Holger Braunschweig - Publications

Affiliations: 
Institute of Inorganic Chemistry University of Würzburg, Würzburg, Bayern, Germany 

500 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Czernetzki C, Kunz T, Huynh S, Lamprecht A, Sprenger J, Finze M, Arrowsmith M, Braunschweig H. Synthesis and Reactivity of Tricoordinate Organoberyllium Azides. Angewandte Chemie (International Ed. in English). e202401279. PMID 38470074 DOI: 10.1002/anie.202401279  0.311
2024 Dhara D, Endres L, Krummenacher I, Arrowsmith M, Dewhurst RD, Engels B, Bertermann R, Finze M, Demeshko S, Meyer F, Fantuzzi F, Braunschweig H. Synthesis and Reactivity of a Dialane-Bridged Diradical. Angewandte Chemie (International Ed. in English). e202401052. PMID 38415886 DOI: 10.1002/anie.202401052  0.485
2024 Czernetzki C, Arrowsmith M, Endres L, Krummenacher I, Braunschweig H. Tricoordinate Beryllium Radicals and Their Reactivity. Inorganic Chemistry. 63: 2670-2678. PMID 38259240 DOI: 10.1021/acs.inorgchem.3c04014  0.325
2024 Duwe D, Saha K, Endres L, Brückner T, Dewhurst RD, Dietz M, Radacki K, Fantuzzi F, Braunschweig H. Stepwise and selective synthesis of chelating, multimetallic and mixed-metal π-diborene complexes. Chemical Communications (Cambridge, England). 60: 1120-1123. PMID 38193141 DOI: 10.1039/d3cc05477b  0.306
2023 Haufe LC, Endres L, Arrowsmith M, Bertermann R, Dietz M, Fantuzzi F, Finze M, Braunschweig H. Boron Insertion into the N≡N Bond of a Tungsten Dinitrogen Complex. Journal of the American Chemical Society. 145: 23986-23993. PMID 37875434 DOI: 10.1021/jacs.3c06259  0.308
2023 Xiang L, Wang J, Krummenacher I, Radacki K, Braunschweig H, Lin Z, Ye Q. Persistent and Predominantly Localized Boron Radical from the Reduction of a Three-dimensional Analogue of NHC-Stabilized Borafluorenium. Chemistry (Weinheim An Der Bergstrasse, Germany). e202301270. PMID 37098696 DOI: 10.1002/chem.202301270  0.492
2023 Gärtner A, Karaca US, Rang M, Heinz M, Engel PD, Krummenacher I, Arrowsmith M, Hermann A, Matler A, Rempel A, Witte R, Braunschweig H, Holthausen MC, Légaré MA. Achieving Control over the Reduction/Coupling Dichotomy of N by Boron Metallomimetics. Journal of the American Chemical Society. PMID 36977310 DOI: 10.1021/jacs.3c01762  0.714
2023 Huynh S, Arrowsmith M, Meier L, Dietz M, Härterich M, Michel M, Gärtner A, Braunschweig H. Cyclic alkyl(amino)iminates (CAAIs) as strong 2σ,4π-electron donor ligands for the stabilisation of boranes and diboranes(4): a synthetic and computational study. Dalton Transactions (Cambridge, England : 2003). 52: 3869-3876. PMID 36876450 DOI: 10.1039/d3dt00298e  0.312
2022 Witte R, Arrowsmith M, Lamprecht A, Schorr F, Krummenacher I, Braunschweig H. C-C and C-N Bond Activation, Lewis-Base Coordination and One- and Two-Electron Oxidation at a Linear Aminoborylene. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 36562195 DOI: 10.1002/chem.202203663  0.306
2022 Lindl F, Lamprecht A, Arrowsmith M, Khitro E, Rempel A, Dietz M, Wellnitz T, Bélanger-Chabot G, Stoy A, Paprocki V, Prieschl D, Lenczyk C, Ramler J, Lichtenberg C, Braunschweig H. Aromatic 1,2-Azaborinin-1-yls as Electron-Withdrawing Anionic Nitrogen Ligands for Main Group Elements. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 36412126 DOI: 10.1002/chem.202203345  0.733
2022 Lindl F, Fantuzzi F, Mailänder L, Hörl C, Bélanger-Chabot G, Braunschweig H. Azidoborolate anions and azidoborole adducts: isolable forms of an unstable borole azide. Chemical Communications (Cambridge, England). 58: 4735-4738. PMID 35322835 DOI: 10.1039/d2cc00543c  0.719
2021 Braunschweig H, Lu W, Jayaraman A, Fantuzzi F, Dewhurst RD, Härterich M, Dietz M, Hagspiel S, Krummenacher I, Hammond K, Cui J. An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small-Molecule Activation and Rearrangement Chemistry. Angewandte Chemie (International Ed. in English). PMID 34750945 DOI: 10.1002/anie.202113947  0.326
2021 Heß M, Krummenacher I, Dellermann T, Braunschweig H. Rhodium-Mediated Stoichiometric Synthesis of Mono-, Bi-, and Bis-1,2-Azaborinines: 1-Rhoda-3,2-azaboroles as Reactive Precursors. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34060149 DOI: 10.1002/chem.202100795  0.313
2021 Stoy A, Arrowsmith M, Eyßelein M, Dellermann T, Mies J, Radacki K, Kupfer T, Braunschweig H. NHC-Stabilized 1,2-Dihalodiborenes: Synthesis, Characterization, and Reactivity Toward Elemental Chalcogens. Inorganic Chemistry. PMID 34042444 DOI: 10.1021/acs.inorgchem.1c01169  0.321
2021 Brunecker C, Arrowsmith M, Fantuzzi F, Braunschweig H. Platinum-templated Coupling of B=N Units: Synthesis of BNBN Analogues of 1,3-Dienes and a Butatriene. Angewandte Chemie (International Ed. in English). PMID 34036694 DOI: 10.1002/anie.202106161  0.313
2021 Lindl F, Guo X, Krummenacher I, Rauch F, Rempel A, Paprocki V, Dellermann T, Stennett TE, Lamprecht A, Brückner T, Radacki K, Bélanger-Chabot G, Marder TB, Lin Z, Braunschweig H. Rethinking Borole Cycloaddition Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34008250 DOI: 10.1002/chem.202101290  0.715
2021 Saha K, Roy DK, Dewhurst RD, Ghosh S, Braunschweig H. Recent Advances in the Synthesis and Reactivity of Transition Metal σ-Borane/Borate Complexes. Accounts of Chemical Research. PMID 33565872 DOI: 10.1021/acs.accounts.0c00819  0.759
2020 Dewhurst RD, Légaré MA, Braunschweig H. Towards the catalytic activation of inert small molecules by main-group ambiphiles. Communications Chemistry. 3: 131. PMID 36703344 DOI: 10.1038/s42004-020-00371-4  0.681
2020 Heß M, Stennett TE, Fantuzzi F, Bertermann R, Schock M, Schäfer M, Thiess T, Braunschweig H. Diverse ring-opening reactions of rhodium η-azaborete complexes. Chemical Science. 11: 9134-9140. PMID 34123162 DOI: 10.1039/d0sc02283g  0.342
2020 Macha BB, Dhara D, Radacki K, Dewhurst RD, Braunschweig H. Intermetallic transfer of unsymmetrical borylene fragments: isolation of the second early-transition-metal terminal borylene complex and other rare species. Dalton Transactions (Cambridge, England : 2003). PMID 33237059 DOI: 10.1039/d0dt03557b  0.301
2020 Roy DK, Tröster T, Fantuzzi F, Dewhurst RD, Lenczyk C, Radacki K, Pranckevicius C, Engels B, Braunschweig H. Isolation and Reactivity of an s-Block Metal Antiaromatic. Angewandte Chemie (International Ed. in English). PMID 33210400 DOI: 10.1002/anie.202014557  0.659
2020 Rempel A, Mellerup S, Fantuzzi F, Herzog A, Deißenberger A, Bertermann R, Engels B, Braunschweig H. Functionalization of N2 via Formal 1,3-Haloboration of a Tungsten(0) σ-Dinitrogen Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32957161 DOI: 10.1002/Chem.202002678  0.35
2020 Légaré MA, Bélanger-Chabot G, Rang M, Dewhurst RD, Krummenacher I, Bertermann R, Braunschweig H. One-pot, room-temperature conversion of dinitrogen to ammonium chloride at a main-group element. Nature Chemistry. PMID 32929247 DOI: 10.1038/S41557-020-0520-6  0.793
2020 Drescher R, Lin S, Hofmann A, Lenczyk C, Kachel S, Krummenacher I, Lin Z, Braunschweig H. Ring expansion of alumoles with organic azides: selective formation of six-membered aluminum-nitrogen heterocycles. Chemical Science. 11: 5559-5564. PMID 32874499 DOI: 10.1039/D0Sc02032J  0.362
2020 Liu S, Légaré MA, Seufert J, Prieschl D, Rempel A, Englert L, Dellermann T, Paprocki V, Stoy A, Braunschweig H. Correction to 2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent. Inorganic Chemistry. PMID 32842732 DOI: 10.1021/Acs.Inorgchem.0C02324  0.685
2020 Narsaria AK, Rauch F, Krebs J, Endres P, Friedrich A, Krummenacher I, Braunschweig H, Finze M, Nitsch J, Bickelhaupt FM, Marder TB. Computationally Guided Molecular Design to Minimize the LE/CT Gap in D-π-A Fluorinated Triarylboranes for Efficient TADF via D and π-Bridge Tuning. Advanced Functional Materials. 30: 2002064. PMID 32774198 DOI: 10.1002/Adfm.202002064  0.322
2020 Nees S, Kupfer T, Hofmann A, Braunschweig H. Planar cyclopenten-4-yl cations - highly delocalized π aromatics stabilized by hyperconjugation. Angewandte Chemie (International Ed. in English). PMID 32701182 DOI: 10.1002/Anie.202009644  0.401
2020 Liu S, Légaré MA, Seufert J, Prieschl D, Rempel A, Englert L, Dellermann T, Paprocki V, Stoy A, Braunschweig H. 2,2'-Bipyridyl as a Redox-Active Borylene Abstraction Agent. Inorganic Chemistry. PMID 32672448 DOI: 10.1021/Acs.Inorgchem.0C01383  0.768
2020 Tian YM, Guo XN, Wu Z, Friedrich A, Westcott SA, Braunschweig H, Radius U, Marder TB. Ni-catalyzed traceless, directed C3-selective C-H borylation of indoles. Journal of the American Chemical Society. PMID 32594737 DOI: 10.1021/Jacs.0C05434  0.336
2020 Rauch F, Krebs J, Günther J, Friedrich A, Hähnel M, Krummenacher I, Braunschweig H, Finze M, Marder TB. Electronically-driven regioselective iridium-catalyzed C-H borylation of donor-π-acceptor chromophores containing triarylboron acceptors. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32510684 DOI: 10.1002/Chem.202002348  0.358
2020 Liu S, Légaré MA, Hofmann A, Dellermann T, Braunschweig H. Transition-metal-carbene-like intermolecular insertion of a borylene into C-H bonds. Chemical Communications (Cambridge, England). PMID 32478366 DOI: 10.1039/D0Cc03075A  0.742
2020 Hermann A, Fantuzzi F, Arrowsmith M, Zorn T, Krummenacher I, Ritschel B, Radacki K, Engels B, Braunschweig H. Oxidation, Coordination and Nickel-Mediated Deconstruction of a Highly Electron-Rich Diboron Analogue of 1,3,5-Hexatriene. Angewandte Chemie (International Ed. in English). PMID 32449598 DOI: 10.1002/Anie.202006131  0.432
2020 Rauch F, Endres P, Friedrich A, Sieh D, Hähnel M, Krummenacher I, Braunschweig H, Finze M, Ji L, Marder TB. An iterative divergent approach to conjugated starburst borane dendrimers. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32428359 DOI: 10.1002/Chem.202001985  0.327
2020 Merz J, Dietrich L, Nitsch J, Krummenacher I, Braunschweig H, Moos M, Mims D, Lambert C, Marder TB. Synthesis, Photophysical and Electronic Properties of Mono-, Di-, Tri-Amino-Substituted Ortho-Perylenes, and Comparison to the Tetra-Substituted Derivative. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32329914 DOI: 10.1002/Chem.202001475  0.328
2020 Braunschweig H, Paprocki V, Hrobárik P, Harriman KLM, Luff MS, Kupfer T, Kaupp M, Murugesu M. Stable actinide π complexes of neutral 1,4-diborabenzene. Angewandte Chemie (International Ed. in English). PMID 32329111 DOI: 10.1002/Anie.202004501  0.408
2020 Prieschl D, Arrowsmith M, Dietz M, Rempel A, Müller M, Braunschweig H. Synthesis of polyheterocyclic 1,1-diboryltriazenes by γ-nitrogen insertion of azides into activated B-B single bonds. Chemical Communications (Cambridge, England). PMID 32319468 DOI: 10.1039/D0Cc02305A  0.392
2020 Thiess T, Bélanger-Chabot G, Fantuzzi F, Michel M, Ernst M, Engels B, Braunschweig H. Diborane(4) Azides: High-Energy Molecules as Surprisingly Stable Sources of Transient Iminoboranes. Angewandte Chemie (International Ed. in English). PMID 32270577 DOI: 10.1002/Anie.202003050  0.713
2020 Ewing WC, Dellermann T, Wong YTA, Mattock J, Vargas A, Bryce D, Dewhurst RD, Braunschweig H. π-Complexes of Diborynes with Main Group Atoms. Chemistry, An Asian Journal. PMID 32207211 DOI: 10.1002/Asia.202000185  0.447
2020 Hagspiel S, Arrowsmith M, Fantuzzi F, Hermann A, Paprocki V, Drescher R, Krummenacher I, Braunschweig H. Reduction of a dihydroboryl cation to a boryl anion and its air-stable, neutral hydroboryl radical through hydrogen shuttling. Chemical Science. 11: 551-555. PMID 32206272 DOI: 10.1039/C9Sc05026D  0.35
2020 Brunecker C, Müssig JH, Arrowsmith M, Fantuzzi F, Stoy A, Böhnke J, Hofmann A, Bertermann R, Engels B, Braunschweig H. Boranediyl- and Diborane(4)-1,2-diyl-bridged Platinum A-Frame Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32196775 DOI: 10.1002/Chem.202001168  0.43
2020 Hermann A, Arrowsmith M, Trujillo-Gonzalez DE, Jiménez-Halla JOC, Vargas A, Braunschweig H. Trapping of a Borirane Intermediate in the Reductive Coupling of an Arylborane to a Diborene. Journal of the American Chemical Society. 142: 5562-5567. PMID 32151134 DOI: 10.1021/Jacs.0C02306  0.387
2020 Rauch F, Fuchs S, Friedrich A, Sieh D, Krummenacher I, Braunschweig H, Finze M, Marder TB. Highly stable, readily reducible, fluorescent, trifluoromethylated 9-borafluorenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31999019 DOI: 10.1002/Chem.201905559  0.317
2020 Braunschweig H, Thiess T, Kupfer T, Ernst M. Facile access to substituted 1,4-diaza-2,3-diborinines. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31944442 DOI: 10.1002/Chem.201905356  0.411
2020 Pranckevicius C, Weber M, Krummenacher I, Phukan AK, Braunschweig H. Phosphinoborylenes as stable sources of fleeting borylenes Chemical Science. DOI: 10.1039/D0Sc04826G  0.336
2020 Heß M, Stennett TE, Fantuzzi F, Bertermann R, Schock M, Schäfer M, Thiess T, Braunschweig H. Diverse ring-opening reactions of rhodium η4-azaborete complexes Chemical Science. 11: 9134-9140. DOI: 10.1039/D0Sc02283G  0.44
2020 Stennett TE, Jayaraman A, Brückner T, Schneider L, Braunschweig H. Hydrophosphination of boron–boron multiple bonds Chemical Science. 11: 1335-1341. DOI: 10.1039/C9Sc05908C  0.355
2020 Horrer G, Krahfuß MJ, Lubitz K, Krummenacher I, Braunschweig H, Radius U. N -Heterocyclic Carbene and Cyclic (Alkyl)(amino)carbene Complexes of Titanium(IV) and Titanium(III) European Journal of Inorganic Chemistry. 2020: 281-291. DOI: 10.1002/Ejic.201901207  0.366
2019 Schumann A, Reiß F, Jiao H, Rabeah J, Siewert JE, Krummenacher I, Braunschweig H, Hering-Junghans C. A selective route to aryl-triphosphiranes and their titanocene-induced fragmentation. Chemical Science. 10: 7859-7867. PMID 31853345 DOI: 10.1039/C9Sc02322D  0.361
2019 Muessig J, Lisinetskaya P, Dewhurst R, Bertermann R, Thaler M, Mitrić R, Braunschweig H. Tetraiododiborane(4) (B2I4) is a Polymer based on sp3 Boron in the Solid State. Angewandte Chemie (International Ed. in English). PMID 31840333 DOI: 10.1002/Anie.201913590  0.31
2019 Prieschl D, Bélanger-Chabot G, Guo X, Dietz M, Müller M, Krummenacher I, Lin Z, Braunschweig H. Synthesis of Complex Boron-Nitrogen Heterocycles Comprising Borylated Triazenes and Tetrazenes Under Mild Conditions. Journal of the American Chemical Society. PMID 31830413 DOI: 10.1021/Jacs.9B12336  0.756
2019 Goettel JT, Gao H, Dotzauer S, Braunschweig H. MeCAAC=N-: A Cyclic (Alkyl)(Amino)Carbene Imino Ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31777982 DOI: 10.1002/Chem.201904715  0.429
2019 Ribbeck T, Kerpen C, Schmidle C, Keppner F, Sprenger JAP, Arrowsmith M, Braunschweig H, Igant'ev NV, Finze M. Hydroxytricyanoborate Anion: Synthetic Aspects and Structural, Chemical, and Spectroscopic Properties. Inorganic Chemistry. PMID 31765132 DOI: 10.1021/Acs.Inorgchem.9B02802  0.385
2019 Lenczyk C, Roy DK, Oberdorf K, Nitsch J, Dewhurst RD, Radacki K, Halet JF, Marder TB, Bickelhaupt FM, Braunschweig H. Ruthenium-Templated Construction of an Arylated B4 Chain by Dihydroborane Dehydrocoupling. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31663648 DOI: 10.1002/Chem.201904772  0.708
2019 Schmidt U, Werner L, Arrowsmith M, Deissenberger A, Hermann A, Hofmann A, Ullrich S, Mattock J, Vargas A, Braunschweig H. Trans-selective Insertional Dihydroboration of a cis-Diborene: Synthesis of Linear sp3-sp2-sp3-Triboranes and Subsequent Cationization. Angewandte Chemie (International Ed. in English). PMID 31621993 DOI: 10.1002/Anie.201911645  0.373
2019 Merz J, Dietz M, Vonhausen Y, Wöber F, Friedrich A, Sieh D, Krummenacher I, Braunschweig H, Moos M, Holzapfel M, Lambert C, Marder TB. Synthesis, Photophysical and Electronic Properties of New Red to NIR Emitting Donor-Acceptor Pyrene Derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31593316 DOI: 10.1002/Chem.201904219  0.315
2019 Merz J, Steffen A, Nitsch J, Fink J, Schürger CB, Friedrich A, Krummenacher I, Braunschweig H, Moos M, Mims D, Lambert C, Marder TB. Synthesis, photophysical and electronic properties of tetra-donor- or acceptor-substituted -perylenes displaying four reversible oxidations or reductions. Chemical Science. 10: 7516-7534. PMID 31588303 DOI: 10.1039/C9Sc02420D  0.344
2019 Mellerup SK, Cui Y, Fantuzzi F, Schmid P, Goettel JT, Bélanger-Chabot G, Arrowsmith M, Krummenacher I, Ye Q, Engel V, Engels B, Braunschweig H. Lewis-Base Stabilization of the Parent Al(I) Hydride under Ambient Conditions. Journal of the American Chemical Society. PMID 31577138 DOI: 10.1021/Jacs.9B09128  0.74
2019 Brückner T, Dewhurst RD, Dellermann T, Müller M, Braunschweig H. Mild synthesis of diboryldiborenes by diboration of B-B triple bonds. Chemical Science. 10: 7375-7378. PMID 31489159 DOI: 10.1039/C9Sc02544H  0.341
2019 He J, Rauch F, Friedrich A, Sieh D, Ribbeck T, Krummenacher I, Braunschweig H, Finze M, Marder TB. N-Heterocyclic Olefins as Electron Donors in Combination with Triarylborane Acceptors: Synthesis, Optical and Electronic Properties of D-π-A Compounds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31471986 DOI: 10.1002/Chem.201903118  0.356
2019 Brückner T, Stennett TE, Heß M, Braunschweig H. Single and Double Hydroboration of B-B Triple Bonds and Convergent Routes to a Cationic Tetraborane. Journal of the American Chemical Society. PMID 31454483 DOI: 10.1021/Jacs.9B07991  0.402
2019 Lenczyk C, Roy DK, Nitsch J, Radacki K, Rauch F, Dewhurst RD, Bickelhaupt FM, Marder TB, Braunschweig H. Steric Effects Dictate the Formation of Terminal Arylborylene Complexes of Ruthenium from Dihydroboranes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31433081 DOI: 10.1002/Chem.201902890  0.714
2019 Thiess T, Mellerup SK, Braunschweig H. B-B Cleavage and Ring-Expansion of a 1,4,2,3-Diazadiborinine with N-Heterocyclic Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31429506 DOI: 10.1002/Chem.201903259  0.401
2019 Bélanger-Chabot G, Braunschweig H. Hexahalodiborate Dianions: A New Family of Binary Boron Halides. Angewandte Chemie (International Ed. in English). PMID 31361383 DOI: 10.1002/Anie.201906666  0.696
2019 Prieschl D, Dietz M, Muessig JH, Wagner K, Krummenacher I, Braunschweig H. Pseudodiborenes: hydride-bridged diboranes(5) as two-electron reductants of chalcogens. Chemical Communications (Cambridge, England). PMID 31355376 DOI: 10.1039/C9Cc04692E  0.392
2019 Martínez-Martínez AJ, Kennedy AR, Paprocki V, Fantuzzi F, Dewhurst RD, O'Hara CT, Braunschweig H, Mulvey RE. Selective mono- and dimetallation of a group 3 sandwich complex. Chemical Communications (Cambridge, England). PMID 31347619 DOI: 10.1039/C9Cc03825F  0.376
2019 Pranckevicius C, Herok C, Fantuzzi F, Engels B, Braunschweig H. Bond-Strengthening Backdonation in Aminoborylene-Stabilized-Aminoborylenes: at the Intersection of Borylenes and Diborenes. Angewandte Chemie (International Ed. in English). PMID 31241232 DOI: 10.1002/Anie.201906671  0.449
2019 Arrowsmith M, Schweizer JI, Heinz M, Härterich M, Krummenacher I, Holthausen MC, Braunschweig H. Synthesis and reduction chemistry of mixed-Lewis-base-stabilised chloroborylenes. Chemical Science. 10: 5095-5103. PMID 31183061 DOI: 10.1039/C9Sc01039D  0.388
2019 Ji L, Hahn S, Biegger P, Reiss H, Han J, Friedrich A, Krummenacher I, Braunschweig H, Moos M, Freudenberg J, Lambert C, Dreuw A, Marder T, Bunz UH. Mono- and Dianion of a Bis(benzobuta)tetraazapentacene Derivative. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31155772 DOI: 10.1002/Chem.201901982  0.321
2019 Liu S, Légaré MA, Hofmann A, Rempel A, Hagspiel S, Braunschweig H. Synthesis of unsymmetrical BE and BE heterocycles by borylene insertion into boradichalcogeniranes. Chemical Science. 10: 4662-4666. PMID 31123576 DOI: 10.1039/C9Sc00657E  0.714
2019 Brückner T, Arrowsmith M, Heß M, Hammond K, Müller M, Braunschweig H. Synthesis of fused B,N-heterocycles by alkyne cleavage, NHC ring-expansion and C-H activation at a diboryne. Chemical Communications (Cambridge, England). PMID 31106314 DOI: 10.1039/C9Cc02657F  0.39
2019 Lenczyk C, Roy DK, Ghosh B, Schwarzmann J, Phukan AK, Braunschweig H. First Bis(σ)-borane Complexes of Group 6 Transition Metals: Experimental and Theoretical Studies. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31066951 DOI: 10.1002/Chem.201901075  0.72
2019 Dömling M, Arrowsmith M, Schmidt U, Werner L, Castro A, Jimenez-Halla JOC, Müssig J, Prieschl D, Braunschweig H. Spontaneous trans-Selective Transfer Hydrogenation of Apolar B=B Double Bonds. Angewandte Chemie (International Ed. in English). PMID 31062910 DOI: 10.1002/Anie.201902656  0.347
2019 Hofmann A, Tröster T, Kupfer T, Braunschweig H. Monomeric CpAl(i): synthesis, reactivity, and the concept of valence isomerism. Chemical Science. 10: 3421-3428. PMID 30996931 DOI: 10.1039/C8Sc05175E  0.37
2019 Hofmann A, Légaré MA, Wüst L, Braunschweig H. Heterodiatomic Multiple Bonding in Group 13: A Complex with a B-Al π Bond Reduces CO2. Angewandte Chemie (International Ed. in English). PMID 30985966 DOI: 10.1002/Anie.201902655  0.756
2019 Englert L, Stoy A, Arrowsmith M, Muessig J, Thaler M, Deißenberger A, Häfner A, Böhnke J, Hupp F, Seufert J, Mies J, Damme A, Dellermann T, Hammond K, Kupfer T, ... ... Braunschweig H, et al. Stable Lewis Base Adducts of Tetrahalodiboranes: Synthetic Methods and Structural Diversity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30974025 DOI: 10.1002/Chem.201901437  0.431
2019 Légaré MA, Rang M, Bélanger-Chabot G, Schweizer JI, Krummenacher I, Bertermann R, Arrowsmith M, Holthausen MC, Braunschweig H. The reductive coupling of dinitrogen. Science (New York, N.Y.). 363: 1329-1332. PMID 30898929 DOI: 10.1126/Science.Aav9593  0.793
2019 Ketkov SY, Tzeng SY, Rychagova EA, Kalakutskaya LV, Fuss M, Braunschweig H, Tzeng WB. Rydberg state mediated multiphoton ionization of (η-CH)(η-CH)Cr: DFT-supported experimental insights into the molecular and electronic structures of excited sandwich complexes. Physical Chemistry Chemical Physics : Pccp. PMID 30895988 DOI: 10.1039/C9Cp00888H  0.316
2019 Meier M, Ji L, Nitsch J, Krummenacher I, Deißenberger A, Auerhammer D, Schäfer M, Marder TB, Braunschweig H. Preparation and Characterization of a π-Conjugated Donor-Acceptor System Containing the Strongly Electron-Accepting Tetraphenylborolyl Unit. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30786077 DOI: 10.1002/Chem.201805454  0.346
2019 Stennett T, Bissinger P, Griesbeck S, Ullrich S, Krummenacher I, Auth M, Sperlich A, Stolte M, Radacki K, Yao CJ, Würthner F, Steffen A, Marder T, Braunschweig H. Near-infrared quadrupolar chromophores combining three-coordinate boron-based superdonor and -acceptor units. Angewandte Chemie (International Ed. in English). PMID 30779454 DOI: 10.1002/Anie.201900889  0.345
2019 Muessig JH, Stennett TE, Schmidt U, Dewhurst RD, Mailänder L, Braunschweig H. Oxidative addition of arsenic halides to platinum(0). Dalton Transactions (Cambridge, England : 2003). PMID 30758372 DOI: 10.1039/C8Dt04995E  0.364
2019 Muessig JH, Thaler M, Dewhurst RD, Paprocki V, Seufert J, Mattock JD, Vargas A, Braunschweig H. Phosphine-Stabilized Diiododiborenes: Isolable Diborenes with Six Labile Bonds. Angewandte Chemie (International Ed. in English). PMID 30719809 DOI: 10.1002/Anie.201814230  0.337
2019 Schuster JK, Roy DK, Lenczyk C, Mies J, Braunschweig H. New Outcomes of Beryllium Chemistry: Lewis Base Adducts for Salt Elimination Reactions. Inorganic Chemistry. PMID 30707568 DOI: 10.1021/Acs.Inorgchem.8B03263  0.726
2019 Hofmann A, Pranckevicius C, Tröster T, Braunschweig H. Aluminum(I)/Boron(III) Redox Reactions. Angewandte Chemie (International Ed. in English). PMID 30644156 DOI: 10.1002/Anie.201813619  0.418
2019 Légaré MA, Pranckevicius C, Braunschweig H. Metallomimetic Chemistry of Boron. Chemical Reviews. PMID 30640447 DOI: 10.1021/Acs.Chemrev.8B00561  0.747
2019 Deissenberger A, Welz E, Drescher R, Krummenacher I, Dewhurst RD, Engels B, Braunschweig H. A New Class of Neutral Boron-Based Diradicals Spanned by a Two-Carbon-Atom Bridge. Angewandte Chemie (International Ed. in English). 58: 1842-1846. PMID 30549204 DOI: 10.1002/Anie.201813335  0.325
2019 Braunschweig H, Müller J, Ganter B. Molecular Structure of [CpFe(CO)(2)](2)AlAr (Ar = 2-[(Dimethylamino)methyl]phenyl): An Alanediyl Complex with Two Fe-Al Bonds. Inorganic Chemistry. 35: 7443-7444. PMID 11666941 DOI: 10.1021/Ic960471F  0.597
2019 Braunschweig H, Colling M, Kollann C, Stammler HG, Neumann B. Terminal Borylene Complexes as a Source for the Borylene B-N(SiMe(3))(2): Alternative Synthesis and Structure of Angewandte Chemie (International Ed. in English). 40: 2298-2300. PMID 11433500 DOI: 10.1002/1521-3773(20010618)40:12<2298::Aid-Anie2298>3.0.Co;2-E  0.354
2019 Goettel JT, Braunschweig H. Recent advances in boron-centered ligands and their transition metal complexes Coordination Chemistry Reviews. 380: 184-200. DOI: 10.1016/J.Ccr.2018.09.013  0.398
2018 Tian Y, Guo X, Kuntze-Fechner M, Krummenacher I, Braunschweig H, Radius U, Steffen A, Marder TB. Selective Photocatalytic C-F Borylation of Polyfluoroarenes by Rh/Ni Dual Catalysis Providing Valuable Fluorinated Arylboronate Esters. Journal of the American Chemical Society. PMID 30474979 DOI: 10.1021/Jacs.8B09790  0.378
2018 Lindl F, Lin S, Krummenacher I, Lenczyk C, Stoy A, Müller M, Lin Z, Braunschweig H. 1,2,3-Diazaborinine: A BN Analog of Pyridine by Ring Expansion of a Borole with an Organic Azide. Angewandte Chemie (International Ed. in English). PMID 30394650 DOI: 10.1002/Anie.201811601  0.371
2018 Zhao Q, Dewhurst RD, Braunschweig H, Chen X. A New Perspective on Borane Chemistry: the Nucleophilicity of the B-H Bonding Pair Electrons. Angewandte Chemie (International Ed. in English). PMID 30353633 DOI: 10.1002/Anie.201809733  0.38
2018 Stennett TE, Bertermann R, Braunschweig H. Construction of Linear and Branched Tetraboranes via 1,1- and 1,2-Diboration of Diborenes. Angewandte Chemie (International Ed. in English). PMID 30276985 DOI: 10.1002/Anie.201809976  0.352
2018 Arrowsmith M, Mattock J, Hagspiel S, Krummenacher I, Vargas A, Braunschweig H. Facile Synthesis of a Stable Dihydroboryl {BH2}. Angewandte Chemie (International Ed. in English). PMID 30238575 DOI: 10.1002/Anie.201809983  0.31
2018 Muessig JH, Prieschl D, Deißenberger A, Dewhurst RD, Dietz M, Jiménez-Halla JOC, Trumpp A, Wang SR, Brunecker C, Haefner A, Gärtner A, Thiess T, Böhnke J, Radacki K, Bertermann R, ... ... Braunschweig H, et al. Reactivity of Tetrahalo- and Difluorodiboranes(4) Towards Lewis-Basic Platinum(0): Bis(boryl), Borylborato and Doubly Boryl-Bridged Platinum Complexes. Journal of the American Chemical Society. PMID 30222320 DOI: 10.1021/Jacs.8B08428  0.39
2018 Stennett T, Mattock J, Pentecost L, Vargas A, Braunschweig H. Chelated Diborenes and their Inverse-Electron-Demand Diels-Alder Reactions with Dienes. Angewandte Chemie (International Ed. in English). PMID 30204298 DOI: 10.1002/Anie.201809217  0.388
2018 Welz E, Böhnke J, Dewhurst RD, Braunschweig H, Engels B. Unravelling the Dramatic Electro-Structural Differences Between NHC- and CAAC-Stabilized Low-Valent Main Group Species. Journal of the American Chemical Society. PMID 30180566 DOI: 10.1021/Jacs.8B07644  0.345
2018 Liu S, Légaré MA, Hofmann A, Braunschweig H. A Boradiselenirane and a Boraditellurirane: Isolable Heavy Analogs of Dioxiranes and Dithiiranes. Journal of the American Chemical Society. PMID 30130957 DOI: 10.1021/Jacs.8B07829  0.722
2018 Kelch H, Kachel S, Wahler J, Celik MA, Stoy A, Krummenacher I, Kramer T, Radacki K, Braunschweig H. Borabicyclo[3.2.0]heptadiene: A Fused Bicyclic Isomer of Borepin. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30095190 DOI: 10.1002/Chem.201803509  0.405
2018 Winner L, Ewing WC, Geetharani K, Dellermann T, Jouppi B, Kupfer T, Schäfer M, Braunschweig H. Spontaneous Metal-Free Transfer Hydrogenation of Iminoboranes with Ammonia Borane and Amine Boranes. Angewandte Chemie (International Ed. in English). PMID 30075060 DOI: 10.1002/Anie.201807435  0.351
2018 Winner L, Bélanger-Chabot G, Celik MA, Schäfer M, Braunschweig H. Intriguing migrations in transient iminoborane adducts: two new pathways to aminoboranes. Chemical Communications (Cambridge, England). 54: 9349-9351. PMID 30074595 DOI: 10.1039/C8Cc05220D  0.744
2018 Pranckevicius C, Jimenéz-Halla JOC, Kirsch M, Krummenacher I, Braunschweig H. Complexation and Release of N-Heterocyclic Carbene-Aminoborylene Ligands from Group VI and VIII Metals. Journal of the American Chemical Society. PMID 30048122 DOI: 10.1021/Jacs.8B05398  0.439
2018 Roy DK, Krummenacher I, Stennett TE, Lenczyk C, Thiess T, Welz E, Engels B, Braunschweig H. Selective one- and two-electron reductions of a haloborane enabled by a π-withdrawing carbene ligand. Chemical Communications (Cambridge, England). PMID 30046799 DOI: 10.1039/C8Cc03433H  0.693
2018 Böhnke J, Arrowsmith M, Braunschweig H. Reactivity Enhancement of a Zerovalent Diboron Compound by Desymmetrization. Journal of the American Chemical Society. PMID 30040887 DOI: 10.1021/Jacs.8B06930  0.367
2018 Böhnke J, Brückner T, Hermann A, González-Belman OF, Arrowsmith M, Jiménez-Halla JOC, Braunschweig H. Single and double activation of acetone by isolobal B[triple bond, length as m-dash]N and B[triple bond, length as m-dash]B triple bonds. Chemical Science. 9: 5354-5359. PMID 30009006 DOI: 10.1039/C8Sc01249K  0.366
2018 Winner L, Hermann A, Bélanger-Chabot G, González-Belman OF, Jiménez-Halla JOC, Kelch H, Braunschweig H. Cleavage of BN triple bonds by main group reagents. Chemical Communications (Cambridge, England). PMID 29978863 DOI: 10.1039/C8Cc02317D  0.724
2018 Hofmann A, Lamprecht A, Jimenez-Halla JOC, Tröster T, Dewhurst RD, Lenczyk C, Braunschweig H. Lewis-Base-Induced Disproportionation of a Dialane. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29920807 DOI: 10.1002/Chem.201802300  0.353
2018 Hermann A, Cid J, Mattock J, Dewhurst R, Krummenacher I, Vargas A, Ingleson MJ, Braunschweig H. Diboryldiborenes: pi-Conjugated B4 Chains Isoelectronic to the Butadiene Dication. Angewandte Chemie (International Ed. in English). PMID 29897648 DOI: 10.1002/Anie.201805394  0.348
2018 Seufert J, Welz E, Krummenacher I, Paprocki V, Böhnke J, Hagspiel S, Dewhurst RD, Tacke R, Engels B, Braunschweig H. Isolation and Characterization of Crystalline, Neutral Diborane(4) Radicals. Angewandte Chemie (International Ed. in English). PMID 29785795 DOI: 10.1002/Anie.201804048  0.345
2018 Auerhammer D, Arrowsmith M, Dewhurst RD, Kupfer T, Böhnke J, Braunschweig H. Closely related yet different: a borylene and its dimer are non-interconvertible but connected through reactivity. Chemical Science. 9: 2252-2260. PMID 29719698 DOI: 10.1039/C7Sc04789D  0.367
2018 Wang Z, Zhou Y, Zhang JX, Krummenacher I, Braunschweig H, Lin Z. DFT Studies on the reactions of boroles with alkynes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29687511 DOI: 10.1002/Chem.201801094  0.357
2018 Arrowsmith M, Mattock JD, Böhnke J, Krummenacher I, Vargas A, Braunschweig H. Direct access to a cAAC-supported dihydrodiborene and its dianion. Chemical Communications (Cambridge, England). PMID 29682660 DOI: 10.1039/C8Cc01580E  0.376
2018 Schuster J, Muessig J, Dewhurst RD, Braunschweig H. Reactions of Digallanes with p- and d-Block Lewis Bases: Adducts, Bis(gallyl) Complexes and Naked Ga+ as Ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29667760 DOI: 10.1002/Chem.201801471  0.381
2018 Böhnke J, Dellermann T, Celik MA, Krummenacher I, Dewhurst RD, Demeshko S, Ewing WC, Hammond K, Heß M, Bill E, Welz E, Röhr MIS, Mitrić R, Engels B, Meyer F, ... Braunschweig H, et al. Isolation of diborenes and their 90°-twisted diradical congeners. Nature Communications. 9: 1197. PMID 29567960 DOI: 10.1038/S41467-018-02998-3  0.534
2018 Wang S, Prieschl D, Mattock J, Arrowsmith M, Pranckevicius C, Stennett T, Dewhurst R, Vargas A, Braunschweig H. Bottleable Neutral Analogues of [B2H5]- as Versatile and Strongly Binding eta2 Donor Ligands. Angewandte Chemie (International Ed. in English). PMID 29537119 DOI: 10.1002/Anie.201801722  0.406
2018 Nutz M, Borthakur B, Pranckevicius C, Dewhurst R, Schäfer M, Dellermann T, Glaab F, Thaler M, Phukan A, Braunschweig H. Release of Isonitrile- and NHC-stabilized Borylenes from Group VI Terminal Borylene Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29498441 DOI: 10.1002/Chem.201800593  0.377
2018 Stoy A, Böhnke J, Jiménez-Halla JOC, Dewhurst RD, Thiess T, Braunschweig H. CO2 Binding and Splitting by Boron-Boron Multiple Bonds. Angewandte Chemie (International Ed. in English). PMID 29493885 DOI: 10.1002/Anie.201802117  0.326
2018 Ji L, Krummenacher I, Friedrich A, Lorbach A, Haehnel M, Edkins K, Braunschweig H, Marder TB. Synthesis, Photophysical, and Electrochemical Properties of Pyrenes Substituted with Donors or Acceptors at the 4- or 4,9-Positions. The Journal of Organic Chemistry. PMID 29480011 DOI: 10.1021/Acs.Joc.7B03227  0.345
2018 Légaré MA, Bélanger-Chabot G, Dewhurst RD, Welz E, Krummenacher I, Engels B, Braunschweig H. Nitrogen fixation and reduction at boron. Science (New York, N.Y.). 359: 896-900. PMID 29472479 DOI: 10.1126/Science.Aaq1684  0.788
2018 Stennett T, Mattock J, Vollert I, Vargas A, Braunschweig H. Unsymmetrical, Cyclic Diborenes and Thermal Rearrangement to a Borylborylene. Angewandte Chemie (International Ed. in English). PMID 29451345 DOI: 10.1002/Anie.201800671  0.356
2018 Hofmann A, Lamprecht A, González-Belman OF, Dewhurst RD, Jiménez-Halla JOC, Kachel S, Braunschweig H. Dialumination of unsaturated species with a reactive bis(cyclopentadienyl) dialane. Chemical Communications (Cambridge, England). PMID 29376161 DOI: 10.1039/C7Cc09596A  0.378
2018 Braunschweig H, Damme A, Dück K, Krummenacher I, Paprocki V, Radacki K, Ramler J, Schiller C, Schneider C. Boryl- and Silyl-Substituted Mixed Sandwich Compounds of Scandium. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29363206 DOI: 10.1002/Chem.201704908  0.421
2018 Böhnke J, Braunschweig H, Jiménez-Halla JOC, Krummenacher I, Stennett TE. Half-Sandwich Complexes of an Extremely Electron-Donating, Redox-Active η6-Diborabenzene Ligand. Journal of the American Chemical Society. PMID 29244502 DOI: 10.1021/Jacs.7B12394  0.413
2018 Braunschweig H, Brunecker C, Dewhurst RD, Schneider C. Does Lewis basicity correlate with catalytic performance in zerovalent group 8 complexes? Zeitschrift FüR Naturforschung B. 73: 149-153. DOI: 10.1515/Znb-2017-0193  0.392
2018 Cid J, Hermann A, Radcliffe JE, Curless LD, Braunschweig H, Ingleson MJ. Synthesis of Unsymmetrical Diboron(5) Compounds and Their Conversion to Diboron(5) Cations Organometallics. 37: 1992-1998. DOI: 10.1021/Acs.Organomet.8B00288  0.404
2018 Meyer K, Braunschweig H. Organometallic Chemistry in Europe Organometallics. 37: 625-627. DOI: 10.1021/Acs.Organomet.8B00012  0.32
2017 Auerhammer D, Arrowsmith M, Braunschweig H, Dewhurst RD, Jiménez-Halla JOC, Kupfer T. Nucleophilic addition and substitution at coordinatively saturated boron by facile 1,2-hydrogen shuttling onto a carbene donor. Chemical Science. 8: 7066-7071. PMID 29147534 DOI: 10.1039/C7Sc03193A  0.38
2017 Braunschweig H, Dewhurst RD, Jimenez-Halla JOC, Matito E, Muessig J. Transition Metal pi-Ligation of a Tetrahalodiborane. Angewandte Chemie (International Ed. in English). PMID 29134749 DOI: 10.1002/Anie.201709515  0.406
2017 Böhnke J, Braunschweig H, Deißenberger A, Dellermann T, Dewhurst RD, Jiménez-Halla JOC, Kachel S, Kelch H, Prieschl D. Alkylideneborate zwitterions and C-C coupling by atypical diboration of electron-rich alkynes. Chemical Communications (Cambridge, England). PMID 29075685 DOI: 10.1039/C7Cc07409C  0.346
2017 Auerhammer D, Arrowsmith M, Bissinger P, Braunschweig H, Dellermann T, Kupfer T, Lenczyk C, Roy D, Schäfer M, Schneider C. Increasing the Reactivity of Diborenes: Derivatization of NHC-Supported Dithienyldiborenes with Electron-Donor Groups. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29068503 DOI: 10.1002/Chem.201704669  0.692
2017 Rixin Wang S, Arrowsmith M, Braunschweig H, Dewhurst RD, Paprocki V, Winner L. CuOTf-mediated intramolecular diborene hydroarylation. Chemical Communications (Cambridge, England). PMID 29051948 DOI: 10.1039/C7Cc07371B  0.403
2017 Liu S, Légaré MA, Auerhammer D, Hoffmann A, Braunschweig H. The First Boron-Tellurium Double Bond: Direct Insertion of Heavy Chalcogens into a Mn=B Double Bond. Angewandte Chemie (International Ed. in English). PMID 29048719 DOI: 10.1002/Anie.201708729  0.748
2017 Ji L, Friedrich A, Krummenacher I, Eichhorn A, Braunschweig H, Moos M, Hahn S, Geyer F, Tverskoy O, Han J, Lambert C, Dreuw A, Marder TB, Bunz UHF. Preparation, Properties and Structures of the Anions and Di-anions of Azapentacenes. Journal of the American Chemical Society. PMID 28988473 DOI: 10.1021/Jacs.7B09460  0.345
2017 Braunschweig H, Dömling M, Kachel S, Kelch H, Kramer T, Krummenacher I, Lenczyk C, Lin S, Lin Z, Possiel C, Radacki K. Abnormal Tin-Boron Exchange in the Attempted Synthesis of a Borylated Borole. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28960516 DOI: 10.1002/Chem.201703810  0.364
2017 Arrowsmith M, Böhnke J, Braunschweig H, Celik M. Reactivity of a Dihydrodiborene with CO: Coordination, Insertion, Cleavage and Spontaneous Cyclic Alkyne Formation. Angewandte Chemie (International Ed. in English). PMID 28892234 DOI: 10.1002/Anie.201707907  0.38
2017 Wang SR, Arrowsmith M, Braunschweig H, Dewhurst RD, Dömling M, Mattock JD, Pranckevicius C, Vargas A. Monomeric 16-Electron π-Diborene Complexes of Zn(II) and Cd(II). Journal of the American Chemical Society. PMID 28745882 DOI: 10.1021/Jacs.7B06644  0.394
2017 Arrowsmith M, Auerhammer D, Bertermann R, Braunschweig H, Celik MA, Erdmannsdörfer J, Kupfer T, Krummenacher I. From Borane to Borylene without Reduction: Ambiphilic Behavior of a Monovalent Silylisonitrile Boron Species. Angewandte Chemie (International Ed. in English). PMID 28640395 DOI: 10.1002/Anie.201705561  0.301
2017 Lehmann A, Lechner L, Radacki K, Braunschweig H, Holzgrabe U. Crystal structure of (3S*,4R*)-4-fluoro-3-(4-meth-oxy-phen-yl)-1-oxo-2-phenyl-1,2,3,4-tetra-hydro-iso-quinoline-4-carb-oxy-lic acid. Acta Crystallographica. Section E, Crystallographic Communications. 73: 867-870. PMID 28638647 DOI: 10.1107/S2056989017007186  0.313
2017 Wang Z, Zhou Y, Lam WH, Dewhurst RD, Braunschweig H, Marder TB, Lin Z. DFT Studies of Dimerization Reactions of Boroles. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28627022 DOI: 10.1002/Chem.201701737  0.359
2017 Braunschweig H, Brückner T, Deißenberger A, Dewhurst R, Gackstatter A, Gärtner A, Hofmann A, Kupfer T, Prieschl D, Thiess T, Wang S. Reaction of Dihalodiboranes(4) with N-Heterocyclic Silylenes: Facile Construction of 1-Aryl-2-Silyl-1,2-Diboraindanes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28608587 DOI: 10.1002/Chem.201702377  0.38
2017 Borthakur B, Braunschweig H, Deißenberger A, Dellermann T, Dewhurst R, Krummenacher I, Nutz M, Phukan A, Schäfer M. Synthesis and Trapping of Iminoboranes via M=B / C=N Bond Metathesis. Angewandte Chemie (International Ed. in English). PMID 28508513 DOI: 10.1002/Anie.201703324  0.42
2017 Wang S, Arrowsmith M, Böhnke J, Braunschweig H, Dellermann T, Dewhurst R, Kelch H, Krummenacher I, Mattock J, Müssig J, Thiess T, Vargas A, Zhang J. Engineering a Small HOMO-LUMO Gap and Intramolecular C-H Borylation by Diborene/Anthracene Orbital Intercalation. Angewandte Chemie (International Ed. in English). PMID 28493620 DOI: 10.1002/Anie.201704063  0.374
2017 Braunschweig H, Celik M, Dellermann T, Frenking G, Hammond K, Hupp F, Kelch H, Krummenacher I, Lindl F, Mailänder L, Müssig J, Ruppert A. Scope of the Thermal Ring Expansion Reaction of Boroles with Organoazides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28430374 DOI: 10.1002/Chem.201700749  0.373
2017 Arrowsmith M, Böhnke J, Braunschweig H, Gao H, Légaré MA, Paprocki V, Seufert J. Synthesis and Reduction of Sterically Encumbered Mesoionic Carbene-Stabilized Aryldihaloboranes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28326622 DOI: 10.1002/Chem.201700500  0.749
2017 Braunschweig H, Dellermann T, Dewhurst RD, Hupp B, Kramer T, Mattock JD, Mies J, Phukan AK, Steffen A, Vargas A. Strongly Phosphorescent Transition Metal π Complexes of Boron-Boron Triple Bonds. Journal of the American Chemical Society. PMID 28221795 DOI: 10.1021/Jacs.7B00766  0.417
2017 Braunschweig H, Krummenacher I, Légaré MA, Matler A, Radacki K, Ye Q. Main-Group Metallomimetics - Transition Metal-like Photolytic CO Substitution at Boron. Journal of the American Chemical Society. PMID 28103028 DOI: 10.1021/Jacs.6B13047  0.793
2017 Bélanger-Chabot G, Braunschweig H, Roy DK. Cover Feature: Recent Developments in Azaborinine Chemistry (Eur. J. Inorg. Chem. 38-39/2017) European Journal of Inorganic Chemistry. 2017: 4347-4347. DOI: 10.1002/Ejic.201701120  0.758
2017 Bélanger-Chabot G, Braunschweig H, Roy DK. Recent Developments in Azaborinine Chemistry European Journal of Inorganic Chemistry. 2017: 4353-4368. DOI: 10.1002/Ejic.201700562  0.779
2017 Arrowsmith M, Auerhammer D, Bertermann R, Braunschweig H, Celik MA, Erdmannsdörfer J, Krummenacher I, Kupfer T. Vom Boran zum Borylen ohne Reduktion: ambiphiles Verhalten einer monovalenten Silylisonitril-Borverbindung Angewandte Chemie. 129: 11417-11421. DOI: 10.1002/Ange.201705561  0.304
2017 Wang SR, Arrowsmith M, Böhnke J, Braunschweig H, Dellermann T, Dewhurst RD, Kelch H, Krummenacher I, Mattock JD, Müssig JH, Thiess T, Vargas A, Zhang J. Generierung einer kleinen HOMO-LUMO-Lücke und intramolekulare C-H-Borylierung durch Diboren-Anthracen-Orbitalinterkalation Angewandte Chemie. 129: 8122-8126. DOI: 10.1002/Ange.201704063  0.321
2017 Nutz M, Borthakur B, Dewhurst RD, Deißenberger A, Dellermann T, Schäfer M, Krummenacher I, Phukan AK, Braunschweig H. Synthese und Nachweis von Iminoboranen durch M=B/C=N-Bindungsmetathese Angewandte Chemie. 129: 8084-8089. DOI: 10.1002/Ange.201703324  0.326
2016 Braunschweig H, Ewing WC, Ghosh S, Kramer T, Mattock JD, Östreicher S, Vargas A, Werner C. Trimetallaborides as starting points for the syntheses of large metal-rich molecular borides and clusters. Chemical Science. 7: 109-116. PMID 29861971 DOI: 10.1039/C5Sc03206G  0.574
2016 Ansell MB, Kostakis GE, Braunschweig H, Navarro O, Spencer J. Synthesis of Functionalized Hydrazines: Facile Homogeneous (N-Heterocyclic Carbene)-Palladium(0)-Catalyzed Diboration and Silaboration of Azobenzenes. Advanced Synthesis & Catalysis. 358: 3765-3769. PMID 28111537 DOI: 10.1002/Adsc.201601106  0.362
2016 Braunschweig H, Krummenacher I, Lichtenberg C, Mattock JD, Schäfer M, Schmidt U, Schneider C, Steffenhagen T, Ullrich S, Vargas A. Dibora[2]ferrocenophane: A Carbene-Stabilized Diborene in a Strained cis-Configuration. Angewandte Chemie (International Ed. in English). PMID 27995698 DOI: 10.1002/Anie.201609601  0.344
2016 Bertermann R, Böhnke J, Braunschweig H, Dewhurst RD, Kupfer T, Muessig JH, Pentecost L, Radacki K, Sen SS, Vargas A. Dynamic, Reversible Oxidative Addition of Highly Polar Bonds to a Transition Metal. Journal of the American Chemical Society. 138: 16140-16147. PMID 27960339 DOI: 10.1021/Jacs.6B10609  0.673
2016 Arrowsmith M, Braunschweig H, Radacki K, Thiess T, Turkin A. Facile Access to Unprecedented Electron-Precise Monohydrodiboranes(4), cis-1,2-Dihydrodiboranes(4) and a 1,1-Dihydrodiborane(5). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27935652 DOI: 10.1002/Chem.201605270  0.309
2016 Arrowsmith M, Braunschweig H, Stennett T. Formation and Reactivity of Electron-Precise B-B Single and Multiple Bonds. Angewandte Chemie (International Ed. in English). PMID 27860056 DOI: 10.1002/Anie.201610072  0.349
2016 Arnold N, Bertermann R, Bickelhaupt M, Braunschweig H, Drisch M, Finze M, Hupp F, Poater J, Sprenger J. Formation of a Trifluorophosphane Platinum(II) Complex via P-F Bond Activation of Phosphorus Pentafluoride with a Pt(0) Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27813174 DOI: 10.1002/Chem.201604997  0.432
2016 Bertermann R, Braunschweig H, Celik MA, Dellermann T, Kelch H. Cyclisation of biscarbenoids - a novel mode of cyclobutadiene stabilisation. Chemical Communications (Cambridge, England). PMID 27774552 DOI: 10.1039/C6Cc07741B  0.382
2016 Arrowsmith M, Auerhammer D, Bertermann R, Braunschweig H, Bringmann G, Celik MA, Dewhurst RD, Finze M, Grüne M, Hailmann M, Hertle T, Krummenacher I. Generation of Dicoordinate Boron(I) Units by Fragmentation of a Tetra-Boron(I) Molecular Square. Angewandte Chemie (International Ed. in English). PMID 27730749 DOI: 10.1002/Anie.201608429  0.381
2016 Gackstatter A, Braunschweig H, Kupfer T, Voigt C, Arnold N. N-Heterocyclic Silylenes in Boron Chemistry: Facile Formation of Silylboranes and Silaborinines. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27709713 DOI: 10.1002/Chem.201603945  0.37
2016 Arrowsmith M, Böhnke J, Braunschweig H, Celik M, Dellermann T, Hammond K. Uncatalyzed Hydrogenation of First-Row Main Group Multiple Bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27685839 DOI: 10.1002/Chem.201604094  0.333
2016 Braunschweig H, Jimenez-Halla JO, Radacki K, Shang R. Direct Conversion from Terminal Borylene to Terminal Phosphinidene. Angewandte Chemie (International Ed. in English). PMID 27621216 DOI: 10.1002/Anie.201603548  0.591
2016 Arnold N, Braunschweig H, Dewhurst RD, Hupp F, Radacki K, Trumpp A. Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27514500 DOI: 10.1002/Chem.201602805  0.391
2016 Kelch H, Kachel S, Celik MA, Schaefer M, Wennemann B, Radacki K, Petrov A, Tamm M, Braunschweig H. Elucidating the Reactivity of Vicinal Dicarbenoids: from Lewis Adduct Formation to B-C Bond Activation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27428270 DOI: 10.1002/Chem.201603234  0.422
2016 Braunschweig H, Celik MA, Dewhurst RD, Ferkinghoff K, Hermann A, Jimenez-Halla JO, Kramer T, Radacki K, Shang R, Siedler E, Weißenberger F, Werner C. Interactions of Isonitriles with Metal-Boron Bonds: Insertions, Coupling, Ring Formation, and Liberation of Monovalent Boron. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27388206 DOI: 10.1002/Chem.201600793  0.616
2016 Arnold N, Braunschweig H, Ewing WC, Kupfer T, Radacki K, Thiess T, Trumpp A. Controlling Regiochemistry in the Syntheses of Boraindanes from Diborane(4) Starting Materials. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27385314 DOI: 10.1002/Chem.201601522  0.375
2016 Arrowsmith M, Böhnke J, Braunschweig H, Celik MA, Claes C, Ewing WC, Krummenacher I, Lubitz K, Schneider C. Neutral Diboron Analogues of Archetypal Aromatic Species by Spontaneous Cycloaddition. Angewandte Chemie (International Ed. in English). PMID 27374193 DOI: 10.1002/Anie.201602384  0.417
2016 Arrowsmith M, Braunschweig H, Celik MA, Dellermann T, Dewhurst RD, Ewing WC, Hammond K, Kramer T, Krummenacher I, Mies J, Radacki K, Schuster JK. Neutral zero-valent s-block complexes with strong multiple bonding. Nature Chemistry. 8: 638-42. PMID 27334631 DOI: 10.1038/Nchem.2542  0.433
2016 Paul US, Braunschweig H, Radius U. Iridium-catalysed dehydrocoupling of aryl phosphine-borane adducts: synthesis and characterisation of high molecular weight poly(phosphinoboranes). Chemical Communications (Cambridge, England). PMID 27320239 DOI: 10.1039/C6Cc04363A  0.362
2016 Schäfer M, Beattie NA, Geetharani K, Schaefer J, Ewing WC, Krahfuss M, Hörl C, Dewhurst RD, Macgregor SA, Lambert C, Braunschweig H. Synthesis of Functionalized 1,4-Azaborinines by the Cyclization of Di-tert-butyliminoborane and Alkynes. Journal of the American Chemical Society. PMID 27286231 DOI: 10.1021/Jacs.6B04128  0.446
2016 Braunschweig H, Demeshko S, Ewing WC, Krummenacher I, Macha BB, Mattock JD, Meyer F, Mies J, Schäfer M, Vargas A. A Binuclear 1,1'-Bis(boratabenzene) Complex: Unprecedented Intramolecular Metal-Metal Communication through a B-B Bond. Angewandte Chemie (International Ed. in English). PMID 27240267 DOI: 10.1002/Anie.201603437  0.612
2016 Schäfer M, Schäfer J, Dewhurst RD, Ewing WC, Krahfuß M, Kuntze-Fechner MW, Wehner M, Lambert C, Braunschweig H. Regioselective Catalytic and Stepwise Routes to Bulky, Functional-Group-Appended, and Luminescent 1,2-Azaborinines. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27166798 DOI: 10.1002/Chem.201600653  0.348
2016 Braunschweig H, Celik MA, Dewhurst RD, Ferkinghoff K, Radacki K, Weißenberger F. Boron-Metallated Borirenes and Bis(Borirenes). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27159272 DOI: 10.1002/Chem.201600651  0.39
2016 Braunschweig H, Damme A, Dewhurst R, Radacki K, Weißenberger F, Wennemann B, Ye Q. Fundamental Differences Between Group 8 Metals: Unexpected Oxidation State Preferences and Mechanisms in Ruthenium Borylene Complex Formation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27124888 DOI: 10.1002/Chem.201601602  0.585
2016 Braunschweig H, Constantinidis P, Dellermann T, Ewing WC, Fischer I, Hess M, Knight FR, Rempel A, Schneider C, Ullrich S, Vargas A, Woollins JD. Highly Strained Heterocycles Constructed from Boron-Boron Multiple Bonds and Heavy Chalcogens. Angewandte Chemie (International Ed. in English). PMID 27027522 DOI: 10.1002/Anie.201601691  0.398
2016 Braunschweig H, Celik MA, Dewhurst RD, Kachel S, Wennemann B. Mild and Complete Carbonyl Ligand Scission on a Mononuclear Transition Metal Complex. Angewandte Chemie (International Ed. in English). PMID 26990148 DOI: 10.1002/Anie.201600307  0.424
2016 Arnold N, Braunschweig H, Damme A, Dewhurst RD, Pentecost L, Radacki K, Stellwag-Konertz S, Thiess T, Trumpp A, Vargas A. New outcomes of Lewis base addition to diboranes(4): electronic effects override strong steric disincentives. Chemical Communications (Cambridge, England). PMID 26974684 DOI: 10.1039/C6Cc01493C  0.318
2016 Braunschweig H, Dewhurst RD, Pentecost L, Radacki K, Vargas A, Ye Q. Dative Bonding between Group 13 Elements Using a Boron-Centered Lewis Base. Angewandte Chemie (International Ed. in English). 55: 436-40. PMID 26768824 DOI: 10.1002/Anie.201509289  0.538
2016 Bissert R, Braunschweig H, Dewhurst RD, Schneider C. Metal-Only Lewis Pairs Based on Zerovalent Osmium Organometallics. 35: 2567-2573. DOI: 10.1021/Acs.Organomet.6B00495  0.407
2016 Braunschweig H, Dewhurst RD, Schneider C. Steric Control between Neutral Metal-Only Lewis Pairs and Metal-Stabilized Gallenium and Gallinium Cations Organometallics. 35: 1002-1007. DOI: 10.1021/Acs.Organomet.6B00045  0.337
2016 Braunschweig H, Légaré M, Matler A, Wennemann B. Silylosmium Anions for the Synthesis of Borylosmium(II) Complexes by Salt Elimination European Journal of Inorganic Chemistry. 2016: 3376-3379. DOI: 10.1002/Ejic.201600262  0.401
2016 Braunschweig H, Jimenez-Halla JOC, Radacki K, Shang R. Direkte Umwandlung eines terminalen Borylen- in einen terminalen Phosphinidenkomplex Angewandte Chemie. 128: 12864-12868. DOI: 10.1002/Ange.201603548  0.488
2016 Braunschweig H, Demeshko S, Ewing WC, Krummenacher I, Macha BB, Mattock JD, Meyer F, Mies J, Schäfer M, Vargas A. Ein zweikerniger 1,1′-Bis(boratabenzol)-Komplex: beispiellose intramolekulare Metall-Metall-Kommunikation durch eine B-B-Bindung Angewandte Chemie. 128: 7839-7842. DOI: 10.1002/Ange.201603437  0.516
2015 Braunschweig H, Radacki K, Shang R. Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments. Chemical Science. 6: 2989-2996. PMID 29403636 DOI: 10.1039/C5Sc00211G  0.615
2015 Perras FA, Ewing WC, Dellermann T, Böhnke J, Ullrich S, Schäfer T, Braunschweig H, Bryce DL. Spying on the boron-boron triple bond using spin-spin coupling measured from (11)B solid-state NMR spectroscopy. Chemical Science. 6: 3378-3382. PMID 29142694 DOI: 10.1039/C5Sc00644A  0.318
2015 Braunschweig H, Celik MA, Dewhurst RD, Heid M, Hupp F, Sen SS. Stepwise isolation of low-valent, low-coordinate Sn and Pb mono- and dications in the coordination sphere of platinum. Chemical Science. 6: 425-435. PMID 28936301 DOI: 10.1039/C4Sc02948H  0.63
2015 Zhang Z, Edkins RM, Haehnel M, Wehner M, Eichhorn A, Mailänder L, Meier M, Brand J, Brede F, Müller-Buschbaum K, Braunschweig H, Marder TB. Taming the beast: fluoromesityl groups induce a dramatic stability enhancement in boroles. Chemical Science. 6: 5922-5927. PMID 28791091 DOI: 10.1039/C5Sc02205C  0.389
2015 Braunschweig H, Gackstatter A, Kupfer T, Scheller T, Hupp F, Damme A, Arnold N, Ewing WC. Generation of 1,2-azaboretidines reduction of ADC borane adducts. Chemical Science. 6: 3461-3465. PMID 28706706 DOI: 10.1039/C5Sc01077B  0.379
2015 Arnold N, Braunschweig H, Dewhurst RD, Ewing WC. Unprecedented Borane, Diborane(3), Diborene and Borylene Ligands via Pt-Mediated Borane Dehydrogenation. Journal of the American Chemical Society. PMID 26667300 DOI: 10.1021/Jacs.5B11315  0.433
2015 Braunschweig H, Brunecker C, Dewhurst RD, Schneider C, Wennemann B. Lewis Acid Binding and Transfer as a Versatile Experimental Gauge of the Lewis Basicity of Fe(0) , Ru(0) , and Pt(0) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 19195-201. PMID 26555043 DOI: 10.1002/Chem.201503536  0.408
2015 Kupfer T, Braunschweig H, Radacki K. The Triboracyclopropenyl Dianion: The Lightest Possible Main-Group-Element Hückel π Aromatic. Angewandte Chemie (International Ed. in English). PMID 26530854 DOI: 10.1002/Anie.201508670  0.397
2015 Braunschweig H, Dewhurst RD, Ferkinghoff K. Carbene-induced synthesis of the first borironium cations using the [(η(5)-C5Me5)Fe(CO)2](-) anion as an unlikely leaving group. Chemical Communications (Cambridge, England). 52: 183-5. PMID 26511336 DOI: 10.1039/C5Cc07503C  0.379
2015 Braunschweig H, Hupp F, Krummenacher I, Mailänder L, Rauch F. Ring Expansions of Boroles with Diazo Compounds: Steric Control of C or N Insertion and Aromatic/Nonaromatic Products. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 17844-9. PMID 26482113 DOI: 10.1002/Chem.201503048  0.385
2015 Böhnke J, Braunschweig H, Dellermann T, Ewing WC, Hammond K, Jimenez-Halla JO, Kramer T, Mies J. The Synthesis of B2 (SIDip)2 and its Reactivity Between the Diboracumulenic and Diborynic Extremes. Angewandte Chemie (International Ed. in English). 54: 13801-5. PMID 26427026 DOI: 10.1002/Anie.201506368  0.337
2015 Braunschweig H, Jimenez-Halla JO, Radacki K, Shang R. A metal-mediated boron-centred isomerisation reaction via C-H activation. Chemical Communications (Cambridge, England). 51: 16569-72. PMID 26420173 DOI: 10.1039/C5Cc07681A  0.617
2015 Braunschweig H, Damme A, Dück K, Fuß M, Hörl C, Kramer T, Krummenacher I, Kupfer T, Paprocki V, Schneider C. Ansa-Complexes of [Mn(η(5) -C5 H5 )(η(6) -C6 H6 )]: Preparation, Characterization, and Reactivity of [n]Manganoarenophanes (n=1, 2, 3). Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 14797-803. PMID 26387512 DOI: 10.1002/Chem.201502161  0.357
2015 Bissinger P, Braunschweig H, Celik MA, Claes C, Dewhurst RD, Endres S, Kelch H, Kramer T, Krummenacher I, Schneider C. Synthesis of cyclic diborenes with unprecedented cis-configuration. Chemical Communications (Cambridge, England). 51: 15917-20. PMID 26360103 DOI: 10.1039/C5Cc07103H  0.326
2015 Bertermann R, Braunschweig H, Constantinidis P, Dellermann T, Dewhurst RD, Ewing WC, Fischer I, Kramer T, Mies J, Phukan AK, Vargas A. Exclusive π Encapsulation of Light Alkali Metal Cations by a Neutral Molecule. Angewandte Chemie (International Ed. in English). 54: 13090-4. PMID 26358853 DOI: 10.1002/Anie.201506487  0.354
2015 Braunschweig H, Dewhurst RD, Radacki K, Wennemann B, Ye Q. 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group. Chemical Communications (Cambridge, England). 51: 15465-8. PMID 26346156 DOI: 10.1039/C5Cc06425B  0.58
2015 Braunschweig H, Krummenacher I, Mailänder L, Rauch F. O,N,B-Containing eight-membered heterocycles by ring expansion of boroles with nitrones. Chemical Communications (Cambridge, England). 51: 14513-5. PMID 26280089 DOI: 10.1039/C5Cc05368D  0.365
2015 Braunschweig H, Gackstatter A, Kupfer T, Radacki K, Franke S, Meyer K, Fucke K, Lemée-Cailleau MH. Uranium Hydridoborates: Synthesis, Magnetism, and X-ray/Neutron Diffraction Structures. Inorganic Chemistry. 54: 8022-8. PMID 26247295 DOI: 10.1021/Acs.Inorgchem.5B01205  0.327
2015 Arnold N, Braunschweig H, Brenner PB, Celik MA, Dewhurst RD, Haehnel M, Kramer T, Krummenacher I, Marder TB. Correlations and Contrasts in Homo- and Heteroleptic Cyclic (Alkyl)(amino)carbene-Containing Pt(0) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 12357-62. PMID 26241579 DOI: 10.1002/Chem.201502048  0.381
2015 Braunschweig H, Ewing WC, Kramer T, Mattock JD, Vargas A, Werner C. Organometallic Probe for the Electronics of Base-Stabilized Group 11 Metal Cations. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 12347-56. PMID 26178571 DOI: 10.1002/Chem.201500788  0.394
2015 Braunschweig H, Ewing WC, Ferkinghoff K, Hermann A, Kramer T, Shang R, Siedler E, Werner C. Activation of boryl-, borylene and metalloborylene complexes by isonitriles. Chemical Communications (Cambridge, England). 51: 13032-5. PMID 26177877 DOI: 10.1039/C5Cc04712A  0.626
2015 Braunschweig H, Dellermann T, Ewing WC, Kramer T, Schneider C, Ullrich S. Reductive Insertion of Elemental Chalcogens into Boron-Boron Multiple Bonds. Angewandte Chemie (International Ed. in English). 54: 10271-5. PMID 26118498 DOI: 10.1002/Anie.201503398  0.374
2015 Braunschweig H, Brückner C, Celik MA, Dück K, Hupp F, Kramer T, Krebs J, Krummenacher I. Ansa-Bridged Bis(benzene) Titanium Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 11056-64. PMID 26111216 DOI: 10.1002/Chem.201500737  0.393
2015 Braunschweig H, Dewhurst RD, Hupp F, Nutz M, Radacki K, Tate CW, Vargas A, Ye Q. Multiple complexation of CO and related ligands to a main-group element. Nature. 522: 327-30. PMID 26085273 DOI: 10.1038/Nature14489  0.596
2015 Braunschweig H, Celik MA, Dück K, Hupp F, Krummenacher I. f-Block Ansa Complexes in the Solid State: [3]Thoro- and [3]Uranocenophanes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 9339-42. PMID 26013999 DOI: 10.1002/Chem.201501545  0.384
2015 Ji L, Edkins RM, Lorbach A, Krummenacher I, Brückner C, Eichhorn A, Braunschweig H, Engels B, Low PJ, Marder TB. Electron Delocalization in Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene. Journal of the American Chemical Society. 137: 6750-3. PMID 25948415 DOI: 10.1021/Jacs.5B03805  0.362
2015 Dewhurst RD, Neeve EC, Braunschweig H, Marder TB. sp(2)-sp(3) diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis. Chemical Communications (Cambridge, England). 51: 9594-607. PMID 25912808 DOI: 10.1039/C5Cc02316E  0.341
2015 Braunschweig H, Celik MA, Hupp F, Krummenacher I, Mailänder L. Formation of BN Isosteres of Azo Dyes by Ring Expansion of Boroles with Azides. Angewandte Chemie (International Ed. in English). 54: 6347-51. PMID 25808881 DOI: 10.1002/Anie.201500970  0.349
2015 Braunschweig H, Shang R. Reactivity of transition-metal borylene complexes: recent advances in B-C and B-B bond formation via borylene ligand coupling. Inorganic Chemistry. 54: 3099-106. PMID 25760461 DOI: 10.1021/Acs.Inorgchem.5B00091  0.641
2015 Bertsch S, Brand J, Braunschweig H, Hupp F, Radacki K. Platinum oxoboryl complexes as substrates for the formation of 1:1, 1:2, and 2:1 Lewis acid-base adducts and 1,2-dipolar additions. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 6278-85. PMID 25760032 DOI: 10.1002/Chem.201500143  0.332
2015 Braunschweig H, Dewhurst RD, Kramer T. Synthesis of the first heteroaryl-substituted boryl complexes: strong stabilizing effects of boron-aryl π-conjugation. Inorganic Chemistry. 54: 3619-23. PMID 25751161 DOI: 10.1021/Acs.Inorgchem.5B00192  0.42
2015 Braunschweig H, Ye Q, Celik MA, Dewhurst RD, Radacki K. Cyclization of a 1,4-diborabutadiene ligand with both atoms of CO. Angewandte Chemie (International Ed. in English). 54: 5065-8. PMID 25727338 DOI: 10.1002/Anie.201411967  0.585
2015 Böhnke J, Braunschweig H, Dellermann T, Ewing WC, Kramer T, Krummenacher I, Vargas A. From an electron-rich bis(boraketenimine) to an electron-poor diborene. Angewandte Chemie (International Ed. in English). 54: 4469-73. PMID 25690666 DOI: 10.1002/Anie.201412006  0.384
2015 Bissinger P, Steffen A, Vargas A, Dewhurst RD, Damme A, Braunschweig H. Unexpected luminescence behavior of coinage metal π-diborene complexes. Angewandte Chemie (International Ed. in English). 54: 4362-6. PMID 25663001 DOI: 10.1002/Anie.201408993  0.361
2015 Böhnke J, Braunschweig H, Constantinidis P, Dellermann T, Ewing WC, Fischer I, Hammond K, Hupp F, Mies J, Schmitt HC, Vargas A. Experimental assessment of the strengths of B-B triple bonds. Journal of the American Chemical Society. 137: 1766-9. PMID 25625817 DOI: 10.1021/Ja5116293  0.338
2015 Braunschweig H, Damme A, Demeshko S, Dück K, Kramer T, Krummenacher I, Meyer F, Radacki K, Stellwag-Konertz S, Whittell GR. A paramagnetic heterobimetallic polymer: synthesis, reactivity, and ring-opening polymerization of tin-bridged homo- and heteroleptic vanadoarenophanes. Journal of the American Chemical Society. 137: 1492-500. PMID 25565127 DOI: 10.1021/Ja510884H  0.519
2015 Braunschweig H, Claes C, Damme A, Deissenberger A, Dewhurst RD, Hörl C, Kramer T. A facile and selective route to remarkably inert monocyclic NHC-stabilized boriranes. Chemical Communications (Cambridge, England). 51: 1627-30. PMID 25503081 DOI: 10.1039/C4Cc09036E  0.367
2015 Jimenez-Halla JO, Matito E, Solà M, Braunschweig H, Hörl C, Krummenacher I, Wahler J. A theoretical study of the aromaticity in neutral and anionic borole compounds. Dalton Transactions (Cambridge, England : 2003). 44: 6740-7. PMID 25494445 DOI: 10.1039/C4Dt03445G  0.306
2015 Braunschweig H, Dewhurst RD, Hupp F, Wolf J. Unprecedented oxidative addition and metal-only Lewis pair chemistry of antimony trihalides. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 1860-2. PMID 25491232 DOI: 10.1002/Chem.201405867  0.384
2015 Braunschweig H, Ewing WC, Geetharani K, Schäfer M. The reactivities of iminoboranes with carbenes: BN isosteres of carbene-alkyne adducts. Angewandte Chemie (International Ed. in English). 54: 1662-5. PMID 25475584 DOI: 10.1002/Anie.201409699  0.394
2015 Braunschweig H, Damme A, Dewhurst RD, Kelch H, Macha BB, Radacki K, Vargas A, Ye Q. Platinum trans-Bis(borirene) complexes displaying coplanarity and communication across a platinum metal center. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 2377-86. PMID 25430871 DOI: 10.1002/Chem.201405803  0.612
2015 Arnold T, Braunschweig H, Ewing WC, Kramer T, Mies J, Schuster JK. Beryllium bis(diazaborolyl): old neighbors finally shake hands. Chemical Communications (Cambridge, England). 51: 737-40. PMID 25417558 DOI: 10.1039/C4Cc08519A  0.37
2015 Bissinger P, Braunschweig H, Damme A, Hörl C, Krummenacher I, Kupfer T. Boron as a powerful reductant: synthesis of a stable boron-centered radical-anion radical-cation pair. Angewandte Chemie (International Ed. in English). 54: 359-62. PMID 25389108 DOI: 10.1002/Anie.201409513  0.321
2015 Braunschweig H, Ghosh S, Jimenez-Halla JO, Klein JH, Lambert C, Radacki K, Steffen A, Vargas A, Wahler J. A combined experimental and theoretical study on the isomers of 2,3,4,5-tetracarba-nido-hexaborane(6) derivatives and their photophysical properties. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 210-8. PMID 25351663 DOI: 10.1002/Chem.201405017  0.589
2015 Braunschweig H, Radacki K, Shang R. Side-on coordination of boryl and borylene complexes to cationic coinage metal fragments Chemical Science. 6: 2989-2996. DOI: 10.1039/c5sc00211g  0.571
2015 Arnold N, Braunschweig H, Brenner PB, Dewhurst R, Kramer T, Radacki K. Investigation of Steric Factors Involved in the Formation of Terminal Cationic Platinum Arylborylene Complexes Organometallics. 34: 2343-2347. DOI: 10.1021/Om501141G  0.39
2015 Arnold N, Mozo S, Paul U, Radius U, Braunschweig H. Aryldihydroborane Coordination to Iridium and Osmium Hydrido Complexes Organometallics. 34: 5709-5715. DOI: 10.1021/Acs.Organomet.5B00788  0.401
2015 Simpson PV, Radacki K, Braunschweig H, Schatzschneider U. An iridium N-heterocyclic carbene complex [IrCl(CO)2(NHC)] as a carbon monoxide-releasing molecule (CORM) Journal of Organometallic Chemistry. 782: 116-123. DOI: 10.1016/J.Jorganchem.2014.12.034  0.38
2015 Schäfer M, Krummenacher I, Braunschweig H, Finze M. Boron Clusters with a Ferrocenylalkynyl Group Bonded to Boron: Synthesis, Characterization, and Electrochemical Trends Zeitschrift Fur Anorganische Und Allgemeine Chemie. DOI: 10.1002/Zaac.201400524  0.359
2015 Brand J, Braunschweig H, Dewhurst RD, Hupp F, Lang K. Synthesis and hydroboration of a mixed-donor iminoboryl complex of platinum European Journal of Inorganic Chemistry. 2015: 2592-2595. DOI: 10.1002/Ejic.201500215  0.384
2015 Braunschweig H, Damme A, Dewhurst RD, Kelch H, Macha BB, Radacki K, Vargas A, Ye Q. Cover Picture: Platinum trans -Bis(borirene) Complexes Displaying Coplanarity and Communication Across a Platinum Metal Center (Chem. Eur. J. 6/2015) Chemistry - a European Journal. 21: 2273-2273. DOI: 10.1002/Chem.201590020  0.562
2015 Braunschweig H, Dewhurst RD, Mozo S. Building Electron-Precise Boron-Boron Single Bonds: Imposing Monogamy on a Promiscuous Element Chemcatchem. DOI: 10.1002/Cctc.201500219  0.36
2015 Braunschweig H, Celik MA, Hupp F, Krummenacher I, Mailänder L. Synthese BN-isosterer Verbindungen von Azofarbstoffen durch Ringerweiterung von Borolen mit Aziden Angewandte Chemie. 127: 6445-6449. DOI: 10.1002/Ange.201500970  0.312
2014 Braunschweig H, Kramer T. Crystal structure of μ-1κC:2(η(2))-carbonyl-carbonyl-1κC-chlorido-2κCl-μ-chlorido-borylene-1:2κ(2) B:B-[1(η(5))-penta-methyl-cyclo-penta-dien-yl](tri-cyclo-hexyl-phosphane-2κP)iron(II)platinum(II) benzene monosolvate. Acta Crystallographica. Section E, Structure Reports Online. 70: 421-3. PMID 25484763 DOI: 10.1107/S1600536814023381  0.364
2014 Braunschweig H, Dewhurst RD, Hupp F, Schneider C. Silver(I) and thallium(I) cations as unsupported bridges between two metal bases. Chemical Communications (Cambridge, England). 50: 15685-8. PMID 25373731 DOI: 10.1039/C4Cc08508F  0.376
2014 Hupp F, Ma M, Kroll F, Jimenez-Halla JO, Dewhurst RD, Radacki K, Stasch A, Jones C, Braunschweig H. Platinum complexes containing pyramidalized germanium and tin dihalide ligands bound through σ,σ M=E multiple bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 16888-98. PMID 25358255 DOI: 10.1002/Chem.201404342  0.427
2014 Braunschweig H, Hörl C. Unexpected cluster formation upon hydroboration of a neutral diborene with 9-BBN. Chemical Communications (Cambridge, England). 50: 10983-5. PMID 25096570 DOI: 10.1039/C4Cc04476B  0.368
2014 Holzmeier F, Lang M, Hemberger P, Bodi A, Schäfer M, Dewhurst RD, Braunschweig H, Fischer I. Photoionization and pyrolysis of a 1,4-azaborinine: retro-hydroboration in the cation and identification of novel organoboron ring systems. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9683-92. PMID 24976576 DOI: 10.1002/Chem.201402884  0.321
2014 Braunschweig H, Hörl C, Mailänder L, Radacki K, Wahler J. Antiaromaticity to aromaticity: from boroles to 1,2-azaborinines by ring expansion with azides. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9858-61. PMID 24964998 DOI: 10.1002/Chem.201403101  0.355
2014 Braunschweig H, Ye Q, Vargas A, Dewhurst RD, Hupp F. Complete and partial 1,2-additions across transition metal-boron double bonds. Journal of the American Chemical Society. 136: 9560-3. PMID 24959972 DOI: 10.1021/Ja504761F  0.582
2014 Rao YL, Hörl C, Braunschweig H, Wang S. Reversible photochemical and thermal isomerization of azaboratabisnorcaradiene to azaborabenzotropilidene. Angewandte Chemie (International Ed. in English). 53: 9086-9. PMID 24943291 DOI: 10.1002/Anie.201404435  0.33
2014 Bissinger P, Braunschweig H, Damme A, Krummenacher I, Phukan AK, Radacki K, Sugawara S. Isolation of a neutral boron-containing radical stabilized by a cyclic (alkyl)(amino)carbene. Angewandte Chemie (International Ed. in English). 53: 7360-3. PMID 24917474 DOI: 10.1002/Anie.201403514  0.35
2014 Böhnke J, Braunschweig H, Ewing WC, Hörl C, Kramer T, Krummenacher I, Mies J, Vargas A. Diborabutatriene: an electron-deficient cumulene. Angewandte Chemie (International Ed. in English). 53: 9082-5. PMID 24864006 DOI: 10.1002/Anie.201403888  0.386
2014 Nagel C, McLean S, Poole RK, Braunschweig H, Kramer T, Schatzschneider U. Introducing [Mn(CO)3(tpa-κ(3)N)](+) as a novel photoactivatable CO-releasing molecule with well-defined iCORM intermediates - synthesis, spectroscopy, and antibacterial activity. Dalton Transactions (Cambridge, England : 2003). 43: 9986-97. PMID 24855638 DOI: 10.1039/C3Dt51848E  0.371
2014 Braunschweig H, Dewhurst RD, Radacki K, Tate CW, Vargas A. Trihapto ligation of a borirene to a single metal atom: a heterocyclic analogue of the η³-cyclopropenyl ligand. Angewandte Chemie (International Ed. in English). 53: 6263-6. PMID 24802284 DOI: 10.1002/Anie.201402815  0.411
2014 Bertermann R, Braunschweig H, Ewing WC, Kramer T, Phukan AK, Vargas A, Werner C. Synthesis and characterization of a mercury-containing trimetalloboride. Chemical Communications (Cambridge, England). 50: 5729-32. PMID 24740635 DOI: 10.1039/C4Cc01246A  0.4
2014 Bertermann R, Braunschweig H, Dewhurst RD, Hörl C, Kramer T, Krummenacher I. Evidence for extensive single-electron-transfer chemistry in boryl anions: isolation and reactivity of a neutral borole radical. Angewandte Chemie (International Ed. in English). 53: 5453-7. PMID 24719250 DOI: 10.1002/Anie.201402556  0.411
2014 Bissinger P, Braunschweig H, Damme A, Kupfer T, Krummenacher I, Vargas A. Boron radical cations from the facile oxidation of electron-rich diborenes. Angewandte Chemie (International Ed. in English). 53: 5689-93. PMID 24711294 DOI: 10.1002/Anie.201311110  0.374
2014 Bertsch S, Bertermann R, Braunschweig H, Damme A, Dewhurst RD, Phukan AK, Saalfrank C, Vargas A, Wennemann B, Ye Q. Metal-only Lewis pairs by reversible insertion of ruthenium and osmium fragments into metal-boron double bonds. Angewandte Chemie (International Ed. in English). 53: 4240-3. PMID 24623646 DOI: 10.1002/Anie.201310520  0.607
2014 Braunschweig H, Geetharani K, Jimenez-Halla JO, Schäfer M. Direct synthetic route to functionalized 1,2-azaborinines. Angewandte Chemie (International Ed. in English). 53: 3500-4. PMID 24574145 DOI: 10.1002/Anie.201309707  0.379
2014 Braunschweig H, Dewhurst RD, Hörl C, Phukan AK, Pinzner F, Ullrich S. Direct hydroboration of B=B bonds: a mild strategy for the proliferation of B-B bonds. Angewandte Chemie (International Ed. in English). 53: 3241-4. PMID 24554602 DOI: 10.1002/Anie.201309325  0.378
2014 Braunschweig H, Brown CK, Dewhurst RD, Jimenez-Halla JO, Kramer T, Krummenacher I, Pfaffinger B. Boryl-functionalized σ-alkynyl and vinylidene rhodium complexes: synthesis and electronic properties. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 1427-33. PMID 24458915 DOI: 10.1002/Chem.201303681  0.395
2014 Brand J, Braunschweig H, Hupp F, Phukan AK, Radacki K, Sen SS. A B-C double bond unit coordinated to platinum: an alkylideneboryl ligand that is isoelectronic to neutral aminoborylene Ligands. Angewandte Chemie (International Ed. in English). 53: 2240-4. PMID 24453206 DOI: 10.1002/Anie.201310557  0.687
2014 Bertermann R, Braunschweig H, Brown CK, Damme A, Dewhurst RD, Hörl C, Kramer T, Krummenacher I, Pfaffinger B, Radacki K. Diverse reactions of N-heterocyclic carbenes with an alkynylborane and isolation of a reactive zwitterionic borataallene. Chemical Communications (Cambridge, England). 50: 97-9. PMID 24185233 DOI: 10.1039/C3Cc46947F  0.352
2014 Brand J, Braunschweig H, Sen SS. B═B and B≡E (E = N and o) multiple bonds in the coordination sphere of late transition metals. Accounts of Chemical Research. 47: 180-91. PMID 23952302 DOI: 10.1021/Ar400106U  0.709
2014 Braunschweig H, Dewhurst RD, Hupp F, Kaufmann C, Phukan AK, Schneider C, Ye Q. Gauging metal Lewis basicity of zerovalent iron complexes via metal-only Lewis pairs Chemical Science. 5: 4099-4104. DOI: 10.1039/C4Sc01539H  0.575
2014 Braunschweig H, Kramer T, Radacki K, Shang R, Siedler E, Werner C. Isolation of the key intermediates of base-promoted borylene-carbonyl coupling reactions Chemical Science. 5: 2271-2276. DOI: 10.1039/C4Sc00183D  0.59
2014 Braunschweig H, Dewhurst RD. Boron-boron multiple bonding: From charged to neutral and back again Organometallics. 33: 6271-6277. DOI: 10.1021/Om500875G  0.351
2014 Braunschweig H, Dewhurst RD, Kramer T, Siedler E. A Simple decarbonylative route to heterodinuclear alkylborylene complexes Organometallics. 33: 3877-3881. DOI: 10.1021/Om500596X  0.389
2014 Bertsch S, Braunschweig H, Dewhurst RD, Radacki K, Saalfrank C, Wennemann B, Ye Q. Partially and Fully Reversible Solvation-Controlled Borylene Swapping and Metal-Only Lewis Pair Formation Organometallics. 33: 3649-3651. DOI: 10.1021/Om5002414  0.579
2014 Braunschweig H, Dellermann T, Dewhurst RD, Mies J, Radacki K, Stellwag-Konertz S, Vargas A. Strained ansa Half-Sandwich Complexes of Ruthenium and Osmium and a Non-Iron Metallopolymer by Ring-Opening Polymerization Organometallics. 33: 1536-1539. DOI: 10.1021/Om500111R  0.348
2014 Arnold T, Braunschweig H, Damme A, Hörl C, Kramer T, Krummenacher I, Mager J. Tin-bridged ansa-metallocenes of the late transition metals cobalt and nickel: Preparation, molecular and electronic structures, and redox chemistry Organometallics. 33: 1659-1664. DOI: 10.1021/Om401212N  0.37
2014 Braunschweig H, Damme A, Dewhurst RD, Kramer T, Krummenacher I, Phukan AK. Short survey of the chemical reduction behavior of the base-stabilized iron dichloroboryl complexes [(η5-C5Me5)Fe(CO) 2BCl2(LB)] Organometallics. 33: 604-606. DOI: 10.1021/Om401176H  0.408
2014 Rammo A, Bejan I, Meltzer A, Radacki K, Braunschweig H, Scheschkewitz D. ChemInform Abstract: 1,2-Disilabicyclo[1.1.1]pentan-4-ones from a Disilenide and Acryloyl Chlorides. Cheminform. 45: no-no. DOI: 10.1002/CHIN.201412192  0.532
2014 Hupp F, Ma M, Kroll F, Jimenez-Halla JOC, Dewhurst RD, Radacki K, Stasch A, Jones C, Braunschweig H. Frontispiece: Platinum Complexes Containing Pyramidalized Germanium and Tin Dihalide Ligands Bound through σ,σ ME Multiple Bonds Chemistry - a European Journal. 20: n/a-n/a. DOI: 10.1002/Chem.201485162  0.38
2014 Braunschweig H, Ewing WC, Geetharani K, Schäfer M. Inside Back Cover: The Reactivities of Iminoboranes with Carbenes: BN Isosteres of Carbene-Alkyne Adducts (Angew. Chem. Int. Ed. 5/2015) Angewandte Chemie International Edition. 54: 1677-1677. DOI: 10.1002/Anie.201411644  0.33
2014 Braunschweig H, Ewing WC, Geetharani K, Schäfer M. Innenrücktitelbild: Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN-Isostere von Carben-Alkin-Addukten (Angew. Chem. 5/2015) Angewandte Chemie. 127: 1697-1697. DOI: 10.1002/Ange.201411644  0.318
2014 Braunschweig H, Ewing WC, Geetharani K, Schäfer M. Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN-Isostere von Carben-Alkin-Addukten Angewandte Chemie. 127: 1682-1685. DOI: 10.1002/Ange.201409699  0.305
2014 Rao Y, Hörl C, Braunschweig H, Wang S. Reversible photochemische und thermische Isomerisierung von Azaboratabisnorcaradien zu Azaborabenzotropyliden Angewandte Chemie. 126: 9232-9236. DOI: 10.1002/Ange.201404435  0.3
2014 Böhnke J, Braunschweig H, Ewing WC, Hörl C, Kramer T, Krummenacher I, Mies J, Vargas A. Diborabutatrien: ein elektronenarmes Cumulen Angewandte Chemie. 126: 9228-9231. DOI: 10.1002/Ange.201403888  0.307
2014 Braunschweig H, Dewhurst RD, Radacki K, Tate CW, Vargas A. Trihapto-Koordination eines Borirens an ein einzelnes Metallatom: ein heterocyclisches Analogon des η3-Cyclopropenylliganden Angewandte Chemie. 126: 6378-6381. DOI: 10.1002/Ange.201402815  0.306
2014 Bertermann R, Braunschweig H, Dewhurst RD, Hörl C, Kramer T, Krummenacher I. Deutliche Belege für Ein-Elektronen-Übertragungen in der Boryl-Anionenchemie: Isolierung und Reaktivität eines neutralen Borolradikals Angewandte Chemie. 126: 5557-5561. DOI: 10.1002/Ange.201402556  0.308
2014 Brand J, Braunschweig H, Hupp F, Phukan AK, Radacki K, Sen SS. Aufbau einer B-C-Doppelbindung in der Koordinationssphäre des Platins: ein Alkylidenborylligand, der isoelektronisch zu neutralen Aminoborylenen ist Angewandte Chemie. 126: 2273-2277. DOI: 10.1002/Ange.201310557  0.624
2014 Bertsch S, Bertermann R, Braunschweig H, Damme A, Dewhurst RD, Phukan AK, Saalfrank C, Vargas A, Wennemann B, Ye Q. Rein metallische Lewis-Paare (MOLPs) durch reversible Insertion von Ruthenium- und Osmiumfragmenten in Metall-Bor-Doppelbindungen Angewandte Chemie. 126: 4326-4329. DOI: 10.1002/Ange.201310520  0.536
2013 Braunschweig H, Guethlein F, Mailänder L, Marder TB. Synthesis of catechol-, pinacol-, and neopentylglycolborane through the heterogeneous catalytic B-B hydrogenolysis of diboranes(4). Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 14831-5. PMID 24591216 DOI: 10.1002/Chem.201302677  0.378
2013 Braunschweig H, Dellermann T, Dewhurst RD, Ewing WC, Hammond K, Jimenez-Halla JO, Kramer T, Krummenacher I, Mies J, Phukan AK, Vargas A. Metal-free binding and coupling of carbon monoxide at a boron-boron triple bond. Nature Chemistry. 5: 1025-8. PMID 24256866 DOI: 10.1038/Nchem.1778  0.353
2013 Bauer J, Bertsch S, Braunschweig H, Dewhurst RD, Ferkinghoff K, Hörl C, Kraft K, Radacki K. Hydridoborylene complexes and di-, tri-, and tetranuclear borido complexes with hydride ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 17608-12. PMID 24218369 DOI: 10.1002/Chem.201303716  0.409
2013 Braunschweig H, Dyakonov V, Engels B, Falk Z, Hörl C, Klein JH, Kramer T, Kraus H, Krummenacher I, Lambert C, Walter C. Multiple reduction of 2,5-bis(borolyl)thiophene: isolation of a negative bipolaron by comproportionation. Angewandte Chemie (International Ed. in English). 52: 12852-5. PMID 24123828 DOI: 10.1002/Anie.201306969  0.34
2013 Braunschweig H, Ye Q, Vargas A, Radacki K, Damme A. Phosphine-triggered co-catenation of :BR and CO on an iron atom. Angewandte Chemie (International Ed. in English). 52: 10657-60. PMID 24038997 DOI: 10.1002/Anie.201304972  0.54
2013 Braunschweig H, Damme A, Kupfer T. Conversion of trans-diboran(4)yl platinum complexes into their cis-bisboryl analogues. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 14682-6. PMID 24027132 DOI: 10.1002/Chem.201301827  0.403
2013 Braunschweig H, Radacki K, Shang R. σ-Coordination of metal-boryl bonds to gold(I). Chemical Communications (Cambridge, England). 49: 9905-7. PMID 23999534 DOI: 10.1039/C3Cc45455J  0.627
2013 Bissinger P, Braunschweig H, Damme A, Dewhurst RD, Kraft K, Kramer T, Radacki K. Base-stabilized boryl and cationic haloborylene complexes of iron. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 13402-7. PMID 23959699 DOI: 10.1002/Chem.201302263  0.368
2013 Bauer J, Braunschweig H, Hörl C, Radacki K, Wahler J. Synthesis of zwitterionic cobaltocenium borate and borata-alkene derivatives from a borole-radical anion. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 13396-401. PMID 23939930 DOI: 10.1002/Chem.201302201  0.386
2013 Braunschweig H, Dewhurst RD, Hörl C, Radacki K, Tate CW, Vargas A, Ye Q. Reductive borylene-CO coupling with a bulky arylborylene complex. Angewandte Chemie (International Ed. in English). 52: 10120-3. PMID 23894013 DOI: 10.1002/Anie.201303798  0.6
2013 Braunschweig H, Hupp F, Kramer T, Mager J. Structure and reactivity of distanna[2]metallocenophanes of ruthenium and osmium. Inorganic Chemistry. 52: 9060-5. PMID 23876041 DOI: 10.1021/Ic4012247  0.355
2013 Braunschweig H, Ye Q, Damme A, Radacki K. Synthesis and structure of the first heterodinuclear bis(borylene) complexes. Chemical Communications (Cambridge, England). 49: 7593-5. PMID 23873145 DOI: 10.1039/C3Cc43877E  0.595
2013 Braunschweig H, Damme A, Kupfer T. Diboran(4)yl platinum(II) complexes. Inorganic Chemistry. 52: 7822-4. PMID 23805976 DOI: 10.1021/Ic400641A  0.413
2013 Bissinger P, Braunschweig H, Damme A, Kupfer T, Radacki K. An electron-precise, tetrahedral μ3 boride complex. Angewandte Chemie (International Ed. in English). 52: 7038-41. PMID 23733377 DOI: 10.1002/Anie.201302828  0.324
2013 Arnold T, Braunschweig H, Jimenez-Halla JO, Radacki K, Sen SS. Simultaneous fragmentation and activation of white phosphorus. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 9114-7. PMID 23712610 DOI: 10.1002/Chem.201300895  0.564
2013 Bauer J, Braunschweig H, Damme A, Jimenez-Halla JO, Kramer T, Radacki K, Shang R, Siedler E, Ye Q. Metathesis reactions of a manganese borylene complex with polar heteroatom-carbon double bonds: a pathway to previously inaccessible carbene complexes. Journal of the American Chemical Society. 135: 8726-34. PMID 23692498 DOI: 10.1021/Ja403389W  0.699
2013 Braunschweig H, Damme A, Dewhurst RD, Kramer T, Kupfer T, Radacki K, Siedler E, Trumpp A, Wagner K, Werner C. Quaternizing diboranes(4): highly divergent outcomes and an inorganic Wagner-Meerwein rearrangement. Journal of the American Chemical Society. 135: 8702-7. PMID 23687934 DOI: 10.1021/Ja403037K  0.395
2013 Bauer J, Braunschweig H, Dewhurst RD, Radacki K. Reactivity of Lewis basic platinum complexes towards fluoroboranes. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 8797-805. PMID 23677702 DOI: 10.1002/Chem.201301056  0.326
2013 Braunschweig H, Ye Q, Radacki K. Synthesis and structure of a carbene-stabilized boraallene coordinated to rhodium. Inorganic Chemistry. 52: 5639-41. PMID 23631599 DOI: 10.1021/Ic4005505  0.583
2013 Braunschweig H, Damme A. Thermodynamic control of oxidative addition and reductive elimination processes in cis-bis(dimethoxyboryl)-bis(tricyclohexylphosphine)platinum(II). Chemical Communications (Cambridge, England). 49: 5216-8. PMID 23629507 DOI: 10.1039/C3Cc41444B  0.318
2013 Braunschweig H, Damme A, Kupfer T. Synthesis of a bicyclic diborane by selective boron carbon bond formation. Chemical Communications (Cambridge, England). 49: 2774-6. PMID 23439955 DOI: 10.1039/C3Cc38789E  0.321
2013 Braunschweig H, Bertermann R, Damme A, Kupfer T. A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a μ2-bridging coordination mode. Chemical Communications (Cambridge, England). 49: 2439-41. PMID 23417092 DOI: 10.1039/C3Cc38686D  0.333
2013 Braunschweig H, Dewhurst RD, Gessner VH. Transition metal borylene complexes. Chemical Society Reviews. 42: 3197-208. PMID 23403460 DOI: 10.1039/C3Cs35510A  0.635
2013 Braunschweig H, Brenner P, Dewhurst RD, Jimenez-Halla JO, Kupfer T, Rais D, Uttinger K. Maximizing coordinative and electronic unsaturation: three-coordinate dicationic platinum complexes. Angewandte Chemie (International Ed. in English). 52: 2981-4. PMID 23364920 DOI: 10.1002/Anie.201209717  0.353
2013 Braunschweig H, Dewhurst RD. Single, double, triple bonds and chains: the formation of electron-precise B-B bonds. Angewandte Chemie (International Ed. in English). 52: 3574-83. PMID 23362015 DOI: 10.1002/Anie.201208189  0.334
2013 Braunschweig H, Damme A, Dewhurst RD, Vargas A. Bond-strengthening π backdonation in a transition-metal π-diborene complex. Nature Chemistry. 5: 115-21. PMID 23344432 DOI: 10.1038/Nchem.1520  0.391
2013 Braunschweig H, Herbst T, Radacki K, Tate CW, Vargas A. Cyclic (amino)(imino)carbene complexes by borylene transfer to isocyanides. Chemical Communications (Cambridge, England). 49: 1702-4. PMID 23340804 DOI: 10.1039/C3Cc38379B  0.409
2013 Braunschweig H, Damme A, Dewhurst RD, Kramer T, Östreicher S, Radacki K, Vargas A. Ditopic ambiphilicity of an anionic dimetalloborylene complex. Journal of the American Chemical Society. 135: 2313-20. PMID 23331127 DOI: 10.1021/Ja310895W  0.416
2013 Braunschweig H, Damme A, Dewhurst RD, Ghosh S, Kramer T, Pfaffinger B, Radacki K, Vargas A. Electronic and structural effects of stepwise borylation and quaternization on borirene aromaticity. Journal of the American Chemical Society. 135: 1903-11. PMID 23305227 DOI: 10.1021/Ja3110126  0.565
2013 Bringmann G, Zhang G, Büttner T, Bauckmann G, Kupfer T, Braunschweig H, Brun R, Mudogo V. Jozimine A2: the first dimeric Dioncophyllaceae-type naphthylisoquinoline alkaloid, with three chiral axes and high antiplasmodial activity. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 916-23. PMID 23225585 DOI: 10.1002/Chem.201202755  0.343
2013 Braunschweig H, Breher F, Capper S, Dück K, Fuß M, Jimenez-Halla JO, Krummenacher I, Kupfer T, Nied D, Radacki K. Heteroleptic [n]chromoarenophanes: ansa complexes derived from [Cr(η(5)-C5H5)(η(6)-C6H6)]. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 270-81. PMID 23180426 DOI: 10.1002/Chem.201203288  0.442
2013 Braunschweig H, Radacki K, Shang R, Tate CW. Reversible intramolecular coupling of the terminal borylene and a carbonyl ligand of [Cp(CO)2Mn=B-tBu]. Angewandte Chemie (International Ed. in English). 52: 729-33. PMID 23165638 DOI: 10.1002/Anie.201207017  0.632
2013 Braunschweig H, Brenner PB, Dewhurst RD, Radacki K. A Base-stabilized Iodoborylene Complex of Platinum(II) Zeitschrift FüR Naturforschung B. 68: 747-749. DOI: 10.5560/Znb.2013-3079  0.397
2013 Rammo A, Bejan I, Meltzer A, Radacki K, Braunschweig H, Scheschkewitz D. 1,2-Disilabicyclo[1.1.1]pentan-4-ones from a Disilenide and Acryloyl Chlorides Australian Journal of Chemistry. 66: 1311. DOI: 10.1071/Ch13265  0.614
2013 Arnold T, Braunschweig H, Damme A, Krummenacher I, Radacki K. Synthesis and Structure of Group IV Distanna[2]metallocenophanes Organometallics. 33: 254-259. DOI: 10.1021/Om400993G  0.378
2013 Braunschweig H, Maier J, Radacki K, Wahler J. Ring expansion of 7-boranorbornadienes by coordination with an N-heterocyclic carbene Organometallics. 32: 6353-6359. DOI: 10.1021/Om400708Y  0.406
2013 Braunschweig H, Damme A, Hörl C, Kupfer T, Wahler J. Si-H bond activation at the boron center of pentaphenylborole Organometallics. 32: 6800-6803. DOI: 10.1021/Om4005934  0.345
2013 Braunschweig H, Krummenacher I, Wahler J. Free Boroles. The Effect of Antiaromaticity on Their Physical Properties and Chemical Reactivity Advances in Organometallic Chemistry. 61: 1-53. DOI: 10.1016/B978-0-12-407692-1.00001-1  0.312
2013 Braunschweig H, Brenner P, Radacki K. Wolfphos in sheep's clothing: The first trinuclear triboryl- and other boryl platinum complexes featuring a flexible phosphine ligand Zeitschrift Fur Anorganische Und Allgemeine Chemie. 639: 1129-1133. DOI: 10.1002/Zaac.201200556  0.395
2013 Arnold T, Braunschweig H, Hupp F, Radacki K, Sen SS. Reactions of a [1],[1]Disilamolybdenocenophane with Unsaturated Compounds European Journal of Inorganic Chemistry. 2013: 5027-5032. DOI: 10.1002/Ejic.201300766  0.685
2013 Braunschweig H, Chiu CW, Gamon D, Gruß K, Hörl C, Kupfer T, Radacki K, Wahler J. Lewis acid-base adducts of 1-mesityl- and 1-chloro-2,3,4,5- tetraphenylborole European Journal of Inorganic Chemistry. 1525-1530. DOI: 10.1002/Ejic.201201383  0.358
2013 Braunschweig H, Dyakonov V, Engels B, Falk Z, Hörl C, Klein JH, Kramer T, Kraus H, Krummenacher I, Lambert C, Walter C. Mehrfache Reduktion von 2,5-Bis(borolyl)thiophen: Isolierung eines negativen Bipolarons durch Komproportionierung Angewandte Chemie. 125: 13088-13092. DOI: 10.1002/Ange.201306969  0.344
2013 Braunschweig H, Ye Q, Vargas A, Radacki K, Damme A. Phosphan-induzierte Verkettung von :BR und CO an einem Eisenatom Angewandte Chemie. 125: 10851-10854. DOI: 10.1002/Ange.201304972  0.339
2012 Braunschweig H, Damme A, Jimenez-Halla JO, Hörl C, Krummenacher I, Kupfer T, Mailänder L, Radacki K. 1-Heteroaromatic-substituted tetraphenylboroles: π-π interactions between aromatic and antiaromatic rings through a B-C bond. Journal of the American Chemical Society. 134: 20169-77. PMID 23171432 DOI: 10.1021/Ja309935T  0.38
2012 Braunschweig H, Damme A, Kupfer T. Evidence for a strong trans influence of the diboran(4)yl ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 15927-31. PMID 23138869 DOI: 10.1002/Chem.201203220  0.396
2012 Braunschweig H, Chiu CW, Damme A, Engels B, Gamon D, Hörl C, Kupfer T, Krummenacher I, Radacki K, Walter C. Oligo(borolyl)benzenes--synthesis and properties. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14292-304. PMID 23019113 DOI: 10.1002/Chem.201202345  0.385
2012 Bagh B, Breit NC, Harms K, Schatte G, Burgess IJ, Braunschweig H, Müller J. [1.1]Ferrocenophanes and bis(ferrocenyl) species with aluminum and gallium as bridging elements: synthesis, characterization, and electrochemical studies. Inorganic Chemistry. 51: 11155-67. PMID 23009679 DOI: 10.1021/Ic301777Y  0.57
2012 Braunschweig H, Damme A, Dewhurst RD, Hupp F, Jimenez-Halla JO, Radacki K. σ-Donor-σ-acceptor plumbylene ligands: synergic σ-donation between ambiphilic Pt(0) and Pb(II) fragments. Chemical Communications (Cambridge, England). 48: 10410-2. PMID 22992759 DOI: 10.1039/C2Cc35777A  0.373
2012 Bauer J, Braunschweig H, Radacki K. Transmetallation between metal-only Lewis pairs: a new rhodium alane complex. Chemical Communications (Cambridge, England). 48: 10407-9. PMID 22990068 DOI: 10.1039/C2Cc35248F  0.371
2012 Bauer J, Braunschweig H, Damme A, Radacki K. Reversible insertion of platinum into coinage group metal-halogen bonds. Angewandte Chemie (International Ed. in English). 51: 10030-3. PMID 22961701 DOI: 10.1002/Anie.201205438  0.328
2012 Braunschweig H, Damme A, Jimenez-Halla JO, Pfaffinger B, Radacki K, Wolf J. Metal-mediated synthesis of 1,4-di-tert-butyl-1,4-azaborine. Angewandte Chemie (International Ed. in English). 51: 10034-7. PMID 22952191 DOI: 10.1002/Anie.201205795  0.314
2012 Bissinger P, Braunschweig H, Damme A, Kupfer T, Vargas A. Base-stabilized diborenes: selective generation and η2 side-on coordination to silver(I). Angewandte Chemie (International Ed. in English). 51: 9931-4. PMID 22945511 DOI: 10.1002/Anie.201204449  0.406
2012 Braunschweig H, Chiu CW, Gamon D, Kaupp M, Krummenacher I, Kupfer T, Müller R, Radacki K. Synthesis, structure, and reactivity of borole-functionalized ferrocenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 11732-46. PMID 22886835 DOI: 10.1002/Chem.201201317  0.32
2012 Braunschweig H, Ye Q, Radacki K, Damme A. Borylene transfer from an iron bis(borylene) complex: synthesis of 1,4-diboracyclohexadiene and 1,4-dibora-1,3-butadiene complexes. Angewandte Chemie (International Ed. in English). 51: 7839-42. PMID 22730188 DOI: 10.1002/Anie.201202764  0.554
2012 Arnold N, Braunschweig H, Damme A. Bis(μ-diisopropyl-phosphanido-κ(2)P:P)bis-[hydrido(triisopropyl-phosphane-κP)platinum(II)]. Acta Crystallographica. Section E, Structure Reports Online. 68: m808. PMID 22719354 DOI: 10.1107/S1600536812022829  0.34
2012 Braunschweig H, Ye Q, Vargas A, Dewhurst RD, Radacki K, Damme A. Controlled homocatenation of boron on a transition metal. Nature Chemistry. 4: 563-7. PMID 22717442 DOI: 10.1038/Nchem.1379  0.578
2012 Braunschweig H, Brenner P, Dewhurst RD, Guethlein F, Jimenez-Halla JO, Radacki K, Wolf J, Zöllner L. Observation of elementary steps in the catalytic borane dehydrocoupling reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8605-9. PMID 22706916 DOI: 10.1002/Chem.201201739  0.308
2012 Braunschweig H, Dewhurst RD, Hammond K, Mies J, Radacki K, Vargas A. Ambient-temperature isolation of a compound with a boron-boron triple bond. Science (New York, N.Y.). 336: 1420-2. PMID 22700924 DOI: 10.1126/Science.1221138  0.374
2012 Braunschweig H, Brenner P, Dewhurst RD, Krummenacher I, Pfaffinger B, Vargas A. Unsupported boron-carbon σ-coordination to platinum as an isolable snapshot of σ-bond activation. Nature Communications. 3: 872. PMID 22643899 DOI: 10.1038/Ncomms1884  0.432
2012 Braunschweig H, Damme A, Gamon D, Kelch H, Krummenacher I, Kupfer T, Radacki K. Synthesis, coordination behavior, and reduction chemistry of cymantrenyl-1,3-bis(2,3,4,5-tetraphenyl)borole. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8430-6. PMID 22639411 DOI: 10.1002/Chem.201200284  0.335
2012 Bauer J, Bertermann R, Braunschweig H, Gruss K, Hupp F, Kramer T. New metal-only Lewis pairs: elucidating the electronic influence of N-heterocyclic carbenes and phosphines on the dative Pt-Al bond. Inorganic Chemistry. 51: 5617-26. PMID 22548527 DOI: 10.1021/Ic300531B  0.401
2012 Fischer KH, Schneider M, Fischer I, Pfaffinger B, Braunschweig H, Sztáray B, Bodi A. Bonding in a borylene complex investigated by photoionization and dissociative photoionization. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 4533-40. PMID 22422725 DOI: 10.1002/Chem.201103993  0.351
2012 Braunschweig H, Dyakonov V, Jimenez-Halla JO, Kraft K, Krummenacher I, Radacki K, Sperlich A, Wahler J. An isolable radical anion based on the borole framework. Angewandte Chemie (International Ed. in English). 51: 2977-80. PMID 22334371 DOI: 10.1002/Anie.201108632  0.415
2012 Braunschweig H, Ye Q, Radacki K. High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex. Chemical Communications (Cambridge, England). 48: 2701-3. PMID 22301941 DOI: 10.1039/c2cc17445f  0.489
2012 Bauer J, Braunschweig H, Dewhurst RD, Kraft K, Radacki K. Monohaloboryls (BHX-) as bridging ligands: observable dinuclear σ-(halo)boranyl intermediates in the synthesis of metalloborylenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 2327-34. PMID 22267281 DOI: 10.1002/Chem.201103163  0.416
2012 Braunschweig H, Dewhurst RD, Kraft K, Ostreicher S, Radacki K. Planar four-coordinate boron: a single, flat boron atom as a ligand for four metals. Angewandte Chemie (International Ed. in English). 51: 2183-6. PMID 22253194 DOI: 10.1002/Anie.201107248  0.335
2012 Braunschweig H, Dörfler R, Hammond K, Kramer T, Mies J, Radacki K, Schäfer M. Synthesis and structure of distanna and tristanna ansa half-sandwich complexes of ruthenium and nickel. Inorganic Chemistry. 51: 1225-7. PMID 22243038 DOI: 10.1021/Ic202512Y  0.377
2012 Braunschweig H, Damme A, Mies J, Schäfer M. Insertion of chalcogens and bis(tert-butylisonitrile)palladium(0) into a strained ruthenium half-sandwich complex Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 67: 1173-1177. DOI: 10.5560/Znb.2012-0242  0.374
2012 Braunschweig H, Ye Q, Radacki K. High yield synthesis of a neutral and carbonyl-rich terminal arylborylene complex Chemical Communications. 48: 2701-2703. DOI: 10.1039/C2Cc17445F  0.535
2012 Braunschweig H, Hörl C, Hupp F, Radacki K, Wahler J. Borole-Derived Spirocyclic Tetraorganoborate Organometallics. 31: 8463-8466. DOI: 10.1021/Om301070Q  0.377
2012 Braunschweig H, Damme A, Hammond K, Mager J. Synthesis and structure of new [3]silametallocenophanes of group 8 metals Organometallics. 31: 6317-6321. DOI: 10.1021/Om300564Y  0.335
2012 Arnold N, Braunschweig H, Brenner P, Jimenez-Halla JOC, Kupfer T, Radacki K. Reactivity of boryl complexes: Synthesis and structure of new neutral and cationic platinum boryls and borylenes Organometallics. 31: 1897-1907. DOI: 10.1021/Om2012248  0.433
2012 Braunschweig H, Friedrich M, Radacki K, Wolf J. Synthesis and reactivity of palladium- and platinum-bridged heterobimetallic [3]trochrocenophanes Organometallics. 31: 3027-3034. DOI: 10.1021/Om201119V  0.376
2012 Bauer J, Braunschweig H, Dewhurst RD. Metal-only lewis pairs with transition metal lewis bases Chemical Reviews. 112: 4329-4346. DOI: 10.1021/Cr3000048  0.349
2012 Braunschweig H, Claes C, Guethlein F. Dehydrocoupling of catecholborane catalyzed by group 4 compounds Journal of Organometallic Chemistry. 706: 144-145. DOI: 10.1016/J.Jorganchem.2012.02.004  0.376
2012 Braunschweig H, Dörfler R, Mies J, Radacki K, Schmitt M. Iron ansa half sandwich complexes bearing a bridging distannadiyl moiety Journal of Organometallic Chemistry. 699: 26-30. DOI: 10.1016/J.Jorganchem.2011.11.002  0.371
2012 Braunschweig H, Kupfer T. [n]Borametalloarenophanes (n = 1, 2): Strained systems with uncommon reactivity patterns European Journal of Inorganic Chemistry. 1319-1332. DOI: 10.1002/Ejic.201100609  0.368
2012 Fischer KH, Schneider M, Fischer I, Pfaffinger B, Braunschweig H, Sztáray B, Bodi A. Cover Picture: Bonding in a Borylene Complex Investigated by Photoionization and Dissociative Photoionization (Chem. Eur. J. 15/2012) Chemistry - a European Journal. 18: 4437-4437. DOI: 10.1002/Chem.201290055  0.361
2012 Braunschweig H, Radacki K, Shang R, Tate CW. Reversible intramolekulare Kupplung von terminalen Borylen- und Carbonylliganden in [Cp(CO)2MnB-tBu] Angewandte Chemie. 125: 757-761. DOI: 10.1002/Ange.201207017  0.527
2012 Braunschweig H, Damme A, Jimenez-Halla JOC, Pfaffinger B, Radacki K, Wolf J. Metall-vermittelte Synthese von 1,4-Di-tert-butyl-1,4-azaborin Angewandte Chemie. 124: 10177-10180. DOI: 10.1002/Ange.201205795  0.321
2012 Bissinger P, Braunschweig H, Damme A, Kupfer T, Vargas A. Selektive Herstellung Basen-stabilisierter Diborene und deren η2-Side-on-Koordination an Silber(I) Angewandte Chemie. 124: 10069-10073. DOI: 10.1002/Ange.201204449  0.327
2012 Braunschweig H, Dewhurst RD, Kraft K, Östreicher S, Radacki K. Ein planar vierfach koordiniertes Boratom als Ligand für vier Metalle Angewandte Chemie. 124: 2225-2228. DOI: 10.1002/Ange.201107248  0.306
2011 Braunschweig H, Guethlein F. Transition-metal-catalyzed synthesis of diboranes(4) Angewandte Chemie - International Edition. 50: 12613-12616. PMID 22057739 DOI: 10.1002/Anie.201104854  0.377
2011 Bauer J, Braunschweig H, Damme A, Gruss K, Radacki K. Extending unsupported metal-only Lewis pairs to palladium. Chemical Communications (Cambridge, England). 47: 12783-5. PMID 22048659 DOI: 10.1039/C1Cc15561J  0.382
2011 Bissinger P, Braunschweig H, Damme A, Dewhurst RD, Kupfer T, Radacki K, Wagner K. Generation of a carbene-stabilized bora-borylene and its insertion into a C-H bond. Journal of the American Chemical Society. 133: 19044-7. PMID 22032808 DOI: 10.1021/Ja208372K  0.348
2011 Braunschweig H, Bertermann R, Brenner P, Burzler M, Dewhurst RD, Radacki K, Seeler F. trans-[Pt(BCat')Me(PCy3)2]: an experimental case study of reductive elimination processes in Pt-Boryls through associative mechanisms. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 11828-37. PMID 21901774 DOI: 10.1002/Chem.201101823  0.394
2011 Braunschweig H, Ye Q, Damme A, Kupfer T, Radacki K, Wolf J. Synthesis of 1-aza-2-borabutatriene rhodium complexes by thermal borylene transfer from [(OC)5Mo=BN(SiMe3)2]. Angewandte Chemie (International Ed. in English). 50: 9462-6. PMID 21882319 DOI: 10.1002/Anie.201104026  0.556
2011 Adams CJ, Braunschweig H, Fuss M, Kraft K, Kupfer T, Manners I, Radacki K, Whittell GR. Syntheses of Group 4 ansa-trovacene complexes and conversion of [1]silatrovacenophanes into paramagnetic metallopolymers by ring-opening polymerization. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 10379-87. PMID 21812040 DOI: 10.1002/Chem.201100919  0.512
2011 Braunschweig H, Dewhurst RD, Kraft K, Radacki K. Borido complexes via intermetallic metalloborylene transfer. Chemical Communications (Cambridge, England). 47: 9900-2. PMID 21808766 DOI: 10.1039/C1Cc13444B  0.379
2011 Arnold T, Braunschweig H, Gruss K. cyclo-Tri-μ-oxido-tris-{[(η,η)-1,2-bis-(cyclo-penta-dien-yl)-1,1,2,2-tetra-methyl-disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene. Acta Crystallographica. Section E, Structure Reports Online. 67: m391. PMID 21753927 DOI: 10.1107/S1600536811007094  0.349
2011 Braunschweig H, Kupfer T. Recent developments in the chemistry of antiaromatic boroles. Chemical Communications (Cambridge, England). 47: 10903-14. PMID 21735004 DOI: 10.1039/C1Cc13071D  0.31
2011 Braunschweig H, Damme A, Kupfer T. Unexpected bonding mode of the diboran(4)yl ligand: combining the boryl motif with a dative Pt-B interaction. Angewandte Chemie (International Ed. in English). 50: 7179-82. PMID 21681878 DOI: 10.1002/Anie.201102593  0.333
2011 Safont-Sempere MM, Osswald P, Stolte M, Grüne M, Renz M, Kaupp M, Radacki K, Braunschweig H, Würthner F. Impact of molecular flexibility on binding strength and self-sorting of chiral π-surfaces. Journal of the American Chemical Society. 133: 9580-91. PMID 21553857 DOI: 10.1021/Ja202696D  0.31
2011 Braunschweig H, Damme A, Gamon D, Kupfer T, Radacki K. Synthesis and coordination chemistry of 1-cymantrenyl-2,3,4,5-tetraphenylborole. Inorganic Chemistry. 50: 4250-2. PMID 21506525 DOI: 10.1021/Ic200559D  0.344
2011 Braunschweig H, Chiu CW, Kupfer T, Radacki K. NHC-stabilized 1-hydro-1H-borole and its nondegenerate sigmatropic isomers. Inorganic Chemistry. 50: 4247-9. PMID 21480647 DOI: 10.1021/Ic200533E  0.337
2011 Braunschweig H, Fuss M, Kupfer T, Radacki K. Selective dilithiation of [Ti(η(5)-C5H5)(η(8)-C8H8)] and subsequent conversion into neutral and cationic ansa-complexes. Journal of the American Chemical Society. 133: 5780-3. PMID 21443202 DOI: 10.1021/Ja2014218  0.38
2011 Braunschweig H, Ghosh S, Kupfer T, Radacki K, Wahler J. High-yield synthesis of a hybrid 2,3,4,5-tetracarba-1,6-nido-hexaborane(6) cluster with an exo-polyhedral boracycle. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 4081-4. PMID 21400622 DOI: 10.1002/Chem.201100453  0.513
2011 Braunschweig H, Friedrich M, Kupfer T, Radacki K. Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers. Chemical Communications (Cambridge, England). 47: 3998-4000. PMID 21336343 DOI: 10.1039/C1Cc10207A  0.316
2011 Braunschweig H, Ye Q, Radacki K, Kupfer T. Reactivity of a platinum-substituted borirene. Dalton Transactions (Cambridge, England : 2003). 40: 3666-70. PMID 21331418 DOI: 10.1039/C0Dt01694B  0.598
2011 Bertsch S, Braunschweig H, Forster M, Gruss K, Radacki K. Carbonyl complexes of platinum(0): synthesis and structure of [(Cy3P)2Pt(CO)] and [(Cy3P)2Pt(CO)2]. Inorganic Chemistry. 50: 1816-9. PMID 21265543 DOI: 10.1021/Ic102200T  0.346
2011 Pandey KK, Braunschweig H, Lledós A. Nature of bonding in terminal borylene, alylene, and gallylene complexes of vanadium and niobium [(η(5)-C5H5)(CO)3M(ENR2)] (M = V, Nb; E = B, Al, Ga; R = CH3, SiH3, CMe3, SiMe3): a DFT study. Inorganic Chemistry. 50: 1402-10. PMID 21188983 DOI: 10.1021/Ic1019718  0.387
2011 Bertsch S, Braunschweig H, Christ B, Forster M, Schwab K, Radacki K. Towards homoleptic borylene complexes: incorporation of two borylene ligands into a mononuclear iridium species. Angewandte Chemie (International Ed. in English). 49: 9517-20. PMID 21053226 DOI: 10.1002/Anie.201004103  0.329
2011 Braunschweig H, Ye Q, Radacki K, Brenner P, Frenking G, De S. Borylene-based functionalization of iron-alkynyl-σ-complexes and stepwise reversible metal-boryl-to-borirene transformation: synthesis, characterization, and density functional theory studies. Inorganic Chemistry. 50: 62-71. PMID 20712372 DOI: 10.1021/Ic1010874  0.577
2011 Braunschweig H, Kraft K, Ostreicher S, Radacki K, Seeler F. Neutral and anionic transition-metal-base-stabilized metalloborylene complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 10635-7. PMID 20687150 DOI: 10.1002/Chem.201001368  0.343
2011 Braunschweig H, Gruß K. Synthesis and Structural Characterization of the Dinuclear Beryllium Species [Be2Cl2(μ-Cl)2(PCy3)2] Zeitschrift FüR Naturforschung B. 66: 55-57. DOI: 10.1515/Znb-2011-0109  0.348
2011 Braunschweig H, Dewhurst RD. Transition metals as Lewis bases: "z-Type" boron ligands and metal-to-boron dative bonding Dalton Transactions. 40: 549-558. DOI: 10.1039/C0Dt01181A  0.38
2011 Braunschweig H, Drisch M, Friedrich M, Kupfer T, Radacki K. Metal-enriched [3]trochrocenophanes: Bimetallic metalloarenophanes by coordination to chelating bis(phosphanyls) Organometallics. 30: 5202-5207. DOI: 10.1021/Om200577B  0.409
2011 Braunschweig H, Chiu CW, Damme A, Ferkinghoff K, Kraft K, Radacki K, Wahler J. Unwinding antiaromaticity in 1-bromo-2,3,4,5-tetraphenylborole Organometallics. 30: 3210-3216. DOI: 10.1021/Om200315P  0.373
2011 Bauer F, Braunschweig H, Gruss K, Kupfer T. Diboration of dialkynes with [2]boraferrocenophanes Organometallics. 30: 2869-2884. DOI: 10.1021/Om200214W  0.321
2011 Braunschweig H, Dörfler R, Gruss K, Köhler J, Radacki K. Insertion vs Ligand Exchange: Reactivity of DistannaAnsaHalf-Sandwich Complexes of Molybdenum and Tungsten toward Isocyanide and Phosphine Complexes of Nickel and Palladium Organometallics. 30: 305-312. DOI: 10.1021/Om101049D  0.361
2011 Braunschweig H, Gross M, Kraft K. Synthesis and reactivity of [2]disilaniobocenophanes Journal of Organometallic Chemistry. 696: 568-571. DOI: 10.1016/J.Jorganchem.2010.09.027  0.332
2011 Braunschweig H, Cogswell P, Schwab K. Synthesis, structure and reactivity of complexes containing a transition metal-bismuth bond Coordination Chemistry Reviews. 255: 101-117. DOI: 10.1016/J.Ccr.2010.07.002  0.399
2011 Braunschweig H, Dörfler R, Gruß K, Radacki K. Synthesis and reactivity of a dilithiated molybdenum half-sandwich complex Zeitschrift Fur Anorganische Und Allgemeine Chemie. 637: 381-385. DOI: 10.1002/Zaac.201000376  0.42
2011 Pandey KK, Braunschweig H, Dewhurst RD. DFT study on alkyl- and haloborylene complexes of manganese and rhenium: Structure and bonding energy analysis in [(n5-C5H 5)(CO)2M(BR)] and [(n5-C5H 5)(CO)2M(BX)] (M = Mn, Re; R = Me, Et, iPr, tBu; X = F, Cl, Br, I) European Journal of Inorganic Chemistry. 2045-2056. DOI: 10.1002/Ejic.201001200  0.418
2011 Braunschweig H, Dörfler R, Mies J, Oechsner A. Sterically demanding hetero-substituted [2]borametallocenophanes of group IV metals: Synthesis, structure and reactivity Chemistry - a European Journal. 17: 12101-12107. DOI: 10.1002/Chem.201101774  0.384
2011 Braunschweig H, Guethlein F. Übergangsmetall-katalysierte Synthese von Diboranen(4) Angewandte Chemie. 123: 12821-12824. DOI: 10.1002/Ange.201104854  0.314
2011 Braunschweig H, Ye Q, Damme A, Kupfer T, Radacki K, Wolf J. Synthese von 1-Aza-2-borabutatrien-Rhodiumkomplexen durch thermischen Borylentransfer von [(OC)5MoBN(SiMe3)2] Angewandte Chemie. 123: 9634-9638. DOI: 10.1002/Ange.201104026  0.333
2010 Braunschweig H, Breher F, Chiu CW, Gamon D, Nied D, Radacki K. The reduction chemistry of ferrocenylborole. Angewandte Chemie (International Ed. in English). 49: 8975-8. PMID 20941718 DOI: 10.1002/Anie.201003611  0.302
2010 Braunschweig H, Chiu CW, Wahler J, Radacki K, Kupfer T. Chemical reduction and dimerization of 1-chloro-2,3,4,5-tetraphenylborole. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 12229-33. PMID 20839188 DOI: 10.1002/Chem.201001556  0.373
2010 Bauer J, Braunschweig H, Brenner P, Kraft K, Radacki K, Schwab K. Late-transition-metal complexes as tunable Lewis bases. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 11985-92. PMID 20836094 DOI: 10.1002/Chem.201001228  0.423
2010 Braunschweig H, Fuß M, Mohapatra SK, Kraft K, Kupfer T, Lang M, Radacki K, Daniliuc CG, Jones PG, Tamm M. Synthesis and reactivity of boron-, silicon-, and tin-bridged ansa-cyclopentadienyl-cycloheptatrienyl titanium complexes (troticenophanes). Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 11732-43. PMID 20803585 DOI: 10.1002/Chem.201001486  0.399
2010 Braunschweig H, Chiu CW, Radacki K, Kupfer T. Synthesis and structure of a carbene-stabilized pi-boryl anion. Angewandte Chemie (International Ed. in English). 49: 2041-4. PMID 20157901 DOI: 10.1002/Anie.200906884  0.303
2010 Arnold T, Braunschweig H, Gross M, Kaupp M, Müller R, Radacki K. Electronic structure and reactivity of a [1],[1]disilamolybdenocenophane. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 3014-20. PMID 20146271 DOI: 10.1002/Chem.200902883  0.346
2010 Braunschweig H, Chiu CW, Radacki K, Brenner P. Platinum substituted boroles. Chemical Communications (Cambridge, England). 46: 916-8. PMID 20107649 DOI: 10.1039/B923652J  0.349
2010 Braunschweig H, Kupfer T. Non-iron [n]metalloarenophanes. Accounts of Chemical Research. 43: 455-65. PMID 19957950 DOI: 10.1021/Ar900234Z  0.431
2010 Braunschweig H, Radacki K, Kraft K, Stellwag S. Molybdenum-Boron Bonds in the Crystal – Structural Characterization of K[(η5-C5H5)Mo(CO)3] and[(η5-C5H5) (OC)3Mo-{B(NMe2)-B(NMe2)Br}] Zeitschrift FüR Naturforschung B. 65: 1073-1076. DOI: 10.1515/Znb-2010-0903  0.377
2010 Braunschweig H, Radacki K, Schneider A. Oxoboryl complexes: Boron-oxygen triple bonds stabilized in the coordination sphere of platinum Science. 328: 345-347. DOI: 10.1126/Science.1186028  0.359
2010 Braunschweig H, Radacki K, Schneider A. Reactivity of an oxoboryl complex toward fluorinated aryl boron reagents Chemical Communications. 46: 6473-6475. DOI: 10.1039/C0Cc01802C  0.395
2010 Braunschweig H, Brenner P, Cogswell P, Kraft K, Schwab K. Oxidative addition of the bismuth-chloride bond: Synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}] Chemical Communications. 46: 7894-7896. DOI: 10.1039/C0Cc00639D  0.35
2010 Braunschweig H, Radacki K, Schwab K. An early-late heterobimetallic complex with an unsupported dative bond: Synthesis and structure of [(Cy3P)2Pt-ZrCl4] Chemical Communications. 46: 913-915. DOI: 10.1039/B921608A  0.368
2010 Bauer F, Braunschweig H, Schwab K. 1,1-diboration of isocyanides with [2] borametalloarenophanes Organometallics. 29: 934-938. DOI: 10.1021/Om9009813  0.336
2010 Bissinger P, Braunschweig H, Kupfer T, Radacki K. Monoborane NHC adducts in the coordination sphere of transition metals Organometallics. 29: 3987-3990. DOI: 10.1021/Om100634B  0.411
2010 Braunschweig H, Matz F, Radacki K, Schneider A. Reactivity of platinum iminoboryl complexes toward covalent element-hydrogen bonds of opposing polarity Organometallics. 29: 3457-3462. DOI: 10.1021/Om1004868  0.399
2010 Bera H, Braunschweig H, Dörfler R, Kupfer T, Radacki K, Seeler F. Half-sandwich tungsten complexes with metal-and η5- cyclopentadienyl-bound functional stannyl groups and their transformation into ansa complexes Organometallics. 29: 5111-5120. DOI: 10.1021/Om100324M  0.403
2010 Braunschweig H, Brenner P, Gross M, Radacki K. Reactivity of [1],[1] Disilamolybdenocenophane toward zerovalent platinum complexes Journal of the American Chemical Society. 132: 11343-11349. DOI: 10.1021/Ja1049548  0.41
2010 Pandey KK, Patidar P, Braunschweig H. Structure and bonding energy analysis of M-Ga bonds in dihalogallyl complexes frans-[X(PMe3)2M(GaX2)] (M = Ni, Pd, Pt; X = Cl, Br, I) Inorganic Chemistry. 49: 6994-7000. DOI: 10.1021/Ic1005506  0.351
2010 Braunschweig H, Dewhurst RD, Schneider A. Electron-precise coordination modes of boron-centered ligands Chemical Reviews. 110: 3924-3957. DOI: 10.1021/Cr900333N  0.425
2010 Bera H, Braunschweig H, Oechsner A, Seeler F, Sigritz R. Synthesis of a distanna [2]ferrocenophane and reactivity of [2]ferrocenophanes towards elemental sulfur and selenium Journal of Organometallic Chemistry. 695: 2609-2613. DOI: 10.1016/J.Jorganchem.2010.08.028  0.336
2010 Braunschweig H, Kraft K, Kupfer T, Siedler E. Manganese-σ-borane complexes from dihaloboranes Zeitschrift Fur Anorganische Und Allgemeine Chemie. 636: 2565-2567. DOI: 10.1002/Zaac.201000244  0.378
2010 Köhler J, Lindenmeier S, Fischer I, Braunschweig H, Kupfer T, Gamon D, Chiu CW. Probing antiaromaticity: Resonance Raman investigation of a series of differently substituted boroles Journal of Raman Spectroscopy. 41: 636-641. DOI: 10.1002/Jrs.2491  0.303
2010 Braunschweig H, Dörfler R, Hammond K, Mies J, Radacki K. Synthesis and Structure of Trisilane-1,3-diyl ansa Half-Sandwich Complexes of Group 6 Metals European Journal of Inorganic Chemistry. 2010: 5383-5385. DOI: 10.1002/Ejic.201000965  0.415
2010 Braunschweig H, Damme A, Kupfer T. New [2]Boraferrocenophane and Diferrocenyldiborane(4) Derivatives European Journal of Inorganic Chemistry. 4423-4426. DOI: 10.1002/Ejic.201000705  0.388
2010 BRAUNSCHWEIG H, HITCHCOCK PB, LAPPERT MF, PIERSSENS LJ. ChemInform Abstract: Synthesis, Structures, and Reactions of Two Bis(diaminostannylene)s and a Bis(diaminogermylene) Containing a Central C6 Ring. Cheminform. 25: no-no. DOI: 10.1002/chin.199444193  0.421
2010 BRAUNSCHWEIG H, MANNERS I, PAETZOLD P. ChemInform Abstract: The Reaction of (Butadiene)zirconocene with Iminoborane. Cheminform. 22: no-no. DOI: 10.1002/chin.199104281  0.383
2010 Braunschweig H, Radacki K, Schneider A. Cyclodimerization of an oxoboryl complex induced by trans ligand abstraction Angewandte Chemie - International Edition. 49: 5993-5996. DOI: 10.1002/Anie.201002300  0.374
2010 Braunschweig H, Dewhurst RD. Fashionably late: Synthesis and characterization of transition-metal- fluoroborylene complexes Angewandte Chemie - International Edition. 49: 3412-3414. DOI: 10.1002/Anie.201000841  0.349
2010 Braunschweig H, Dewhurst R. Spät aber mit Stil: Synthese und Charakterisierung der ersten Übergangsmetall-Fluorborylenkomplexe Angewandte Chemie. 122: 3486-3488. DOI: 10.1002/Ange.201000841  0.311
2010 Braunschweig H, Chiu C, Radacki K, Kupfer T. Synthese und Struktur eines Carben-stabilisierten π-Boryl-Anions Angewandte Chemie. 122: 2085-2088. DOI: 10.1002/Ange.200906884  0.382
2009 Breuning M, Häuser T, Mehler C, Däschlein C, Strohmann C, Oechsner A, Braunschweig H. Enantioselective synthesis of tricyclic amino acid derivatives based on a rigid 4-azatricyclo[5.2.1.0]decane skeleton. Beilstein Journal of Organic Chemistry. 5: 81. PMID 20300505 DOI: 10.3762/Bjoc.5.81  0.494
2009 Braunschweig H, Brenner P, Dewhurst RD, Kaupp M, Müller R, Ostreicher S. A trimetallic gold boride complex with a fluxional gold-boron bond. Angewandte Chemie (International Ed. in English). 48: 9735-8. PMID 19924750 DOI: 10.1002/Anie.200904774  0.351
2009 Braunschweig H, Ye Q, Radacki K. Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)(5)Cr=BN(SiMe(3))(2)]. Chemical Communications (Cambridge, England). 6979-81. PMID 19904367 DOI: 10.1039/b915926f  0.544
2009 Braunschweig H, Herbst T, Radacki K, Frenking G, Celik MA. Chemoselective boron-carbon bond cleavage by hydroboration of borirenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 12099-106. PMID 19780118 DOI: 10.1002/Chem.200901749  0.367
2009 Bera H, Braunschweig H, Dörfler R, Hammond K, Oechsner A, Radacki K, Uttinger K. Synthesis, structure and reactivity of disila- and distanna ansa half-sandwich complexes of molybdenum and tungsten. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 12092-8. PMID 19780110 DOI: 10.1002/Chem.200901422  0.396
2009 Braunschweig H, Dewhurst RD, Kraft K, Radacki K. Low-coordinate boride ligands: a true trimetalloborane. Angewandte Chemie (International Ed. in English). 48: 5837-40. PMID 19585627 DOI: 10.1002/Anie.200901211  0.3
2009 Braunschweig H, Christ B, Colling-Hendelkens M, Forster M, Götz K, Kaupp M, Radacki K, Seeler F. Synthesis, structure, and bonding of novel homodinuclear cobalt and nickel borylene complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 7150-5. PMID 19544503 DOI: 10.1002/Chem.200900679  0.422
2009 Braunschweig H, Herbst T, Rais D, Ghosh S, Kupfer T, Radacki K, Crawford AG, Ward RM, Marder TB, Fernández I, Frenking G. Borylene-based direct functionalization of organic substrates: synthesis, characterization, and photophysical properties of novel pi-conjugated borirenes. Journal of the American Chemical Society. 131: 8989-99. PMID 19480461 DOI: 10.1021/Ja902198Z  0.587
2009 Braunschweig H, Gruss K, Radacki K. Complexes with dative bonds between d- and s-block metals: synthesis and structure of [(Cy3P)2Pt-Be(Cl)X] (X = Cl, Me). Angewandte Chemie (International Ed. in English). 48: 4239-41. PMID 19415703 DOI: 10.1002/anie.200900521  0.319
2009 Götz K, Kaupp M, Braunschweig H, Stalke D. Comparative analysis of electron-density and electron-localization function for dinuclear manganese complexes with bridging boron- and carbon-centered ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 623-32. PMID 19040224 DOI: 10.1002/Chem.200801073  0.391
2009 Braunschweig H, Ye Q, Radacki K. Borylene-based functionalization of Pt-alkynyl complexes by photochemical borylene transfer from [(OC)5CrBN(SiMe3)2] Chemical Communications. 6979-6981. DOI: 10.1039/B915926F  0.586
2009 Braunschweig H, Dörfler R, Mager J, Radacki K, Seeler F. Structural characterization of the anionic halfsandwich complex [Li (TMEDA)2] [Mo (η5 - C5 H5) (CO)3] and its reactivity towards stannanes and distannanes Journal of Organometallic Chemistry. 694: 1134-1137. DOI: 10.1016/J.Jorganchem.2008.10.028  0.363
2009 Ketkov SY, Isachenkov NA, Braunschweig H, Kupfer T. Electronic structures of mixed sandwich ansa-complexes of chromium as studied by Gas-phase absorption spectroscopy and quantum chemistry Russian Chemical Bulletin. 58: 682-690. DOI: 10.1007/S11172-009-0079-2  0.321
2009 Braunschweig H, Brenner P, Radacki K. A bromide-bridged platinum(II) complex as precursor to a neutral platinum compound with a base-stabilized borylene ligand Zeitschrift Fur Anorganische Und Allgemeine Chemie. 635: 2089-2092. DOI: 10.1002/Zaac.200900122  0.407
2009 Braunschweig H, Fuß M, Radacki K, Uttinger K. Synthesis of chloro boryl complexes by oxidative addition of B-Cl bonds Zeitschrift Fur Anorganische Und Allgemeine Chemie. 635: 208-210. DOI: 10.1002/Zaac.200800426  0.371
2009 Braunschweig H, Grünewald B, Schwab K, Sigritz R. 1,1′-Diborylferrocenes from [2]Boraferrocenophanes by boron-boron exchange European Journal of Inorganic Chemistry. 4860-4863. DOI: 10.1002/Ejic.200900772  0.35
2009 Braunschweig H, Kupfer T, Mies J, Oechsner A. Difluorenyl[2]borametallocenophanes of group 4 metals: synthesis and structure European Journal of Inorganic Chemistry. 2844-2850. DOI: 10.1002/Ejic.200900277  0.408
2009 Braunschweig H, Forster M, Seeler F. Synthesis and structure of heterodinuclear rhodium and iridium borylene complexes Chemistry - a European Journal. 15: 469-473. DOI: 10.1002/Chem.200801820  0.398
2009 Braunschweig H, Gruss K, Radacki K. Complexes with dative bonds between d- and s-block metals: Synthesis and structure of [(Cy3P)2Pt-Be(Cl)X] (X = Cl, Me) Angewandte Chemie - International Edition. 48: 4239-4241. DOI: 10.1002/Anie.200900521  0.436
2009 Braunschweig H, Dewhurst RD. Reversible σ-borane-to-borylene transformation: A little something for everyone Angewandte Chemie - International Edition. 48: 1893-1895. DOI: 10.1002/Anie.200805248  0.336
2008 Bringmann G, Götz DC, Gulder TA, Gehrke TH, Bruhn T, Kupfer T, Radacki K, Braunschweig H, Heckmann A, Lambert C. Axially chiral beta,beta'-bisporphyrins: synthesis and configurational stability tuned by the central metals. Journal of the American Chemical Society. 130: 17812-5. PMID 19055342 DOI: 10.1021/Ja8055886  0.325
2008 Braunschweig H, Kupfer T. Direct functionalization at the boron center of antiaromatic chloroborole. Chemical Communications (Cambridge, England). 4487-9. PMID 18802599 DOI: 10.1039/B808483A  0.329
2008 Braunschweig H, Gross M, Hammond K, Friedrich M, Kraft M, Oechsner A, Radacki K, Stellwag S. [2]borametallocenophanes of group 4 metals: synthesis and structure. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 8972-9. PMID 18696525 DOI: 10.1002/Chem.200800964  0.392
2008 Braunschweig H, Kaupp M, Adams CJ, Kupfer T, Radacki K, Schinzel S. Synthesis, reactivity, and electronic structure of [n]vanadoarenophanes: an experimental and theoretical study. Journal of the American Chemical Society. 130: 11376-93. PMID 18680259 DOI: 10.1021/Ja802034P  0.379
2008 Braunschweig H, Dewhurst RD, Herbst T, Radacki K. Reactivity of a terminal chromium borylene complex towards olefins: insertion of a borylene into a C-H bond. Angewandte Chemie (International Ed. in English). 47: 5978-80. PMID 18604785 DOI: 10.1002/Anie.200801579  0.36
2008 Braunschweig H, Forster M, Kupfer T, Seeler F. Borylene transfer under thermal conditions for the synthesis of rhodium and iridium borylene complexes. Angewandte Chemie (International Ed. in English). 47: 5981-3. PMID 18600820 DOI: 10.1002/Anie.200801756  0.321
2008 Braunschweig H, Green H, Radacki K, Uttinger K. Synthesis of eta1-borazine complexes of palladium and platinum. Dalton Transactions (Cambridge, England : 2003). 3531-4. PMID 18594698 DOI: 10.1039/B805298K  0.37
2008 Braunschweig H, Burzler M, Dewhurst RD, Radacki K. A linear, anionic dimetalloborylene complex. Angewandte Chemie (International Ed. in English). 47: 5650-3. PMID 18567044 DOI: 10.1002/Anie.200801848  0.317
2008 Braunschweig H, Kupfer T, Radacki K, Schneider A, Seeler F, Uttinger K, Wu H. Synthesis and reactivity studies of iminoboryl complexes. Journal of the American Chemical Society. 130: 7974-83. PMID 18510321 DOI: 10.1021/Ja8016889  0.428
2008 Braunschweig H, Kraft K, Kupfer T, Radacki K, Seeler F. B+ in the coordination sphere of two transition metals. Angewandte Chemie (International Ed. in English). 47: 4931-3. PMID 18496804 DOI: 10.1002/Anie.200800533  0.316
2008 Flierler U, Burzler M, Leusser D, Henn J, Ott H, Braunschweig H, Stalke D. Electron-density investigation of metal-metal bonding in the dinuclear "borylene" complex [{Cp(CO)2Mn}2(mu-BtBu)]. Angewandte Chemie (International Ed. in English). 47: 4321-5. PMID 18454439 DOI: 10.1002/Anie.200705257  0.354
2008 Braunschweig H, Adams CJ, Kupfer T, Manners I, Richardson RM, Whittell GR. Synthesis of a paramagnetic polymer by ring-opening polymerization of a strained [1]vanadoarenophane. Angewandte Chemie (International Ed. in English). 47: 3826-9. PMID 18393349 DOI: 10.1002/Anie.200800081  0.409
2008 Braunschweig H, Kupfer T. Stoichiometric and homogeneous-catalytic diboration of the n=n double bond of azobenzene. Journal of the American Chemical Society. 130: 4242-3. PMID 18327947 DOI: 10.1021/Ja8006879  0.382
2008 Apostolico L, Braunschweig H, Crawford AG, Herbst T, Rais D. Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials. Chemical Communications (Cambridge, England). 497-8. PMID 18188480 DOI: 10.1039/B715597B  0.429
2008 Bera H, Braunschweig H, Dörfler R, Radacki K. Synthesis of a bimetallic platinum-tungsten complex with a bridging μ-diboranyl-oxycarbyne moiety Dalton Transactions. 8: 440-443. DOI: 10.1039/B714763E  0.385
2008 Anderson CE, Braunschweig H, Dewhurst RD. Borylene transfer from transition metal borylene complexes Organometallics. 27: 6381-6389. DOI: 10.1021/Om800883M  0.385
2008 Braunschweig H, Radacki K, Uttinger K. Syntheses and structures of mono- and dinuclear cationic base-stabilized platinum borylene complexes Organometallics. 27: 6005-6012. DOI: 10.1021/Om800689H  0.405
2008 Braunschweig H, Breher F, Kaupp M, Gross M, Kupfer T, Nied D, Radacki K, Schinzel S. Synthesis, crystal structure, EPR and DFT studies, and redox properties of [2]tetramethyldisilacobaltocenophane Organometallics. 27: 6427-6433. DOI: 10.1021/Om8003724  0.334
2008 Braunschweig H, Leech R, Rais D, Radacki K, Uttinger K. Conversion of trans-bromoboryl platinum complexes into their cis-analogues upon treatment with chelating bisphosphines Organometallics. 27: 418-422. DOI: 10.1021/Om700976T  0.367
2008 Braunschweig H, Gruss K, Radacki K. Reactivity of Pt0 complexes toward gallium(III) halides: Synthesis of a platinum gallane complex and oxidative addition of gallium halides to Pt0 Inorganic Chemistry. 47: 8595-8597. DOI: 10.1021/Ic801293E  0.38
2008 Braunschweig H, Burzler M, Dewhurst RD, Radacki K, Seeler F. Dimanganese Bridging Borylene Complexes and their Reactions with Unsaturated Palladium(0) Complexes - Syntheses, Structures and Calculated Properties Zeitschrift FüR Anorganische Und Allgemeine Chemie. 634: 1875-1879. DOI: 10.1002/Zaac.200800252  0.369
2008 Braunschweig H, Gruss K, Radacki K, Uttinger K. Oxidative addition of B-Br bonds to Pd0: Synthesis and structure of trans-bromo(boryl)palladium complexes European Journal of Inorganic Chemistry. 1462-1466. DOI: 10.1002/Ejic.200701214  0.314
2008 Braunschweig H, Radacki K, Uttinger K. T-shaped platinum boryl complexes: Synthesis and structure Chemistry - a European Journal. 14: 7858-7866. DOI: 10.1002/Chem.200800879  0.374
2008 Braunschweig H, Gross M, Radacki K, Rothgaengel C. Intramolecular activation of a disila[2]molybdenocenophanedihydride: Synthesis and structure of a [1],[1]metalloarenophane Angewandte Chemie - International Edition. 47: 9979-9981. DOI: 10.1002/Anie.200803223  0.385
2008 Braunschweig H, Gross M, Radacki K, Rothgaengel C. Intramolekulare Aktivierung eines Disila[2]molybdänocenophandihydrids - Synthese und Struktur eines [1],[1]Metalloarenophans Angewandte Chemie. 120: 10127-10129. DOI: 10.1002/Ange.200803223  0.313
2008 Braunschweig H, Forster M, Kupfer T, Seeler F. Thermischer Borylentransfer zur Synthese von Rhodium- und Iridiumborylenkomplexen Angewandte Chemie. 120: 6070-6072. DOI: 10.1002/Ange.200801756  0.338
2008 Braunschweig H, Adams C, Kupfer T, Manners I, Richardson R, Whittell G. Synthese eines paramagnetischen Polymers durch ringöffnende Polymerisation eines gespannten [1]Vanadoarenophans Angewandte Chemie. 120: 3886-3889. DOI: 10.1002/Ange.200800081  0.383
2007 Braunschweig H, Burzler M, Radacki K, Seeler F. Borylene metathesis through [2+2] cycloaddition Angewandte Chemie - International Edition. 46: 8071-8073. PMID 17806094 DOI: 10.1002/Anie.200702982  0.382
2007 Braunschweig H, Burzler M, Kupfer T, Radacki K, Seeler F. Synthesis and electronic structure of a terminal alkylborylene complex. Angewandte Chemie (International Ed. in English). 46: 7785-7. PMID 17803182 DOI: 10.1002/Anie.200702029  0.327
2007 Braunschweig H, Radacki K, Rais D, Schneider A, Seeler F. Reactivity of a platinum iminoboryl complex toward Lewis and Brønsted acids. Journal of the American Chemical Society. 129: 10350-1. PMID 17685529 DOI: 10.1021/Ja0742636  0.41
2007 Braunschweig H, Brenner P, Müller A, Radacki K, Rais D, Uttinger K. Experimental studies on the trans-influence of boryl ligands in square-planar platinum(II) complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 7171-6. PMID 17594710 DOI: 10.1002/Chem.200700539  0.379
2007 Braunschweig H, Kupfer T, Lutz M, Radacki K. Ansa [1]trochrocenophanes and their related unstrained 1,1'-disubstituted counterparts: synthesis and electronic structure. Journal of the American Chemical Society. 129: 8893-906. PMID 17592847 DOI: 10.1021/Ja0724947  0.382
2007 Braunschweig H, Forster M, Radacki K, Seeler F, Whittell GR. Stepwise intermetal borylene transfer: synthesis and structure of mono- and dinuclear cobalt-borylene complexes. Angewandte Chemie (International Ed. in English). 46: 5212-4. PMID 17542035 DOI: 10.1002/Anie.200701142  0.346
2007 Braunschweig H, Radacki K, Uttinger K. Synthesis and structure of a cationic platinum borylene complex Angewandte Chemie - International Edition. 46: 3979-3982. PMID 17431864 DOI: 10.1002/Anie.200605191  0.411
2007 Braunschweig H, Buggisch N, Englert U, Homberger M, Kupfer T, Leusser D, Lutz M, Radacki K. Dilithiation of Bis(benzene)molybdenum and subsequent isolation of a molybdenum-containing paracyclophane. Journal of the American Chemical Society. 129: 4840-6. PMID 17375929 DOI: 10.1021/Ja0692130  0.436
2007 Blank B, Colling-Hendelkens M, Kollann C, Radacki K, Rais D, Uttinger K, Whittell GR, Braunschweig H. Aminoborylene complexes of group 6 elements and iron: a synthetic, structural, and quantum chemical study. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 4770-81. PMID 17366491 DOI: 10.1002/Chem.200601520  0.393
2007 Braunschweig H, Kraft M, Schwarz S, Seeler F, Stellwag S. Preparation and structural characterization of transition-metal complexes featuring the cymantrenyl(bromo)boryl ligand. Inorganic Chemistry. 45: 5275-7. PMID 16813387 DOI: 10.1021/Ic0607080  0.381
2007 Flierler U, Burzler M, Ott H, Leusser D, Henn J, Braunschweig H, Stalke D. Metal-metal bonding in the μ-BMn2triangular motif of [μ-BtBu (η5-C5H5)Mn(CO)22] Acta Crystallographica Section a Foundations of Crystallography. 63: s28-s29. DOI: 10.1107/S0108767307099357  0.337
2007 Braunschweig H, Gross M, Radacki K. Synthesis, molecular structure, and reactivity of the first strained [2]silanickelocenophane Organometallics. 26: 6688-6690. DOI: 10.1021/Om701037S  0.387
2007 Braunschweig H, Radacki K, Uttinger K. Syntheses of mono- and dinuclear diiodoboryl complexes of platinum Inorganic Chemistry. 46: 8796-8800. DOI: 10.1021/Ic7011028  0.382
2007 Braunschweig H, Seeler F, Sigritz R. Alternative synthesis and crystal structure of a [2]boraferrocenophane Journal of Organometallic Chemistry. 692: 2354-2356. DOI: 10.1016/J.Jorganchem.2007.02.008  0.34
2007 Braunschweig H, Clentsmith GKB, Hess S, Kupfer T, Radacki K. Interaction of dilithiated ferrocene with AlMe2Cl reagents Inorganica Chimica Acta. 360: 1274-1277. DOI: 10.1016/J.Ica.2006.01.047  0.358
2007 Braunschweig H, Bera H, Stellwag S, Schwarz S, Hemberger Y, Radacki K. [{Br2B(η5-C5H4)}Mn(CO)3] – A versatile Precursor for Boron-based Ligands Zeitschrift FüR Anorganische Und Allgemeine Chemie. 633: 2314-2320. DOI: 10.1002/Zaac.200700207  0.354
2007 Braunschweig H, Radacki K, Uttinger K. Synthesis and characterisation of semi-bridging molybdenum borylene complexes European Journal of Inorganic Chemistry. 4350-4356. DOI: 10.1002/Ejic.200700356  0.404
2007 Braunschweig H, Bera H, Geibel B, Dörfler R, Götz D, Seeler F, Kupfer T, Radacki K. Synthesis of half-sandwich tungsten chlorogermyl and chlorostannyl complexes European Journal of Inorganic Chemistry. 3416-3424. DOI: 10.1002/Ejic.200700292  0.395
2007 Braunschweig H, Gruss K, Radacki K. Interaction between d- and p-block metals: Synthesis and structure of platinum-alane adducts Angewandte Chemie - International Edition. 46: 7782-7784. DOI: 10.1002/Anie.200702726  0.388
2007 Braunschweig H. Lithiumboryl - A synthon for a nucleophilic boryl anion Angewandte Chemie - International Edition. 46: 1946-1948. DOI: 10.1002/Anie.200605053  0.329
2007 Braunschweig H, Burzler M, Kupfer T, Radacki K, Seeler F. Synthese und Elektronenstruktur eines terminalen Alkylborylenkomplexes Angewandte Chemie. 119: 7932-7934. DOI: 10.1002/Ange.200702029  0.318
2007 Braunschweig H, Forster M, Radacki K, Seeler F, Whittell G. Stufenweiser Intermetallborylentransfer: Synthese und Struktur von ein- und zweikernigen Cobaltborylenkomplexen Angewandte Chemie. 119: 5304-5306. DOI: 10.1002/Ange.200701142  0.301
2007 Braunschweig H, Fernández I, Frenking G, Radacki K, Seeler F. Synthese und Elektronenstruktur eines Ferroborirens Angewandte Chemie. 119: 5307-5310. DOI: 10.1002/Ange.200700382  0.318
2007 Braunschweig H, Radacki K, Uttinger K. Synthese und Struktur eines kationischen Platinborylenkomplexes Angewandte Chemie. 119: 4054-4057. DOI: 10.1002/Ange.200605191  0.317
2006 Bartole-Scott A, Braunschweig H, Kupfer T, Lutz M, Manners I, Nguyen TL, Radacki K, Seeler F. Synthesis of ansa-[n]silacyclopentadienyl-cycloheptatrienyl-chromium complexes (n = 1, 2): novel precursors for polymers bearing chromium in the backbone. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 1266-73. PMID 16281318 DOI: 10.1002/Chem.200500689  0.533
2006 Braunschweig H, Radacki K, Rais D, Whittell GR. A boryl bridged complex: an unusual coordination mode of the BR2 ligand. Angewandte Chemie (International Ed. in English). 44: 1192-4. PMID 15662654 DOI: 10.1002/Anie.200462444  0.333
2006 Braunschweig H, Kraft M, Radacki K, Stellwag S. Piperidino substituted [1]borametallocenophanes. Synthesis, reactivity, and structure Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 61: 509-516. DOI: 10.1515/Znb-2006-0503  0.361
2006 Braunschweig H, Bera H, Götz D, Radacki K. Phosphine-substituted diborane(4)yl complexes of tungsten Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 61: 29-32. DOI: 10.1515/Znb-2006-0106  0.372
Show low-probability matches.