Zvi Rappoport - Publications

Affiliations: 
Chemistry Hebrew University, Jerusalem, Jerusalem, Israel 

233 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2010 SKLENAK S, APELOIG Y, RAPPOPORT Z. ChemInform Abstract: Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HC=C(OH)X (X: OH, NH2, NMe2, OMe, OCHO, F, Cl, Br). Cheminform. 30: no-no. DOI: 10.1002/CHIN.199909032  0.47
2010 Rappoport Z, Biali SE. Stable Aryl-Substituted Enols Bulletin Des SociéTéS Chimiques Belges. 91: 388-388. DOI: 10.1002/Bscb.19820910547  0.379
2009 Bernasconi CF, Rappoport Z. Recent advances in our mechanistic understanding of S(N)V reactions. Accounts of Chemical Research. 42: 993-1003. PMID 19522460 DOI: 10.1021/Ar900048Q  0.392
2009 Schmittel M, Lal M, Lal R, Röck M, Langels A, Rappoport Z, Basheer A, Schlirf J, Deiseroth H, Flörke U, Gescheidt G. A comprehensive picture of the one-electron oxidation chemistry of enols, enolates and α-carbonyl radicals: oxidation potentials and characterization of radical intermediates Tetrahedron. 65: 10842-10855. DOI: 10.1016/J.Tet.2009.10.039  0.316
2009 Basheer A, Mishima M, Rappoport Z. Enols of 2‐nitro‐ and related 2‐substituted malonamides Journal of Physical Organic Chemistry. 23: 255-265. DOI: 10.1002/Poc.1611  0.339
2008 Karni M, Bernasconi CF, Rappoport Z. Role of negative hyperconjugation and anomeric effects in the stabilization of the intermediate in SNV reactions. The Journal of Organic Chemistry. 73: 2980-94. PMID 18376875 DOI: 10.1021/Jo7017476  0.311
2008 Basheer A, Rappoport Z. Enols and thioenols of substituted cyanomonothiocarbonylmalonamides: structures, enolization vs. thioenolization, equilibria and conformations. Organic & Biomolecular Chemistry. 6: 1071-82. PMID 18327333 DOI: 10.1039/B717556F  0.337
2008 Basheer A, Rappoport Z. A rich array of reactions of Cyanomonothiocarbonylmalonamides RNHCSCH(CN)CONHR' and their Thioenols RNHC(SH)=C(CN)CONHR'1. The Journal of Organic Chemistry. 73: 1386-96. PMID 18211087 DOI: 10.1021/Jo7022262  0.373
2008 Basheer A, Rappoport Z. Oxa-ene reaction of enols of amides with 4-phenyl-1,2,4-triazoline-3,5-dione. The Journal of Organic Chemistry. 73: 184-90. PMID 18072789 DOI: 10.1021/Jo702083U  0.374
2008 Basheer A, Rappoport Z. Thioenols and thioamides substituted by twoβ-EWGs. Comparison with analogous amides and enols Journal of Physical Organic Chemistry. 21: 483-491. DOI: 10.1002/Poc.1359  0.38
2007 Song J, Lei YX, Rappoport Z. The first solid enols of anhydrides. Structure, properties, and enol/anhydride equilibria(1). The Journal of Organic Chemistry. 72: 9152-62. PMID 17973427 DOI: 10.1021/Jo071206M  0.368
2007 Song J, Mishima M, Rappoport Z. Isomeric solid enols on ring- and amide-carbonyls of substituted 2-carbanilido-1,3-indandiones. Organic Letters. 9: 4307-10. PMID 17880230 DOI: 10.1021/Ol7018554  0.35
2007 Song J, Yamataka H, Rappoport Z. Dialkoxyphosphinyl-substituted enols of carboxamides. The Journal of Organic Chemistry. 72: 7605-24. PMID 17760461 DOI: 10.1021/Jo0710679  0.351
2007 Basheer A, Yamataka H, Ammal SC, Rappoport Z. Enols of substituted cyanomalonamides. The Journal of Organic Chemistry. 72: 5297-312. PMID 17559283 DOI: 10.1021/Jo070877H  0.343
2007 Bernasconi CF, Brown SD, Eventova I, Rappoport Z. Spectroscopic and kinetic evidence for an accumulating intermediate in an SNV reaction with amine nucleophiles. Reaction of methyl beta-methylthio-alpha-nitrocinnamate with piperidine and morpholine. The Journal of Organic Chemistry. 72: 3302-10. PMID 17407355 DOI: 10.1021/Jo062602S  0.344
2006 Basheer A, Rappoport Z. Substituted 2-methylene-1,3-oxazolidines, -1,3-thiazolidines, -1,3-benzothiazines, -1,3-oxazines, and substituted imidazopyrimidinediones from Cl(CH2)nNCO and Cl(CH2)nNCS and active methylene compounds. The Journal of Organic Chemistry. 71: 9743-50. PMID 17168593 DOI: 10.1021/Jo061835G  0.36
2006 Basheer A, Rappoport Z. The first example of isomeric solid amide and its enol. Organic Letters. 8: 5931-4. PMID 17165897 DOI: 10.1021/Ol062322Z  0.301
2006 Bernasconi CF, Brown SD, Ali M, Rappoport Z, Yamataka H, Salim H. Hydrolysis of α-alkyl-α-(methylthio)methylene Meldrum's acids. A kinetic and computational investigation of steric effects Journal of Organic Chemistry. 71: 4795-4802. PMID 16776504 DOI: 10.1021/Jo060254O  0.314
2006 Biswas S, Ali M, Rappoport Z, Salim H. Reactions of α-isobutyl-α-(methylthio)methylene Meldrum's acid with primary amines in aqueous DMSO Canadian Journal of Chemistry. 84: 1679-1685. DOI: 10.1139/V06-166  0.36
2006 Ali M, Biswas S, Rappoport Z, Bernasconi CF. Kinetics and mechanism of reactions of substituted (methylthio)benzylidene Meldrum's acids with primary amines in aqueous DMSO Journal of Physical Organic Chemistry. 19: 647-653. DOI: 10.1002/Poc.1109  0.333
2005 Saloň J, Milata V, Gatial A, Prónayová N, Leško J, Černuchová P, Rappoport Z, Vo-Thanh G, Loupy A. Nucleophilic Vinylic Substitution (SNV) of Activated Alkoxymethylene Derivatives with 6-Aminoquinoxaline European Journal of Organic Chemistry. 2005: 4870-4878. DOI: 10.1002/Ejoc.200500298  0.356
2004 Bernasconi CF, Ali M, Nguyen K, Ruddat V, Rappoport Z. Reactions of substituted (methylthio)benzylidene Meldrum's acids with secondary alicyclic amines in aqueous DMSO. Evidence for rate-limiting proton transfer. The Journal of Organic Chemistry. 69: 9248-54. PMID 15609963 DOI: 10.1021/Jo040244S  0.308
2004 Basheer A, Rappoport Z. Enols of amides activated by the 2,2,2-trichloroethoxycarbonyl group. The Journal of Organic Chemistry. 69: 1151-60. PMID 14961664 DOI: 10.1021/Jo030266Z  0.32
2003 Galli C, Rappoport Z. Unequivocal S(RN)1 route of vinyl halides with a multitude of competing pathways: reactivity and structure of the vinyl radical intermediate. Accounts of Chemical Research. 36: 580-7. PMID 12924954 DOI: 10.1021/Ar030028Q  0.33
2003 Lei YX, Casarini D, Cerioni G, Rappoport Z. Stable enols of amides ArNHC(OH)=C(CN)CO(2)R. E/Z enols, equilibria with the amides, solvent effects, and hydrogen bonding. The Journal of Organic Chemistry. 68: 947-59. PMID 12558420 DOI: 10.1021/Jo020464A  0.352
2003 Rochlin E, Rappoport Z. Stable simple enols. Resolution of chiral 1-[9'-(2'-fluoroanthryl)]-2,2-dimesitylethenol. A different racemization mechanism for the enol and its acetate. The Journal of Organic Chemistry. 68: 216-26. PMID 12530843 DOI: 10.1021/Jo020497Q  0.327
2003 Fujio M, Rappoport Z, Uddin K, Kim HJ, Tsuno Y. Substituent effects in the 1,1-diphenylcarbenium systems: Hydration and bromination of 1,1-diphenylethylenes Bulletin of the Chemical Society of Japan. 76: 163-169. DOI: 10.1246/Bcsj.76.163  0.309
2003 Lei YX, Casarini D, Cerioni G, Rappoport Z. N-Isopropyl enols of carboxylic acid amides Journal of Physical Organic Chemistry. 16: 525-545. DOI: 10.1002/Poc.629  0.328
2002 Lei YX, Rappoport Z. Reactions of enols of amides with diazomethane. The Journal of Organic Chemistry. 67: 6971-8. PMID 12353990 DOI: 10.1021/Jo0203802  0.387
2002 Annunziata A, Galli C, Gentili P, Guarnieri A, Beit-Yannai M, Rappoport Z. A Search for Unambiguous Vinylic SRN1 Reactions European Journal of Organic Chemistry. 2002: 2136. DOI: 10.1002/1099-0690(200207)2002:13<2136::Aid-Ejoc2136>3.0.Co;2-8  0.343
2001 Bernasconi CF, Ketner RJ, Ragains ML, Chen X, Rappoport Z. Unraveling structure-reactivity relationships in SNV reactions: Kinetics of the reactions of methoxybenzylidenemalononitrile, 2-(methylthiobenzylidene)- 1,3-indandione, 2-(benzylthiobenzylidene)-1,3-indandione, and methyl β-methylthio-α-nitrocinnamate with OH- and thiolate ions in aqueous DMSO Journal of the American Chemical Society. 123: 2155-2164. PMID 11456860 DOI: 10.1021/Ja003536T  0.368
2001 Beit-Yannai M, Chen X, Rappoport Z. Amine catalysis in the vinylic substitution of α-methylthio-α-arylmethylene Meldrum's acids and its absence in the substitution of methyl β-iodo-α-nitrocinnamate by amines Journal of the Chemical Society-Perkin Transactions 1. 1534-1545. DOI: 10.1039/B103486N  0.367
2001 Salim H, Chen X, Rappoport Z. Revisit of the leaving group (LG)/halogen exchange in 1,2-dimesityl-2-phenylvinyl-LG systems: a caveat about ‘mistaken identity’ by X-ray diffraction Journal of Physical Organic Chemistry. 14: 778-787. DOI: 10.1002/Poc.430  0.331
2001 Rappoport Z, Lei Y, Yamataka H. Observable Enols of Anhydrides: Claimed Literature Systems, Calculations, and Predictions Helvetica Chimica Acta. 84: 1405-1431. DOI: 10.1002/1522-2675(20010613)84:6<1405::Aid-Hlca1405>3.0.Co;2-G  0.342
2000 Mukhopadhyaya JK, Sklenak S, Rappoport Z. Cyano-, nitro-, and alkoxycarbonyl-activated observable stable enols of carboxylic acid amides The Journal of Organic Chemistry. 65: 6856-67. PMID 11031002 DOI: 10.1021/Jo000293E  0.673
2000 Lei YX, Cerioni G, Rappoport Z. Stable enols of carboxylic esters. The poly(methoxycarbonyl)cyclopentadiene systems Journal of Organic Chemistry. 65: 4028-4038. PMID 10866621 DOI: 10.1021/Jo000046A  0.351
2000 Sklenak S, Apeloig Y, Rappoport Z. Equilibria of simple thioenol/thiocarbonyl pairs. Comparison with the oxygen analogs and with the parent selenium and tellurium systems. A theoretical study Journal of the Chemical Society-Perkin Transactions 1. 2269-2279. DOI: 10.1039/B004289G  0.714
2000 Mishima M, Mustanir, Eventova I, Rappoport Z. Acidities and pKEnol values of stable simple enols in the gas phase Journal of the Chemical Society-Perkin Transactions 1. 1505-1512. DOI: 10.1039/B001155J  0.307
2000 Mukhopadhyaya JK, Sklenák S, Rappoport Z. Enols of Carboxylic Acid Amides with β-Electron-Withdrawing Substituents Journal of the American Chemical Society. 122: 1325-1336. DOI: 10.1021/Ja992059F  0.321
1999 Rochlin E, Rappoport Z, Kastner F, Pustet N, Mannschreck A. Four Enantiomerization Routes of 1,2,2-Trimesitylvinyl Acetate. Enantioselective Liquid Chromatography of (E)- and (Z)-2-m-Methoxymesityl-1,2-dimesitylvinyl Acetates. The Journal of Organic Chemistry. 64: 8840-8845. PMID 11674787 DOI: 10.1021/Jo9910435  0.321
1999 Bernasconi CF, Ketner RJ, Brown SD, Chen X, Rappoport Z. Acid-Catalyzed Breakdown of Alkoxide and Thiolate Ion Adducts of Benzylidene Meldrum's Acid, Methoxybenzylidene Meldrum's Acid and Thiomethoxybenzylidene Meldrum's Acid. The Journal of Organic Chemistry. 64: 8829-8839. PMID 11674786 DOI: 10.1021/Jo991041K  0.332
1999 Gur E, Kaftory M, Biali SE, Rappoport Z. Conformations and Threshold Rotational Mechanisms of the (Z)-1,2-Diarylethene Moiety: A Structural Correlation Study. The Journal of Organic Chemistry. 64: 8144-8148. PMID 11674729 DOI: 10.1021/Jo9907540  0.706
1999 Bernasconi CF, Leyes AE, Rappoport Z. Kinetics of the Reaction of beta-Methoxy-alpha-nitrostilbene with Cyanamide in 50 DMSO-50 Water. Failure to Detect the S(N)V Intermediate. The Journal of Organic Chemistry. 64: 2897-2902. PMID 11674363 DOI: 10.1021/Jo990044U  0.34
1999 Bernasconi CF, Ketner RJ, Chen X, Rappoport Z. Detection and kinetic characterization of S(N)V intermediates. Reactions of thiomethoxybenzylidene Meldrum's acid with thiolate ions, alkoxide ions, OH-, and water in aqueous DMSO Canadian Journal of Chemistry. 77: 584-594. DOI: 10.1139/V99-009  0.368
1999 Chen X, Yamataka H, Galli C, Rappoport Z. Stereoelectronic effect in the capture reaction of the 1,2-dimesityl-2-phenylvinyl radical Journal of the Chemical Society-Perkin Transactions 1. 1369-1374. DOI: 10.1039/A901671F  0.37
1999 Rappoport Z, Kobayashi S, Stanger A, Boese R. Crystal Structure of 1,2-Diphenyl-5,7-di-tert-butylspiro[2.5]octa-1,4,7-trien-6-one, a Possible Model for Diphenylvinylidenephenonium Ions The Journal of Organic Chemistry. 64: 4370-4375. DOI: 10.1021/Jo982482R  0.601
1998 Schmittel M, Keller M, Burghart A, Rappoport Z, Langels A. Electronic effects in polyarylvinyl propellers. Solid state structures and dynamic behaviour in solution of several crowded enol derivatives Journal of the Chemical Society-Perkin Transactions 1. 869-876. DOI: 10.1039/A707906K  0.301
1998 Sklenák S, Apeloig Y, Rappoport Z. Calculated pKEnolValues for Enols of Carboxylic Acid Derivatives HCC(OH)X (X = OH, NH2, NMe2, OMe, OCHO, F, Cl, Br) Journal of the American Chemical Society. 120: 10359-10364. DOI: 10.1021/Ja980354E  0.718
1998 Bernasconi CF, Ketner RJ, Chen X, Rappoport Z. Kinetics of the reactions of methoxybenzylidene Meldrum's acid with thiolate ions, alkoxide ions, OH-, and water in aqueous DMSO. Detection and kinetic characterization of the S(N)V intermediate Journal of the American Chemical Society. 120: 7461-7468. DOI: 10.1021/Ja9743102  0.38
1997 Frey J, Rappoport Z. Static and Dynamic Stereochemistry and Solvation of 2,2-Ditipylethenols(1). The Journal of Organic Chemistry. 62: 8372-8386. PMID 11671975 DOI: 10.1021/Jo971049Z  0.312
1997 Beit-Yannai M, Rappoport Z, Shainyan BA, Danilevich YS. Intramolecular Geminal and Vicinal Element Effects in Substitution of Simple Bromo(chloro)alkenes by Methoxide and Thiolate Ions. An Example of a Single Step Substitution? The Journal of Organic Chemistry. 62: 8049-8057. PMID 11671910 DOI: 10.1021/Jo9709357  0.36
1997 Rappoport Z, Frey J, Sigalov M, Rochlin E. Recent advances in the chemistry of stable simple enols Pure and Applied Chemistry. 69: 1933-1940. DOI: 10.1351/Pac199769091933  0.385
1997 Sigalov M, Rappoport Z. Intramolecular cyclization of bis(2,4,6-trialkylphenyl) ketenes to isochromenes Journal of the Chemical Society-Perkin Transactions 1. 1911-1912. DOI: 10.1039/A703443A  0.345
1997 Frey J, Rappoport Z. 2,2',4,4',6-Penta-Tert-Butylbenzil : An Unexpected Product In The Attempted Coupling Of Tri-Tert-Butylbenzoyl Chloride With Magnesium-Magnesium Iodide Journal of the Chemical Society-Perkin Transactions 1. 1395-1398. DOI: 10.1039/A607222D  0.315
1997 Bordwell FG, Zhang S, Eventova I, Rappoport Z. Acidities of Stable Simple Enols and Bond Dissociation Enthalpies of Their H-O Bonds in DMSO Journal of Organic Chemistry. 62: 5371-5373. DOI: 10.1021/Jo970404I  0.331
1997 Galli C, Guarnieri A, Koch H, Mencarelli P, Rappoport Z. Effect of Substituents on the Structure of the Vinyl Radical:  Calculations and Experiments The Journal of Organic Chemistry. 62: 4072-4077. DOI: 10.1021/Jo962373H  0.334
1997 Rappoport Z, Shainyan BA. Substitution of 9-(?-bromo-?-arylmethylene)fluorenes by thiolate ions in aqueous acetonitrile Journal of Physical Organic Chemistry. 10: 871-878. DOI: 10.1002/(Sici)1099-1395(199712)10:12<871::Aid-Poc952>3.0.Co;2-R  0.384
1996 Galli C, Gentili P, Guarnieri A, Rappoport Z. Stereochemistry of the Vinylic S(RN)1 Reaction of Triarylvinyl Halides. The Structure of the Intermediate alpha-Arylvinyl Radical. The Journal of Organic Chemistry. 61: 8878-8884. PMID 11667868 DOI: 10.1021/Jo961007V  0.354
1996 Selzer T, Rappoport Z. Bis(dimesitylmethylene)-1,3-dithietane, -1,2,4-trithiane, and -1,2,4,5-tetrathiane. Conformation and DNMR Study. Observable Dimesityl Thioketene. The Journal of Organic Chemistry. 61: 7326-7334. PMID 11667658 DOI: 10.1021/Jo960911K  0.348
1996 Mishima M, Ariga T, Matsumoto T, Kobayashi S, Taniguchi H, Fujio M, Tsuno Y, Rappoport Z. Gas Phase Basicities of Phenylacetylenes. Intrinsic Resonance Demand of the 1-Phenylvinyl Cation Bulletin of the Chemical Society of Japan. 69: 445-451. DOI: 10.1246/Bcsj.69.445  0.324
1996 Schottland EZ, Rappoport Z. Triflate/Mesylate Ratios and Competing C−O and S−O Bond Cleavages in Nucleophilic Vinylic Substitution The Journal of Organic Chemistry. 61: 8536-8543. DOI: 10.1021/Jo961108T  0.427
1996 Selzer T, Rappoport Z. Triphenylethenethiol. Structure, Equilibria with the Thioketone, Solvation, and Association with DMSO† The Journal of Organic Chemistry. 61: 5462-5467. DOI: 10.1021/Jo9604651  0.38
1996 Santiago AN, Lassaga G, Rappoport Z, Rossi RA. SRN1 Photostimulated Reaction of Triphenylvinyl Bromide with Carbanions in DMSO The Journal of Organic Chemistry. 61: 1125-1128. DOI: 10.1021/Jo951144C  0.328
1996 Yamataka H, Aleksiuk O, Biali SE, Rappoport Z. Stereoelectronic Effects in the Nucleophilic Addition to the sp-Hybridized Carbon of a Ketene and Vinyl Cation:  When Is a Mesityl Effectively Smaller than a Phenyl Ring?1 Journal of the American Chemical Society. 118: 12580-12587. DOI: 10.1021/Ja962573A  0.754
1996 Frey J, Rappoport Z. Reactions of the Relatively Persistent Carboxylic Acid Enol2,2-Ditipylethene-1,1-diol. The Reversibility of Ketene Hydration1 Journal of the American Chemical Society. 118: 5182-5191. DOI: 10.1021/Ja960456+  0.401
1996 Cerioni G, Biali SE, Rappoport Z. Hydrogen bonding in calix[n]arenes. A preliminary 17O NMR study Tetrahedron Letters. 37: 5797-5800. DOI: 10.1016/0040-4039(96)01229-4  0.323
1995 Amatore C, Galli C, Gentili P, Guarnieri A, Schottland E, Rappoport Z. Effect of substituents on the competition between several mechanisms of nucleophilic vinylic substitution Journal of the Chemical Society-Perkin Transactions 1. 2341-2350. DOI: 10.1039/P29950002341  0.373
1995 Frey J, Faraggi E, Rappoport Z, Kaftory M. Crystal Structure Of The Solid State Photoreactive 2,2',4,4',6,6'-Hexaisopropylbenzil Journal of the Chemical Society-Perkin Transactions 1. 1745-1748. DOI: 10.1039/P29950001745  0.3
1995 Frey J, Eventova I, Rappoport Z, Müller T, Takai Y, Sawada M. 17O and13C NMR spectra of stable simple enols Journal of the Chemical Society-Perkin Transactions 1. 621-637. DOI: 10.1039/P29950000621  0.333
1995 Maeda K, Okamoto Y, Morlender N, Haddad N, Eventova I, Biali SE, Rappoport Z. Does the Threshold Enantiomerization Route of Crowded Tetraarylethenes Involve Double Bond Rotation? Journal of the American Chemical Society. 117: 9686-9689. DOI: 10.1021/Ja00143A010  0.316
1995 Bernasconi CF, Leyes AE, Eventova I, Rappoport Z. Kinetics of the Reactions of .beta.-Methoxy-.alpha.-nitrostilbene with Methoxyamine and N-Methylmethoxyamine. Direct Observation of the Intermediate in Nucleophilic Vinylic Substitution Journal of the American Chemical Society. 117: 1703-1711. DOI: 10.1021/Ja00111A006  0.328
1995 Cerioni G, Plumitallo A, Frey J, Rappoport Z. 17O NMR studies of diaryl α-diketones. The case of 2,2′,4,4′,6,6′-hexa-tert-butylbenzil Magnetic Resonance in Chemistry. 33: 874-878. DOI: 10.1002/Mrc.1260331106  0.305
1995 Cerioni G, Plumitallo A, Frey J, Rappoport Z. Oxygen-17 and carbon-13 NMR studies of diarylketenes Magnetic Resonance in Chemistry. 33: 669-673. DOI: 10.1002/Mrc.1260330809  0.312
1994 Frey J, Schottland E, Rappoport Z, Bravo-Zhivotovskii D, Nakash M, Botoshansky M, Kaftory M, Apeloig Y. The effective ‘size’ of the tris(trimethylsilyl)silyl group in several molecular environments Journal of the Chemical Society-Perkin Transactions 1. 2555-2562. DOI: 10.1039/P29940002555  0.778
1994 Galli C, Gentili P, Rappoport Z. Competition of Mechanisms in Nucleophilic Substitution of Vinyl Halides. An Unequivocal Example of the Vinylic SRN1 Route1 The Journal of Organic Chemistry. 59: 6786-6795. DOI: 10.1021/Jo00101A045  0.351
1994 Schottland E, Frey J, Rappoport Z. Intramolecular Rotations in 2,2-Dimesityl-1-(9-anthryl)- and -1-(9-triptycyl)vinyl Acetates The Journal of Organic Chemistry. 59: 1663-1671. DOI: 10.1021/Jo00086A015  0.313
1994 Jonas J, Mazal C, Rappoport Z. AnE ?Z isomerization of an electrophilic vinyl azide by15N3?. A probe for internal rotation processes in the carbanionic intermediate of nucleophilic vinylic substitution Journal of Physical Organic Chemistry. 7: 652-654. DOI: 10.1002/Poc.610071111  0.333
1994 Eventova I, Nadler EB, Frey J, Rappoport Z. Low temperature enol-enol association of stable 2,2-diarylethenols Journal of Physical Organic Chemistry. 7: 28-30. DOI: 10.1002/Poc.610070106  0.305
1993 Shainyan BA, Eventova I, Rappoport Z. Sites of successive bromination of the ambident nucleophiles 2-methoxy-, 2,4-dimethoxy- and 2,4,6-trimethoxy-benzylidenefluorenes and 2,2-dimesityl-1-tert-butylethenol Journal of the Chemical Society-Perkin Transactions 1. 1281-1286. DOI: 10.1039/P19930001281  0.332
1993 Shainyan BA, Rappoport Z. Nucleophilic reactions at vinylic center. 27. Vinylic substitution of 1,2-dibromo-1,2-difluoroethylene and tribromofluoroethylene. An intramolecular kBr/kF element effect and apparent inversion of configuration in SNV reactions The Journal of Organic Chemistry. 58: 3421-3428. DOI: 10.1021/Jo00064A036  0.377
1993 Bernasconi CF, Leyes AE, Rappoport Z, Eventova I. Reaction of N-methylmethoxyamine with .beta.-methoxy-.alpha.-nitrostilbene. First direct observation of the intermediate in a nucleophilic vinylic substitution with an amine nucleophile Journal of the American Chemical Society. 115: 7513-7514. DOI: 10.1021/Ja00069A065  0.336
1993 Nadler EB, RÖCk M, Schmittel M, Rappoport Z. Relative stability of crowded isomeric enols: 2-Mesityl-2-phenylethenols and their methyl ethers Journal of Physical Organic Chemistry. 6: 233-242. DOI: 10.1002/Poc.610060407  0.338
1992 Rochlin E, Rappoport Z. Stable simple enols. 31. Substituted xanthenylidene enols. The importance of .beta.-Ar-C:C conjugation in the stabilization of aryl-substituted enols Journal of the American Chemical Society. 114: 230-241. DOI: 10.1021/Ja00027A030  0.307
1992 Rappoport Z. The rapid steps in nucleophilic vinylic addition-elimination substitution. Recent developments Accounts of Chemical Research. 25: 474-479. DOI: 10.1021/Ar00022A007  0.335
1992 Ta-Shma R, Rappoport Z. Solvent-induced changes in the selectivity of solvolyses in aqueous alcohols and related mixtures Advances in Physical Organic Chemistry. 27: 239-291. DOI: 10.1016/S0065-3160(08)60066-0  0.749
1992 Fujio M, Tomita N, Tsuno Y, Kobayashi S, Taniguchi H, Kaspi J, Rappoport Z. Solvent effects on the solvolysis of 1-(p-methoxyphenyl)-2-methylpropen-1-yl tosylate Tetrahedron Letters. 33: 1309-1312. DOI: 10.1016/S0040-4039(00)91609-5  0.328
1991 Hoz S, Basch H, Wolk JL, Rappoport Z, Goldberg M. Calculated double-bond stabilization by bromine and chlorine. Relevance to the kBr/kCl element effect The Journal of Organic Chemistry. 56: 5424-5426. DOI: 10.1021/Jo00018A042  0.564
1991 Nadler EB, Zipory ES, Rappoport Z. Formation of .alpha.-[bis(dimethylamino)phosphoryl]-substituted stable enols and N,N-dialkyl diarylacetamides from diarylketenes and methyllithium in hexamethyl phosphoric triamide The Journal of Organic Chemistry. 56: 4241-4246. DOI: 10.1021/Jo00013A031  0.323
1991 Meyer AY, Rappoport Z. Stable simple enols. Part 28. Representation of the strain in 2,2-dimesitylethenol and its 1-alkyl derivatives The Journal of Organic Chemistry. 56: 3948-3950. DOI: 10.1021/Jo00012A031  0.303
1991 Frey J, Nugiel DA, Rappoport Z. Two dimers derived from the 2,4,6-tri-tert-butylphenyl radical, formed during reactions of the aryllithium or the Grignard reagent with carbonyl compounds Journal of Organic Chemistry. 56: 466-469. DOI: 10.1021/Jo00001A094  0.35
1991 Bernasconi CF, Fassberg J, Killion RB, Schuck DF, Rappoport Z. Kinetics of reactions of hydroxide ion and water with .beta.-X-substituted .alpha.-nitrostilbenes (X = Cl, I, SEt, OMe, SCH2CH2OH) in 50% Me2SO-50% water. Search for the intermediate in nucleophilic vinylic substitution Journal of the American Chemical Society. 113: 4937-4946. DOI: 10.1021/Ja00013A033  0.363
1991 Nadler EB, Rappoport Z. Internal rotation in 2,2-dimesityl-1-trimethylsilylethenol Tetrahedron Letters. 32: 1233-1236. DOI: 10.1016/S0040-4039(00)92053-7  0.343
1991 Zipori E, Rappoport Z. A rearranged acetylene from an E1 solvolysis of a substituted α-trimethylsilylvinyl system Tetrahedron Letters. 32: 6391-6394. DOI: 10.1016/0040-4039(91)80177-8  0.368
1990 Bernasconi CF, Fassberg J, Killion RB, Rappoport Z. Kinetics of reactions of amines with .alpha.-nitro-.beta.-substituted-stilbenes in 50% dimethyl sulfoxide-50% water. Search for the intermediate in nucleophilic vinylic substitution reactions The Journal of Organic Chemistry. 55: 4568-4575. DOI: 10.1021/Jo00302A020  0.35
1990 Nadler EB, Rappoport Z. Stable simple enols. 24. Unusual kinetic stability of enols to ketonization: 1,2-dimesityl-3-methylbut-1-en-1-ol and related .beta.-alkyl-.alpha.,.beta.-dimesitylethenols The Journal of Organic Chemistry. 55: 2673-2682. DOI: 10.1021/Jo00296A025  0.338
1990 Apeloig Y, Arad D, Rappoport Z. Alkyl- and silyl-substituent effects on keto-enol equilibria and the structures of simple aliphatic enols. A theoretical ab initio study Journal of the American Chemical Society. 112: 9131-9140. DOI: 10.1021/Ja00181A015  0.514
1990 RAPPOPORT Z, AVRAMOVITCH B, KARNI M, APELOIG Y. ChemInform Abstract: Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 37. Thiocyanate Ion Promoted E ⇌ Z Isomerization of α-Bromo-β,β-Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS-. Cheminform. 21. DOI: 10.1002/chin.199007084  0.501
1989 Rappoport Z, Topol A. Nucleophilic attacks on carbon-carbon double bonds. Part 39. Nucleophile and nucleofuge effects, catalysis and stereochemistry in vinylic substitution of electrophilic nitro olefins The Journal of Organic Chemistry. 54: 5967-5977. DOI: 10.1021/Jo00286A033  0.367
1989 Lodder G, Van Dorp JWJ, Avramovitch B, Rappoport Z. Nucleophilic attacks on carbon-carbon double bonds. Part 38. Chloride ion exchange and E .dblharw. Z isomerization of an electrophilic vinyl chloride The Journal of Organic Chemistry. 54: 2574-2580. DOI: 10.1021/Jo00272A022  0.347
1989 Bernasconi CF, Killion RB, Fassberg J, Rappoport Z. Kinetics of the reaction of .beta.-methoxy-.alpha.-nitrostilbene with thiolate ions. First direct observation of the intermediate in a nucleophilic vinylic substitution Journal of the American Chemical Society. 111: 6862-6864. DOI: 10.1021/Ja00199A068  0.339
1989 Biali SE, Nugiel DA, Rappoport Z. Stable simple enols. Part 19. Steric effects and threshold rotational mechanisms in 1-substituted 2,2-dimesitylethenols Journal of the American Chemical Society. 111: 846-852. DOI: 10.1021/Ja00185A010  0.315
1989 Nadler EB, Rappoport Z. Stable simple enols. Part 21. Solvent and .alpha.- and .beta.-substituent effects on the association with hydrogen bond accepting solvents and the hydroxyl conformation of stable simple enols Journal of the American Chemical Society. 111: 213-223. DOI: 10.1021/Ja00183A033  0.333
1989 Rappoport Z, Avramovitch B, Karni M, Apeloig Y. Thiocyanate Ion Promoted E ⇌ Z Isomerization of a‐Bromo‐β,β‐Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS − Israel Journal of Chemistry. 29: 267-279. DOI: 10.1002/Ijch.198900036  0.574
1988 Nadler EB, Rappoport Z. Aryl exchange via reversible Friedel-Crafts reaction in the synthesis of a diarylacetic acid The Journal of Organic Chemistry. 53: 5361-5363. DOI: 10.1021/Jo00257A033  0.335
1988 Avramovitch B, Rappoport Z. Nucleophilic attacks on carbon-carbon double bonds. 36. Stereochemistry of substitution of good nucleofuges at the stereoconvergence region as a tool for investigating the rapid step of nucleophilic vinylic substitution Journal of the American Chemical Society. 110: 911-922. DOI: 10.1021/Ja00211A035  0.372
1988 Rappoport Z, Biali SE. Sterically crowded stable simple enols Accounts of Chemical Research. 21: 442-449. DOI: 10.1021/Ar00156A002  0.308
1987 Nadler EB, Rappoport Z, Arad D, Apeloig Y. The first .alpha.-silicon-substituted simple enol. The stabilizing effect of the silyl substituent Journal of the American Chemical Society. 109: 7873-7875. DOI: 10.1021/Ja00259A041  0.514
1987 Rappoport Z, Gazit A. Nucleophilic attacks on carbon-carbon double bonds. Part 35. Methyl trideuteriomethyl (E)-(.alpha.-bromoarylidene)malonates. Simple stereochemical probes in nucleophilic vinylic substitution near the retention/stereoconvergence borderline Journal of the American Chemical Society. 109: 6698-6710. DOI: 10.1021/Ja00256A024  0.336
1987 Avramovitch B, Weyerstahl P, Rappoport Z. Nucleophilic attacks on carbon-carbon double bonds. 34. Intramolecular elements effect in competitive expulsion of two halide nucleofuges as a tool for investigating the rapid step of nucleophilic vinylic substitution Journal of the American Chemical Society. 109: 6687-6697. DOI: 10.1021/Ja00256A023  0.33
1986 Rappoport Z, Gazit A. Nucleophilic attacks on carbon-carbon double bonds. 33. Approaching the retention region from the stereoconvergence region in nucleophilic substitution of (E)- and (Z)-methyl p-substituted .alpha.-formyl- and .alpha.-(tert-butoxycarbonyl)-.beta.-halocinnamates The Journal of Organic Chemistry. 51: 4112-4131. DOI: 10.1021/Jo00372A005  0.352
1986 Biali SE, Rappoport Z. Vinylic cations from solvolysis. 42. Cyclization on methyl, capture by solvent, and degenerate rearrangement of the trimesitylvinyl cation The Journal of Organic Chemistry. 51: 964-970. DOI: 10.1021/Jo00357A002  0.331
1986 Rabin I, Biali SE, Rappoport Z, Lifshitz C. The gas-phase ion chemistry of an enol/aldehyde pair: 2,2-dimesitylethenol and 2,2-dimesitylethanal International Journal of Mass Spectrometry and Ion Processes. 70: 301-320. DOI: 10.1016/0168-1176(86)87005-7  0.32
1986 Uggerud E, Drewello T, Schwarz H, Nadler EB, Biali SE, Rappoport Z. The gas-phase ion chemistry of crowded, triaryl-substituted keto/enol pairs International Journal of Mass Spectrometry and Ion Processes. 71: 287-302. DOI: 10.1016/0168-1176(86)80037-4  0.375
1986 Bottino FA, Musumarra G, Rappoport Z. Studies of substituent effects by carbon-13 NMR spectroscopy.V—Ethyl (E)-(α-cyano)cinnamates, (E)-(α-cyano)cinnamamides and ethyl (α-ethoxycarbonyl)cinnamates Magnetic Resonance in Chemistry. 24: 31-34. DOI: 10.1002/Mrc.1260240108  0.333
1986 Lecoultre J, Heilbronner E, Biali SE, Rappoport Z. Ionization Energies of 1-R-2,2-dimesitylethenols, 1,2-Dimesityl-2-phenylethenol, and Some of their Keto Tautomers Helvetica Chimica Acta. 69: 2108-2113. DOI: 10.1002/Hlca.19860690835  0.305
1985 Kaftory M, Apeloig Y, Rappoport Z. The effect of steric crowding on the structures of solvolytically reactive arylvinyl systems Journal of the Chemical Society-Perkin Transactions 1. 16: 29-37. DOI: 10.1039/P29850000029  0.538
1985 Rappoport Z, Gazit A. Nucleophilic attacks on carbon-carbon double bonds. 31. Complete and partial stereoconversion in vinylic substitution of (E)- and (Z)-.beta.-chloro-.alpha.-phenylcinnamaldehydes and (E)-2-iodo-1,2-diphenyl-1-nitroethylene by nucleophiles The Journal of Organic Chemistry. 50: 3184-3194. DOI: 10.1021/Jo00217A033  0.323
1985 Nugiel D, Rappoport Z. Additions and Corrections - Stable Simple Enols. 11. Equilibrium Constants for the 1-Alkyl-2,2-dimesitylethenol /1-Alkyl2,2-dimesitylethanone Systems in Hexane. The Predominance of Steric Effects on KenolValues Journal of the American Chemical Society. 107: 5832-5832. DOI: 10.1021/Ja00306A603  0.314
1985 Biali SE, Rappoport Z. Stable simple enols. 8. Synthesis and keto .dblharw. enol equilibria of the elusive 2,2-dimesitylethanal and 1,2,2-trimesitylethanone. Conformations of 1,2,2-trimesitylethanone and 1,2,2-trimesitylethanol Journal of the American Chemical Society. 107: 1007-1015. DOI: 10.1021/Ja00290A043  0.307
1985 Biali SE, Rappoport Z, Depke G, Eckart K, Schwarz H. Specific reciprocal methyl/hydrogen transfer reactions and hydrogen exchange processes between aryl rings in crowded ketone cation radicals International Journal of Mass Spectrometry and Ion Processes. 63: 289-304. DOI: 10.1016/0168-1176(85)80031-8  0.385
1985 Nugiel DA, Rappoport Z. Stable simple enols. 11. Equilibrium constants for the 1-alkyl-2,2-dimesitylethenol/1-alkyl-2,2-dimesitylethanone systems in hexane. The predominance of steric effects on Kenol values Journal of the American Chemical Society. 107: 3669-3676. DOI: 10.1002/Chin.198540075  0.305
1985 KAFTORY M, APELOIG Y, RAPPOPORT Z. ChemInform Abstract: THE EFFECT OF STERIC CROWDING ON THE STRUCTURES OF SOLVOLYTICALLY REACTIVE ARYLVINYL SYSTEMS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198516080  0.434
1984 Gazit A, Rappoport Z. Methyl vs. methylene condensation of aromatic aldehydes with 1,1,1-trifluoroacetylacetone Journal of the Chemical Society-Perkin Transactions 1. 16: 2863-2870. DOI: 10.1039/P19840002863  0.33
1984 Rappoport Z, Rav-Acha C. The kBr/kCl element effect for nucleophilic vinylic substitution of the highly reactive tricyanovinyl-x system by substituted anilines Tetrahedron Letters. 25: 117-120. DOI: 10.1016/S0040-4039(01)91164-5  0.335
1984 Biali SE, Depke G, Rappoport Z, Schwarz H. Highly specific reciprocal methyl/hydrogen transfer reactions preceding some unimolecular dissociations of crowded enol cation radicals in the gas phase as examples for conformationally controlled processes Journal of the American Chemical Society. 106: 496-501. DOI: 10.1002/Chin.198419066  0.313
1983 Apeloig Y, Karni M, Rappoport Z. Nucleophilic attacks on carbon-carbon double bonds. Part 29. Role of hyperconjugation in determining the stereochemistry of nucleophilic epoxidation and cyclopropanation of electrophilic olefins Journal of the American Chemical Society. 105: 2784-2793. DOI: 10.1021/Ja00347A044  0.548
1983 Ta-Shma R, Rappoport Z. Azide-water competition in solvolysis reactions. A revisit of the reactivity-selectivity relationship Journal of the American Chemical Society. 105: 6082-6095. DOI: 10.1002/Chin.198352071  0.753
1983 APELOIG Y, KARNI M, RAPPOPORT Z. ChemInform Abstract: NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 29. ROLE OF HYPERCONJUGATION IN DETERMINING THE STEREOCHEMISTRY OF NUCLEOPHILIC EPOXIDATION AND CYCLOPROPANATION OF ELECTROPHILIC OLEFINS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198332103  0.503
1982 Rappoport Z, Avramovitch B. Nucleophilic attacks on carbon-carbon double bonds. 28. Complete and partial stereoconversion in the substitution of methyl (E)- and (Z)-.beta.-chloro-.alpha.-cyano-p-nitrocinnamates by nucleophiles The Journal of Organic Chemistry. 47: 1397-1408. DOI: 10.1021/Jo00347A003  0.338
1982 Rappoport Z, Ta-Shma R. On the selectivity-selectivity relationship in the solvolysis reactions of alkyl halides The Journal of Organic Chemistry. 47: 5207-5209. DOI: 10.1021/Jo00147A036  0.759
1982 Kitamura T, Kobayashi S, Taniguchi H, Rappoport Z. Vinylic cations from solvolysis. Part 36. Vinylation of aromatic substrates with solvolytically generated trisubstituted vinyl cations The Journal of Organic Chemistry. 47: 5003-5009. DOI: 10.1021/Jo00146A033  0.335
1982 Ta-Shma R, Rappoport Z. On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides Tetrahedron Letters. 23: 781-784. DOI: 10.1016/S0040-4039(00)86948-8  0.753
1981 Apeloig Y, Franke W, Rappoport Z, Schwarz H, Stahl D. Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: experimental and computational evidence for the formation of stable .alpha.-arylvinyl cations both by direct means and by spontaneous exothermic isomerization of unstable isomeric ions Journal of the American Chemical Society. 103: 2770-2780. DOI: 10.1021/Ja00400A047  0.538
1981 APELOIG Y, FRANKE W, RAPPOPORT Z, SCHWARZ H, STAHL D. ChemInform Abstract: DISSOCIATIVE IONIZATION OF ARYL-SUBSTITUTED VINYL BROMIDES IN THE GAS PHASE: EXPERIMENTAL AND COMPUTATIONAL EVIDENCE FOR THE FORMATION OF STABLE α-ARYLVINYL CATIONS BOTH BY DIRECT MEANS AND BY SPONTANEOUS EXOTHERMIC ISOMERIZATION OF U Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198134069  0.554
1980 Van Ginkel FIM, Hartman ER, Lodder G, Greenblatt J, Rappoport Z. Vinylic cations from solvolysis. 30. Bromide exchange as a reactivity-selectivity probe in vinylic solvolysis Journal of the American Chemical Society. 102: 7514-7519. DOI: 10.1021/Ja00545A020  0.3
1980 Rappoport Z, Apeloig Y, Greenblatt J. Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions Journal of the American Chemical Society. 102: 3837-3848. DOI: 10.1021/Ja00531A028  0.538
1980 Rappoport Z, Topol A. Nucleophilic attacks on carbon-carbon double bonds. 26. Stereoconvergence in nucleophilic vinylic substitution of an activated nitro olefin Journal of the American Chemical Society. 102: 406-407. DOI: 10.1021/Ja00521A083  0.334
1980 RAPPOPORT Z, GREENBLATT J, APELOIG Y. ChemInform Abstract: 1,10-, 1,4-, AND 1,2-ELIMINATIONS AND 1,5- AND 1,7-REARRANGEMENTS IN THE REACTIONS OF SUBSTITUTED 9-ANISYLIDENE-9,10-DIHYDROANTHRACENES AND ANTHRONES IN ACETIC ACID Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198007218  0.524
1979 Rappoport Z, Greenblatt J, Apeloig Y. 1,10-, 1,4-, and 1,2-Eliminations and 1,5- and 1,7-rearrangements in the reactions of substituted 9-anisylidene-9,10-dihydroanthracenes and anthrones in acetic acid The Journal of Organic Chemistry. 44: 3687-3694. DOI: 10.1021/Jo01335A015  0.562
1979 Apeloig Y, Rappoport Z. The importance of hyperconjugation in nucleophilic vinylic substitution Journal of the American Chemical Society. 101: 5095-5098. DOI: 10.1021/Ja00511A065  0.577
1979 Rappoport Z, Peled P. Nucleophilic attacks on carbon-carbon double bonds. 25. Reactions of monoamines and diamines with 1,1-dicyano-2-p-dimethylaminophenyl-2-trifluoroethoxyethylene Journal of the American Chemical Society. 101: 2682-2693. DOI: 10.1021/Ja00504A032  0.34
1979 Rappoport Z. On the coexistence of the “reactivity-selectivity” and the “constant selectivity” relationships in reactions of carbonium ions with nucleophiles Tetrahedron Letters. 20: 2559-2562. DOI: 10.1016/S0040-4039(01)86348-6  0.333
1979 APELOIG Y, RAPPOPORT Z. ChemInform Abstract: THE IMPORTANCE OF HYPERCONJUGATION IN NUCLEOPHILIC VINYLIC SUBSTITUTION Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197947088  0.542
1977 Rappoport Z. Nucleophilic attacks on carbon–carbon double bonds. Part 24. Nucleophilic substitution of (E)- and (Z)-3-chloro-2-phenylpropenonitriles; comments on the work of Le Guillanton and Cariou Journal of the Chemical Society-Perkin Transactions 1. 8: 1000-1003. DOI: 10.1039/P29770001000  0.394
1977 Ta-Shma R, Rappoport Z. Nucleophilic attacks on carbon–nitrogen double bonds. Part 4. Substitution of N-arylbenzimidoyl cyanides by amines in acetonitrile and by alkoxides in alcohols Journal of the Chemical Society-Perkin Transactions 1. 8: 659-667. DOI: 10.1039/P29770000659  0.779
1977 Ta-Shma R, Rappoport Z. Additions and Corrections - Nucleophilic Attacks on Carbon-Nitrogen Double Bonds. 3. Diversity of Mechanisms for the Substitution of Diarylimidoyl Chlorides by Amines in Acetonitrile. Journal of the American Chemical Society. 99: 3894-3894. DOI: 10.1021/Ja00453A605  0.781
1976 Ta-Shma R, Rappoport Z. Nucleophilic attacks on carbon-nitrogen double bonds. 3. Diversity of mechanisms for the substitution of diarylimidoyl chlorides by amines in acetonitrile Journal of the American Chemical Society. 98: 8460-8467. DOI: 10.1021/Ja00442A024  0.78
1976 Houminer Y, Noy E, Rappoport Z. Vinylic cations from solvolysis. 24. Degenerate .beta.-aryl rearrangements during the solvolysis of 1,2-dianisyl-2-phenylvinyl bromides and trianisylvinyl bromide. Free vinyl cations as intermediates Journal of the American Chemical Society. 98: 5632-5642. DOI: 10.1021/Ja00434A038  0.311
1975 HOZ S, ALBECK M, RAPPOPORT Z. Fluoride Ion as a Catalyst for Michael Additions to Nitro-Alkenes Synthesis. 1975: 162-162. DOI: 10.1055/S-1975-23689  0.536
1975 Rappoport Z, Topol A. Nucleophilic attacks on carbon–carbon double bonds. Part XXIII. Substitution of β-chloro-α-phenylacrylonitriles Journal of the Chemical Society-Perkin Transactions 1. 982-988. DOI: 10.1039/P29750000982  0.398
1975 Rappoport Z, Topol A. Nucleophilic attacks on carbon–carbon double bonds. Part XXII. Base catalysis, leaving group effects, and solvent effects in several nucleophilic vinylic substitutions by amines Journal of the Chemical Society-Perkin Transactions 1. 6: 863-874. DOI: 10.1039/P29750000863  0.372
1975 Albeck M, Hoz S, Rappoport Z. E1cB and E2cB mechanisms in the elimination of trifluoroethoxide ion from α,α-dinitro-β,β-diphenyl-β-(trifluoroethoxy)ethanide anion and the non-reactivity of the β-cyano-α,α-dinitro-β,β-diphenylethanide anion Journal of the Chemical Society-Perkin Transactions 1. 628-637. DOI: 10.1039/P29750000628  0.586
1975 Rappoport Z, Hoz S. Nucleophilic attacks on carbon–carbon double bonds. Part XXI. Substitution of (E)-α-chloro-β-nitrostyrene by anilines in acetonitrile Journal of the Chemical Society-Perkin Transactions 1. 6: 272-277. DOI: 10.1039/P29750000272  0.642
1975 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XXI. Solvent effects on the external ion return and the internal return in several vinylic solvolyses Journal of the American Chemical Society. 97: 836-842. DOI: 10.1021/Ja00837A024  0.526
1975 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XX. Ion pairs and free ions in the solvolysis and isomerization of 1,2-dianisyl-2-phenylvinyl halides and mesylates. Use of cis-trans isomerization as a mechanistic tool Journal of the American Chemical Society. 97: 821-835. DOI: 10.1021/Ja00837A023  0.519
1975 RAPPOPORT Z, TOPOL A. ChemInform Abstract: NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 23, SUBSTITUTION OF BETA-CHLORO-ALPHA-PHENYLACRYLONITRILES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197543092  0.321
1975 ALBECK M, HOZ S, RAPPOPORT Z. ChemInform Abstract: E1CB AND E2CB MECHANISMS IN THE ELIMINATION OF TRIFLUOROETHOXIDE ION FROM ALPHA,ALPHA-DINITRO-BETA,BETA-DIPHENYL-BETA-(TRIFLUOROETHOXY)ETHANIDE ANION AND THE NON-REACTIVITY OF THE BETA-CYANO-ALPHA,ALPHA-DINITRO-BETA-,BETA-DIPHENYLETHA Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197530133  0.517
1975 HOZ S, ALBECK M, RAPPOPORT Z. ChemInform Abstract: FLUORIDE ION AS A CATALYST FOR MICHAEL ADDITION TO NITRO-ALKENES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197524134  0.498
1975 RAPPOPORT Z, HOZ S. ChemInform Abstract: NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 21, SUBSTITUTION OF (E)-ALPHA-CHLORO-BETA-NITROSTYRENE BY ANILINES IN ACETONITRILE Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/chin.197520125  0.537
1975 RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 21, SOLVENT EFFECTS ON THE EXTERNAL ION RETURN AND THE INTERNAL RETURN IN SEVERAL VINYLIC SOLVOLYSES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197518116  0.547
1975 Rappoport Z, Apeloig Y. Vinylic Cations From Solvolysis Part 20, Ion Pairs And Free Ions In The Solvolysis And Isomerization Of 1,2-Dianisyl-2-Phenylvinyl Halides And Mesylates, Use Of Cis-Trans Isomerization As A Mechanistic Tool Cheminform. 6. DOI: 10.1002/Chin.197518115  0.519
1974 Rappoport Z, Ladkani D. Nucleophilic attacks on carbon–carbon double bonds. Part XX. Reaction of active methylene compounds with electrophilic olefins. Formation of substituted 2-amino-4-cyano-4H-pyrans Journal of the Chemical Society-Perkin Transactions 1. 6: 2595-2601. DOI: 10.1039/P19740002595  0.4
1974 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XXII. High stereoselectivity in the synthesis of and ion pair return in the solvolysis of (E)-.alpha.-bromo-.beta.-deuterio-p-methoxystyrene Journal of the American Chemical Society. 96: 6428-6436. DOI: 10.1021/Ja00827A029  0.526
1974 Rappoport Z, Kaspi J. Vinylic cations from solvolysis. XVIII. Unusual solvent effects and external ion return in the solvolysis of several vinylic compounds in aqueous trifluoroethanol Journal of the American Chemical Society. 96: 4518-4530. DOI: 10.1021/Ja00821A027  0.308
1974 Rappoport Z, Kaspi J, Apeloig Y. Vinylic cations from solvolysis. XIX. Low tosylate-bromide reactivity ratios in vinylic solvolyses. Do kOTs/kBr ratios measure the polarity of the solvolytic transition state Journal of the American Chemical Society. 96: 2612-2614. DOI: 10.1021/Ja00815A049  0.503
1974 Rappoport Z, Kaspi J. Solvolysis of 1-p-Methoxyphenyl-2-Methylpropen-1-Yl Trifluoroacetate and 3,5-Dinitrobenzoate Israel Journal of Chemistry. 12: 989-1002. DOI: 10.1002/Ijch.197400094  0.382
1974 RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 22, HIGH STEREOSELECTIVITY IN THE SYNTHESIS OF AND ION PAIR RETURN IN THE SOLVOLYSIS OF (E)-ALPHA-BROMO-BETA-DEUTERIO-P-METHOXYSTYRENE Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197450131  0.534
1974 RAPPOPORT Z, KASPI J. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 18, UNUSUAL SOLVENT EFFECTS AND EXTERNAL ION RETURN IN THE SOLVOLYSIS OF SEVERAL VINYLIC COMPOUNDS IN AQUEOUS TRIFLUOROAETHANOL Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197438106  0.325
1974 RAPPOPORT Z, KASPI J, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 19, LOW TOSYLATE-BROMIDE REACTIVITY RATIOS IN VINYLIC SOLVOLYSES, DO K(OTS)/K(BR) RATIOS MEASURE THE POLARITY OF THE SOLVOLYTIC TRANSITION STATE Chemischer Informationsdienst. 5. DOI: 10.1002/Chin.197426157  0.509
1974 RAPPOPORT Z, LADKANI D. ChemInform Abstract: NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS PART 19, SIGMA, RHO ANALYSIS OF NUCLEOPHILIC REACTIONS ON ARYL-SUBSTITUTED ELECTROPHILIC OLEFINS Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197422121  0.382
1973 Rappoport Z, Houminer Y. Vinylic cations from solvolysis. Part XV. β-Phenyl and β-p-methoxyphenyl rearrangement during the solvolysis of 2,2-diaryl-1-phenylvinyl bromides Journal of the Chemical Society-Perkin Transactions 1. 4: 1506-1518. DOI: 10.1039/P29730001506  0.342
1973 Rappoport Z, Ladkani D. Nucleophilic attacks on carbon–carbon double bonds. Part XVIII. Reaction of 2-dicyanomethyleneindane-1,3-dione with anilines in acetonitrile Journal of the Chemical Society-Perkin Transactions 1. 4: 1045-1052. DOI: 10.1039/P29730001045  0.386
1973 Rappoport Z, Peled P. Nucleophilic attacks on carbon–carbon double bonds. Part XVII. Base-catalysis in the displacement of vinylic ethoxy-, fluoro-, and cyano-leaving groups by amines Journal of the Chemical Society-Perkin Transactions 1. 616-625. DOI: 10.1039/P29730000616  0.357
1973 Rappoport Z, Pross A, Apeloig Y. Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes Tetrahedron Letters. 14: 2015-2018. DOI: 10.1016/S0040-4039(01)86795-2  0.527
1973 RAPPOPORT Z, PROSS A, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS, HIGH K(CIS)/K(TRANS)-REACTIVITY RATIO IN THE SOLVOLYSIS OF ALPHA-BROMO-BETA-TERT.-BUTYL-P-METHOXY-STYRENES Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197337114  0.518
1972 Rappoport Z, Atidia M. Vinylic cations from solvolysis. Part XII. Solvolysis of cis- and trans-α-bromo- and-αβ-dibromo-4,4′-dimethoxystilbenes Journal of the Chemical Society-Perkin Transactions 1. 2316-2323. DOI: 10.1039/P29720002316  0.354
1972 Rappoport Z, Topol A. Nucleophilic attacks on carbon–carbon double bonds. Part XVI. Some relative reactivities of the leaving groups (kBr/kCl, kOMs/kCl, and kOBs/kOTs) in vinylic substitutions Journal of the Chemical Society-Perkin Transactions 1. 1823-1831. DOI: 10.1039/P29720001823  0.415
1972 Albeck M, Hoz S, Rappoport Z. E1cB eliminations. Substituent and solvent effects on the E1cB elimination of the second type from 2-aryl-1,1,2-tricyanopropanes Journal of the Chemical Society-Perkin Transactions 1. 1248-1255. DOI: 10.1039/P29720001248  0.613
1972 Rappoport Z, Kaspi J. Vinylic cations from solvolysis. Part XI. Solvolysis of triarylvinyl arenesulphonates and bromides Journal of the Chemical Society-Perkin Transactions 1. 1102-1111. DOI: 10.1039/P29720001102  0.392
1972 Rappoport Z, Ronen N. Nucleophilic attacks on carbon–carbon double bonds. Part XV. Further evidence for base-catalysis in the reaction of 1,1-dicyano-2-p-dimethylaminophenyl-2-fluoroethylene with substituted anilines in acetonitrile Journal of the Chemical Society-Perkin Transactions 1. 955-961. DOI: 10.1039/P29720000955  0.386
1972 Rappoport Z, Schnabel I. Trityl cation as a leaving group in electrophilic vinylic substitution Journal of the Chemical Society-Perkin Transactions 1. 146-148. DOI: 10.1039/P29720000146  0.341
1972 Kitching W, Sakakiyama T, Rappoport Z, Sleezer PD, Winstein S, Young WG. Metal acetate promoted reactions of .sigma.- and .pi.-allylic organometallics Journal of the American Chemical Society. 94: 2329-2335. DOI: 10.1021/Ja00762A026  0.492
1972 Rappoport Z, Winstein S, Young WG. Allylic oxidation of olefins by mercuric acetate Journal of the American Chemical Society. 94: 2320-2329. DOI: 10.1021/Ja00762A025  0.381
1972 Hoz S, Albeck M, Rappoport Z. A very slow ElcB elimination under extreme ElcB conditions Tetrahedron Letters. 13: 3511-3514. DOI: 10.1016/S0040-4039(01)94086-9  0.503
1972 Rappoport Z, Ta-Shma R. Hindered rotation in several diarylamidines Tetrahedron Letters. 13: 5281-5284. DOI: 10.1016/S0040-4039(01)85230-8  0.72
1972 HOZ S, ALBECK M, RAPPOPORT Z. ChemInform Abstract: EINE SEHR LANGSAME E1CB-ELIMINIERUNG UNTER EXTREMEN E1CB-BEDINGUNGEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197249174  0.563
1972 ALBECK M, HOZ S, RAPPOPORT Z. ChemInform Abstract: E1CB-ELIMINIERUNGEN, SUBSTITUENTEN- UND LOESUNGSMITTELEINFLUESSE AUF DIE E1CB-ELIMINIERUNG DES ZWEITEN TYPS AUS 2-ARYL-1,1,2-TRICYAN-PROPANEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197240134  0.553
1972 RAPPOPORT Z, KASPI J. ChemInform Abstract: VINYLKATIONEN BEI SOLVOLYSEN 11. MITT. SOLVOLYSE VON TRIARYLVINYLARENSULFONATEN UND -BROMIDEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197240122  0.3
1972 RAPPOPORT Z, RONEN N. ChemInform Abstract: NUCLEOPHILE ANGRIFFE AUF KOHLENSTOFF-KOHLENSTOFF-DOPPELBINDUNGEN 15. MITT. WEITERER NACHWEIS EINER BASENKATALYSE BEI DER RK. VON 1,1-DICYANO-2-(P-DIMETHYLAMINO-PHENYL)-2-FLUORAETHYLEN MIT SUBSTITUIERTEN ANILINEN IN ACETONITRIL Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197235152  0.311
1972 KITCHING W, SAKAKIYAMA T, RAPPOPORT Z, SLEEZER PD, WINSTEIN S, YOUNG WG. ChemInform Abstract: DURCH METALLACETATE BESCHLEUNIGTE RK. VON SIGMA- UND PI-ALLYL-METALLVERBINDUNGEN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197226164  0.524
1972 RAPPOPORT Z, WINSTEIN S, YOUNG WG. ChemInform Abstract: ALLYLISCHE OX. VON OLEFINEN DURCH QUECKSILBER(II)-ACETAT Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197226139  0.452
1971 Elmaleh D, Patai S, Rappoport Z. Reaction of 1,1-diarylethylenes with tellurium halides Journal of the Chemical Society C: Organic. 3100-3108. DOI: 10.1039/J39710003100  0.782
1971 Elmaleh D, Patai S, Rappoport Z. Reactions of 1,1-diarylethylenes with selenium compounds Journal of the Chemical Society C: Organic. 2637-2640. DOI: 10.1039/J39710002637  0.791
1971 Rappoport Z, Shohamy E. E1cB eliminations. Part V. Two types of E1cB reaction in the amine-catalysed elimination of HCN from 2,6-dimethyl-4-(ααββ-tetracyanoethyl)aniline in chloroform Journal of the Chemical Society B: Physical Organic. 2060-2068. DOI: 10.1039/J29710002060  0.353
1971 Rappoport Z, Ta-Shma R. Nucleophilic attacks on carbon–carbon double bonds. Part XIV. Low-element effects and amine catalysis in the substitution of 1,1-dicyano-2-p-dimethylaminophenyl-2-halogenoethylenes by anilines in alcohols Journal of the Chemical Society B: Physical Organic. 1461-1467. DOI: 10.1039/J29710001461  0.789
1971 Rappoport Z, Ta-Shma R. Nucleophilic attacks on carbon–carbon double bonds. Part XIII. Vinylic substitution of 1,1-dicyano-2-p-dimethylaminophenyl-2-halogenoethylenes by aromatic amines in acetonitrile Journal of the Chemical Society B: Physical Organic. 871-881. DOI: 10.1039/J29710000871  0.79
1971 Rappoport Z. Sensitivity to the activating group in E1CB eliminations Journal of the Chemical Society B: Physical Organic. 171-173. DOI: 10.1039/J29710000171  0.343
1971 Rappoport Z, Kaspi J. Vinylic cations from solvolysis. IX. Trifluoroacetolysis of 1-anisyl-2-methylpropen-1-yl arylsulfonates Tetrahedron Letters. 12: 4039-4042. DOI: 10.1016/S0040-4039(01)97355-1  0.34
1971 Rappoport Z, Ta-Shma R. Nucleophilic attacks on carbon-nitrogen double bonds. Part I. Substitution of diarylimidoyl chlorides with amines in benzene Tetrahedron Letters. 12: 3813-3816. DOI: 10.1016/S0040-4039(01)97296-X  0.781
1971 Elmaleh D, Patai S, Rappoport Z. NMR Investigation of the Reaction of 1,1-Diarylethylenes with Seleninyl Chloride and Diselenium Dichloride Israel Journal of Chemistry. 9: 155-164. DOI: 10.1002/Ijch.197100025  0.363
1971 ELMALEH D, PATAI S, RAPPOPORT Z. ChemInform Abstract: RK. VON 1,1-DIARYL-AETHYLENEN MIT TELLURHALOGENIDEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197150277  0.769
1971 ELMALEH D, PATAI S, RAPPOPORT Z. ChemInform Abstract: RK. VON 1,1-DIARYL-AETHYLENEN MIT SELENVERBINDUNGEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197145326  0.769
1971 RAPPOPORT Z, TA-SHMA R. ChemInform Abstract: NUCLEOPHILE ANGRIFFE AUF C=C-DOPPELBINDUNGEN 14. MITT. KLEINE ELEMENTEFFEKTE UND AMIN-KATALYSE BEI SUBSTITUTION VON 1,1-DICYAN-2-(P-DIMETHYLAMINO-PHENYL)-2-HALOGEN-AETHYLEN DURCH ANILINE IN ALKOHOLEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197142200  0.761
1971 RAPPOPORT Z. ChemInform Abstract: EMPFINDLICHKEIT GEGENUEBER DER AKTIVIERENDEN GRUPPE BEI E1CB-ELIMINIERUNGEN Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197113208  0.304
1970 Elmaleh D, Patai S, Rappoport Z. Nuclear magnetic resonance and mass spectra of benzoselenopheno-[2,3-b]benzoselenophens Journal of the Chemical Society C: Organic. 939-942. DOI: 10.1039/J39700000939  0.693
1970 Shenhav H, Rappoport Z, Patai S. Nucleophilic attacks on carbon–carbon double bonds. Part XII. Addition of amines to electrophilic olefins and reactivity order of the activating groups Journal of the Chemical Society B: Physical Organic. 469-476. DOI: 10.1039/J29700000469  0.732
1970 Rappoport Z, Baessler T, Hanack M. Vinyl cations from solvolysis Journal of the American Chemical Society. 92: 4985-4987. DOI: 10.1021/Ja00719A040  0.326
1970 Rappoport Z, Dyall LK, Winstein S, Young WG. Allylic oxidation of allylbenzene by mercuric acetate Tetrahedron Letters. 11: 3483-3488. DOI: 10.1016/S0040-4039(01)98508-9  0.371
1970 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. VI. Cis-trans isomerization as a tool for studying vinyl cation formation Tetrahedron Letters. 11: 1845-1848. DOI: 10.1016/S0040-4039(01)98098-0  0.526
1970 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. IV. Absence of β-aryl participation in the solvolysis of triarylvinyl halides Tetrahedron Letters. 11: 1817-1820. DOI: 10.1016/S0040-4039(01)98091-8  0.522
1970 RAPPOPORT Z, DYALL LK, WINSTEIN S, YOUNG WG. ChemInform Abstract: ALLYLOXIDATION VON ALLYLBENZOL MIT QUECKSILBERACETAT Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197046296  0.437
1970 RAPPOPORT Z, BAESSLER T, HANACK M. ChemInform Abstract: VINYLKATIONEN DURCH SOLVOLYSE Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197044150  0.301
1970 RAPPOPORT Z, KASPI J. ChemInform Abstract: VINYL-KATIONEN DURCH SOLVOLYSE 3. MITT. SOLVOLYSE VON TRIARYLVINYL-ARYLSULFONATEN IN WAESSRIGEM ACETON Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197033186  0.347
1970 ELMALEH D, PATAI S, RAPPOPORT Z. ChemInform Abstract: NMR- UND MASSENSPEKTREN VON BENZOSELENOPHENO(2,3-B)BENZOSELENOPHENEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197029130  0.757
1970 SHENHAV H, RAPPOPORT Z, PATAI S. ChemInform Abstract: NUCLEOPHILER ANGRIFF AUF C=C-DOPPELBINDUNGEN 12. MITT. ADDITION VON AMINEN AN ELEKTROPHILE OLEFINE UND REAKTIVITAETSREIHENFOLGE DER AKTIVIERENDEN GRUPPEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197024128  0.701
1970 RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLKATIONEN DURCH SOLVOLYSE 2. MITT. STEREOCHEMIE DER SN1-RK. VON 1,2-DIANISYL-2-PHENYL-VINYLHALIDEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197009092  0.561
1969 Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. II. Stereochemistry of the SN1 reaction of 1,2-dianisyl-2-phenylvinyl halides Journal of the American Chemical Society. 91: 6734-6742. DOI: 10.1021/Ja01052A033  0.549
1969 Rappoport Z, Gal A. Vinylic cations form solvolysis. I. Trianisylvinyl halide system Journal of the American Chemical Society. 91: 5246-5254. DOI: 10.1021/Ja01047A012  0.321
1969 Rappoport Z. Nucleophilic Vinylic Substitution Advances in Physical Organic Chemistry. 7: 1-114. DOI: 10.1016/S0065-3160(08)60263-4  0.401
1968 Rappoport Z, Sheradsky T. The ultraviolet spectra of nitrophenylhydrazones in neutral solution; substituent and solvent effects Journal of the Chemical Society B: Physical Organic. 277-291. DOI: 10.1039/J29680000277  0.366
1966 Grünbaum Z, Patai S, Rappoport Z. Nucleophilic attacks on carbon–carbon double bonds. Part X. Nucleophile-catalysed cis–trans isomerisation of cis-4-nitrochalcone and of diethyl maleate in 95% ethanol Journal of the Chemical Society B: Physical Organic. 1133-1137. DOI: 10.1039/J29660001133  0.721
1966 Kitching W, Rappoport Z, Winstein S, Young WG. Allylic Oxidation of Olefins by Palladium Acetate1 Journal of the American Chemical Society. 88: 2054-2055. DOI: 10.1021/Ja00961A043  0.453
1964 Rappoport Z, Gertler S. 263. Nucleophilic attacks on carbon–carbon double bonds. Part IX. The primary (equilibrium) step. The reaction of tri-n-butylphosphine with arylmethylenemalononitriles in methanol Journal of the Chemical Society (Resumed). 1360-1368. DOI: 10.1039/Jr9640001360  0.377
1964 Rappoport Z, Horowitz A. 262. Nucleophilic attacks on carbon–carbon double bonds. Part VIII. The reaction of N-methylaniline with tetracyanoethylene in chloroform Journal of the Chemical Society (Resumed). 1348-1359. DOI: 10.1039/Jr9640001348  0.369
1964 Rappoport Z, Greenzaid P, Horowitz A. 261. Nucleophilic attacks on carbon–carbon double bonds. Part VII. The “element effect” in tricyanovinylation. The reaction of tricyanovinyl chloride with NN-dialkylanilines Journal of the Chemical Society (Resumed). 1334-1347. DOI: 10.1039/Jr9640001334  0.391
1963 Rappoport Z, Degani C, Patai S. 861. Nucleophilic attacks on carbon–carbon double bonds. Part VI. Amine-catalysed cis–trans-isomerisation of ethyl α-cyano-β-O-methoxyphenylacrylate through a zwitterionic carbanion in benzene Journal of the Chemical Society (Resumed). 4513-4521. DOI: 10.1039/Jr9630004513  0.727
1963 Rappoport Z. 860. Nucleophilic attacks on carbon–carbon double bonds. Part V. The reaction of dimethylaniline with tetracyanoethylene: π- and σ-complexes in electrophilic aromatic and nucleophilic vinylic substitutions Journal of the Chemical Society (Resumed). 4498-4512. DOI: 10.1039/Jr9630004498  0.397
1962 Patai S, Weinstein S, Rappoport Z. 332. The kinetics and mechanism of the decomposition of Michael adducts: an example of the E1cB elimination Journal of the Chemical Society (Resumed). 1741-1748. DOI: 10.1039/Jr9620001741  0.703
1962 Rappoport Z, Patai S. 140. Carbonyl–methylene condensations. Part XIII. Acid-catalysed condensation of ethyl cyanoacetate with aromatic aldehydes Journal of the Chemical Society (Resumed). 731-734. DOI: 10.1039/Jr9620000731  0.704
1962 Patai S, Rappoport Z. 73. Nucleophilic attacks on carbon–carbon double bonds. Part IV. cis–trans-Isomerisation of ethyl α-cyano-β-o-methoxyphenylacrylate by various nucleophiles Journal of the Chemical Society (Resumed). 396-403. DOI: 10.1039/Jr9620000396  0.722
1962 Patai S, Rappoport Z. 72. Nucleophilic attacks on carbon–carbon double bonds. Part III. Base-catalysed hydrolysis of activated carbon–carbon double bonds in 95% ethanol Journal of the Chemical Society (Resumed). 392-396. DOI: 10.1039/Jr9620000392  0.72
1962 Patai S, Rappoport Z. 71. Nucleophilic attacks on carbon–carbon double bonds. Part II. Cleavage of arylmethylenemalononitriles by water in 95% ethanol Journal of the Chemical Society (Resumed). 383-391. DOI: 10.1039/Jr9620000383  0.705
1962 Patai S, Rappoport Z. 70. Nucleophilic attacks on carbon–carbon double bonds. Part I. General considerations: arylmethylene transfer and cyclodimerisation Journal of the Chemical Society (Resumed). 377-382. DOI: 10.1039/Jr9620000377  0.719
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