Chemical Society. 143: 5330-5335. PMID 33784090 DOI: 10.1021/jacs.1c02117  0.419
2021 Feng S, Buchwald SL. CuH-Catalyzed Regio- and Enantioselective Hydrocarboxylation of Allenes: Toward Carboxylic Acids with Acyclic Quaternary Centers. Journal of the American Chemical Society. PMID 33761252 DOI: 10.1021/jacs.1c01880  0.318
2021 Jbara M, Rodriguez J, Dhanjee HH, Loas A, Buchwald SL, Pentelute BL. Oligonucleotide Bioconjugation with Bifunctional Palladium Reagents. Angewandte Chemie (International Ed. in English). PMID 33730425 DOI: 10.1002/anie.202103180  0.338
2021 Knippel JL, Ye Y, Buchwald SL. Enantioselective C2-Allylation of Benzimidazoles Using 1,3-Diene Pronucleophiles. Organic Letters. PMID 33646778 DOI: 10.1021/acs.orglett.1c00306  0.409
2020 Feng S, Hao H, Liu P, Buchwald SL. Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes. Acs Catalysis. 10: 282-291. PMID 33664986 DOI: 10.1021/acscatal.9b04871  0.362
2020 Dhanjee HH, Buslov I, Windsor IW, Raines RT, Pentelute BL, Buchwald SL. Palladium-Protein Oxidative Addition Complexes by Amine-Selective Acylation. Journal of the American Chemical Society. PMID 33319995 DOI: 10.1021/jacs.0c09180  0.318
2020 McCann SD, Reichert EC, Arrechea PL, Buchwald SL. Development of an Aryl Amination Catalyst with Broad Scope Guided by Consideration of Catalyst Stability. Journal of the American Chemical Society. 142: 15027-15037. PMID 32786769 DOI: 10.1021/Jacs.0C06139  0.5
2020 Link A, Zhou Y, Buchwald SL. CuH-Catalyzed Asymmetric Reductive Amidation of α,β-Unsaturated Carboxylic Acids. Organic Letters. 22: 5666-5670. PMID 32628019 DOI: 10.1021/Acs.Orglett.0C02064  0.408
2020 Dhanjee HH, Saebi A, Buslov I, Loftis AR, Buchwald SL, Pentelute BL. Correction to "Protein-Protein Cross-Coupling via Palladium-Protein Oxidative Addition Complexes from Cysteine Residues". Journal of the American Chemical Society. PMID 32603593 DOI: 10.1021/Jacs.0C06703  0.589
2020 Guo S, Zhu J, Buchwald SL. Enantioselective Synthesis of β-Amino Acid Derivatives Enabled by Ligand-Controlled Reversal of Hydrocupration Regiochemistry. Angewandte Chemie (International Ed. in English). PMID 32598506 DOI: 10.1002/Anie.202007005  0.357
2020 Zhang H, Ruiz-Castillo P, Schuppe AW, Buchwald SL. Improved Process for the Palladium-Catalyzed C-O Cross-Coupling of Secondary Alcohols. Organic Letters. PMID 32579375 DOI: 10.1021/Acs.Orglett.0C01668  0.411
2020 Mo Y, Lu Z, Rughoobur G, Patil P, Gershenfeld N, Akinwande AI, Buchwald SL, Jensen KF. Microfluidic electrochemistry for single-electron transfer redox-neutral reactions. Science (New York, N.Y.). 368: 1352-1357. PMID 32554592 DOI: 10.1126/Science.Aba3823  0.381
2020 Gribble MW, Liu RY, Buchwald SL. Evidence for Simultaneous Dearomatization of Two Aromatic Rings Under Mild Conditions in Cu(I)-Catalyzed Direct Asymmetric Dearomatization of Pyridine. Journal of the American Chemical Society. PMID 32453952 DOI: 10.1021/Jacs.0C04486  0.448
2020 Lu Z, Buchwald SL. The Enantioselective Preparation of Arenes with β-Stereogenic Centers: Confronting the 1,1-Disubstituted Olefin Problem Using CuH/Pd Cooperative Catalysis. Angewandte Chemie (International Ed. in English). PMID 32438497 DOI: 10.1002/Anie.202004414  0.541
2020 Ye Y, Kevlishvili I, Feng S, Liu P, Buchwald SL. Highly Enantioselective Synthesis of Indazoles with a C3-Quaternary Chiral Center Using CuH Catalysis. Journal of the American Chemical Society. PMID 32408745 DOI: 10.1021/Jacs.0C04286  0.461
2020 Liu RY, Buchwald SL. CuH-Catalyzed Olefin Functionalization: From Hydroamination to Carbonyl Addition. Accounts of Chemical Research. PMID 32401530 DOI: 10.1021/Acs.Accounts.0C00164  0.559
2020 Zhou Y, Zhou L, Jesikiewicz LT, Liu P, Buchwald SL. Synthesis of Pyrroles Through the CuH-Catalyzed Coupling of Enynes and Nitriles. Journal of the American Chemical Society. PMID 32395998 DOI: 10.1021/Jacs.0C03859  0.525
2020 Dhanjee HH, Saebi A, Buslov I, Loftis AR, Buchwald SL, Pentelute BL. Protein-Protein Cross-Coupling via Palladium-Protein Oxidative Addition Complexes from Cysteine Residues. Journal of the American Chemical Society. PMID 32364380 DOI: 10.1021/Jacs.0C03143  0.616
2020 Liu RY, Dennis JM, Buchwald SL. The Quest for the Ideal Base: Rational Design of a Nickel Precatalyst Enables Mild, Homogeneous C-N Cross-Coupling. Journal of the American Chemical Society. PMID 32040909 DOI: 10.1021/Jacs.0C00286  0.486
2020 Park BY, Pirnot MT, Buchwald SL. Visible Light-Mediated (Hetero)aryl Amination Using Ni(II) Salts and Photoredox Catalysis in Flow: A Synthesis of Tetracaine. The Journal of Organic Chemistry. PMID 31895983 DOI: 10.1021/Acs.Joc.9B03107  0.839
2019 Xu J, Liu RY, Yeung CS, Buchwald SL. Monophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Bases. Acs Catalysis. 9: 6461-6466. PMID 31929949 DOI: 10.1021/Acscatal.9B01913  0.489
2019 Ingoglia BT, Wagen CC, Buchwald SL. Biaryl Monophosphine Ligands in Palladium-Catalyzed C-N Coupling: An Updated User's Guide. Tetrahedron. 75: 4199-4211. PMID 31896889 DOI: 10.1016/J.Tet.2019.05.003  0.844
2019 Schuppe AW, Borrajo-Calleja GM, Buchwald SL. Enantioselective Olefin Hydrocyanation without Cyanide. Journal of the American Chemical Society. PMID 31687821 DOI: 10.1021/Jacs.9B10875  0.525
2019 Dennis JM, White NA, Liu RY, Buchwald SL. Pd-Catalyzed C-N Coupling Reactions Facilitated by Organic Bases: Mechanistic Investigation Leads to Enhanced Reactivity in the Arylation of Weakly Binding Amines. Acs Catalysis. 9: 3822-3830. PMID 31649828 DOI: 10.1021/Acscatal.9B00981  0.711
2019 Ichikawa S, Buchwald SL. Asymmetric Synthesis of γ-Amino Alcohols by Copper-Catalyzed Hydroamination. Organic Letters. 21: 8736-8739. PMID 31625750 DOI: 10.1021/Acs.Orglett.9B03356  0.358
2019 Li C, Shin K, Liu RY, Buchwald SL. Engaging Aldehydes in CuH-Catalyzed Reductive Coupling Reactions: Stereoselective Allylation with Unactivated 1,3-Diene Pronucleophiles. Angewandte Chemie (International Ed. in English). PMID 31552701 DOI: 10.1002/Anie.201911008  0.742
2019 Wagen CC, Ingoglia BT, Buchwald SL. Unexpected Formation of Hexasubstituted Arenes through a Twofold Palladium-Mediated Ligand Arylation. The Journal of Organic Chemistry. PMID 31512875 DOI: 10.1021/Acs.Joc.9B02091  0.818
2019 Bayeh-Romero L, Buchwald SL. Copper Hydride Catalyzed Enantioselective Synthesis of Axially Chiral 1,3-Disubstituted Allenes. Journal of the American Chemical Society. PMID 31423768 DOI: 10.1021/Jacs.9B07582  0.468
2019 Ichikawa S, Dai XJ, Buchwald SL. Regio- and Enantioselective Synthesis of 1,2-Diamine Derivatives by Copper-Catalyzed Hydroamination. Organic Letters. PMID 31099584 DOI: 10.1021/Acs.Orglett.9B01592  0.482
2019 Li C, Liu RY, Jesikiewicz LT, Yang Y, Liu P, Buchwald SL. CuH-Catalyzed Enantioselective Ketone Allylation with 1,3-Dienes: Scope, Mechanism, and Applications. Journal of the American Chemical Society. PMID 30817137 DOI: 10.1021/Jacs.9B01784  0.727
2019 Ye Y, Kim ST, Jeong J, Baik MH, Buchwald SL. CuH-Catalyzed Enantioselective Alkylation of Indole Derivatives with Ligand-Controlled Regiodivergence. Journal of the American Chemical Society. PMID 30696242 DOI: 10.1021/Jacs.8B11838  0.501
2019 Liu RY, Zhou Y, Yang Y, Buchwald SL. Enantioselective Allylation Using Allene, a Petroleum Cracking Byproduct. Journal of the American Chemical Society. PMID 30685967 DOI: 10.1021/Jacs.8B13907  0.497
2019 Uehling MR, King RP, Krska SW, Cernak T, Buchwald SL. Pharmaceutical diversification via palladium oxidative addition complexes. Science (New York, N.Y.). 363: 405-408. PMID 30679373 DOI: 10.1126/Science.Aac6153  0.703
2019 Dai XJ, Engl OD, León T, Buchwald SL. Catalytic Asymmetric Synthesis of α-Arylpyrrolidines and Benzo-fused Nitrogen Heterocycles. Angewandte Chemie (International Ed. in English). PMID 30659729 DOI: 10.1002/Anie.201814331  0.849
2019 Feng S, Hao H, Liu P, Buchwald SL. Diastereo- and Enantioselective CuH-Catalyzed Hydroamination of Strained Trisubstituted Alkenes Acs Catalysis. 10: 282-291. DOI: 10.1021/Acscatal.9B04871  0.447
2019 King RP, Buchwald SL. Synthesis of (MeCN)2Pd(CF3)OTs, a General Precursor to Palladium(II) Trifluoromethyl Complexes LPd(CF3)X Organometallics. 38: 3490-3493. DOI: 10.1021/Acs.Organomet.9B00516  0.455
2019 Baumgartner LM, Dennis JM, White NA, Buchwald SL, Jensen KF. Use of a Droplet Platform To Optimize Pd-Catalyzed C–N Coupling Reactions Promoted by Organic Bases Organic Process Research & Development. 23: 1594-1601. DOI: 10.1021/Acs.Oprd.9B00236  0.655
2019 Zhang C, Vinogradova EV, Spokoyny AM, Buchwald SL, Pentelute BL. Arylierungschemie für die Biokonjugation Angewandte Chemie. 131: 4860-4892. DOI: 10.1002/Ange.201806009  0.678
2019 Huang W, Einzinger M, Maurano A, Zhu T, Tiepelt J, Yu C, Chae HS, Van Voorhis T, Baldo MA, Buchwald SL. Large Increase in External Quantum Efficiency by Dihedral Angle Tuning in a Sky‐Blue Thermally Activated Delayed Fluorescence Emitter Advanced Optical Materials. 7: 1900476. DOI: 10.1002/Adom.201900476  0.597
2019 Wang H, Buchwald SL. Copper‐Catalyzed, Enantioselective Hydrofunctionalization of Alkenes Organic Reactions. 121-206. DOI: 10.1002/0471264180.Or100.03  0.489
2018 Pentelute B, Zhang C, Vinogradova E, Spokoyny A, Buchwald S. Arylation Chemistry for Bioconjugation. Angewandte Chemie (International Ed. in English). PMID 30399206 DOI: 10.1002/Anie.201806009  0.794
2018 Cohen DT, Zhang C, Fadzen CM, Mijalis AJ, Hie L, Johnson KD, Shriver Z, Plante O, Miller SJ, Buchwald SL, Pentelute BL. A chemoselective strategy for late-stage functionalization of complex small molecules with polypeptides and proteins. Nature Chemistry. PMID 30397320 DOI: 10.1038/S41557-018-0154-0  0.735
2018 Guo S, Yang JC, Buchwald SL. A Practical Electrophilic Nitrogen Source for the Synthesis of Chiral Primary Amines by Copper-Catalyzed Hydroamination. Journal of the American Chemical Society. PMID 30371077 DOI: 10.1021/Jacs.8B10564  0.468
2018 Liu RY, Buchwald SL. Copper-Catalyzed Enantioselective Hydroamination of Alkenes. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 95: 80-96. PMID 30287975 DOI: 10.15227/Orgsyn.095.0080  0.442
2018 Thomas AA, Speck K, Kevlishvili I, Lu Z, Liu P, Buchwald SL. Mechanistically Guided Design of Ligands that Significantly Improve the Efficiency of CuH-Catalyzed Hydroamination Reactions. Journal of the American Chemical Society. PMID 30244567 DOI: 10.1021/Jacs.8B09565  0.43
2018 Buchwald SL, Khan RKM, Zhao Y, Scully T. Catalytic Arylhydroxylation of Dehydroalanine in Continuous Flow for Simple Access to Unnatural Amino Acids. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30102444 DOI: 10.1002/Chem.201804094  0.41
2018 Ichikawa S, Zhu S, Buchwald SL. A Modified System for the Synthesis of Enantioenriched N-Arylamines through Copper-Catalyzed Hydroamination. Angewandte Chemie (International Ed. in English). PMID 29847002 DOI: 10.1002/Anie.201803026  0.756
2018 Shi SL, Wong ZL, Buchwald SL. Addendum: Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols. Nature. PMID 29795353 DOI: 10.1038/S41586-018-0112-4  0.691
2018 Tsai EY, Liu RY, Yang Y, Buchwald SL. Correction to "A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes". Journal of the American Chemical Society. PMID 29737849 DOI: 10.1021/Jacs.8B04366  0.836
2018 Zhou Y, Engl OD, Bandar JS, Chant ED, Buchwald SL. CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes. Angewandte Chemie (International Ed. in English). PMID 29660768 DOI: 10.1002/Anie.201802797  0.848
2018 Gribble MW, Guo S, Buchwald SL. Asymmetric Cu-Catalyzed 1,4-Dearomatization of Pyridines and Pyridazines without Preactivation of the Heterocycle or Nucleophile. Journal of the American Chemical Society. PMID 29609461 DOI: 10.1021/Jacs.8B02568  0.509
2018 Dennis JM, White NA, Liu RY, Buchwald SL. Breaking the Base Barrier: An Electron-Deficient Palladium Catalyst Enables the Use of a Common, Soluble Base in C-N Coupling. Journal of the American Chemical Society. PMID 29529363 DOI: 10.1021/Jacs.8B01696  0.699
2018 Zhang H, Ruiz-Castillo P, Buchwald SL. Palladium-Catalyzed C-O Cross-Coupling of Primary Alcohols. Organic Letters. PMID 29474078 DOI: 10.1021/Acs.Orglett.8B00325  0.437
2018 Kubota K, Dai P, Pentelute BL, Buchwald SL. Palladium Oxidative Addition Complexes for Peptide and Protein Crosslinking. Journal of the American Chemical Society. PMID 29406701 DOI: 10.1021/Jacs.8B00172  0.616
2018 Tsai E, Liu RY, Yang Y, Buchwald SL. A Regio- and Enantioselective CuH-Catalyzed Ketone Allylation with Terminal Allenes. Journal of the American Chemical Society. PMID 29376366 DOI: 10.1021/Jacs.7B12271  0.841
2018 Liu RY, Bae M, Buchwald SL. Mechanistic Insight Facilitates Discovery of a Mild and Efficient Copper-Catalyzed Dehydration of Primary Amides to Nitriles Using Hydrosilanes. Journal of the American Chemical Society. PMID 29353477 DOI: 10.1021/Jacs.8B00643  0.453
2018 Zhou Y, Bandar JS, Liu RY, Buchwald SL. CuH-Catalyzed Asymmetric Reduction of α,β-Unsaturated Carboxylic Acids to β-Chiral Aldehydes. Journal of the American Chemical Society. PMID 29283578 DOI: 10.1021/Jacs.7B12260  0.771
2018 Huang W, Einzinger M, Zhu T, Chae HS, Jeon S, Ihn S, Sim M, Kim S, Su M, Teverovskiy G, Wu T, Van Voorhis T, Swager TM, Baldo MA, Buchwald SL. Molecular Design of Deep Blue Thermally Activated Delayed Fluorescence Materials Employing a Homoconjugative Triptycene Scaffold and Dihedral Angle Tuning Chemistry of Materials. 30: 1462-1466. DOI: 10.1021/Acs.Chemmater.7B03490  0.753
2017 Rojas AJ, Zhang C, Vinogradova EV, Buchwald NH, Reilly J, Pentelute BL, Buchwald SL. Divergent unprotected peptide macrocyclisation by palladium-mediated cysteine arylation. Chemical Science. 8: 4257-4263. PMID 29081961 DOI: 10.1039/C6Sc05454D  0.781
2017 Lu G, Liu RY, Yang Y, Fang C, Lambrecht DS, Buchwald SL, Liu P. Ligand-Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins. Journal of the American Chemical Society. PMID 29064694 DOI: 10.1021/Jacs.7B07373  0.459
2017 Rojas AJ, Pentelute BL, Buchwald SL. Water-Soluble Palladium Reagents for Cysteine S-Arylation under Ambient Aqueous Conditions. Organic Letters. PMID 28777001 DOI: 10.1021/Acs.Orglett.7B01911  0.775
2017 Zhang H, Buchwald SL. Palladium-Catalyzed Negishi Coupling of α-CF3 Oxiranyl Zincate: Access to Chiral CF3-substituted Benzylic Tertiary Alcohols. Journal of the American Chemical Society. PMID 28753004 DOI: 10.1021/Jacs.7B06630  0.39
2017 Olsen EPK, Arrechea PL, Buchwald SL. Mechanistic Insight Leads to a Ligand That Facilitates the Pd-Catalyzed Formation of 2-(Hetero)Arylaminooxazoles and 4-(Hetero)Arylaminothiazoles. Angewandte Chemie (International Ed. in English). PMID 28605135 DOI: 10.1002/Anie.201705525  0.45
2017 Wang H, Yang JC, Buchwald SL. CuH-Catalyzed Regioselective Intramolecular Hydroamination for the Synthesis of Alkyl-Substituted Chiral Aziridines. Journal of the American Chemical Society. PMID 28594548 DOI: 10.1021/Jacs.7B04816  0.494
2017 Zhou Y, Bandar JS, Buchwald SL. Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates. Journal of the American Chemical Society. 139: 8126-8129. PMID 28565905 DOI: 10.1021/Jacs.7B04937  0.803
2017 Friis SD, Pirnot MT, Dupuis LN, Buchwald SL. A Dual Palladium and Copper Hydride Catalyzed Approach for Alkyl-Aryl Cross-Coupling of Aryl Halides and Olefins. Angewandte Chemie (International Ed. in English). 56: 7242-7246. PMID 28510287 DOI: 10.1002/Anie.201703400  0.844
2017 Zhao W, Lee HG, Buchwald SL, Hooker JM. Direct (11)CN-Labeling of Unprotected Peptides via Palladium-Mediated Sequential Cross-Coupling Reactions. Journal of the American Chemical Society. 139: 7152-7155. PMID 28502164 DOI: 10.1021/Jacs.7B02761  0.613
2017 Ingoglia BT, Buchwald SL. Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine Ligands. Organic Letters. 19: 2853-2856. PMID 28498667 DOI: 10.1021/Acs.Orglett.7B01082  0.824
2017 Lee HG, Lautrette G, Pentelute BL, Buchwald SL. Palladium-Mediated Arylation of Lysine in Unprotected Peptides. Angewandte Chemie (International Ed. in English). 56: 3177-3181. PMID 28206688 DOI: 10.1002/Anie.201611202  0.714
2017 Gribble MW, Pirnot MT, Bandar JS, Liu RY, Buchwald SL. Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles. Journal of the American Chemical Society. 139: 2192-2195. PMID 28117996 DOI: 10.1021/Jacs.6B13029  0.828
2016 Reizman BJ, Wang YM, Buchwald SL, Jensen KF. Suzuki-Miyaura cross-coupling optimization enabled by automated feedback. Reaction Chemistry & Engineering. 1: 658-666. PMID 27928513 DOI: 10.1039/C6Re00153J  0.536
2016 Ye Y, Takada T, Buchwald SL. Palladium-Catalyzed Fluorination of Cyclic Vinyl Triflates: Effect of TESCF3 as an Additive. Angewandte Chemie (International Ed. in English). 55: 15559-15563. PMID 27862732 DOI: 10.1002/Anie.201608927  0.528
2016 Liu RY, Yang Y, Buchwald SL. Regiodivergent and Diastereoselective CuH-Catalyzed Allylation of Imines with Terminal Allenes. Angewandte Chemie (International Ed. in English). 55: 14077-14080. PMID 27723269 DOI: 10.1002/Anie.201608446  0.51
2016 Ruiz-Castillo P, Buchwald SL. Applications of Palladium-Catalyzed C-N Cross-Coupling Reactions. Chemical Reviews. 116: 12564-12649. PMID 27689804 DOI: 10.1021/Acs.Chemrev.6B00512  0.52
2016 Sather AC, Buchwald SL. The Evolution of Pd(0)/Pd(II)-Catalyzed Aromatic Fluorination. Accounts of Chemical Research. 49: 2146-2157. PMID 27656765 DOI: 10.1021/Acs.Accounts.6B00247  0.789
2016 Arrechea PL, Buchwald SL. Biaryl Phosphine Based Pd(II) Amido Complexes: The Effect of Ligand Structure on Reductive Elimination. Journal of the American Chemical Society. 138: 12486-93. PMID 27562724 DOI: 10.1021/Jacs.6B05990  0.467
2016 Park NH, Senter TJ, Buchwald SL. Rapid Synthesis of Aryl Fluorides in Continuous Flow through the Balz-Schiemann Reaction. Angewandte Chemie (International Ed. in English). 55: 11907-11. PMID 27558308 DOI: 10.1002/Anie.201606601  0.841
2016 King SM, Buchwald SL. Development of a Method for the N-Arylation of Amino Acid Esters with Aryl Triflates. Organic Letters. 18: 4128-31. PMID 27498618 DOI: 10.1021/Acs.Orglett.6B02082  0.72
2016 Huang W, Buchwald SL. Palladium-Catalyzed N-Arylation of Iminodibenzyls and Iminostilbenes with Aryl- and Heteroaryl Halides. Chemistry (Weinheim An Der Bergstrasse, Germany). 22: 14186-9. PMID 27481439 DOI: 10.1002/Chem.201603449  0.741
2016 Roesner S, Buchwald SL. Continuous-Flow Synthesis of Biaryls by Negishi Cross-Coupling of Fluoro- and Trifluoromethyl-Substituted (Hetero)arenes. Angewandte Chemie (International Ed. in English). 55: 10463-7. PMID 27456275 DOI: 10.1002/Anie.201605584  0.77
2016 Yang Y, Perry IB, Buchwald SL. Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration. Journal of the American Chemical Society. 138: 9787-90. PMID 27454393 DOI: 10.1021/Jacs.6B06299  0.52
2016 Friis SD, Pirnot MT, Buchwald SL. Asymmetric Hydroarylation of Vinylarenes Using a Synergistic Combination of CuH and Pd Catalysis. Journal of the American Chemical Society. 138: 8372-5. PMID 27346525 DOI: 10.1021/Jacs.6B04566  0.827
2016 Corcoran EB, Pirnot MT, Lin S, Dreher SD, DiRocco DA, Davies IW, Buchwald SL, MacMillan DW. Aryl amination using ligand-free Ni(II) salts and photoredox catalysis. Science (New York, N.Y.). 353: 279-83. PMID 27338703 DOI: 10.1126/Science.Aag0209  0.815
2016 Yang Y, Perry IB, Lu G, Liu P, Buchwald SL. Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones. Science (New York, N.Y.). 353: 144-50. PMID 27284169 DOI: 10.1126/Science.Aaf7720  0.503
2016 Bandar JS, Ascic E, Buchwald SL. Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids. Journal of the American Chemical Society. 138: 5821-4. PMID 27121395 DOI: 10.1021/Jacs.6B03086  0.809
2016 Smith SM, Buchwald SL. Regioselective 2-Amination of Polychloropyrimidines. Organic Letters. 18: 2180-3. PMID 27082704 DOI: 10.1021/Acs.Orglett.6B00799  0.464
2016 Wang YM, Buchwald SL. Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes. Journal of the American Chemical Society. 138: 5024-7. PMID 27042864 DOI: 10.1021/Jacs.6B02527  0.547
2016 Shi SL, Wong ZL, Buchwald SL. Copper-catalysed enantioselective stereodivergent synthesis of amino alcohols. Nature. 532: 353-6. PMID 27018656 DOI: 10.1038/Nature17191  0.71
2016 Zhu S, Niljianskul N, Buchwald SL. A direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroamination. Nature Chemistry. 8: 144-50. PMID 26791897 DOI: 10.1038/Nchem.2418  0.823
2016 Yang JC, Niu D, Karsten BP, Lima F, Buchwald SL. Use of a "Catalytic" Cosolvent, N,N-Dimethyl Octanamide, Allows the Flow Synthesis of Imatinib with no Solvent Switch. Angewandte Chemie (International Ed. in English). 55: 2531-5. PMID 26756279 DOI: 10.1002/Anie.201509922  0.694
2016 Bhonde VR, O'Neill BT, Buchwald SL. An Improved System for the Aqueous Lipshutz-Negishi Cross-Coupling of Alkyl Halides with Aryl Electrophiles. Angewandte Chemie (International Ed. in English). 55: 1849-53. PMID 26676401 DOI: 10.1002/Anie.201509341  0.477
2016 Pirnot MT, Wang YM, Buchwald SL. Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes. Angewandte Chemie (International Ed. in English). 55: 48-57. PMID 26661678 DOI: 10.1002/Anie.201507594  0.832
2016 Liu RY, Yang Y, Buchwald SL. Regio- and Diastereoselective Copper-Catalyzed Allylation of Imines Synfacts. 12: 1258-1258. DOI: 10.1055/S-0036-1589695  0.452
2016 Yang Y, Perry IB, Lu G, Liu P, Buchwald SL. ChemInform Abstract: Copper-Catalyzed Asymmetric Addition of Olefin-Derived Nucleophiles to Ketones. Cheminform. 47. DOI: 10.1002/CHIN.201639024  0.38
2015 Milner PJ, Yang Y, Buchwald SL. In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides. Organometallics. 34: 4775-4780. PMID 27056379 DOI: 10.1021/Acs.Organomet.5B00631  0.736
2015 Bandar JS, Pirnot MT, Buchwald SL. Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins. Journal of the American Chemical Society. 137: 14812-8. PMID 26522837 DOI: 10.1021/Jacs.5B10219  0.84
2015 Vinogradova EV, Zhang C, Spokoyny AM, Pentelute BL, Buchwald SL. Organometallic palladium reagents for cysteine bioconjugation. Nature. 526: 687-91. PMID 26511579 DOI: 10.1038/Nature15739  0.829
2015 Sather AC, Lee HG, De La Rosa VY, Yang Y, Müller P, Buchwald SL. A Fluorinated Ligand Enables Room-Temperature and Regioselective Pd-Catalyzed Fluorination of Aryl Triflates and Bromides. Journal of the American Chemical Society. 137: 13433-8. PMID 26413908 DOI: 10.1021/Jacs.5B09308  0.816
2015 Sather AC, Lee HG, Colombe JR, Zhang A, Buchwald SL. Dosage delivery of sensitive reagents enables glove-box-free synthesis. Nature. 524: 208-11. PMID 26268191 DOI: 10.1038/Nature14654  0.812
2015 Wang YM, Bruno NC, Placeres ÁL, Zhu S, Buchwald SL. Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach. Journal of the American Chemical Society. 137: 10524-7. PMID 26256576 DOI: 10.1021/Jacs.5B07061  0.832
2015 Cohen DT, Zhang C, Pentelute BL, Buchwald SL. An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides. Journal of the American Chemical Society. 137: 9784-7. PMID 26225900 DOI: 10.1021/Jacs.5B05447  0.732
2015 Niu D, Buchwald SL. Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination. Journal of the American Chemical Society. 137: 9716-21. PMID 26144542 DOI: 10.1021/Jacs.5B05446  0.64
2015 Yang Y, Shi SL, Niu D, Liu P, Buchwald SL. ORGANIC CHEMISTRY. Catalytic asymmetric hydroamination of unactivated internal olefins to aliphatic amines. Science (New York, N.Y.). 349: 62-6. PMID 26138973 DOI: 10.1126/Science.Aab3753  0.795
2015 Zhu R, Buchwald SL. Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes. Journal of the American Chemical Society. 137: 8069-77. PMID 26070105 DOI: 10.1021/Jacs.5B04821  0.614
2015 Colombe JR, DeBergh JR, Buchwald SL. Synthesis of Heteroaryl Sulfonamides from Organozinc Reagents and 2,4,6-Trichlorophenyl Chlorosulfate. Organic Letters. 17: 3170-3. PMID 26065317 DOI: 10.1021/Acs.Orglett.5B01540  0.488
2015 Park NH, Vinogradova EV, Surry DS, Buchwald SL. Design of New Ligands for the Palladium-Catalyzed Arylation of α-Branched Secondary Amines. Angewandte Chemie (International Ed. in English). 54: 8259-62. PMID 26032920 DOI: 10.1002/Anie.201502626  0.687
2015 Ascic E, Buchwald SL. Highly diastereo- and enantioselective CuH-catalyzed synthesis of 2,3-disubstituted indolines. Journal of the American Chemical Society. 137: 4666-9. PMID 25826004 DOI: 10.1021/Jacs.5B02316  0.504
2015 Ruiz-Castillo P, Blackmond DG, Buchwald SL. Rational ligand design for the arylation of hindered primary amines guided by reaction progress kinetic analysis. Journal of the American Chemical Society. 137: 3085-92. PMID 25651374 DOI: 10.1021/Ja512903G  0.471
2015 Lee HG, Milner PJ, Placzek MS, Buchwald SL, Hooker JM. Virtually instantaneous, room-temperature [(11)C]-cyanation using biaryl phosphine Pd(0) complexes. Journal of the American Chemical Society. 137: 648-51. PMID 25565277 DOI: 10.1021/Ja512115S  0.779
2015 Cohen DT, Buchwald SL. Mild palladium-catalyzed cyanation of (hetero)aryl halides and triflates in aqueous media. Organic Letters. 17: 202-5. PMID 25555140 DOI: 10.1021/Ol5032359  0.673
2015 Shi SL, Buchwald SL. Copper-catalysed selective hydroamination reactions of alkynes. Nature Chemistry. 7: 38-44. PMID 25515888 DOI: 10.1038/Nchem.2131  0.763
2015 Shi SL, Buchwald SL. Palladium-catalyzed intramolecular C-H difluoroalkylation: synthesis of substituted 3,3-difluoro-2-oxindoles. Angewandte Chemie (International Ed. in English). 54: 1646-50. PMID 25476241 DOI: 10.1002/Anie.201410471  0.751
2015 Niljianskul N, Zhu S, Buchwald SL. Enantioselective synthesis of α-aminosilanes by copper-catalyzed hydroamination of vinylsilanes. Angewandte Chemie (International Ed. in English). 54: 1638-41. PMID 25475991 DOI: 10.1002/Anie.201410326  0.84
2015 Chen M, Ichikawa S, Buchwald SL. Rapid and efficient copper-catalyzed Finkelstein reaction of (hetero)aromatics under continuous-flow conditions. Angewandte Chemie (International Ed. in English). 54: 263-6. PMID 25378244 DOI: 10.1002/Anie.201409595  0.573
2015 Wang Y-, Bruno NC, Placeres ÁL, Zhu S, Buchwald SL. Copper-Catalyzed Enantioselective Synthesis of Carbo- and Heterocycles Synfacts. 11: 1167-1167. DOI: 10.1055/S-0035-1560692  0.837
2015 Cohen DT, Zhang C, Pentelute BL, Buchwald SL. An Umpolung Approach for the Chemoselective Arylation of Selenocysteine in Unprotected Peptides Journal of the American Chemical Society. 137: 9784-9787. DOI: 10.1021/jacs.5b05447  0.647
2015 Milner PJ, Yang Y, Buchwald SL. Correction to In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides Organometallics. 34: 5361-5361. DOI: 10.1021/Acs.Organomet.5B00881  0.401
2015 Milner PJ, Yang Y, Buchwald SL. In-Depth Assessment of the Palladium-Catalyzed Fluorination of Five-Membered Heteroaryl Bromides Organometallics. 34: 4775-4780. DOI: 10.1021/acs.organomet.5b00631  0.672
2015 Yang Y, Shi S, Niu D, Liu P, Buchwald SL. ChemInform Abstract: Catalytic Asymmetric Hydroamination of Unactivated Internal Olefins to Aliphatic Amines. Cheminform. 46: no-no. DOI: 10.1002/chin.201549026  0.602
2015 Shi S, Buchwald SL. ChemInform Abstract: Palladium-Catalyzed Intramolecular C-H Difluoroalkylation: Synthesis of Substituted 3,3-Difluoro-2-oxindoles. Cheminform. 46: no-no. DOI: 10.1002/chin.201524131  0.319
2015 Pirnot MT, Wang Y, Buchwald SL. Kupferhydrid-katalysierte Hydroaminierung von Alkenen und Alkinen Angewandte Chemie. 128: 48-57. DOI: 10.1002/Ange.201507594  0.751
2014 Lee HG, Milner PJ, Colvin MT, Andreas L, Buchwald SL. Structure and Reactivity of [(L•Pd)n•(1,5-cyclooctadiene)] (n=1-2) Complexes Bearing Biaryl Phosphine Ligands. Inorganica Chimica Acta. 422: 188-192. PMID 25346547 DOI: 10.1016/J.Ica.2014.06.008  0.75
2014 Zhu S, Buchwald SL. Enantioselective CuH-catalyzed anti-Markovnikov hydroamination of 1,1-disubstituted alkenes. Journal of the American Chemical Society. 136: 15913-6. PMID 25339089 DOI: 10.1021/Ja509786V  0.751
2014 Milner PJ, Kinzel T, Zhang Y, Buchwald SL. Studying regioisomer formation in the Pd-catalyzed fluorination of aryl triflates by deuterium labeling. Journal of the American Chemical Society. 136: 15757-66. PMID 25299957 DOI: 10.1021/Ja509144R  0.697
2014 Yang Y, Niedermann K, Han C, Buchwald SL. Highly selective palladium-catalyzed cross-coupling of secondary alkylzinc reagents with heteroaryl halides. Organic Letters. 16: 4638-41. PMID 25153332 DOI: 10.1021/Ol502230P  0.665
2014 Friis SD, Skrydstrup T, Buchwald SL. Mild Pd-catalyzed aminocarbonylation of (hetero)aryl bromides with a palladacycle precatalyst. Organic Letters. 16: 4296-9. PMID 25090373 DOI: 10.1021/Ol502014B  0.467
2014 Ernst JB, Tay NE, Jui NT, Buchwald SL. Regioselective synthesis of benzimidazolones via cascade C-N coupling of monosubstituted ureas. Organic Letters. 16: 3844-6. PMID 24971635 DOI: 10.1021/Ol501531Q  0.768
2014 Yang Y, Buchwald SL. Copper-catalyzed regioselective ortho C-H cyanation of vinylarenes. Angewandte Chemie (International Ed. in English). 53: 8677-81. PMID 24801708 DOI: 10.1002/Anie.201402449  0.46
2014 Cheung CW, Buchwald SL. Palladium-catalyzed hydroxylation of aryl and heteroaryl halides enabled by the use of a palladacycle precatalyst. The Journal of Organic Chemistry. 79: 5351-8. PMID 24762125 DOI: 10.1021/Jo500662S  0.557
2014 Bruno NC, Niljianskul N, Buchwald SL. N-substituted 2-aminobiphenylpalladium methanesulfonate precatalysts and their use in C-C and C-N cross-couplings. The Journal of Organic Chemistry. 79: 4161-6. PMID 24724692 DOI: 10.1021/Jo500355K  0.809
2014 Vinogradova EV, Müller P, Buchwald SL. Structural reevaluation of the electrophilic hypervalent iodine reagent for trifluoromethylthiolation supported by the crystalline sponge method for X-ray analysis. Angewandte Chemie (International Ed. in English). 53: 3125-8. PMID 24677728 DOI: 10.1002/Anie.201310897  0.548
2014 Zhu Y, Buchwald SL. Ligand-controlled asymmetric arylation of aliphatic α-amino anion equivalents. Journal of the American Chemical Society. 136: 4500-3. PMID 24621247 DOI: 10.1021/Ja501560X  0.577
2014 Lee HG, Milner PJ, Buchwald SL. Pd-catalyzed nucleophilic fluorination of aryl bromides. Journal of the American Chemical Society. 136: 3792-5. PMID 24559304 DOI: 10.1021/Ja5009739  0.801
2014 Su M, Hoshiya N, Buchwald SL. Palladium-catalyzed amination of unprotected five-membered heterocyclic bromides. Organic Letters. 16: 832-5. PMID 24417224 DOI: 10.1021/Ol4035947  0.675
2014 Park NH, Teverovskiy G, Buchwald SL. Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates. Organic Letters. 16: 220-3. PMID 24283652 DOI: 10.1021/Ol403209K  0.838
2014 Lautens M, Petrone DA, Zhu Y, Buchwald SL. Synthesis of Enantioenriched Amines via an Asymmetric Palladium-Catalyzed Arylation Synfacts. 10: 716-716. DOI: 10.1055/S-0034-1378290  0.555
2014 Shi S, Buchwald SL. Erratum: Copper-catalysed selective hydroamination reactions of alkynes Nature Chemistry. 7: 178-178. DOI: 10.1038/Nchem.2167  0.69
2014 Yang Y, Buchwald SL. Copper-Catalyzed RegioselectiveorthoCH Cyanation of Vinylarenes Angewandte Chemie. 126: 8677-8681. DOI: 10.1002/Ange.201402449  0.368
2013 Yang Y, Mustard TJ, Cheong PH, Buchwald SL. Palladium-catalyzed completely linear-selective Negishi cross-coupling of allylzinc halides with aryl and vinyl electrophiles. Angewandte Chemie (International Ed. in English). 52: 14098-102. PMID 24353232 DOI: 10.1002/Anie.201308585  0.696
2013 Tardiff DF, Jui NT, Khurana V, Tambe MA, Thompson ML, Chung CY, Kamadurai HB, Kim HT, Lancaster AK, Caldwell KA, Caldwell GA, Rochet JC, Buchwald SL, Lindquist S. Yeast reveal a "druggable" Rsp5/Nedd4 network that ameliorates α-synuclein toxicity in neurons. Science (New York, N.Y.). 342: 979-83. PMID 24158909 DOI: 10.1126/Science.1245321  0.665
2013 Chung CY, Khurana V, Auluck PK, Tardiff DF, Mazzulli JR, Soldner F, Baru V, Lou Y, Freyzon Y, Cho S, Mungenast AE, Muffat J, Mitalipova M, Pluth MD, Jui NT, ... ... Buchwald SL, et al. Identification and rescue of α-synuclein toxicity in Parkinson patient-derived neurons. Science (New York, N.Y.). 342: 983-7. PMID 24158904 DOI: 10.1126/Science.1245296  0.697
2013 Colombe JR, Bernhardt S, Stathakis C, Buchwald SL, Knochel P. Synthesis of solid 2-pyridylzinc reagents and their application in Negishi reactions. Organic Letters. 15: 5754-7. PMID 24156393 DOI: 10.1021/Ol402798Z  0.444
2013 Lee HG, Milner PJ, Buchwald SL. An improved catalyst system for the Pd-catalyzed fluorination of (hetero)aryl triflates. Organic Letters. 15: 5602-5. PMID 24138611 DOI: 10.1021/Ol402859K  0.789
2013 Zhu R, Buchwald SL. Enantioselective functionalization of radical intermediates in redox catalysis: copper-catalyzed asymmetric oxytrifluoromethylation of alkenes. Angewandte Chemie (International Ed. in English). 52: 12655-8. PMID 24133010 DOI: 10.1002/Anie.201307790  0.563
2013 Zhu S, Niljianskul N, Buchwald SL. Enantio- and regioselective CuH-catalyzed hydroamination of alkenes. Journal of the American Chemical Society. 135: 15746-9. PMID 24106781 DOI: 10.1021/Ja4092819  0.833
2013 Chen M, Buchwald SL. Rapid and efficient trifluoromethylation of aromatic and heteroaromatic compounds using potassium trifluoroacetate enabled by a flow system. Angewandte Chemie (International Ed. in English). 52: 11628-31. PMID 24038907 DOI: 10.1002/Anie.201306094  0.536
2013 Jui NT, Buchwald SL. Cascade palladium catalysis: a predictable and selectable regiocontrolled synthesis of N-arylbenzimidazoles. Angewandte Chemie (International Ed. in English). 52: 11624-7. PMID 24038854 DOI: 10.1002/Anie.201306007  0.747
2013 Oberli MA, Buchwald SL. Correction to A General Method for Suzuki–Miyaura Coupling Reactions Using Lithium Triisopropyl Borates Organic Letters. 15: 2892-2892. PMID 23956687 DOI: 10.1021/Ol401288Q  0.41
2013 Senecal TD, Shu W, Buchwald SL. A general, practical palladium-catalyzed cyanation of (hetero)aryl chlorides and bromides. Angewandte Chemie (International Ed. in English). 52: 10035-9. PMID 23934947 DOI: 10.1002/Anie.201304188  0.829
2013 Düfert MA, Billingsley KL, Buchwald SL. Suzuki-Miyaura cross-coupling of unprotected, nitrogen-rich heterocycles: substrate scope and mechanistic investigation. Journal of the American Chemical Society. 135: 12877-85. PMID 23909907 DOI: 10.1021/Ja4064469  0.788
2013 Cheung CW, Buchwald SL. Mild and general palladium-catalyzed synthesis of methyl aryl ethers enabled by the use of a palladacycle precatalyst. Organic Letters. 15: 3998-4001. PMID 23883393 DOI: 10.1021/Ol401796V  0.529
2013 DeBergh JR, Niljianskul N, Buchwald SL. Synthesis of aryl sulfonamides via palladium-catalyzed chlorosulfonylation of arylboronic acids. Journal of the American Chemical Society. 135: 10638-41. PMID 23837740 DOI: 10.1021/Ja405949A  0.838
2013 Yang Y, Buchwald SL. Ligand-controlled palladium-catalyzed regiodivergent Suzuki-Miyaura cross-coupling of allylboronates and aryl halides. Journal of the American Chemical Society. 135: 10642-5. PMID 23837686 DOI: 10.1021/Ja405950C  0.511
2013 Cheung CW, Surry DS, Buchwald SL. Mild and highly selective palladium-catalyzed monoarylation of ammonia enabled by the use of bulky biarylphosphine ligands and palladacycle precatalysts. Organic Letters. 15: 3734-7. PMID 23815096 DOI: 10.1021/Ol401612C  0.407
2013 Bruno NC, Buchwald SL. Synthesis and application of palladium precatalysts that accommodate extremely bulky di-tert-butylphosphino biaryl ligands. Organic Letters. 15: 2876-9. PMID 23675976 DOI: 10.1021/Ol401208T  0.838
2013 Bruno NC, Tudge MT, Buchwald SL. Design and Preparation of New Palladium Precatalysts for C-C and C-N Cross-Coupling Reactions. Chemical Science. 4: 916-920. PMID 23667737 DOI: 10.1039/C2Sc20903A  0.817
2013 Chen M, Buchwald SL. Continuous-flow synthesis of 1-substituted benzotriazoles from chloronitrobenzenes and amines in a C-N bond formation/hydrogenation/diazotization/cyclization sequence. Angewandte Chemie (International Ed. in English). 52: 4247-50. PMID 23450692 DOI: 10.1002/Anie.201300615  0.516
2013 Vinogradova EV, Park NH, Fors BP, Buchwald SL. Palladium-catalyzed synthesis of N-aryl carbamates. Organic Letters. 15: 1394-7. PMID 23441814 DOI: 10.1021/Ol400369N  0.797
2013 DeAngelis A, Wang DH, Buchwald SL. Mild and rapid Pd-catalyzed cross-coupling with hydrazine in continuous flow: application to the synthesis of functionalized heterocycles. Angewandte Chemie (International Ed. in English). 52: 3434-7. PMID 23404773 DOI: 10.1002/Anie.201208544  0.822
2013 Wang X, Buchwald SL. Synthesis of optically pure 2-trifluoromethyl lactic acid by asymmetric hydroformylation. The Journal of Organic Chemistry. 78: 3429-33. PMID 23394066 DOI: 10.1021/Jo400115R  0.405
2013 Yang Y, Oldenhuis NJ, Buchwald SL. Mild and general conditions for negishi cross-coupling enabled by the use of palladacycle precatalysts. Angewandte Chemie (International Ed. in English). 52: 615-9. PMID 23172689 DOI: 10.1002/Anie.201207750  0.487
2012 Spokoyny AM, Lewis CD, Teverovskiy G, Buchwald SL. Extremely Electron-Rich, Boron-Functionalized, Icosahedral Carborane-Based Phosphinoboranes. Organometallics. 31: 8478-8481. PMID 23667288 DOI: 10.1021/Om301116X  0.798
2012 Hoshiya N, Buchwald SL. An Improved Synthesis of BrettPhos and RockPhos-Type Biarylphosphine Ligands. Advanced Synthesis & Catalysis. 354: 2031-2037. PMID 23539491 DOI: 10.1002/Adsc.201200398  0.391
2012 Milner PJ, Maimone TJ, Su M, Chen J, Müller P, Buchwald SL. Investigating the dearomative rearrangement of biaryl phosphine-ligated Pd(II) complexes. Journal of the American Chemical Society. 134: 19922-34. PMID 23153301 DOI: 10.1021/Ja310351E  0.804
2012 Tsvelikhovsky D, Buchwald SL. Correction to Synthesis of Heterocycles via Pd-Ligand Controlled Cyclization of 2-Chloro-N-(2-vinyl)aniline: Preparation of Carbazoles, Indoles, Dibenzazepines, and Acridines. Journal of the American Chemical Society. 134: 16917. PMID 23009568 DOI: 10.1021/ja3066094  0.324
2012 Ueda S, Buchwald SL. Catalyst-controlled chemoselective arylation of 2-aminobenzimidazoles. Angewandte Chemie (International Ed. in English). 51: 10364-7. PMID 22969040 DOI: 10.1002/Anie.201204710  0.462
2012 Oberli MA, Buchwald SL. A general method for Suzuki-Miyaura coupling reactions using lithium triisopropyl borates. Organic Letters. 14: 4606-9. PMID 22894743 DOI: 10.1021/Ol302063G  0.44
2012 Cheung CW, Buchwald SL. Room temperature copper(II)-catalyzed oxidative cyclization of enamides to 2,5-disubstituted oxazoles via vinylic C-H functionalization. The Journal of Organic Chemistry. 77: 7526-37. PMID 22838632 DOI: 10.1021/Jo301332S  0.438
2012 Chernyak N, Buchwald SL. Continuous-flow synthesis of monoarylated acetaldehydes using aryldiazonium salts. Journal of the American Chemical Society. 134: 12466-9. PMID 22812501 DOI: 10.1021/Ja305660A  0.68
2012 Zhu R, Buchwald SL. Copper-catalyzed oxytrifluoromethylation of unactivated alkenes. Journal of the American Chemical Society. 134: 12462-5. PMID 22804336 DOI: 10.1021/Ja305840G  0.536
2012 McGowan MA, McAvoy CZ, Buchwald SL. Palladium-catalyzed N-monoarylation of amidines and a one-pot synthesis of quinazoline derivatives. Organic Letters. 14: 3800-3. PMID 22765354 DOI: 10.1021/Ol301700Y  0.855
2012 Vinogradova EV, Fors BP, Buchwald SL. Palladium-catalyzed cross-coupling of aryl chlorides and triflates with sodium cyanate: a practical synthesis of unsymmetrical ureas. Journal of the American Chemical Society. 134: 11132-5. PMID 22716197 DOI: 10.1021/Ja305212V  0.781
2012 Shu W, Buchwald SL. Enantioselective β-arylation of ketones enabled by lithiation/borylation/1,4-addition sequence under flow conditions. Angewandte Chemie (International Ed. in English). 51: 5355-8. PMID 22511537 DOI: 10.1002/Anie.201202221  0.32
2012 Su M, Buchwald SL. A bulky biaryl phosphine ligand allows for palladium-catalyzed amidation of five-membered heterocycles as electrophiles. Angewandte Chemie (International Ed. in English). 51: 4710-3. PMID 22473747 DOI: 10.1002/Anie.201201244  0.685
2012 McGowan MA, Henderson JL, Buchwald SL. Palladium-catalyzed N-arylation of 2-aminothiazoles. Organic Letters. 14: 1432-5. PMID 22394197 DOI: 10.1021/Ol300178J  0.51
2012 Parsons AT, Senecal TD, Buchwald SL. Iron(II)-catalyzed trifluoromethylation of potassium vinyltrifluoroborates. Angewandte Chemie (International Ed. in English). 51: 2947-50. PMID 22328162 DOI: 10.1002/Anie.201108267  0.813
2012 Ueda S, Ali S, Fors BP, Buchwald SL. Me3(OMe)tBuXPhos: a surrogate ligand for Me4tBuXPhos in palladium-catalyzed C-N and C-O bond-forming reactions. The Journal of Organic Chemistry. 77: 2543-7. PMID 22313416 DOI: 10.1021/Jo202537E  0.691
2012 Zhu R, Buchwald SL. Combined oxypalladation/C-H functionalization: palladium(II)-catalyzed intramolecular oxidative oxyarylation of hydroxyalkenes. Angewandte Chemie (International Ed. in English). 51: 1926-9. PMID 22237989 DOI: 10.1002/Anie.201108129  0.576
2012 Salvi L, Davis NR, Ali SZ, Buchwald SL. A new biarylphosphine ligand for the Pd-catalyzed synthesis of diaryl ethers under mild conditions. Organic Letters. 14: 170-3. PMID 22182186 DOI: 10.1021/Ol202955H  0.701
2012 Ueda S, Su M, Buchwald SL. Completely N1-selective palladium-catalyzed arylation of unsymmetric imidazoles: application to the synthesis of nilotinib. Journal of the American Chemical Society. 134: 700-6. PMID 22126442 DOI: 10.1021/Ja2102373  0.625
2012 Chernyak N, Buchwald SL. Correction to Continuous-Flow Synthesis of Monoarylated Acetaldehydes Using Aryldiazonium Salts Journal of the American Chemical Society. 134: 18147-18147. DOI: 10.1021/Ja309119Y  0.591
2011 Surry DS, Buchwald SL. Dialkylbiaryl Phosphines in Pd-Catalyzed Amination: A User's Guide. Chemical Science. 2: 27-50. PMID 22432049 DOI: 10.1039/C0Sc00331J  0.447
2011 Maiti D, Fors BP, Henderson JL, Nakamura Y, Buchwald SL. Palladium-Catalyzed Coupling of Functionalized Primary and Secondary Amines with Aryl and Heteroaryl Halides: Two Ligands Suffice in Most Cases. Chemical Science. 2: 57-68. PMID 22384311 DOI: 10.1039/C0Sc00330A  0.793
2011 Parsons AT, Buchwald SL. Organic chemistry: A radical approach to diversity. Nature. 480: 184-5. PMID 22158236 DOI: 10.1038/480184A  0.677
2011 Cho EJ, Buchwald SL. The palladium-catalyzed trifluoromethylation of vinyl sulfonates. Organic Letters. 13: 6552-5. PMID 22111687 DOI: 10.1021/Ol202885W  0.64
2011 Wang X, Buchwald SL. Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins. Journal of the American Chemical Society. 133: 19080-3. PMID 22035143 DOI: 10.1021/Ja2092689  0.482
2011 Maimone TJ, Milner PJ, Kinzel T, Zhang Y, Takase MK, Buchwald SL. Evidence for in situ catalyst modification during the Pd-catalyzed conversion of aryl triflates to aryl fluorides. Journal of the American Chemical Society. 133: 18106-9. PMID 21999801 DOI: 10.1021/Ja208461K  0.808
2011 Shu W, Pellegatti L, Oberli MA, Buchwald SL. Continuous-flow synthesis of biaryls enabled by multistep solid-handling in a lithiation/borylation/Suzuki-Miyaura cross-coupling sequence. Angewandte Chemie (International Ed. in English). 50: 10665-9. PMID 21932237 DOI: 10.1002/Anie.201105223  0.342
2011 Parsons AT, Buchwald SL. Copper-catalyzed trifluoromethylation of unactivated olefins. Angewandte Chemie (International Ed. in English). 50: 9120-3. PMID 21919144 DOI: 10.1002/Anie.201104053  0.687
2011 Wu X, Fors BP, Buchwald SL. A single phosphine ligand allows palladium-catalyzed intermolecular C-O bond formation with secondary and primary alcohols. Angewandte Chemie (International Ed. in English). 50: 9943-7. PMID 21913292 DOI: 10.1002/Anie.201104361  0.682
2011 Pan J, Wang X, Zhang Y, Buchwald SL. An improved palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides. Organic Letters. 13: 4974-6. PMID 21863838 DOI: 10.1021/Ol202098H  0.54
2011 Ueda S, Su M, Buchwald SL. Highly N2-selective palladium-catalyzed arylation of 1,2,3-triazoles. Angewandte Chemie (International Ed. in English). 50: 8944-7. PMID 21853510 DOI: 10.1002/Anie.201103882  0.624
2011 Tsvelikhovsky D, Buchwald SL. Concise palladium-catalyzed synthesis of dibenzodiazepines and structural analogues. Journal of the American Chemical Society. 133: 14228-31. PMID 21838278 DOI: 10.1021/Ja206229Y  0.461
2011 Noël T, Maimone TJ, Buchwald SL. Accelerating palladium-catalyzed C-F bond formation: use of a microflow packed-bed reactor. Angewandte Chemie (International Ed. in English). 50: 8900-3. PMID 21837710 DOI: 10.1002/Anie.201104652  0.774
2011 Noël T, Buchwald SL. Cross-coupling in flow. Chemical Society Reviews. 40: 5010-29. PMID 21826351 DOI: 10.1039/C1Cs15075H  0.559
2011 Pan J, Su M, Buchwald SL. Palladium(0)-catalyzed intermolecular amination of unactivated C(sp³)-H bonds. Angewandte Chemie (International Ed. in English). 50: 8647-51. PMID 21812078 DOI: 10.1002/Anie.201102880  0.546
2011 Teverovskiy G, Surry DS, Buchwald SL. Pd-catalyzed synthesis of Ar-SCF3 compounds under mild conditions. Angewandte Chemie (International Ed. in English). 50: 7312-4. PMID 21692157 DOI: 10.1002/Ange.201102543  0.814
2011 Li P, Buchwald SL. Continuous-flow synthesis of 3,3-disubstituted oxindoles by a palladium-catalyzed α-arylation/alkylation sequence. Angewandte Chemie (International Ed. in English). 50: 6396-400. PMID 21656623 DOI: 10.1002/Anie.201102401  0.403
2011 Rousseaux S, García-Fortanet J, Del Aguila Sanchez MA, Buchwald SL. Palladium(0)-catalyzed arylative dearomatization of phenols. Journal of the American Chemical Society. 133: 9282-5. PMID 21612204 DOI: 10.1021/Ja203644Q  0.481
2011 Breitler S, Oldenhuis NJ, Fors BP, Buchwald SL. Synthesis of unsymmetrical diarylureas via Pd-catalyzed C-N cross-coupling reactions. Organic Letters. 13: 3262-5. PMID 21604792 DOI: 10.1021/Ol201210T  0.728
2011 Noël T, Kuhn S, Musacchio AJ, Jensen KF, Buchwald SL. Suzuki-Miyaura cross-coupling reactions in flow: multistep synthesis enabled by a microfluidic extraction. Angewandte Chemie (International Ed. in English). 50: 5943-6. PMID 21591040 DOI: 10.1002/Anie.201101480  0.591
2011 Senecal TD, Parsons AT, Buchwald SL. Room temperature aryl trifluoromethylation via copper-mediated oxidative cross-coupling. The Journal of Organic Chemistry. 76: 1174-6. PMID 21235259 DOI: 10.1021/Jo1023377  0.821
2011 Tsvelikhovsky D, Buchwald SL. Concise Palladium-Catalyzed Synthesis of Dibenzodiazepines Synfacts. 2011: 1163-1163. DOI: 10.1055/S-0031-1289284  0.515
2011 Teverovskiy G, Surry DS, Buchwald SL. Pd-Catalyzed Synthesis of (Het)Ar-SCF3 Compounds Synfacts. 2011: 1119-1119. DOI: 10.1055/S-0030-1261079  0.81
2011 Buchwald S, Fors B. A Multiligand-Based Palladium Catalyst for C-N Cross-Coupling Reactions Synfacts. 2011: 0199-0199. DOI: 10.1055/S-0030-1259242  0.703
2011 Shu W, Buchwald SL. Use of precatalysts greatly facilitate palladium-catalyzed alkynylations in batch and continuous-flow conditions Chemical Science. 2: 2321-2325. DOI: 10.1039/C1Sc00409C  0.42
2011 Noël T, Naber JR, Hartman RL, Mcmullen JP, Jensen KF, Buchwald SL. Palladium-catalyzed amination reactions in flow: Overcoming the challenges of clogging via acoustic irradiation Chemical Science. 2: 287-290. DOI: 10.1039/C0Sc00524J  0.827
2011 Noel T, Buchwald SL. ChemInform Abstract: Cross-Coupling in Flow Cheminform. 43: no-no. DOI: 10.1002/chin.201204225  0.454
2010 Naber JR, Fors BP, Wu X, Gunn J, Buchwald SL. STILLE CROSS-COUPLING REACTIONS OF ARYL MESYLATES AND TOSYLATES USING A BIARYLPHOSPHINE BASED CATALYST SYSTEM. Heterocycles. 80: 1215-1226. PMID 23596345 DOI: 10.3987/Com-09-S(S)105  0.854
2010 Surry DS, Buchwald SL. Diamine Ligands in Copper-Catalyzed Reactions. Chemical Science. 1: 13-31. PMID 22384310 DOI: 10.1039/C0Sc00107D  0.477
2010 Naber JR, Buchwald SL. Packed-bed reactors for continuous-flow C-N cross-coupling. Angewandte Chemie (International Ed. in English). 49: 9469-74. PMID 21038337 DOI: 10.1002/Anie.201004425  0.749
2010 Fors BP, Buchwald SL. A multiligand based Pd catalyst for C-N cross-coupling reactions. Journal of the American Chemical Society. 132: 15914-7. PMID 20979367 DOI: 10.1021/Ja108074T  0.72
2010 Henderson JL, Buchwald SL. Efficient Pd-catalyzed amination reactions for heterocycle functionalization. Organic Letters. 12: 4442-5. PMID 20860403 DOI: 10.1021/Ol101929V  0.458
2010 Henderson JL, McDermott SM, Buchwald SL. Palladium-catalyzed amination of unprotected halo-7-azaindoles. Organic Letters. 12: 4438-41. PMID 20860393 DOI: 10.1055/S-0030-1259416  0.523
2010 Tsvelikhovsky D, Buchwald SL. Synthesis of heterocycles via Pd-ligand controlled cyclization of 2-chloro-N-(2-vinyl)aniline: preparation of carbazoles, indoles, dibenzazepines, and acridines. Journal of the American Chemical Society. 132: 14048-51. PMID 20858012 DOI: 10.1021/Ja107511G  0.461
2010 Kinzel T, Zhang Y, Buchwald SL. A new palladium precatalyst allows for the fast Suzuki-Miyaura coupling reactions of unstable polyfluorophenyl and 2-heteroaryl boronic acids. Journal of the American Chemical Society. 132: 14073-5. PMID 20858009 DOI: 10.1021/Ja1073799  0.458
2010 Shen X, Hyde AM, Buchwald SL. Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides. Journal of the American Chemical Society. 132: 14076-8. PMID 20857936 DOI: 10.1021/Ja107481A  0.82
2010 Shen X, Jones GO, Watson DA, Bhayana B, Buchwald SL. Enantioselective synthesis of axially chiral biaryls by the Pd-catalyzed Suzuki-Miyaura reaction: substrate scope and quantum mechanical investigations. Journal of the American Chemical Society. 132: 11278-87. PMID 20698695 DOI: 10.1021/Ja104297G  0.798
2010 Maimone TJ, Buchwald SL. Pd-catalyzed O-arylation of ethyl acetohydroximate: synthesis of O-arylhydroxylamines and substituted benzofurans. Journal of the American Chemical Society. 132: 9990-1. PMID 20604520 DOI: 10.1021/Ja1044874  0.706
2010 Cho EJ, Senecal TD, Kinzel T, Zhang Y, Watson DA, Buchwald SL. The palladium-catalyzed trifluoromethylation of aryl chlorides. Science (New York, N.Y.). 328: 1679-81. PMID 20576888 DOI: 10.1126/Science.1190524  0.839
2010 Dooleweerdt K, Fors BP, Buchwald SL. Pd-catalyzed cross-coupling reactions of amides and aryl mesylates. Organic Letters. 12: 2350-3. PMID 20420379 DOI: 10.1021/Ol100720X  0.745
2010 Jones GO, Liu P, Houk KN, Buchwald SL. Computational explorations of mechanisms and ligand-directed selectivities of copper-catalyzed Ullmann-type reactions. Journal of the American Chemical Society. 132: 6205-13. PMID 20387898 DOI: 10.1021/Ja100739H  0.742
2010 Maiti D, Buchwald SL. Cu-catalyzed arylation of phenols: synthesis of sterically hindered and heteroaryl diaryl ethers. The Journal of Organic Chemistry. 75: 1791-4. PMID 20141182 DOI: 10.1021/Jo9026935  0.599
2010 Hartman RL, Naber JR, Buchwald SL, Jensen KF. Multistep microchemical synthesis enabled by microfluidic distillation. Angewandte Chemie (International Ed. in English). 49: 899-903. PMID 20025004 DOI: 10.1002/Anie.200904634  0.783
2010 Shen X, Buchwald SL. Rhodium-catalyzed asymmetric intramolecular hydroamination of unactivated alkenes. Angewandte Chemie (International Ed. in English). 49: 564-7. PMID 20014268 DOI: 10.1002/Anie.200905402  0.521
2010 Buchwald S, Maimone T. O-Arylhydroxylamines and Benzofurans via O-Arylation of Ethyl Acetohydroximate Synfacts. 2010: 1284-1284. DOI: 10.1055/s-0030-1258705  0.574
2010 Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Palladium-Catalyzed Conversion of Aryl Triflates to ArylFluorides Synfacts. 2010: 85-85. DOI: 10.1055/S-0029-1218434  0.863
2010 Hartman RL, Naber JR, Zaborenko N, Buchwald SL, Jensen KF. Overcoming the challenges of solid bridging and constriction during Pd-catalyzed C-N bond formation in microreactors Organic Process Research and Development. 14: 1347-1357. DOI: 10.1021/Op100154D  0.796
2010 Hamada T, Buchwald SL. ChemInform Abstract: P-Chirogenic Binaphthyl-Substituted Monophosphines: Synthesis and Use in Enolate Vinylation/Arylation Reactions. Cheminform. 33: no-no. DOI: 10.1002/chin.200236026  0.373
2010 Sturla SJ, Buchwald SL. ChemInform Abstract: Monocyclopentadienyltitanium Aryloxide Complexes: Preparation, Characterization, and Application in Cyclization Reactions. Cheminform. 33: no-no. DOI: 10.1002/chin.200229058  0.591
2010 Zhang X, Harris MC, Sadighi JP, Buchwald SL. ChemInform Abstract: The Use of Palladium Chloride as a Precatalyst for the Amination of Aryl Bromides. Cheminform. 33: no-no. DOI: 10.1002/chin.200227065  0.802
2010 Moradi WA, Buchwald SL. ChemInform Abstract: Palladium-Catalyzed α-Arylation of Esters. Cheminform. 32: no-no. DOI: 10.1002/chin.200151107  0.306
2010 Moritani Y, Appella DH, Jurkauskas V, Buchwald SL. ChemInform Abstract: Synthesis of β-Alkyl Cyclopentanones in High Enantiomeric Excess via Copper-Catalyzed Asymmetric Conjugate Reduction. Cheminform. 31: no-no. DOI: 10.1002/chin.200046030  0.827
2010 Fox JM, Huang X, Chieffi A, Buchwald SL. ChemInform Abstract: Highly Active and Selective Catalysts for the Formation of α-Aryl Ketones. Cheminform. 31: no-no. DOI: 10.1002/chin.200021064  0.56
2010 Buchwald SL, Hicks FA. ChemInform Abstract: Pauson-Khand-Type Reactions Cheminform. 31: no-no. DOI: 10.1002/chin.200018244  0.72
2010 Wagaw S, Yang BH, Buchwald SL. ChemInform Abstract: A Palladium-Catalyzed Method for the Preparation of Indoles via the Fischer Indole Synthesis. Cheminform. 31: no-no. DOI: 10.1002/chin.200012126  0.393
2010 Wolfe JP, Singer RA, Yang BH, Buchwald SL. ChemInform Abstract: Highly Active Palladium Catalysts for Suzuki Coupling Reactions. Cheminform. 31: no-no. DOI: 10.1002/chin.200006062  0.619
2010 Appella DH, Moritani Y, Shintani R, Ferreira EM, Buchwald SL. ChemInform Abstract: Asymmetric Conjugate Reduction of α,β-Unsaturated Esters Using a Chiral Phosphine-Copper Catalyst. Cheminform. 31: no-no. DOI: 10.1002/chin.200004030  0.737
2010 Hicks FA, Buchwald SL. ChemInform Abstract: An Intramolecular Titanium-Catalyzed Asymmetric Pauson-Khand Type Reaction. Cheminform. 30: no-no. DOI: 10.1002/chin.199951028  0.757
2010 Yun J, Buchwald SL. ChemInform Abstract: Titanocene-Catalyzed Asymmetric Ketone Hydrosilylation: The Effect of Catalyst Activation Protocol and Additives on the Reaction Rate and Enantioselectivity. Cheminform. 30: no-no. DOI: 10.1002/chin.199942027  0.581
2010 Hicks FA, Kablaoui NM, Buchwald SL. ChemInform Abstract: Scope of the Intramolecular Titanocene-Catalyzed Pauson-Khand Type Reaction. Cheminform. 30: no-no. DOI: 10.1002/chin.199941033  0.832
2010 Aranyos A, Old DW, Kiyomori A, Wolfe JP, Sadighi JP, Buchwald SL. ChemInform Abstract: Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers. Cheminform. 30: no-no. DOI: 10.1002/chin.199936105  0.766
2010 Troutman MV, Appella DH, Buchwald SL. ChemInform Abstract: Asymmetric Hydrogenation of Unfunctionalized Tetrasubstituted Olefins with a Cationic Zirconocene Catalyst. Cheminform. 30: no-no. DOI: 10.1002/chin.199936066  0.618
2010 Yang BH, Buchwald SL. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Halides and Sulfonates Cheminform. 30: no-no. DOI: 10.1002/chin.199931326  0.472
2010 Sturla SJ, Kablaoui NM, Buchwald SL. ChemInform Abstract: A Titanocene-Catalyzed Intramolecular Ene Reaction: Cycloisomerization of Enynes and Dienynes. Cheminform. 30: no-no. DOI: 10.1002/chin.199929044  0.82
2010 Kiyomori A, Marcoux J, Buchwald SL. ChemInform Abstract: An Efficient Copper-Catalyzed Coupling of Aryl Halides with Imidazoles. Cheminform. 30: no-no. DOI: 10.1002/chin.199927145  0.343
2010 Singer RA, Buchwald SL. ChemInform Abstract: Preparation of 2-Amino-2′-hydroxy-1,1′-binaphthyl and N-Arylated 2-Amino-1,1′-binaphthyl Derivatives via Palladium-Catalyzed Amination. Cheminform. 30: no-no. DOI: 10.1002/chin.199921103  0.317
2010 Wolfe JP, Wagaw S, Marcoux J, Buchwald SL. ChemInform Abstract: Rational Development of Practical Catalysts for Aromatic Carbon-Nitrogen Bond Formation Cheminform. 30: no-no. DOI: 10.1002/chin.199912328  0.526
2010 OLD DW, WOLFE JP, BUCHWALD SL. ChemInform Abstract: A Highly Active Catalyst for Palladium-Catalyzed Cross-Coupling Reactions: Room-Temperature Suzuki Couplings and Amination of Unactivated Aryl Chlorides. Cheminform. 30: no-no. DOI: 10.1002/chin.199905063  0.628
2010 WAGAW S, YANG BH, BUCHWALD SL. ChemInform Abstract: A Palladium-Catalyzed Strategy for the Preparation of Indoles: A Novel Entry into the Fischer Indole Synthesis. Cheminform. 29: no-no. DOI: 10.1002/chin.199846131  0.388
2010 SADIGHI JP, HARRIS MC, BUCHWALD SL. ChemInform Abstract: A Highly Active Palladium Catalyst System for the Arylation of Anilines. Cheminform. 29: no-no. DOI: 10.1002/chin.199841080  0.782
2010 SADIGHI JP, SINGER RA, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed Synthesis of Monodisperse, Controlled-Length, and Functionalized Oligoanilines. Cheminform. 29: no-no. DOI: 10.1002/chin.199837092  0.699
2010 HANSEN MC, VERDAGUER X, BUCHWALD SL. ChemInform Abstract: Convenient Two-Step Conversion of Lactones into Cyclic Ethers. Cheminform. 29: no-no. DOI: 10.1002/chin.199831097  0.311
2010 VERDAGUER X, LANGE UEW, BUCHWALD SL. ChemInform Abstract: Amine Additives Greatly Expand the Scope of Asymmetric Hydrosilylation of Imines. Cheminform. 29: no-no. DOI: 10.1002/chin.199831035  0.378
2010 AAHMAN J, WOLFE JP, TROUTMAN MV, PALUCKI M, BUCHWALD SL. ChemInform Abstract: Asymmetric Arylation of Ketone Enolates. Cheminform. 29: no-no. DOI: 10.1002/chin.199825052  0.638
2010 SINGER RA, SADIGHI JP, BUCHWALD SL. ChemInform Abstract: A General Synthesis of End-Functionalized Oligoanilines via Palladium-Catalyzed Amination. Cheminform. 29: no-no. DOI: 10.1002/chin.199817086  0.729
2010 PALUCKI M, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed α-Arylation of Ketones. Cheminform. 29: no-no. DOI: 10.1002/chin.199809087  0.317
2010 MARCOUX J, DOYE S, BUCHWALD SL. ChemInform Abstract: A General Copper-Catalyzed Synthesis of Diaryl Ethers. Cheminform. 29: no-no. DOI: 10.1002/chin.199807122  0.636
2010 WOLFE JP, BUCHWALD SL. ChemInform Abstract: Room Temperature Catalytic Amination of Aryl Iodides. Cheminform. 29: no-no. DOI: 10.1002/chin.199803057  0.549
2010 WOLFE JP, AAHMAN J, SADIGHI JP, SINGER RA, BUCHWALD SL. ChemInform Abstract: An Ammonia Equivalent for the Palladium-Catalyzed Amination of Aryl Halides and Triflates. Cheminform. 28: no-no. DOI: 10.1002/chin.199749102  0.817
2010 WOLFE JP, BUCHWALD SL. ChemInform Abstract: Improved Functional Group Compatibility in the Palladium-Catalyzed Amination of Aryl Bromides. Cheminform. 28: no-no. DOI: 10.1002/chin.199749100  0.596
2010 WOLFE JP, BUCHWALD SL. ChemInform Abstract: Nickel-Catalyzed Amination of Aryl Chlorides. Cheminform. 28: no-no. DOI: 10.1002/chin.199742064  0.651
2010 KABLAOUI NM, HICKS FA, BUCHWALD SL. ChemInform Abstract: Titanocene-Catalyzed Cyclocarbonylation of o-Allyl Aryl Ketones to . gamma.-Butyrolactones. Cheminform. 28: no-no. DOI: 10.1002/chin.199736122  0.813
2010 MARCOUX J, WAGAW S, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Bromides: Use of Phosphinoether Ligands for the Efficient Coupling of Acyclic Secondary Amines. Cheminform. 28: no-no. DOI: 10.1002/chin.199733098  0.39
2010 PALUCKI M, WOLFE JP, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed Intermolecular Carbon-Oxygen Bond Formation: A New Synthesis of Aryl Ethers. Cheminform. 28: no-no. DOI: 10.1002/chin.199732017  0.56
2010 GURAM AS, RENNELS RA, BUCHWALD SL, BARTA NS, PEARSON WH. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Halides with Amines Cheminform. 28: no-no. DOI: 10.1002/chin.199714314  0.473
2010 HICKS FA, BUCHWALD SL. ChemInform Abstract: Highly Enantioselective Catalytic Pauson-Khand Type Formation of Bicyclic Cyclopentenones. Cheminform. 28: no-no. DOI: 10.1002/chin.199711041  0.736
2010 PALUCKI M, WOLFE JP, BUCHWALD SL. ChemInform Abstract: Synthesis of Oxygen Heterocycles via a Palladium-Catalyzed C-O Bond- Forming Reaction. Cheminform. 28: no-no. DOI: 10.1002/chin.199707150  0.576
2010 HICKS FA, KABLAOUI NM, BUCHWALD SL. ChemInform Abstract: Titanocene-Catalyzed Cyclocarbonylation of Enynes to Cyclopentenones. Cheminform. 28: no-no. DOI: 10.1002/chin.199703130  0.839
2010 CHIN B, BUCHWALD SL. ChemInform Abstract: An Improved Procedure for the Resolution of (rac)-Ethylenebis( tetrahydroindenyl)titanium Derivatives. Cheminform. 28: no-no. DOI: 10.1002/chin.199702152  0.499
2010 WOLFE JP, WAGAW S, BUCHWALD SL. ChemInform Abstract: Improved Catalyst System for Aromatic Carbon-Nitrogen Bond Formation: The Possible Involvement of Bis(Phosphine) Palladium Complexes as Key Intermediates. Cheminform. 27: no-no. DOI: 10.1002/chin.199645086  0.577
2010 VERDAGUER X, LANGE UEW, REDING MT, BUCHWALD SL. ChemInform Abstract: Highly Enantioselective Imine Hydrosilylation Using (S,S)-Ethylenebis(. eta.5-tetrahydroindenyl)titanium Difluoride. Cheminform. 27: no-no. DOI: 10.1002/chin.199644069  0.66
2010 KABLAOUI NM, HICKS FA, BUCHWALD SL. ChemInform Abstract: Diastereoselective Synthesis of γ-Butyrolactones from Enones Mediated or Catalyzed by a Titanocene Complex. Cheminform. 27: no-no. DOI: 10.1002/chin.199639139  0.833
2010 WOLFE JP, RENNELS RA, BUCHWALD SL. ChemInform Abstract: Intramolecular Palladium-Catalyzed Aryl Amination and Aryl Amidation. Cheminform. 27: no-no. DOI: 10.1002/chin.199638071  0.672
2010 KABLAOUI NM, BUCHWALD SL. ChemInform Abstract: Development of a Method for the Reductive Cyclization of Enones by a Titanium Catalyst. Cheminform. 27: no-no. DOI: 10.1002/chin.199630070  0.752
2010 WOLFE JP, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Iodides. Cheminform. 27: no-no. DOI: 10.1002/chin.199627112  0.674
2010 VERDAGUER X, BERK SC, BUCHWALD SL. ChemInform Abstract: Catalytic Method for the Reduction of Lactones to Lactols. Cheminform. 27: no-no. DOI: 10.1002/chin.199616072  0.705
2010 REDING MT, BUCHWALD SL. ChemInform Abstract: An Inexpensive Air-Stable Titanium-Based System for the Conversion of Esters to Primary Alcohols. Cheminform. 27: no-no. DOI: 10.1002/chin.199615070  0.65
2010 JOHNSON JR, CUNY GD, BUCHWALD SL. ChemInform Abstract: Rhodium-Catalyzed Hydroformylation of Internal Alkynes to α,. beta.-Unsaturated Aldehydes. Cheminform. 26: no-no. DOI: 10.1002/chin.199548084  0.542
2010 KABLAOUI NM, BUCHWALD SL. ChemInform Abstract: Reductive Cyclization of Enones by a Titanium Catalyst. Cheminform. 26: no-no. DOI: 10.1002/chin.199543069  0.752
2010 CUNY GD, BUCHWALD SL. ChemInform Abstract: Regioselective Olefin Hydroformylation as a Route to Indolizidine and Pyrrolizidine Alkaloids. Cheminform. 26: no-no. DOI: 10.1002/chin.199540237  0.592
2010 GURAM AS, RENNELS RA, BUCHWALD SL. ChemInform Abstract: A Simple Catalytic Method for the Conversion of Aryl Bromides to Arylamines. Cheminform. 26: no-no. DOI: 10.1002/chin.199540100  0.352
2010 DE REGE FMG, BUCHWALD SL. ChemInform Abstract: The Regioselective Synthesis of Halophenols. Cheminform. 26: no-no. DOI: 10.1002/chin.199535113  0.316
2010 TIDWELL JH, PEAT AJ, BUCHWALD SL. ChemInform Abstract: Synthesis and Reactions of 3-(Bromomethyl)-1-carbethoxy-4-iodoindole: The Preparation of 3,4-Differentially Substituted Indoles. Cheminform. 26: no-no. DOI: 10.1002/chin.199523116  0.672
2010 TIDWELL JH, BUCHWALD SL. ChemInform Abstract: Synthesis of Polysubstituted Indoles and Indolines by Means of Zirconocene-Stabilized Benzyne Complexes. Cheminform. 26: no-no. DOI: 10.1002/chin.199522123  0.604
2010 CARTER MB, SCHIOTT B, GUTIERREZ A, BUCHWALD SL. ChemInform Abstract: Enantioselective Hydrosilylation of Ketones with a Chiral Titanocene Catalyst. Cheminform. 26: no-no. DOI: 10.1002/chin.199521039  0.611
2010 HSU DP, WARNER BP, FISHER RA, DAVIS WM, BUCHWALD SL. ChemInform Abstract: Synthesis and Structure of a Novel Bis(stibole). Cheminform. 26: no-no. DOI: 10.1002/chin.199520162  0.685
2010 GURAM AS, BUCHWALD SL. ChemInform Abstract: Palladium-Catalyzed Aromatic Aminations with in situ Generated Aminostannanes. Cheminform. 26: no-no. DOI: 10.1002/chin.199515092  0.41
2010 WARNER BP, BUCHWALD SL. ChemInform Abstract: A Catalytic Method for the Conversion of Silanes to Stannanes. Cheminform. 26: no-no. DOI: 10.1002/chin.199514202  0.689
2010 BARR KJ, BERK SC, BUCHWALD SL. ChemInform Abstract: Titanocene-Catalyzed Reduction of Esters Using Polymethylhydrosiloxane as the Stoichiometric Reductant. Cheminform. 26: no-no. DOI: 10.1002/chin.199505085  0.815
2010 WILLOUGHBY CA, BUCHWALD SL. ChemInform Abstract: Synthesis of Highly Enantiomerically Enriched Cyclic Amines by the Catalytic Asymmetric Hydrogenation of Cyclic Imines. Cheminform. 25: no-no. DOI: 10.1002/chin.199419041  0.346
2010 BROENE RD, BUCHWALD SL. ChemInform Abstract: Asymmetric Hydrogenation of Unfunctionalized Trisubstituted Olefins with a Chiral Titanocene Catalyst. Cheminform. 25: no-no. DOI: 10.1002/chin.199415056  0.772
2010 BERK SC, GROSSMAN RB, BUCHWALD SL. ChemInform Abstract: Titanocene-Catalyzed Conversion of Enynes to Bicyclic Cyclopentenones. Cheminform. 24: no-no. DOI: 10.1002/chin.199340158  0.812
2010 CUNY GD, BUCHWALD SL. ChemInform Abstract: Practical, High-Yield, Regioselective, Rhodium-Catalyzed Hydroformylation of Functionalized α-Olefins. Cheminform. 24: no-no. DOI: 10.1002/chin.199330120  0.588
2010 GROSSMAN RB, BUCHWALD SL. ChemInform Abstract: Reductive Cyclization of Ester-Containing Enynes with a Practical Titanocene Reagent. Synthesis of Bicyclic Cyclopentenones and Iminocyclopentenes. Cheminform. 24: no-no. DOI: 10.1002/chin.199309065  0.609
2010 BARR KJ, WATSON BT, BUCHWALD SL. ChemInform Abstract: Zirconocene(iso-butyl) Chloride: In situ Generation of a Zirconocene( methyl) Chloride Equivalent for Use in Organic Synthesis. Cheminform. 23: no-no. DOI: 10.1002/chin.199225234  0.782
2010 BERK SC, KREUTZER KA, BUCHWALD SL. ChemInform Abstract: A Catalytic Method for the Reduction of Esters to Alcohols. Cheminform. 22: no-no. DOI: 10.1002/chin.199141081  0.674
2010 HSU DP, LUCAS EA, BUCHWALD SL. ChemInform Abstract: Synthesis and Reactions of a Zirconocene-Benzdiyne Equivalent. Cheminform. 22: no-no. DOI: 10.1002/chin.199140201  0.618
2010 GROSSMAN RB, DAVIS WM, BUCHWALD SL. ChemInform Abstract: Enantioselective, Zirconium-Mediated Synthesis of Allylic Amines. Cheminform. 22: no-no. DOI: 10.1002/chin.199130134  0.646
2010 CUNY GD, GUTIERREZ A, BUCHWALD SL. ChemInform Abstract: Cis Difunctionalization of Cyclic Olefins with Use of Organozirconium Intermediates. Cheminform. 22: no-no. DOI: 10.1002/chin.199129138  0.508
2010 CUNY GD, BUCHWALD SL. ChemInform Abstract: Ring-Opening Reactions of Cyclic Allylic Ethers by Zirconocene Complexes of Cyclic Alkynes. Cheminform. 22: no-no. DOI: 10.1002/chin.199117054  0.628
2010 BUCHWALD SL, KING SM. ChemInform Abstract: Regiospecific Synthesis of Polysubstituted Naphthalenes and Iodoacylnaphthoquinones via Zirconocene Complexes of Naphthalynes. Cheminform. 22: no-no. DOI: 10.1002/chin.199115141  0.688
2010 Fors BP, Buchwald SL. Commentary on "a new, efficient and recyclable lanthanum(III) oxide-catalyzed C-N cross-coupling" by S. Narayana Murthy, B. Madhav, V. Prakash Reddy, and Y. V. D. Nageswar, Adv. Synth. Catal. 2010, 352, 3241-3245 Advanced Synthesis and Catalysis. 352: 3119-3120. DOI: 10.1002/Adsc.201000905  0.62
2009 Lee BK, Biscoe MR, Buchwald SL. Simple, Efficient Protocols for the Pd-Catalyzed Cross-Coupling Reaction of Aryl Chlorides and Dimethylamine. Tetrahedron Letters. 50: 3672-3674. PMID 21818164 DOI: 10.1016/J.Tetlet.2009.03.137  0.778
2009 Fors BP, Dooleweerdt K, Zeng Q, Buchwald SL. An Efficient System For the Pd-Catalyzed Cross-Coupling of Amides and Aryl Chlorides. Tetrahedron. 65: 6576-6583. PMID 20740063 DOI: 10.1016/J.Tet.2009.04.096  0.752
2009 Maiti D, Buchwald SL. Orthogonal Cu- and Pd-based catalyst systems for the O- and N-arylation of aminophenols. Journal of the American Chemical Society. 131: 17423-9. PMID 19899753 DOI: 10.1021/Ja9081815  0.59
2009 Hicks JD, Hyde AM, Cuezva AM, Buchwald SL. Pd-catalyzed N-arylation of secondary acyclic amides: catalyst development, scope, and computational study. Journal of the American Chemical Society. 131: 16720-34. PMID 19886610 DOI: 10.1021/Ja9044357  0.775
2009 Fors BP, Buchwald SL. Pd-catalyzed conversion of aryl chlorides, triflates, and nonaflates to nitroaromatics. Journal of the American Chemical Society. 131: 12898-9. PMID 19737014 DOI: 10.1021/Ja905768K  0.739
2009 Watson DA, Su M, Teverovskiy G, Zhang Y, García-Fortanet J, Kinzel T, Buchwald SL. Formation of ArF from LPdAr(F): catalytic conversion of aryl triflates to aryl fluorides. Science (New York, N.Y.). 325: 1661-4. PMID 19679769 DOI: 10.1126/Science.1178239  0.828
2009 Bhayana B, Fors BP, Buchwald SL. A versatile catalyst system for Suzuki-Miyaura cross-coupling reactions of C(sp(2))-tosylates and mesylates. Organic Letters. 11: 3954-7. PMID 19663467 DOI: 10.1021/Ol9015892  0.734
2009 Taylor AM, Altman RA, Buchwald SL. Palladium-catalyzed enantioselective alpha-arylation and alpha-vinylation of oxindoles facilitated by an axially chiral P-stereogenic ligand. Journal of the American Chemical Society. 131: 9900-1. PMID 19580273 DOI: 10.1021/Ja903880Q  0.69
2009 Buchwald SL, Bolm C. On the role of metal contaminants in catalyses with FeCl3. Angewandte Chemie (International Ed. in English). 48: 5586-7. PMID 19554587 DOI: 10.1002/Anie.200902237  0.447
2009 Hyde AM, Buchwald SL. Synthesis of 5,5-disubstituted butenolides based on a Pd-catalyzed gamma-arylation strategy. Organic Letters. 11: 2663-6. PMID 19449882 DOI: 10.1021/Ol9007102  0.779
2009 Han C, Buchwald SL. Negishi coupling of secondary alkylzinc halides with aryl bromides and chlorides. Journal of the American Chemical Society. 131: 7532-3. PMID 19441851 DOI: 10.1021/Ja902046M  0.634
2009 García-Fortanet J, Kessler F, Buchwald SL. Palladium-catalyzed asymmetric dearomatization of naphthalene derivatives. Journal of the American Chemical Society. 131: 6676-7. PMID 19388652 DOI: 10.1021/Ja9025193  0.525
2009 Fors BP, Davis NR, Buchwald SL. An efficient process for pd-catalyzed C-N cross-coupling reactions of aryl iodides: insight into controlling factors. Journal of the American Chemical Society. 131: 5766-8. PMID 19348431 DOI: 10.1021/Ja901414U  0.823
2009 Biscoe MR, Buchwald SL. Selective monoarylation of acetate esters and aryl methyl ketones using aryl chlorides. Organic Letters. 11: 1773-5. PMID 19296693 DOI: 10.1021/Ol900295U  0.787
2009 Strieter ER, Bhayana B, Buchwald SL. Mechanistic studies on the copper-catalyzed N-arylation of amides. Journal of the American Chemical Society. 131: 78-88. PMID 19072233 DOI: 10.1021/Ja0781893  0.768
2009 Buchwald S, Fors B. Palladium-Catalyzed Synthesis of Nitroarenes Using Sodium Nitrite Synfacts. 2009: 1388-1388. DOI: 10.1055/S-0029-1218172  0.731
2009 Buchwald S, Bhayana B, Fors B. A Versatile Ligand for Suzuki-Miyaura Coupling of Tosylates and Mesylates Synfacts. 2009: 1385-1385. DOI: 10.1055/S-0029-1218165  0.651
2009 Taylor AM, Altman RA, Buchwald SL. Pd-Catalyzed Asymmetric α-Arylation and α-Vinylationof Oxindoles Synfacts. 2009: 1116-1116. DOI: 10.1055/S-0029-1217838  0.355
2009 García-Fortanet J, Kessler F, Buchwald SL. Palladium-Catalyzed Asymmetric Dearomatization Synfacts. 2009: 887-887. DOI: 10.1055/S-0029-1217423  0.556
2009 Garcia-Fortanet J, Buchwald SL. ChemInform Abstract: Asymmetric Palladium-Catalyzed Intramolecular α-Arylation of Aldehydes. Cheminform. 40. DOI: 10.1002/CHIN.200907100  0.351
2008 Martín R, Buchwald SL. An improved protocol for the Pd-catalyzed alpha-arylation of aldehydes with aryl halides. Organic Letters. 10: 4561-4. PMID 18808127 DOI: 10.1021/Ol8017775  0.772
2008 Fors BP, Watson DA, Biscoe MR, Buchwald SL. A highly active catalyst for Pd-catalyzed amination reactions: cross-coupling reactions using aryl mesylates and the highly selective monoarylation of primary amines using aryl chlorides. Journal of the American Chemical Society. 130: 13552-4. PMID 18798626 DOI: 10.1021/Ja8055358  0.858
2008 García-Fortanet J, Buchwald SL. Asymmetric palladium-catalyzed intramolecular alpha-arylation of aldehydes. Angewandte Chemie (International Ed. in English). 47: 8108-11. PMID 18792905 DOI: 10.1002/Anie.200803809  0.512
2008 Tsang WC, Munday RH, Brasche G, Zheng N, Buchwald SL. Palladium-catalyzed method for the synthesis of carbazoles via tandem C-H functionalization and C-N bond formation. The Journal of Organic Chemistry. 73: 7603-10. PMID 18761437 DOI: 10.1021/Jo801273Q  0.516
2008 Watson DA, Fan X, Buchwald SL. Carbonylation of aryl chlorides with oxygen nucleophiles at atmospheric pressure. Preparation of phenyl esters as acyl transfer agents and the direct preparation of alkyl esters and carboxylic acids. The Journal of Organic Chemistry. 73: 7096-101. PMID 18720992 DOI: 10.1021/Jo800907E  0.656
2008 Martinelli JR, Watson DA, Freckmann DM, Barder TE, Buchwald SL. Palladium-catalyzed carbonylation reactions of aryl bromides at atmospheric pressure: a general system based on Xantphos. The Journal of Organic Chemistry. 73: 7102-7. PMID 18720970 DOI: 10.1021/Jo801279R  0.844
2008 Surry DS, Buchwald SL. Biaryl phosphane ligands in palladium-catalyzed amination. Angewandte Chemie (International Ed. in English). 47: 6338-61. PMID 18663711 DOI: 10.1002/Anie.200800497  0.537
2008 Martin R, Buchwald SL. Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions employing dialkylbiaryl phosphine ligands. Accounts of Chemical Research. 41: 1461-73. PMID 18620434 DOI: 10.1021/Ar800036S  0.779
2008 Fors BP, Krattiger P, Strieter E, Buchwald SL. Water-mediated catalyst preactivation: an efficient protocol for C-N cross-coupling reactions. Organic Letters. 10: 3505-8. PMID 18620415 DOI: 10.1021/Ol801285G  0.828
2008 Altman RA, Hyde AM, Huang X, Buchwald SL. Orthogonal Pd- and Cu-based catalyst systems for C- and N-arylation of oxindoles. Journal of the American Chemical Society. 130: 9613-20. PMID 18588302 DOI: 10.1021/Ja803179S  0.826
2008 Billingsley KL, Buchwald SL. An improved system for the palladium-catalyzed borylation of aryl halides with pinacol borane. The Journal of Organic Chemistry. 73: 5589-91. PMID 18576604 DOI: 10.1021/Jo800727S  0.809
2008 Altman RA, Anderson KW, Buchwald SL. Pyrrole-2-carboxylic acid as a ligand for the Cu-catalyzed reactions of primary anilines with aryl halides. The Journal of Organic Chemistry. 73: 5167-9. PMID 18543973 DOI: 10.1021/Jo8008676  0.772
2008 Minatti A, Buchwald SL. Synthesis of indolines via a domino Cu-catalyzed amidation/cyclization reaction. Organic Letters. 10: 2721-4. PMID 18522394 DOI: 10.1021/Ol8008792  0.491
2008 Billingsley KL, Buchwald SL. A general and efficient method for the Suzuki-Miyaura coupling of 2-pyridyl nucleophiles. Angewandte Chemie (International Ed. in English). 47: 4695-8. PMID 18491343 DOI: 10.1002/Anie.200801465  0.822
2008 Wang H, Duennwald ML, Roberts BE, Rozeboom LM, Zhang YL, Steele AD, Krishnan R, Su LJ, Griffin D, Mukhopadhyay S, Hennessy EJ, Weigele P, Blanchard BJ, King J, Deniz AA, ... Buchwald SL, et al. Direct and selective elimination of specific prions and amyloids by 4,5-dianilinophthalimide and analogs. Proceedings of the National Academy of Sciences of the United States of America. 105: 7159-64. PMID 18480256 DOI: 10.1073/Pnas.0801934105  0.645
2008 Brasche G, García-Fortanet J, Buchwald SL. Twofold C-H functionalization: palladium-catalyzed ortho arylation of anilides. Organic Letters. 10: 2207-10. PMID 18465866 DOI: 10.1021/Ol800619C  0.388
2008 Biscoe MR, Fors BP, Buchwald SL. A new class of easily activated palladium precatalysts for facile C-N cross-coupling reactions and the low temperature oxidative addition of aryl chlorides. Journal of the American Chemical Society. 130: 6686-7. PMID 18447360 DOI: 10.1021/Ja801137K  0.837
2008 Munday RH, Martinelli JR, Buchwald SL. Palladium-catalyzed carbonylation of aryl tosylates and mesylates. Journal of the American Chemical Society. 130: 2754-5. PMID 18257577 DOI: 10.1021/Ja711449E  0.748
2008 Brasche G, Buchwald SL. C-H functionalization/C-N bond formation: copper-catalyzed synthesis of benzimidazoles from amidines. Angewandte Chemie (International Ed. in English). 47: 1932-4. PMID 18228236 DOI: 10.1002/Anie.200705420  0.353
2008 Altman RA, Shafir A, Choi A, Lichtor PA, Buchwald SL. An improved Cu-based catalyst system for the reactions of alcohols with aryl halides. The Journal of Organic Chemistry. 73: 284-6. PMID 18044928 DOI: 10.1021/Jo702024P  0.727
2008 Hyde AM, Buchwald SL. Palladium-catalyzed gamma-arylation of beta,gamma-unsaturated ketones: application to a one-pot synthesis of tricyclic indolines. Angewandte Chemie (International Ed. in English). 47: 177-80. PMID 18033712 DOI: 10.1002/Anie.200704529  0.749
2008 Altman RA, Hyde AM, Huang X, Buchwald SL. N- and C-Arylations of Oxindoles: Orthogonal Selectivityof Pd and Cu Catalysts Synfacts. 2008: 1096-1096. DOI: 10.1055/S-2008-1078230  0.394
2008 Munday RH, Martinelli JR, Buchwald SL. Carbonylation of Aryl Tosylates and Mesylates Synfacts. 2008: 515-515. DOI: 10.1055/S-2008-1072526  0.754
2008 Martín R, Cuenca A, Buchwald SL. Copper-Catalyzed C-N Bond Coupling Approach to Highly Substituted Oxazoles Synfacts. 2008: 237-237. DOI: 10.1055/S-2008-1042746  0.387
2008 Altman RA, Shafir A, Choi A, Lichtor PA, Buchwald SL. An Improved Catalyst System for Ullmann-Type Couplings between Alcohols and Aryl Halides Synfacts. 2008: 303-303. DOI: 10.1055/S-2008-1042741  0.374
2008 Martinelli JR, Watson DA, Freckmann DMM, Barder TE, Buchwald SL. Pd-Catalyzed Carbonylation of Aryl Bromides at AtmosphericPressure Synfacts. 2008: 1312-1312. DOI: 10.1055/S-0028-1083588  0.816
2008 Buchwald S, Fors B, Krattiger P, Strieter E. Water-Mediated Catalyst Preactivation for Efficient Pd-Catalyzed Aminations Synfacts. 2008: 1206-1206. DOI: 10.1055/S-0028-1083461  0.805
2008 Hyde AM, Buchwald SL. ChemInform Abstract: Palladium-Catalyzed γ-Arylation of β,γ-Unsaturated Ketones: Application to a One-Pot Synthesis of Tricyclic Indolines. Cheminform. 39. DOI: 10.1002/chin.200817118  0.752
2008 Naber JR, Buchwald SL. Palladium-catalyzed Stille cross-coupling reaction of aryl chlorides using a pre-milled palladium acetate and XPhos catalyst system Advanced Synthesis and Catalysis. 350: 957-961. DOI: 10.1002/Adsc.200800032  0.841
2007 Altman RA, Buchwald SL. Pd-catalyzed Suzuki-Miyaura reactions of aryl halides using bulky biarylmonophosphine ligands. Nature Protocols. 2: 3115-21. PMID 18079711 DOI: 10.1038/Nprot.2007.411  0.757
2007 Martín R, Cuenca A, Buchwald SL. Sequential copper-catalyzed vinylation/cyclization: an efficient synthesis of functionalized oxazoles. Organic Letters. 9: 5521-4. PMID 18020351 DOI: 10.1021/Ol7024718  0.772
2007 Altman RA, Fors BP, Buchwald SL. Pd-catalyzed amination reactions of aryl halides using bulky biarylmonophosphine ligands. Nature Protocols. 2: 2881-7. PMID 18007623 DOI: 10.1038/Nprot.2007.414  0.831
2007 Minatti A, Zheng X, Buchwald SL. Synthesis of chiral 3-substituted indanones via an enantioselective reductive-Heck reaction. The Journal of Organic Chemistry. 72: 9253-8. PMID 17967034 DOI: 10.1021/Jo701741Y  0.518
2007 Zheng N, Buchwald SL. Copper-catalyzed regiospecific synthesis of N-alkylbenzimidazoles. Organic Letters. 9: 4749-51. PMID 17949007 DOI: 10.1021/Ol7020737  0.505
2007 Altman RA, Buchwald SL. Cu-catalyzed Goldberg and Ullmann reactions of aryl halides using chelating N- and O-based ligands. Nature Protocols. 2: 2474-9. PMID 17947989 DOI: 10.1038/Nprot.2007.364  0.741
2007 Ikawa T, Barder TE, Biscoe MR, Buchwald SL. Pd-catalyzed amidation of aryl chlorides using monodentate biaryl phosphine ligands: a kinetic, computational, and synthetic investigation. Journal of the American Chemical Society. 129: 13001-7. PMID 17918833 DOI: 10.1021/Ja0717414  0.85
2007 Martinelli JR, Clark TP, Watson DA, Munday RH, Buchwald SL. Palladium-catalyzed aminocarbonylation of aryl chlorides at atmospheric pressure: the dual role of sodium phenoxide. Angewandte Chemie (International Ed. in English). 46: 8460-3. PMID 17902084 DOI: 10.1002/Anie.200702943  0.752
2007 Jones CP, Anderson KW, Buchwald SL. Sequential Cu-catalyzed amidation-base-mediated camps cyclization: a two-step synthesis of 2-Aryl-4-quinolones from o-halophenones. The Journal of Organic Chemistry. 72: 7968-73. PMID 17850097 DOI: 10.1021/Jo701384N  0.788
2007 Barder TE, Buchwald SL. Insights into amine binding to biaryl phosphine palladium oxidative addition complexes and reductive elimination from biaryl phosphine arylpalladium amido complexes via density functional theory. Journal of the American Chemical Society. 129: 12003-10. PMID 17850080 DOI: 10.1021/Ja073747Z  0.769
2007 Martín R, Buchwald SL. A general method for the direct alpha-arylation of aldehydes with aryl bromides and chlorides. Angewandte Chemie (International Ed. in English). 46: 7236-9. PMID 17722128 DOI: 10.1002/Anie.200703009  0.723
2007 Zheng N, Anderson KW, Huang X, Nguyen HN, Buchwald SL. A palladium-catalyzed regiospecific synthesis of N-aryl benzimidazoles. Angewandte Chemie (International Ed. in English). 46: 7509-12. PMID 17722125 DOI: 10.1002/Anie.200702542  0.766
2007 McNeill E, Barder TE, Buchwald SL. Palladium-catalyzed silylation of aryl chlorides with hexamethyldisilane. Organic Letters. 9: 3785-8. PMID 17705501 DOI: 10.1021/Ol701518F  0.815
2007 Biscoe MR, Barder TE, Buchwald SL. Electronic effects on the selectivity of pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: the competitive roles of amine binding and acidity. Angewandte Chemie (International Ed. in English). 46: 7232-5. PMID 17680583 DOI: 10.1002/Anie.200702122  0.823
2007 Surry DS, Buchwald SL. Selective palladium-catalyzed arylation of ammonia: synthesis of anilines as well as symmetrical and unsymmetrical di- and triarylamines. Journal of the American Chemical Society. 129: 10354-5. PMID 17672469 DOI: 10.1021/Ja074681A  0.506
2007 Martín R, Larsen CH, Cuenca A, Buchwald SL. Cu-catalyzed tandem C-N bond formation for the synthesis of pyrroles and heteroarylpyrroles. Organic Letters. 9: 3379-82. PMID 17655316 DOI: 10.1021/Ol7014225  0.827
2007 Altman RA, Koval ED, Buchwald SL. Copper-catalyzed N-arylation of imidazoles and benzimidazoles. The Journal of Organic Chemistry. 72: 6190-9. PMID 17625886 DOI: 10.1021/Jo070807A  0.754
2007 Billingsley KL, Barder TE, Buchwald SL. Palladium-catalyzed borylation of aryl chlorides: scope, applications, and computational studies. Angewandte Chemie (International Ed. in English). 46: 5359-63. PMID 17562550 DOI: 10.1002/Anie.200701551  0.818
2007 Murphy ER, Martinelli JR, Zaborenko N, Buchwald SL, Jensen KF. Accelerating reactions with microreactors at elevated temperatures and pressures: profiling aminocarbonylation reactions. Angewandte Chemie (International Ed. in English). 46: 1734-7. PMID 17397088 DOI: 10.1002/Anie.200604175  0.663
2007 Barder TE, Buchwald SL. Rationale behind the resistance of dialkylbiaryl phosphines toward oxidation by molecular oxygen. Journal of the American Chemical Society. 129: 5096-101. PMID 17388595 DOI: 10.1021/Ja0683180  0.763
2007 Martin R, Buchwald SL. Pd-catalyzed Kumada-Corriu cross-coupling reactions at low temperatures allow the use of Knochel-type Grignard reagents. Journal of the American Chemical Society. 129: 3844-5. PMID 17352483 DOI: 10.1021/Ja070830D  0.778
2007 Shafir A, Lichtor PA, Buchwald SL. N- versus O-arylation of aminoalcohols: orthogonal selectivity in copper-based catalysts. Journal of the American Chemical Society. 129: 3490-1. PMID 17341083 DOI: 10.1021/Ja068926F  0.447
2007 Billingsley K, Buchwald SL. Highly efficient monophosphine-based catalyst for the palladium-catalyzed suzuki-miyaura reaction of heteroaryl halides and heteroaryl boronic acids and esters. Journal of the American Chemical Society. 129: 3358-66. PMID 17326639 DOI: 10.1021/Ja068577P  0.811
2007 Rivero MR, Buchwald SL. Copper-catalyzed vinylation of hydrazides. A regioselective entry to highly substituted pyrroles. Organic Letters. 9: 973-6. PMID 17311390 DOI: 10.1021/Ol062978S  0.503
2007 Altman RA, Buchwald SL. Cu-catalyzed N- and O-arylation of 2-, 3-, and 4-hydroxypyridines and hydroxyquinolines. Organic Letters. 9: 643-6. PMID 17286371 DOI: 10.1021/Ol062904G  0.718
2007 Barder TE, Buchwald SL. Benchtop monitoring of reaction progress via visual recognition with a handheld UV lamp: in situ monitoring of boronic acids in the Suzuki-Miyaura reaction. Organic Letters. 9: 137-9. PMID 17192104 DOI: 10.1021/Ol062802Q  0.765
2007 Billingsley KL, Barder TE, Buchwald SL. Palladium-Catalyzed Borylation and Homocoupling of Aryl Chlorides Synfacts. 2007: 1194-1194. DOI: 10.1055/S-2007-991238  0.863
2007 Barder TE, Biscoe MR, Buchwald SL. Structural insights into active catalyst structures and oxidative addition to (biaryl)phosphine - palladium complexes via density functional theory and experimental studies Organometallics. 26: 2183-2192. DOI: 10.1021/Om0701017  0.823
2006 Martinelli JR, Freckmann DM, Buchwald SL. Convenient method for the preparation of Weinreb amides via Pd-catalyzed aminocarbonylation of aryl bromides at atmospheric pressure. Organic Letters. 8: 4843-6. PMID 17020317 DOI: 10.1021/Ol061902T  0.703
2006 Martín R, Rodríguez Rivero M, Buchwald SL. Domino cu-catalyzed C--N coupling/hydroamidation: a highly efficient synthesis of nitrogen heterocycles. Angewandte Chemie (International Ed. in English). 45: 7079-82. PMID 17009380 DOI: 10.1002/Anie.200602917  0.744
2006 Anderson KW, Tundel RE, Ikawa T, Altman RA, Buchwald SL. Monodentate phosphines provide highly active catalysts for Pd-catalyzed C-N bond-forming reactions of heteroaromatic halides/amines and (H)N-heterocycles. Angewandte Chemie (International Ed. in English). 45: 6523-7. PMID 16955526 DOI: 10.1002/Anie.200601612  0.835
2006 Anderson KW, Ikawa T, Tundel RE, Buchwald SL. The selective reaction of aryl halides with KOH: synthesis of phenols, aromatic ethers, and benzofurans. Journal of the American Chemical Society. 128: 10694-5. PMID 16910660 DOI: 10.1021/Ja0639719  0.859
2006 Shafir A, Buchwald SL. Highly selective room-temperature copper-catalyzed C-N coupling reactions. Journal of the American Chemical Society. 128: 8742-3. PMID 16819863 DOI: 10.1021/Ja063063B  0.484
2006 Altman RA, Buchwald SL. 4,7-Dimethoxy-1,10-phenanthroline: an excellent ligand for the Cu-catalyzed N-arylation of imidazoles. Organic Letters. 8: 2779-82. PMID 16774255 DOI: 10.1021/Ol0608505  0.737
2006 Burgos CH, Barder TE, Huang X, Buchwald SL. Significantly improved method for the pd-catalyzed coupling of phenols with aryl halides: understanding ligand effects. Angewandte Chemie (International Ed. in English). 45: 4321-6. PMID 16733839 DOI: 10.1002/Anie.200601253  0.811
2006 Billingsley KL, Anderson KW, Buchwald SL. A highly active catalyst for Suzuki-Miyaura cross-coupling reactions of heteroaryl compounds. Angewandte Chemie (International Ed. in English). 45: 3484-8. PMID 16639772 DOI: 10.1002/Anie.200600493  0.815
2006 Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. Journal of the American Chemical Society. 128: 3584-91. PMID 16536531 DOI: 10.1021/Ja045533C  0.768
2006 Tundel RE, Anderson KW, Buchwald SL. Expedited palladium-catalyzed amination of aryl nonaflates through the use of microwave-irradiation and soluble organic amine bases. The Journal of Organic Chemistry. 71: 430-3. PMID 16388678 DOI: 10.1021/Jo052131U  0.852
2006 Strieter ER, Buchwald SL. Evidence for the formation and structure of palladacycles during Pd-catalyzed C-N bond formation with catalysts derived from bulky monophosphinobiaryl ligands. Angewandte Chemie (International Ed. in English). 45: 925-8. PMID 16381052 DOI: 10.1002/Anie.200502927  0.744
2006 Larsen CH, Anderson KW, Tundel RE, Buchwald SL. Palladium-catalyzed Heck alkynylation of benzyl chlorides Synlett. 2941-2946. DOI: 10.1055/S-2006-949625  0.842
2006 Buchwald S, Anderson K, Ikawa T, Tundel R. Pd-Catalyzed Synthesis of Phenols and Aromatic Ethers from Aryl Halides Synfacts. 2006: 1163-1163. DOI: 10.1055/S-2006-949484  0.831
2006 Buchwald S, Shafir A. A Mild Copper-Catalyzed Amination of Haloarenes Synfacts. 2006: 1055-1055. DOI: 10.1055/s-2006-949307  0.304
2006 Klingensmith LM, Strieter ER, Barder TE, Buchwald SL. New insights into xantphos/Pd-catalyzed C-N bond forming reactions: A structural and kinetic study Organometallics. 25: 82-91. DOI: 10.1021/Om050715G  0.804
2006 Enguehard-Gueiffier C, Thery I, Gueiffier A, Buchwald SL. A General and Efficient Method for the Copper-Catalyzed Cross-Coupling of Amides and Thiophenols with 6-Halogenoimidazo[1,2-a]pyridines. Cheminform. 37. DOI: 10.1016/J.Tet.2006.04.007  0.45
2006 Buchwald S, Mauger C, Mignani G, Scholz U. Cover Picture: Industrial-Scale Palladium-Catalyzed Coupling of Aryl Halides and Amines –A Personal Account (Adv. Synth. Catal. 1-2/2006) Advanced Synthesis & Catalysis. 348: 1-1. DOI: 10.1002/Adsc.200690000  0.457
2006 Buchwald S, Mauger C, Mignani G, Scholz U. Industrial-Scale Palladium-Catalyzed Coupling of Aryl Halides and Amines –A Personal Account Advanced Synthesis & Catalysis. 348: 23-39. DOI: 10.1002/Adsc.200505158  0.423
2005 Tsang WC, Zheng N, Buchwald SL. Combined C-H functionalization/C-N bond formation route to carbazoles. Journal of the American Chemical Society. 127: 14560-1. PMID 16231894 DOI: 10.1021/Ja055353I  0.5
2005 Rainka MP, Milne JE, Buchwald SL. Dynamic kinetic resolution of alpha,beta-unsaturated lactones through asymmetric copper-catalyzed conjugate reduction: application to the total synthesis of eupomatilone-3. Angewandte Chemie (International Ed. in English). 44: 6177-80. PMID 16130153 DOI: 10.1002/Anie.200501890  0.792
2005 Hennessy EJ, Buchwald SL. Synthesis of 4,5-dianilinophthalimide and related analogues for potential treatment of Alzheimer's disease via palladium-catalyzed amination. The Journal of Organic Chemistry. 70: 7371-5. PMID 16122261 DOI: 10.1021/Jo051096O  0.75
2005 Charles MD, Schultz P, Buchwald SL. Efficient pd-catalyzed amination of heteroaryl halides. Organic Letters. 7: 3965-8. PMID 16119943 DOI: 10.1021/ol0514754  0.351
2005 Anderson KW, Buchwald SL. General catalysts for the Suzuki-Miyaura and Sonogashira coupling reactions of aryl chlorides and for the coupling of challenging substrate combinations in water. Angewandte Chemie (International Ed. in English). 44: 6173-7. PMID 16097019 DOI: 10.1002/Anie.200502017  0.653
2005 Vorogushin AV, Huang X, Buchwald SL. Use of tunable ligands allows for intermolecular Pd-catalyzed C--O bond formation. Journal of the American Chemical Society. 127: 8146-9. PMID 15926842 DOI: 10.1021/Ja050471R  0.603
2005 Barder TE, Walker SD, Martinelli JR, Buchwald SL. Catalysts for Suzuki-Miyaura coupling processes: scope and studies of the effect of ligand structure. Journal of the American Chemical Society. 127: 4685-96. PMID 15796535 DOI: 10.1021/Ja042491J  0.859
2005 Strieter ER, Blackmond DG, Buchwald SL. The role of chelating diamine ligands in the goldberg reaction: a kinetic study on the copper-catalyzed amidation of aryl iodides. Journal of the American Chemical Society. 127: 4120-1. PMID 15783164 DOI: 10.1021/Ja050120C  0.733
2005 Buchwald S, Rainka M, Milne J. Dynamic Kinetic Resolution in Cu-Catalyzed Conjugate Hydride Addition Synfacts. 2006: 0034-0034. DOI: 10.1055/S-2005-921676  0.777
2005 Charles MD, Schultz P, Buchwald SL. Synthesis of Heteroaromatic Amines by C-N Cross-Coupling Synfacts. 2005: 210-210. DOI: 10.1055/S-2005-916068  0.377
2004 Chae J, Yun J, Buchwald SL. One-pot sequential Cu-catalyzed reduction and Pd-catalyzed arylation of silyl enol ethers. Organic Letters. 6: 4809-12. PMID 15606072 DOI: 10.1021/Ol048313C  0.738
2004 Milne JE, Buchwald SL. An extremely active catalyst for the Negishi cross-coupling reaction. Journal of the American Chemical Society. 126: 13028-32. PMID 15469301 DOI: 10.1021/Ja0474493  0.495
2004 Antilla JC, Baskin JM, Barder TE, Buchwald SL. Copper-diamine-catalyzed N-arylation of pyrroles, pyrazoles, indazoles, imidazoles, and triazoles. The Journal of Organic Chemistry. 69: 5578-87. PMID 15307726 DOI: 10.1021/Jo049658B  0.857
2004 Barder TE, Buchwald SL. Efficient catalyst for the Suzuki-Miyaura coupling of potassium aryl trifluoroborates with aryl chlorides. Organic Letters. 6: 2649-52. PMID 15281735 DOI: 10.1021/Ol0491686  0.831
2004 Chae J, Buchwald SL. Palladium-catalyzed regioselective hydrodebromination of dibromoindoles: application to the enantioselective synthesis of indolodioxane U86192A. The Journal of Organic Chemistry. 69: 3336-9. PMID 15132539 DOI: 10.1021/Jo035819K  0.679
2004 Rainka MP, Aye Y, Buchwald SL. Copper-catalyzed asymmetric conjugate reduction as a route to novel beta-azaheterocyclic acid derivatives. Proceedings of the National Academy of Sciences of the United States of America. 101: 5821-3. PMID 15067136 DOI: 10.1073/Pnas.0307764101  0.814
2004 Walker SD, Barder TE, Martinelli JR, Buchwald SL. A rationally designed universal catalyst for Suzuki-Miyaura coupling processes. Angewandte Chemie (International Ed. in English). 43: 1871-6. PMID 15054800 DOI: 10.1002/Anie.200353615  0.839
2004 Klapars A, Parris S, Anderson KW, Buchwald SL. Synthesis of medium ring nitrogen heterocycles via a tandem copper-catalyzed C-N bond formation-ring-expansion process. Journal of the American Chemical Society. 126: 3529-33. PMID 15025480 DOI: 10.1021/Ja038565T  0.646
2004 Murata M, Buchwald SL. A General and Efficient Method for the Palladium-Catalyzed Cross-Coupling of Thiols and Secondary Phosphines. Cheminform. 35. DOI: 10.1016/J.Tet.2004.05.044  0.516
2004 Hennessy EJ, Buchwald SL. Synthesis of Substituted Oxindoles from α-Chloroacetanilides via Palladium-Catalyzed C—H Functionalization. Cheminform. 35. DOI: 10.1002/chin.200404090  0.721
2004 Buchwald S. Transition Metal-Catalyzed Cross-Coupling and the Heck Coupling Processes: Powerful Reactions for Carbon-Carbon and Carbon-Heteroatom Bond Formation Advanced Synthesis & Catalysis. 346: 1524-1524. DOI: 10.1002/Adsc.200404335  0.329
2003 Hughes G, Kimura M, Buchwald SL. Catalytic enantioselective conjugate reduction of lactones and lactams. Journal of the American Chemical Society. 125: 11253-8. PMID 16220945 DOI: 10.1021/Ja0351692  0.449
2003 Gelman D, Buchwald SL. Efficient palladium-catalyzed coupling of aryl chlorides and tosylates with terminal alkynes: use of a copper cocatalyst inhibits the reaction. Angewandte Chemie (International Ed. in English). 42: 5993-6. PMID 14679552 DOI: 10.1002/Anie.200353015  0.734
2003 Anderson KW, Mendez-Perez M, Priego J, Buchwald SL. Palladium-catalyzed amination of aryl nonaflates. The Journal of Organic Chemistry. 68: 9563-73. PMID 14656080 DOI: 10.1021/Jo034962A  0.718
2003 Strieter ER, Blackmond DG, Buchwald SL. Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation. Journal of the American Chemical Society. 125: 13978-80. PMID 14611232 DOI: 10.1021/Ja037932Y  0.742
2003 Hennessy EJ, Buchwald SL. Synthesis of substituted oxindoles from alpha-chloroacetanilides via palladium-catalyzed C[bond]H functionalization. Journal of the American Chemical Society. 125: 12084-5. PMID 14518981 DOI: 10.1021/Ja037546G  0.766
2003 Jiang L, Job GE, Klapars A, Buchwald SL. Copper-catalyzed coupling of amides and carbamates with vinyl halides. Organic Letters. 5: 3667-9. PMID 14507200 DOI: 10.1021/Ol035355C  0.508
2003 Nguyen HN, Huang X, Buchwald SL. The first general palladium catalyst for the Suzuki-Miyaura and carbonyl enolate coupling of aryl arenesulfonates. Journal of the American Chemical Society. 125: 11818-9. PMID 14505394 DOI: 10.1021/Ja036947T  0.653
2003 Jurkauskas V, Sadighi JP, Buchwald SL. Conjugate reduction of alpha,beta-unsaturated carbonyl compounds catalyzed by a copper carbene complex. Organic Letters. 5: 2417-20. PMID 12841744 DOI: 10.1021/Ol034560P  0.819
2003 Zim D, Buchwald SL. An air and thermally stable one- component catalyst for the amination of aryl chlorides. Organic Letters. 5: 2413-5. PMID 12841743 DOI: 10.1021/Ol034561H  0.446
2003 Enguehard C, Allouchi H, Gueiffier A, Buchwald SL. Ipso- or cine-substitutions of 6-haloimidazo[1,2-a]pyridine derivatives with different azoles depending on the reaction conditions. The Journal of Organic Chemistry. 68: 5614-7. PMID 12839453 DOI: 10.1021/Jo034439W  0.474
2003 Gelman D, Jiang L, Buchwald SL. Copper-catalyzed C-P bond construction via direct coupling of secondary phosphines and phosphites with aryl and vinyl halides. Organic Letters. 5: 2315-8. PMID 12816437 DOI: 10.1021/Ol0346640  0.757
2003 Huang X, Anderson KW, Zim D, Jiang L, Klapars A, Buchwald SL. Expanding Pd-catalyzed C-N bond-forming processes: the first amidation of aryl sulfonates, aqueous amination, and complementarity with Cu-catalyzed reactions. Journal of the American Chemical Society. 125: 6653-5. PMID 12769573 DOI: 10.1021/Ja035483W  0.749
2003 Enguehard C, Allouchi H, Gueiffier A, Buchwald SL. Easy access to novel substituted 6-aminoimidazo[1,2-a]pyridines using palladium- and copper-catalyzed aminations. The Journal of Organic Chemistry. 68: 4367-70. PMID 12762738 DOI: 10.1021/Jo0341463  0.467
2003 Nordmann G, Buchwald SL. A domino copper-catalyzed C-O coupling-Claisen rearrangement process. Journal of the American Chemical Society. 125: 4978-9. PMID 12708838 DOI: 10.1021/Ja034809Y  0.476
2003 Kwong FY, Buchwald SL. Mild and efficient copper-catalyzed amination of aryl bromides with primary alkylamines. Organic Letters. 5: 793-6. PMID 12633073 DOI: 10.1021/Ol0273396  0.694
2003 Zanon J, Klapars A, Buchwald SL. Copper-catalyzed domino halide exchange-cyanation of aryl bromides. Journal of the American Chemical Society. 125: 2890-1. PMID 12617652 DOI: 10.1021/Ja0299708  0.521
2003 Huang X, Anderson KW, Zim D, Jiang L, Klapars aA, Buchwald SL. Expanding Pd-Catalyzed C−N Bond-Forming Processes: The First Amidation of Aryl Sulfonates, Aqueous Amination, and Complementarity with Cu-Catalyzed Reactions [J. Am. Chem. Soc. 2003, 125, 6653−6655]. Journal of the American Chemical Society. 125: 10767-10767. DOI: 10.1021/Ja033450A  0.723
2003 Jurkauskas V, Sadighi JP, Buchwald SL. Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds Catalyzed by a Copper Carbene Complex. Cheminform. 34. DOI: 10.1002/chin.200348047  0.8
2003 Buchwald SL, LaMaire SJ, Nielsen RB, Watson BT, King SM. Schwartz's Reagent Organic Syntheses. 77-77. DOI: 10.1002/0471264180.Os071.10  0.77
2002 Rutherford JL, Rainka MP, Buchwald SL. An annulative approach to highly substituted indoles: unusual effect of phenolic additives on the success of the arylation of ketone enolates. Journal of the American Chemical Society. 124: 15168-9. PMID 12487580 DOI: 10.1021/Ja0288993  0.846
2002 Klapars A, Buchwald SL. Copper-catalyzed halogen exchange in aryl halides: an aromatic Finkelstein reaction. Journal of the American Chemical Society. 124: 14844-5. PMID 12475315 DOI: 10.1021/Ja028865V  0.518
2002 Singh UK, Strieter ER, Blackmond DG, Buchwald SL. Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions. Journal of the American Chemical Society. 124: 14104-14. PMID 12440909 DOI: 10.1021/Ja026885R  0.76
2002 Kwong FY, Buchwald SL. A general, efficient, and inexpensive catalyst system for the coupling of aryl iodides and thiols. Organic Letters. 4: 3517-20. PMID 12323058 DOI: 10.1021/Ol0266673  0.688
2002 Antilla JC, Klapars A, Buchwald SL. The copper-catalyzed N-arylation of indoles. Journal of the American Chemical Society. 124: 11684-8. PMID 12296734 DOI: 10.1021/Ja027433H  0.67
2002 Harris MC, Huang X, Buchwald SL. Improved functional group compatibility in the palladium-catalyzed synthesis of aryl amines. Organic Letters. 4: 2885-8. PMID 12182580 DOI: 10.1021/Ol0262688  0.753
2002 Klapars A, Huang X, Buchwald SL. A general and efficient copper catalyst for the amidation of aryl halides. Journal of the American Chemical Society. 124: 7421-8. PMID 12071751 DOI: 10.1021/Ja0260465  0.633
2002 Yin J, Buchwald SL. Pd-catalyzed intermolecular amidation of aryl halides: the discovery that xantphos can be trans-chelating in a palladium complex. Journal of the American Chemical Society. 124: 6043-8. PMID 12022838 DOI: 10.1021/Ja012610K  0.467
2002 Sturla SJ, Buchwald SL. Cobalt-phosphite-catalyzed asymmetric Pauson-Khand reaction. The Journal of Organic Chemistry. 67: 3398-403. PMID 12003551 DOI: 10.1021/Jo016038R  0.695
2002 Spielvogel DJ, Buchwald SL. Nickel-BINAP catalyzed enantioselective alpha-arylation of alpha-substituted gamma-butyrolactones. Journal of the American Chemical Society. 124: 3500-1. PMID 11929227 DOI: 10.1021/Ja017545T  0.306
2002 Jurkauskas V, Buchwald SL. Dynamic kinetic resolution via asymmetric conjugate reduction: enantio- and diastereoselective synthesis of 2,4-dialkyl cyclopentanones. Journal of the American Chemical Society. 124: 2892-3. PMID 11902878 DOI: 10.1021/Ja025603K  0.817
2002 Hamada T, Buchwald SL. P-chirogenic binaphthyl-substituted monophosphines: synthesis and use in enolate vinylation/arylation reactions. Organic Letters. 4: 999-1001. PMID 11893206 DOI: 10.1021/Ol025563P  0.421
2002 Wolter M, Nordmann G, Job GE, Buchwald SL. Copper-catalyzed coupling of aryl iodides with aliphatic alcohols. Organic Letters. 4: 973-6. PMID 11893199 DOI: 10.1021/Ol025548K  0.344
2002 Kwong FY, Klapars A, Buchwald SL. Copper-catalyzed coupling of alkylamines and aryl iodides: an efficient system even in an air atmosphere. Organic Letters. 4: 581-4. PMID 11843596 DOI: 10.1021/Ol0171867  0.714
2002 Hamada T, Chieffi A, Ahman J, Buchwald SL. An improved catalyst for the asymmetric arylation of ketone enolates. Journal of the American Chemical Society. 124: 1261-8. PMID 11841295 DOI: 10.1021/Ja011122+  0.784
2002 Yin J, Rainka MP, Zhang XX, Buchwald SL. A highly active Suzuki catalyst for the synthesis of sterically hindered biaryls: novel ligand coordination. Journal of the American Chemical Society. 124: 1162-3. PMID 11841272 DOI: 10.1021/Ja017082R  0.825
2002 Gaertzen O, Buchwald SL. Palladium-catalyzed intramolecular alpha-arylation of alpha-amino acid esters. The Journal of Organic Chemistry. 67: 465-75. PMID 11798319 DOI: 10.1021/Jo0107756  0.377
2002 Hennessy EJ, Buchwald SL. A general and mild copper-catalyzed arylation of diethyl malonate. Organic Letters. 4: 269-72. PMID 11796067 DOI: 10.1021/Ol017038G  0.775
2002 Vogl EM, Buchwald SL. Palladium-catalyzed monoarylation of nitroalkanes. The Journal of Organic Chemistry. 67: 106-11. PMID 11777446 DOI: 10.1021/Jo010953V  0.539
2002 Wolfe JP, Buchwald SL, Norling H, Hegedus LS. Palladium-catalyzed amination of aryl halides and aryl triflates: N-hexyl-2-methyl-4-methoxyaniline and N-methyl-N-(4-chlorophenyl) aniline: [ Benzenamine, 4-chloro-N-methyl-N-phenyl- ] Organic Syntheses. 78: 23-35. DOI: 10.15227/Orgsyn.078.0023  0.547
2002 Sturla SJ, Buchwald SL. Monocyclopentadienyltitanium aryloxide complexes: Preparation, characterization, and application in cyclization reactions Organometallics. 21: 739-748. DOI: 10.1021/Om010755U  0.664
2002 Muci AR, Buchwald SL. Practical Palladium Catalysts for C-N and C-O Bond Formation Topics in Current Chemistry. 219: 131-209. DOI: 10.1007/3-540-45313-X_5  0.452
2001 Kuwabe SI, Torraca KE, Buchwald SL. Palladium-catalyzed intramolecular C-O bond formation. Journal of the American Chemical Society. 123: 12202-6. PMID 11734019 DOI: 10.1021/Ja012046D  0.847
2001 Wolter M, Klapars A, Buchwald SL. Synthesis of N-aryl hydrazides by copper-catalyzed coupling of hydrazides with aryl iodides. Organic Letters. 3: 3803-5. PMID 11700143 DOI: 10.1021/Ol0168216  0.486
2001 Torraca KE, Huang X, Parrish CA, Buchwald SL. An efficient intermolecular palladium-catalyzed synthesis of aryl ethers. Journal of the American Chemical Society. 123: 10770-1. PMID 11674023 DOI: 10.1021/Ja016863P  0.853
2001 Huang X, Buchwald SL. New ammonia equivalents for the Pd-catalyzed amination of aryl halides. Organic Letters. 3: 3417-9. PMID 11594848 DOI: 10.1021/Ol0166808  0.64
2001 Moradi WA, Buchwald SL. Palladium-catalyzed alpha-arylation of esters. Journal of the American Chemical Society. 123: 7996-8002. PMID 11506555 DOI: 10.1021/Ja010797+  0.497
2001 Klapars A, Antilla JC, Huang X, Buchwald SL. A general and efficient copper catalyst for the amidation of aryl halides and the N-arylation of nitrogen heterocycles. Journal of the American Chemical Society. 123: 7727-9. PMID 11481007 DOI: 10.1021/Ja016226Z  0.768
2001 Antilla JC, Buchwald SL. Copper-catalyzed coupling of arylboronic acids and amines. Organic Letters. 3: 2077-9. PMID 11418053 DOI: 10.1021/Ol0160396  0.719
2001 Chieffi A, Kamikawa K, Ahman J, Fox JM, Buchwald SL. Catalytic asymmetric vinylation of ketone enolates. Organic Letters. 3: 1897-900. PMID 11405739 DOI: 10.1021/Ol0159470  0.825
2001 Parrish CA, Buchwald SL. Use of polymer-supported dialkylphosphinobiphenyl ligands for palladium-catalyzed amination and Suzuki reactions. The Journal of Organic Chemistry. 66: 3820-7. PMID 11375003 DOI: 10.1021/Jo010025W  0.492
2001 Yun J, Buchwald SL. One-pot synthesis of enantiomerically enriched 2,3-disubstituted cyclopentanones via copper-catalyzed 1,4-reduction and alkylation. Organic Letters. 3: 1129-31. PMID 11348176 DOI: 10.1021/Ol015577F  0.665
2001 Ali MH, Buchwald SL. An improved method for the palladium-catalyzed amination of aryl iodides. The Journal of Organic Chemistry. 66: 2560-5. PMID 11304171 DOI: 10.1021/Jo0008486  0.534
2001 Parrish CA, Buchwald SL. Palladium-catalyzed formation of aryl tert-butyl ethers from unactivated aryl halides. The Journal of Organic Chemistry. 66: 2498-500. PMID 11281795 DOI: 10.1021/Jo001426Z  0.546
2001 Zhang X, Harris MC, Sadighi JP, Buchwald SL. The use of palladium chloride as a precatalyst for the amination of aryl bromides Canadian Journal of Chemistry. 79: 1799-1805. DOI: 10.1139/V01-152  0.847
2001 Yin J, Buchwald SL. ChemInform Abstract: A Catalytic Asymmetric Suzuki Coupling for the Synthesis of Axially Chiral Biaryl Compounds. Cheminform. 32: no-no. DOI: 10.1002/chin.200116119  0.326
2001 Torraca KE, Kuwabe S, Buchwald SL. ChemInform Abstract: A High-Yield, General Method for the Catalytic Formation of Oxygen Heterocycles. Cheminform. 32: no-no. DOI: 10.1002/chin.200116057  0.792
2001 Kaye S, Fox JM, Hicks FA, Buchwald SL. The Use of Catalytic Amounts of CuCl and Other Improvements in the Benzyne Route to Biphenyl-Based Phosphine Ligands Advanced Synthesis and Catalysis. 343: 789-794. DOI: 10.1002/1615-4169(20011231)343:8<789::Aid-Adsc789>3.0.Co;2-A  0.795
2001 Wolfe JP, Buchwald SL. Palladium-catalyzed amination of aryl halides and aryl triflates: N-hexyl-2-methyl-4-methoxyaniline and N-methyl-N-(4-chlorophenyl)aniline Organic Syntheses. 78: 23-30. DOI: 10.1002/0471264180.Os078.03  0.572
2000 Zhang XX, Buchwald SL. Efficient synthesis of N-aryl-aza-crown ethers via palladium-catalyzed amination The Journal of Organic Chemistry. 65: 8027-31. PMID 11073613 DOI: 10.1021/Jo005577D  0.532
2000 Tomori H, Fox JM, Buchwald SL. An improved synthesis of functionalized biphenyl-based phosphine ligands. The Journal of Organic Chemistry. 65: 5334-41. PMID 10993363 DOI: 10.1021/Jo000691H  0.613
2000 Harris MC, Buchwald SL. One-pot synthesis of unsymmetrical triarylamines from aniline precursors. The Journal of Organic Chemistry. 65: 5327-33. PMID 10993362 DOI: 10.1021/Jo000674S  0.708
2000 Hundertmark T, Littke AF, Buchwald SL, Fu GC. Pd(PhCN)(2)Cl(2)/P(t-Bu)(3): a versatile catalyst for Sonogashira reactions of aryl bromides at room temperature. Organic Letters. 2: 1729-31. PMID 10880212 DOI: 10.1021/Ol0058947  0.621
2000 Yun J, Buchwald SL. Kinetic resolution and isomerization of 2,5-disubstituted pyrrolines. Chirality. 12: 476-8. PMID 10824173 DOI: 10.1002/(Sici)1520-636X(2000)12:5/6<476::Aid-Chir31>3.0.Co;2-B  0.618
2000 Old DW, Harris MC, Buchwald SL. Efficient palladium-catalyzed N-arylation of indoles. Organic Letters. 2: 1403-6. PMID 10814458 DOI: 10.1021/Ol005728Z  0.716
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