Brandon Q. Mercado, Ph.D. - Publications

Affiliations: 
2014- Chemistry Yale University, New Haven, CT 
Area:
X-ray crystallography, inorganic chemistry

99 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Bhutto SM, Hooper RX, McWilliams SF, Mercado BQ, Holland PL. Iron(iv) alkyl complexes: electronic structure contributions to Fe-C bond homolysis and migration reactions that form N-C bonds from N. Chemical Science. 15: 3485-3494. PMID 38455018 DOI: 10.1039/d3sc05939a  0.325
2023 Hooper RX, Mercado BQ, Holland PL. Desulfurization and N Binding at an Iron Complex Derived from the C-S Activation of Benzothiophene. Organometallics. 42: 2019-2027. PMID 38282963 DOI: 10.1021/acs.organomet.3c00220  0.342
2023 Bhutto SM, Mercado BQ, Holland PL. Dinitrogen Binding and Functionalization from a Low-Coordinate Alkynyliron Complex. Inorganic Chemistry. 62: 9335-9342. PMID 37294074 DOI: 10.1021/acs.inorgchem.3c00167  0.315
2021 Kim LJ, Xue M, Li X, Xu Z, Paulson E, Mercado B, Nelson HM, Herzon SB. Structure Revision of the Lomaiviticins. Journal of the American Chemical Society. PMID 33900077 DOI: 10.1021/jacs.1c01729  0.337
2020 Rutledge KM, Griesbach C, Mercado BQ, Peczuh MW. Structures of three disubstituted [13]-macro-di-lac-tones reveal effects of substitution on macrocycle conformation. Acta Crystallographica. Section E, Crystallographic Communications. 76: 1617-1623. PMID 33117575 DOI: 10.1107/S2056989020012037  0.311
2020 Shen Z, Li C, Mercado BQ, Ellman JA. Cobalt(III)-Catalyzed Diastereoselective Three-Component C-H Bond Addition to Butadiene and Activated Ketones. Synthesis. 52: 1239-1246. PMID 32884161 DOI: 10.1055/S-0039-1690741  0.396
2020 McWilliams SF, Broere DLJ, Halliday CJV, Bhutto SM, Mercado BQ, Holland PL. Coupling dinitrogen and hydrocarbons through aryl migration. Nature. 584: 221-226. PMID 32788733 DOI: 10.1038/S41586-020-2565-5  0.36
2020 Hu G, Jiang JJ, Kelly HR, Matula AJ, Wu Y, Romano N, Mercado BQ, Wang H, Batista VS, Crabtree RH, Brudvig GW. Surprisingly big linker-dependence of activity and selectivity in CO reduction by an iridium(i) pincer complex. Chemical Communications (Cambridge, England). 56: 9126-9129. PMID 32779668 DOI: 10.1039/D0Cc03207G  0.305
2020 Fisher KJ, Feuer ML, Lant HMC, Mercado BQ, Crabtree RH, Brudvig GW. Concerted proton-electron transfer oxidation of phenols and hydrocarbons by a high-valent nickel complex. Chemical Science. 11: 1683-1690. PMID 32206289 DOI: 10.1039/C9Sc05565G  0.373
2020 Nagelski AL, Fataftah MS, Bollmeyer MM, McWilliams SF, MacMillan SN, Mercado BQ, Lancaster KM, Holland PL. The influences of carbon donor ligands on biomimetic multi-iron complexes for N2 reduction Chemical Science. DOI: 10.1039/D0Sc03447A  0.394
2020 Townsend TM, Bernskoetter WH, Brudvig GW, Hazari N, Lant HM, Mercado BQ. Synthesis of organometallic pincer-supported cobalt(II) complexes Polyhedron. 177: 114308. DOI: 10.1016/J.Poly.2019.114308  0.337
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene. Organometallics. 38: 4224-4232. PMID 34103782 DOI: 10.1021/acs.organomet.9b00534  0.716
2019 Barth EL, Davis RM, Beromi MM, Walden AG, Balcells D, Brudvig GW, Dardir AH, Hazari N, Lant HMC, Mercado BQ, Peczak IL. Bis(dialkylphosphino)ferrocene-Ligated Nickel(II) Precatalysts for Suzuki-Miyaura Reactions of Aryl Carbonates. Organometallics. 38: 3377-3387. PMID 32565607 DOI: 10.1021/Acs.Organomet.9B00543  0.332
2019 DeRosha DE, Chilkuri VG, Van Stappen C, Bill E, Mercado BQ, DeBeer S, Neese F, Holland PL. Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity. Nature Chemistry. PMID 31611632 DOI: 10.1038/S41557-019-0341-7  0.311
2019 Martin DJ, Mercado BQ, Mayer JM. Synthesis and Prior Misidentification of 4--butyl-2,6-dinitrobenzaldehyde. The Journal of Organic Chemistry. PMID 31433645 DOI: 10.1021/Acs.Joc.9B01737  0.321
2019 Speelman AL, Čorić I, Van Stappen C, DeBeer S, Mercado BQ, Holland PL. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site. Journal of the American Chemical Society. PMID 31403298 DOI: 10.1021/Jacs.9B05353  0.375
2019 Connor GP, Mercado BQ, Lant HMC, Mayer JM, Holland PL. Chemical Oxidation of a Coordinated PNP-Pincer Ligand Forms Unexpected Re-Nitroxide Complexes with Reversal of Nitride Reactivity. Inorganic Chemistry. PMID 31389243 DOI: 10.1021/Acs.Inorgchem.9B01075  0.365
2019 DeRosha DE, Arnet NA, Mercado BQ, Holland PL. A [2Fe-1S] Complex That Affords Access to Bimetallic and Higher-Nuclearity Iron-Sulfur Clusters. Inorganic Chemistry. PMID 31247861 DOI: 10.1021/Acs.Inorgchem.9B01212  0.308
2019 Kim D, Rahaman SMW, Mercado BQ, Poli R, Holland PL. Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study. Journal of the American Chemical Society. PMID 31025567 DOI: 10.1021/Jacs.9B02117  0.37
2019 Stone EA, Mercado BQ, Miller SJ. Structure and Reactivity of Highly Twisted N-Acylimidazoles. Organic Letters. PMID 30860852 DOI: 10.1021/Acs.Orglett.9B00624  0.339
2019 Mohadjer Beromi M, Brudvig GW, Hazari N, Lant HM, Mercado BQ. Synthesis and Reactivity of Paramagnetic Ni Polypyridyl Complexes Relevant to Csp2-Csp3 Coupling Reactions. Angewandte Chemie (International Ed. in English). PMID 30859704 DOI: 10.1002/Anie.201901866  0.327
2019 MacLeod KC, DiMucci IM, Zovinka EP, McWilliams SF, Mercado BQ, Lancaster KM, Holland PL. Masked Radicals: Iron Complexes of Trityl, Benzophenone, and Phenylacetylene Organometallics. 38: 4224-4232. DOI: 10.1021/Acs.Organomet.9B00534  0.728
2019 Lynn MA, Miecznikowski JR, Jasinski JP, Kaur M, Mercado BQ, Reinheimer E, Almanza EM, Kharbouch RM, Smith MR, Zygmont SE, Flaherty NF, Smith AC. Copper(I) SNS pincer complexes: Impact of ligand design and solvent coordination on conformer interconversion from spectroscopic and computational studies Inorganica Chimica Acta. 495: 118996. DOI: 10.1016/J.Ica.2019.118996  0.37
2019 Shopov DY, Sharninghausen LS, Sinha SB, Mercado BQ, Brudvig GW, Crabtree RH. Modification of a pyridine-alkoxide ligand during the synthesis of coordination compounds Inorganica Chimica Acta. 484: 75-78. DOI: 10.1016/J.Ica.2018.09.020  0.35
2018 Beromi MM, Banerjee G, Brudvig GW, Charboneau DJ, Hazari N, Lant HMC, Mercado BQ. Modifications to the Aryl Group of dppf-Ligated Ni ‑Aryl Precatalysts: Impact on Speciation and Catalytic Activity in Suzuki-Miyaura Coupling Reactions. Organometallics. 37: 3943-3955. PMID 31736532 DOI: 10.1021/Acs.Organomet.8B00589  0.308
2018 Boerth JA, Maity S, Williams SK, Mercado BQ, Ellman JA. Selective and synergistic cobalt(III)-catalyzed three-component C-H bond addition to dienes and aldehydes. Nature Catalysis. 1: 673-679. PMID 30221249 DOI: 10.1038/s41929-018-0123-4  0.334
2018 McWilliams SF, Bill E, Lukat-Rodgers G, Rodgers KR, Mercado BQ, Holland PL. Effects of N Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex. Journal of the American Chemical Society. PMID 29957940 DOI: 10.1021/Jacs.8B04828  0.35
2018 Bonyhady SJ, DeRosha DE, Vela J, Vinyard DJ, Cowley RE, Mercado BQ, Brennessel WW, Holland PL. Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation. Inorganic Chemistry. PMID 29741884 DOI: 10.1021/Acs.Inorgchem.8B00468  0.367
2018 Broere D, Mercado B, Lukens J, Vilbert A, Banerjee G, Lant H, Lee SH, Bill E, Lancaster K, Sproules S, Holland P. Reversible Ligand-Centered Reduction in Low- Coordinate Iron Formazanate Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29663542 DOI: 10.1002/Chem.201801298  0.369
2018 Shopov DY, Sharninghausen LS, Sinha SB, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH. A Dinuclear Iridium(V,V) Oxo-Bridged Complex Characterized Using a Bulk Electrolysis Technique for Crystallizing Highly Oxidizing Compounds. Inorganic Chemistry. PMID 29634253 DOI: 10.1021/Acs.Inorgchem.8B00757  0.334
2018 Broere D, Mercado BQ, Holland PL. Selective Conversion of CO2 to Isocyanate by Low-Coordinate Fe. Angewandte Chemie (International Ed. in English). PMID 29633494 DOI: 10.1002/Anie.201802357  0.31
2018 Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL. Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry. Inorganic Chemistry. PMID 29629752 DOI: 10.1021/Acs.Inorgchem.8B00226  0.383
2018 Halskov KS, Witten MR, Hoang GL, Mercado BQ, Ellman JA. Rhodium(III)-Catalyzed Imidoyl C-H Activation for Annulations to Azolopyrimidines. Organic Letters. PMID 29582661 DOI: 10.1021/Acs.Orglett.8B00816  0.433
2018 Rudshteyn B, Fisher KJ, Lant HMC, Yang KR, Mercado BQ, Brudvig GW, Crabtree RH, Batista VS. Water-Nucleophilic Attack Mechanism for the CuII(pyalk)2Water-Oxidation Catalyst Acs Catalysis. 8: 7952-7960. DOI: 10.1021/Acscatal.8B02466  0.319
2018 Curley JB, Smith NE, Bernskoetter WH, Hazari N, Mercado BQ. Catalytic Formic Acid Dehydrogenation and CO2 Hydrogenation Using Iron PNRP Pincer Complexes with Isonitrile Ligands Organometallics. 37: 3846-3853. DOI: 10.1021/Acs.Organomet.8B00534  0.355
2017 Horitani M, Grubel K, McWilliams SF, Stubbert BD, Mercado BQ, Yu Y, Gurubasavaraj PM, Lees NS, Holland PL, Hoffman BM. ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase. Chemical Science. 8: 5941-5948. PMID 28989623 DOI: 10.1039/C7Sc01602F  0.443
2017 Kim B, Storch G, Banerjee G, Mercado BQ, Castillo-Lora J, Brudvig GW, Mayer JM, Miller SJ. Stereodynamic Quinone-Hydroquinone Molecules That Enantiomerize at sp(3)-Carbon via Redox-Interconversion. Journal of the American Chemical Society. PMID 28931280 DOI: 10.1021/Jacs.7B09176  0.324
2017 Sharninghausen LS, Sinha SB, Shopov DY, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH. Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand. Angewandte Chemie (International Ed. in English). 56: 13047-13051. PMID 28815915 DOI: 10.1002/Anie.201707593  0.354
2017 Arnet NA, McWilliams SF, DeRosha DE, Mercado BQ, Holland PL. Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron. Inorganic Chemistry. 56: 9185-9193. PMID 28726395 DOI: 10.1021/Acs.Inorgchem.7B01230  0.368
2017 Sinha SB, Shopov DY, Sharninghausen LS, Stein CJ, Mercado BQ, Balcells D, Pedersen TB, Reiher M, Brudvig GW, Crabtree RH. Redox Activity of Oxo-Bridged Iridium Dimers in an N,O-Donor Environment: Characterization of Remarkably Stable Ir(IV,V) Complexes. Journal of the American Chemical Society. 139: 9672-9683. PMID 28648068 DOI: 10.1021/Jacs.7B04874  0.329
2017 Potter TJ, Kamber DN, Mercado BQ, Ellman JA. Rh(III)-Catalyzed Aryl and Alkenyl C-H Bond Addition to Diverse Nitroalkenes. Acs Catalysis. 7: 150-153. PMID 28435749 DOI: 10.1021/Acscatal.6B03217  0.435
2017 DeRosha DE, Mercado BQ, Lukat-Rodgers G, Rodgers KR, Holland PL. Enhancement of C-H Oxidizing Ability in Co-O2  Complexes through an Isolated Heterobimetallic Oxo Intermediate. Angewandte Chemie (International Ed. in English). 56: 3211-3215. PMID 28194845 DOI: 10.1002/Anie.201612010  0.41
2017 Reesbeck ME, Grubel K, Kim D, Brennessel WW, Mercado BQ, Holland PL. Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II). Inorganic Chemistry. 56: 1019-1022. PMID 28067506 DOI: 10.1021/Acs.Inorgchem.6B01952  0.377
2017 Metrano AJ, Abascal NC, Mercado BQ, Paulson EK, Hurtley AE, Miller SJ. Diversity of Secondary Structure in Catalytic Peptides with β-Turn-Biased Sequences. Journal of the American Chemical Society. 139: 492-516. PMID 28029251 DOI: 10.1021/Jacs.6B11348  0.302
2017 MacLeod KC, Lewis RA, DeRosha DE, Mercado BQ, Holland PL. C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron. Angewandte Chemie (International Ed. in English). 56: 1069-1072. PMID 28000416 DOI: 10.1002/Anie.201610679  0.439
2017 Shopov DY, Sharninghausen LS, Sinha SB, Borowski JE, Mercado BQ, Brudvig GW, Crabtree RH. Synthesis of pyridine-alkoxide ligands for formation of polynuclear complexes New Journal of Chemistry. 41: 6709-6719. DOI: 10.1039/C7Nj01845B  0.332
2017 Smith NE, Bernskoetter WH, Hazari N, Mercado BQ. Synthesis and Catalytic Activity of PNP-Supported Iron Complexes with Ancillary Isonitrile Ligands Organometallics. 36: 3995-4004. DOI: 10.1021/Acs.Organomet.7B00602  0.34
2017 Obaid AH, Stracey NG, Incarvito CD, Mercado BQ, Parr J. Transfer hydrogenation of ketones catalyzed by complexes of ruthenium(II) with the heterotridentate [P,N,O] ligands (S)-2-[{2-(diphenylphosphanyl)benzylidene}amino]propan-1-ol, (S)-2-[{2-(diphenylphosphanyl)benzyl}amino]propan-1-ol or the [P,N,S] ligand (S)-2-(dimethylamino)-1-(diphenylphosphino)-3-(methylthio)propane Journal of Organometallic Chemistry. 830: 74-84. DOI: 10.1016/J.Jorganchem.2016.12.008  0.322
2017 Miecznikowski JR, Bernier NA, Van Akin CA, Bonitatibus SC, Morgan ME, Kharbouch RM, Mercado BQ, Lynn MA. Deactivation of a ruthenium(II) N-heterocyclic carbene p-cymene complex during transfer hydrogenation catalysis Transition Metal Chemistry. 43: 21-29. DOI: 10.1007/S11243-017-0189-X  0.365
2016 Michaelos TK, Lant HMC, Sharninghausen LS, Craig SM, Menges FS, Mercado BQ, Brudvig GW, Crabtree RH. Catalytic Oxygen Evolution from Manganese Complexes with an Oxidation-Resistant N,N,O-Donor Ligand. Chempluschem. 81: 1129-1132. PMID 31964076 DOI: 10.1002/Cplu.201600353  0.346
2016 MacLeod KC, McWilliams SF, Mercado BQ, Holland PL. Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia. Chemical Science. 7: 5736-5746. PMID 28066537 DOI: 10.1039/C6Sc00423G  0.364
2016 Bailey WF, Lambert KM, Stempel ZD, Wiberg KB, Mercado BQ. Controlling the Conformational Energy of a Phenyl Group by Tuning the Strength of a Nonclassical CH···O Hydrogen Bond: The Case of 5-Phenyl-1,3-dioxane. The Journal of Organic Chemistry. 81: 12116-12127. PMID 27978750 DOI: 10.1021/Acs.Joc.6B02428  0.32
2016 Sharninghausen LS, Sinha SB, Shopov DY, Choi B, Mercado BQ, Roy X, Balcells D, Brudvig GW, Crabtree RH. High Oxidation State Iridium Mono-μ-oxo Dimers Related to Water Oxidation Catalysis. Journal of the American Chemical Society. 138: 15917-15926. PMID 27960326 DOI: 10.1021/Jacs.6B07716  0.379
2016 Vealey ZN, Mercado BQ, Vaccaro PH. The tropolone-isobutylamine complex: a hydrogen-bonded troponoid without dominant π-π interactions. Acta Crystallographica. Section C, Structural Chemistry. 72: 730-737. PMID 27703119 DOI: 10.1107/S2053229616013474  0.368
2016 Chen S, Bacauanu V, Knecht T, Mercado BQ, Bergman RG, Ellman JA. New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks. Journal of the American Chemical Society. 138: 12664-70. PMID 27642766 DOI: 10.1021/Jacs.6B08355  0.315
2016 MacLeod KC, Menges FS, McWilliams SF, Craig SM, Mercado BQ, Johnson MA, Holland PL. Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides. Journal of the American Chemical Society. 138: 11185-91. PMID 27571271 DOI: 10.1021/Jacs.6B04984  0.412
2016 Bloomfield AJ, Matula AJ, Mercado BQ, Batista VS, Crabtree RH. Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic-Inorganic Ligand. Inorganic Chemistry. 55: 8121-9. PMID 27462911 DOI: 10.1021/Acs.Inorgchem.6B01218  0.357
2016 Magpusao AN, Rutledge K, Hamlin TA, Lawrence JM, Mercado BQ, Leadbeater NE, Peczuh MW. Rules of Macrocycle Topology: A [13]-Macrodilactone Case Study. Chemistry (Weinheim An Der Bergstrasse, Germany). 22: 6001-11. PMID 27001347 DOI: 10.1002/Chem.201504684  0.306
2016 McWilliams SF, Rodgers KR, Lukat-Rodgers G, Mercado BQ, Grubel K, Holland PL. Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes. Inorganic Chemistry. 55: 2960-8. PMID 26925968 DOI: 10.1021/Acs.Inorgchem.5B02841  0.341
2016 Huang DL, Beltrán-Suito R, Thomsen JM, Hashmi SM, Materna KL, Sheehan SW, Mercado BQ, Brudvig GW, Crabtree RH. New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis. Inorganic Chemistry. 55: 2427-35. PMID 26901517 DOI: 10.1021/Acs.Inorgchem.5B02809  0.327
2016 Aldrich EP, Bussey KA, Connell JR, Reinhart EF, Oshin KD, Mercado BQ, Oliver AG. Crystal structure of the thermochromic bis-(di-ethyl-ammonium) tetra-chlorido-cuprate(II) complex. Acta Crystallographica. Section E, Crystallographic Communications. 72: 40-3. PMID 26870581 DOI: 10.1107/S2056989015023348  0.342
2016 Charboneau DJ, Balcells D, Hazari N, Lant HMC, Mayer JM, Melvin PR, Mercado BQ, Morris WD, Repisky M, Suh H. Dinitrogen-Facilitated Reversible Formation of a Si–H Bond in a Pincer-Supported Ni Complex Organometallics. 35: 3154-3162. DOI: 10.1021/Acs.Organomet.6B00514  0.334
2015 Zhang Y, MacIntosh AD, Wong JL, Bielinski EA, Williard PG, Mercado BQ, Hazari N, Bernskoetter WH. Iron catalyzed CO2 hydrogenation to formate enhanced by Lewis acid co-catalysts. Chemical Science. 6: 4291-4299. PMID 29218198 DOI: 10.1039/C5Sc01467K  0.343
2015 Sinha SB, Shopov DY, Sharninghausen LS, Vinyard DJ, Mercado BQ, Brudvig GW, Crabtree RH. A Stable Coordination Complex of Rh(IV) in an N,O-Donor Environment. Journal of the American Chemical Society. 137: 15692-5. PMID 26641941 DOI: 10.1021/Jacs.5B12148  0.363
2015 Suh HW, Balcells D, Edwards AJ, Guard LM, Hazari N, Mader EA, Mercado BQ, Repisky M. Understanding the Solution and Solid-State Structures of Pd and Pt PSiP Pincer-Supported Hydrides. Inorganic Chemistry. 54: 11411-22. PMID 26582548 DOI: 10.1021/Acs.Inorgchem.5B02073  0.302
2015 Arnet NA, Dugan TR, Menges FS, Mercado BQ, Brennessel WW, Bill E, Johnson MA, Holland PL. Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride. Journal of the American Chemical Society. 137: 13220-3. PMID 26457740 DOI: 10.1021/Jacs.5B06841  0.366
2015 Sarina EA, Mercado BQ, Franco JU, Thompson CJ, Easterling ML, Olmstead MM, Balch AL. 2-Aminoethanol Extraction as a Method for Purifying Sc3N@C80 and for Differentiating Classes of Endohedral Fullerenes on the Basis of Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 17035-43. PMID 26437717 DOI: 10.1002/Chem.201502415  0.579
2015 Sharninghausen LS, Mercado BQ, Crabtree RH, Balcells D, Campos J. Gel-assisted crystallization of [Ir4(IMe)7(CO)H10](2+) and [Ir4(IMe)8H9](3+) clusters derived from catalytic glycerol dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 44: 18403-10. PMID 26435314 DOI: 10.1039/C5Dt03302K  0.308
2015 Čorić I, Mercado BQ, Bill E, Vinyard DJ, Holland PL. Binding of dinitrogen to an iron-sulfur-carbon site. Nature. 526: 96-9. PMID 26416755 DOI: 10.1038/Nature15246  0.357
2015 Sharninghausen LS, Mercado BQ, Crabtree RH, Hazari N. Selective conversion of glycerol to lactic acid with iron pincer precatalysts. Chemical Communications (Cambridge, England). 51: 16201-4. PMID 26399400 DOI: 10.1039/C5Cc06857F  0.324
2015 Phillips EM, Mesganaw T, Patel A, Duttwyler S, Mercado BQ, Houk KN, Ellman JA. Synthesis of ent-ketorfanol via a C-H alkenylation/torquoselective 6π electrocyclization cascade. Angewandte Chemie (International Ed. in English). 54: 12044-8. PMID 26385263 DOI: 10.1002/Anie.201505604  0.349
2015 Reesbeck ME, Rodriguez MM, Brennessel WW, Mercado BQ, Vinyard D, Holland PL. Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 20: 875-83. PMID 26044124 DOI: 10.1007/S00775-015-1272-4  0.34
2015 Bailey WF, Lambert KM, Wiberg KB, Mercado BQ. Effect of remote aryl substituents on the conformational equilibria of 2,2-diaryl-1,3-dioxanes: importance of electrostatic interactions. The Journal of Organic Chemistry. 80: 4108-15. PMID 25803722 DOI: 10.1021/Acs.Joc.5B00422  0.318
2014 Grubel K, Brennessel WW, Mercado BQ, Holland PL. Alkali metal control over N-N cleavage in iron complexes. Journal of the American Chemical Society. 136: 16807-16. PMID 25412468 DOI: 10.1021/Ja507442B  0.306
2014 Lewis RA, MacLeod KC, Mercado BQ, Holland PL. Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons. Chemical Communications (Cambridge, England). 50: 11114-7. PMID 25111358 DOI: 10.1039/C4Cc05495D  0.398
2014 Duttwyler S, Chen S, Lu C, Mercado BQ, Bergman RG, Ellman JA. Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers. Angewandte Chemie (International Ed. in English). 53: 3877-80. PMID 24604837 DOI: 10.1002/Anie.201310517  0.338
2014 Chen J, Campos J, Mercado BQ, Crabtree RH, Balcells D. Distortional effects of noncovalent interactions in the crystal lattice of a Cp∗Ir(III) acylhydroxamic acid complex: A joint experimental-computational study Organometallics. 33: 4417-4424. DOI: 10.1021/Om500625C  0.361
2013 Bowles FL, Mercado BQ, Ghiassi KB, Chen SY, Olmstead MM, Yang H, Liu Z, Balch AL. Ordered structures from crystalline carbon disulfide solvates of the nano-tubular fullerenes D5h(1)-C90 and D 5h-C70 Crystal Growth and Design. 13: 4591-4598. DOI: 10.1021/Cg401138G  0.747
2013 Stich TA, Krzystek J, Mercado BQ, McAlpin JG, Ohlin CA, Olmstead MM, Casey WH, David Britt R. Structural insights into [Co4O4(C5H 5N)4(CH3CO2)4] +, a rare Co(IV)-containing cuboidal complex Polyhedron. 64: 304-307. DOI: 10.1016/J.Poly.2013.05.038  0.454
2013 Mercado BQ, Chaur MN, Echegoyen L, Gharamaleki JA, Olmstead MM, Balch AL. A single crystal X-ray diffraction study of a fully ordered cocrystal of pristine Sc3N@D3h(5)-C78 Polyhedron. 58: 129-133. DOI: 10.1016/J.Poly.2012.08.035  0.615
2013 Derikvand Z, Olmstead MM, Mercado BQ, Shokrollahi A, Shahryari M. Solution and solid state studies of three new supramolecular compounds of zinc(II), nickel(II) and uranium(VI) with chelidamic acid and 9-aminoacridine Inorganica Chimica Acta. 406: 256-265. DOI: 10.1016/J.Ica.2013.04.041  0.483
2012 Stevenson S, Rose CB, Maslenikova JS, Villarreal JR, Mackey MA, Mercado BQ, Chen K, Olmstead MM, Balch AL. Selective synthesis, isolation, and crystallographic characterization of LaSc2N@I(h)-C80. Inorganic Chemistry. 51: 13096-102. PMID 23214426 DOI: 10.1021/Ic300888E  0.626
2012 Yang H, Jin H, Wang X, Liu Z, Yu M, Zhao F, Mercado BQ, Olmstead MM, Balch AL. X-ray crystallographic characterization of new soluble endohedral fullerenes utilizing the popular C82 bucky cage. Isolation and structural characterization of Sm@C3v(7)-C82, Sm@C(s)(6)-C82, and Sm@C2(5)-C82. Journal of the American Chemical Society. 134: 14127-36. PMID 22860880 DOI: 10.1021/Ja304867J  0.635
2012 Tian Y, Beavers CM, Busani T, Martin KE, Jacobsen JL, Mercado BQ, Swartzentruber BS, van Swol F, Medforth CJ, Shelnutt JA. Binary ionic porphyrin nanosheets: electronic and light-harvesting properties regulated by crystal structure. Nanoscale. 4: 1695-700. PMID 22310932 DOI: 10.1039/C2Nr11826B  0.609
2012 Biggs-Houck JE, Davis RL, Wei J, Mercado BQ, Olmstead MM, Tantillo DJ, Shaw JT. Carbon-carbon bond-forming reactions of α-thioaryl carbonyl compounds for the synthesis of complex heterocyclic molecules. The Journal of Organic Chemistry. 77: 160-72. PMID 22023077 DOI: 10.1021/Jo201541E  0.476
2011 Yang H, Jin H, Hong B, Liu Z, Beavers CM, Zhen H, Wang Z, Mercado BQ, Olmstead MM, Balch AL. Large endohedral fullerenes containing two metal ions, Sm2@D2(35)-C88, Sm2@C1(21)-C90, and Sm2@D3(85)-C92, and their relationship to endohedral fullerenes containing two gadolinium ions. Journal of the American Chemical Society. 133: 16911-9. PMID 21913729 DOI: 10.1021/Ja206244W  0.731
2011 Beavers CM, Jin H, Yang H, Wang Z, Wang X, Ge H, Liu Z, Mercado BQ, Olmstead MM, Balch AL. Very large, soluble endohedral fullerenes in the series La2C90 to La2C138: isolation and crystallographic characterization of La2@D5(450)-C100. Journal of the American Chemical Society. 133: 15338-41. PMID 21863855 DOI: 10.1021/Ja207090E  0.721
2011 Wang GW, Liu TX, Jiao M, Wang N, Zhu SE, Chen C, Yang S, Bowles FL, Beavers CM, Olmstead MM, Mercado BQ, Balch AL. The cycloaddition reaction of I(h)-Sc₃N@C₈₀ with 2-amino-4,5-diisopropoxybenzoic acid and isoamyl nitrite to produce an open-cage metallofullerene. Angewandte Chemie (International Ed. in English). 50: 4658-62. PMID 21495143 DOI: 10.1002/Anie.201100510  0.649
2011 Mercado BQ, Chen N, Rodríguez-Fortea A, Mackey MA, Stevenson S, Echegoyen L, Poblet JM, Olmstead MM, Balch AL. The shape of the Sc2(μ2-S) unit trapped in C82: crystallographic, computational, and electrochemical studies of the isomers, Sc2(μ2-S)@C(s)(6)-C82 and Sc2(μ2-S)@C(3v)(8)-C82. Journal of the American Chemical Society. 133: 6752-60. PMID 21473581 DOI: 10.1021/Ja200289W  0.626
2011 Yang H, Jin H, Zhen H, Wang Z, Liu Z, Beavers CM, Mercado BQ, Olmstead MM, Balch AL. Isolation and crystallographic identification of four isomers of Sm@C90. Journal of the American Chemical Society. 133: 6299-306. PMID 21452811 DOI: 10.1021/Ja111465N  0.739
2011 Ohlin CA, Harley SJ, McAlpin JG, Hocking RK, Mercado BQ, Johnson RL, Villa EM, Fidler MK, Olmstead MM, Spiccia L, Britt RD, Casey WH. Rates of water exchange for two cobalt(II) heteropolyoxotungstate compounds in aqueous solution. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 4408-17. PMID 21416515 DOI: 10.1002/Chem.201003550  0.437
2011 Li FF, Pinzón JR, Mercado BQ, Olmstead MM, Balch AL, Echegoyen L. [2 + 2] cycloaddition reaction to Sc3N@I(h)-C80. The formation of very stable [5,6]- and [6,6]-adducts. Journal of the American Chemical Society. 133: 1563-71. PMID 21218804 DOI: 10.1021/Ja1097176  0.596
2011 Yang H, Mercado BQ, Jin H, Wang Z, Jiang A, Liu Z, Beavers CM, Olmstead MM, Balch AL. Fullerenes without symmetry: crystallographic characterization of C1(30)-C90 and C1(32)-C90. Chemical Communications (Cambridge, England). 47: 2068-70. PMID 21140021 DOI: 10.1039/C0Cc03017A  0.718
2010 Mercado BQ, Stuart MA, Mackey MA, Pickens JE, Confait BS, Stevenson S, Easterling ML, Valencia R, Rodríguez-Fortea A, Poblet JM, Olmstead MM, Balch AL. Sc2(mu2-O) trapped in a fullerene cage: the isolation and structural characterization of Sc2(mu2-O)@C(s)6-C82 and the relevance of the thermal and entropic effects in fullerene isomer selection. Journal of the American Chemical Society. 132: 12098-105. PMID 20698534 DOI: 10.1021/Ja104902E  0.628
2010 Yang H, Beavers CM, Wang Z, Jiang A, Liu Z, Jin H, Mercado BQ, Olmstead MM, Balch AL. Isolation of a small carbon nanotube: the surprising appearance of D(5h)(1)-C(90). Angewandte Chemie (International Ed. in English). 49: 886-90. PMID 20025012 DOI: 10.1002/Anie.200906023  0.73
2010 Mercado BQ, Olmstead MM, Beavers CM, Easterling ML, Stevenson S, Mackey MA, Coumbe CE, Phillips JD, Phillips JP, Poblet JM, Balch AL. A seven atom cluster in a carbon cage, the crystallographically determined structure of Sc4(mu3-O)3@Ih-C80. Chemical Communications (Cambridge, England). 46: 279-81. PMID 20024351 DOI: 10.1039/B918731F  0.692
2010 Chaur MN, Aparicio-Anglès X, Mercado BQ, Elliott B, Rodríguez-Fortea A, Clotet A, Olmstead MM, Balch AL, Poblet JM, Echegoyen L. Structural and electrochemical property correlations of metallic nitride endohedral metallofullerenes Journal of Physical Chemistry C. 114: 13003-13009. DOI: 10.1021/Jp104352D  0.611
2009 Mercado BQ, Jiang A, Yang H, Wang Z, Jin H, Liu Z, Olmstead MM, Balch AL. Isolation and structural characterization of the molecular nanocapsule Sm(2)@D(3d)(822)-C(104). Angewandte Chemie (International Ed. in English). 48: 9114-6. PMID 19856363 DOI: 10.1002/Anie.200904662  0.561
2008 Mercado BQ, Beavers CM, Olmstead MM, Chaur MN, Walker K, Holloway BC, Echegoyen L, Balch AL. Is the isolated pentagon rule merely a suggestion for endohedral fullerenes? The structure of a second egg-shaped endohedral fullerene--Gd3N@C(s)(39663)-C82. Journal of the American Chemical Society. 130: 7854-5. PMID 18517200 DOI: 10.1021/Ja8032263  0.729
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