| Year |
Citation |
Score |
| 2024 |
Li L, Hu L, Sae-Jew J, Rawal VH. Vinyltriarylbismuthonium Salts: Powerful Vehicles for α-Vinylation of Carbonyl Compounds. Journal of the American Chemical Society. PMID 38922228 DOI: 10.1021/jacs.4c05709 |
0.38 |
|
| 2023 |
Baidilov D, Elkin PK, Athe S, Rawal VH. Rapid Access to 2,2-Disubstituted Indolines via Dearomative Indolic-Claisen Rearrangement: Concise, Enantioselective Total Synthesis of (+)-Hinckdentine A. Journal of the American Chemical Society. 145: 14831-14838. PMID 37364288 DOI: 10.1021/jacs.3c03611 |
0.365 |
|
| 2022 |
Taenzler F, Xu J, Athe S, Rawal VH. Dearomative (4 + 3) Cycloaddition Reactions of 3-Alkenylindoles and 3-Alkenylpyrroles to Afford Cyclohepta[]indoles and Cyclohepta[]pyrroles. Organic Letters. 24: 8109-8114. PMID 36315976 DOI: 10.1021/acs.orglett.2c02983 |
0.484 |
|
| 2021 |
Cassaidy KJ, Rawal VH. Enantioselective Total Synthesis of (+)-Heilonine. Journal of the American Chemical Society. 143: 16394-16400. PMID 34585920 DOI: 10.1021/jacs.1c08756 |
0.411 |
|
| 2021 |
Hu L, Rawal VH. Total Synthesis of the Chlorinated Pentacyclic Indole Alkaloid (+)-Ambiguine G. Journal of the American Chemical Society. PMID 34279940 DOI: 10.1021/jacs.1c05762 |
0.355 |
|
| 2021 |
Elkin PK, Durfee ND, Rawal VH. Diels-Alder Reactions of 1-Alkoxy-1-amino-1,3-butadienes: Direct Synthesis of 6-Substituted and 6,6-Disubstituted 2-Cyclohexenones and 6-Substituted 5,6-Dihydropyran-2-ones. Organic Letters. PMID 34062059 DOI: 10.1021/acs.orglett.1c01031 |
0.499 |
|
| 2019 |
Wu YK, Rawal VH. Rapid construction of tetrahydropyridine scaffolds via formal imino Diels-Alder reactions of Schiff bases and Nazarov reagents. Organic & Biomolecular Chemistry. PMID 31553010 DOI: 10.1039/C9Ob01880H |
0.652 |
|
| 2019 |
Xu J, Rawal VH. Total Synthesis of (-)-Ambiguine P. Journal of the American Chemical Society. PMID 30855140 DOI: 10.1021/Jacs.9B01739 |
0.478 |
|
| 2018 |
Hu L, Rombola M, Rawal VH. Synthesis of 1,2-Oxazinanes via Hydrogen Bond Mediated [3 + 3] Cycloaddition Reactions of Oxyallyl Cations with Nitrones. Organic Letters. PMID 30133293 DOI: 10.1021/Acs.Orglett.8B02301 |
0.557 |
|
| 2018 |
Rombola M, Rawal VH. Dicyclopentyl Dithiosquarate as an Intermediate for the Synthesis of Thiosquaramides. Organic Letters. PMID 29336576 DOI: 10.1021/Acs.Orglett.7B03549 |
0.536 |
|
| 2017 |
Reyes JR, Xu J, Kobayashi K, Bhat V, Rawal VH. Total Synthesis of (-)-N-Methylwelwitindolinone B Isothiocyanate. Angewandte Chemie (International Ed. in English). PMID 28700100 DOI: 10.1002/Anie.201705322 |
0.689 |
|
| 2017 |
Rombola M, Sumaria CS, Montgomery TD, Rawal VH. Development of Chiral, Bifunctional Thiosquaramides: Enantioselective Michael Additions of Barbituric Acids to Nitroalkenes. Journal of the American Chemical Society. PMID 28375610 DOI: 10.1021/Jacs.7B01115 |
0.829 |
|
| 2016 |
Serda M, Wu YK, Barth ED, Halpern HJ, Rawal VH. EPR Imaging Spin Probe Trityl Radical OX063: A Method for Its Isolation from Animal Effluent, Redox Chemistry of Its Quinone Methide Oxidation Product, and in Vivo Application in a Mouse. Chemical Research in Toxicology. 29: 2153-2156. PMID 27989135 DOI: 10.1021/Acs.Chemrestox.6B00277 |
0.465 |
|
| 2016 |
Turkmen YE, Gravel M, Rawal VH. Studies Directed toward the Synthesis of Aspidophytine: Construction of its Perhydroquinoline Core. The Journal of Organic Chemistry. PMID 27525506 DOI: 10.1021/Acs.Joc.6B01574 |
0.853 |
|
| 2016 |
Kagawa N, Nibbs AE, Rawal VH. One-Carbon Homologation of Primary Alcohols to Carboxylic Acids, Esters, and Amides via Mitsunobu Reactions with MAC Reagents. Organic Letters. PMID 27135854 DOI: 10.1021/Acs.Orglett.6B00790 |
0.431 |
|
| 2016 |
Montgomery TD, Rawal VH. Palladium-Catalyzed Modular Synthesis of Substituted Piperazines and Related Nitrogen Heterocycles. Organic Letters. PMID 26824482 DOI: 10.1021/Acs.Orglett.5B03708 |
0.847 |
|
| 2016 |
Reyes JR, Rawal VH. Reductive Chlorination and Bromination of Ketones via Trityl Hydrazones. Angewandte Chemie (International Ed. in English). PMID 26823122 DOI: 10.1002/Anie.201510909 |
0.507 |
|
| 2015 |
Nibbs AE, Montgomery TD, Zhu Y, Rawal VH. Access to Spirocyclized Oxindoles and Indolenines via Palladium-Catalyzed Cascade Reactions of Propargyl Carbonates with 2-Oxotryptamines and Tryptamines. The Journal of Organic Chemistry. 80: 4928-41. PMID 25876139 DOI: 10.1021/Acs.Joc.5B00277 |
0.849 |
|
| 2014 |
Bhat V, Dave A, MacKay JA, Rawal VH. The Chemistry of Hapalindoles, Fischerindoles, Ambiguines, and Welwitindolinones. The Alkaloids. Chemistry and Biology. 73: 65-160. PMID 26521649 DOI: 10.1016/B978-0-12-411565-1.00002-0 |
0.774 |
|
| 2014 |
Yang KS, Rawal VH. Synthesis of α-amino acid derivatives and peptides via enantioselective addition of masked acyl cyanides to imines. Journal of the American Chemical Society. 136: 16148-51. PMID 25366558 DOI: 10.1021/Ja510135T |
0.84 |
|
| 2014 |
Montgomery TD, Nibbs AE, Zhu Y, Rawal VH. Rapid access to spirocyclized indolenines via palladium-catalyzed cascade reactions of tryptamine derivatives and propargyl carbonate. Organic Letters. 16: 3480-3. PMID 24964382 DOI: 10.1021/Ol501409A |
0.853 |
|
| 2014 |
Sumaria CS, Türkmen YE, Rawal VH. Non-precious metals catalyze formal [4 + 2] cycloaddition reactions of 1,2-diazines and siloxyalkynes under ambient conditions. Organic Letters. 16: 3236-9. PMID 24911346 DOI: 10.1021/Ol501254H |
0.809 |
|
| 2014 |
Bhat V, Dave A, MacKay JA, Rawal VH. The Chemistry of Hapalindoles, Fischerindoles, Ambiguines, and Welwitindolinones Alkaloids: Chemistry and Biology. 73: 65-160. DOI: 10.1016/B978-0-12-411565-1.00002-0 |
0.779 |
|
| 2013 |
Türkmen YE, Sen S, Rawal VH. Stacks and clips: Uncanny similarities in the modes of self-assembly in tenary Ag(I) complexes with 1,2-diazines and chelating heteroarenes. Crystengcomm / Rsc. 2013: 4221-4224. PMID 24701132 DOI: 10.1039/C3Ce40500A |
0.701 |
|
| 2013 |
Montavon TJ, Türkmen YE, Shamsi NA, Miller C, Sumaria CS, Rawal VH, Kozmin SA. [2+2+2] Cycloadditions of siloxy alkynes with 1,2-diazines: from reaction discovery to identification of an antiglycolytic chemotype. Angewandte Chemie (International Ed. in English). 52: 13576-9. PMID 24346942 DOI: 10.1002/Anie.201305711 |
0.835 |
|
| 2013 |
Yang KS, Nibbs AE, Türkmen YE, Rawal VH. Squaramide-catalyzed enantioselective Michael addition of masked acyl cyanides to substituted enones. Journal of the American Chemical Society. 135: 16050-3. PMID 24090310 DOI: 10.1021/Ja409012Q |
0.854 |
|
| 2013 |
Türkmen YE, Rawal VH. Exploring the potential of diarylacetylenediols as hydrogen bonding catalysts. The Journal of Organic Chemistry. 78: 8340-53. PMID 23869597 DOI: 10.1021/Jo400926N |
0.763 |
|
| 2013 |
Hutson GE, Türkmen YE, Rawal VH. Salen promoted enantioselective Nazarov cyclizations of activated and unactivated dienones. Journal of the American Chemical Society. 135: 4988-91. PMID 23506509 DOI: 10.1021/Ja401908M |
0.838 |
|
| 2013 |
Montgomery TD, Zhu Y, Kagawa N, Rawal VH. Palladium-catalyzed decarboxylative allylation and benzylation of N-alloc and N-Cbz indoles. Organic Letters. 15: 1140-3. PMID 23427905 DOI: 10.1021/Ol400334U |
0.827 |
|
| 2012 |
Türkmen YE, Montavon TJ, Kozmin SA, Rawal VH. Silver-catalyzed formal inverse electron-demand Diels-Alder reaction of 1,2-diazines and siloxy alkynes. Journal of the American Chemical Society. 134: 9062-5. PMID 22607029 DOI: 10.1021/Ja302537J |
0.844 |
|
| 2012 |
Allan KM, Kobayashi K, Rawal VH. A unified route to the welwitindolinone alkaloids: total syntheses of (-)-N-methylwelwitindolinone C isothiocyanate, (-)-N-methylwelwitindolinone C isonitrile, and (-)-3-hydroxy-N-methylwelwitindolinone C isothiocyanate. Journal of the American Chemical Society. 134: 1392-5. PMID 22235963 DOI: 10.1021/Ja210793X |
0.455 |
|
| 2012 |
Zhu Y, Rawal VH. Palladium-catalyzed C3-benzylation of indoles. Journal of the American Chemical Society. 134: 111-4. PMID 22133348 DOI: 10.1021/Ja2095393 |
0.565 |
|
| 2012 |
Rawal VH, Kozmin SA. ChemInform Abstract: Introduction to the Synthesis of 1,3-Dienes Cheminform. 43: no-no. DOI: 10.1002/chin.201222225 |
0.691 |
|
| 2011 |
Bhat V, Mackay JA, Rawal VH. Lessons Learned while Traversing the Welwitindolinone Alkaloids Obstacle Course. Tetrahedron. 67: 100997-10104. PMID 22962500 DOI: 10.1016/J.Tet.2011.09.088 |
0.684 |
|
| 2011 |
Bhat V, Rawal VH. Stereocontrolled synthesis of 20,21-dihydro N-methylwelwitindolinone B isothiocyanate. Chemical Communications (Cambridge, England). 47: 9705-7. PMID 21792443 DOI: 10.1039/C1Cc13498A |
0.609 |
|
| 2011 |
Dang Y, Schneider-Poetsch T, Eyler DE, Jewett JC, Bhat S, Rawal VH, Green R, Liu JO. Inhibition of eukaryotic translation elongation by the antitumor natural product Mycalamide B. Rna (New York, N.Y.). 17: 1578-88. PMID 21693620 DOI: 10.1261/Rna.2624511 |
0.687 |
|
| 2011 |
Bhat V, Mackay JA, Rawal VH. Directed oxidative cyclizations to C2- or C4-positions of indole: efficient construction of the bicyclo[4.3.1]decane core of welwitindolinones. Organic Letters. 13: 3214-7. PMID 21615098 DOI: 10.1021/Ol201122F |
0.71 |
|
| 2011 |
Bhat V, Allan KM, Rawal VH. Total synthesis of N-methylwelwitindolinone D isonitrile. Journal of the American Chemical Society. 133: 5798-801. PMID 21446729 DOI: 10.1021/Ja201834U |
0.695 |
|
| 2011 |
Bhat V, Allan KM, Rawal VH. Synthesis of N-MethylwelwitindolinoneD Isonitrile Synfacts. 2011: 812-812. DOI: 10.1055/S-0030-1260752 |
0.341 |
|
| 2010 |
Jewett JC, Rawal VH. Temporary restraints to overcome steric obstacles: an efficient strategy for the synthesis of mycalamide B. Angewandte Chemie (International Ed. in English). 49: 8682-5. PMID 20931583 DOI: 10.1002/Anie.201003361 |
0.733 |
|
| 2010 |
Qian Y, Ma G, Lv A, Zhu HL, Zhao J, Rawal VH. Squaramide-catalyzed enantioselective Friedel-Crafts reaction of indoles with imines. Chemical Communications (Cambridge, England). 46: 3004-6. PMID 20386849 DOI: 10.1039/B922120D |
0.569 |
|
| 2010 |
Konishi H, Lam TY, Malerich JP, Rawal VH. Enantioselective alpha-amination of 1,3-dicarbonyl compounds using squaramide derivatives as hydrogen bonding catalysts. Organic Letters. 12: 2028-31. PMID 20359172 DOI: 10.1021/Ol1005104 |
0.393 |
|
| 2010 |
Gondi VB, Hagihara K, Rawal VH. Diastereoselective and enantioselective Mukaiyama aldol reactions of alpha-ketoesters using hydrogen bond catalysis. Chemical Communications (Cambridge, England). 46: 904-6. PMID 20107645 DOI: 10.1039/B919929B |
0.828 |
|
| 2010 |
Zhu Y, Malerich JP, Rawal VH. Squaramide-catalyzed enantioselective Michael addition of diphenyl phosphite to nitroalkenes. Angewandte Chemie (International Ed. in English). 49: 153-6. PMID 19950156 DOI: 10.1002/Anie.200904779 |
0.686 |
|
| 2010 |
Huang Y, Rawal VH. ChemInform Abstract: Hydrogen-Bond-Promoted Hetero-Diels-Alder Reactions of Unactivated Ketones. Cheminform. 33: no-no. DOI: 10.1002/chin.200250097 |
0.363 |
|
| 2010 |
Kozmin SA, Janey JM, Rawal VH. ChemInform Abstract: 1-Amino-3-siloxy-1,3-butadienes: Highly Reactive Dienes for the Diels-Alder Reaction. Cheminform. 30: no-no. DOI: 10.1002/chin.199939041 |
0.832 |
|
| 2010 |
DVORAK CA, DUFOUR C, IWASA S, RAWAL VH. ChemInform Abstract: Rapid Synthesis of Di- and Triquinanes by Direct Reductive Fragmentation of Paterno-Buechi-Derived Oxetanes. Cheminform. 30: no-no. DOI: 10.1002/chin.199901182 |
0.573 |
|
| 2010 |
RAWAL VH, FABRE A, IWASA S. ChemInform Abstract: Photocyclization-Fragmentation Route to Linear Triquinanes: Stereocontrolled Synthesis of (.+-.)-endo-Hirsutene. Cheminform. 27: no-no. DOI: 10.1002/chin.199601212 |
0.537 |
|
| 2010 |
Ekoue-Kovi K, Wolf C, Bhat V, Rawal V. Metal-free one-pot oxidative amination of aromatic aldehydes: Conversion of benzaldehyde to N-benzoyl pyrrolidine Organic Syntheses. 87: 1-7. |
0.513 |
|
| 2010 |
Benohoud M, Erkkila A, Pihko PM, Turkmen Y, Rawal V. Organocatalytic α-methylenation of aldehydes: Preparation of 3,7-dimethyl-2-methylene-6-octenal Organic Syntheses. 87: 201-208. |
0.729 |
|
| 2009 |
Okamoto K, Hayashi T, Rawal VH. Electronic and steric tuning of chiral diene ligands for rhodium-catalyzed asymmetric arylation of imines. Chemical Communications (Cambridge, England). 4815-7. PMID 19652790 DOI: 10.1039/B904624K |
0.449 |
|
| 2009 |
Gondi VB, Hagihara K, Rawal VH. Diastereoselective and enantioselective synthesis of tertiary alpha-hydroxy phosphonates through hydrogen-bond catalysis. Angewandte Chemie (International Ed. in English). 48: 776-9. PMID 19097127 DOI: 10.1002/Anie.200804244 |
0.868 |
|
| 2009 |
Rawal V, Gondi V, Hagihara K. Asymmetric Mukaiyama Aldol Reactions of Acetyl Phosphonates Synfacts. 2009: 0324-0324. DOI: 10.1055/S-0028-1087725 |
0.845 |
|
| 2009 |
Malerich JP, Hagihara K, Rawal VH. Chiral Squaramide Organocatalysis Synfacts. 2009: 94-94. DOI: 10.1055/S-0028-1087420 |
0.349 |
|
| 2009 |
Gálvez E, Romea P, Urpí F, Gondi VB, Rawal VH. Stereoselective synthesis of anti α-methyl-β-methoxy carboxylic compounds Organic Syntheses. 86: 81-91. |
0.784 |
|
| 2009 |
Gálvez E, Romea P, Urpí F, Jewett JC, Rawal VH. Preparation of (S)-4-Isopropyl-N-propanoyl-1,3-thiazolidine-2-thione Organic Syntheses. 86: 70-80. |
0.654 |
|
| 2008 |
Malerich JP, Hagihara K, Rawal VH. Chiral squaramide derivatives are excellent hydrogen bond donor catalysts. Journal of the American Chemical Society. 130: 14416-7. PMID 18847268 DOI: 10.1021/Ja805693P |
0.457 |
|
| 2008 |
Okamoto K, Hayashi T, Rawal VH. Simple chiral diene ligands provide high enantioselectivities in transition-metal-catalyzed conjugate addition reactions. Organic Letters. 10: 4387-9. PMID 18771267 DOI: 10.1021/Ol801931V |
0.54 |
|
| 2008 |
Kagawa N, Malerich JP, Rawal VH. Palladium-catalyzed beta-allylation of 2,3-disubstituted indoles. Organic Letters. 10: 2381-4. PMID 18491859 DOI: 10.1021/Ol8006277 |
0.394 |
|
| 2008 |
Hayashida J, Rawal VH. Total synthesis of (+/-)-platencin. Angewandte Chemie (International Ed. in English). 47: 4373-6. PMID 18454442 DOI: 10.1002/Anie.200800756 |
0.74 |
|
| 2008 |
Jewett JC, Rawal VH. Synthesis of Pederin Synfacts. 2008: 11-11. DOI: 10.1055/S-2007-992392 |
0.751 |
|
| 2008 |
Rawal V, Hayashida J. Synthesis of ()-Platencin Synfacts. 2008: 1134-1134. DOI: 10.1055/S-0028-1083416 |
0.746 |
|
| 2007 |
Thadani AN, Huang Y, Rawal VH. Expedient, high-yielding synthesis of silyl-substituted salen ligands. Organic Letters. 9: 3873-6. PMID 17764187 DOI: 10.1021/Ol0713436 |
0.582 |
|
| 2007 |
Hutson GE, Dave AH, Rawal VH. Highly enantioselective carbonyl-ene reactions catalyzed by a hindered silyl-salen-cobalt complex. Organic Letters. 9: 3869-72. PMID 17764186 DOI: 10.1021/Ol071342D |
0.83 |
|
| 2007 |
Jewett JC, Rawal VH. Total synthesis of pederin. Angewandte Chemie (International Ed. in English). 46: 6502-4. PMID 17645272 DOI: 10.1002/Anie.200701677 |
0.745 |
|
| 2007 |
Zhong HM, Sohn JH, Rawal VH. Studies toward the asymmetric synthesis of the right part of the mycalamides. The Journal of Organic Chemistry. 72: 386-97. PMID 17221953 DOI: 10.1021/Jo0615145 |
0.661 |
|
| 2007 |
Rawal VH, Thadani AN. Enantioselective Cycloaddition Reactions Catalyzed by Hydrogen Bonding Cheminform. 38. DOI: 10.1002/chin.200728218 |
0.383 |
|
| 2007 |
McGilvra JD, Gondi VB, Rawal VH. Asymmetric Proton Catalysis Enantioselective Organocatalysis: Reactions and Experimental Procedures. 189-254. DOI: 10.1002/9783527610945.ch6 |
0.77 |
|
| 2006 |
Iwama T, Rawal VH. Palladium-catalyzed regiocontrolled alpha-arylation of trimethylsilyl enol ethers with aryl halides. Organic Letters. 8: 5725-8. PMID 17134257 DOI: 10.1021/Ol062093G |
0.508 |
|
| 2006 |
Johnson PD, Sohn JH, Rawal VH. Synthesis of C-15 vindoline analogues by palladium-catalyzed cross-coupling reactions. The Journal of Organic Chemistry. 71: 7899-902. PMID 16995709 DOI: 10.1021/Jo061243Y |
0.685 |
|
| 2006 |
McGilvra JD, Unni AK, Modi K, Rawal VH. Highly diastereo- and enantioselective Mukaiyama aldol reactions catalyzed by hydrogen bonding. Angewandte Chemie (International Ed. in English). 45: 6130-3. PMID 16906613 DOI: 10.1002/Anie.200601638 |
0.82 |
|
| 2006 |
Huang Q, Rawal VH. Total synthesis of (+/-)-bipinnatin J. Organic Letters. 8: 543-5. PMID 16435880 DOI: 10.1021/Ol053054S |
0.444 |
|
| 2006 |
Rawal V, McGilvra J, Unni A, Modi K. Asymmetric Mukaiyama Aldol Reaction Catalyzed by Hydrogen Bonding Synfacts. 2006: 1172-1172. DOI: 10.1055/S-2006-949462 |
0.814 |
|
| 2005 |
Gondi VB, Gravel M, Rawal VH. Hydrogen bond catalyzed enantioselective vinylogous Mukaiyama aldol reaction. Organic Letters. 7: 5657-60. PMID 16321015 DOI: 10.1021/Ol052301P |
0.85 |
|
| 2005 |
Smith ND, Hayashida J, Rawal VH. Facile synthesis of the indeno-tetrahydropyridine core of haouamine A. Organic Letters. 7: 4309-12. PMID 16178520 DOI: 10.1021/Ol0512740 |
0.767 |
|
| 2005 |
MacKay JA, Bishop RL, Rawal VH. Rapid synthesis of the N-methylwelwitindolinone skeleton. Organic Letters. 7: 3421-4. PMID 16048307 DOI: 10.1021/Ol051043T |
0.744 |
|
| 2005 |
Sohn JH, Waizumi N, Zhong HM, Rawal VH. Total synthesis of mycalamide A. Journal of the American Chemical Society. 127: 7290-1. PMID 15898759 DOI: 10.1021/Ja050728L |
0.637 |
|
| 2005 |
Unni AK, Takenaka N, Yamamoto H, Rawal VH. Axially chiral biaryl diols catalyze highly enantioselective hetero-Diels-Alder reactions through hydrogen bonding. Journal of the American Chemical Society. 127: 1336-7. PMID 15686341 DOI: 10.1021/Ja044076X |
0.856 |
|
| 2005 |
Rawal V, Gondi V, Gravel M. Organocatalytic Asymmetric Vinylogous Mukaiyama Aldol Reaction Synfacts. 2006: 0079-0079. DOI: 10.1055/S-2005-921719 |
0.843 |
|
| 2005 |
Sohn J, Waizumi N, Zhong HM, Rawal VH. Total Synthesis of Mycalamide A (I). Cheminform. 36. DOI: 10.1002/chin.200542233 |
0.55 |
|
| 2004 |
Thadani AN, Stankovic AR, Rawal VH. Enantioselective Diels-Alder reactions catalyzed by hydrogen bonding. Proceedings of the National Academy of Sciences of the United States of America. 101: 5846-50. PMID 15069185 DOI: 10.1073/Pnas.0308545101 |
0.81 |
|
| 2004 |
Santos LS, Pilli RA, Rawal VH. Enantioselective total syntheses of (+)-arborescidine A, (-)-arborescidine B, and (-)-arborescidine C. The Journal of Organic Chemistry. 69: 1283-9. PMID 14961682 DOI: 10.1002/CHIN.200429188 |
0.44 |
|
| 2004 |
McGilvra JD, Rawal VH. Carbon-substituted Co(III) salens as effective catalysts for enantioselective Diels-Alder reactions Synlett. 2440-2442. DOI: 10.1055/S-2004-834799 |
0.849 |
|
| 2003 |
Waizumi N, Stankovic AR, Rawal VH. A general strategy to elisabethane diterpenes: stereocontrolled synthesis of elisapterosin B via oxidative cyclization of an elisabethin precursor. Journal of the American Chemical Society. 125: 13022-3. PMID 14570464 DOI: 10.1021/Ja035898H |
0.779 |
|
| 2003 |
Zhu X, Lambertino AT, Houghton TJ, McGilvra JD, Xu C, Rawal VH, Leff AR. Structural determinants of blockade of eosinophil activation, adhesion and secretion by synthetic analogs of phomactin. Life Sciences. 73: 3005-16. PMID 14519449 DOI: 10.1016/J.Lfs.2003.06.001 |
0.77 |
|
| 2003 |
Huang Y, Unni AK, Thadani AN, Rawal VH. Hydrogen bonding: single enantiomers from a chiral-alcohol catalyst. Nature. 424: 146. PMID 12853945 DOI: 10.1038/424146A |
0.822 |
|
| 2003 |
Kozmin SA, He S, Rawal VH. [4 + 2] Cycloaddition of 1‐Dimethylamino‐3‐tert‐Butyldimethylsiloxy‐1,3‐Butadiene with Methyl Acrylate: 4‐Hydroxymethyl‐2‐Cyclohexen‐1‐One Organic Syntheses. 160-160. DOI: 10.1002/0471264180.Os078.18 |
0.78 |
|
| 2003 |
Kozmin SA, He S, Rawal VH. Preparation of (E)‐1‐Dimethylamino‐3‐tert‐Butyldimethylsiloxy‐1,3‐Butadiene Organic Syntheses. 152-152. DOI: 10.1002/0471264180.Os078.17 |
0.745 |
|
| 2002 |
Thadani AN, Rawal VH. Multifunctional palladium catalysis. 2. Tandem haloallylation followed by Wacker-Tsuji oxidation or sonogashira cross-coupling. Organic Letters. 4: 4321-3. PMID 12443088 DOI: 10.1021/Ol0269603 |
0.459 |
|
| 2002 |
Thadani AN, Rawal VH. Stereospecific synthesis of highly substituted skipped dienes through multifunctional palladium catalysis. Organic Letters. 4: 4317-20. PMID 12443087 DOI: 10.1021/Ol0269594 |
0.577 |
|
| 2002 |
Huang Y, Rawal VH. Hydrogen-bond-promoted hetero-Diels-Alder reactions of unactivated ketones. Journal of the American Chemical Society. 124: 9662-3. PMID 12175197 DOI: 10.1021/Ja0267627 |
0.6 |
|
| 2002 |
Reddy TJ, Iwama T, Halpern HJ, Rawal VH. General synthesis of persistent trityl radicals for EPR imaging of biological systems. The Journal of Organic Chemistry. 67: 4635-9. PMID 12098269 DOI: 10.1021/Jo011068F |
0.319 |
|
| 2002 |
Huang Y, Iwama T, Rawal VH. Design and development of highly effective Lewis acid catalysts for enantioselective Diels-Alder reactions. Journal of the American Chemical Society. 124: 5950-1. PMID 12022822 DOI: 10.1021/Ja026088T |
0.509 |
|
| 2002 |
Kozmin SA, Iwama T, Huang Y, Rawal VH. An efficient approach to Aspidosperma alkaloids via [4 + 2] cycloadditions of aminosiloxydienes: stereocontrolled total synthesis of (+/-)-tabersonine. Gram-scale catalytic asymmetric syntheses of (+)-tabersonine and (+)-16-methoxytabersonine. Asymmetric syntheses of (+)-aspidospermidine and (-)-quebrachamine. Journal of the American Chemical Society. 124: 4628-41. PMID 11971711 DOI: 10.1021/Ja017863S |
0.775 |
|
| 2002 |
Huang Y, Iwama T, Rawal VH. Broadly effective enantioselective Diels-Alder reactions of 1-amino-substituted-1,3-butadienes. Organic Letters. 4: 1163-6. PMID 11922808 DOI: 10.1021/Ol0255716 |
0.611 |
|
| 2002 |
Takenaka N, Huang Y, Rawal VH. The first catalytic enantioselective Diels-Alder reactions of 1,2-dihydropyridine: Efficient syntheses of optically active 2-azabicyclo[2.2.2]octanes with chiral BINAM derived Cr(III) salen complexes Tetrahedron. 58: 8299-8305. DOI: 10.1016/S0040-4020(02)00980-8 |
0.715 |
|
| 2001 |
Houghton TJ, Choi S, Rawal VH. Efficient assembly of the phomactin core via two different macrocyclization protocols. Organic Letters. 3: 3615-7. PMID 11700095 DOI: 10.1021/Ol0163833 |
0.482 |
|
| 2001 |
Kozmin SA, He S, Rawal VH. Preparation of (E)-1-dimethylamino-3-tert-butyldimethylsiloxy-1,3-butadiene Organic Syntheses. 78: 152-158. |
0.584 |
|
| 2001 |
Kozmin SA, He S, Rawal VH. [4+2] Cycloaddition of 1-dimethylamino-3-tert-butyldimethylsiloxy-1,3- butadiene with methyl acrylate: 4-hydroxymethyl-2-cyclohexen-1-one Organic Syntheses. 78: 160-168. |
0.602 |
|
| 2000 |
Janey JM, Iwama T, Kozmin SA, Rawal VH. Racemic and asymmetric Diels-Alder reactions of 1-(2-oxazolidinon-3-yl)-3-siloxy-1,3-butadienes. The Journal of Organic Chemistry. 65: 9059-68. PMID 11149852 DOI: 10.1021/Jo005619Y |
0.845 |
|
| 2000 |
Huang Y, Rawal VH. Hetero Diels-Alder reactions of 1-amino-3-siloxy-1,3-butadienes under strictly thermal conditions. Organic Letters. 2: 3321-3. PMID 11029200 DOI: 10.1021/Ol006404D |
0.595 |
|
| 2000 |
Reddy TJ, Rawal VH. Expeditious syntheses of (+/-)-5-oxosilphiperfol-6-ene and (+/-)-silphiperfol-6-ene. Organic Letters. 2: 2711-2. PMID 10990434 DOI: 10.1021/Ol006292Q |
0.538 |
|
| 2000 |
He S, Kozmin SA, Rawal VH. Highly diastereoselective asymmetric thio-Claisen rearrangements Journal of the American Chemical Society. 122: 190-191. DOI: 10.1021/Ja992959W |
0.775 |
|
| 2000 |
Huang Y, Iwama T, Rawal VH. Highly enantioselective Diels-Alder reactions of 1-amino-3-siloxy-dienes catalyzed by Cr(III)-salen complexes [17] Journal of the American Chemical Society. 122: 7843-7844. DOI: 10.1021/Ja002058J |
0.542 |
|
| 1999 |
Kozmin SA, Janey JM, Rawal VH. 1-Amino-3-siloxy-1,3-butadienes: Highly Reactive Dienes for the Diels-Alder Reaction. The Journal of Organic Chemistry. 64: 3039-3052. PMID 11674400 DOI: 10.1021/Jo981563K |
0.839 |
|
| 1999 |
Iwama T, Birman VB, Kozmin SA, Rawal VH. Regiocontrolled synthesis of carbocycle-fused indoles via arylation of silyl enol ethers with o-nitrophenylphenyliodonium fluoride. Organic Letters. 1: 673-6. PMID 10823199 DOI: 10.1021/Ol990759J |
0.813 |
|
| 1999 |
Hennings DD, Iwama T, Rawal VH. Palladium-catalyzed (Ullmann-type) homocoupling of aryl halides: A convenient and general synthesis of symmetrical biaryls via inter- and intramolecular coupling reactions Organic Letters. 1: 1205-1208. DOI: 10.1021/Ol990872+ |
0.501 |
|
| 1999 |
Kozmin SA, Green MT, Rawal VH. On the reactivity of 1-amino-3-siloxy-1,3-dienes: Kinetics investigation and theoretical interpretation Journal of Organic Chemistry. 64: 8045-8047. DOI: 10.1021/Jo990923G |
0.65 |
|
| 1999 |
Kozmin SA, Janey JM, Rawal VH. 1-amino-3-siloxy-1,3-butadienes: Highly reactive dienes for the Diels- Alder reaction Journal of Organic Chemistry. 64: 3039-3052. DOI: 10.1021/jo981563k |
0.829 |
|
| 1999 |
Dorr H, Rawal VH. The intramolecular Diels-Alder reactions of photochemically generated trans-cycloalkenones [10] Journal of the American Chemical Society. 121: 10229-10230. DOI: 10.1021/Ja992287+ |
0.51 |
|
| 1999 |
Kozmin SA, Rawal VH. Chiral amino siloxy dienes in the Diels-Alder reaction: Applications to the asymmetric synthesis of 4-substituted and 4,5-disubstituted cyclohexenones and the total synthesis of (-)-α-elemene Journal of the American Chemical Society. 121: 9562-9573. DOI: 10.1021/Ja9921930 |
0.777 |
|
| 1998 |
Yotsu-Yamashita M, Yasumoto T, Rawal VH. Synthesis and confirmation of the structures of polonicumtoxins A, B and C Heterocycles. 48: 79-93. DOI: 10.3987/Com-97-8006 |
0.306 |
|
| 1998 |
Krishnamurthy V, Rawal VH. Novel routes to angular and linear triquinanes via radical induced epoxide fragmentation-H-abstraction-cyclization cascades Journal of the Brazilian Chemical Society. 9: 341-344. DOI: 10.1590/S0103-50531998000400006 |
0.308 |
|
| 1998 |
Birman VB, Rawal VH. A general, stereocontrolled route to the geissoschizine family of alkaloids. Concise synthesis of the apogeissoschizine skeleton Journal of Organic Chemistry. 63: 9146-9147. DOI: 10.1021/Jo981415U |
0.689 |
|
| 1998 |
Dvorak CA, Dufour C, Iwasa S, Rawal VH. Rapid Synthesis of Di- and Triquinanes by Direct Reductive Fragmentation of Paterno - Büchi-Derived Oxetanes Journal of Organic Chemistry. 63: 5302-5303. DOI: 10.1021/Jo980814M |
0.618 |
|
| 1998 |
Kozmin SA, Rawal VH. A general strategy to Aspidosperma alkaloids: Efficient, stereocontrolled synthesis of tabersonine [6] Journal of the American Chemical Society. 120: 13523-13524. DOI: 10.1021/Ja983198K |
0.675 |
|
| 1998 |
Birman VB, Rawal VH. A novel route to the geissoschizine skeleton: The influence of ligands on the diastereoselectivity of the heck cyclization Tetrahedron Letters. 39: 7219-7222. DOI: 10.1016/S0040-4039(98)01591-3 |
0.737 |
|
| 1998 |
Dvorak CA, Rawal VH. Catalysis of benzoin condensation by conformationally-restricted chiral bicyclic thiazolium salts Tetrahedron Letters. 39: 2925-2928. DOI: 10.1016/S0040-4039(98)00439-0 |
0.462 |
|
| 1998 |
Kozmin SA, Rawal VH. Asymmetric Diels-Alder reaction of chiral I-amino-3-siloxy-I,3-butadiene: Application to the enantioselective synthesis of (-)-α-elemene Chemtracts. 11: 41-45. |
0.74 |
|
| 1997 |
Hennings DD, Iwasa S, Rawal VH. Anion-Accelerated Palladium-Catalyzed Intramolecular Coupling of Phenols with Aryl Halides. The Journal of Organic Chemistry. 62: 2-3. PMID 11671356 DOI: 10.1021/Jo961876K |
0.621 |
|
| 1997 |
Dvorak CA, Rawal VH. Synthesis of the naturally occurring [3.3.3]propellane (±)-modhephene featuring a photocycloaddition-reductive fragmentation diquinane construction Chemical Communications. 2381-2382. DOI: 10.1039/A704260D |
0.362 |
|
| 1997 |
Kozmin SA, Rawal VH. Preparation and Diels-Alder Reactivity of 1-Amino-3-siloxy-1,3-butadienes Journal of Organic Chemistry. 62: 5252-5253. DOI: 10.1021/Jo970438Q |
0.689 |
|
| 1997 |
Kozmin SA, Rawal VH. Asymmetric Diels-Alder reactions of chiral 1-amino-3-siloxy-1,3- butadiene: Application to the enantioselective synthesis of (-)-α-elemene [5] Journal of the American Chemical Society. 119: 7165-7166. DOI: 10.1021/Ja971272D |
0.761 |
|
| 1997 |
Hennings DD, Iwasa S, Rawal VH. Anion-accelerated palladium-mediated intramolecular cyclizations: Synthesis of benzofurans, indoles, and a benzopyran Tetrahedron Letters. 38: 6379-6382. DOI: 10.1016/S0040-4039(97)01468-8 |
0.656 |
|
| 1997 |
Chambournier G, Krishnamurthy V, Rawal VH. Radical induced cyclopropane fragmentation - H-abstraction - Cyclization cascade: Synthesis of carbocyclic systems containing bridgehead methyl groups Tetrahedron Letters. 38: 6313-6316. DOI: 10.1016/S0040-4039(97)01450-0 |
0.376 |
|
| 1996 |
Rawal VH, Eschbach A, Dufour C, Iwasa S. Photocyclization-fragmentation route to di- and triquinanes: Stereocontrolled asymmetric synthesis of (-)-isocomene Pure and Applied Chemistry. 68: 675-678. DOI: 10.1351/Pac199668030675 |
0.698 |
|
| 1996 |
Dufour C, Iwasa S, Fabré A, Rawal VH. Unexpected fragmentations leading to quinanes and hydrindanes mediated by a silyl radical Tetrahedron Letters. 37: 7867-7870. DOI: 10.1016/0040-4039(96)01801-1 |
0.536 |
|
| 1995 |
Rawal VH, Fabré A, Iwasa S. Photocyclization-fragmentation route to linear triquinanes: Stereocontrolled synthesis of (±)-endo-hirsutene Tetrahedron Letters. 36: 6851-6854. DOI: 10.1016/0040-4039(95)01445-N |
0.619 |
|
| 1995 |
Rawal VH, Dufour C, Iwasa S. Photocycloaddition-fragmentation route to quinanes: Alternate fragmentation pathways Tetrahedron Letters. 36: 19-22. DOI: 10.1016/0040-4039(94)02159-9 |
0.51 |
|
| 1994 |
Rawal VH, Dufour C, Eschbach A. Stereocontrolled synthesis of isocomene by a novel photocycloaddition- fragmentation strategy Journal of the Chemical Society, Chemical Communications. 1797-1798. DOI: 10.1039/C39940001797 |
0.46 |
|
| 1994 |
Rawal VH, Iwasa S. A short, stereocontrolled synthesis of strychnine Journal of Organic Chemistry. 59: 2685-2686. DOI: 10.1021/Jo00089A008 |
0.586 |
|
| 1994 |
Rawal VH, Zhong HM. One-step conversion of esters to acyl azides using diethylaluminum azide Tetrahedron Letters. 35: 4947-4950. DOI: 10.1016/S0040-4039(00)73289-8 |
0.459 |
|
| 1994 |
Rawal VH, Florjancic AS, Singh SP. A new strategy for the synthesis of axially chiral biaryl compounds Tetrahedron Letters. 35: 8985-8988. DOI: 10.1016/0040-4039(94)88406-4 |
0.417 |
|
| 1993 |
Rawal VH, Singh SP, Dufour C, Michoud C. Scope of alkoxymethyl radical cyclizations Journal of Organic Chemistry. 58: 7718-7727. DOI: 10.1021/Jo00079A016 |
0.456 |
|
| 1993 |
Rawal VH, Michoud C. An unexpected Heck reaction. Inversion of olefin geometry facilitated by the apparent intramolecular carbamate chelation of the .sigma.-palladium intermediate Journal of Organic Chemistry. 58: 5583-5584. DOI: 10.1021/Jo00073A006 |
0.5 |
|
| 1993 |
Rawal VH, Michoud C, Monestel RF. General strategy for the stereocontrolled synthesis of Strychnos alkaloids: A concise synthesis of (±)-dehydrotubifoline Journal of the American Chemical Society. 115: 3030-3031. DOI: 10.1021/Ja00060A083 |
0.359 |
|
| 1993 |
Rawal VH, Zhong HM. Radical-induced epoxide fragmentation chemistry, V. Formation of medium-sized rings via β-scission of alkoxy radicals Tetrahedron Letters. 34: 5197-5200. DOI: 10.1016/S0040-4039(00)73951-7 |
0.382 |
|
| 1993 |
Rawal VH, Krishnamurthy V, Fabre A. Radical-induced epoxide fragmentation chemistry. n-Bu3Sn· radical catalyzed isomerization of epoxyketones to carbocycles Tetrahedron Letters. 34: 2899-2902. DOI: 10.1016/S0040-4039(00)60475-6 |
0.356 |
|
| 1993 |
Rawal VH, Michoud C. An unexpected Heck reaction. Inversion of olefin geometry facilitated by the apparent intramolecular carbamate chelation of the σ-palladium intermediate Journal of Organic Chemistry. 58: 5583-5584. |
0.462 |
|
| 1992 |
Rawal VH, Krishnamurthy V. Phenylthio radical catalyzed rearrangement of acetoxyalkenyl epoxides to acetoxyalkenyl cyclopentanols Tetrahedron Letters. 33: 3439-3442. DOI: 10.1016/S0040-4039(00)92657-1 |
0.384 |
|
| 1992 |
Rawal VH, Iwasa S. Radical-induced epoxide fragmentation chemistry. Atom transfer cyclization of iodoepoxides to cyclopentanols Tetrahedron Letters. 33: 4687-4690. DOI: 10.1016/S0040-4039(00)61259-5 |
0.624 |
|
| 1991 |
Rawal VH, Singh SP, Dufour C, Michoud C. Cyclization of alkoxymethyl radicals Journal of Organic Chemistry. 56: 5245-5247. DOI: 10.1021/Jo00018A005 |
0.303 |
|
| 1991 |
Rawal VH, Michoud C. A general solution to the synthesis of 2-azabicyclo[3.3.1]nonane unit of Strychnos alkaloids Tetrahedron Letters. 32: 1695-1698. DOI: 10.1016/S0040-4039(00)74306-1 |
0.478 |
|
| 1990 |
Rawal VH, Newton RC, Krishnamurthy V. Synthesis of carbocyclic systems via radical-induced epoxide fragmentation Journal of Organic Chemistry. 55: 5181-5183. DOI: 10.1021/Jo00305A001 |
0.317 |
|
| 1987 |
Rawal VH, Jones RJ, Cava MP. Review of synthetic studies toward CC-1065, PDE-I, and PDE-II Heterocycles. 25: 701-728. DOI: 10.3987/S-1987-01-0701 |
0.429 |
|
| 1987 |
Rawal VH, Jones RJ, Cava MP. Photocyclization strategy for the synthesis of antitumor agent CC-1065: Synthesis of dideoxy PDE-I and PDE-II. Synthesis of thiophene and furan analogues of dideoxy PDE-I and PDE-II Journal of Organic Chemistry. 52: 19-28. DOI: 10.1021/Jo00377A004 |
0.538 |
|
| 1987 |
RAWAL VH, JONES RJ, CAVA MP. ChemInform Abstract: Photocyclization Strategy for the Synthesis of Antitumor Agent CC-1065: Synthesis of Dideoxy PDE-I (I) and PDE-II (II). Synthesis of Thiophene and Furan Analogues of Dideoxy PDE-I and PDE-II. Cheminform. 18. DOI: 10.1002/chin.198728326 |
0.455 |
|
| 1986 |
Rawal VH, Cava MP. Photocyclization strategy for the synthesis of antitumor agent CC-1065. Synthesis of the B and C unit fragments Journal of the American Chemical Society. 108: 2110-2112. DOI: 10.1021/Ja00268A073 |
0.506 |
|
| 1986 |
RAWAL VH, CAVA MP. ChemInform Abstract: Photocyclization Strategy for the Synthesis of Antitumor Agent CC- 1065. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198632325 |
0.532 |
|
| 1985 |
Rawal VH, Appa Rao J, Cava MP. A convenient synthesis of t-butyldimethylsilyl protected cyanohydrins Tetrahedron Letters. 26: 4275-4278. DOI: 10.1016/S0040-4039(00)98711-2 |
0.525 |
|
| 1985 |
Rawal VH, Cava MP. Thermolytic removal of t-butyloxycarbonyl (BOC) protecting group on indoles and pyrroles Tetrahedron Letters. 26: 6141-6142. DOI: 10.1016/S0040-4039(00)95036-6 |
0.497 |
|
| 1985 |
Rawal VH, Jones RJ, Cava MP. Palladium mediated dehydrogenation in the photochemical cyclization of heterocyclic analogs of stilbene Tetrahedron Letters. 26: 2423-2426. DOI: 10.1016/S0040-4039(00)94843-3 |
0.496 |
|
| 1984 |
Rawal VH, Akiba M, Cava MP. α-METhoxythioanisole. Further Uses As An Umpolung Reagent Synthetic Communications. 14: 1129-1139. DOI: 10.1080/00397918408059645 |
0.598 |
|
| 1984 |
Rawal VH, Cava MP. Photocyclization of pyrrole analogues of stilbene: An expedient approach to antitumour agent CC-1065 Journal of the Chemical Society, Chemical Communications. 1526-1527. DOI: 10.1039/C39840001526 |
0.547 |
|
| 1983 |
Rawal VH, Cava MP. Synthesis of scillascillin, a naturally occurring benzocyclobutene Tetrahedron Letters. 24: 5581-5584. DOI: 10.1016/S0040-4039(00)94146-7 |
0.56 |
|
| 1983 |
Adesomoju AA, Rawal VH, Lakshmikantham MV, Cava MP. Cimilophytine, a new bisindole alkaloid from Haplophyton cimicidum (Apocynaceae) Journal of Organic Chemistry. 48: 3015-3017. DOI: 10.1002/Chin.198404314 |
0.454 |
|
| Show low-probability matches. |