| Year |
Citation |
Score |
| 2024 |
Medina JT, Tran QH, Hughes RP, Wang X, Brookhart M, Daugulis O. Ethylene Polymerizations Catalyzed by Fluorinated "Sandwich" Diimine-Nickel and Palladium Complexes. Journal of the American Chemical Society. PMID 38781282 DOI: 10.1021/jacs.4c01322 |
0.789 |
|
| 2020 |
Daugulis O, Brookhart M, Janeta M, Heidlas JX. 2,4,6-Triphenylpyridinium: A Bulky, Highly Electron-Withdrawing Substituent Which Enhances Properties of Nickel(II) Ethylene Polymerization Catalysts. Angewandte Chemie (International Ed. in English). PMID 33230900 DOI: 10.1002/anie.202013854 |
0.814 |
|
| 2020 |
Han XW, Daugulis O, Brookhart M. Unsaturated Alcohols as Chain-Transfer Agents in Olefin Polymerization: Synthesis of Aldehyde End-Capped Oligomers and Polymers. Journal of the American Chemical Society. PMID 32852948 DOI: 10.1021/Jacs.0C06644 |
0.792 |
|
| 2020 |
Tran QH, Brookhart M, Daugulis O. New Neutral Nickel and Palladium Sandwich Catalysts: Synthesis of Ultra-High Molecular Weight Polyethylene (UHMWPE) via Highly Controlled Polymerization and Mechanistic Studies of Chain Propagation. Journal of the American Chemical Society. PMID 32233435 DOI: 10.1021/Jacs.0C02045 |
0.778 |
|
| 2020 |
Farquhar AH, Brookhart M, Miller AJM. Oligomerization and polymerization of 5-ethylidene-2-norbornene by cationic palladium and nickel catalysts Polymer Chemistry. 11: 2576-2584. DOI: 10.1039/D0Py00216J |
0.414 |
|
| 2019 |
Kocen AL, Brookhart M, Daugulis O. A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis. Nature Communications. 10: 438. PMID 30683873 DOI: 10.1038/S41467-019-08309-8 |
0.752 |
|
| 2019 |
Böhm VP, Brookhart M. Dehydrocoupling of Phosphanes Catalyzed by a Rhodium(I) Complex We thank the National Institutes of Health (NIH) for financial support and O. Daugulis for samples of dimesitylphosphane and 2,4,6-tri-tert-butylphenylphosphane. V.P.W.B. acknowledges a Feodor Lynen fellowship of the Alexander-von-Humboldt-Stiftung (Germany). Angewandte Chemie (International Ed. in English). 40: 4694-4696. PMID 12404387 DOI: 10.1002/1521-3773(20011217)40:24<4694::Aid-Anie4694>3.0.Co;2-7 |
0.4 |
|
| 2018 |
Chen Z, Brookhart M. Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts. Accounts of Chemical Research. PMID 30028122 DOI: 10.1021/acs.accounts.8b00225 |
0.365 |
|
| 2017 |
Chen Z, Leatherman MD, Daugulis O, Brookhart M. Nickel-Catalyzed Copolymerization of Ethylene and Vinyltrialkoxysilanes: Catalytic Production of Cross-Linkable Polyethylene and Elucidation of the Chain-Growth Mechanism. Journal of the American Chemical Society. PMID 29083899 DOI: 10.1021/Jacs.7B10281 |
0.827 |
|
| 2017 |
Kocen AL, Brookhart M, Daugulis O. Palladium-catalysed alkene chain-running isomerization. Chemical Communications (Cambridge, England). PMID 28835962 DOI: 10.1039/C7Cc04953F |
0.755 |
|
| 2017 |
Bézier D, Daugulis O, Brookhart M. Polymerization of Ethylene Catalyzed by Phosphine-Iminophosphorane Palladium Complexes Organometallics. 36: 2947-2951. DOI: 10.1021/Acs.Organomet.7B00391 |
0.786 |
|
| 2017 |
Kocen AL, Klimovica K, Brookhart M, Daugulis O. Alkene Isomerization by “Sandwich” Diimine-Palladium Catalysts Organometallics. 36: 787-790. DOI: 10.1021/Acs.Organomet.6B00856 |
0.778 |
|
| 2017 |
Bézier D, Daugulis O, Brookhart M. Oligomerization of Ethylene Using a Diphosphine Palladium Catalyst Organometallics. 36: 443-447. DOI: 10.1021/Acs.Organomet.6B00850 |
0.769 |
|
| 2016 |
Bézier D, Guan C, Krogh-Jespersen K, Goldman AS, Brookhart M. Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex. Chemical Science. 7: 2579-2586. PMID 28660029 DOI: 10.1039/C5Sc04794C |
0.716 |
|
| 2016 |
Chen Z, Liu W, Daugulis O, Brookhart M. Mechanistic Studies of Pd(II)-Catalyzed Copolymerization of Ethylene and Vinylalkoxysilanes: Evidence for a β-Silyl Elimination Chain Transfer Mechanism. Journal of the American Chemical Society. 138: 16120-16129. PMID 27960299 DOI: 10.1021/Jacs.6B10462 |
0.814 |
|
| 2016 |
Bolig AD, Lyons TW, DiSalvo DT, Brookhart M. Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies. Polyhedron. 103: 51-57. PMID 26858471 DOI: 10.1016/J.Poly.2015.07.076 |
0.398 |
|
| 2016 |
Chen Z, Allen KE, White PS, Daugulis O, Brookhart M. Synthesis of Branched Polyethylene with "half-Sandwich" Pyridine-Imine Nickel Complexes Organometallics. 35: 1756-1760. DOI: 10.1021/Acs.Organomet.6B00165 |
0.791 |
|
| 2016 |
Yao W, Jia X, Leng X, Goldman AS, Brookhart M, Huang Z. Catalytic alkane transfer-dehydrogenation by PSCOP iridium pincer complexes Polyhedron. 116: 12-19. DOI: 10.1016/J.Poly.2016.02.044 |
0.758 |
|
| 2016 |
Bolig AD, Lyons TW, DiSalvo DT, Brookhart M. Intramolecular hydrogen transfer reactions catalyzed by pentamethylcyclopentadienyl rhodium and cobalt olefin complexes: Mechanistic studies Polyhedron. 103: 51-57. DOI: 10.1016/j.poly.2015.07.076 |
0.308 |
|
| 2015 |
Chen Z, Mesgar M, White PS, Daugulis O, Brookhart M. Synthesis of branched ultrahigh-molecular-weight polyethylene using highly active neutral, single-component Ni(II) catalysts Acs Catalysis. 5: 631-636. DOI: 10.1021/Cs501948D |
0.804 |
|
| 2015 |
Allen KE, Campos J, Daugulis O, Brookhart M. Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using "Sandwich" Diimine Palladium Catalysts Acs Catalysis. 5: 456-464. DOI: 10.1021/Cs5016029 |
0.794 |
|
| 2015 |
Turlington CR, White PS, Brookhart M, Templeton JL. Sequential Nitrene Transfers to an Organometallic Half-Sandwich Iridium Complex Organometallics. 34: 4810-4812. DOI: 10.1021/Acs.Organomet.5B00717 |
0.619 |
|
| 2015 |
Lyons TW, Bézier D, Brookhart M. Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor Organometallics. 34: 4058-4062. DOI: 10.1021/Acs.Organomet.5B00501 |
0.425 |
|
| 2015 |
Kang P, Chen Z, Brookhart M, Meyer TJ. Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work Topics in Catalysis. 58: 30-45. DOI: 10.1007/S11244-014-0344-Y |
0.361 |
|
| 2014 |
Cheng C, Kim BG, Guironnet D, Brookhart M, Guan C, Wang DY, Krogh-Jespersen K, Goldman AS. Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle. Journal of the American Chemical Society. 136: 6672-83. PMID 24746026 DOI: 10.1021/Ja501572G |
0.824 |
|
| 2014 |
Turlington CR, White PS, Brookhart M, Templeton JL. Oxygen atom transfer to a half-sandwich iridium complex: clean oxidation yielding a molecular product. Journal of the American Chemical Society. 136: 3981-94. PMID 24571611 DOI: 10.1021/Ja413023F |
0.586 |
|
| 2014 |
Turlington CR, Morris J, White PS, Brennessel WW, Jones WD, Brookhart M, Templeton JL. Exploring oxidation of half-sandwich rhodium complexes: Oxygen atom insertion into the rhodium-carbon bond of κ2-coordinated 2-phenylpyridine Organometallics. 33: 4442-4448. DOI: 10.1021/Om500660N |
0.658 |
|
| 2014 |
Bézier D, Brookhart M. Applications of PC(sp3)P iridium complexes in transfer dehydrogenation of alkanes Acs Catalysis. 4: 3411-3420. DOI: 10.1021/Cs500892P |
0.472 |
|
| 2014 |
Gruhn NE, Goldberg KI, Brookhart M. Virtual issue on research in the center for enabling new technologies through catalysis (CENTC) Acs Catalysis. 4: 1318-1319. DOI: 10.1021/Cs500312Z |
0.511 |
|
| 2014 |
Turlington CR, White PS, Brookhart M, Templeton JL. Half-sandwich Rh(Cp*) and Ir(Cp*) complexes with oxygen atom transfer reagents as ligands Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.02.007 |
0.581 |
|
| 2013 |
Turlington CR, Harrison DP, White PS, Brookhart M, Templeton JL. Probing the oxidation chemistry of half-sandwich iridium complexes with oxygen atom transfer reagents. Inorganic Chemistry. 52: 11351-60. PMID 24063760 DOI: 10.1021/Ic4016405 |
0.628 |
|
| 2013 |
Walter MD, White PS, Schauer CK, Brookhart M. Stability and dynamic processes in 16VE iridium(III) ethyl hydride and rhodium(I) σ-ethane complexes: experimental and computational studies. Journal of the American Chemical Society. 135: 15933-47. PMID 24053635 DOI: 10.1021/Ja4079539 |
0.644 |
|
| 2013 |
Lyons TW, Brookhart M. Cobalt-catalyzed hydrosilation/hydrogen-transfer cascade reaction: a new route to silyl enol ethers. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 10124-7. PMID 23780615 DOI: 10.1002/Chem.201301502 |
0.412 |
|
| 2013 |
Bézier D, Park S, Brookhart M. Selective reduction of carboxylic acids to aldehydes catalyzed by B(C6F5)3. Organic Letters. 15: 496-9. PMID 23317512 DOI: 10.1021/Ol303296A |
0.356 |
|
| 2013 |
Campos J, Kundu S, Pahls DR, Brookhart M, Carmona E, Cundari TR. Mechanism of hydrogenolysis of an iridium-methyl bond: evidence for a methane complex intermediate. Journal of the American Chemical Society. 135: 1217-20. PMID 23311932 DOI: 10.1021/Ja310982V |
0.699 |
|
| 2013 |
Wingard LA, Finniss MC, Norris M, White PS, Brookhart M, Templeton JL. Synthesis, structure, and reactivity of iridium(III) complexes containing a 4,6-dimethyl-1,3-benzenediphenylimine pincer ligand. Inorganic Chemistry. 52: 515-26. PMID 23265184 DOI: 10.1021/Ic302589B |
0.568 |
|
| 2013 |
Kang P, Meyer TJ, Brookhart M. Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst Chemical Science. 4: 3497-3502. DOI: 10.1039/C3Sc51339D |
0.415 |
|
| 2013 |
Walter MD, White PS, Brookhart M. Synthesis, structure and computational studies of a cationic T-shaped Pd-complex New Journal of Chemistry. 37: 1128-1133. DOI: 10.1039/C3Nj41145A |
0.37 |
|
| 2013 |
Zhang D, Nadres ET, Brookhart M, Daugulis O. Synthesis of highly branched polyethylene using "sandwich" (8-p-tolyl naphthyl α-diimine)nickel(II) catalysts Organometallics. 32: 5136-5143. DOI: 10.1021/Om400704H |
0.83 |
|
| 2013 |
Campos J, Peloso R, Brookhart M, Carmona E. A cationic terminal methylene complex of Ir(I) supported by a pincer ligand Organometallics. 32: 3423-3426. DOI: 10.1021/Om400383S |
0.634 |
|
| 2013 |
Nawara-Hultzsch AJ, Hackenberg JD, Punji B, Supplee C, Emge TJ, Bailey BC, Schrock RR, Brookhart M, Goldman AS. Rational design of highly active "hybrid" phosphine-phosphinite pincer iridium catalysts for alkane metathesis Acs Catalysis. 3: 2505-2514. DOI: 10.1021/Cs400624C |
0.772 |
|
| 2013 |
Kundu S, Lyons TW, Brookhart M. Synthesis of piperylene and toluene via transfer dehydrogenation of pentane and pentene Acs Catalysis. 3: 1768-1773. DOI: 10.1021/Cs400398W |
0.602 |
|
| 2012 |
Lyons TW, Guironnet D, Findlater M, Brookhart M. Synthesis of p-xylene from ethylene. Journal of the American Chemical Society. 134: 15708-11. PMID 22934909 DOI: 10.1021/Ja307612B |
0.789 |
|
| 2012 |
Cheng C, Brookhart M. Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane. Journal of the American Chemical Society. 134: 11304-7. PMID 22770123 DOI: 10.1021/ja304547s |
0.317 |
|
| 2012 |
Park S, Bézier D, Brookhart M. An efficient iridium catalyst for reduction of carbon dioxide to methane with trialkylsilanes. Journal of the American Chemical Society. 134: 11404-7. PMID 22765847 DOI: 10.1021/Ja305318C |
0.413 |
|
| 2012 |
Biswas S, Huang Z, Choliy Y, Wang DY, Brookhart M, Krogh-Jespersen K, Goldman AS. Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations. Journal of the American Chemical Society. 134: 13276-95. PMID 22765770 DOI: 10.1021/Ja301464C |
0.757 |
|
| 2012 |
Haibach MC, Kundu S, Brookhart M, Goldman AS. Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry. Accounts of Chemical Research. 45: 947-58. PMID 22584036 DOI: 10.1021/Ar3000713 |
0.765 |
|
| 2012 |
Kang P, Cheng C, Chen Z, Schauer CK, Meyer TJ, Brookhart M. Selective electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complexes. Journal of the American Chemical Society. 134: 5500-3. PMID 22390391 DOI: 10.1021/Ja300543S |
0.441 |
|
| 2012 |
Findlater M, Schultz KM, Bernskoetter WH, Cartwright-Sykes A, Heinekey DM, Brookhart M. Dihydrogen complexes of iridium and rhodium. Inorganic Chemistry. 51: 4672-8. PMID 22364621 DOI: 10.1021/Ic202630X |
0.762 |
|
| 2012 |
Park S, Brookhart M. Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines. Journal of the American Chemical Society. 134: 640-53. PMID 22091749 DOI: 10.1021/Ja209567M |
0.48 |
|
| 2012 |
Cheng C, Brookhart M. Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane Journal of the American Chemical Society. 134: 11304-11307. DOI: 10.1021/Ja304547S |
0.43 |
|
| 2012 |
Park S, Kim BG, Göttker-Schnetmann I, Brookhart M. Redistribution of trialkyl silanes catalyzed by iridium silyl complexes Acs Catalysis. 2: 307-316. DOI: 10.1021/Cs200629T |
0.462 |
|
| 2012 |
Cheng C, Brookhart M. Efficient reduction of esters to aldehydes through iridium-catalyzed hydrosilylation Angewandte Chemie - International Edition. 51: 9422-9424. DOI: 10.1002/Anie.201205154 |
0.345 |
|
| 2011 |
Chen Z, Chen C, Weinberg DR, Kang P, Concepcion JJ, Harrison DP, Brookhart MS, Meyer TJ. Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes. Chemical Communications (Cambridge, England). 47: 12607-9. PMID 21998823 DOI: 10.1039/C1Cc15071E |
0.396 |
|
| 2011 |
Findlater M, Cartwright-Sykes A, White PS, Schauer CK, Brookhart M. Role of coordination geometry in dictating the barrier to hydride migration in d6 square-pyramidal iridium and rhodium pincer complexes. Journal of the American Chemical Society. 133: 12274-84. PMID 21702471 DOI: 10.1021/Ja204851X |
0.718 |
|
| 2011 |
Cheng C, Guironnet D, Barborak J, Brookhart M. Preparation and characterization of conjugated polymers made by postpolymerization reactions of alternating polyketones. Journal of the American Chemical Society. 133: 9658-61. PMID 21615113 DOI: 10.1021/Ja202361K |
0.787 |
|
| 2011 |
Cochrane NA, Brookhart MS, Gagné MR. Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors. Organometallics. 30: 2457-2460. PMID 21572581 DOI: 10.1021/Om2001958 |
0.397 |
|
| 2011 |
Choi J, MacArthur AH, Brookhart M, Goldman AS. Dehydrogenation and related reactions catalyzed by iridium pincer complexes. Chemical Reviews. 111: 1761-79. PMID 21391566 DOI: 10.1021/Cr1003503 |
0.7 |
|
| 2011 |
Vicente BC, Huang Z, Brookhart M, Goldman AS, Scott SL. Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes. Dalton Transactions (Cambridge, England : 2003). 40: 4268-74. PMID 21384048 DOI: 10.1039/C0Dt01369B |
0.767 |
|
| 2011 |
Park S, Brookhart M. Hydrosilylation of epoxides catalyzed by a cationic η1- silane iridium(iii) complex Chemical Communications. 47: 3643-3645. PMID 21321708 DOI: 10.1039/C0Cc05714B |
0.435 |
|
| 2011 |
Ahuja R, Punji B, Findlater M, Supplee C, Schinski W, Brookhart M, Goldman AS. Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes. Nature Chemistry. 3: 167-71. PMID 21258391 DOI: 10.1038/Nchem.946 |
0.798 |
|
| 2011 |
Walter MD, White PS, Schauer CK, Brookhart M. The quest for stable σ-methane complexes: Computational and experimental studies New Journal of Chemistry. 35: 2884-2893. DOI: 10.1039/C1Nj20602H |
0.43 |
|
| 2011 |
Cheng C, Guironnet D, Barborak J, Brookhart M. Preparation and characterization of conjugated polymers made by postpolymerization reactions of alternating polyketones Journal of the American Chemical Society. 133: 9658-9661. DOI: 10.1021/ja202361k |
0.79 |
|
| 2011 |
Urbin SA, Pintauer T, White P, Brookhart M. Synthesis, characterization, and reactivity of (π-allyl)palladium(II) wrap-around complexes with 1,3-dienes Inorganica Chimica Acta. 369: 150-158. DOI: 10.1016/J.Ica.2010.12.046 |
0.821 |
|
| 2011 |
Goldman AS, Krogh-Jespersen K, Brookhart M. Dehydrogenation and related reactions of alkanes catalyzed by pincerâ-iridium complexes Acs National Meeting Book of Abstracts. |
0.674 |
|
| 2010 |
Park S, Brookhart M. Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) Complex. Organometallics. 29: 6057-6064. PMID 21572562 DOI: 10.1021/Om100818Y |
0.474 |
|
| 2010 |
Huang Z, White PS, Brookhart M. Ligand exchanges and selective catalytic hydrogenation in molecular single crystals. Nature. 465: 598-601. PMID 20520710 DOI: 10.1038/Nature09085 |
0.458 |
|
| 2010 |
Findlater M, Bernskoetter WH, Brookhart M. Proton-catalyzed hydrogenation of a d(8) Ir(I) complex yields a trans Ir(III) dihydride. Journal of the American Chemical Society. 132: 4534-5. PMID 20232913 DOI: 10.1021/Ja100168W |
0.812 |
|
| 2010 |
Bochmann M, Brookhart M, Gladysz JA, Lichtenberger DL, Liebeskind LS, Marks TJ, Schrock RR, Sweigart DA, Whitmire KH. Dedication to the special volume for Dietmar Seyferth Organometallics. 29: 4647. DOI: 10.1021/Om100975M |
0.553 |
|
| 2010 |
Park S, Brookhart M. Hydrosilylation of carbonyl-containing substrates catalyzed by an electrophilic η1-silane iridium(III) complex Organometallics. 29: 6057-6064. DOI: 10.1021/om100818y |
0.327 |
|
| 2010 |
O'Connor AR, White PS, Brookhart M. Synthesis, characterization, and reactivity studies of (cyclohexenyl) nickel(ii) complexes Organometallics. 29: 5382-5389. DOI: 10.1021/Om100391V |
0.724 |
|
| 2010 |
O'Connor AR, Brookhart M. Polymerization of 1,3-dienes and styrene catalyzed by cationic allyl ni(II) complexes Journal of Polymer Science, Part a: Polymer Chemistry. 48: 1901-1912. DOI: 10.1002/Pola.23955 |
0.716 |
|
| 2010 |
Huang Z, Rolfe E, Carson EC, Brookhart M, Goldman AS, El-Khalafy SH, Roy MacArthur AH. Efficient heterogeneous dual catalyst systems for alkane metathesis Advanced Synthesis and Catalysis. 352: 125-135. DOI: 10.1002/Adsc.200900539 |
0.736 |
|
| 2009 |
Bernskoetter WH, Schauer CK, Goldberg KI, Brookhart M. Characterization of a rhodium(I) sigma-methane complex in solution. Science (New York, N.Y.). 326: 553-6. PMID 19900892 DOI: 10.1126/Science.1177485 |
0.765 |
|
| 2009 |
Walter MD, White PS, Brookhart M. Gamma-agostic interactions stabilize the propagating species in the vinyl addition polymerization of norbornene. Chemical Communications (Cambridge, England). 6361-3. PMID 19841777 DOI: 10.1039/B916457J |
0.577 |
|
| 2009 |
Rix FC, Rachita MJ, Wagner MI, Brookhart M, Milani B, Barborak JC. Palladium(II)-catalyzed copolymerization of styrenes with carbon monoxide: mechanism of chain propagation and chain transfer. Dalton Transactions (Cambridge, England : 2003). 8977-92. PMID 19826731 DOI: 10.1039/b911392d |
0.311 |
|
| 2009 |
Bernskoetter WH, Hanson SK, Buzak SK, Davis Z, White PS, Swartz R, Goldberg KI, Brookhart M. Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex. Journal of the American Chemical Society. 131: 8603-13. PMID 19489584 DOI: 10.1021/Ja901706B |
0.778 |
|
| 2009 |
Walter MD, Moorhouse RA, Urbin SA, White PS, Brookhart M. Gamma-agostic species as key intermediates in the vinyl addition polymerization of norbornene with cationic (allyl)Pd catalysts: synthesis and mechanistic insights. Journal of the American Chemical Society. 131: 9055-69. PMID 19473005 DOI: 10.1021/Ja9025598 |
0.828 |
|
| 2009 |
Rix FC, Rachita MJ, Wagner MI, Brookhart M, Milani B, Barborak JC. Palladium(ii)-catalyzed copolymerization of styrenes with carbon monoxide: Mechanism of chain propagation and chain transfer Dalton Transactions. 8977-8992. DOI: 10.1039/B911392D |
0.435 |
|
| 2009 |
Kundu S, Choliy Y, Zhuo G, Ahuja R, Emge TJ, Warmuth R, Brookhart M, Krogh-Jespersen K, Goldman AS. Rational design and synthesis of highly active pincer-iridium catalysts for alkane dehydrogenation Organometallics. 28: 5432-5444. DOI: 10.1021/Om900568F |
0.775 |
|
| 2009 |
O'Connor AR, Urbin SA, Moorhouse RA, While PS, Brookhart M. Synthesis and reactivity of cationic (Allyl)(arene)nickel(II) and (Allyl)(arene)palladium(II) complexes Organometallics. 28: 2372-2384. DOI: 10.1021/Om801103P |
0.82 |
|
| 2009 |
Bailey BC, Schrock RR, Kundu S, Goldman AS, Huang Z, Brookhart M. Evaluation of molybdenum and tungsten metathesis catalysts for homogeneous tandem alkane metathesis Organometallics. 28: 355-360. DOI: 10.1021/Om800877Q |
0.804 |
|
| 2009 |
Walter MD, Moorhouse RA, White PS, Brookhart M. Vinyl addition polymerization of norbornene with cationic (allyl)Ni catalysts: Mechanistic insights and characterization of first insertion products Journal of Polymer Science, Part a: Polymer Chemistry. 47: 2560-2573. DOI: 10.1002/Pola.23340 |
0.433 |
|
| 2009 |
Huang Z, Brookhart M, Goldman AS, Kundu S, Ray A, Scott SL, Vicente BC. Highly active and recyclable heterogeneous iridium pincer catalysts for transfer dehydrogenation of alkanes Advanced Synthesis and Catalysis. 351: 188-206. DOI: 10.1002/Adsc.200800615 |
0.786 |
|
| 2009 |
Yang J, Brookhart M. Reduction of alkyl halides by triethylsilane based on a cationic iridium bis(phosphinite) pincer catalyst: Scope, selectivity and mechanism Advanced Synthesis and Catalysis. 351: 175-187. DOI: 10.1002/Adsc.200800528 |
0.495 |
|
| 2009 |
Goldman AS, Brookhart M, Huang Z, Krogh-Jespersen K, Kundu S, Scott SL. Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes: Solution-phase and solid-supported iridium-based pincer catalysts Acs National Meeting Book of Abstracts. |
0.705 |
|
| 2009 |
Biswas S, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. Regioselectivity in the transfer-dehydrogenation of alkanes by two pincer-iridium-based catalysts Acs National Meeting Book of Abstracts. |
0.665 |
|
| 2008 |
Yang J, White PS, Brookhart M. Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane. Journal of the American Chemical Society. 130: 17509-18. PMID 19053420 DOI: 10.1021/Ja806419H |
0.464 |
|
| 2008 |
Yang J, White PS, Schauer CK, Brookhart M. Structural and spectroscopic characterization of an unprecedented cationic transition-metal eta1-silane complex. Angewandte Chemie (International Ed. in English). 47: 4141-3. PMID 18435435 DOI: 10.1002/Anie.200705359 |
0.316 |
|
| 2008 |
Ahuja R, Kundu S, Goldman AS, Brookhart M, Vicente BC, Scott SL. Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. Chemical Communications (Cambridge, England). 253-5. PMID 18092104 DOI: 10.1039/B712197K |
0.751 |
|
| 2008 |
Bernskoetter WH, Brookhart M. Kinetics and mechanism of iridium-catalyzed dehydrogenation of primary amines to nitriles Organometallics. 27: 2036-2045. DOI: 10.1021/Om701148T |
0.709 |
|
| 2008 |
Biswas S, Ahuja R, Ray A, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. A tale of two ligands. Subtle differences in sterics exert major differences in the energetics of alkane dehydrogenation catalyzed by pincer complexes (tBuPCP)Ir vs. (tBuPOCOP)Ir Acs National Meeting Book of Abstracts. |
0.68 |
|
| 2007 |
Bolig AD, Brookhart M. Activation of sp3 C-H bonds with cobalt(I): Catalytic synthesis of enamines Journal of the American Chemical Society. 129: 14544-14545. PMID 17985901 DOI: 10.1021/Ja075694R |
0.42 |
|
| 2007 |
Yang J, Brookhart M. Iridium-catalyzed reduction of alkyl halides by triethylsilane. Journal of the American Chemical Society. 129: 12656-7. PMID 17900122 DOI: 10.1021/ja075725i |
0.3 |
|
| 2007 |
Brookhart M, Green ML, Parkin G. Agostic interactions in transition metal compounds. Proceedings of the National Academy of Sciences of the United States of America. 104: 6908-14. PMID 17442749 DOI: 10.1073/Pnas.0610747104 |
0.615 |
|
| 2007 |
O'Connor AR, White PS, Brookhart M. The mechanism of polymerization of butadiene by "ligand-free" nickel(II) complexes. Journal of the American Chemical Society. 129: 4142-3. PMID 17371029 DOI: 10.1021/Ja070364S |
0.737 |
|
| 2007 |
Shiotsuki M, White PS, Brookhart M, Templeton JL. Mechanistic studies of platinum(II)-catalyzed ethylene dimerization: determination of barriers to migratory insertion in diimine Pt(II) hydrido ethylene and ethyl ethylene intermediates. Journal of the American Chemical Society. 129: 4058-67. PMID 17346046 DOI: 10.1021/Ja068118O |
0.615 |
|
| 2007 |
Roy AH, Lenges CP, Brookhart M. Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes. Journal of the American Chemical Society. 129: 2082-93. PMID 17263531 DOI: 10.1021/Ja066509X |
0.489 |
|
| 2007 |
Doherty MD, Grant B, White PS, Brookhart M. Reactions of H 2 and R 3SiH with electrophilic cobalt(III) alkyl complexes: Spectroscopic characterization, dynamics, and chemistry of [Cp*Co(L)(H)(η 2-H 2)][B(Ar F) 4] and [Cp*Co(L)(H)η 2-HSiR 3][B(Ar F) 4] Organometallics. 26: 5950-5960. DOI: 10.1021/Om700620W |
0.667 |
|
| 2007 |
Doherty MD, Trudeau S, White PS, Morken JP, Brookhart M. Ethylene oligomerization catalyzed by a unique phosphine - Oxazoline palladium(II) complex. Propagation and chain transfer mechanisms Organometallics. 26: 1261-1269. DOI: 10.1021/Om061025V |
0.72 |
|
| 2007 |
McCord EF, McLain SJ, Nelson LTJ, Ittel SD, Tempel D, Killian CM, Johnson LK, Brookhart M. 13C NMR analysis of α-olefin enchainment in poly(α-olefins) produced with nickel and palladium α-diimine catalysts Macromolecules. 40: 410-420. DOI: 10.1021/Ma061547M |
0.426 |
|
| 2007 |
Yang J, Brookhart M. Iridium-catalyzed reduction of alkyl halides by triethylsilane Journal of the American Chemical Society. 129: 12656-12657. DOI: 10.1021/Ja075725I |
0.444 |
|
| 2007 |
Domski GJ, Rose JM, Coates GW, Bolig AD, Brookhart M. Living alkene polymerization: New methods for the precision synthesis of polyolefins Progress in Polymer Science (Oxford). 32: 30-92. DOI: 10.1016/J.Progpolymsci.2006.11.001 |
0.332 |
|
| 2006 |
Sykes AC, White P, Brookhart M. Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I) Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base Coordination. Organometallics. 25: 1664-1675. PMID 19079781 DOI: 10.1021/Om051070N |
0.809 |
|
| 2006 |
Göttker-Schnetmann I, Heinekey DM, Brookhart M. Temperature- and solvent-dependent binding of dihydrogen in iridium pincer complexes. Journal of the American Chemical Society. 128: 17114-9. PMID 17177464 DOI: 10.1021/Ja065854J |
0.406 |
|
| 2006 |
Goldman AS, Roy AH, Huang Z, Ahuja R, Schinski W, Brookhart M. Catalytic alkane metathesis by tandem alkane dehydrogenation-olefin metathesis. Science (New York, N.Y.). 312: 257-61. PMID 16614220 DOI: 10.1126/Science.1123787 |
0.722 |
|
| 2006 |
Schrekker HS, Kotov V, Preishuber-Pflugl P, White P, Brookhart M. Efficient slurry-phase homopolymerization of ethylene to branched polyethylenes using α-diimine nickel(II) catalysts covalently linked to silica supports Macromolecules. 39: 6341-6354. DOI: 10.1021/Ma061032V |
0.413 |
|
| 2005 |
Williams BS, Leatherman MD, White PS, Brookhart M. Reactions of vinyl acetate and vinyl trifluoroacetate with cationic diimine Pd(II) and Ni(II) alkyl complexes: identification of problems connected with copolymerizations of these monomers with ethylene. Journal of the American Chemical Society. 127: 5132-46. PMID 15810848 DOI: 10.1021/Ja045969S |
0.807 |
|
| 2005 |
Díaz-Requejo MM, Wehrmann P, Leatherman MD, Trofimenko S, Mecking S, Brookhart M, Pérez PJ. Controlled, copper-catalyzed functionalization of polyolefins Macromolecules. 38: 4966-4969. DOI: 10.1021/Ma050626F |
0.752 |
|
| 2004 |
Göttker-Schnetmann I, Brookhart M. Mechanistic studies of the transfer dehydrogenation of cyclooctane catalyzed by iridium bis(phosphinite) p-XPCP pincer complexes Journal of the American Chemical Society. 126: 9330-9338. PMID 15281824 DOI: 10.1021/Ja048393F |
0.325 |
|
| 2004 |
Jenkins JC, Brookhart M. A mechanistic investigation of the polymerization of ethylene catalyzed by neutral Ni(II) complexes derived from bulky anilinotropone ligands. Journal of the American Chemical Society. 126: 5827-42. PMID 15125675 DOI: 10.1021/Ja030634G |
0.713 |
|
| 2004 |
Göttker-Schnetmann I, White P, Brookhart M. Iridium Bis(phosphinite) p-XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes Journal of the American Chemical Society. 126: 1804-1811. PMID 14871112 DOI: 10.1021/Ja0385235 |
0.374 |
|
| 2004 |
Liu W, Brookhart M. Mechanistic studies of palladium(II)-a-diimine-catalyzed polymerizations of cis- and trans-2-butenes Organometallics. 23: 6099-6107. DOI: 10.1021/Om040077M |
0.422 |
|
| 2004 |
Taw FL, Bergman RG, Brookhart M. Silicon-hydrogen bond activation and formation of silane complexes using a cationic rhodium(III) complex Organometallics. 23: 886-890. DOI: 10.1021/Om0341303 |
0.825 |
|
| 2004 |
Göttker-Schnetmann I, White PS, Brookhart M. Synthesis and Properties of Iridium Bis(phosphinite) Pincer Complexes (p-XPCP)IrH 2, (p-XPCP)Ir(CO), (p-XPCP)Ir(H)(aryl), and {(p-XPCP)Ir}H 2{μ-N 2} and Their Relevance in Alkane Transfer Dehydrogenation Organometallics. 23: 1766-1776. DOI: 10.1021/Om030670O |
0.417 |
|
| 2004 |
Daugulis O, Brookhart M. Decarbonylation of aryl ketones mediated by bulky cyclopentadienylrhodium Bis(ethylene) complexes Organometallics. 23: 527-534. DOI: 10.1021/Om030563U |
0.785 |
|
| 2004 |
Corkey BK, Taw FL, Bergman RG, Brookhart M. Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition Polyhedron. 23: 2943-2954. DOI: 10.1016/J.Poly.2004.09.005 |
0.816 |
|
| 2003 |
Taw FL, Mueller AH, Bergman RG, Brookhart M. A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. Journal of the American Chemical Society. 125: 9808-13. PMID 12904046 DOI: 10.1021/Ja034468O |
0.815 |
|
| 2003 |
Leatherman MD, Svejda SA, Johnson LK, Brookhart M. Mechanistic studies of nickel(II) alkyl agostic cations and alkyl ethylene complexes: investigations of chain propagation and isomerization in (alpha-diimine)Ni(II)-catalyzed ethylene polymerization. Journal of the American Chemical Society. 125: 3068-81. PMID 12617674 DOI: 10.1021/Ja021071W |
0.839 |
|
| 2003 |
Diaz-Requejo MM, DiSalvo D, Brookhart M. Synthesis of 1,2-diheteroatom-substituted alkenes via rhodium-catalyzed intramolecular hydrogen transfer. Journal of the American Chemical Society. 125: 2038-9. PMID 12590518 DOI: 10.1021/Ja029393N |
0.767 |
|
| 2003 |
Daugulis O, Brookhart M, White PS. Ethylene polymerization using tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of cobalt Organometallics. 22: 4699-4704. DOI: 10.1021/Om030414B |
0.782 |
|
| 2003 |
Malinoski JM, Brookhart M. Polymerization and Oligomerization of Ethylene by Cationic Nickel (II) and Palladium(II) Complexes Containing Bidentate Phenacyldiarylphosphine Ligands Organometallics. 22: 5324-5335. DOI: 10.1021/Om030388H |
0.823 |
|
| 2003 |
Hicks FA, Jenkins JC, Brookhart M. Synthesis and ethylene polymerization activity of a series of 2-anilinotropone-based neutral nickel(II) catalysts Organometallics. 22: 3533-3545. DOI: 10.1021/Om030142C |
0.696 |
|
| 2003 |
Malinoski JM, White PS, Brookhart M. Structural characterization of [κ2-(t-Bu)2PCH2C(O)C6 H5]PdMe(η2-C2H4)+ BAr′4-: A model for the catalyst resting state for ethylene polymerization Organometallics. 22: 621-623. DOI: 10.1021/Om020951G |
0.798 |
|
| 2003 |
Jenkins JC, Brookhart M. A highly active anilinoperinaphthenone-based neutral nickel(II) catalyst for ethylene polymerization Organometallics. 22: 250-256. DOI: 10.1021/Om020648F |
0.701 |
|
| 2003 |
Gottfried AC, Brookhart M. Living and block copolymerization of ethylene and α-olefins using palladium(II)-α-diimine catalysts Macromolecules. 36: 3085-3100. DOI: 10.1021/Ma025902U |
0.832 |
|
| 2002 |
Taw FL, Mellows H, White PS, Hollander FJ, Bergman RG, Brookhart M, Heinekey DM. Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. Journal of the American Chemical Society. 124: 5100-8. PMID 11982375 DOI: 10.1021/Ja0165990 |
0.801 |
|
| 2002 |
Taw FL, White PS, Bergman RG, Brookhart M. Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. Journal of the American Chemical Society. 124: 4192-3. PMID 11960431 DOI: 10.1021/Ja0255094 |
0.796 |
|
| 2002 |
Daugulis O, Brookhart M, White PS. Phosphinidine-palladium complexes for the polymerization and oligomerization of ethylene Organometallics. 21: 5935-5943. DOI: 10.1021/Om020631X |
0.795 |
|
| 2002 |
Daugulis O, Brookhart M. Polymerization of ethylene with cationic palladium and nickel catalysts containing bulky nonenolizable imine-phosphine ligands Organometallics. 21: 5926-5934. DOI: 10.1021/Om0206305 |
0.802 |
|
| 2002 |
Liu W, Malinoski JM, Brookhart M. Ethylene polymerization and ethylene/methyl 10-undecenoate copolymerization using nickel(II) and palladium(II) complexes derived from a bulky P,O chelating ligand Organometallics. 21: 2836-2838. DOI: 10.1021/Om0201516 |
0.811 |
|
| 2002 |
Reinartz S, Brookhart M, Templeton JL. Platinum(II) and platinum(IV) acyl and formyl complexes Organometallics. 21: 247-249. DOI: 10.1021/Om010772J |
0.614 |
|
| 2002 |
Preishuber-Pflugl P, Brookhart M. Highly Active Supported Nickel Diimine Catalysts for Polymerization of Ethylene Macromolecules. 35: 6074-6076. DOI: 10.1021/Ma020230T |
0.398 |
|
| 2002 |
Hong SC, Jia S, Teodorescu M, Kowalewski T, Matyjaszewski K, Gottfried AC, Brookhart M. Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n-butyl acrylate)-graft-polyethylene through the combination of Pd-mediated living olefin polymerization and atom transfer radical polymerization Journal of Polymer Science, Part a: Polymer Chemistry. 40: 2736-2749. DOI: 10.1002/Pola.10348 |
0.794 |
|
| 2001 |
Reinartz S, White PS, Brookhart M, Templeton JL. Structural characterization of an intermediate in arene C-H bond activation and measurement of the barrier to C-H oxidative addition: a platinum(II) eta(2)-benzene adduct. Journal of the American Chemical Society. 123: 12724-5. PMID 11741456 DOI: 10.1021/Ja011765P |
0.561 |
|
| 2001 |
Shultz LH, Tempel DJ, Brookhart M. Palladium(II) beta-agostic alkyl cations and alkyl ethylene complexes: investigation of polymer chain isomerization mechanisms. Journal of the American Chemical Society. 123: 11539-55. PMID 11716707 DOI: 10.1021/Ja011055J |
0.505 |
|
| 2001 |
Shultz CS, DeSimone JM, Brookhart M. Four- and five-coordinate CO insertion mechanisms in d(8)-nickel(II) complexes. Journal of the American Chemical Society. 123: 9172-3. PMID 11552830 DOI: 10.1021/Ja0160896 |
0.529 |
|
| 2001 |
Reinartz S, Baik MH, White PS, Brookhart M, Templeton JL. Synthesis, structure, and electronic properties of monomeric and dimeric trispyrazolylborate platinum(II) hydride complexes. Inorganic Chemistry. 40: 4726-32. PMID 11511222 DOI: 10.1021/Ic010099Q |
0.633 |
|
| 2001 |
Dias EL, Brookhart M, White PS. Rhodium(I)-catalyzed homologation of aromatic aldehydes with trimethylsilyldiazomethane. Journal of the American Chemical Society. 123: 2442-3. PMID 11456901 DOI: 10.1021/Ja003608G |
0.366 |
|
| 2001 |
Reinartz S, White PS, Brookhart M, Templeton JL. Five-coordinate trispyrazolylborate dihydridosilyl platinum(IV) complexes. Journal of the American Chemical Society. 123: 6425-6. PMID 11427073 DOI: 10.1021/Ja0104047 |
0.598 |
|
| 2001 |
Dias EL, Brookhart M, White PS. Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions Chemical Communications. 423-424. DOI: 10.1039/B007815H |
0.457 |
|
| 2001 |
Ledford J, Shultz CS, Gates DP, White PS, DeSimone JM, Brookhart M. Bond angle effects on the migratory insertion of ethylene and carbon monoxide into palladium(II)-methyl bonds in complexes bearing bidentate phosphine ligands Organometallics. 20: 5266-5276. DOI: 10.1021/Om010489K |
0.45 |
|
| 2001 |
Hicks FA, Brookhart M. A highly active anilinotropone-based neutral nickel(II) catalyst for ethylene polymerization Organometallics. 20: 3217-3219. DOI: 10.1021/Om010211S |
0.504 |
|
| 2001 |
and LHS, Brookhart M. Measurement of the Barrier to β-Hydride Elimination in a β-Agostic Palladium−Ethyl Complex: A Model for the Energetics of Chain-Walking in (α-Diimine)PdR+ Olefin Polymerization Catalysts Organometallics. 20: 3975-3982. DOI: 10.1021/Om010197J |
0.436 |
|
| 2001 |
Reinartz S, White PS, Brookhart M, Templeton JL. Syntheses of platinum(IV) aryl dihydride complexes via arene C-H bond activation Organometallics. 20: 1709-1712. DOI: 10.1021/Om001029E |
0.642 |
|
| 2001 |
Shultz CS, DeSimone JM, Brookhart M. Cationic Four- and Five-Coordinate Nickel(II) Complexes: Insights into the Nickel(II)-Catalyzed Copolymerization of Ethylene and Carbon Monoxide Organometallics. 20: 16-18. DOI: 10.1021/Om0008023 |
0.597 |
|
| 2001 |
Leatherman MD, Brookhart M. Ni(II)-catalyzed polymerization of trans-2-butene [4] Macromolecules. 34: 2748-2750. DOI: 10.1021/Ma002142J |
0.8 |
|
| 2001 |
Gottfried AC, Brookhart M. Living polymerization of ethylene using Pd(II) α-diimine catalysts Macromolecules. 34: 1140-1142. DOI: 10.1021/Ma001595L |
0.808 |
|
| 2001 |
Mccord EF, Mclain SJ, Nelson LTJ, Arthur SD, Coughlin EB, Ittel SD, Johnson LK, Tempel D, Killian CM, Brookhart M. 13C and 2D NMR Analysis of Propylene Polymers Made with α-Diimine Late Metal Catalysts† Macromolecules. 34: 362-371. DOI: 10.1021/Ma0012898 |
0.413 |
|
| 2001 |
Brookhart M, Johnnson LK, Killian CM, Svejda SA, Gates D, Tempel DJ, Huff RL, Leatherman MD. Olefin polymerizations using cationic Ni(II) and Pd(II) diimine complexes Macromolecular Symposia. 174: 29-30. DOI: 10.1002/1521-3900(200109)174:1<29::Aid-Masy29>3.0.Co;2-Y |
0.807 |
|
| 2001 |
Böhm VPW, Brookhart M. Rhodium(I)‐katalysierte Dehydrokupplung von Phosphanen Angewandte Chemie. 113: 4832-4834. DOI: 10.1002/1521-3757(20011217)113:24<4832::Aid-Ange4832>3.0.Co;2-V |
0.338 |
|
| 2000 |
Ittel SD, Johnson LK, Brookhart M. Late-metal catalysts for ethylene homo- and copolymerization. Chemical Reviews. 100: 1169-204. PMID 11749263 DOI: 10.1021/Cr9804644 |
0.352 |
|
| 2000 |
Brookhart M, Grant BE, Lenges CP, Prosenc MH, White PS. High Oxidation State Organocobalt Complexes: Synthesis and Characterization of Dihydridodisilyl Cobalt(V) Species Angewandte Chemie. 39: 1676-1679. PMID 10820474 DOI: 10.1002/(Sici)1521-3773(20000502)39:9<1676::Aid-Anie1676>3.0.Co;2-M |
0.322 |
|
| 2000 |
Hicks FA, Brookhart M. Synthesis of 2-anilinotropones via palladium-catalyzed amination of 2-triflatotropone Organic Letters. 2: 219-21. PMID 10814286 DOI: 10.1021/Ol991310T |
0.352 |
|
| 2000 |
Gates DP, White PS, Brookhart M. The insertion of sulfur dioxide into palladium–methyl bonds: the synthesis and X-ray crystal structure of an unusual [(dppp)PdOS(Me)O]2[BAr′4]2 dimer Chemical Communications. 47-48. DOI: 10.1039/A905993H |
0.365 |
|
| 2000 |
Lenges CP, White PS, Marshall aWJ, Brookhart M. Synthesis, Structure, and Reactivity of [C5Me5CoLL‘] Complexes with L = Pyridine and L‘ = Olefin or L−L‘ = Bipyridine Organometallics. 19: 1247-1254. DOI: 10.1021/Om990860S |
0.436 |
|
| 2000 |
Reinartz S, White PS, Brookhart M, Templeton JL. Acid-assisted reductive elimination as a route to platinum(II) products from platinum(IV) tris(pyrazolyl)borate reagents Organometallics. 19: 3854-3866. DOI: 10.1021/Om000440Z |
0.596 |
|
| 2000 |
Reinartz S, White PS, Brookhart M, Templeton JL. Tp′PtH3: a stable platinum(IV) trihydride Organometallics. 19: 3748-3750. DOI: 10.1021/Om000406K |
0.608 |
|
| 2000 |
Yagyu T, Osakada K, Brookhart M. Single and Multiple Insertion of Carbon−Carbon Triple Bonds into the Palladium−Aryl Bond of Cationic and Neutral Arylpalladium Complexes with a 2,2‘-Bipyridine Ligand Organometallics. 19: 2125-2129. DOI: 10.1021/Om0000360 |
0.366 |
|
| 2000 |
Gates DP, Svejda SA, Oñate E, Killian CM, Johnson LK, White PS, Brookhart M. Synthesis of Branched Polyethylene Using (α-Diimine)nickel(II) Catalysts: Influence of Temperature, Ethylene Pressure, and Ligand Structure on Polymer Properties Macromolecules. 33: 2320-2334. DOI: 10.1021/Ma991234+ |
0.416 |
|
| 2000 |
Shultz CS, Ledford J, DeSimone JM, Brookhart M. Kinetic studies of migratory insertion reactions at the (1,3- bis(diphenylphosphino)propane)Pd(II) center and their relationship to the alternating copolymerization of ethylene and carbon monoxide Journal of the American Chemical Society. 122: 6351-6356. DOI: 10.1021/Ja994251N |
0.561 |
|
| 2000 |
Tempel DJ, Johnson LK, Huff RL, White PS, Brookhart M. Mechanistic studies of Pd(II)-α-diimine-catalyzed olefin polymerizations Journal of the American Chemical Society. 122: 6686-6700. DOI: 10.1021/Ja000893V |
0.45 |
|
| 2000 |
Rachita MJ, Huff RL, Bennett JL, Brookhart M. Oligomerization of ethylene to branched alkenes using neutral phosphinosulfonamide nickel(II) complexes Journal of Polymer Science Part A. 38: 4627-4640. DOI: 10.1002/1099-0518(200012)38:1+<4627::Aid-Pola20>3.0.Co;2-9 |
0.504 |
|
| 1999 |
Lenges CP, Brookhart M, White PS. Structure and Reactivity of a Cobalt(I) Phthalaldehyde Complex with Both σ- and π-Bonded Aldehyde Groups. Angewandte Chemie (International Ed. in English). 38: 552-555. PMID 29711779 DOI: 10.1002/(Sici)1521-3773(19990215)38:4<552::Aid-Anie552>3.0.Co;2-B |
0.433 |
|
| 1999 |
Lenges CP, Brookhart M. Isomerization of Aldehydes Catalyzed by Rhodium(I) Olefin Complexes. Angewandte Chemie. 38: 3533-3537. PMID 10602233 DOI: 10.1002/(Sici)1521-3773(19991203)38:23<3533::Aid-Anie3533>3.0.Co;2-E |
0.445 |
|
| 1999 |
Svejda SA, Brookhart M. Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts Organometallics. 18: 65-74. DOI: 10.1021/Om980736T |
0.492 |
|
| 1999 |
Small BL, Brookhart M. Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination Macromolecules. 32: 2120-2130. DOI: 10.1021/Ma981698S |
0.441 |
|
| 1999 |
Svejda SA, Johnson LK, Brookhart M. Low-temperature spectroscopic observation of chain growth and migratory insertion barriers in (α-diimine)Ni(II) olefin polymerization catalysts [5] Journal of the American Chemical Society. 121: 10634-10635. DOI: 10.1021/Ja991931H |
0.4 |
|
| 1999 |
Lenges CP, Brookhart M. Addition of Olefins to Aromatic Ketones Catalyzed by Rh(I) Olefin Complexes Journal of the American Chemical Society. 121: 6616-6623. DOI: 10.1021/Ja990702S |
0.507 |
|
| 1999 |
Lenges CP, White PS, Brookhart M. Hydrogen/Deuterium Exchange Reactions and Transfer Hydrogenations Catalyzed by [C5Me5Rh(olefin)2] Complexes: Conversion of Alkoxysilanes to Silyl Enolates† Journal of the American Chemical Society. 121: 4385-4396. DOI: 10.1021/Ja984409O |
0.365 |
|
| 1999 |
Çetinkaya B, Çetinkaya E, Brookhart M, White PS. Ruthenium(II) complexes with 2,6-pyridyl-diimine ligands: synthesis, characterization and catalytic activity in epoxidation reactions Journal of Molecular Catalysis a-Chemical. 142: 101-112. DOI: 10.1016/S1381-1169(98)00285-4 |
0.463 |
|
| 1998 |
Tempel DJ, Brookhart M. The Dynamics of the β-Agostic Isopropyl Complex (ArNC(R)−C(R)NAr)Pd(CH(CH2-μ-H)(CH3))+BAr4‘- (Ar = 2,6-C6H3(i-Pr)2): Evidence for In-Place Rotation versus Dissociation of the Agostic Methyl Group Organometallics. 17: 2290-2296. DOI: 10.1021/Om971137+ |
0.378 |
|
| 1998 |
and AML, Brookhart M. Reactions of Cationic Palladium(II) Methyl and Vinyl Complexes with Alkynes Organometallics. 17: 1530-1537. DOI: 10.1021/Om9710125 |
0.39 |
|
| 1998 |
McLain SJ, Feldman J, McCord EF, Gardner KH, Teasley MF, Coughlin EB, Sweetman KJ, Johnson LK, Brookhart M. Addition Polymerization of Cyclopentene with Nickel and Palladium Catalysts Macromolecules. 31: 6705-6707. DOI: 10.1021/Ma971639Z |
0.42 |
|
| 1998 |
Small BL, Brookhart M. Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins Journal of the American Chemical Society. 120: 7143-7144. DOI: 10.1021/Ja981317Q |
0.339 |
|
| 1998 |
Lenges CP, White aPS, Brookhart M. Mechanistic and Synthetic Studies of the Addition of Alkyl Aldehydes to Vinylsilanes Catalyzed by Co(I) Complexes Journal of the American Chemical Society. 120: 6965-6979. DOI: 10.1021/Ja980610N |
0.446 |
|
| 1998 |
Small BL, Brookhart M, Bennett AMA. Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene Journal of the American Chemical Society. 120: 4049-4050. DOI: 10.1021/Ja9802100 |
0.355 |
|
| 1998 |
Mecking S, Johnson LK, Wang L, Brookhart M. Mechanistic Studies of the Palladium-Catalyzed Copolymerization of Ethylene and α-Olefins with Methyl Acrylate Journal of the American Chemical Society. 120: 888-899. DOI: 10.1021/Ja964144I |
0.72 |
|
| 1998 |
Chang S, Scharrer E, Brookhart M. Catalytic silane alcoholysis based on the C5H5(CO)(PPh3)Fe+ moiety. NMR spectroscopic identification of key intermediates Journal of Molecular Catalysis a-Chemical. 130: 107-119. DOI: 10.1016/S1381-1169(97)00205-7 |
0.424 |
|
| 1997 |
Díaz-Requejo MM, Pérez PJ, Brookhart M, Templeton JL. Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para-Substituted Styrenes† Organometallics. 16: 4399-4402. DOI: 10.1021/Om970382Q |
0.79 |
|
| 1997 |
Killian CM, Johnson aLK, Brookhart M. Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts Organometallics. 16: 2005-2007. DOI: 10.1021/Om961057Q |
0.416 |
|
| 1997 |
Tanner MJ, Brookhart M, DeSimone JM. Observation of an Inverse Kinetic Isotope Effect in a Co(III)-Catalyzed Polymerization of Ethylene Journal of the American Chemical Society. 119: 7617-7618. DOI: 10.1021/Ja971300S |
0.545 |
|
| 1997 |
and CPL, Brookhart M. Co(I)-Catalyzed Inter- and Intramolecular Hydroacylation of Olefins with Aromatic Aldehydes Journal of the American Chemical Society. 119: 3165-3166. DOI: 10.1021/Ja9639776 |
0.377 |
|
| 1997 |
LaPointe AM, Rix FC, Brookhart M. Mechanistic studies of palladium(II)-catalyzed hydrosilation and dehydrogenative silation reactions Journal of the American Chemical Society. 119: 906-917. DOI: 10.1021/Ja962979N |
0.72 |
|
| 1997 |
Lenges CP, Brookhart M, Grant BE. H/D exchange reactions between C6D6 and C5Me5Co(CH2=CHR)2 (R = H, SiMe3): Evidence for oxidative addition of Csp2−H bonds to the [C5Me5(L)Co] moiety Journal of Organometallic Chemistry. 528: 199-203. DOI: 10.1016/S0022-328X(96)06592-8 |
0.354 |
|
| 1996 |
Casarrubios L, Pérez JA, Brookhart M, Templeton JL. Lewis acid-catalyzed synthesis of aziridines Journal of Organic Chemistry. 61: 8358-8359. DOI: 10.1021/Jo961391W |
0.514 |
|
| 1996 |
Killian CM, Tempel DJ, Johnson LK, Brookhart M. Living polymerization of α-olefins using Ni(II)-α-diimine catalysts. Synthesis of new block polymers based on α-olefins Journal of the American Chemical Society. 118: 11664-11665. DOI: 10.1021/Ja962516H |
0.364 |
|
| 1996 |
Brookhart M, Wagner MI. Synthesis of a Stereoblock Polyketone through Ancillary Ligand Exchange Journal of the American Chemical Society. 118: 7219-7220. DOI: 10.1021/Ja9610141 |
0.426 |
|
| 1996 |
DiRenzo GM, White PS, Brookhart M. Mechanistic studies of catalytic olefin dimerization reactions using electrophilic η3-allyl-palladium(II) complexes Journal of the American Chemical Society. 118: 6225-6234. DOI: 10.1021/Ja9602354 |
0.441 |
|
| 1996 |
Rix FC, Brookhart M, White PS. Mechanistic Studies of the Palladium(II)-Catalyzed Copolymerization of Ethylene with Carbon Monoxide Journal of the American Chemical Society. 118: 4746-4764. DOI: 10.1021/Ja953276T |
0.352 |
|
| 1996 |
Johnson LK, Mecking S, Brookhart M. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts Journal of the American Chemical Society. 118: 267-268. DOI: 10.1021/Ja953247I |
0.703 |
|
| 1996 |
Rix FC, Brookhart M, White PS. Electronic effects on the {Beta}-alkyl migratory insertion reaction of para-substituted styrene methyl palladium complexes Journal of the American Chemical Society. 118: 2436-2448. DOI: 10.1021/Ja9527434 |
0.399 |
|
| 1995 |
Brookhart M, DeSimone JM, Grant BE, Tanner MJ. Cobalt(III)-Catalyzed Living Polymerization of Ethylene: Routes to End-Capped Polyethylene with a Narrow Molar Mass Distribution Macromolecules. 28: 5378-5380. DOI: 10.1021/Ma00119A033 |
0.511 |
|
| 1995 |
Johnson LK, Killian CM, Brookhart M. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins Journal of the American Chemical Society. 117: 6414-6415. DOI: 10.1021/Ja00128A054 |
0.394 |
|
| 1995 |
Rix FC, Brookhart M. Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes Journal of the American Chemical Society. 117: 1137-1138. DOI: 10.1021/Ja00108A034 |
0.433 |
|
| 1995 |
Scharrer E, Brookhart M. Insertion Reactions Of Electrophilic Iron Carbene Complexes With Organosilanes : A Synthetic And Mechanistic Study Journal of Organometallic Chemistry. 497: 61-71. DOI: 10.1016/0022-328X(95)00117-9 |
0.386 |
|
| 1995 |
Rix F, Barborak J, Wagner M, Tahliani S, Desimone J, Brookhart M, Elder D. Transition metal catalyzed alternating copolymerizations of olefins and co Macromolecular Symposia. 98: 219-219. DOI: 10.1002/Masy.19950980118 |
0.575 |
|
| 1994 |
Powell KR, Perez PJ, Luan L, Feng SG, White PS, Brookhart M, Templeton JL. Synthesis and Reactivity of Low-Valent Amido, Imido, Azavinylidene, and Nitrido Complexes of Tungsten Organometallics. 13: 1851-1864. DOI: 10.1021/Om00017A048 |
0.755 |
|
| 1994 |
Hauptman E, Brookhart M, Fagan PJ, Calabrese JC. Generation of [C5(CH3)5Ru(NO)(CH3)(H2O)]+ [BAr'4]- (Ar' = 3,5-C6H3(CF3)2) and its reaction with methyl acrylate to produce chelate complexes of the type C5(CH3)5Ru(NO)(CH(R)CH2COOCH3)+ (R = H, CH3) Organometallics. 13: 774-780. DOI: 10.1021/Om00015A010 |
0.339 |
|
| 1994 |
Hauptman E, Sabo-Etienne S, White PS, Brookhart M, Garner JM, Fagan PJ, Calabrese JC. Design and Study of Rh(III) Catalysts for the Selective Tail-to-Tail Dimerization of Methyl Acrylate Journal of the American Chemical Society. 116: 8038-8060. DOI: 10.1021/Ja00097A011 |
0.383 |
|
| 1994 |
Brookhart M, Wagner MI, Balavoine GGA, Haddou HA. Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands Journal of the American Chemical Society. 116: 3641-3642. DOI: 10.1021/Ja00087A077 |
0.434 |
|
| 1994 |
Chang S, Yoon J, Brookhart M. Carbon-Carbon Bond-Forming Reactions of Eta(3)-Allyl Iron Tricarbonyl Anions with Carbon Electrophiles Journal of the American Chemical Society. 116: 1869-1879. DOI: 10.1021/Ja00084A030 |
0.339 |
|
| 1994 |
Perez PJ, White PS, Brookhart M, Templeton JL. Nitrene Transfer to Trimethylphosphine from Cationic Tungsten Tosylnitrene Complexes [Tp'(CO)2W(NTs)][X] Inorganic Chemistry. 33: 6050-6056. DOI: 10.1021/Ic00104A013 |
0.718 |
|
| 1993 |
Pérez PJ, Brookhart M, Templeton JL. A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines Organometallics. 12: 261-262. DOI: 10.1021/Om00026A007 |
0.774 |
|
| 1992 |
Brookhart M, Grant B, Volpe AF. [(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes Organometallics. 11: 3920-3922. DOI: 10.1021/Om00059A071 |
0.388 |
|
| 1992 |
Brookhart M, Chandler WA, Pfister AC, Santini CC, White PS. Synthesis and reactivity of bidentate phosphine iron complex [(C2F5)2PCH2CH2P(C2F5)2]Fe(CO)3 Organometallics. 11: 1263-1274. DOI: 10.1021/Om00039A036 |
0.301 |
|
| 1992 |
Bennett MA, McMahon IJ, Pelling S, Brookhart M, Lincoln DM. Protonation of diene complexes of rhodium, iridium, ruthenium, and osmium: a fine balance between terminal and agostic hydrides Organometallics. 11: 127-138. DOI: 10.1021/Om00037A028 |
0.394 |
|
| 1992 |
Brookhart M, Hauptman E, Lincoln DM. .beta.-Migratory insertion reactions of (.eta.5-C5R'5)Rh(L)(C2H4)R+BF4- (R' = hydrogen, methyl; R = hydrogen, ethyl; L = P(OMe)3, PMe3). Comparison of the energetics of hydride versus alkyl migration Journal of the American Chemical Society. 114: 10394-10401. DOI: 10.1021/Ja00052A040 |
0.344 |
|
| 1992 |
Brookhart M, Rix FC, DeSimone JM, Barborak JC. Palladium(II) catalysts for living alternating copolymerization of olefins and carbon monoxide Journal of the American Chemical Society. 114: 5894-5895. DOI: 10.1021/Ja00040A082 |
0.612 |
|
| 1992 |
Brookhart M, Hauptman E. Mechanism of rhodium(III)-catalyzed methyl acrylate dimerization Journal of the American Chemical Society. 114: 4437-4439. DOI: 10.1021/Ja00037A081 |
0.332 |
|
| 1992 |
Brookhart M, Chandler W, Kessler RJ, Liu Y, Pienta NJ, Santini CC, Hall C, Perutz RN, Timney JA. Matrix isolation and transient absorption studies of [bis[bis(pentafluoroethyl)phosphino]ethane]tetracarbonylchromium: intermolecular alkane complexes and intramolecular F-coordination Journal of the American Chemical Society. 114: 3802-3815. DOI: 10.1021/Ja00036A032 |
0.319 |
|
| 1991 |
Brookhart M, Sabo-Etienne S. Catalytic tail-to-tail dimerization of methyl acrylate using rhodium(III) catalysts Journal of the American Chemical Society. 113: 2777-2779. DOI: 10.1021/Ja00007A076 |
0.411 |
|
| 1991 |
Brookhart M, Liu Y. Investigation of the stereochemistry of iron-carbon.alpha. bond cleavage when phenylcyclopropane is generated by .gamma.-ionization of stereospecifically deuterated C5H5(CO)2FeCHDCHDCH(OCH3)C6H5 complexes. A transition-state model for transfer of the carbene ligand from C5H5(CO)2Fe:CHR+ to alkenes Journal of the American Chemical Society. 113: 939-944. DOI: 10.1021/Ja00003A029 |
0.393 |
|
| 1991 |
Brookhart M, Liu Y, Goldman EW, Timmers DA, Williams GD. Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+. A mechanistic analysis of the carbene transfer reaction Journal of the American Chemical Society. 113: 927-939. DOI: 10.1021/Ja00003A028 |
0.385 |
|
| 1991 |
Feng SG, Luan L, White P, Brookhart MS, Templeton JL, Young CG. Mononuclear cis-carbonyloxotungsten(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate Inorganic Chemistry. 30: 2582-2584. DOI: 10.1021/Ic00012A003 |
0.555 |
|
| 1990 |
Brookhart M, Volpe AF, Lincoln DM, Horvath IT, Millar JM. Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction Journal of the American Chemical Society. 112: 5634-5636. DOI: 10.1021/Ja00170A035 |
0.449 |
|
| 1990 |
Brookhart M, Lincoln DM, Bennett MA, Pelling S. Dynamics of agostic complexes of the type C5R5(C2H4)M(CH2CH2-.mu.-H)+. Energy differences between and ancillary ligand control of agostic and terminal hydride structures Journal of the American Chemical Society. 112: 2691-2694. DOI: 10.1021/Ja00163A033 |
0.354 |
|
| 1990 |
Peng WJ, Gamble AS, Templeton JL, Brookhart M. Reactions of [Cp(CO)2Fe:CHAr]+ (Ar = p-C6H4OMe) with O:N-Ar'(Ar' = C6H5, p-C6H4NMe2) and PhN:NPh Inorganic Chemistry. 29: 463-467. DOI: 10.1021/Ic00328A024 |
0.531 |
|
| 1989 |
Brookhart M, Liu Y. Resolution of the chiral-at-iron acetyl complexes C5H5(CO)(PR3)FeC(O)CH3 (R = CH3, CH2CH3). Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+ (R = CH3, CH2CH3) Organometallics. 8: 1572-1573. DOI: 10.1021/Om00108A037 |
0.373 |
|
| 1989 |
Brookhart M, Liu Y. When phenylcyclopropanes are generated by .gamma.-ionization of erythro- and threo-d2-C5H5(CO)2FeCHDCHDCH(OCH3)C6H5, cleavage of the Fe-C.alpha. bond occurs with inversion of configuration of C.alpha. Organometallics. 8: 1569-1572. DOI: 10.1021/Om00108A036 |
0.315 |
|
| 1989 |
Brookhart M, Lincoln DM, Volpe AF, Schmidt GF. Ligand and substituent effects on the dynamics and structure of agostic ethylenecobalt complexes of the type C5R5(L)Co(CH2CHR'-.mu.-H)+ BF4- [L = P(OMe)3, PMe3; R = H, Me; R' = H, Me] Organometallics. 8: 1212-1218. DOI: 10.1021/Om00107A014 |
0.324 |
|
| 1989 |
Brookhart M, Studabaker WB, Humphrey MB, Husk GR. Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M:CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to aryl rotation and benzylidene transfer reactions Organometallics. 8: 132-140. DOI: 10.1021/Om00103A016 |
0.355 |
|
| 1989 |
Brookhart M, Buck RC, Danielson E. Synthesis, spectroscopic characterization, dynamics, and phosphine trapping of Cp(CO)Fe[.eta.3-CH(R)C6H5] complexes (R = H, OCH3) Journal of the American Chemical Society. 111: 567-574. DOI: 10.1021/Ja00184A026 |
0.354 |
|
| 1989 |
Brookhart M, Buck RC. Formation of Cp(CO)(PR3)FeCH(OCH3)C6H5 complexes via PR3 substitution reactions, hydride addition to Cp(CO)(PR3)Fe:C(OCH3)C6H5+, and methoxide addition to Cp(CO)(PR3)Fe:CHC6H5+. Kinetic and thermodynamic diastereoselectivities. Relative reactivities of synclinal and anticlinal iron carbene isomers Journal of the American Chemical Society. 111: 559-567. DOI: 10.1021/Ja00184A025 |
0.362 |
|
| 1989 |
Brookhart M, Buck RC. Enantioselective benzylidene transfer reactions using the chiral-at-iron benzylidene complexes (SFeSc)- and (RFeSc)-Cp(CO)(Ph2R★P_Fe=CH6H5+ (R★ = (S-2-methylbutyl) and SFe- and (RFe)-Cp(CO)PEt3Fe=CHC6H5+ Journal of Organometallic Chemistry. 370: 111-127. DOI: 10.1016/0022-328X(89)87279-1 |
0.406 |
|
| 1988 |
Brookhart M, Noh SK, Timmers FJ, Hong YH. Anionic manganese tricarbonyl complexes of C7 and C8 cyclic dienes and polyenes: synthesis and reactions with electrophiles Organometallics. 7: 2458-2465. DOI: 10.1021/Om00102A005 |
0.374 |
|
| 1988 |
Brookhart M, Liu Y, Buck RC. Diastereoselective reactions of chiral-at-iron carbene complexes C5H5(CO)(PR3)Fe:CHR+. Synclinal isomers are more reactive than anticlinal isomers Journal of the American Chemical Society. 110: 2337-2339. DOI: 10.1021/Ja00215A074 |
0.313 |
|
| 1987 |
Brookhart M, Noh SK, Timmers FJ. General route to anionic (.eta.4-diene)manganese tricarbonyl complexes. Reactions with electrophiles Organometallics. 6: 1829-1831. DOI: 10.1021/Om00151A043 |
0.416 |
|
| 1987 |
Brookhart M, Studabaker WB, Husk GR. Iron and ruthenium cyclopropylcarbene complexes C5H5(CO)2M:CH(c-C3H5)+ CF3SO3-. Cyclopropylcarbene transfer reactions Organometallics. 6: 1141-1145. DOI: 10.1021/Om00149A001 |
0.381 |
|
| 1987 |
Brookhart M, Studabaker WB. Cyclopropanes from reactions of transition metal carbene complexes with olefins Chemical Reviews. 87: 411-432. DOI: 10.1021/Cr00078A008 |
0.345 |
|
| 1986 |
Rush PK, Noh SK, Brookhart M. A general route to C6H6(CO)2Mn-R complexes via C6H6(CO)2Mn−Na+: alkyl group migrations from manganese to the coordinated arene ring Organometallics. 5: 1745-1747. DOI: 10.1021/Om00139A038 |
0.405 |
|
| 1986 |
Studabaker WB, Brookhart M. (η5-C5H5)(Ph2PCH2CH2PPH2)RuCH2+ AsF6−. Spectral Characterization and measurement of the barrier to methylene rotation Journal of Organometallic Chemistry. 310. DOI: 10.1016/S0022-328X(00)99564-0 |
0.379 |
|
| 1985 |
Brookhart M, Cox K, Cloke FGN, Green JC, Green MLH, Hare PM, Bashkin J, Derome AE, Grebenik PD. Hexakis(trimethylphosphine)molybdenum chemistry: Dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives Journal of the Chemical Society, Dalton Transactions. 423-433. DOI: 10.1039/Dt9850000423 |
0.363 |
|
| 1985 |
Timmers F, Brookhart M. Synthesis and reactivity of methyl-substituted butenylmanganese tricarbonyl complexes containing a two-electron, three-center Mn.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.C interaction Organometallics. 4: 1365-1371. DOI: 10.1021/Om00127A011 |
0.407 |
|
| 1985 |
Brookhart M, Studabaker WB, Husk GR. Synthesis, spectral characterization, and carbene-transfer reactions of CpFe(CO)2=CH(c-C3H5)+ CF3SO3-. Stabilization of cyclopropylmethylidene by an organometallic fragment Organometallics. 4: 943-944. DOI: 10.1021/Om00124A028 |
0.34 |
|
| 1985 |
Schmidt GF, Brookhart M. Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst Journal of the American Chemical Society. 107: 1443-1444. DOI: 10.1021/Ja00291A073 |
0.353 |
|
| 1985 |
BROOKHART M, COX K, CLOKE FGN, GREEN JC, GREEN MLH, HARE PM, BASHKIN J, DEROME AE, GREBENIK PD. ChemInform Abstract: HEXAKIS(TRIMETHYLPHOSPHINE)MOLYBDENUM CHEMISTRY: DINITROGEN, ETHYLENE, BUTADIENE, η-CYCLOPENTADIENYL, AND RELATED DERIVATIVES Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198526303 |
0.357 |
|
| 1984 |
Brookhart M, Timmers D, Tucker JR, Williams GD, Husk GR, Brunner H, Hammer B. Enantioselective Cyclopropane Synthesis Using The Chiral Carbene Complexes (Sfesc)- And (Rfesc)-(C5H5)(Co)(Ph2R*P)Fe:Chch3+ (R* = (S)-2-Methylbutyl). Role Of Metal Vs. Ligand Chirality In The Optical Induction Cheminform. 15. DOI: 10.1002/Chin.198406258 |
0.37 |
|
| 1983 |
Brookhart M, Green MLH, Pardy RBA. Two-electron, three-centre carbon–hydrogen–cobalt bonds in the compounds [Co(η-C5Me4R)(η-C2H4)(η-C2H4-µ-H)] BF4, R = Me and Et Journal of the Chemical Society, Chemical Communications. 691-693. DOI: 10.1039/C39830000691 |
0.326 |
|
| 1983 |
Brookhart M, Timmers D, Tucker JR, Williams GD, Husk GR, Brunner H, Hammer B. Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFeSC)- and (RFeSC)-(C5H5)(CO)(Ph2R*P)Fe=CHCH3+ (R*=(S)-2-methylbutyl). Role of metal vs. ligand chirality in the optical induction Journal of the American Chemical Society. 105: 6721-6723. DOI: 10.1021/Ja00360A034 |
0.349 |
|
| 1983 |
Brookhart M, Tucker JR, Husk GR. Synthesis, spectral characterization and alkylidene-transfer reactions of electrophilic iron carbene complexes Cp(CO)(L)Fe:CHR+ (L = CO, PPh3; R = Me, Et, CHMe2) Journal of the American Chemical Society. 105: 258-264. DOI: 10.1021/Ja00340A020 |
0.326 |
|
| 1982 |
Kegley SE, Brookhart M, Husk GR. Spectroscopic characterization of electrophilic d4 methylene and benzylidene complexes of the type Cp(CO)2(L)M(:CHR)+ (L = PPh3, PEt3; M = Mo, W; R = H, Ph). Experimental determination of barriers to rotation about the tungsten-methylene multiple bond Organometallics. 1: 760-762. DOI: 10.1021/Om00065A019 |
0.331 |
|
| 1981 |
Brookhart M, Tucker JR, Husk GR. Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+ Journal of the American Chemical Society. 103: 979-981. DOI: 10.1021/Ja00394A063 |
0.359 |
|
| 1981 |
Brookhart M, Humphrey MB, Kratzer HJ, Nelson GO. Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions Cheminform. 12. DOI: 10.1002/Chin.198112326 |
0.34 |
|
| 1980 |
Brookhart M, Humphrey MB, Kratzer HJ, Nelson GO. Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions Journal of the American Chemical Society. 102: 7802-7803. DOI: 10.1021/Ja00546A039 |
0.34 |
|
| 1980 |
Brookhart M, Tucker JR, Flood TC, Jensen J. Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2+ Journal of the American Chemical Society. 102: 1203-1205. DOI: 10.1021/Ja00523A068 |
0.312 |
|
| 1980 |
Brookhart M, Tucker JR, Husk GR. Measurement of barriers to aryl rotation in Cp(CO)2FeCHC6H5+ and Cp(CO)2FeCH(p-CH3C6H4)+ Journal of Organometallic Chemistry. 193. DOI: 10.1016/S0022-328X(00)86090-8 |
0.393 |
|
| 1980 |
Brookhart M, Tucker JR, Husk GR. Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+ Cheminform. 12. DOI: 10.1002/Chin.198122291 |
0.359 |
|
| 1979 |
Lewis CP, Brookhart M, Hitching W, Eisenstadt A. Fluxional Behavior and Substituent Site Preferences in Cationic Monosubstituted Tropyliumiron Tricarbonyl Complexes Journal of the American Chemical Society. 101: 4896-4906. DOI: 10.1021/Ja00511A019 |
0.362 |
|
| 1979 |
Brookhart M, Nelson GO. The reaction of benzylideneacetoneiron tricarbonyl with dienes; measurement of relative reactivities using competition experiments Journal of Organometallic Chemistry. 164: 193-202. DOI: 10.1016/S0022-328X(00)86704-2 |
0.38 |
|
| 1979 |
Lewis CP, Kitching W, Eisenstadt A, Brookhart M. Fluxional Behavior And Substituent Site Preferences In Cationic Monosubstituted Tropyliumiron Tricarbonyl Complexes Cheminform. 10. DOI: 10.1002/Chin.197947298 |
0.314 |
|
| 1977 |
Graham CR, Scholes G, Brookhart M. Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthetic and mechanistic studies of the reactions of 1,3,5-cyclooctatriene and its derivatives with benzylideneacetoneiron tricarbonyl Journal of the American Chemical Society. 99: 1180-1188. DOI: 10.1021/Ja00446A033 |
0.307 |
|
| 1977 |
Brookhart MS, Lewis CP, Eisenstadt A. Low temperature spectroscopic observation of oxygen-protonated troponeiron tricarbonyl complexes Journal of Organometallic Chemistry. 127: C14-C18. DOI: 10.1016/S0022-328X(00)84206-0 |
0.317 |
|
| 1977 |
Graham CR, Scholes G, Brookhart M. Selective Trapping Of Dienes By Benzylideneacetoneiron Tricarbonyl. Synthetic And Mechanistic Studies Of The Reactions Of 1,3,5-Cyclooctatriene And Its Derivatives With Benzylideneacetoneiron Tricarbonyl Cheminform. 8. DOI: 10.1002/Chin.197719301 |
0.307 |
|
| 1976 |
Brookhart M, Nelson GO, Scholes G, Watson RA. Preparation of bicyclo[4.2.0]octa-2,4-dien-7-one via trapping with benzylideneacetoneiron tricarbonyl Journal of the Chemical Society, Chemical Communications. 195-196. DOI: 10.1039/C39760000195 |
0.329 |
|
| 1976 |
Brookhart MS, Koszalka GW, Nelson GO, Scholes G, Watson RA. Synthesis and reactions of the tautomeric complexes η-2,3,4,5-cyclooctatrienoneiron tricarbonyl and bicyclo[4.2.0]octa-2,4-dien-7-oneiron tricarbonyl. Generation of bicyclo[4.2.0]octa-2,4-dien-7-one Journal of the American Chemical Society. 98: 8155-8161. DOI: 10.1021/Ja00441A045 |
0.414 |
|
| 1976 |
Brookhart M, Whitesides TH, Crockett JM. Spectroscopic studies of the structures of protonated dieneiron tricarbonyl complexes Inorganic Chemistry. 15: 1550-1554. DOI: 10.1021/Ic50161A017 |
0.34 |
|
| 1973 |
Brookhart M, Harris DL, Dammann RC. Observation of a π- to σ-rearrangement upon proton addition to bicyclo[6,1,0]nonatrienetricarbonylmolybdenum Journal of the Chemical Society, Chemical Communications. 187. DOI: 10.1039/C39730000187 |
0.359 |
|
| 1973 |
Brookhart M, Lippman NM, Reardon EJ. Isomerization of 1,3,5-cyclooctatrieneiron tricarbonyl to bicyclo[4.2.0]octa-2,4,-dieneiron tricarbonyl Journal of Organometallic Chemistry. 54: 247-253. DOI: 10.1016/S0022-328X(00)85015-9 |
0.326 |
|
| 1973 |
Isidor JL, Brookhart MS, Mckee RL. Ein Neues Furan-Dimeres Cheminform. 4. DOI: 10.1002/Chin.197320272 |
0.307 |
|
| 1972 |
Lustgarten RK, Brookhart M, Winstein S. Degenerate and nondegenerate isomerizations of 7-norbornadienyl cations Journal of the American Chemical Society. 94: 2347-2363. DOI: 10.1021/Ja00762A028 |
0.502 |
|
| 1972 |
Brookhart M, Harris DL. Generation of trans-π-pentadienyliron tricarbonyl cations from protonation of (trans,trans-2,4-hexadienal)iron tricarbonyl Journal of Organometallic Chemistry. 42: 441-446. DOI: 10.1016/S0022-328X(00)90094-9 |
0.304 |
|
| 1972 |
Lustgarten RK, Brookhart M, Winstein S. Entartete Und Nichtentartete Isomerisierungen Von Norbornadienyl-(7)-Kationen Cheminform. 3. DOI: 10.1002/Chin.197226165 |
0.431 |
|
| 1971 |
Brookhart M, Lustgarten RK, Harris DL, Winstein S. Direkte Beobachtungen An Substituierten Quadricyclyl-Kationen Und Ihre Umlagerungen Cheminform. 2. DOI: 10.1002/Chin.197128152 |
0.434 |
|
| 1970 |
Richey, Jr. HG, Nichols JD, Gassman PG, Fentiman, Jr. AF, Winstein S, Brookhart M, Lustgarten RK. Additions and Corrections - A Classical 7-Norbornenyl Cation. Competition between Aryl and Alkenyl Functions in Stabilizing 7-Aryl-7-norborenyl Cations Journal of the American Chemical Society. 92: 7240-7240. DOI: 10.1021/Ja00727A605 |
0.513 |
|
| 1970 |
Richey HG, Nichols JD, Gassman PG, Fentiman AF, Winstein S, Brookhart M, Lustgarten RK. A classical 7-norbornenyl cation. Competition between aryl and alkenyl functions in stabilizing 7-aryl-7-norbornenyl cations [1] Journal of the American Chemical Society. 92: 3783-3784. DOI: 10.1021/Ja00715A041 |
0.51 |
|
| 1970 |
Richey HGJ, Nichols JD, Gassman PG, Fentiman AFJ, Winstein S, Brookhart M, Lustgarten RK. Ein Klassisches Norbornenyl-(7)-Kation, Konkurrenz Zwischen Aryl- Und Alkenylfunktionen In Stabilisierten 7-Aryl-Norbornenyl-(7)-Kationen Cheminform. 1. DOI: 10.1002/Chin.197037140 |
0.539 |
|
| 1968 |
Lustgarten RK, Brookhart M, Winstein S. Direct observation of methyl-substituted 7-norbornadienyl and bicyclo[3.2.0]heptadienyl cations [18] Journal of the American Chemical Society. 90: 7364-7366. DOI: 10.1021/Ja01028A045 |
0.491 |
|
| 1967 |
Brookhart M, Lustgarten RK, Winstein S. 7-Phenyl- and 7-methoxynorbornadienyl cations Journal of the American Chemical Society. 89: 6354-6355. DOI: 10.1021/Ja01000A067 |
0.509 |
|
| 1967 |
Brookhart M, Lustgarten RK, Winstein S. Bridge flipping and rearrangement of norbornadienyl and 7-methylnorbornadienyl cations [3] Journal of the American Chemical Society. 89: 6352-6354. DOI: 10.1021/Ja01000A066 |
0.513 |
|
| 1967 |
Lustgarten RK, Brookhart M, Winstein S. Degenerate five-carbon scrambling in the 7-norbornadienyl cation. Journal of the American Chemical Society. 89: 6350-6352. DOI: 10.1021/Ja01000A065 |
0.44 |
|
| 1964 |
Baker EW, Brookhart MS, Corwin AH. Piperidinate complexes of nickel and copper mesoporphyrin IX Journal of the American Chemical Society. 86: 4587-4590. DOI: 10.1021/Ja01075A014 |
0.351 |
|
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