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Robert Phipps, Ph.D. - Publications

Affiliations: 
Chemistry University of Cambridge, Cambridge, England, United Kingdom 
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40 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2025 Lit AR, Takano S, Zachau C, Băltărețu I, Phipps RJ. Asymmetric Aziridination of Allylic Carbamates Using Ion-Paired Rhodium Complexes and Extrapolation to C─H Amination of Phenethyl Carbamates. Angewandte Chemie (International Ed. in English). e202507532. PMID 40364763 DOI: 10.1002/anie.202507532  0.316
2024 Kadarauch M, Moss TA, Phipps RJ. Intermolecular Asymmetric Arylative Dearomatization of 1-Naphthols. Journal of the American Chemical Society. 146: 34970-34978. PMID 39631941 DOI: 10.1021/jacs.4c14754  0.416
2024 Hodson NJ, Takano S, Fanourakis A, Phipps RJ. Enantioselective Nitrene Transfer to Hydrocinnamyl Alcohols and Allylic Alcohols Enabled by Systematic Exploration of the Structure of Ion-Paired Rhodium Catalysts. Journal of the American Chemical Society. 146: 22629-22641. PMID 39083568 DOI: 10.1021/jacs.4c07117  0.348
2024 Paterson KJ, Dahiya A, Williams BD, Phipps RJ. Tertiary Amides as Directing Groups for Enantioselective C-H Amination using Ion-Paired Rhodium Complexes. Angewandte Chemie (International Ed. in English). e202317489. PMID 38348742 DOI: 10.1002/anie.202317489  0.364
2023 Docherty PJ, Kadarauch M, Mistry N, Phipps RJ. Application of sSPhos as a Chiral Ligand for Palladium-Catalyzed Asymmetric Allylic Alkylation. Organic Letters. PMID 38147571 DOI: 10.1021/acs.orglett.3c04025  0.394
2023 Kadarauch M, Whalley DM, Phipps RJ. sSPhos: A General Ligand for Enantioselective Arylative Phenol Dearomatization via Electrostatically-Directed Palladium Catalysis. Journal of the American Chemical Society. 145: 25553-25558. PMID 37972383 DOI: 10.1021/jacs.3c10663  0.325
2023 Ermanis K, Gibson DC, Genov GR, Phipps RJ. Interrogating the Crucial Interactions at Play in the Chiral Cation-Directed Enantioselective Borylation of Arenes. Acs Catalysis. 13: 13043-13055. PMID 37822864 DOI: 10.1021/acscatal.3c03384  0.334
2023 Gillespie JE, Lam NYS, Phipps RJ. -Selective amination of arene carboxylic acids rearrangement of acyl -hydroxylamines. Chemical Science. 14: 10103-10111. PMID 37772106 DOI: 10.1039/d3sc03293k  0.324
2023 Bacoş PD, Lahdenperä ASK, Phipps RJ. Discovery and Development of the Enantioselective Minisci Reaction. Accounts of Chemical Research. 56: 2037-2049. PMID 37405731 DOI: 10.1021/acs.accounts.3c00247  0.384
2023 Fanourakis A, Hodson NJ, Lit AR, Phipps RJ. Substrate-Directed Enantioselective Aziridination of Alkenyl Alcohols Controlled by a Chiral Cation. Journal of the American Chemical Society. 145: 7516-7527. PMID 36961353 DOI: 10.1021/jacs.3c00693  0.338
2022 Lahdenperä ASK, Bacoş PD, Phipps RJ. Enantioselective Giese Additions of Prochiral α-Amino Radicals. Journal of the American Chemical Society. PMID 36454604 DOI: 10.1021/jacs.2c11367  0.333
2022 Pearce-Higgins R, Hogenhout LN, Docherty PJ, Whalley DM, Chuentragool P, Lee N, Lam NYS, McGuire TM, Valette D, Phipps RJ. An Enantioselective Suzuki-Miyaura Coupling To Form Axially Chiral Biphenols. Journal of the American Chemical Society. PMID 35969692 DOI: 10.1021/jacs.2c06529  0.346
2022 Colgan AC, Proctor RSJ, Gibson DC, Chuentragool P, Lahdenpera A, Ermanis K, Phipps RJ. Hydrogen Atom Transfer Driven Enantioselective Minisci Reaction of Alcohols. Angewandte Chemie (International Ed. in English). PMID 35420220 DOI: 10.1002/anie.202200266  0.377
2021 Fanourakis A, Williams BD, Paterson KJ, Phipps RJ. Enantioselective Intermolecular C-H Amination Directed by a Chiral Cation. Journal of the American Chemical Society. 143: 10070-10076. PMID 34181401 DOI: 10.1021/jacs.1c05206  0.386
2021 Gillespie JE, Morrill C, Phipps RJ. Regioselective Radical Arene Amination for the Concise Synthesis of -Phenylenediamines. Journal of the American Chemical Society. PMID 34128670 DOI: 10.1021/jacs.1c05531  0.337
2021 Proctor RSJ, Chuentragool P, Colgan AC, Phipps RJ. Hydrogen Atom Transfer-Driven Enantioselective Minisci Reaction of Amides. Journal of the American Chemical Society. PMID 33780237 DOI: 10.1021/jacs.1c01556  0.364
2020 Golding WA, Phipps RJ. Electrostatically-directed Pd-catalysis in combination with C-H activation: site-selective coupling of remote chlorides with fluoroarenes and fluoroheteroarenes. Chemical Science. 11: 3022-3027. PMID 34122805 DOI: 10.1039/d0sc00105h  0.325
2020 Golding WA, Schmitt HL, Phipps RJ. Systematic Variation of Ligand and Cation Parameters Enables Site-Selective C-C and C-N Cross-Coupling of Multiply Chlorinated Arenes through Substrate-Ligand Electrostatic Interactions. Journal of the American Chemical Society. PMID 33332114 DOI: 10.1021/jacs.0c11056  0.6
2020 Ermanis K, Colgan AC, Proctor RSJ, Hadrys BW, Phipps RJ, Goodman JM. A Computational and Experimental Investigation of the Origin of Selectivity in the Chiral Phosphoric Acid Catalyzed Enantioselective Minisci Reaction. Journal of the American Chemical Society. PMID 33252228 DOI: 10.1021/jacs.0c09668  0.371
2019 Reid JP, Proctor RSJ, Sigman MS, Phipps RJ. Predictive Multivariate Linear Regression Analysis Guides Successful Catalytic Enantioselective Minisci Reactions of Diazines. Journal of the American Chemical Society. PMID 31710210 DOI: 10.1021/Jacs.9B11658  0.311
2019 Mihai MT, Williams BD, Phipps RJ. Para-Selective C-H Borylation of Common Arene Building Blocks Enabled by Ion-Pairing with a Bulky Countercation. Journal of the American Chemical Society. PMID 31382747 DOI: 10.1021/jacs.9b07267  0.354
2019 Lee B, Mihai MT, Stojalnikova V, Phipps RJ. Ion Pair-Directed Borylation of Aromatic Phosphonium Salts. The Journal of Organic Chemistry. PMID 31117572 DOI: 10.1021/acs.joc.9b00878  0.325
2018 Golding WA, Pearce-Higgins R, Phipps RJ. Site-Selective Cross-Coupling of Remote Chlorides Enabled by Electrostatically-Directed Palladium Catalysis. Journal of the American Chemical Society. PMID 30295472 DOI: 10.1021/jacs.8b08686  0.316
2018 Proctor RSJ, Davis HJ, Phipps RJ. Catalytic enantioselective Minisci-type addition to heteroarenes. Science (New York, N.Y.). PMID 29622723 DOI: 10.1126/science.aar6376  0.321
2017 Davis HJ, Genov GR, Phipps R. Meta Selective C-H Borylation of Benzylamine, Phenethylamine and Phenylpropylamine-Derived Amides Enabled by a Single Anionic Ligand. Angewandte Chemie (International Ed. in English). PMID 28877397 DOI: 10.1002/anie.201708967  0.396
2017 Davis HJ, Phipps RJ. Harnessing non-covalent interactions to exert control over regioselectivity and site-selectivity in catalytic reactions. Chemical Science. 8: 864-877. PMID 28572898 DOI: 10.1039/c6sc04157d  0.316
2016 Beaud R, Phipps RJ, Gaunt MJ. Enantioselective Cu-Catalyzed Arylation of Secondary Phosphine Oxides with Diaryliodonium Salts toward the Synthesis of P-Chiral Phosphines. Journal of the American Chemical Society. PMID 27689432 DOI: 10.1021/jacs.6b09334  0.679
2015 Yang X, Wu T, Phipps RJ, Toste FD. Advances in catalytic enantioselective fluorination, mono-, di-, and trifluoromethylation, and trifluoromethylthiolation reactions. Chemical Reviews. 115: 826-70. PMID 25337896 DOI: 10.1021/Cr500277B  0.506
2014 Tissot M, Phipps RJ, Lucas C, Leon RM, Pace RD, Ngouansavanh T, Gaunt MJ. Gram-scale enantioselective formal synthesis of morphine through an ortho-para oxidative phenolic coupling strategy. Angewandte Chemie (International Ed. in English). 53: 13498-501. PMID 25288124 DOI: 10.1002/anie.201408435  0.709
2014 Yang X, Phipps RJ, Toste FD. Asymmetric fluorination of α-branched cyclohexanones enabled by a combination of chiral anion phase-transfer catalysis and enamine catalysis using protected amino acids. Journal of the American Chemical Society. 136: 5225-8. PMID 24684209 DOI: 10.1021/Ja500882X  0.522
2013 Wu J, Wang YM, Drljevic A, Rauniyar V, Phipps RJ, Toste FD. A combination of directing groups and chiral anion phase-transfer catalysis for enantioselective fluorination of alkenes. Proceedings of the National Academy of Sciences of the United States of America. 110: 13729-33. PMID 23922394 DOI: 10.1073/Pnas.1304346110  0.72
2013 Phipps RJ, Toste FD. Chiral anion phase-transfer catalysis applied to the direct enantioselective fluorinative dearomatization of phenols. Journal of the American Chemical Society. 135: 1268-71. PMID 23330962 DOI: 10.1021/Ja311798Q  0.564
2012 Honjo T, Phipps RJ, Rauniyar V, Toste FD. A doubly axially chiral phosphoric acid catalyst for the asymmetric tandem oxyfluorination of enamides. Angewandte Chemie (International Ed. in English). 51: 9684-8. PMID 22930652 DOI: 10.1002/Anie.201205383  0.53
2012 Phipps RJ, Hamilton GL, Toste FD. The progression of chiral anions from concepts to applications in asymmetric catalysis. Nature Chemistry. 4: 603-14. PMID 22824891 DOI: 10.1038/Nchem.1405  0.544
2012 Phipps RJ, McMurray L, Ritter S, Duong HA, Gaunt MJ. Copper-catalyzed alkene arylation with diaryliodonium salts. Journal of the American Chemical Society. 134: 10773-6. PMID 22712572 DOI: 10.1021/ja3039807  0.68
2012 Phipps RJ, Hiramatsu K, Toste FD. Asymmetric fluorination of enamides: access to α-fluoroimines using an anionic chiral phase-transfer catalyst. Journal of the American Chemical Society. 134: 8376-9. PMID 22574822 DOI: 10.1021/Ja303959P  0.57
2011 Ciana CL, Phipps RJ, Brandt JR, Meyer FM, Gaunt MJ. A highly para-selective copper(II)-catalyzed direct arylation of aniline and phenol derivatives. Angewandte Chemie (International Ed. in English). 50: 458-62. PMID 21140387 DOI: 10.1002/anie.201004703  0.682
2011 Duong HA, Gilligan RE, Cooke ML, Phipps RJ, Gaunt MJ. Copper(II)-catalyzed meta-selective direct arylation of α-aryl carbonyl compounds. Angewandte Chemie (International Ed. in English). 50: 463-6. PMID 20967917 DOI: 10.1002/anie.201004704  0.706
2009 Phipps RJ, Gaunt MJ. A meta-selective copper-catalyzed C-H bond arylation. Science (New York, N.Y.). 323: 1593-7. PMID 19299616 DOI: 10.1126/science.1169975  0.684
2008 Phipps RJ, Grimster NP, Gaunt MJ. Cu(II)-catalyzed direct and site-selective arylation of indoles under mild conditions. Journal of the American Chemical Society. 130: 8172-4. PMID 18543910 DOI: 10.1021/ja801767s  0.717
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