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Rhett C. Smith, Ph.D. - Publications

Affiliations: 
Chemistry Clemson University, Clemson, SC, United States 
Area:
Organic/Inorganic Materials for catalytic, biomimetic and biosensor applications
Website:
http://www.clemson.edu/ces/departments/chemistry/people/faculty/rsmith.html
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74 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Li G, Smith R, Gembicky M, Rheingold AL, Protasiewicz JD. Sterically crowded 1,4-diiodobenzene as a precursor to difunctional hypervalent iodine compounds. Chemical Communications (Cambridge, England). PMID 34981095 DOI: 10.1039/d1cc06486j  0.667
2019 Wan W, Silva MS, McMillen CD, Creager SE, Smith RC. Highly Luminescent Heavier Main Group Analogues of Boron-Dipyrromethene. Journal of the American Chemical Society. PMID 31120244 DOI: 10.1021/Jacs.9B03235  0.362
2019 Wan W, Bedford MS, Conrad CA, Yang X, Smith RC. Influence of Side‐Chain Composition on Polythiophene Properties and Supramolecular Assembly of Anionic Polythiophene Derivatives Journal of Polymer Science Part a: Polymer Chemistry. 57: 1173-1179. DOI: 10.1002/Pola.29371  0.327
2017 Wan W, Yang X, Smith RC. Convenient synthetic route to tetraarylphosphonium polyelectrolytes via palladium-catalyzed P-C coupling of aryl triflates and diphenylphosphine Journal of Polymer Science Part a: Polymer Chemistry. 55: 1984-1990. DOI: 10.1002/Pola.28564  0.366
2016 Wan W, Yang X, Smith RC. Convenient route to tetraarylphosphonium polyelectrolytes via metal-catalysed P-C coupling polymerisation of aryl dihalides and diphenylphosphine. Chemical Communications (Cambridge, England). PMID 27928557 DOI: 10.1039/C6Cc08938K  0.339
2015 Yang X, Conrad CA, Wan W, Bedford MS, Hu L, Chumanov G, Smith RC. Influence of spacer length and rigidity on properties of phosphonium polymers and on their supramolecular assembly with a conjugated polyelectrolyte Journal of Materials Chemistry C. 3: 4537-4544. DOI: 10.1039/C4Tc02576H  0.312
2015 Bedford MS, Yang X, Jolly KM, Binnicker RL, Cramer SB, Keen CE, Mairena CJ, Patel AP, Rivenbark MT, Galabura Y, Luzinova I, Smith RC. Tetraarylphosphonium polyelectrolyte chromophores: Synthesis, stability, photophysics, film morphology and critical surface energy Polymer Chemistry. 6: 900-908. DOI: 10.1039/C4Py01483A  0.32
2015 Laughlin BJ, Htet Y, He S, Duniho TL, El Homsi SJ, Ma J, Tennyson AG, Smith RC. Preparation of poly(p-phenylene vinylene) derivatives by a debromination-chain polymerization-debromination sequence European Polymer Journal. 70: 197-202. DOI: 10.1016/J.Eurpolymj.2015.05.012  0.788
2015 Conrad CA, Bedford MS, Buelt AA, Galabura Y, Luzinov I, Smith RC. Phosphonium polyelectrolytes: Influence of diphosphine spacer on layer-by-layer assembly with anionic conjugated polymers Polymer International. DOI: 10.1002/Pi.4930  0.301
2015 Buelt AA, Conrad CA, Mackay WD, Shehata MF, Smith VD, Smith RC. Conjugated polymers with regularly spaced m-phenylene units and post-polymerization modification to yield stimuli-responsive materials Polymer International. 64: 730-739. DOI: 10.1002/Pi.4877  0.376
2014 Buelt AA, Osti NC, Htet Y, Conrad CA, Shehata MF, Potai R, Tennyson AG, Perahia D, Smith RC. Conjugated polymers with m-pyridine linkages: Synthesis, photophysics, solution structure and film morphology Journal of Materials Chemistry C. 2: 8113-8121. DOI: 10.1039/C4Tc00419A  0.355
2014 Saraf SL, Fish TJ, Benninghoff AD, Buelt AA, Smith RC, Berreau LM. Photochemical reactivity of RuII(η6-p-cymene) flavonolato compounds Organometallics. 33: 6341-6351. DOI: 10.1021/Om5006337  0.382
2014 Duniho TL, Laughlin BJ, Buelt AA, Baker WF, Conrad CA, Smith RC. Conjugated polymers for the fluorescent detection of nitroaromatics: Influence of side-chain sterics and π-system electronics Journal of Polymer Science, Part a: Polymer Chemistry. 52: 1487-1492. DOI: 10.1002/Pola.27143  0.779
2014 Mangalum A, Morgan BP, Tennyson AG, Smith RC. Conjugated polymers featuring oxacyclophane-scaffolded π-stacking interactions Macromolecular Chemistry and Physics. 215: 351-357. DOI: 10.1002/Macp.201300630  0.766
2014 Laughlin BJ, Burdette MK, Powell CR, Levy BE, Tennyson AG, Smith RC. Donor-acceptor 1,4-fluorenylene chromophores: Photophysics, electrochemistry, and synthesis through a route for asymmetric chromophore preparation European Journal of Organic Chemistry. DOI: 10.1002/Ejoc.201402181  0.788
2013 Laughlin BJ, Duniho TL, El Homsi SJ, Levy BE, Deligonul N, Gaffen JR, Protasiewicz JD, Tennyson AG, Smith RC. Comparison of 1,4-distyrylfluorene and 1,4-distyrylbenzene analogues: synthesis, structure, electrochemistry and photophysics. Organic & Biomolecular Chemistry. 11: 5425-34. PMID 23863862 DOI: 10.1039/C3Ob40580J  0.781
2013 Kristufek SL, Maltais TR, Tennyson EG, Osti NC, Perahia D, Tennyson AG, Smith RC. Bipyridyl-modified phosphonium polyelectrolytes: Synthesis, photophysics, metal ion coordination and layer-by-layer assembly with anionic conjugated polymers Polymer Chemistry. 4: 5387-5394. DOI: 10.1039/C3Py20765J  0.311
2013 Laughlin FL, Deligonul N, Rheingold AL, Golen JA, Laughlin BJ, Smith RC, Protasiewicz JD. Fluorescent heteroacenes with multiply-bonded phosphorus Organometallics. 32: 7116-7121. DOI: 10.1021/Om400838G  0.781
2013 Grubel K, Saraf SL, Anderson SN, Laughlin BJ, Smith RC, Arif AM, Berreau LM. Synthesis, characterization, and photoinduced CO-release reactivity of a Pb(II) flavonolate complex: Comparisons to Group 12 analogs Inorganica Chimica Acta. 407: 91-97. DOI: 10.1016/J.Ica.2013.07.029  0.778
2012 Laughlin FL, Rheingold AL, Deligonul N, Laughlin BJ, Smith RC, Higham LJ, Protasiewicz JD. Naphthoxaphospholes as examples of fluorescent phospha-acenes. Dalton Transactions (Cambridge, England : 2003). 41: 12016-22. PMID 22899483 DOI: 10.1039/C2Dt30902E  0.773
2012 Laughlin BJ, Baker WF, Duniho TL, El Homsi SJ, Tennyson AG, Smith RC. Synthesis, photophysical and electrochemical properties of conjugated polymers incorporating 9,9-dialkyl-1,4-fluorenylene units with thiophene, carbazole and triarylamine comonomers Polymer Chemistry. 3: 3318-3323. DOI: 10.1039/C2Py20493B  0.79
2012 He S, Buelt AA, Hanley JM, Morgan BP, Tennyson AG, Smith RC. Sterically encumbered bipyridyl-derivatized conjugated polymers and metallopolymers incorporating phenylenevinylene, phenyleneethynylene, and fluorenylene segments Macromolecules. 45: 6344-6352. DOI: 10.1021/Ma2025144  0.609
2012 Grubel K, Marts AR, Greer SM, Tierney DL, Allpress CJ, Anderson SN, Laughlin BJ, Smith RC, Arif AM, Berreau LM. Photoinitiated dioxygenase-type reactivity of open-shell 3d divalent metal flavonolato complexes European Journal of Inorganic Chemistry. 4750-4757. DOI: 10.1002/Ejic.201200212  0.786
2011 Grubel K, Laughlin BJ, Maltais TR, Smith RC, Arif AM, Berreau LM. Photochemically-induced dioxygenase-type CO-release reactivity of group 12 metal flavonolate complexes. Chemical Communications (Cambridge, England). 47: 10431-3. PMID 21842090 DOI: 10.1039/C1Cc13961D  0.766
2010 Buelt AA, Colberg AJ, Dennis AE, Jecen KM, Morgan BP, Smith RC. Poly(p-phenylenevinylene) Derivatives with Defined Conjugation Segments and Post-Polymerization Modification with Sterically Enshrouded Chromophores. Macromolecular Rapid Communications. 31: 752-7. PMID 21590967 DOI: 10.1002/Marc.200900755  0.633
2010 Mangalum A, Gilliard RJ, Hanley JM, Parker AM, Smith RC. Metal ion detection by luminescent 1,3-bis(dimethylaminomethyl) phenyl receptor-modified chromophores and cruciforms. Organic & Biomolecular Chemistry. 8: 5620-7. PMID 20938511 DOI: 10.1039/C0Ob00156B  0.76
2010 Mangalum A, Morgan BP, Hanley JM, Jecen KM, McGill CJ, Robertson GA, Smith RC. Interchromophore orientation scaffolding by m-terphenyl oxacyclophanes. Chemical Communications (Cambridge, England). 46: 5136-8. PMID 20539881 DOI: 10.1039/C0Cc00247J  0.757
2010 Mangalum A, Smith RC. Bifunctional cross-conjugated luminescent phosphines and phosphine derivatives: phospha-cruciforms. Dalton Transactions (Cambridge, England : 2003). 39: 5145-51. PMID 20407729 DOI: 10.1039/B921895E  0.785
2010 Laughlin BJ, Smith RC. Gilch and horner-wittig routes to poly(p-phenylenevinylene) derivatives incorporating monoalkyl defect-free 9,9-Dialkyl-1,4-fluorenylene Units Macromolecules. 43: 3744-3749. DOI: 10.1021/Ma902346W  0.773
2009 He S, Dennis AE, Smith RC. Steric coordination control of interchain interactions in conducting metallopolymers. Macromolecular Rapid Communications. 30: 2079-83. PMID 21638497 DOI: 10.1002/Marc.200900388  0.321
2009 Smith RC. Covalently Scaffolded Inter-π-System Orientations in π-Conjugated Polymers and Small Molecule Models. Macromolecular Rapid Communications. 30: 2067-78. PMID 21638496 DOI: 10.1002/Marc.200900387  0.336
2009 Morgan BP, Gilliard RJ, Loungani RS, Smith RC. Poly(p-phenylene ethynylene) Incorporating Sterically Enshrouding m-Terphenyl Oxacyclophane Canopies. Macromolecular Rapid Communications. 30: 1399-405. PMID 21638397 DOI: 10.1002/Marc.200900160  0.783
2009 Tennyson EG, Smith RC. Visible chromophore phosphines as functional elements of luminescent metallopolymers. Inorganic Chemistry. 48: 11483-5. PMID 20000644 DOI: 10.1021/Ic901155V  0.36
2009 Morgan BP, Galdamez GA, Gilliard RJ, Smith RC. Canopied trans-chelating bis(N-heterocyclic carbene) ligand: synthesis, structure and catalysis. Dalton Transactions (Cambridge, England : 2003). 2020-8. PMID 19259573 DOI: 10.1039/B815739A  0.787
2009 Mangalum A, Smith RC. Polyglycerol-bound phosphotriesterase enzyme model complexes for detection and hydrolysis of phosphorus species in aqueous solution Tetrahedron. 65: 4298-4303. DOI: 10.1016/J.Tet.2009.03.051  0.788
2009 Gilliard RJ, Iacono ST, Budy SM, Moody JD, Smith DW, Smith RC. Chromophore-derivatized semifluorinated polymers for colorimetric and turn-on fluorescent anion detection Sensors and Actuators, B: Chemical. 143: 1-5. DOI: 10.1016/J.Snb.2009.08.047  0.313
2009 Coggins MK, Parker AM, Mangalum A, Galdamez GA, Smith RC. Dizinc Phosphohydrolase Model Built on am-Terphenyl Scaffold and Its Use in Indicator Displacement Assays for Pyrophosphate Under Physiological Conditions (Eur. J. Org. Chem. 3/2009) European Journal of Organic Chemistry. 2009: 311-311. DOI: 10.1002/Ejoc.200990000  0.765
2009 Coggins MK, Parker AM, Mangalum A, Galdamez GA, Smith RC. Dizinc phosphohydrolase model built on a m-terphenyl scaffold and its use in indicator displacement assays for pyrophosphate under physiological conditions European Journal of Organic Chemistry. 343-348. DOI: 10.1002/Ejoc.200800882  0.781
2008 He S, Iacono ST, Budy SM, Dennis AE, Smith DW, Smith RC. Photoluminescence and ion sensing properties of a bipyridyl chromophore-modified semifluorinated polymer and its metallopolymer derivatives Journal of Materials Chemistry. 18: 1970-1976. DOI: 10.1039/B713458D  0.358
2008 Iacono ST, Budy SM, Moody JD, Smith RC, Smith DW. Modular approach to chromophore encapsulation in fluorinated arylene vinylene ether polymers possessing tunable photoluminescence Macromolecules. 41: 7490-7496. DOI: 10.1021/Ma801440T  0.346
2008 Morgan BP, Smith RC. Wide bite angle diphosphine rhodium complexes: Synthesis, structure, and catalytic 1,4-addition of arylboronic acids to enones Journal of Organometallic Chemistry. 693: 11-16. DOI: 10.1016/J.Jorganchem.2007.09.034  0.609
2008 Morgan BP, Smith RC. ChemInform Abstract: Wide Bite Angle Diphosphine Rhodium Complexes: Synthesis, Structure, and Catalytic 1,4-Addition of Arylboronic Acids to Enones. Cheminform. 39. DOI: 10.1002/chin.200824048  0.564
2007 Morgan BP, He S, Smith RC. Dizinc enzyme model/complexometric indicator pairs in indicator displacement assays for inorganic phosphates under physiological conditions. Inorganic Chemistry. 46: 9262-6. PMID 17915862 DOI: 10.1021/Ic701374H  0.61
2007 Tennyson AG, Do L, Smith RC, Lippard SJ. Selective fluorescence detection of nitroxyl over nitric oxide in buffered aqueous solution using a conjugated metallopolymer Polyhedron. 26: 4625-4630. DOI: 10.1016/J.Poly.2007.04.003  0.709
2006 Smith RC, Tennyson AG, Won AC, Lippard SJ. Conjugated metallopolymers for fluorescent turn-on detection of nitric oxide. Inorganic Chemistry. 45: 9367-73. PMID 17083235 DOI: 10.1021/Ic061099Z  0.568
2006 Do L, Smith RC, Tennyson AG, Lippard SJ. Luminescent properties of water-soluble conjugated metallopolymers and their application to fluorescent nitric oxide detection. Inorganic Chemistry. 45: 8998-9005. PMID 17054360 DOI: 10.1021/Ic060998K  0.701
2006 Smith RC, Tennyson AG, Lippard SJ. Polymer-bound dirhodium tetracarboxylate films for fluorescent detection of nitric oxide. Inorganic Chemistry. 45: 6222-6. PMID 16878931 DOI: 10.1021/Ic060070S  0.568
2006 Smith RC, Gleason LB, Protasiewicz JD. Solution and film photoluminescence of mesityl-substituted PPVs and low molecular weight models Journal of Materials Chemistry. 16: 2445-2452. DOI: 10.1039/B601824F  0.697
2005 Smith RC, Tennyson AG, Lim MH, Lippard SJ. Conjugated polymer-based fluorescence turn-on sensor for nitric oxide. Organic Letters. 7: 3573-5. PMID 16048345 DOI: 10.1021/Ol0513903  0.654
2005 Smith RC, Bodner CR, Earl MJ, Sears NC, Hill NE, Bishop LM, Sizemore N, Hehemann DT, Bohn JJ, Protasiewicz JD. Suzuki and Heck coupling reactions mediated by palladium complexes bearing trans-spanning diphosphines Journal of Organometallic Chemistry. 690: 477-481. DOI: 10.1016/J.Jorganchem.2004.09.077  0.693
2005 Ma L, Smith RC, Protasiewicz JD. Self-assembly of cationic palladium complexes by redistribution of pyridine ligands Inorganica Chimica Acta. 358: 3478-3482. DOI: 10.1016/J.Ica.2005.04.015  0.667
2005 Smith RC, Bodner CR, Earl MJ, Sears NC, Hill NE, Bishop LM, Sizemore N, Hehemann DT, Bohn JJ, Protasiewicz JD. Suzuki and Heck Coupling Reactions Mediated by Palladium Complexes Bearing trans-Spanning Diphosphines. Cheminform. 36. DOI: 10.1002/chin.200527102  0.67
2004 Smith RC, Protasiewicz JD. Conjugated polymers featuring heavier main group element multiple bonds: a diphosphene-PPV. Journal of the American Chemical Society. 126: 2268-9. PMID 14982406 DOI: 10.1021/Ja0394683  0.723
2004 Chen X, Smith RC, Protasiewicz JD. Cycloaddition of phosphanylidene-sigma4-phosphoranes ArP=PMe3 and quinones to yield 1,3,2-dioxophospholanes. Chemical Communications (Cambridge, England). 146-7. PMID 14737521 DOI: 10.1039/B309165A  0.77
2004 Smith RC, Protasiewicz JD. A trans-spanning diphosphine ligand based on a m-terphenyl scaffold and its palladium and nickel complexes Organometallics. 23: 4215-4222. DOI: 10.1021/Om049662D  0.713
2004 Smith RC, Gantzel P, Rheingold AL, Protasiewicz JD. Arsa-wittig complexes (ArAs=PMe 3) as intermediates to diarsenes Organometallics. 23: 5124-5126. DOI: 10.1021/Om049340+  0.705
2004 Smith RC, Protasiewicz JD. Conjugated Polymers Featuring Heavier Main Group Element Multiple Bonds: A Diphosphene-PPV Journal of the American Chemical Society. 126: 2268-2269. DOI: 10.1021/ja0394683  0.653
2004 Smith RC, Woloszynek RA, Chen W, Ren T, Protasiewicz JD. Suzuki reactions catalyzed by palladium complexes bearing the bulky (2,6-dimesitylphenyl)dimethylphosphine Tetrahedron Letters. 45: 8327-8330. DOI: 10.1016/J.Tetlet.2004.09.069  0.773
2004 Smith RC, Earl MJ, Protasiewicz JD. Synthesis and photoluminescent properties of a series of pnictogen-centered chromophores Inorganica Chimica Acta. 357: 4139-4143. DOI: 10.1016/J.Ica.2004.06.051  0.71
2004 Smith RC, Protasiewicz JD. Systematic investigation of PPV analogue oligomers incorporating low-coordinate phosphorus centres European Journal of Inorganic Chemistry. 998-1006. DOI: 10.1002/Ejic.200300551  0.706
2004 Chen X, Smith RC, Protasiewicz JD. Cycloaddition of phosphanylidene-σ4-phosphoranes ArP=PMe3 and quinones to yield 1,3,2-dioxophospholanes Chemical Communications. 10: 146-147.  0.651
2003 Dutan C, Shah S, Smith RC, Choua S, Berclaz T, Geoffroy M, Protasiewicz JD. Sterically encumbered diphosphaalkenes and a bis(diphosphene) as potential multiredox-active molecular switches: EPR and DFT investigations. Inorganic Chemistry. 42: 6241-51. PMID 14514299 DOI: 10.1021/Ic030079J  0.735
2003 Smith RC, Chen X, Protasiewicz JD. A fluorescent E-poly(p-phenylenephosphaalkene) prepared by a phospha-Wittig reaction. Inorganic Chemistry. 42: 5468-70. PMID 12950188 DOI: 10.1021/Ic0345471  0.792
2003 Smith RC, Shah S, Umezius E, Protasiewicz JD. An unusual equilibrium chlorine atom transfer process and its potential for assessment of steric pressure by bulky aryls Journal of the American Chemical Society. 125: 40-41. PMID 12515501 DOI: 10.1021/Ja028422R  0.714
2003 Smith RC, Protasiewicz JD. Synthesis and luminescence properties of a series of tris(4-styrylphenyl)phosphorus-(III) and -(V) compounds and of a [Cu(PR3)4]BF4 complex Dalton Transactions. 4738-4741. DOI: 10.1039/B309735H  0.706
2003 Shah S, Eichler BE, Smith RC, Power PP, Protasiewicz JD. Synthesis and solid state structures of increasingly sterically crowded 1,4-diiodo-2,3,5,6-tetraarylbenzenes: A new series of bulky benzenes and aryls New Journal of Chemistry. 27: 442-445. DOI: 10.1039/B210577B  0.751
2003 Smith RC, Chen X, Protasiewicz JD. A fluorescent (E)-poly(p-phenylenephosphaalkene) prepared by a phospha-Wittig reaction Inorganic Chemistry. 42: 5468-5470. DOI: 10.1021/ic0345471  0.784
2003 Dutan C, Shah S, Smith RC, Choua S, Berclaz T, Geoffroy M, Protasiewicz JD. Sterically encumbered diphosphaalkenes and a bis(diphosphene) as potential multiredox-active molecular switches: EPR and DFT investigations Inorganic Chemistry. 42: 6241-6251. DOI: 10.1021/ic030079j  0.698
2003 Copeland T, Shea MP, Milliken MC, Smith RC, Protasiewicz JD, Simpson MC. Raman excitation profile of a sterically protected diphosphene [ArP=PAr] Analytica Chimica Acta. 496: 155-163. DOI: 10.1016/S0003-2670(03)00996-6  0.667
2002 Smith RC, Urnezius E, Lam KC, Rheingold AL, Protasiewicz JD. Syntheses and structural characterizations of the unsymmetrical diphosphene DmpP=PMes* (Dmp = 2,6-Mes2C6H3, Mes* = 2,4,6-tBu3C6H2) and the cyclotetraphosphane [DmpPPPh]2 Inorganic Chemistry. 41: 5296-5299. PMID 12354064 DOI: 10.1021/Ic025759L  0.783
2002 Smith RC, Shah S, Protasiewicz JD. A role for free phosphinidenes in the reaction of magnesium and sterically encumbered ArPCl2 in solution at room temperature Journal of Organometalic Chemistry. 646: 255-261. DOI: 10.1016/S0022-328X(01)01384-5  0.724
2002 Smith R, Ren T, Protasiewicz J. A Robust, Reactive, and Remarkably Simple to Prepare Sterically Encumbered meta-Terphenyl Ligand European Journal of Inorganic Chemistry. 2002: 2779-2783. DOI: 10.1002/1099-0682(200211)2002:11<2779::AID-EJIC2779>3.0.CO;2-Q  0.714
2002 Smith RC, Ren T, Protasiewicz JD. A robust, reactive, and remarkably simple to prepare sterically encumbered meta-terphenyl ligand European Journal of Inorganic Chemistry. 2779-2783. DOI: 10.1002/1099-0682(200211)2002:11<2779::Aid-Ejic2779>3.0.Co;2-Q  0.722
2001 Shah S, Simpson MC, Smith RC, Protasiewicz JD. Three different fates for phosphinidenes generated by photocleavage of phospha-wittig reagents ArP=PMe3 Journal of the American Chemical Society. 123: 6925-6926. PMID 11448199 DOI: 10.1021/Ja015767L  0.693
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