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Donald J. Darensbourg, Ph.D. - Publications

Affiliations: 
1969-1973 Chemistry State University of New York, Buffalo, Buffalo, NY, United States 
 1973-1982 Chemistry Tulane University, New Orleans, LA, United States 
 1982- Chemistry Texas A & M University, College Station, TX, United States 
Area:
Organometallic chemistry, polymer chemistry
Website:
http://www.chem.tamu.edu/rgroup/djd/
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413 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Schoonover KG, Hsieh CM, Sengoden M, Ahmed N, Sivaperuman Kalairaj M, Ware TH, Darensbourg DJ, Pentzer EB, Wei P. Bridging polymer architecture, printability, and properties by digital light processing of block copolycarbonates. Chemical Science. PMID 39144463 DOI: 10.1039/d4sc04593a  0.726
2023 Jana M, Zheng X, Le T, Quiroz M, Guererro-Almaraz P, Darensbourg DJ, Darensbourg MY. Bond Trading: Intramolecular Metal and Ligand Exchange within a NO/Ni/Co Complex. Advanced Science (Weinheim, Baden-Wurttemberg, Germany). e2307113. PMID 38044312 DOI: 10.1002/advs.202307113  0.656
2023 Sengoden M, Bhat GA, Rutledge RJ, Rashid S, Dar AA, Darensbourg DJ. Micellar catalysis: Polymer bound palladium catalyst for carbon-carbon coupling reactions in water. Proceedings of the National Academy of Sciences of the United States of America. 120: e2312907120. PMID 37922331 DOI: 10.1073/pnas.2312907120  0.823
2023 Wei P, Bhat GA, Darensbourg DJ. Enabling New Approaches: Recent Advances in Processing Aliphatic Polycarbonate-Based Materials. Angewandte Chemie (International Ed. in English). e202307507. PMID 37534963 DOI: 10.1002/anie.202307507  0.564
2022 Sengoden M, Bhat GA, Darensbourg DJ. Bifunctional organoboron-phosphonium catalysts for coupling reactions of CO and epoxides. Rsc Advances. 12: 32440-32447. PMID 36425720 DOI: 10.1039/d2ra06358a  0.823
2022 Le TH, Nguyen H, Arnold HA, Darensbourg DJ, Darensbourg MY. Chirality-Guided Isomerization of MnS Diamond Core Complexes: A Mechanistic Study. Inorganic Chemistry. PMID 36194618 DOI: 10.1021/acs.inorgchem.2c02460  0.647
2022 Wei P, Bhat GA, Cipriani CE, Mohammad H, Schoonover K, Pentzer EB, Darensbourg DJ. 3D Printed CO -Based Triblock Copolymers and Post-Printing Modification. Angewandte Chemie (International Ed. in English). e202208355. PMID 35880834 DOI: 10.1002/anie.202208355  0.624
2021 Bhat GA, Darensbourg DJ, Rashad AZ, Ji X, Quiroz M, Fang L. TEMPO Containing Radical Polymonothicarbonate Polymers with Regio- and Stereo-Regularities: Synthesis, Characterization, and Electrical Conductivity Studies. Angewandte Chemie (International Ed. in English). PMID 34270852 DOI: 10.1002/anie.202108041  0.607
2020 Yue TJ, Bhat GA, Zhang WJ, Ren WM, Lu XB, Darensbourg DJ. Facile Synthesis of Well-Defined Branched Sulfur-Containing Copolymers via a "One-Pot" Copolymerization of Carbonyl Sulfide and Epoxide. Angewandte Chemie (International Ed. in English). PMID 32372553 DOI: 10.1002/Anie.202005806  0.64
2020 Kariyawasam Pathirana KD, Ghosh P, Hsieh CH, Elrod LC, Bhuvanesh N, Darensbourg DJ, Darensbourg MY. Synthetic Metallodithiolato Ligands as Pendant Bases in [FeFe], [Fe[Fe(NO)]], and [(μ-H)FeFe] Complexes. Inorganic Chemistry. PMID 32083850 DOI: 10.1021/Acs.Inorgchem.9B03409  0.651
2020 Bhat GA, Rashad AZ, Darensbourg DJ. Synthesis of terpyridine-containing polycarbonates with post polymerization providing water-soluble and micellar polymers and their metal complexes Polymer Chemistry. 11: 4699-4705. DOI: 10.1039/D0Py00850H  0.723
2020 Bhat GA, Darensbourg MY, Darensbourg DJ. Copolymerization of propylene oxide and 13 CO 2 to afford completely alternating regioregular 13 C-labeled Poly(propylene carbonate) Polymer Journal. 1-4. DOI: 10.1038/S41428-020-0391-0  0.779
2020 Wu S, Luo M, Darensbourg DJ, Zeng D, Yao Y, Zuo X, Hu X, Tan D. Non-Isocyanate and Catalyst-Free Synthesis of a Recyclable Polythiourethane with Cyclic Structure Acs Sustainable Chemistry & Engineering. 8: 5693-5703. DOI: 10.1021/Acssuschemeng.0C00435  0.34
2020 Tan D, Hu X, Cao Z, Luo M, Darensbourg DJ. Zwitterionic Alternating Polymerization to Generate Semicrystalline and Recyclable Cyclic Polythiourethanes Acs Macro Letters. 9: 866-871. DOI: 10.1021/Acsmacrolett.0C00302  0.396
2020 Bhat GA, Rashad AZ, Folsom TM, Darensbourg DJ. Placing Single-Metal Complexes into the Backbone of CO2-Based Polycarbonate Chains, Construction of Nanostructures for Prospective Micellar Catalysis Organometallics. 39: 1612-1618. DOI: 10.1021/Acs.Organomet.9B00704  0.678
2019 Le T, Nguyen H, Perez LM, Darensbourg D, Darensbourg MY. Metal-Templated, Tight Loop Conformation of a Cys-X-Cys Biomimetic Assembles a Dimanganese Complex. Angewandte Chemie (International Ed. in English). PMID 31851781 DOI: 10.1002/Anie.201913259  0.683
2019 Yempally V, Moncho S, Wang Y, Kyran SJ, Fan WY, Brothers EN, Darensbourg DJ, Bengali AA. Thermal Dehydrogenation of Dimethylamine Borane Catalyzed by a Bifunctional Rhenium Complex Organometallics. 38: 2602-2609. DOI: 10.1021/Acs.Organomet.9B00115  0.823
2019 Folsom TM, Bhat GA, Rashad AZ, Darensbourg DJ. Approach for Introducing a Single Metal Complex into a Polymer Chain: Metallo-Chain Transfer Agents in CO2 or COS/Epoxide Copolymerization Processes Macromolecules. 52: 5217-5222. DOI: 10.1021/Acs.Macromol.9B00906  0.702
2019 Folsom TM, Darensbourg DJ. Kinetic studies of thermal dissociation of carbon monoxide ligands from manganese tri- and tetra-carbonyl derivatives containing the bulky dipiperidylmethane ligand, CH2Pip2 Inorganica Chimica Acta. 484: 443-449. DOI: 10.1016/J.Ica.2018.09.004  0.474
2018 Sil D, Martinez Z, Ding S, Bhuvanesh N, Darensbourg DJ, Hall MB, Darensbourg MY. Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process. Journal of the American Chemical Society. PMID 30001628 DOI: 10.1021/Jacs.8B04189  0.641
2018 Huang Z, Wang Y, Zhang N, Zhang L, Darensbourg DJ. One-Pot Synthesis of Ion-Containing CO2-Based Polycarbonates Using Protic Ionic Liquids as Chain Transfer Agents Macromolecules. 51: 9122-9130. DOI: 10.1021/Acs.Macromol.8B01834  0.318
2018 Chen K, Shi G, Li H, Wang C, Darensbourg DJ. Design of Betaine Functional Catalyst for Efficient Copolymerization of Oxirane and CO2 Macromolecules. 51: 6057-6062. DOI: 10.1021/Acs.Macromol.8B01103  0.378
2018 Yang G, Zhang Y, Wang Y, Wu G, Xu Z, Darensbourg DJ. Construction of Autonomic Self-Healing CO2-Based Polycarbonates via One-Pot Tandem Synthetic Strategy Macromolecules. 51: 1308-1313. DOI: 10.1021/Acs.Macromol.7B02715  0.318
2018 Zhang Y, Yang G, Wang Y, Lu X, Wu G, Zhang Z, Wang K, Zhang R, Nealey PF, Darensbourg DJ, Xu Z. Synthesis of CO2-Based Block Copolymers via Chain Transfer Polymerization Using Macroinitiators: Activity, Blocking Efficiency, and Nanostructure Macromolecules. 51: 791-800. DOI: 10.1021/Acs.Macromol.7B02231  0.329
2018 Darensbourg DJ. Comments on the depolymerization of polycarbonates derived from epoxides and carbon dioxide: A mini review Polymer Degradation and Stability. 149: 45-51. DOI: 10.1016/J.Polymdegradstab.2018.01.019  0.36
2018 Folsom TM, Darensbourg DJ. Oxygen atom exchange in rhenium bipyridine and phenanthroline tetracarbonyl cations with H218O Polyhedron. 156: 58-63. DOI: 10.1016/J.Poly.2018.08.074  0.347
2018 Wang Y, Darensbourg DJ. Carbon dioxide-based functional polycarbonates: Metal catalyzed copolymerization of CO2 and epoxides Coordination Chemistry Reviews. 372: 85-100. DOI: 10.1016/J.Ccr.2018.06.004  0.394
2017 Yang JL, Wu HL, Li Y, Zhang XH, Darensbourg DJ. Perfectly Alternating and Regioselective Copolymerization of Carbonyl Sulfide and Epoxides by Metal-Free Lewis Pairs. Angewandte Chemie (International Ed. in English). PMID 28444916 DOI: 10.1002/Anie.201701780  0.425
2017 Darensbourg DJ. Switchable catalytic processes involving the copolymerization of epoxides and carbon dioxide for the preparation of block polymers Inorganic Chemistry Frontiers. 4: 412-419. DOI: 10.1039/C7Qi00013H  0.345
2017 Poland SJ, Darensbourg DJ. A quest for polycarbonates provided via sustainable epoxide/CO2copolymerization processes Green Chem.. 19: 4990-5011. DOI: 10.1039/C7Gc02560B  0.308
2017 Li Y, Duan H, Luo M, Zhang Y, Zhang X, Darensbourg DJ. Mechanistic Study of Regio-Defects in the Copolymerization of Propylene Oxide/Carbonyl Sulfide Catalyzed by (Salen)CrX Complexes Macromolecules. 50: 8426-8437. DOI: 10.1021/Acs.Macromol.7B01867  0.401
2016 Luo M, Zhang XH, Darensbourg DJ. Poly(monothiocarbonate)s from the Alternating and Regioselective Copolymerization of Carbonyl Sulfide with Epoxides. Accounts of Chemical Research. PMID 27676451 DOI: 10.1021/Acs.Accounts.6B00345  0.439
2016 Tsai FT, Wang Y, Darensbourg DJ. Environmentally Benign CO2-Based Copolymers: Degradable Polycarbonates Derived from Dihydroxybutyric Acid and Their Platinum-Polymer Conjugates. Journal of the American Chemical Society. PMID 26974858 DOI: 10.1021/Jacs.6B01327  0.387
2016 Wu GP, Darensbourg DJ. Mechanistic Insights into Water-Mediated Tandem Catalysis of Metal-Coordination CO2/Epoxide Copolymerization and Organocatalytic Ring-Opening Polymerization: One-Pot, Two Steps, and Three Catalysis Cycles for Triblock Copolymers Synthesis Macromolecules. 49: 807-814. DOI: 10.1021/Acs.Macromol.5B02752  0.387
2016 Darensbourg DJ. Copolymerization of Epoxides and CO2: Polymer Chemistry for Incorporation in Undergraduate Inorganic Chemistry Journal of Chemical Education. 94: 1691-1695. DOI: 10.1021/Acs.Jchemed.6B00505  0.366
2016 Han B, Zhang L, Kyran SJ, Liu B, Duan Z, Darensbourg DJ. Copolymerization of carbon dioxide and cyclohexene oxide catalyzed by chromium complexes bearing semirigid [ONSO]-type ligands Journal of Polymer Science, Part a: Polymer Chemistry. 54: 1938-1944. DOI: 10.1002/Pola.28052  0.831
2015 Wang Y, Fan J, Darensbourg DJ. Construction of Versatile and Functional Nanostructures Derived from CO2 -based Polycarbonates. Angewandte Chemie (International Ed. in English). PMID 26177634 DOI: 10.1002/Anie.201505076  0.345
2015 Luo M, Zhang XH, Darensbourg DJ. Highly regioselective and alternating copolymerization of carbonyl sulfide with phenyl glycidyl ether Polymer Chemistry. 6: 6955-6958. DOI: 10.1039/C5Py01197C  0.359
2015 Luo M, Zhang XH, Darensbourg DJ. Synthesis of cyclic monothiocarbonates via the coupling reaction of carbonyl sulfide (COS) with epoxides Catalysis Science and Technology. 6: 188-192. DOI: 10.1039/C5Cy00977D  0.404
2015 Darensbourg DJ, Wang Y. Terpolymerization of propylene oxide and vinyl oxides with CO2: Copolymer cross-linking and surface modification via thiol-ene click chemistry Polymer Chemistry. 6: 1768-1776. DOI: 10.1039/C4Py01612B  0.386
2015 Darensbourg DJ, Yeung AD. Kinetics of the (salen)Cr(iii)- and (salen)Co(iii)-catalyzed copolymerization of epoxides with CO2, and of the accompanying degradation reactions Polymer Chemistry. 6: 1103-1117. DOI: 10.1039/C4Py01322K  0.633
2015 Darensbourg DJ, Kyran SJ. Carbon Dioxide Copolymerization Study with a Sterically Encumbering Naphthalene-Derived Oxide Acs Catalysis. 5: 5421-5430. DOI: 10.1021/Acscatal.5B01375  0.811
2015 Kyran SJ, Sanchez SG, Arp CJ, Darensbourg DJ. Syntheses and Structures of [CH2(NCnH2n)2]Mo(CO)4 (n = 4,5) Complexes with Bis(cycloamine) Ligands Easily Prepared from CH2Cl2 Organometallics. 34: 3598-3602. DOI: 10.1021/Acs.Organomet.5B00396  0.793
2015 Luo M, Zhang XH, Darensbourg DJ. An Examination of the Steric and Electronic Effects in the Copolymerization of Carbonyl Sulfide and Styrene Oxide Macromolecules. 48: 6057-6062. DOI: 10.1021/Acs.Macromol.5B01427  0.439
2015 Luo M, Zhang XH, Darensbourg DJ. An Investigation of the Pathways for Oxygen/Sulfur Scramblings during the Copolymerization of Carbon Disulfide and Oxetane Macromolecules. 48: 5526-5532. DOI: 10.1021/Acs.Macromol.5B01251  0.413
2015 Darensbourg DJ, Chung WC, Yeung AD, Luna M. Dramatic behavioral differences of the copolymerization reactions of 1,4-cyclohexadiene and 1,3-cyclohexadiene oxides with carbon dioxide Macromolecules. 48: 1679-1687. DOI: 10.1021/Acs.Macromol.5B00172  0.639
2014 Yempally V, Kyran SJ, Raju RK, Fan WY, Brothers EN, Darensbourg DJ, Bengali AA. Thermal and photochemical reactivity of manganese tricarbonyl and tetracarbonyl complexes with a bulky diazabutadiene ligand. Inorganic Chemistry. 53: 4081-8. PMID 24689898 DOI: 10.1021/Ic500025K  0.812
2014 Mendes LL, Fernandes C, Franco RWA, Lube LM, Wei SH, Reibenspies JH, Darensbourg DJ, Horn A. Iron complexes containing electrochemically active diazocycle-bis(di-tert- butyl-phenol) ligands Journal of the Brazilian Chemical Society. 25: 1050-1061. DOI: 10.5935/0103-5053.20140078  0.511
2014 Pulukkody R, Kyran SJ, Drummond MJ, Hsieh CH, Darensbourg DJ, Darensbourg MY. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes Chemical Science. 5: 3795-3802. DOI: 10.1039/C4Sc01523A  0.792
2014 Darensbourg DJ, Yeung AD. A concise review of computational studies of the carbon dioxide-epoxide copolymerization reactions Polymer Chemistry. 5: 3949-3962. DOI: 10.1039/C4Py00299G  0.573
2014 Darensbourg DJ, Yeung AD. Kinetics and thermodynamics of the decarboxylation of 1,2-glycerol carbonate to produce glycidol: Computational insights Green Chemistry. 16: 247-252. DOI: 10.1039/C3Gc41643G  0.604
2014 Darensbourg DJ, Chung WC, Arp CJ, Tsai FT, Kyran SJ. Copolymerization and cycloaddition products derived from coupling reactions of 1,2-epoxy-4-cyclohexene and carbon dioxide. Postpolymerization functionalization via thiol-ene click reactions Macromolecules. 47: 7347-7353. DOI: 10.1021/Ma501781K  0.815
2014 Darensbourg DJ, Chung WC. Availability of other aliphatic polycarbonates derived from geometric isomers of butene oxide and carbon dioxide coupling reactions Macromolecules. 47: 4943-4948. DOI: 10.1021/Ma501004W  0.411
2014 Darensbourg DJ, Tsai FT. Postpolymerization functionalization of copolymers produced from carbon dioxide and 2-vinyloxirane: Amphiphilic/water-soluble CO2-Based polycarbonates Macromolecules. 47: 3806-3813. DOI: 10.1021/Ma500834R  0.396
2014 Darensbourg DJ, Chung WC, Wang K, Zhou HC. Sequestering CO2 for short-term storage in MOFs: Copolymer synthesis with oxiranes Acs Catalysis. 4: 1511-1515. DOI: 10.1021/Cs500259B  0.392
2014 Darensbourg DJ. Personal Adventures in the Synthesis of Copolymers from Carbon Dioxide and Cyclic Ethers Advances in Inorganic Chemistry. 66: 1-23. DOI: 10.1016/B978-0-12-420221-4.00001-9  0.378
2013 Muhammad S, Moncho S, Li B, Kyran SJ, Brothers EN, Darensbourg DJ, Bengali AA. Light-enhanced displacement of methyl acrylate from iron carbonyl: investigation of the reactive intermediate via rapid-scan Fourier transform infrared and computational studies. Inorganic Chemistry. 52: 12655-60. PMID 24128341 DOI: 10.1021/Ic401836N  0.796
2013 Feng D, Chung WC, Wei Z, Gu ZY, Jiang HL, Chen YP, Darensbourg DJ, Zhou HC. Construction of ultrastable porphyrin Zr metal-organic frameworks through linker elimination. Journal of the American Chemical Society. 135: 17105-10. PMID 24125517 DOI: 10.1021/Ja408084J  0.649
2013 Darensbourg DJ, Wu GP. A one-pot synthesis of a triblock copolymer from propylene oxide/carbon dioxide and lactide: intermediacy of polyol initiators. Angewandte Chemie (International Ed. in English). 52: 10602-6. PMID 23946153 DOI: 10.1002/Anie.201304778  0.389
2013 Pulukkody R, Kyran SJ, Bethel RD, Hsieh CH, Hall MB, Darensbourg DJ, Darensbourg MY. Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC). Journal of the American Chemical Society. 135: 8423-30. PMID 23668326 DOI: 10.1021/Ja403916V  0.795
2013 Li B, Kyran SJ, Yeung AD, Bengali AA, Darensbourg DJ. Acrylic acid derivatives of group 8 metal carbonyls: a structural and kinetic study. Inorganic Chemistry. 52: 5438-47. PMID 23614349 DOI: 10.1021/Ic4003737  0.825
2013 Sohail M, Moncho S, Brothers EN, Darensbourg DJ, Bengali AA. Estimating the strength of the M-H-B interaction: a kinetic approach. Dalton Transactions (Cambridge, England : 2003). 42: 6720-3. PMID 23584745 DOI: 10.1039/C3Dt50813G  0.317
2013 Darensbourg DJ, Yeung AD, Wei SH. Base initiated depolymerization of polycarbonates to epoxide and carbon dioxide co-monomers: A computational study Green Chemistry. 15: 1578-1583. DOI: 10.1039/C3Gc40475G  0.595
2013 Darensbourg DJ, Wilson SJ, Yeung AD. Oxygen/sulfur scrambling during the copolymerization of cyclopentene oxide and carbon disulfide: Selectivity for copolymer vs cyclic [Thio]carbonates Macromolecules. 46: 8102-8110. DOI: 10.1021/Ma4015438  0.625
2013 Darensbourg DJ, Wilson SJ. Synthesis of CO2-derived poly(indene carbonate) from indene oxide utilizing bifunctional cobalt(III) catalysts Macromolecules. 46: 5929-5934. DOI: 10.1021/Ma4013779  0.409
2013 Darensbourg DJ, Wei SH, Yeung AD, Ellis WC. An efficient method of depolymerization of poly(cyclopentene carbonate) to its comonomers: Cyclopentene oxide and carbon dioxide Macromolecules. 46: 5850-5855. DOI: 10.1021/Ma401286X  0.619
2013 Darensbourg DJ, Wei SH, Wilson SJ. Depolymerization of poly(indene carbonate). A unique degradation pathway Macromolecules. 46: 3228-3233. DOI: 10.1021/Ma400441M  0.369
2013 Wu GP, Xu PX, Lu XB, Zu YP, Wei SH, Ren WM, Darensbourg DJ. Crystalline CO2 copolymer from epichlorohydrin via Co(III)-complex-mediated stereospecific polymerization Macromolecules. 46: 2128-2133. DOI: 10.1021/Ma400252H  0.44
2013 Darensbourg DJ, Yeung AD. Thermodynamics of the carbon dioxide-epoxide copolymerization and kinetics of the metal-free degradation: A computational study Macromolecules. 46: 83-95. DOI: 10.1021/Ma3021823  0.611
2013 Darensbourg DJ, Chung WC, Wilson SJ. Catalytic coupling of cyclopentene oxide and CO2 utilizing bifunctional (salen)Co(III) and (salen)Cr(III) catalysts: Comparative processes involving binary (salen)Cr(III) analogs Acs Catalysis. 3: 3050-3057. DOI: 10.1021/Cs4008667  0.413
2013 Darensbourg DJ, Chung WC. Relative basicities of cyclic ethers and esters. Chemistry of importance to ring-opening co- and terpolymerization reactions Polyhedron. 58: 139-143. DOI: 10.1016/J.Poly.2012.08.076  0.377
2013 Darensbourg DJ, Kyran SJ, Yeung AD, Bengali AA. Kinetic and thermodynamic investigations of CO2 insertion reactions into Ru-Me and Ru-H bonds - An experimental and computational study European Journal of Inorganic Chemistry. 4024-4031. DOI: 10.1002/Ejic.201300179  0.813
2012 Muhammad S, Yempally V, Anas M, Moncho S, Kyran SJ, Brothers EN, Darensbourg DJ, Bengali AA. Mechanism of CO displacement from an unusually labile rhenium complex: an experimental and theoretical investigation. Inorganic Chemistry. 51: 13041-9. PMID 23153281 DOI: 10.1021/Ic302182B  0.815
2012 Wu GP, Darensbourg DJ, Lu XB. Tandem metal-coordination copolymerization and organocatalytic ring-opening polymerization via water to synthesize diblock copolymers of styrene oxide/CO2 and lactide. Journal of the American Chemical Society. 134: 17739-45. PMID 23016983 DOI: 10.1021/Ja307976C  0.397
2012 Muhammad S, Moncho S, Brothers EN, Darensbourg MY, Darensbourg DJ, Bengali AA. Time resolved infrared spectroscopy: kinetic studies of weakly binding ligands in an iron-iron hydrogenase model compound. Inorganic Chemistry. 51: 7362-9. PMID 22680284 DOI: 10.1021/Ic300785Z  0.662
2012 Lu XB, Darensbourg DJ. Cobalt catalysts for the coupling of CO2 and epoxides to provide polycarbonates and cyclic carbonates. Chemical Society Reviews. 41: 1462-84. PMID 21858339 DOI: 10.1039/C1Cs15142H  0.409
2012 Darensbourg DJ, Wilson SJ. What's new with CO2? Recent advances in its copolymerization with oxiranes Green Chemistry. 14: 2665-2671. DOI: 10.1039/C2Gc35928F  0.366
2012 Muhammad S, Kyran SJ, Raju RK, Brothers EN, Darensbourg DJ, Bengali AA. Time-resolved infrared spectroscopy studies of olefin binding in photogenerated CpRu(CO)X (X = Cl, I) transients Organometallics. 31: 3972-3979. DOI: 10.1021/Om300197B  0.781
2012 Kyran SJ, Muhammad S, Knestrick M, Bengali AA, Darensbourg DJ. Photochemically generated transients from κ 2- and κ 3-Triphos derivatives of group 6 metal carbonyls and their reactivity with olefins Organometallics. 31: 3163-3170. DOI: 10.1021/Om300044K  0.792
2012 Darensbourg DJ, Wei SH. Depolymerization of polycarbonates derived from carbon dioxide and epoxides to provide cyclic carbonates. A kinetic study Macromolecules. 45: 5916-5922. DOI: 10.1021/Ma301110C  0.396
2012 Darensbourg DJ, Poland RR, Escobedo C. Kinetic studies of the alternating copolymerization of cyclic acid anhydrides and epoxides, and the terpolymerization of cyclic acid anhydrides, epoxides, and CO 2 catalyzed by (salen)Cr IIICl Macromolecules. 45: 2242-2248. DOI: 10.1021/Ma2026385  0.74
2012 Tian D, Liu B, Gan Q, Li H, Darensbourg DJ. Formation of cyclic carbonates from carbon dioxide and epoxides coupling reactions efficiently catalyzed by robust, recyclable one-component aluminum-salen complexes Acs Catalysis. 2: 2029-2035. DOI: 10.1021/Cs300462R  0.456
2012 Darensbourg DJ. Salen metal complexes as catalysts for the synthesis of polycarbonates from cyclic ethers and carbon dioxide Advances in Polymer Science. 245: 1-28. DOI: 10.1007/12-2011-135  0.332
2012 Darensbourg DJ, Poland RR, Strickland AL. (Salan)CrCl, an effective catalyst for the copolymerization and terpolymerization of epoxides and carbon dioxide Journal of Polymer Science, Part a: Polymer Chemistry. 50: 127-133. DOI: 10.1002/Pola.24996  0.761
2011 Darensbourg DJ, Wilson SJ. Synthesis of poly(indene carbonate) from indene oxide and carbon dioxide--a polycarbonate with a rigid backbone. Journal of the American Chemical Society. 133: 18610-3. PMID 22023460 DOI: 10.1021/Ja208711C  0.408
2011 Wu GP, Wei SH, Ren WM, Lu XB, Xu TQ, Darensbourg DJ. Perfectly alternating copolymerization of CO2 and epichlorohydrin using cobalt(III)-based catalyst systems. Journal of the American Chemical Society. 133: 15191-9. PMID 21854028 DOI: 10.1021/Ja206425J  0.421
2011 Darensbourg DJ, Karroonnirun O, Wilson SJ. Ring-opening polymerization of cyclic esters and trimethylene carbonate catalyzed by aluminum half-salen complexes. Inorganic Chemistry. 50: 6775-87. PMID 21675736 DOI: 10.1021/Ic2008057  0.831
2011 Wu GP, Wei SH, Ren WM, Lu XB, Li B, Zu YP, Darensbourg DJ. Alternating copolymerization of CO2 and styrene oxide with Co(iii)-based catalyst systems: Differences between styrene oxide and propylene oxide Energy and Environmental Science. 4: 5084-5092. DOI: 10.1039/C1Ee02566J  0.436
2011 Swennenhuis BHG, Poland R, DeYonker NJ, Webster CE, Darensbourg DJ, Bengali AA. Ligand displacement from TpMn(CO)2L complexes: A large rate enhancement in comparison to the CpMn(CO)2L analogues Organometallics. 30: 3054-3063. DOI: 10.1021/Om200161G  0.738
2011 Darensbourg DJ, Moncada AI, Wei SH. Aliphatic polycarbonates produced from the coupling of carbon dioxide and oxetanes and their depolymerization via cyclic carbonate formation Macromolecules. 44: 2568-2576. DOI: 10.1021/Ma2002323  0.815
2011 Darensbourg DJ, Moncada AI, Wilson SJ. Ring-Opening Polymerization of Renewable Six-Membered Cyclic Carbonates. Monomer Synthesis and Catalysis Green Polymerization Methods: Renewable Starting Materials, Catalysis and Waste Reduction. 163-200. DOI: 10.1002/9783527636167.ch8  0.8
2010 Darensbourg DJ. Chemistry of carbon dioxide relevant to its utilization: a personal perspective. Inorganic Chemistry. 49: 10765-80. PMID 20973491 DOI: 10.1021/Ic101800D  0.333
2010 Swennenhuis BH, Poland R, Fan WY, Darensbourg DJ, Bengali AA. Ligand substitution from the (eta5-DMP)Mn(CO)2(Solv) [DMP = 2,5-dimethylpyrrole, Solv = solvent] complexes: to ring slip or not to ring slip? Inorganic Chemistry. 49: 7597-604. PMID 20690769 DOI: 10.1021/Ic101123Y  0.737
2010 Darensbourg DJ, Karroonnirun O. Ring-opening polymerization of lactides catalyzed by natural amino-acid based zinc catalysts. Inorganic Chemistry. 49: 2360-71. PMID 20121063 DOI: 10.1021/Ic902271X  0.834
2010 Darensbourg DJ, Horn A, Moncada AI. A facile catalytic synthesis of trimethylene carbonate from trimethylene oxide and carbon dioxide Green Chemistry. 12: 1376-1379. DOI: 10.1039/C0Gc00136H  0.814
2010 Darensbourg DJ, Karroonnirun O. Stereoselective ring-opening polymerization of rac -lactides catalyzed by chiral and achiral aluminum half-salen complexes Organometallics. 29: 5627-5634. DOI: 10.1021/Om100518E  0.818
2010 Wu GP, Wei SH, Lu XB, Ren WM, Darensbourg DJ. Highly selective synthesis of CO2 copolymer from styrene oxide Macromolecules. 43: 9202-9204. DOI: 10.1021/Ma1021456  0.329
2010 Darensbourg DJ, Karroonnirun O. Ring-opening polymerization of l-lactide and ε-caprolactone utilizing biocompatible zinc catalysts. random copolymerization of l-lactide and ε-caprolactone Macromolecules. 43: 8880-8886. DOI: 10.1021/Ma101784Y  0.806
2010 Darensbourg DJ, Moncada AI. Tuning the selectivity of the oxetane and CO2 coupling process catalyzed by (Salen)CrCl/ n-Bu4NX: Cyclic carbonate formation vs aliphatic polycarbonate production Macromolecules. 43: 5996-6003. DOI: 10.1021/Ma100896X  0.83
2010 DARENSBOURG DJ, LONGRIDGE EM, ATNIP EV, REIBENSPIES JH. ChemInform Abstract: A Linear, Monomeric Copper(I) Acetate Derivative, (Cu(phen)2)2(Cu( O2CCH3)2)×(O2CCH3)2H. An Effective Catalyst for the Decarboxylation of Carboxylic Acids. Cheminform. 24: no-no. DOI: 10.1002/chin.199301234  0.403
2010 DARENSBOURG DJ, JOO F, KANNISTO M, KATHO A, REIBENSPIES JH. ChemInform Abstract: Water-Soluble Organometallic Compounds. Part 2. Catalytic Hydrogenation of Aldehydes and Olefins by New Water-Soluble 1,3,5- Triaza-7-phosphaadamantane Complexes of Ruthenium and Rhodium. Cheminform. 23: no-no. DOI: 10.1002/chin.199239117  0.434
2010 DARENSBOURG DJ, LONGRIDGE EM, ATNIP EV, REIBENSPIES JH. ChemInform Abstract: Preparation and Solid-State Structure of a Novel Carboxylate Derivative of Copper(I), (Ph3P)2Cu(O2CCH2CN)2H Cheminform. 22: no-no. DOI: 10.1002/chin.199122232  0.407
2010 DARENSBOURG DJ, CHAO C, BISCHOFF C, REIBENSPIES JH. ChemInform Abstract: Solid-State and Solution Structure of (bpy)CuCo(CO)4 (bpy: 2,2′- Bipyridine). Cheminform. 22: no-no. DOI: 10.1002/chin.199108287  0.411
2010 Darensbourg DJ, Andreatta JR, Moncada AI. Polymers from Carbon Dioxide: Polycarbonates, Polythiocarbonates, and Polyurethanes Carbon Dioxide as Chemical Feedstock. 213-248. DOI: 10.1002/9783527629916.ch8  0.783
2009 Darensbourg DJ, Andreatta JR, Jungman MJ, Reibenspies JH. Investigations into the coupling of cyclohexene oxide and carbon disulfide catalyzed by (salen)CrCl. Selectivity for the production of copolymers vs. cyclic thiocarbonates. Dalton Transactions (Cambridge, England : 2003). 8891-9. PMID 19826721 DOI: 10.1039/B911061E  0.815
2009 Andreatta JR, Cieslinski GB, Batool M, Sun XZ, George MW, Brothers EN, Darensbourg DJ, Bengali AA. Displacement kinetics of eta(2)-bound furan and 2,3-dihydrofuran from Mn and Cr centers: evidence for the partial dearomatization of the furan ligand. Inorganic Chemistry. 48: 7787-93. PMID 19618936 DOI: 10.1021/Ic900724F  0.818
2009 Darensbourg DJ, Fitch SB. Copolymerization of epoxides and carbon dioxide. Evidence supporting the lack of dual catalysis at a single metal site. Inorganic Chemistry. 48: 8668-77. PMID 19537804 DOI: 10.1021/Ic900780A  0.449
2009 Darensbourg DJ, Ulusoy M, Karroonnirum O, Poland RR, Reibenspies JH, Çetinkaya B. Highly selective and reactive (salan)crcl catalyst for the copolymerization and block copolymerization of epoxides with carbon dioxide Macromolecules. 42: 6992-6998. DOI: 10.1021/Ma901364X  0.803
2009 Darensbourg DJ, Moncada AI. (Salen)Co(II)/n-Bu 4NX Catalysts for the coupling of CO 2 and oxetane: Selectivity for cyclic carbonate formation in the production of poly-(trimethylene carbonate) Macromolecules. 42: 4063-4070. DOI: 10.1021/Ma9002006  0.829
2008 Darensbourg DJ, Fitch SB. An exploration of the coupling reactions of epoxides and carbon dioxide catalyzed by tetramethyltetraazaannulene chromium(III) derivatives: formation of copolymers versus cyclic carbonates. Inorganic Chemistry. 47: 11868-78. PMID 19007156 DOI: 10.1021/Ic801728E  0.46
2008 Darensbourg DJ, Moncada AI. Mechanistic insight into the initiation step of the coupling reaction of oxetane or epoxides and CO2 catalyzed by (salen)CrX complexes. Inorganic Chemistry. 47: 10000-8. PMID 18821752 DOI: 10.1021/Ic801231P  0.826
2008 Darensbourg DJ, Frantz EB. X-Ray crystal structures of five-coordinate (salen)MnN3 derivatives and their binding abilities towards epoxides: chemistry relevant to the epoxide-CO2 copolymerization process. Dalton Transactions (Cambridge, England : 2003). 5031-6. PMID 18802616 DOI: 10.1039/B806364H  0.841
2008 Darensbourg DJ, Moncada AI, Choi W, Reibenspies JH. Mechanistic studies of the copolymerization reaction of oxetane and carbon dioxide to provide aliphatic polycarbonates catalyzed by (Salen)CrX complexes. Journal of the American Chemical Society. 130: 6523-33. PMID 18444619 DOI: 10.1021/Ja800302C  0.83
2008 Darensbourg DJ, Frantz EB. Studies of the carbon dioxide and epoxide coupling reaction in the presence of fluorinated manganese(III) acacen complexes: kinetics of epoxide ring-opening. Inorganic Chemistry. 47: 4977-87. PMID 18439001 DOI: 10.1021/Ic800286P  0.842
2008 Hongfa C, Tian J, Andreatta J, Darensbourg DJ, Bergbreiter DE. A phase separable polycarbonate polymerization catalyst. Chemical Communications (Cambridge, England). 975-7. PMID 18283354 DOI: 10.1039/B711861A  0.802
2008 Phan L, Andreatta JR, Horvey LK, Edie CF, Luco AL, Mirchandani A, Darensbourg DJ, Jessop PG. Switchable-polarity solvents prepared with a single liquid component. The Journal of Organic Chemistry. 73: 127-32. PMID 18067311 DOI: 10.1021/Jo7017697  0.766
2008 Darensbourg DJ, Choi W, Karroonnirun O, Bhuvanesh N. Ring-opening polymerization of cyclic monomers by complexes derived from biocompatible metals. Production of poly(lactide), poly(trimethylene carbonate), and their copolymers Macromolecules. 41: 3493-3502. DOI: 10.1021/Ma800078T  0.809
2007 Darensbourg DJ, Frantz EB. Manganese(III) Schiff base complexes: chemistry relevant to the copolymerization of epoxides and carbon dioxide. Inorganic Chemistry. 46: 5967-78. PMID 17579473 DOI: 10.1021/Ic7003968  0.827
2007 Darensbourg DJ, Fitch SB. (Tetramethyltetraazaannulene)chromium chloride: a highly active catalyst for the alternating copolymerization of epoxides and carbon dioxide. Inorganic Chemistry. 46: 5474-6. PMID 17567006 DOI: 10.1021/Ic7007842  0.445
2007 Darensbourg DJ. Making plastics from carbon dioxide: salen metal complexes as catalysts for the production of polycarbonates from epoxides and CO2. Chemical Reviews. 107: 2388-410. PMID 17447821 DOI: 10.1021/Cr068363Q  0.423
2007 Ribeiro R, Ganguly P, Darensbourg D, Usta M, Ucisik AH, Liang H. Biomimetic study of a polymeric composite material for joint repair applications Journal of Materials Research. 22: 1632-1639. DOI: 10.1557/Jmr.2007.0204  0.477
2007 Darensbourg DJ, Andreatta JR, Stranahan SM, Reibenspies JH. What is the real steric impact of triphenylphosphite? Solid-state and solution structural studies of cis- and trans-isomers of M(CO) 4[P(OPh)3]2 (M = Mo and W) Organometallics. 26: 6832-6838. DOI: 10.1021/Om700761Q  0.796
2007 Darensbourg DJ, Bottarelli P, Andreatta JR. Inquiry into the formation of cyclic carbonates during the (Salen)CrX catalyzed CO 2/cyclohexene oxide copolymerization process in the presence of ionic initiators Macromolecules. 40: 7727-7729. DOI: 10.1021/Ma071206O  0.805
2007 Darensbourg DJ, Choi W, Richers CP. Ring-opening polymerization of cyclic monomers by biocompatible metal complexes. production of poly(lactide), polycarbonates, and their copolymers Macromolecules. 40: 3521-3523. DOI: 10.1021/Ma062780N  0.619
2007 Darensbourg DJ, Frantz EB, Andreatta JR. Further studies related to the copolymerization of cyclohexene oxide and carbon dioxide catalyzed by chromium Schiff base complexes. Crystal structures of two μ-hydroxo-bridged Schiff base dimers of chromium(III) Inorganica Chimica Acta. 360: 523-528. DOI: 10.1016/J.Ica.2006.07.093  0.834
2006 Darensbourg DJ, Ganguly P, Choi W. Metal salen derivatives as catalysts for the alternating copolymerization of oxetanes and carbon dioxide to afford polycarbonates. Inorganic Chemistry. 45: 3831-3. PMID 16676934 DOI: 10.1021/Ic052109J  0.749
2006 Phelps AL, Rampersad MV, Fitch SB, Darensbourg MY, Darensbourg DJ. A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands. Inorganic Chemistry. 45: 119-26. PMID 16390047 DOI: 10.1021/Ic051367D  0.807
2006 Darensbourg DJ, Choi W, Ganguly P, Richers CP. Biometal derivatives as catalysts for the ring-opening polymerization of trimethylene carbonate. Optimization of the Ca(II) salen catalyst system Macromolecules. 39: 4374-4379. DOI: 10.1021/Ma0603433  0.725
2005 Rampersad MV, Jeffery SP, Golden ML, Lee J, Reibenspies JH, Darensbourg DJ, Darensbourg MY. Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands. Journal of the American Chemical Society. 127: 17323-34. PMID 16332082 DOI: 10.1021/Ja055051G  0.734
2005 Darensbourg DJ, Mackiewicz RM, Rodgers JL. Role of the cocatalyst in the copolymerization of CO2 and cyclohexene oxide utilizing chromium salen complexes. Journal of the American Chemical Society. 127: 14026-38. PMID 16201825 DOI: 10.1021/ja053544f  0.835
2005 Darensbourg DJ, Phelps AL. Effective, selective coupling of propylene oxide and carbon dioxide to poly(propylene carbonate) using (salen)CrN3 catalysts. Inorganic Chemistry. 44: 4622-9. PMID 15962970 DOI: 10.1021/Ic050443+  0.708
2005 Darensbourg DJ, Billodeaux DR. Aluminum salen complexes and tetrabutylammonium salts: a binary catalytic system for production of polycarbonates from CO2 and cyclohexene oxide. Inorganic Chemistry. 44: 1433-42. PMID 15732984 DOI: 10.1021/Ic048508G  0.793
2005 Rampersad MV, Jeffery SP, Reibenspies JH, Ortiz CG, Darensbourg DJ, Darensbourg MY. N2S2Ni metallothiolates as a class of ligands that support organometallic and bioorganometallic reactivity. Angewandte Chemie (International Ed. in English). 44: 1217-20. PMID 15696588 DOI: 10.1002/Anie.200461747  0.79
2005 Ribeiro R, Ganguly P, Darensbourg D, Usta M, Ucisik AH, Liang H. Bio-mimetic study of novel materials for joint replacements Materials Research Society Symposium Proceedings. 898: 72-79. DOI: 10.1557/Proc-0898-L05-19  0.508
2005 Darensbourg DJ, Mackiewicz RM, Billodeaux DR. Pressure dependence of the carbon dioxide/cyclohexene oxide coupling reaction catalyzed by chromium salen complexes. Optimization of the comonomer-alternating enchainment pathway Organometallics. 24: 144-148. DOI: 10.1021/Om049454L  0.811
2005 Darensbourg DJ, Ganguly P, Billodeaux D. Ring-opening polymerization of trimethylene carbonate using aluminum(III) and tin(IV) salen chloride catalysts Macromolecules. 38: 5406-5410. DOI: 10.1021/Ma050666J  0.804
2005 Darensbourg DJ, Mackiewicz aR, Rodgers JL. Role of the Cocatalyst in the Copolymerization of CO2 and Cyclohexene Oxide Utilizing Chromium Salen Complexes [J. Am. Chem. Soc. 2005, 127, 14026−14038]. Journal of the American Chemical Society. 127: 17565-17565. DOI: 10.1021/Ja059920D  0.629
2005 Darensbourg DJ, Lee WZ, Phelps AL. The synthesis and characterization of iron cyanide building blocks: [K]2[CpFe(CN)3] and its pentamethylcyclopentadienyl (Cp*) analog Inorganica Chimica Acta. 358: 4095-4098. DOI: 10.1016/J.Ica.2005.06.027  0.752
2004 Darensbourg DJ, Mackiewicz RM, Phelps AL, Billodeaux DR. Copolymerization of CO2 and epoxides catalyzed by metal salen complexes. Accounts of Chemical Research. 37: 836-44. PMID 15612673 DOI: 10.1021/Ar030240U  0.82
2004 Darensbourg DJ, Phelps AL, Gall NL, Jia L. Mechanistic studies of the copolymerization reaction of aziridines and carbon monoxide to produce poly-beta-peptoids. Journal of the American Chemical Society. 126: 13808-15. PMID 15493940 DOI: 10.1021/Ja046225H  0.67
2004 Darensbourg DJ, Mackiewicz RM, Rodgers JL, Fang CC, Billodeaux DR, Reibenspies JH. Cyclohexene oxide/CO2 copolymerization catalyzed by chromium(III) salen complexes and N-methylimidazole: effects of varying salen ligand substituents and relative cocatalyst loading. Inorganic Chemistry. 43: 6024-34. PMID 15360252 DOI: 10.1021/Ic049182E  0.828
2004 Darensbourg DJ, Mackiewicz RM, Rodgers JL, Phelps AL. (Salen)CrIIIX catalysts for the copolymerization of carbon dioxide and epoxides: role of the initiator and cocatalyst. Inorganic Chemistry. 43: 1831-3. PMID 15018499 DOI: 10.1021/Ic0352856  0.821
2004 Darensbourg DJ, Billodeaux DR, Ganguly P. Cis-Perhydro-1,4-benzodioxin-2,3-dione Acta Crystallographica Section E: Structure Reports Online. 60: o868-o869. DOI: 10.1107/S1600536804009055  0.752
2004 Darensbourg DJ, Billodeaux DR, Perez LM. 113Cd NMR determination of the binding parameters of alicyclic epoxides to [hydrotris(3-phenylpyrazol-1-yl)borate]Cd(II) acetate Organometallics. 23: 5286-5290. DOI: 10.1021/Om049761R  0.689
2004 Darensbourg DJ, Ganguly P, Billodeaux DR. Structural characterization of several (CO) 3(dppp)MnX derivatives, dppp = 1,3-bis(diphenylphosphino)propane and X = H, OTs, OC 2H 5, Cl, Br, or N 3. An assessment of their efficacy for catalyzing the coupling of carbon dioxide and epoxides Organometallics. 23: 6025-6030. DOI: 10.1021/Om049352V  0.825
2004 Darensbourg DJ, Ortiz CG, Kamplain JW. A New Water-Soluble Phosphine Derived from 1,3,5-Triaza-7-phosphaadamantane (PTA), 3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane. Structural, Bonding, and Solubility Properties Organometallics. 23: 1747-1754. DOI: 10.1021/Om0343059  0.702
2004 Darensbourg DJ, Fang CC, Rodgers JL. Catalytic coupling of carbon dioxide and 2,3-epoxy-1,2,3,4-tetrahydronaphthalene in the presence of a (Salen)CrIIICl derivative Organometallics. 23: 924-927. DOI: 10.1021/Om034278M  0.657
2004 Darensbourg DJ, Ortiz CG, Billodeaux DR. Synthesis and structural characterization of iron(III) salen complexes possessing appended anionic oxygen donor ligands Inorganica Chimica Acta. 357: 2143-2149. DOI: 10.1016/J.Ica.2003.12.019  0.825
2004 Darensbourg DJ, Phelps AL. Mixed metal cyanide complexes derived from the CpCo(CN)3 - anion Inorganica Chimica Acta. 357: 1603-1607. DOI: 10.1016/J.Ica.2003.11.016  0.698
2004 Darensbourg DJ, Billodeaux DR. Five-coordinate Schiff base complexes of gallium. Potential catalysts for the copolymerization of carbon dioxide and epoxides Comptes Rendus Chimie. 7: 755-761. DOI: 10.1016/J.Crci.2003.11.013  0.761
2004 Darensbourg DJ, Rodgers JL, Mackiewicz RM, Phelps AL. Probing the mechanistic aspects of the chromium salen catalyzed carbon dioxide/epoxide copolymerization process using in situ ATR/FTIR Catalysis Today. 98: 485-492. DOI: 10.1016/J.Cattod.2004.09.017  0.81
2004 Darensbourg DJ, Lee WZ, Adams MJ. Phosphine ligand derivatives of diamond-shaped, cyanide-bridged iron(II)-copper(I) complexes Inorganic Syntheses. 34: 172-177.  0.601
2003 Darensbourg DJ, Adams MJ, Yarbrough JC, Phelps AL. Synthesis and structural characterization of double metal cyanides of iron and zinc: catalyst precursors for the copolymerization of carbon dioxide and epoxides. Inorganic Chemistry. 42: 7809-18. PMID 14632496 DOI: 10.1021/Ic0347900  0.843
2003 Darensbourg DJ, Ortiz CG, Yarbrough JC. Synthesis and structures of nickel and palladium salicylaldiminato 1,3,5-triaza-7-phosphaadamantane (PTA) complexes. Inorganic Chemistry. 42: 6915-22. PMID 14552643 DOI: 10.1021/Ic0341284  0.839
2003 Darensbourg DJ, Rodgers JL, Fang CC. The copolymerization of carbon dioxide and [2-(3,4-epoxycyclohexyl)ethyl]trimethoxysilane catalyzed by (salen)CrCl. Formation of a CO2 soluble polycarbonate. Inorganic Chemistry. 42: 4498-500. PMID 12870932 DOI: 10.1021/Ic034363M  0.668
2003 Darensbourg DJ, Yarbrough JC, Ortiz C, Fang CC. Comparative kinetic studies of the copolymerization of cyclohexene oxide and propylene oxide with carbon dioxide in the presence of chromium salen derivatives. In situ FTIR measurements of copolymer vs cyclic carbonate production. Journal of the American Chemical Society. 125: 7586-91. PMID 12812499 DOI: 10.1021/Ja034863E  0.82
2003 Darensbourg DJ, Lewis SJ, Rodgers JL, Yarbrough JC. Carbon dioxide/epoxide coupling reactions utilizing Lewis base adducts of zinc halides as catalysts. Cyclic carbonate versus polycarbonate production. Inorganic Chemistry. 42: 581-9. PMID 12693242 DOI: 10.1021/Ic0259641  0.845
2003 Darensbourg DJ, Lee WZ, Phelps AL, Guidry E. Kinetic Study of the Insertion and Deinsertion of Carbon Dioxide into fac-(CO) 3(dppe)MnOR Derivatives Organometallics. 22: 5585-5588. DOI: 10.1021/Om034087J  0.818
2003 Darensbourg DJ, Yarbrough JC, Lewis SJ. 2-Thia-1,3,5-triaza-7-phosphaadamantane 2,2-dioxide (PASO2). Comparative structural and reactivity investigation with the water-soluble phosphine ligand 1,3,5-triaza-7-phosphaadamantane (PTA) Organometallics. 22: 2050-2056. DOI: 10.1021/Om0300225  0.788
2003 Darensbourg DJ, Phelps AL, Adams MJ, Yarbrough JC. Intermolecular hydrogen-bonding in the solid-state structure of CpFe(CN)2(PTAH). Structural and spectral comparisons with its [K][CpFe(CN)2PTA] salt Journal of Organometallic Chemistry. 666: 49-53. DOI: 10.1016/S0022-328X(02)02032-6  0.793
2003 Darensbourg DJ, Adams MJ, Yarbrough JC, Phelps AL. Synthesis and Structural Characterization of Potassium Salts of Phosphane-Substituted (Cyclopentadienyl)iron Dicyanides, and Their Use as Bridging Ligands for Copper(I) Phosphane Derivatives European Journal of Inorganic Chemistry. 3639-3648. DOI: 10.1002/Ejic.200300304  0.826
2002 Darensbourg DJ, Wildeson JR, Lewis SJ, Yarbrough JC. Solution and solid-state structural studies of epoxide adducts of cadmium phenoxides. Chemistry relevant to epoxide activation for ring-opening reactions. Journal of the American Chemical Society. 124: 7075-83. PMID 12059232 DOI: 10.1021/Ja020184C  0.821
2002 Darensbourg DJ, Yarbrough JC. Mechanistic aspects of the copolymerization reaction of carbon dioxide and epoxides, using a chiral salen chromium chloride catalyst. Journal of the American Chemical Society. 124: 6335-42. PMID 12033862 DOI: 10.1021/Ja012714V  0.763
2002 Darensbourg DJ, Wildeson JR, Yarbrough JC. Solid-state structures of zinc(II) benzoate complexes. Catalyst precursors for the coupling of carbon dioxide and epoxides. Inorganic Chemistry. 41: 973-80. PMID 11849101 DOI: 10.1021/Ic0107983  0.85
2002 Darensbourg DJ, Jason Adams M, Yarbrough JC. Synthesis, characterization and crystal structure of a zinc bis-dithiocarboxylate derivative Inorganic Chemistry Communications. 5: 38-41. DOI: 10.1016/S1387-7003(01)00342-2  0.741
2001 Darensbourg DJ, Adams MJ, Yarbrough JC. Toward the design of double metal cyanides for the copolymerization of CO(2) and epoxides. Inorganic Chemistry. 40: 6543-4. PMID 11735460 DOI: 10.1021/ic0155941  0.661
2001 Darensbourg DJ, Lee WZ, Yarbrough JC. Synthesis and characterization of a monocyanide-bridged bimetallic iron(II) and copper(I) complex. Inorganic Chemistry. 40: 6533-6. PMID 11720517 DOI: 10.1021/Ic010683Z  0.795
2001 Darensbourg DJ, Wildeson JR, Yarbrough JC, Taylor RE. Tricyclohexylphosphine derivatives of bis(2,6-difluorophenoxide)cadmium: a solution and solid-state NMR study. Inorganic Chemistry. 40: 3639-42. PMID 11421721 DOI: 10.1021/Ic010104Q  0.796
2001 Darensbourg DJ, Frost BJ, Larkins DL. An experimental and theoretical investigation of the carbon dioxide insertion process into the tungsten-nitrogen bond of an anionic W(0) complex. Inorganic Chemistry. 40: 1993-9. PMID 11304140 DOI: 10.1021/Ic001006S  0.822
2001 Darensbourg DJ, Wildeson JR, Yarbrough JC. Synthesis and structures of (dialkylamino)ethylcyclopentadienyl derivatives of zinc Organometallics. 20: 4413-4417. DOI: 10.1021/Om010519J  0.818
2001 Darensbourg DJ, Rainey P, Yarbrough J. Bis-salicylaldiminato complexes of zinc. Examination of the catalyzed epoxide/co2 copolymerization Inorganic Chemistry. 40: 986-993. DOI: 10.1021/Ic0006403  0.732
2001 Koning C, Wildeson J, Parton R, Plum B, Steeman P, Darensbourg DJ. Synthesis and physical characterization of poly(cyclohexane carbonate), synthesized from CO2 and cyclohexene oxide Polymer. 42: 3995-4004. DOI: 10.1016/S0032-3861(00)00709-6  0.8
2001 Darensbourg DJ, Lee WZ, Adams MJ, Yarbrough JC. Diamond-shaped heterometallic complexes of iron(II) and copper(I) bridged by cyanide groups containing monodentate or bidentate phosphanes bound to copper(I), including an alternative structure based on the nature of the bidentate phosphane ligand European Journal of Inorganic Chemistry. 2811-2822. DOI: 10.1002/1099-0682(200111)2001:11<2811::Aid-Ejic2811>3.0.Co;2-A  0.806
2000 Darensbourg DJ, Zimmer MS, Rainey P, Larkins DL. Solution and solid-state structures of phosphine adducts of monomeric zinc bisphenoxide complexes. Importance of these derivatives in CO2/epoxide copolymerization processes. Inorganic Chemistry. 39: 1578-85. PMID 12526468 DOI: 10.1021/Ic990594A  0.826
2000 Darensbourg DJ, Beckford FA, Reibenspies JH. Water-Soluble Organometallic Compounds. 8[1]. Synthesis, Spectral Properties, and Crystal Structures of 1,3,5-Triaza-7-phosphaadamantane (PTA) Derivatives of Metal Carbonyl Clusters: Ru3(CO)9(PTA)3 and Ir4(CO)7(PTA)5 Journal of Cluster Science. 11: 95-107. DOI: 10.1023/A:1009060614412  0.572
2000 Kovács J, Todd TD, Reibenspies JH, Joó F, Darensbourg DJ. Water-soluble organometallic compounds. 9. Catalytic hydrogenation and selective isomerization of olefins by water-soluble analogues of Vaska's complex Organometallics. 19: 3963-3969. DOI: 10.1021/Om000380X  0.579
2000 Darensbourg DJ, Wildeson JR, Yarbrough JC, Reibenspies JH. Bis 2,6-difluorophenoxide dimeric complexes of zinc and cadmium and their phosphine adducts: Lessons learned relative to carbon dioxide/cyclohexene oxide alternating copolymerization processes catalyzed by zinc phenoxides Journal of the American Chemical Society. 122: 12487-12496. DOI: 10.1021/Ja002855H  0.829
2000 Darensbourg DJ, Rainey P, Larkins DL, Reibenspies JH. Solution 31P and 113Cd NMR studies of phosphine adducts of monomeric cadmium (bisphenoxide) complexes and the solid-state structures of (2,6-di-tert-butylphenoxide)2Cd(PCy3) and (2,6-di-tert-butylphenoxide)2Cd(PMe3)2 Inorganic Chemistry. 39: 473-479. DOI: 10.1021/Ic991008G  0.533
2000 Darensbourg DJ, Yarbrough JC. Synthesis and crystal structure of [H2B(3-Phpz)2]2Zn Journal of Organometallic Chemistry. 614: 305-308. DOI: 10.1016/S0022-328X(00)00594-5  0.748
2000 Darensbourg DJ, Frost BJ, Larkins DL, Reibenspies JH. Organometallic complexes of uracil and orotic acid derivatives: Coordination mode, structure, and reactivity European Journal of Inorganic Chemistry. 2487-2495. DOI: 10.1002/1099-0682(200012)2000:12<2487::Aid-Ejic2487>3.0.Co;2-N  0.835
1999 Darensbourg DJ, Frost BJ, Derecskei-Kovacs A, Reibenspies JH. Coordination Chemistry, Structure, and Reactivity of Thiouracil Derivatives of Tungsten(0) Hexacarbonyl: A Theoretical and Experimental Investigation into the Chelation/Dechelation of Thiouracil via CO Loss and Addition. Inorganic Chemistry. 38: 4715-4723. PMID 11671196 DOI: 10.1021/Ic990758N  0.739
1999 Darensbourg DJ, Draper JD, Frost BJ, Reibenspies JH. Structural and Spectroscopic Studies of 16-Electron, Unsaturated Derivatives of Low-Valent, Group 6 Carbonyl Complexes Containing pi-Donor Ligands. Inorganic Chemistry. 38: 4705-4714. PMID 11671195 DOI: 10.1021/Ic9804216  0.672
1999 Darensbourg DJ, Niezgoda SA, Draper JD, Reibenspies JH. Trigonal-Planar Zinc(II) and Cadmium(II) Tris(phenoxide) Complexes. Inorganic Chemistry. 38: 1356-1359. PMID 11670926 DOI: 10.1021/Ic9805325  0.552
1999 Darensbourg DJ, Zimmer MS. Copolymerization and terpolymerization of CO2 and epoxides using a soluble zinc crotonate catalyst precursor Macromolecules. 32: 2137-2140. DOI: 10.1021/Ma9817471  0.438
1999 Darensbourg DJ, Holtcamp MW, Struck GE, Zimmer MS, Niezgoda SA, Rainey P, Robertson JB, Draper JD, Reibenspies JH. Catalytic activity of a series of Zn(II) phenoxides for the copolymerization of epoxides and carbon dioxide Journal of the American Chemical Society. 121: 107-116. DOI: 10.1021/Ja9826284  0.609
1999 Darensbourg DJ, Lee W, Adams MJ, Larkins DL, Reibenspies JH. Diamond-Shaped Heterometallic Complexes of Iron(II) and Copper(I) Bridged by Cyanide Groups Inorganic Chemistry. 38: 1378-1379. DOI: 10.1021/Ic981419H  0.795
1999 Darensbourg DJ, Robertson JB, Larkins DL, Reibenspies JH. Water-soluble organometallic compounds. 7.1 further studies of 1,3,5-triaza-7-phosphaadamantane derivatives of group 10 metals, including metal carbonyls and hydrides Inorganic Chemistry. 38: 2473-2481. DOI: 10.1021/Ic981243J  0.786
1999 Darensbourg DJ, Draper JD, Frost BJ, Reibenspies JH. Structural and spectroscopic studies of 16-electron, unsaturated derivatives of low-valent, group 6 carbonyl complexes containing π-donor ligands Inorganic Chemistry. 38: 4705-4714.  0.608
1998 Darensbourg DJ, Larkins DL, Reibenspies JH. Bis(triphenylphosphine)copper(I) Complexes of Orotate and L-Dihydroorotate. Inorganic Chemistry. 37: 6125-6128. PMID 11670757 DOI: 10.1021/Ic980464M  0.798
1998 Lai CH, Lee WZ, Miller ML, Reibenspies JH, Darensbourg DJ, Darensbourg MY. Responses of the Fe(CN)2(CO) unit to electronic changes as related to its role in [NiFe]hydrogenase Journal of the American Chemical Society. 120: 10103-10114. DOI: 10.1021/Ja982053A  0.762
1998 Darensbourg DJ, Niezgoda SA, Draper JD, Reibenspies JH. Mechanistic aspects of the copolymerization of CO2 and epoxides by soluble zinc bis(phenoxide) catalysts as revealed by their cadmium analogues Journal of the American Chemical Society. 120: 4690-4698. DOI: 10.1021/Ja9801487  0.582
1998 Darensbourg DJ, Draper JD, Larkins DL, Frost BJ, Reibenspies JH. Organometallic Derivatives of Orotic Acid. CO-Labilizing Ability of the Amido Group in Chromium and Tungsten Carbonyl Complexes Inorganic Chemistry. 37: 2538-2546. DOI: 10.1021/Ic980233F  0.832
1998 Darensbourg DJ, Zimmer MS, Rainey P, Larkins DL. Phosphine Adducts of Monomeric Zinc(bis-phenoxides): Solution and Solid-State Structures of (2,6-Di-tert-butylphenoxide)ZnL Complexes (L = PMePh2 and PCy3) Inorganic Chemistry. 37: 2852-2853. DOI: 10.1021/Ic980185Z  0.801
1998 Darensbourg DJ, Draper JD. Binucleating Coordination ofN,N‘-Ethylenebis(salicylideneamine) (H2salen) to Low-Valent Group 6 Carbonyl Complexes Inorganic Chemistry. 37: 5383-5386. DOI: 10.1021/Ic980173D  0.418
1998 Darensbourg DJ, Klausmeyer KK, Draper JD, Chojnacki JA, Reibenspies JH. The propensity of alkoxide and aryloxide derivatives of tungsten carbonyls to aggregate in solution. Synthesis and X-ray structures of dinuclear, trinuclear and tetranuclear complexes derived from the MeOW(CO)5 - anion Inorganica Chimica Acta. 270: 405-413. DOI: 10.1016/S0020-1693(97)05996-3  0.731
1998 Darensbourg DJ, Yoder JC, Struck GE, Holtcamp MW, Draper JD, Reibenspies JH. Crystal structures of aryloxide complexes of zinc embracing sodium aryl group interactions: Na[Zn(2,6-diphenylphenoxide)3(H2O)] and Na[Zn2(2,6-diisopropylphenoxide)4Cl] · 3THF Inorganica Chimica Acta. 274: 115-121. DOI: 10.1016/S0020-1693(97)05962-8  0.576
1998 Orchin M, Mandal SK, Feldman J, Lee WZ, Darensbourg DJ. Tricarbonyl(hydrido) [1,2-bis(diphenylphosphino)ethane]manganese as precursor to labile site derivatives Inorganic Syntheses. 32: 298-302. DOI: 10.1002/9780470132630.Ch48  0.602
1998 Hakansson M, Niezgoda S, Darensbourg DJ. Labile copper(I) chloride complexes: Preparation and handling Inorganic Syntheses. 32: 222-228. DOI: 10.1002/9780470132630.Ch37  0.371
1998 Joó F, Kovács J, Kathó A, Bényei AC, Decuir T, Darensbourg DJ, Miedaner A, Dubois DL. (Meta-sulfonatophenyl)diphenylphosphine, sodium salt and its complexes with rhodium(I), ruthenium(II), iridium(I) Inorganic Syntheses. 32: 1-8. DOI: 10.1002/9780470132630.Ch1  0.353
1997 Darensbourg DJ, Niezgoda SA, Reibenspies JH, Draper JD. Structural Diversity in Monomeric Cadmium Phenoxides. Inorganic Chemistry. 36: 5686-5688. PMID 11670185 DOI: 10.1021/Ic971002W  0.555
1997 Darensbourg DJ, Draper JD, Reibenspies JH. Amino Acid Complexes of Metal Carbonyls: Mechanistic Aspects of the CO-Labilizing Ability of Glycinate Ligands in Zero-Valent Chromium and Tungsten Derivatives. Inorganic Chemistry. 36: 3648-3656. PMID 11670056 DOI: 10.1021/Ic961344M  0.559
1997 Darensbourg DJ, Niezgoda SA, Holtcamp MW, Draper JD, Reibenspies JH. Syntheses, Structures, and Binding Constants of Cyclic Ether and Thioether Adducts of Soluble Cadmium(II) Carboxylates. Intermediates in the Homopolymerization of Oxiranes and Thiiranes and in Carbon Dioxide Coupling Processes. Inorganic Chemistry. 36: 2426-2432. PMID 11669881 DOI: 10.1021/Ic9701120  0.619
1997 Darensbourg DJ, Reibenspies JH, Lai CH, Lee WZ, Darensbourg MY. Analysis of an organometallic iron site model for the heterodimetallic unit of [NiFe]hydrogenase Journal of the American Chemical Society. 119: 7903-7904. DOI: 10.1021/Ja971559A  0.739
1997 Darensbourg DJ, Decuir TJ, Stafford NW, Robertson JB, Draper JD, Reibenspies JH, Kathó A, Joó F. Water-Soluble Organometallic Compounds. 6. 1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals Inorganic Chemistry. 36: 4218-4226. DOI: 10.1021/Ic970238X  0.601
1996 Darensbourg DJ, Meckfessel Jones ML, Reibenspies JH. The Reversible Insertion Reaction of Carbon Dioxide with the W(CO)(5)OH(-) Anion. Isolation and Characterization of the Resulting Bicarbonate Complex [PPN][W(CO)(5)O(2)COH]. Inorganic Chemistry. 35: 4406-4413. PMID 11666659 DOI: 10.1021/Ic9516525  0.598
1996 Darensbourg DJ, Maynard EL, Holtcamp MW, Klausmeyer KK, Reibenspies JH. Synthesis and X-ray Structure of the Novel Aluminum Complex [{eta(3)-HB(3-Phpz)(2)(5-Phpz)}(2)Al][AlCl(4)]. Catalysis of CO(2)/Propylene Oxide to Propylene Carbonate by the AlCl(4)(-) Anion. Inorganic Chemistry. 35: 2682-2684. PMID 11666488 DOI: 10.1021/Ic951018R  0.744
1996 Darensbourg DJ, Klausmeyer KK, Reibenspies JH. Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by pi-Donating Amido Ligands. Inorganic Chemistry. 35: 1535-1539. PMID 11666369 DOI: 10.1021/Ic950985Z  0.717
1996 Darensbourg DJ, Klausmeyer KK, Reibenspies JH. Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the pi-Donating Ligand 3,5-Di-tert-butylcatecholate. Inorganic Chemistry. 35: 1529-1534. PMID 11666368 DOI: 10.1021/Ic950968+  0.706
1996 Reibenspies JH, Draper JD, Darensbourg DJ. Crystal structure of tetraethylammonium bis(3,5-di-(tert-butyl)-catecholate)dioxorhenate, C36H60NO6Re Zeitschrift FüR Kristallographie - Crystalline Materials. 211. DOI: 10.1524/Zkri.1996.211.7.501  0.484
1996 Reibenspies JH, Draper JD, Struck G, Darensbourg DJ. Crystal structure of tricyclohexylphosphine sulfide, (C6H11)3PS Zeitschrift Fur Kristallographie. 211: 400. DOI: 10.1524/Zkri.1996.211.6.400  0.453
1996 Reibenspies JH, Darensbourg DJ, Benyei AC. Crystal structure of aqua-bis(2, 9-dimethyl-1, 10-phenanthroline)-p-toluenesulfonatoruthenium(II)p-toulenesulfonate-methanol-hydrate(1/2/2),[Ru(C14H12N2)2(CH3C6H4SO3)(OH2)]CH3C6H4SO3·2CH3OH·2H2O Zeitschrift Fur Kristallographie. 211: 977-979. DOI: 10.1524/Zkri.1996.211.12.977  0.486
1996 Darensbourg DJ, Yoder JC, Holtcamp MW, Klausmeyer KK, Reibenspies JH. Cyanide-Bridged Heterobimetallic Complexes of the Group 6 Metal Carbonyls and Copper(I). X-ray Structures of (CO)5MCNCu(PPh3)3 (M = Cr, W) Derivatives Inorganic Chemistry. 35: 4764-4769. DOI: 10.1021/Ic9510627  0.724
1996 Darensbourg DJ, Holtcamp MW, Reibenspies JH. Structural characterizations of coordination complexes of bis-triphenylphosphine copper(I) dicarboxylates Polyhedron. 15: 2341-2349. DOI: 10.1016/0277-5387(95)00518-8  0.57
1996 Joó F, Nádasdi L, Bényei AC, Darensbourg DJ. Aqueous organometallic chemistry: The mechanism of catalytic hydrogenations with chlorotris(1,3,5-triaza-7-phosphaadamantane) rhodium(I) Journal of Organometallic Chemistry. 512: 45-50. DOI: 10.1016/0022-328X(95)05946-M  0.347
1996 Darensbourg DJ, Holtcamp MW. Catalysts for the reactions of epoxides and carbon dioxide Coordination Chemistry Reviews. 153: 155-174. DOI: 10.1016/0010-8545(95)01232-X  0.444
1996 Darensbourg DJ, Klausmeyer KK, Reibenspies JH. Coordinatively and Electronically Unsaturated Tungsten(0) Carbonyl Complexes Stabilized by π-Donating Amido Ligands Inorganic Chemistry. 35: 1535-1539.  0.611
1996 Darensbourg DJ, Klausmeyer KK, Reihenspies JH. Coordinatively Unsaturated Derivatives of Group 6 Metal Carbonyls Containing the π-Donating Ligand 3,5-Di-tert-butylcatecholate Inorganic Chemistry. 35: 1529-1534.  0.624
1996 Reibenspies JH, Darensbourg DJ, Benyei AC. Crystal structure of aqua-bis(2,9-dimethyl-1,10-phenanthroline)-p-toluene-sulfonatoruthenium(II) p-toulenesulfonate-methanol-hydrate(1/2/2), [Ru(C14H12N2)2(CH3C 6H4SO3)(OH2)]CH3C 6H4SO3 · 2CH3OH · 2H2O Zeitschrift Fur Kristallographie. 211: 977-979.  0.428
1996 Darensbourg DJ, Maynard EL, Holtcamp MW, Klausmeyer KK, Reibenspies JH. Synthesis and X-ray Structure of the Novel Aluminum Complex [{η3-HB(3-Phpz)2(5-Phpz)]2Al[AlCl 4]. Catalysis of CO2/Propylene Oxide to Propylene Carbonate by the AlCl4 - Anion Inorganic Chemistry. 35: 2682-2684.  0.639
1995 Reibenspies JH, Klausmeyer K, Niezgoda SA, Holtcamp MW, Darensbourg DJ. Crystal structure of bis(hydro(tris-3-phenylpyrazolyl)borate)-cadmium(II), C27H21BCd0.50N6 Zeitschrift Fur Kristallographie - New Crystal Structures. 210: 617-618. DOI: 10.1524/Zkri.1995.210.8.617  0.671
1995 Darensbourg DJ, Holtcamp MW, Klausmeyer KK, Reibenspies JH. Crystal structure of di-μ-chloro-tris(triphenylphosphine)dicopper(I)-diehloromethane, C55H47Cl4CU2P3 Zeitschrift Fur Kristallographie - New Crystal Structures. 210: 615-616. DOI: 10.1524/Zkri.1995.210.8.615  0.658
1995 Reibenspies JH, Holtcamp MW, Khandelwal B, Darensbourg DJ. Crystal structure of acetato-l,5,9-triazacyclododecane-zinc tetraphenylborate, [(C9H2iN3)(CH3C02)Zn] [(C6H5)4B] Zeitschrift Fur Kristallographie - New Crystal Structures. 210: 148-149. DOI: 10.1524/Zkri.1995.210.2.148  0.467
1995 Reibenspies JH, Holtcamp MW, Khandelwal B, Darensbourg DJ. Crystal structure of cyanoacetato-tetrahydrofuran-tris(3-phenyl-pyrazol-l-yl)hydroborato-cadmium, C34H32BCdN7O3 Zeitschrift Fur Kristallographie - New Crystal Structures. 210: 146-147. DOI: 10.1524/Zkri.1995.210.2.146  0.468
1995 Reibenspies JH, Klausmeyer KK, Darensbourg DJ. Crystal structure of bis(tetraethylammonium) hexafluorotungstate(IV) dihydrate, ((C2H5)4N)2(WF6)(H2O)2 Zeitschrift Fur Kristallographie - New Crystal Structures. 210: 882. DOI: 10.1524/Zkri.1995.210.11.882  0.666
1995 Darensbourg DJ, Holtcamp MW. Catalytic activity of zinc(II) phenoxides which possess readily accessible coordination sites. Copolymerization and terpolymerization of epoxides and carbon dioxide Macromolecules. 28: 7577-7579. DOI: 10.1021/Ma00126A043  0.375
1995 Reger DL, Myers SM, Mason SS, Darensbourg DJ, Holtcamp MW, Reibenspies JH, Lipton AS, Ellis PD. 113Cd Shielding Tensors of Monomeric Cadmium Compounds Containing Nitrogen Donor Atoms. 3. Syntheses, Crystal Structure, and 113Cd NMR Spectroscopy of the Six-Coordinate Complexes [HB(pz)3]2Cd, [HB(3-Phpz)3]2Cd, and [B(pz)4]Cd[HB(3-Phpz)3] (pz = pyrazolyl) Journal of the American Chemical Society. 117: 10998-11005. DOI: 10.1021/Ja00149A024  0.478
1995 Darensbourg DJ, Holtcamp MW, Khandelwal B, Klausmeyer KK, Reibenspies JH. Syntheses and structures of epoxide adducts of soluble cadmium(II) carboxylates. Models for the initiation process in epoxide/CO2 coupling reactions Journal of the American Chemical Society. 117: 538-539. DOI: 10.1021/Ja00106A065  0.705
1995 Darensbourg DJ, Holtcamp MW, Longridge EM, Khandelwal B, Klausmeyer KK, Reibenspies JH. Role of the metal center in the homogeneous catalytic decarboxylation of select carboxylic acids. Copper(I) and zinc(II) derivatives of cyanoacetate Journal of the American Chemical Society. 117: 318-328. DOI: 10.1021/Ja00106A034  0.69
1995 Darensbourg DJ, Holtcamp MW, Khandelwal B, Reibenspies JH. Coordination complexes of bis(triphenylphosphine) copper(I) carbonate and bicarbonate Inorganic Chemistry. 34: 5390-5394. DOI: 10.1021/Ic00125A047  0.585
1995 Darensbourg DJ, Klausmeyer KK, Reibenspies JH. CO-labilizing ability of the fluoride ligand in tungsten(0) carbonyl fluorides. X-ray structure of [Et4N]3[W2(CO)6F3] Inorganic Chemistry. 34: 4933-4934. DOI: 10.1021/Ic00124A002  0.677
1995 Darensbourg DJ, Klausmeyer KK, Reibenspies JH. Chromium tricarbonyl catecholate derivatives. Structural and reactivity studies of "16-electron" complexes Inorganic Chemistry. 34: 4676-4681. DOI: 10.1021/Ic00122A026  0.688
1995 Darensbourg DJ, Holtcamp MW, Khandelwal B, Klausmeyer KK, Reibenspies JH. A more intimate examination of the role of copper(I) in the decarboxylation of derivatives of malonic acid. Comparisons with zinc(II) analogs Inorganic Chemistry. 34: 2389-2398. DOI: 10.1021/Ic00113A021  0.662
1995 Darensbourg DJ, Stafford NW, Katsurao T. Supercritical carbon dioxide as solvent for the copolymerization of carbon dioxide and propylene oxide using a heterogeneous zinc carboxylate catalyst Journal of Molecular Catalysis. a, Chemical. 104: L1-L4. DOI: 10.1016/1381-1169(95)00142-5  0.402
1995 Darensbourg DJ, Stafford NW, Joó F, Reibenspies JH. Water-soluble organometallic compounds. 5. The regio-selective catalytic hydrogenation of unsaturated aldehydes to saturated aldehydes in an aqueous two-phase solvent system using 1,3,5-triaza-7-phosphaadamantane complexes of rhodium Journal of Organometallic Chemistry. 488: 99-108. DOI: 10.1016/0022-328X(94)00024-7  0.592
1995 Reger DL, Myers SM, Mason SS, Darensbourg DJ, Holtcamp MW, Reibenspies JH, Lipton AS, Ellis PD. 113Cd shielding tensors of monomeric cadmium compounds containing nitrogen donor atoms. 2. Syntheses, crystal structures, and 113Cd NMR spectroscopy of the six-coordinate complexes [HB(pz)3]2Cd, [HB(3-Phpz)3]2Cd, and [B(pz)4]Cd[HB(3-Phpz)3] (pz = pyrazolyl) Journal of the American Chemical Society. 117: 10998-11005.  0.385
1994 Reibenspies JH, Klausmeyer K, Darensbourg D. Crystal structure of tetraethylammonium bis(catecholato)-dioxo-molybdenum(VI), C28H48MoN2O6 Zeitschrift Fur Kristallographie - New Crystal Structures. 209: 761-762. DOI: 10.1524/Zkri.1994.209.9.761  0.66
1994 Reibenspies JH, Darensbourg D, Atnip E. Crystal structure of diphenylphosphinepentacarbonyltungsten(0), (C6H5)2PH(CO)5W Zeitschrift FüR Kristallographie - Crystalline Materials. 209. DOI: 10.1524/Zkri.1994.209.9.759  0.444
1994 Reibenspies JH, Darensbourg DJ, Niezgoda SA, Holtcamp MH, Klausmeyer KK. Crystal structure of bis(bis(triphenylphosphane)-μεN,0-cyanoacetato)copper(I)tetrahydrofuran, CH86Cu2N2O6P4 Zeitschrift Fur Kristallographie - New Crystal Structures. 209: 552-553. DOI: 10.1524/Zkri.1994.209.6.552  0.67
1994 Reibenspies J, Darensbourg D, Atnip E. Crystal structure of μ-N,N′-malodinitrile-bis(pentacarbonyltungsten) methylene chloride, C13H4Cl2N2O10W Zeitschrift FüR Kristallographie - Crystalline Materials. 209. DOI: 10.1524/Zkri.1994.209.4.379  0.5
1994 Reibenspies J, Darensbourg D, Jones-Meckfessel M. Crystal structure of tetraethylammonium O-methyldithiocarbonate, C10H23NOS2 Zeitschrift FüR Kristallographie - Crystalline Materials. 209. DOI: 10.1524/Zkri.1994.209.4.377  0.446
1994 Darensbourg DJ, Longridge EM, Khandelwal B, Reibenspies JH. Synthesis and structure of 1, 2-BIS (diphenylphosphino)ethane complexes of copper(I) acetate. catalysts for the decarboxylation of carboxylic acids Journal of Coordination Chemistry. 32: 27-37. DOI: 10.1080/00958979408024235  0.587
1994 Darensbourg DJ, Fontal B, Chojnacki SS, Klausmeyer KK, Reibenspies JH. Aryloxide and alkoxide derivatives of metal clusters. Syntheses, structures, and reactivities of the μ-oxo-bridged triruthenium clusters Ru3(CO)8(μ-η2-OC6H 4Cl)2 and Ru3(CO)8(μ-η2-OCH2C 5H4N)2 Inorganic Chemistry®. 33: 3526-3532. DOI: 10.1021/Ic961354N  0.68
1994 Darensbourg DJ, Atnip EV, Klausmeyer KK, Reibenspies JH. Amino acid derivatives of tungsten carbonyl. Structure and reactivity investigations of zerovalent tungsten glycine derivatives Inorganic Chemistry. 33: 5230-5237. DOI: 10.1021/Ic00101A014  0.659
1994 Darensbourg DJ, Fontal B, Chojnacki SS, Klausmeyer KK, Reibenspies JH. Aryloxide and Alkoxide Derivatives of Metal Clusters. Syntheses, Structures, and Reactivities of the .mu.-Oxo-Bridged Triruthenium Clusters Ru3(CO)8(.mu.-.eta.2-OC6H4Cl)2 and Ru3(CO)8(.mu.-.eta.2-OCH2C5H4N)2 Inorganic Chemistry. 33: 3526-3532. DOI: 10.1021/Ic00094A015  0.665
1994 Darensbourg DJ, Holtcamp MW, Khandelwal B, Klausmeyer KK, Reibenspies JH. Rational synthesis of dinuclear mixed-valence Cu(I)/Cu(II) carboxylate derivatives. Steric influence of phosphine ligands on the structures of the complexes Inorganic Chemistry. 33: 2036-2040. DOI: 10.1021/Ic00087A046  0.663
1994 Darensbourg DJ, Holtcamp MW, Khandelwal B, Reibenspies JH. Intramolecular and intermolecular hydrogen bonding in triphenylphosphine derivatives of copper(I) carboxylates, (Ph3P)2CuO2C(CH2)nCOOH. Role of copper(I) in the decarboxylation of malonic acid and its derivatives Inorganic Chemistry. 33: 531-537. DOI: 10.1021/Ic00081A022  0.545
1994 Darensbourg DJ, Joó F, Kannisto M, Kathó A, Reibenspies JH, Daigle DJ. Water-soluble organometallic compounds. 4. Catalytic hydrogenation of aldehydes in an aqueous two-phase solvent system using a 1,3,5-triaza-7-phosphaadamantane complex of ruthenium Inorganic Chemistry. 33: 200-208. DOI: 10.1021/Ic00080A006  0.544
1994 Darensbourg DJ, Joo F, Katho A, Stafford JNW, Benyei A, Reibenspies JH. Nucleophilic addition of a water-soluble phosphine to aldehydes. Isolation of (1-hydroxyalkyl)phosphonium salts and the crystal structure of the (1-methoxy-1-benzyl)-(m-sulfonatophenyl)diphenylphosphonium salt Inorganic Chemistry. 33: 175-177. DOI: 10.1021/Ic00079A031  0.487
1994 Ovalles C, Fernández C, Darensbourg DJ. Homogeneous catalytic synthesis of formaldehyde using the tungsten carbonyl complex [(CO)5WCl]- in the presence of sodium methoxide Journal of Molecular Catalysis. 93: 125-136. DOI: 10.1016/0304-5102(94)00099-9  0.425
1994 Darensbourg DJ, Holtcamp MW, Longridge EM, Klausmeyer KK, Reibenspies JH. Structural characterization of bidentate carboxylate derivatives of copper(I) bistriphenylphosphine Inorganica Chimica Acta. 227: 223-232. DOI: 10.1016/0020-1693(94)04214-4  0.702
1994 Darensbourg DJ, Joó F, Kathó A, Stafford JNW, Bényei A, Reibenspies JH. Nucleophilic addition of a water-soluble phosphine to aldehydes. Isolation of (1-hydroxyalkyl)phosphonium salts and the crystal structure of the (1-methoxy-1-benzyl)-(m-sulfonatophenyl)diphenylphosphonium salt Inorganic Chemistry. 33: 175-177.  0.416
1993 Reibenspies JH, Fontal B, Darensbourg DJ. Structure of Ru4(CO)8(O2CCH2CH=CH2)4(NMe3)2 Acta Crystallographica Section C Crystal Structure Communications. 49: 1619-1621. DOI: 10.1107/S0108270193002483  0.52
1993 Reibenspies JH, Darensbourg DJ, Longridge EM. Structure of [Cu2(dmpe)3Cl2]n.2CH2Cl2 Acta Crystallographica Section C Crystal Structure Communications. 49: 1140-1142. DOI: 10.1107/S0108270192013015  0.471
1993 Reibenspies JH, Darensbourg DJ. Structure of tetrakis(dimethylphenylphosphine)rhodium(I) chloride Acta Crystallographica Section C Crystal Structure Communications. 49: 141-142. DOI: 10.1107/S0108270192009612  0.533
1993 Darensbourg DJ, Longridge EM, Holtcamp MW, Klausmeyer KK, Reibenspies JH. Reversible decarboxylation of phosphine derivatives of Cu(I) cyanoacetate. Mechanistic aspects germane to catalytic decarboxylation of carboxylic acids Journal of the American Chemical Society. 115: 8839-8840. DOI: 10.1021/Ja00072A047  0.662
1993 Darensbourg DJ, Chojnacki JA, Atnip EV. The catalytic decarboxylation of cyanoacetic acid: anionic tungsten carboxylates as homogeneous catalysts Journal of the American Chemical Society. 115: 4675-4682. DOI: 10.1021/Ja00064A031  0.359
1993 Darensbourg DJ, Meckfessel Jones ML, Reibenspies JH. Synthesis and reactivity of tungsten pentacarbonyl hydroxo and bicarbonato complexes. Molecular structure of [PPN][W(CO)5HCO3], an organometallic analog for carbonic anhydrase Inorganic Chemistry. 32: 4675-4676. DOI: 10.1021/Ic00074A003  0.582
1993 Darensbourg DJ, Bischoff CJ. Water-soluble organometallic compounds. 3. Kinetic investigations of dissociative phosphine substitution processes involving water-soluble Group 6 metal derivatives in miscible aqueous/organic media Inorganic Chemistry. 32: 47-53. DOI: 10.1021/Ic00053A008  0.389
1993 Bényei A, Stafford J, Kathó Á, Darensbourg D, Joó F. The effect of phosphonium salt formation on the kinetics of homogeneous hydrogenations in water utilizing a rhodium meta-sulfonatophenyl-diphenylphosphine complex Journal of Molecular Catalysis. 84: 157-163. DOI: 10.1016/0304-5102(93)85048-X  0.372
1993 Darensbourg DJ, Mueller BL, Reibenspies JH. The synthesis and X-ray structure of a phenoxide-bridged heterobimetallic anion, W(CO)5OPh(Cr(CO)3) −, and its reactivity with carbon dioxide and carbonyl sulfide Journal of Organometallic Chemistry. 451: 83-87. DOI: 10.1016/0022-328X(93)83011-J  0.566
1992 Darensbourg DJ, Joo F, Kannisto M, Katho A, Reibenspies JH. Water-soluble organometallic compounds. 2. Catalytic hydrogenation of aldehydes and olefins by new water-soluble 1,3,5-triaza-7-phosphaadamantane complexes of ruthenium and rhodium Organometallics. 11: 1990-1993. DOI: 10.1021/om00042a006  0.43
1992 Darensbourg DJ, Joo F, Kannisto M, Katho A, Reibenspies JH. Water-soluble organometallic compounds. 2. Catalytic hydrogenation of aldehydes and olefins by new water-soluble 1,3,5-triaza-7-phosphaadamantane complexes of ruthenium and rhodium Organometallics. 11: 1990-1993. DOI: 10.1021/Om00042A006  0.535
1992 Darensbourg DJ, Atnip EV, Reibenspies JH. Structural and reactivity studies of a cyanoacetic acid derivative of tungsten pentacarbonyl. X-ray structure of W(CO)5NCCH2COOH Inorganic Chemistry. 31: 4475-4480. DOI: 10.1021/Ic00048A008  0.528
1992 Darensbourg DJ, Longridge EM, Atnip EV, Reibenspies JH. A linear, monomeric copper(I) acetate derivative, bis[bis(phenanthroline)copper] bis(acetato)cuprate(1-) hydrogen bis(acetate). An effective catalyst for the decarboxylation of carboxylic acids Inorganic Chemistry. 31: 3951-3955. DOI: 10.1021/Ic00045A018  0.525
1992 Darensbourg DJ, Chojnacki JA, Reibenspies JH. Anionic Group 6 metal carbonyl oxalate complexes. X-ray structures of [Et4N]2[W(CO)4C2O4] and [PPN]2[W2(CO)8C2O4].cntdot.1/2(CH3CH2)2O Inorganic Chemistry. 31: 3428-3433. DOI: 10.1021/Ic00042A018  0.558
1992 Darensbourg DJ, Klausmeyer KK, Mueller BL, Reibenspies JH. Cateholates asσ- andπ-Donationg Ligands: The Synthesis and Structure of(Et4N)2[W(CO)4(O2C6H4)] and the“Sixteen Electron” Analogue Resulting from CO Dissociation Angewandte Chemie International Edition in English. 31: 1503-1504. DOI: 10.1002/Anie.199215031  0.7
1992 Darensbourg DJ, Klausmeyer KK, Mueller BL, Reibenspies JH. Catecholate als σ- und π-Donor-Liganden: (Et4N)2[W(CO)4(O2C6H4)] und das durch CO-Abspaltung entstehende 16-Valenzelektronen-Analogon Angewandte Chemie. 104: 1501-1503. DOI: 10.1002/Ange.19921041114  0.632
1991 Darensbourg DJ, Joyce JA, Rheingold A. Carbon dioxide insertion and deinsertion processes involving metal-carbon bonds: solid-state structure of [PPN][W(CO)5CH2CN] Organometallics. 10: 3407-3410. DOI: 10.1021/Om00055A070  0.37
1991 Darensbourg DJ, Wiegreffe HP, Reibenspies JH. Photochemically enhanced carbon-carbon bond-forming reaction between carbon disulfide and methylpentacarbonyltungstate. X-ray structure of [PPN][W(CO)4(.eta.2-S2CCH3)] Organometallics. 10: 6-8. DOI: 10.1021/Om00047A004  0.584
1991 Darensbourg DJ, Mueller BL, Bischoff CJ, Chojnacki SS, Reibenspies JH. Investigations into the steric influences on the reaction mechanism of carbon dioxide insertion into metal-oxygen bonds. Carbonyl sulfide activation as a model for CO2 Inorganic Chemistry. 30: 2418-2424. DOI: 10.1021/Ic00010A035  0.577
1991 Darensbourg DJ, Bischoff CJ, Reibenspies JH. Water-soluble organometallic compounds. 1. The synthesis, characterization, and x-ray structure of (kryptofix-221)sodium pentacarbonyl[tris(m-sulfonatophenyl)phosphine]tungstate(3-) Inorganic Chemistry. 30: 1144-1147. DOI: 10.1021/Ic00005A049  0.498
1991 Darensbourg DJ, Joyce JA, Bischoff CJ, Reibenspies JH. Further studies on the role of neighboring group participation in carbonyl substitution reactions of group 6 metal carboxylates Inorganic Chemistry. 30: 1137-1142. DOI: 10.1021/Ic00005A047  0.51
1991 Darensbourg DJ, Longridge EM, Atnip EV, Reibenspies JH. Preparation and solid-state structure of a novel carboxylate derivative of copper(I), (Ph3P)2Cu(O2CCH2CN)2H Inorganic Chemistry. 30: 357-358. DOI: 10.1021/Ic00003A001  0.475
1990 Darensbourg DJ, Wiegreffe HP, Wiegreffe PW. Mechanistic studies of carbon dioxide insertion into metal hydrides and extrusion from the corresponding metal formates utilizing Group 6 metal carbonyl derivatives as reaction probes Journal of the American Chemical Society. 112: 9252-9257. DOI: 10.1021/Ja00181A030  0.365
1990 Darensbourg DJ, Wiegreffe P, Riordan CG. Mechanistic aspects of decarboxylation reactions of Group 10 metal formato hydrido tricyclohexylphosphine [(PCy3)2M(H)O2CH] derivatives Journal of the American Chemical Society. 112: 5759-5762. DOI: 10.1021/Ja00171A014  0.327
1990 Darensbourg DJ, Chao CS, Bischoff C, Reibenspies JH. Solid-state and solution structure of (2,2'-bipyridine)(tetracarbonylcobalt)copper Inorganic Chemistry. 29: 4637-4640. DOI: 10.1021/Ic00348A011  0.561
1990 Darensbourg DJ, Chao CS, Reibenspies JH, Bischoff CJ. Crystal structure and reactivity of bis[bis(1,2-dimethylphosphino)ethane]copper(2+) bis(tetracarbonylcobalt)curprate(2-): staggered and eclipsed conformations of [(CO)4CoCuCo(CO)4]- anions Inorganic Chemistry. 29: 2153-2157. DOI: 10.1021/Ic00336A023  0.519
1990 Darensbourg DJ, Mueller BL, Bischoff CJ, Reibenspies JH. Chemistry of zerovalent tungsten alkoxides. Synthesis, x-ray structure and reactivity toward carbon dioxide Inorganic Chemistry. 29: 1789-1791. DOI: 10.1021/Ic00335A004  0.543
1990 Darensbourg DJ, Wiegreffe HP. Carbon monoxide ligand substitutional processes involving anionic Group 6 metal carboxylates and their relevance to decarboxylation mechanisms Inorganic Chemistry. 29: 592-597. DOI: 10.1021/Ic00329A010  0.418
1990 Yoong Goh L, Hambley TW, Darensbourg DJ, Reibenspies J. Isolation of pentamethylcyclopentadienylchromium tricarbonyl dimer by two methods. X-Ray crystal structural study of two polymorphs Journal of Organometallic Chemistry. 381: 349-356. DOI: 10.1016/0022-328X(90)80064-7  0.504
1990 Darensbourg DJ, Mueller BL, Bischoff CJ, Johnson CC, Sanchez KM, Reibenspies JH. Multinuclear Metal Carbonyl Alkoxide and Aryloxide Derivatives as Models for Metal Carbonyls Adsorbed on Metal Oxide Supports Israel Journal of Chemistry. 30: 369-376. DOI: 10.1002/Ijch.199000039  0.528
1990 DARENSBOURG DJ, CHAO C, REIBENSPIES JH, BISCHOFF CJ. ChemInform Abstract: Crystal Structure and Reactivity of (Cu(dmpe)2)(Cu(Co(CO)4)2) (dmpe: 1,2-Bis(dimethylphosphino)ethane): Staggered and Eclipsed Conformations of ((CO)4CoCuCo(CO)4)- Anions. Cheminform. 21. DOI: 10.1002/chin.199035248  0.397
1989 Darensbourg DJ, Sanchez KM, Reibenspies JH, Rheingold AL. Synthesis, structure, and reactivity of zerovalent group 6 metal pentacarbonyl aryl oxide complexes. Reactions with carbon dioxide Journal of the American Chemical Society. 111: 7094-7103. DOI: 10.1021/Ja00200A031  0.564
1989 DARENSBOURG DJ, SANCHEZ KM, REIBENSPIES JH, RHEINGOLD AL. ChemInform Abstract: Synthesis, Structure, and Reactivity of Zerovalent Group 6 Metal Pentacarbonyl Aryl Oxide Complexes. Reactions with Carbon Dioxide. Cheminform. 20. DOI: 10.1002/chin.198951228  0.545
1989 DARENSBOURG DJ, BAUCH CG, REIBENSPIES JH, RHEINGOLD AL. ChemInform Abstract: Comparative Reactivities of Anionic Group 6 Alkyl, Silyl, and Stannyl Pentacarbonyl Metalates Toward Carbon Dioxide and Sulfur Dioxide. Crystal Structure of (PPN) (W(CO)5Si(CH3)3). Cheminform. 20. DOI: 10.1002/chin.198911254  0.483
1989 DARENSBOURG DJ, SANCHEZ KM, REIBENSPIES J. ChemInform Abstract: Synthesis and Characterization of (Et4N) (M(CO)5SR) and (Et4N)2(M2(CO)8(SR)2) Complexes (M: Cr, Mo, W). Ligand Substitution Reactions and X-Ray Crystal Structure of (Et4N)2(W2(CO)8(SPh)2). Cheminform. 20. DOI: 10.1002/chin.198904251  0.469
1989 DARENSBOURG DJ, SANCHEZ KM, REIBENSPIES JH. ChemInform Abstract: Synthesis and X-Ray Crystal Structure of Zerovalent Tungsten Aryloxide Dimers. Cheminform. 20. DOI: 10.1002/chin.198901225  0.422
1988 Darensbourg DJ, Bauch CG, Reibenspies JH, Rheingold AL. Comparative reactivities of anionic group 6 alkyl, silyl, and stannyl pentacarbonyl metalates toward carbon dioxide and sulfur dioxide. Crystal structure of bis(triphenylphosphine)nitrogen(1+) pentacarbonyl(trimethylsilyl)tungstate(1-) Inorganic Chemistry. 27: 4203-4207. DOI: 10.1021/Ic00296A022  0.59
1988 Darensbourg DJ, Sanchez KM, Reibenspies J. Synthesis and characterization of carbonyl thiolato [Et4N][M(CO)5SR] and [Et4N]2[M2(CO)8(SR)2] complexes (M = chromium, molybdenum, tungsten). Ligand substitution reactions and x-ray crystal structure of [Et4N]2[W2(CO)8(SPh)2] Inorganic Chemistry. 27: 3636-3643. DOI: 10.1021/Ic00293A040  0.534
1988 Darensbourg DJ, Sanchez KM, Reibenspies JH. Synthesis and x-ray crystal structure of zerovalent tungsten aryloxide dimers Inorganic Chemistry. 27: 3269-3270. DOI: 10.1021/Ic00292A003  0.578
1988 DARENSBOURG DJ, GROETSCH G, WIEGREFFE P, RHEINGOLD AL. ChemInform Abstract: Insertion Reactions of Carbon Dioxide with Square-Planar Rhodium Alkyl and Aryl Complexes. Cheminform. 19. DOI: 10.1002/chin.198810351  0.328
1987 Darensbourg DJ, Darensbourg MY, Goh LY, Ludvig M, Wiegreffe P. The reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of a hydridonickel formate complex, HNi(O2CH)(Cy3P)2 Journal of the American Chemical Society. 109: 7539-7540. DOI: 10.1021/Ja00258A053  0.671
1987 Darensbourg DJ, Ovalles C. Homogeneous catalytic synthesis of alkyl formates from the reaction of alkyl halides, carbon dioxide, and hydrogen in the presence of anionic Group 6 carbonyl catalysts and sodium salts Journal of the American Chemical Society. 109: 3330-3336. DOI: 10.1021/Ja00245A024  0.417
1987 Darensbourg DJ, Sanchez KM, Rheingold AL. Insertion of carbon dioxide into metal alkoxide bonds. Synthesis and structure of tungsten tetracarbonyl carbonate Journal of the American Chemical Society. 109: 290-292. DOI: 10.1021/Ja00235A054  0.379
1987 Darensbourg DJ, Groetsch G, Wiegreffe P, Rheingold AL. Insertion reactions of carbon dioxide with square-planar rhodium alkyl and aryl complexes Inorganic Chemistry. 26: 3827-3830. DOI: 10.1021/Ic00269A043  0.346
1987 Darensbourg DJ, Zalewski DJ, Plepys C, Campana C. Synthesis, reactivity, and x-ray structure of fac-(acetonitrile)tricarbonyl[bis(diphenylphosphino)methane]tungsten. Stereoselective preparation of fac-W(CO)3(13CO)(dppm) and subsequent intramolecular rearrangement processes Inorganic Chemistry. 26: 3727-3732. DOI: 10.1021/Ic00269A022  0.392
1987 Darensbourg DJ, Bauch CG, Reingold AL. Carbon dioxide insertion processes involving metal-carbon bonds: solid-state and solution structure of (18-crown-6) sodium pentacarbonylmethyltungstate(1-) Inorganic Chemistry. 26: 977-980. DOI: 10.1021/Ic00254A003  0.37
1987 Darensbourg DJ, Gray RL, Ovalles C. Selective homogeneous production of alkyl formate from CO and alcohol using metal carbonyl/alkoxide catalyst systems Journal of Molecular Catalysis. 41: 329-347. DOI: 10.1016/0304-5102(87)80110-4  0.612
1987 Butler IS, Xu ZH, Darensbourg DJ, Pala M. FT-IR, photoacoustic and micro-Raman spectra of the dodecacarbonyltriruthenium (O) complexes Ru3(13CO)12and Ru3(CO)12 Journal of Raman Spectroscopy. 18: 357-363. DOI: 10.1002/Jrs.1250180511  0.342
1987 DARENSBOURG DJ, PALA M, SIMMONS D, RHEINGOLD AL. ChemInform Abstract: Chemical and Structural Characterization of W(CO)5OPPh2NPPh3. A Novel Complex Containing a Phosphine Oxide Ligand Derived from the Bis(triphenylphosphine)nitrogen(1+) Cation. Cheminform. 18. DOI: 10.1002/chin.198703269  0.339
1986 Darensbourg MY, Darensbourg DJ. The Chemistry of the Metal-Carbon Bond. Volume 2. The Nature and Cleavage of Metal-Carbon Bonds. Organometallics. 5: 828-828. DOI: 10.1021/Om00135A600  0.652
1986 Tooley PA, Ovalles C, Kao SC, Darensbourg DJ, Darensbourg MY. Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones Journal of the American Chemical Society. 108: 5465-5470. DOI: 10.1021/Ja00278A016  0.647
1986 Darensbourg DJ, Pala M, Simmons D, Rheingold AL. Chemical and structural characterization of W(CO)5OPPh2NPPh3. A novel tungsten carbonyl complex containing a phosphine oxide ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation Inorganic Chemistry. 25: 3537-3541. DOI: 10.1021/Ic00239A047  0.45
1986 Darensbourg DJ, Zalewski DJ, Rheingold AL, Durney RL. Ligand substitution processes in tetranuclear carbonyl clusters. 10. X-ray structural characterization of products resulting from reactions of nonacarbonyl[tris(diphenylphosphino)methane]tetracobalt with phosphine ligands Inorganic Chemistry. 25: 3281-3290. DOI: 10.1021/Ic00238A036  0.335
1986 Darensbourg DJ, Darensbourg MY, Gray RL, Simmons D, Arndt LW. Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives Inorganic Chemistry. 25: 880-882. DOI: 10.1002/Chin.198628095  0.748
1986 Darensbourg DJ, Pala M, Rheingold AL. Preparation and structure of W(CO)5OPPh2NPPh3, a novel complex containing a ligand derived from the bis(triphenylphosphine)nitrogen(1+) cation Inorganic Chemistry. 25: 125-127. DOI: 10.1002/Chin.198621256  0.444
1986 DARENSBOURG DJ, PALA M, RHEINGOLD AL. ChemInform Abstract: Preparation and Structure of W(CO)5OPPh2NPPh3, a Novel Complex Containing a Ligand Derived from the Bis(triphenylphosphine)nitrogen(l +) Cation. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198621256  0.31
1986 DARENSBOURG DJ, KUDAROSKI HANCKEL R, BAUCH CG, PALA M, SIMMONS D, WHITE JN. ChemInform Abstract: A Kinetic Investigation of Carbon Dioxide Insertion Processes Involving Anionic Tungsten Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198613281  0.356
1985 Darensbourg DJ, Kudaroski R, Delord T. Synthesis and x-ray structure of anionic chelating phosphine-acyl derivative of tungsten, [cyclic] [PPh4][W(CO)4C(O)CH2CH2CH2PPh2], and the reactivity of its decarbonylated analog with carbon dioxide Organometallics. 4: 1094-1097. DOI: 10.1021/Om00125A026  0.402
1985 Darensbourg DJ, Zalewski DJ. Ligand substitution processes in tetranuclear carbonyl clusters. 9. Reactions of Co4(CO)9(tripod), tripod = HC(PPh2)3, and its derivatives Organometallics. 4: 92-97. DOI: 10.1021/Om00120A016  0.339
1985 Darensbourg DJ, Hanckel RK, Bauch CG, Pala M, Simmons D, White JN. A kinetic investigation of carbon dioxide insertion processes involving anionic tungsten-alkyl and -aryl derivatives: effects of carbon dioxide pressure, counterions, and ancillary ligands. Comparisons with migratory carbon monoxide insertion processes Journal of the American Chemical Society. 107: 7463-7473. DOI: 10.1021/Ja00311A040  0.386
1985 McNeese TJ, Mueller TE, Wierda DA, Darensbourg DJ, Delord TJ. Synthesis and characterization of polynuclear chromium carbonyl tetraanions Inorganic Chemistry. 24: 3465-3468. DOI: 10.1021/Ic00215A032  0.323
1985 Darensbourg DJ, Gray RL, Delord T. The X-ray structural characterization of a tetrameric binuclear bis(μ-oxo) molybdenum(V) compound bridged by methoxide ligands Inorganica Chimica Acta. 98: L39-L42. DOI: 10.1016/S0020-1693(00)84910-5  0.607
1985 Darensbourg DJ, Gray RL, Ovalles C, Pala M. Homogeneous catalysis of methyl formate production from carbon monoxide and methanol in the presence of metal carbonyl catalysts Journal of Molecular Catalysis. 29: 285-290. DOI: 10.1016/0304-5102(85)87011-5  0.613
1985 Darensbourg DJ, Grotsch G. Stereochemical studies of the carbon dioxide insertion reactions into the tungsten-alkyl bond Journal of the American Chemical Society. 107: 7473-7476. DOI: 10.1002/Chin.198613282  0.366
1985 Darensbourg DJ, Pala M. Cation-anion interaction in the [Na-kryptofix-221][W(CO)5O2CH] derivative and its relevance in carbon dioxide reduction processes Journal of the American Chemical Society. 107: 5687-5693. DOI: 10.1002/Chin.198603055  0.346
1984 Darensbourg DJ, Gray RL, Pala M. A convenient route to carbon-13-enriched triruthenium dodecacarbonyl. Chemistry relevant to methyl formate production from carbon monoxide and methanol Organometallics. 3: 1928-1930. DOI: 10.1021/Om00090A031  0.583
1984 Darensbourg DJ, Zalewski DJ, Delord T. Ligand substitution processes in tetranuclear carbonyl clusters. 7. Molecular structure and carbon monoxide exchange processes of Co4(CO)9(tripod), tripod = 1,1,1-tris(diphenylphosphino)methane or HC(PPh2)3 Organometallics. 3: 1210-1217. DOI: 10.1021/Om00086A012  0.374
1984 Darensbourg DJ, Ovalles C. Anionic Group 6B metal carbonyls as homogeneous catalysts for carbon dioxide/hydrogen activation. The production of alkyl formates Journal of the American Chemical Society. 106: 3750-3754. DOI: 10.1021/Ja00325A007  0.329
1984 Darensbourg DJ, Zalewski DJ. Ligand substitution processes in tetranuclear carbonyl clusters. 8. Reactions of dodecacarbonyltetracobalt (Co4(12CO)12/Co4(13CO)12) with phosphorus donor ligands. Further evidence for cluster integrity during ligand substitution processes Inorganic Chemistry. 23: 4382-4384. DOI: 10.1021/Ic00193A056  0.377
1984 Bursten BE, Darensbourg DJ, Kellogg GE, Lichtenberger DL. Ligand additivity in the valence photoelectron spectroscopy of phosphine-substituted molybdenum carbonyls Inorganic Chemistry. 23: 4361-4365. DOI: 10.1021/Ic00193A050  0.605
1984 Darensbourg DJ, Gray RL. Stereochemical nonrigidity in six-coordinate Group VIB metal carbonyl derivatives via a nondissociative pathway Inorganic Chemistry. 23: 2993-2996. DOI: 10.1002/Chin.198501276  0.575
1984 Darensbourg DJ, Kudaroski R. Metal-induced transformations of carbon dioxide. Carbon-carbon bond-forming processes involving anionic Group VIB metal derivatives, and the x-ray structure of [PNP][cis-MeW(CO)4PMe3] Journal of the American Chemical Society. 106: 3672-3673. DOI: 10.1002/Chin.198438276  0.396
1983 Darensbourg DJ, Pala M, Waller J. Potential intermediates in carbon dioxide reduction processes. Synthesis and structure of (.mu.-formato)decacarbonyltriruthenium and (.mu.-acetato)decacarbonyltriruthenium anions Organometallics. 2: 1285-1291. DOI: 10.1021/Om50004A003  0.336
1983 Darensbourg DJ, Ovalles C, Pala M. Homogeneous catalysts for carbon dioxide/hydrogen activation. Alkyl formate production using anionic ruthenium carbonyl clusters as catalysts Journal of the American Chemical Society. 105: 5937-5939. DOI: 10.1021/Ja00356A049  0.315
1983 Darensbourg DJ, Kudaroski RA. The Activation of Carbon Dioxide by Metai Complexes Advances in Organometallic Chemistry. 22: 129-168. DOI: 10.1016/S0065-3055(08)60402-5  0.391
1982 Darensbourg DJ, Rokicki A. Anionic Group 6B metal carbonyl hydrides and formates. Chemistry relevant to catalysis of the water-gas shift reaction by Group 6B metal hexacarbonyls Organometallics. 1: 1685-1693. DOI: 10.1021/Om00072A026  0.312
1982 Darensbourg DJ, Rokicki A, Kudaroski R. Reactions of cryptand-solubilized sodium sulfide (NaSH) in aprotic solvents with the Group 6B metal hexacarbonyls. X-ray structural analysis and ligand lability studies of the isolated M(CO)5SH- anions Organometallics. 1: 1161-1166. DOI: 10.1021/Om00069A010  0.393
1982 Darensbourg DJ, Peterson BS, Schmidt RE. Ligand-substitution processes in tetranuclear carbonyl clusters. 5. A kinetic and infrared investigation of carbon-13 monoxide incorporation into tri-.mu.-carbonyl-nonacarbonyltetracobalt and its monosubstituted derivatives Organometallics. 1: 306-311. DOI: 10.1021/Om00062A013  0.393
1982 Darensbourg DJ, Baldwin-Zuschke BJ. Ligand substitution processes in tetranuclear carbonyl clusters. 6. Steric contribution to ligand dissociation in multisubstituted tetrairidium dodecacarbonyl derivatives Journal of the American Chemical Society. 104: 3906-3910. DOI: 10.1021/Ja00378A020  0.347
1982 Darensbourg D, Rokicki A, Darensbourg M. Facile Reduction of Carbon Dioxide by Anionic Group 6B Metal Hydrides. Chemistry Relevant to Catalysis of the Water-Gas Shift Reaction - Correction Journal of the American Chemical Society. 104: 1156-1156. DOI: 10.1021/Ja00368A603  0.664
1982 Darensbourg DJ, Rokicki A. Reduction of carbon dioxide and carbonyl sulfide by anionic Group VIB metal hydrides and alkyls. Carbon-hydrogen and carbon-carbon bond formation processes and the structure of [PNP][Cr(CO)5SC(O)H] Journal of the American Chemical Society. 104: 349-350. DOI: 10.1021/Ja00365A089  0.388
1982 Cotton FA, Darensbourg DJ, Klein S, Kolthammer BWS. X-ray structural studies of cis-Mo(CO)4(PR3)2 (R = Me, Et, n-Bu) derivatives and their relationship to solution isomerization processes in these octahedral species Inorganic Chemistry. 21: 2661-2666. DOI: 10.1021/Ic00137A026  0.305
1982 Darensbourg DJ, Kudaroski R, Schenk W. Intermediates in the reaction of trans-Cr(CO)4(PPh3)2 with carbon-13 monoxide and fluxionality in octahedral Group VIB metal carbonyls via a nondissociative mechanism Inorganic Chemistry. 21: 2488-2491. DOI: 10.1021/Ic00136A071  0.397
1982 Cotton FA, Darensbourg DJ, Kolthammer BWS, Kudaroski R. Solid-state and solution structures of [PNP][W(CO)5O2CCH3] and [PNP][W(CO)4(PEt3)O2CCH3] and the carbonyl-labilizing ability of the acetato ligand in these anionic derivatives Inorganic Chemistry. 21: 1656-1662. DOI: 10.1021/Ic00134A076  0.328
1982 Cotton FA, Darensbourg DJ, Klein S, Kolthammer BWS. Structural characterizations of cis-Mo(CO)4(PPhMe2)(NHC5H10) and cis-Mo(CO)4(PPhMe2)(PPh3) and their solution reactivities toward carbon monoxide Inorganic Chemistry. 21: 1651-1655. DOI: 10.1021/Ic00134A075  0.318
1982 Cotton FA, Darensbourg DJ, Klein S, Kolthammer BWS. Steric contributions to the solid-state structures of bis(phosphine) derivatives of molybdenum carbonyl. X-ray structural studies of cis-Mo(CO)4[PPh3-nMen]2 (n = 0, 1, 2) Inorganic Chemistry. 21: 294-299. DOI: 10.1021/Ic00131A055  0.347
1982 Darensbourg DJ. Mechanistic Pathways for Ligand Substitution Processes in Metal Carbonyls Advances in Organometallic Chemistry. 21: 113-150. DOI: 10.1016/S0065-3055(08)60379-2  0.446
1982 Cotton FA, Darensbourg DJ, Kolthammer BWS, Kudaroski R. Solid-State And Solution Structures Of (Pnp)(W(Co)5O2Cch3) And (Pnp)(W(Co)4(Pet3)O2Cch3) And The Carbonyl-Labilizing Ability Of The Acetato Ligand In These Anionic Derivatives Cheminform. 13. DOI: 10.1002/Chin.198229063  0.328
1981 Bond AM, Darensbourg DJ, Mocellin E, Stewart BJ. Electrochemical investigations of compounds having isomeric forms with similar standard redox potentials: oxidation of bis(tri-n-butylphosphine)molybdenum tetracarbonyl and related complexes Journal of the American Chemical Society. 103: 6827-6832. DOI: 10.1021/Ja00413A008  0.364
1981 Darensbourg DJ, Rokicki A, Darensbourg MY. Facile reduction of carbon dioxide by anionic Group 6b metal hydrides. Chemistry relevant to catalysis of the water-gas shift reaction Journal of the American Chemical Society. 103: 3223-3224. DOI: 10.1021/Ja00401A055  0.663
1981 Darensbourg DJ, Fischer MB, Schmidt RE, Baldwin BJ. Formate ion as a monodentate ligand. Synthesis, structure, and decarboxylation of (.eta.5-cyclopentadienyl)dicarbonyl(formato)iron Journal of the American Chemical Society. 103: 1297-1298. DOI: 10.1021/Ja00395A087  0.327
1981 Darensbourg DJ, Ewen JA. Kinetic studies of ligand substitution reactions and general-base catalysis in amine-ligand exchange processes for Group 6B metal carbonyl amine derivatives. Kinetic and spectroscopic evidence for hydrogen-bonded intermediates Inorganic Chemistry. 20: 4168-4177. DOI: 10.1021/Ic50226A029  0.412
1981 Darensbourg DJ, Baldwin-Zuschke BJ. Ligand substitution processes in tetranuclear carbonyl clusters. 4. Molecular structure and reactivity of octacarbonyltetrakis(trimethylphosphine)tetrairidium Inorganic Chemistry. 20: 3846-3850. DOI: 10.1021/Ic50225A049  0.32
1981 Darensbourg DJ, Darensbourg MY, Walker N. Studies using tributylphosphine oxide as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in carbon-13 monoxide Inorganic Chemistry. 20: 1918-1921. DOI: 10.1021/Ic50220A059  0.708
1981 Darensbourg DJ, Incorvia MJ. Ligand substitution processes in tetranuclear carbonyl clusters. 3. Molecular structures of Co4(CO)8(.mu.-CO)3[P(C6H5)3] and Co4(CO)7(.mu.-CO)3[P(OCH3)3]2 Inorganic Chemistry. 20: 1911-1918. DOI: 10.1021/Ic50220A058  0.331
1981 Darensbourg DJ. On the use of 13C13C coupling in establishing intramolecular versus intermolecular CO ligand reaarangement processes in metal carbonyl derivatives Journal of Organometallic Chemistry. 209: C37-C40. DOI: 10.1016/S0022-328X(00)93602-7  0.41
1981 Atwood JD, Atwood ML, Darensbourg MY, Darensbourg DJ. Chromium, molybdenum, and tungsten. Annual survey covering the year 1976 Journal of Organometallic Chemistry. 223: 49-116. DOI: 10.1016/S0022-328X(00)89672-2  0.669
1981 Cotton F, Darensbourg DJ, Kolthammer BW. Reactions of M2Cl4(PR3)4 (M  Mo and W) with carbon monoxide Journal of Organometallic Chemistry. 217: C14-C16. DOI: 10.1016/S0022-328X(00)86032-5  0.301
1981 Darensbourg DJ, Darensbourg MY, Walker N. Studies Using Tributylphosphine Oxide As A Carbon Monoxide Labilizing Ligand In The Synthesis Of Metal Carbonyl Complexes Highly Enriched In Carbon-13 Monoxide Cheminform. 12. DOI: 10.1002/Chin.198137278  0.708
1980 Darensbourg DJ, Baldwin BJ, Froelich JA. Phase-transfer-catalyzed nucleophilic reactions of hydroxide ions at metal-bound carbon monoxide centers Journal of the American Chemical Society. 102: 4688-4694. DOI: 10.1021/Ja00534A022  0.354
1980 Darensbourg DJ, Walker N, Darensbourg MY. Synthesis of metal carbonyl complexes highly enriched in carbon-13: utilization of the carbon monoxide-labilizing ability of (n-Bu)3P:O Journal of the American Chemical Society. 102: 1213-1214. DOI: 10.1021/Ja00523A075  0.689
1980 Darensbourg DJ, Incorvia MJ. Ligand substitution processes in tetranuclear metal carbonyl clusters. 2. Tris(.mu.-carbonyl)-nonacarbonyltetracobalt derivatives Inorganic Chemistry. 19: 2585-2590. DOI: 10.1021/Ic50211A020  0.353
1980 DARENSBOURG DJ, WALKER N, DARENSBOURG MY. ChemInform Abstract: SYNTHESIS OF METAL CARBONYL COMPLEXES HIGHLY ENRICHED IN CARBON-13: UTILIZATION OF THE CARBON MONOXIDE-LABILIZING ABILITY OF (N-BU)3P:O Chemischer Informationsdienst. 11. DOI: 10.1002/Chin.198018283  0.69
1979 Darensbourg DJ, Baldwin BJ. Intramolecular rearrangement of carbonyl ligands in the octahedral complex pentacarbonyl(trimethyl phosphite) tungsten by a nondissociative process: an example of the utility of the oxygen-18 isotope shift on the carbon-13 NMR of the carbonyl ligand Journal of the American Chemical Society. 101: 6447-6449. DOI: 10.1021/Ja00515A058  0.442
1979 Darensbourg DJ. Intramolecular hydrogen-bonding implications on the lability of the molybdenum-piperidine bond. Kinetic and mechanistic studies of the reaction of cis-Mo(CO)4[P(OCH3)3]NHC5H10 with carbon monoxide Inorganic Chemistry. 18: 2821-2825. DOI: 10.1021/Ic50200A039  0.325
1979 Darensbourg DJ, Darensbourg MY, Walker N, Froelich JA, Barros HLC. Reaction of iron pentacarbonyl with oxygen-18-enriched hydroxide. Decarboxylation vs. oxygen exchange in the [Fe(COOH)] intermediate Inorganic Chemistry. 18: 1401-1402. DOI: 10.1021/Ic50195A053  0.611
1979 Darensbourg DJ, Graves AH. Correction. Steric Contributions to the Solution Dynamics Involving Phosphorus Ligand Dissociation in Substituted Derivatives of Molybdenum Hexacarbonyl Inorganic Chemistry. 18: 1257-1261. DOI: 10.1021/Ic50195A017  0.345
1979 Darensbourg DJ, Incorvia MJ. Solution photochemistry of anionic metal carbonyl hydride derivatives. Substitution and dimer disruption processes in .mu.-H[M(CO)5]2- (M = chromium and tungsten) Inorganic Chemistry. 18: 18-22. DOI: 10.1021/Ic50191A004  0.303
1979 Darensbourg DJ. Intramolecular isomerization of an octahedral complex: bis(tri-n-butylphosphine)molybdenum tetracarbonyl Inorganic Chemistry. 18: 14-17. DOI: 10.1021/Ic50191A003  0.39
1979 Darensbourg DJ, Incorvia MJ. Ligand substitution process in tetranuclear metal carbonyl clusters Journal of Organometallic Chemistry. 171: 89-96. DOI: 10.1016/S0022-328X(00)88067-5  0.363
1979 DARENSBOURG DJ, DARENSBOURG MY, WALKER N, FROELICH JA, BARROS HLC. ChemInform Abstract: REACTION OF IRON PENTACARBONYL WITH OXYGEN-18-ENRICHED HYDROXIDE. DECARBOXYLATION VS. OXYGEN EXCHANGE IN THE (FE(COOH)) INTERMEDIATE Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197933304  0.613
1979 Darensbourg DJ, Graves AH. Steric contributions to the solution dynamics involving phosphorus ligand dissociation in substituted derivatives of molybdenum hexacarbonyl Inorganic Chemistry. 18: 1257-1261. DOI: 10.1002/Chin.197933297  0.346
1979 DARENSBOURG DJ, INCORVIA MJ. ChemInform Abstract: SOLUTION PHOTOCHEMISTRY OF ANIONIC METAL CARBONYL HYDRIDE DERIVATIVES. SUBSTITUTION AND DIMER DISRUPTION PROCESSES IN μ-H(M(CO)5)2- (M = CHROMIUM AND TUNGSTEN) Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197915317  0.314
1979 DARENSBOURG DJ, FROELICH JA. ChemInform Abstract: PREPARATION OF OXYGEN-18-LABELED DERIVATIVES OF (MN(CO)3(DIPHOS)H) VIA REACTION OF (MN(CO)4(DIPHOS))(PF6) WITH WATER (OXYGEN-18) IN THE PRESENCE OF TRIETHYLAMINE. DECARBOXYLATION OF A (MN(COOH)) INTERMEDIATE Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197908264  0.303
1978 Darensbourg DJ, Froelich JA. Phase-transfer catalyzed oxygen-18 labeling studies of carbonyl ligands in neutral metal carbonyl derivatives Journal of the American Chemical Society. 100: 338-340. DOI: 10.1021/Ja00469A086  0.395
1978 Darensbourg DJ, Kump RL. A convenient synthesis of cis-Mo(CO)4L2 derivatives (L = Group 5a ligand) and a qualitative study of their thermal reactivity toward ligand dissociation Inorganic Chemistry. 17: 2680-2682. DOI: 10.1021/Ic50187A062  0.324
1978 Darensbourg DJ, Burch RR, Darensbourg MY. Preparation of a stereospecifically carbon-13 monoxide-labeled [(.mu.-H)[Mo(CO)5]2]- species and analysis of its carbonyl stretching vibrational modes Inorganic Chemistry. 17: 2677-2680. DOI: 10.1021/Ic50187A061  0.626
1978 Darensbourg DJ, Murphy MA. Solution photosubstitution chemistry of amine pentacarbonyl derivatives of the Group 6B metals in the presence of carbon-13 monoxide. An example of stereospecific incorporation of carbon-13 monoxide Inorganic Chemistry. 17: 884-888. DOI: 10.1021/Ic50182A018  0.376
1978 Darensbourg MY, Darensbourg DJ, Barros HLC. Solution structure and reactivity of hydridoiron tetracarbonyl anion, [HFe(CO)4]- Inorganic Chemistry. 17: 297-301. DOI: 10.1021/Ic50180A022  0.611
1977 Darensbourg DJ, Nelson HH, Murphy MA. Photochemical substitution reactions of Group 6B metal tetracarbonyl norbornadiene complexes with carbon-13 monoxide, kinetics of subsequent thermal rearrangements in the stereospecifically labeled species, and relation of these results to the photoinduced hydrogenation process Journal of the American Chemical Society. 99: 896-903. DOI: 10.1021/Ja00445A036  0.402
1977 Froelich JA, Darensbourg DJ. Reaction of cationic Group 7B metal carbonyl derivatives with sodium hydrogen sulfide. Production of metal hydrides Inorganic Chemistry. 16: 960-962. DOI: 10.1021/Ic50170A053  0.336
1977 Darensbourg DJ, Tappan JE, Nelson HH. Infrared intensities and calculation of infrared band shapes of the .nu.(carbonyl) and .nu.(carbon:carbon) vibrational modes in Group 6B (norbornadiene)tetracarbonylmetal derivatives Inorganic Chemistry. 16: 534-540. DOI: 10.1021/Ic50169A006  0.303
1977 Darensbourg DJ, Kump RL. A thermal route to stereospecifically 13CO labelled group VIB metal pentacarbonyl amine derivatives Journal of Organometallic Chemistry. 140: C29-C32. DOI: 10.1016/S0022-328X(00)89356-0  0.369
1977 Darensbourg DJ, Todd LJ, Hickey JP. The lack of intramolecular carbonyl ligand rearrangement in the stereospecifically 13co labelled (diamine)molybdenum tetracarbonyl derivatives Journal of Organometallic Chemistry. 137: C1-C7. DOI: 10.1016/S0022-328X(00)80848-7  0.413
1977 DARENSBOURG DJ, NELSON HHI, MURPHY MA. ChemInform Abstract: Photochemical Substitution Reactions of Group 6B Metal Tetracarbonyl Norbornadiene Complexes with 13CO, Kinetics of subsequent Thermal Rearrangements in the Stereospecifically Labeled Species, and Relationship of These Results to the Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/Chin.197717293  0.386
1976 Ewen JA, Darensbourg DJ. Kinetic ambiguity between the Id and D mechanisms in ligand substitution reactions. The intimate mechanism for axial base-ligand exchange reactions in alkyl(base)cobaloximes and related species Journal of the American Chemical Society. 98: 4317-4319. DOI: 10.1021/Ja00430A055  0.355
1976 Darensbourg DJ, Dobson GR, Moradi-araghi A. Evidence for the fluxionality and structure in solution of intermediates of the type W(CO)4(L) (L = lewis base) Journal of Organometallic Chemistry. 116: C17-C20. DOI: 10.1016/S0022-328X(00)91799-6  0.358
1976 Darensbourg DJ, Salzer A. Stereospecific incorporation of 13CO into olefinic substituted metal carbonyl compounds Journal of Organometallic Chemistry. 117: C90-C92. DOI: 10.1016/S0022-328X(00)87219-8  0.417
1976 Darensbourg DJ. Oxygen Exchange Reactions of Cationic Carbonyl Derivatives of Manganese and Rhenium with H218O and Related Processes Israel Journal of Chemistry. 15: 247-252. DOI: 10.1002/Ijch.197600044  0.35
1975 Ewen J, Darensbourg DJ. Evidence for hydrogen-bonded intermediates in amine substitution reactions involving Group 6B metal pentacarbonyl amine derivatives with phosphines Journal of the American Chemical Society. 97: 6874-6876. DOI: 10.1021/Ja00856A053  0.342
1975 Drew D, Darensbourg DJ, Darensbourg MY. Synthesis, spectral properties, and reactions of manganese and rhenium pentacarbonyl phosphine and phosphite cation derivatives and related complexes Inorganic Chemistry. 14: 1579-1584. DOI: 10.1021/Ic50149A027  0.388
1974 Darensbourg DJ, Nelson HH. Stereospecific photochemical reactions of Group VIb metal tetracarbonyl norbornadiene complexes with carbon-13 monoxide Journal of the American Chemical Society. 96: 6511-6513. DOI: 10.1021/ja00827a043  0.308
1974 Darensbourg DJ, Nelson HH, Hyde CL. Detailed analysis of the carbonyl stretching vibrations in axial and equatorial substituted iron carbonyl compounds. Absolute infrared intensities and force constants of the carbonyl ligands Inorganic Chemistry. 13: 2135-2145. DOI: 10.1021/Ic50139A017  0.321
1974 Darensbourg DJ, Madrid D. Preparation of dinitrogen-rhenium complexes with tertiary arsines as coligands. Interaction of indium trichloride with rhenium(I)-dinitrogen species Inorganic Chemistry. 13: 1532-1534. DOI: 10.1021/Ic50136A061  0.312
1974 Darensbourg DJ, Darensbourg MY. Infrared determination of stereochemistry in metal complexes. The determination of symmetry coordinates Journal of Chemical Education. 51: 787. DOI: 10.1021/Ed051P787  0.658
1974 Knebel WJ, Angelici RJ, Gansow OA, Darensbourg DJ. Stereospecific introduction of carbon monoxide into metal carbonyl chelate complexes Journal of Organometallic Chemistry. 66: C11-C13. DOI: 10.1016/S0022-328X(00)93872-5  0.358
1974 York Darensbourg M, Darensbourg D, Drew D. Reactions of phenylacetymanganesepentacarbonyl with phosphine and phosphite ligands Journal of Organometallic Chemistry. 73: C25-C27. DOI: 10.1016/S0022-328X(00)85645-4  0.349
1974 Darensbourg D, Darensbourg M, Drew D, Conder H. The synthesis and spectral properties of manganese pentacarbonyl phosphine and phosphite cation derivatives and related complexes Journal of Organometallic Chemistry. 74: C33-C36. DOI: 10.1016/S0022-328X(00)83603-7  0.352
1974 DARENSBOURG DJ, NELSON HHI. ChemInform Abstract: STEREOSPECIFIC PHOTOCHEMICAL REACTIONS OF GROUP VIB METAL TETRACARBONYL NORBORNADIENE COMPLEXES WITH (13)CO Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197450390  0.382
1974 KNEBEL WJ, ANGELICI RJ, GANSOW OA, DARENSBOURG DJ. ChemInform Abstract: STEREOSPECIFIC INTRODUCTION OF CARBON MONOXIDE INTO METAL CARBONYL CHELATE COMPLEXES Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/chin.197422357  0.316
1974 DARENSBOURG DJ, CONDER HL. ChemInform Abstract: KINETIC STUDIES OF PHOSPHINE AND PHOSPHITE EXCHANGE REACTIONS OF SUBSTITUTED IRON TRICARBONYL CARBENE COMPLEXES, A COMPETITIVE STUDY OF LEWIS BASES FOR THE INTERMEDIATE (FE(CO)3C(OC2H5)CH3) Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197415386  0.354
1973 Darensbourg MY, Conder HL, Darensbourg DJ, Hasday C. Electronic and steric control of reactions of benzylmagnesium chloride with substituted metal carbonyls Journal of the American Chemical Society. 95: 5919-5924. DOI: 10.1021/Ja00799A015  0.329
1973 Darensbourg DJ, Tappan JE, Marwedel BJ. The interaction of Lewis bases with (acyrlic acid) iron tetracarbonyl in solution Journal of Organometallic Chemistry. 54: C39-C44. DOI: 10.1016/S0022-328X(00)84977-3  0.791
1973 Hyde C, Darensbourg D. Reactions of transition-metal carbonyls with organolithium compounds. III. Synthesis of tetracarbonyl (tertiary phosphite) oxy- and amino-carbene complexes of the group VIB metals Inorganica Chimica Acta. 7: 145-149. DOI: 10.1016/S0020-1693(00)94799-6  0.343
1972 Schwenzer G, Darensbourg MY, Darensbourg DJ. Photochemical substitution reactions of substituted Group VI metal carbonyls Inorganic Chemistry. 11: 1967-1970. DOI: 10.1021/Ic50114A055  0.654
1972 Darensbourg DJ. Correlation between the stretching frequency and the absolute infrared intensity of the dinitrogen ligand in isoelectronic transition metal compounds Inorganic Chemistry. 11: 1436-1437. DOI: 10.1021/Ic50112A057  0.312
1972 Dennenberg RJ, Darensbourg DJ. Infrared and kinetic studies of Group VI metal pentacarbonyl amine compounds Inorganic Chemistry. 11: 72-77. DOI: 10.1021/Ic50107A016  0.308
1972 Darensbourg DJ. The nature of binuclear dinitrogen complexes of rhenium(I) and rhenium(V) in solution Inorganica Chimica Acta. 6: 527-530. DOI: 10.1016/S0020-1693(00)91852-8  0.318
1972 Darensbourg DJ. Photochemical reactions of transition-metal dinitrogen compounds in the presence of carbon monoxide Inorganic and Nuclear Chemistry Letters. 8: 529-532. DOI: 10.1016/0020-1650(72)80134-X  0.364
1972 SCHWENZER G, DARENSBOURG MY, DARENSBOURG DJ. ChemInform Abstract: PHOTOCHEMISCHE SUBSTITUTIONSRK. VON SUBSTITUIERTEN METALLCARBONYLEN DER GRUPPE VI Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197243383  0.609
1971 Darensbourg DJ, Darensbourg MY, Dennenberg RJ. Nature of the intermediate procreated in substitution reactions of Group VI metal carbonyls Journal of the American Chemical Society. 93: 2807-2808. DOI: 10.1021/Ja00740A051  0.653
1971 Darensbourg DJ. Relative importance of .sigma. and .pi. bonding of molecular nitrogen and carbonyl in osmium(II) complexes as determined by infrared intensities of the molecular nitrogen and carbonyl stretching vibrations Inorganic Chemistry. 10: 2399-2403. DOI: 10.1021/Ic50105A006  0.333
1971 Darensbourg DJ, Hyde CL. Infrared intensities of the molecular nitrogen and carbonyl stretching vibrations in iridium(I) complexes Inorganic Chemistry. 10: 431-432. DOI: 10.1021/Ic50096A056  0.315
1971 Darensbourg D, Darensbourg M. Reactions of transition metal carbonyls with nucleophilic reagents: reactivity and bonding Inorganica Chimica Acta. 5: 247-253. DOI: 10.1016/S0020-1693(00)95922-X  0.698
1971 DARENSBOURG DJ, DARENSBOURG MY, DENNENBERG RJ. ChemInform Abstract: NATUR DES IN SUBSTITUTIONSREAKTIONEN VON METALLCARBONYLEN DER VI. GRUPPE ERZEUGTEN ZWISCHENPRODUKTES Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197135093  0.599
1971 DARENSBOURG DJ, HYDE CL. ChemInform Abstract: IR-INTENSITAETEN VON DISTICKSTOFF UND CARBONYL-VALENZSCHWINGUNGEN IN IRIDIUM(I)-KOMPLEXEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197116137  0.306
1970 Darensbourg DJ, Darensbourg MY. Reactions of transition metal carbonyls with organolithium compounds. II. Prediction of nucleophilic attack at carbon and resultant stereochemistry Inorganic Chemistry. 9: 1691-1694. DOI: 10.1021/Ic50089A016  0.66
1970 Darensbourg MY, Darensbourg DJ. Spectroscopic studies of some carbene pentacarbonyl complexes of chromium(0) and tungsten(0) Inorganic Chemistry. 9: 32-39. DOI: 10.1021/Ic50083A007  0.669
1970 Darensbourg DJ, Darensbourg MY. Infrared determination of stereochemistry in metal complexes: An application of group theory Journal of Chemical Education. 47: 33. DOI: 10.1021/Ed047P33  0.643
1968 Darensbourg DJ, Brown TL. Kinetics of the thermal decomposition and substitution reactions of molybdenum pentacarbonyl amine compounds Inorganic Chemistry. 7: 1679-1680. DOI: 10.1021/Ic50066A053  0.5
1968 Darensbourg DJ, Brown TL. Infrared intensities of the carbonyl stretching modes and electronic spectra of substituted molybdenum carbonyls Inorganic Chemistry. 7: 959-966. DOI: 10.1021/Ic50063A023  0.463
1967 Brown TL, Darensbourg DJ. Intensities of CO stretching modes in the infrared spectra of adsorbed CO and metal carbonyls Inorganic Chemistry. 6: 971-977. DOI: 10.1021/Ic50051A026  0.472
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