| Year |
Citation |
Score |
| 2023 |
Punjajom K, Sinclair PP, Saha I, Seierstad M, Ameriks MK, García-Reynaga P, Lebold TP, Sarpong R. Convergent synthesis of thiodiazole dioxides from simple ketones and amines through an unusual nitrogen-migration mechanism. Chemical Science. 15: 328-335. PMID 38131085 DOI: 10.1039/d3sc04478e |
0.391 |
|
| 2023 |
Hardy MA, Cooke JH, Feng Z, Noda K, Kerschgens I, Massey LA, Tantillo DJ, Sarpong R. Unified Synthesis of 2-Isocyanoallopupukeanane and 9-Isocyanopupukeanane through a 'Contra-biosynthetic' Rearrangement. Angewandte Chemie (International Ed. in English). e202317348. PMID 38032339 DOI: 10.1002/anie.202317348 |
0.382 |
|
| 2023 |
Bakanas I, Lusi RF, Wiesler S, Hayward Cooke J, Sarpong R. Strategic application of C-H oxidation in natural product total synthesis. Nature Reviews. Chemistry. 7: 783-799. PMID 37730908 DOI: 10.1038/s41570-023-00534-6 |
0.326 |
|
| 2023 |
Soro DM, Roque JB, Rackl JW, Park B, Payer S, Shi Y, Ruble JC, Kaledin AL, Baik MH, Musaev DG, Sarpong R. Photo- and Metal-Mediated Deconstructive Approaches to Cyclic Aliphatic Amine Diversification. Journal of the American Chemical Society. PMID 37171220 DOI: 10.1021/jacs.3c01318 |
0.8 |
|
| 2023 |
Bakanas I, Tang JC, Sarpong R. Skeletal diversification by C-C cleavage to access bicyclic frameworks from a common tricyclooctane intermediate. Chemical Communications (Cambridge, England). 59: 3858-3861. PMID 36916206 DOI: 10.1039/d3cc00945a |
0.303 |
|
| 2022 |
Perea MA, Wang B, Wyler BC, Ham JS, O'Connor NR, Nagasawa S, Kimura Y, Manske C, Scherübl M, Nguyen JM, Sarpong R. General Synthetic Approach to Diverse Taxane Cores. Journal of the American Chemical Society. PMID 36346461 DOI: 10.1021/jacs.2c10272 |
0.831 |
|
| 2022 |
Na CG, Kang SH, Sarpong R. Development of a C-C Bond Cleavage/Vinylation/Mizoroki-Heck Cascade Reaction: Application to the Total Synthesis of 14- and 15-Hydroxypatchoulol. Journal of the American Chemical Society. 144: 19253-19257. PMID 36240482 DOI: 10.1021/jacs.2c09201 |
0.361 |
|
| 2022 |
Sennari G, Gardner KE, Wiesler S, Haider M, Eggert A, Sarpong R. Unified Total Syntheses of Benzenoid Cephalotane-Type Norditerpenoids: Cephanolides and Ceforalides. Journal of the American Chemical Society. PMID 36198090 DOI: 10.1021/jacs.2c08803 |
0.36 |
|
| 2022 |
Lusi RF, Sennari G, Sarpong R. Strategy Evolution in a Skeletal Remodeling and C-H Functionalization-Based Synthesis of the Longiborneol Sesquiterpenoids. Journal of the American Chemical Society. 144: 17277-17294. PMID 36098550 DOI: 10.1021/jacs.2c08136 |
0.38 |
|
| 2022 |
Lusi RF, Perea MA, Sarpong R. C-C Bond Cleavage of α-Pinene Derivatives Prepared from Carvone as a General Strategy for Complex Molecule Synthesis. Accounts of Chemical Research. PMID 35170951 DOI: 10.1021/acs.accounts.1c00783 |
0.4 |
|
| 2022 |
Lusi RF, Sennari G, Sarpong R. Total synthesis of nine longiborneol sesquiterpenoids using a functionalized camphor strategy. Nature Chemistry. PMID 35165424 DOI: 10.1038/s41557-021-00870-4 |
0.397 |
|
| 2021 |
Hardy MA, Nan B, Wiest O, Sarpong R. Strategic elements in computer-assisted retrosynthesis: A case study of the pupukeanane natural products. Tetrahedron. 104. PMID 36743342 DOI: 10.1016/j.tet.2021.132584 |
0.322 |
|
| 2021 |
Jones KE, Park B, Doering NA, Baik MH, Sarpong R. Rearrangements of the Chrysanthenol Core: Application to a Formal Synthesis of Xishacorene B. Journal of the American Chemical Society. PMID 34812038 DOI: 10.1021/jacs.1c10804 |
0.831 |
|
| 2021 |
Palani V, Perea MA, Sarpong R. Site-Selective Cross-Coupling of Polyhalogenated Arenes and Heteroarenes with Identical Halogen Groups. Chemical Reviews. PMID 34402611 DOI: 10.1021/acs.chemrev.1c00513 |
0.765 |
|
| 2021 |
Jurczyk J, Lux MC, Adpressa D, Kim SF, Lam YH, Yeung CS, Sarpong R. Photo-mediated ring contraction of saturated heterocycles. Science (New York, N.Y.). PMID 34385352 DOI: 10.1126/science.abi7183 |
0.31 |
|
| 2021 |
Haley HMS, Payer SE, Papidocha SM, Clemens S, Nyenhuis J, Sarpong R. Bioinspired Diversification Approach Toward the Total Synthesis of Lycodine-Type Alkaloids. Journal of the American Chemical Society. PMID 33729783 DOI: 10.1021/jacs.1c00457 |
0.387 |
|
| 2020 |
Palani V, Perea MA, Gardner KE, Sarpong R. A pyrone remodeling strategy to access diverse heterocycles: application to the synthesis of fascaplysin natural products. Chemical Science. 12: 1528-1534. PMID 34163915 DOI: 10.1039/d0sc06317g |
0.81 |
|
| 2020 |
McCowen SV, Doering NA, Sarpong R. Retrosynthetic strategies and their impact on synthesis of arcutane natural products. Chemical Science. 11: 7538-7552. PMID 33552460 DOI: 10.1039/D0Sc01441A |
0.836 |
|
| 2020 |
Knapp RR, Tona V, Okada T, Sarpong R, Garg NK. Cyanoamidine Cyclization Approach to Remdesivir's Nucleobase. Organic Letters. PMID 33085486 DOI: 10.1021/acs.orglett.0c03052 |
0.521 |
|
| 2020 |
Roque JB, Mercado-Marin EV, Richter SC, Pereira de Sant'Ana D, Mukai K, Ye Y, Sarpong R. A unified strategy to reverse-prenylated indole alkaloids: total syntheses of preparaherquamide, premalbrancheamide, and (+)-VM-55599. Chemical Science. 11: 5929-5934. PMID 32953008 DOI: 10.1039/D0Sc02296A |
0.646 |
|
| 2020 |
Lux MC, Jurczyk J, Lam YH, Song ZJ, Ma C, Roque JB, Ham JS, Sciammetta N, Adpressa D, Sarpong R, Yeung CS. Synthesis of Bridged Bicyclic Amines by Intramolecular Amination of Remote C-H Bonds: Synergistic Activation by Light and Heat. Organic Letters. PMID 32806157 DOI: 10.1021/Acs.Orglett.0C02345 |
0.356 |
|
| 2020 |
Leger PR, Kuroda Y, Chang S, Jurczyk J, Sarpong R. C-C Bond Cleavage Approach to Complex Terpenoids: Development of a Unified Total Synthesis of the Phomactins. Journal of the American Chemical Society. PMID 32799452 DOI: 10.1021/Jacs.0C07316 |
0.419 |
|
| 2020 |
Hardy MA, Wright BA, Bachman JL, Boit TB, Haley HMS, Knapp RR, Lusi RF, Okada T, Tona V, Garg NK, Sarpong R. Treating a Global Health Crisis with a Dose of Synthetic Chemistry. Acs Central Science. 6: 1017-1030. PMID 32719821 DOI: 10.1021/Acscentsci.0C00637 |
0.471 |
|
| 2020 |
Ham JS, Park B, Son M, Roque JB, Jurczyk J, Yeung CS, Baik MH, Sarpong R. C-H/C-C Functionalization Approach to N-Fused Heterocycles from Saturated Azacycles. Journal of the American Chemical Society. PMID 32627545 DOI: 10.1021/Jacs.0C04278 |
0.399 |
|
| 2020 |
Sarpong R, Wang B, Perea MA. Transition Metal-Mediated C-C Single Bond Cleavage: Making the Cut in Total Synthesis. Angewandte Chemie (International Ed. in English). PMID 31984640 DOI: 10.1002/Anie.201915657 |
0.586 |
|
| 2020 |
Roque JB, Kuroda Y, Jurczyk J, Xu L, Ham JS, Göttemann LT, Roberts CA, Adpressa D, Saurí J, Joyce LA, Musaev DG, Yeung CS, Sarpong R. C–C Cleavage Approach to C–H Functionalization of Saturated Aza-Cycles Acs Catalysis. 10: 2929-2941. DOI: 10.1021/Acscatal.9B04551 |
0.363 |
|
| 2020 |
Sarpong R, Wang B, Perea MA. Transition Metal‐Mediated C–C Single Bond Cleavage: Making the Cut in Total Synthesis Angewandte Chemie. DOI: 10.1002/Ange.201915657 |
0.33 |
|
| 2020 |
Doering NA, Sarpong R, Hoffmann RW. Ein Fall für die Bindungs‐Netzwerk‐Analyse bei der Synthese verbrückter polycyclischer komplexer Moleküle: Hetidin‐ und Hetisin‐Diterpen‐Alkaloide Angewandte Chemie. 132: 10810-10820. DOI: 10.1002/Ange.201909656 |
0.775 |
|
| 2019 |
Doering NA, Sarpong R, Hoffmann RW. A Case for Bond-Network Analysis in Bridged Polycyclic Complex Molecule Synthesis: Hetidine and Hetisine Diterpenoid Alkaloids. Angewandte Chemie (International Ed. in English). PMID 31808282 DOI: 10.1002/Anie.201909656 |
0.806 |
|
| 2019 |
Rovira AR, Müller N, Deng W, Ndubaku C, Sarpong R. Bio-inspired synthesis of xishacorenes A, B, and C, and a new congener from fuscol. Chemical Science. 10: 7788-7791. PMID 31588327 DOI: 10.1039/C9Sc02572C |
0.384 |
|
| 2019 |
Hugelshofer CL, Palani V, Sarpong R. Calyciphylline B-type Alkaloids: Evolution of a Synthetic Strategy to (-)-Daphlongamine H. The Journal of Organic Chemistry. PMID 31533427 DOI: 10.1021/Acs.Joc.9B02223 |
0.798 |
|
| 2019 |
Nagasawa S, Jones KE, Sarpong R. Enantiospecific Entry to a Common Decalin Intermediate for the Syntheses of Highly Oxygenated Terpenoids. The Journal of Organic Chemistry. PMID 31454485 DOI: 10.1021/Acs.Joc.9B01937 |
0.386 |
|
| 2019 |
Palani V, Hugelshofer CL, Sarpong R. A Unified Strategy for the Enantiospecific Total Synthesis of Delavatine A and Formal Synthesis of Incarviatone A. Journal of the American Chemical Society. PMID 31433634 DOI: 10.1021/Jacs.9B07693 |
0.819 |
|
| 2019 |
Pfaffenbach M, Bakanas I, O'Connor NR, Herrick JL, Sarpong R. Total Syntheses of Xiamycins A, C, F, H and Oridamycin A and Preliminary Evaluation of their Anti-Fungal Properties. Angewandte Chemie (International Ed. in English). PMID 31419367 DOI: 10.1002/Anie.201908399 |
0.355 |
|
| 2019 |
Owens KR, McCowen S, Blackford KA, Ueno S, Hirooka Y, Weber M, Sarpong R. Total Synthesis of the Diterpenoid Alkaloid Arcutinidine Using a Strategy Inspired by Chemical Network Analysis. Journal of the American Chemical Society. PMID 31276621 DOI: 10.1021/Jacs.9B05815 |
0.715 |
|
| 2019 |
Gritsch PJ, Gimenez-Nueno I, Wonilowicz L, Sarpong R. Copper-Catalyzed [4+2] Cycloaddition of 9 H-Cyclohepta[ b]pyridine-9-one and Electron-Rich Alkenes. The Journal of Organic Chemistry. PMID 31244151 DOI: 10.1021/Acs.Joc.9B00899 |
0.389 |
|
| 2019 |
Hugelshofer CL, Palani V, Sarpong R. Calyciphylline B-Type Alkaloids: Total Syntheses of (-)-Daphlongamine H and (-)-Isodaphlongamine H. Journal of the American Chemical Society. PMID 31074980 DOI: 10.1021/Jacs.9B03576 |
0.798 |
|
| 2019 |
Norseeda K, Gasser V, Sarpong R. A Late-Stage Functionalization Approach to Derivatives of the Pyrano[3,2-a]carbazole Natural Products. The Journal of Organic Chemistry. PMID 30969773 DOI: 10.1021/Acs.Joc.9B00631 |
0.378 |
|
| 2019 |
Johnson RE, Ree H, Hartmann M, Lang L, Sawano S, Sarpong R. Total Synthesis of Pentacyclic (-)-Ambiguine P using Sequential Indole Functionalizations. Journal of the American Chemical Society. PMID 30702879 DOI: 10.1021/Jacs.8B13388 |
0.525 |
|
| 2019 |
Palani V, Hugelshofer CL, Kevlishvili I, Liu P, Sarpong R. A short synthesis of delavatine A unveils new insights into site-selective cross-coupling of 3,5-dibromo-2-pyrone. Journal of the American Chemical Society. PMID 30646686 DOI: 10.1021/Jacs.8B13012 |
0.788 |
|
| 2019 |
Sayes M, Benoit G, Charette AB, Rovira AR, Sarpong R. Three‐Step Synthesis of 2‐(Diiodomethyl)‐4,4,5,5‐Tetramethyl‐1,3,2‐Dioxaborolane from Dichloromethane Organic Syntheses. 96: 277-299. DOI: 10.1002/0471264229.Os096.18 |
0.637 |
|
| 2018 |
Kearney SE, Zahoránszky-Kőhalmi G, Brimacombe KR, Henderson MJ, Lynch C, Zhao T, Wan KK, Itkin Z, Dillon C, Shen M, Cheff DM, Lee TD, Bougie D, Cheng K, Coussens NP, ... ... Sarpong R, et al. Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space. Acs Central Science. 4: 1727-1741. PMID 30648156 DOI: 10.1021/Acscentsci.8B00747 |
0.523 |
|
| 2018 |
Roque JB, Kuroda Y, Göttemann LT, Sarpong R. Deconstructive diversification of cyclic amines. Nature. PMID 30382193 DOI: 10.1038/S41586-018-0700-3 |
0.367 |
|
| 2018 |
Doering NA, Kou KGM, Norseeda K, Lee JC, Marth CJ, Gallego GM, Sarpong R. A Copper-Mediated Conjugate Addition Approach to Analogs of Aconitine-Type Diterpenoid Alkaloids. The Journal of Organic Chemistry. PMID 30216070 DOI: 10.1021/Acs.Joc.8B01967 |
0.799 |
|
| 2018 |
Kuroda Y, Nicacio KJ, da Silva-Jr IA, Leger PR, Chang S, Gubiani JR, Deflon VM, Nagashima N, Rode A, Blackford K, Ferreira AG, Sette LD, Williams DE, Andersen RJ, Jancar S, ... ... Sarpong R, et al. Isolation, synthesis and bioactivity studies of phomactin terpenoids. Nature Chemistry. PMID 30061613 DOI: 10.1038/S41557-018-0084-X |
0.427 |
|
| 2018 |
Kerschgens I, Rovira AR, Sarpong R. Total Synthesis of (-)-Xishacorene B from ( R)-Carvone Using a C-C Activation Strategy. Journal of the American Chemical Society. 140: 9810-9813. PMID 30032603 DOI: 10.1021/Jacs.8B05832 |
0.418 |
|
| 2018 |
Kerschgens I, Rovira AR, Sarpong R. Total Synthesis of (-)-Xishacorene B from ( R)-Carvone Using a C-C Activation Strategy. Journal of the American Chemical Society. 140: 9810-9813. PMID 30032603 DOI: 10.1021/jacs.8b05832 |
0.303 |
|
| 2018 |
Roque JB, Kuroda Y, Göttemann LT, Sarpong R. Deconstructive fluorination of cyclic amines by carbon-carbon cleavage. Science (New York, N.Y.). 361: 171-174. PMID 30002251 DOI: 10.1126/Science.Aat6365 |
0.376 |
|
| 2018 |
Blümel M, Nagasawa S, Blackford K, Hare SR, Tantillo DJ, Sarpong R. Rearrangement of Hydroxylated Pinene Derivatives to Fenchone-Type Frameworks: Computational Evidence for Dynamically-Controlled Selectivity. Journal of the American Chemical Society. PMID 29968475 DOI: 10.1021/Jacs.8B05804 |
0.332 |
|
| 2018 |
Kou KGM, Pflueger JJ, Kiho T, Morrill LC, Fisher EL, Clagg K, Lebold TP, Kisunzu JK, Sarpong R. A Benzyne-Insertion Approach to Hetisine-Type Diterpenoid Alka-loids: Synthesis of Cossonidine (Davisine). Journal of the American Chemical Society. PMID 29889509 DOI: 10.1021/Jacs.8B05043 |
0.83 |
|
| 2018 |
Hugelshofer CL, Palani V, Sarpong R. Oxazaborinines from Vinylogous N-Allylic Amides: Reactivities of Underexplored Heterocyclic Building Blocks. Organic Letters. PMID 29667837 DOI: 10.1021/Acs.Orglett.8B00859 |
0.803 |
|
| 2018 |
Mukai K, de Sant'Ana DP, Hirooka Y, Mercado-Marin EV, Stephens DE, Kou KGM, Richter SC, Kelley N, Sarpong R. Bioinspired chemical synthesis of monomeric and dimeric stephacidin A congeners. Nature Chemistry. 10: 38-44. PMID 29256515 DOI: 10.1038/Nchem.2862 |
0.78 |
|
| 2018 |
Usui K, Haines BE, Musaev DG, Sarpong R. Understanding Regiodivergence in a Pd(II)-Mediated Site-Selective C–H Alkynylation Acs Catalysis. 8: 4516-4527. DOI: 10.1021/Acscatal.8B01116 |
0.398 |
|
| 2018 |
Ruble JC, Vandeveer HG, Navarro A, Palani V, Sarpong R. Large Scale Synthesis of Enantiomerically Pure ( S )‐3‐(4‐Bromophenyl)butanoic Acid Organic Syntheses. 95: 328-344. DOI: 10.1002/0471264229.Os095.23 |
0.762 |
|
| 2017 |
Chen AY, Lu Q, Fu Y, Sarpong R, Stoltz BM, Zhang H. Isocanthine Synthesis via Rh(III)-Catalyzed Intramolecular C-H Functionalization. The Journal of Organic Chemistry. PMID 29182872 DOI: 10.1021/Acs.Joc.7B02731 |
0.746 |
|
| 2017 |
de Rond T, Stow P, Eigl I, Johnson RE, Chan LJG, Goyal G, Baidoo EEK, Hillson NJ, Petzold CJ, Sarpong R, Keasling JD. Oxidative cyclization of prodigiosin by an alkylglycerol monooxygenase-like enzyme. Nature Chemical Biology. PMID 28892091 DOI: 10.1038/Nchembio.2471 |
0.309 |
|
| 2017 |
Lindsay VNG, Murphy RA, Sarpong R. Effect of protic additives in Cu-catalysed asymmetric Diels-Alder cycloadditions of doubly activated dienophiles: towards the synthesis of magellanine-type Lycopodium alkaloids. Chemical Communications (Cambridge, England). PMID 28869258 DOI: 10.1039/C7Cc06367A |
0.78 |
|
| 2017 |
Kou KGM, Kulyk S, Marth CJ, Lee JC, Doering NA, Li BX, Gallego GM, Lebold TP, Sarpong R. A Unifying Synthesis Approach to the C18‒, C19‒, and C20‒Diterpenoid Alkaloids. Journal of the American Chemical Society. PMID 28858498 DOI: 10.1021/Jacs.7B07706 |
0.805 |
|
| 2017 |
Pflueger JJ, Morrill LC, deGruyter JN, Perea MA, Sarpong R. Magnesiate Addition/Ring-Expansion Strategy To Access the 6-7-6 Tricyclic Core of Hetisine-Type C20-Diterpenoid Alkaloids. Organic Letters. PMID 28820600 DOI: 10.1021/Acs.Orglett.7B02260 |
0.731 |
|
| 2017 |
Fraley AE, Garcia-Borràs M, Tripathi A, Khare D, Mercado-Marin EV, Tran H, Dan Q, Webb G, Watts K, Crews P, Sarpong R, Williams RM, Smith JL, Houk KN, Sherman DH. Function and structure of MalA/MalA', iterative halogenases for late-stage C-H functionalization of indole alkaloids. Journal of the American Chemical Society. PMID 28777910 DOI: 10.1021/Jacs.7B06773 |
0.593 |
|
| 2017 |
Finkbeiner P, Murai K, Röpke M, Sarpong R. Total Synthesis of Terpenoids Employing a 'Benzannulation of Car-vone' Strategy: Synthesis of (-)-Crotogoudin. Journal of the American Chemical Society. PMID 28763218 DOI: 10.1021/Jacs.7B06823 |
0.509 |
|
| 2017 |
Wilkerson-Hill SM, Yu D, Painter PP, Fisher EL, Tantillo DJ, Sarpong R, Hein JE. On the Mechanism of a No-metal-added Heterocycloisomerization of Alkynylcyclopropylhydrazones: A Synthesis of Cycloheptane-fused Aminopyrroles Facilitated by Copper Salts at Trace Loadings. Journal of the American Chemical Society. PMID 28683552 DOI: 10.1021/Jacs.7B06007 |
0.788 |
|
| 2017 |
Viart HM, Bachmann A, Kayitare W, Sarpong R. β-Carboline Amides as Intrinsic Directing Groups for C(sp2)-H Functionalization. Journal of the American Chemical Society. PMID 28040899 DOI: 10.1021/Jacs.6B12569 |
0.345 |
|
| 2016 |
Sarpong R. C-H Functionalization/activation in organic synthesis. Beilstein Journal of Organic Chemistry. 12: 2315-2316. PMID 28144298 DOI: 10.3762/Bjoc.12.224 |
0.322 |
|
| 2016 |
Wilkerson-Hill SM, Sawano S, Sarpong R. Bis(1-cyanovinyl acetate) is a Linear Precursor to 3-Oxidopyrylium Ions. The Journal of Organic Chemistry. PMID 27740750 DOI: 10.1021/Acs.Joc.6B02111 |
0.764 |
|
| 2016 |
Leal RA, Bischof C, Lee YV, Sawano S, McAtee CC, Latimer LN, Russ ZN, Dueber JE, Yu JQ, Sarpong R. Application of a Palladium-Catalyzed C-H Functionalization/Indolization Method to Syntheses of cis-Trikentrin A and Herbindole B. Angewandte Chemie (International Ed. in English). PMID 27570932 DOI: 10.1002/Anie.201605475 |
0.471 |
|
| 2016 |
Kou KG, Li BX, Lee JC, Gallego GM, Lebold TP, DiPasquale AG, Sarpong R. Syntheses of Denudatine Diterpenoid Alkaloids: Cochle-arenine, N-Ethyl-1α-Hydroxy-17-Veratroyldictizine, and Paniculamine. Journal of the American Chemical Society. PMID 27525345 DOI: 10.1021/Jacs.6B07268 |
0.809 |
|
| 2016 |
Wilkerson-Hill SM, Lavados CM, Sarpong R. The Diels–Alder reactivity of 2-vinylindenes: synthesis of functionalized tetrahydrofluorenes Tetrahedron. 72: 3635-3640. DOI: 10.1016/J.Tet.2016.03.074 |
0.784 |
|
| 2016 |
Wilkerson-Hill SM, Lavados CM, Sarpong R. ChemInform Abstract: The Diels-Alder Reactivity of 2-Vinylindenes: Synthesis of Functionalized Tetrahydrofluorenes. Cheminform. 47. DOI: 10.1002/chin.201641120 |
0.787 |
|
| 2015 |
Marth CJ, Gallego GM, Lee JC, Lebold TP, Kulyk S, Kou KG, Qin J, Lilien R, Sarpong R. Network-analysis-guided synthesis of weisaconitine D and liljestrandinine. Nature. PMID 26675722 DOI: 10.1038/Nature16440 |
0.818 |
|
| 2015 |
Weber M, Owens K, Masarwa A, Sarpong R. Construction of Enantiopure Taxoid and Natural Product-like Scaffolds Using a C-C Bond Cleavage/Arylation Reaction. Organic Letters. 17: 5432-5. PMID 26485318 DOI: 10.1021/Acs.Orglett.5B02797 |
0.692 |
|
| 2015 |
Mercado-Marin EV, Sarpong R. Unified Approach to Prenylated Indole Alkaloids: Total Syntheses of (-)-17-Hydroxy-Citrinalin B, (+)-Stephacidin A, and (+)-Notoamide I. Chemical Science (Royal Society of Chemistry : 2010). 6: 5048-5052. PMID 26417428 DOI: 10.1039/C5Sc01977J |
0.506 |
|
| 2015 |
Heller ST, Newton JN, Fu T, Sarpong R. One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent. Angewandte Chemie (International Ed. in English). 54: 9839-43. PMID 26138029 DOI: 10.1002/Anie.201502894 |
0.487 |
|
| 2015 |
Johnson RE, de Rond T, Lindsay VN, Keasling JD, Sarpong R. Synthesis of Cycloprodigiosin Identifies the Natural Isolate as a Scalemic Mixture. Organic Letters. PMID 26114660 DOI: 10.1021/Acs.Orglett.5B01527 |
0.703 |
|
| 2015 |
Lindsay VN, Viart HM, Sarpong R. Stereodivergent Intramolecular C(sp(3))-H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N-Heterotricycles. Journal of the American Chemical Society. 137: 8368-71. PMID 26096731 DOI: 10.1021/Jacs.5B04295 |
0.742 |
|
| 2015 |
Weber M, Owens K, Sarpong R. Atropurpuran - Missing Biosynthetic Link Leading to the Hetidine and Arcutine C20-Diterpenoid Alkaloids or an Oxidative Degradation Product? Tetrahedron Letters. 56: 3600-3603. PMID 26028789 DOI: 10.1016/J.Tetlet.2015.01.111 |
0.648 |
|
| 2015 |
Masarwa A, Weber M, Sarpong R. Selective C-C and C-H bond activation/cleavage of pinene derivatives: synthesis of enantiopure cyclohexenone scaffolds and mechanistic insights. Journal of the American Chemical Society. 137: 6327-34. PMID 25892479 DOI: 10.1021/Jacs.5B02254 |
0.365 |
|
| 2015 |
Beng TK, Takeuchi H, Weber M, Sarpong R. Stereocontrolled synthesis of vicinally functionalized piperidines by nucleophilic β-addition of alkyllithiums to α-aryl substituted piperidine enecarbamates. Chemical Communications (Cambridge, England). 51: 7653-6. PMID 25845938 DOI: 10.1039/C5Cc01307K |
0.417 |
|
| 2015 |
Leger PR, Murphy RA, Pushkarskaya E, Sarpong R. Synthetic efforts toward the Lycopodium alkaloids inspires a hydrogen iodide mediated method for the hydroamination and hydroetherification of olefins. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 4377-83. PMID 25641382 DOI: 10.1002/Chem.201406242 |
0.657 |
|
| 2015 |
Lindsay VNG, Viart HMF, Sarpong R. Stereodivergent Intramolecular C(sp3)-H Functionalization of Azavinyl Carbenes: Synthesis of Saturated Heterocycles and Fused N -Heterotricycles Journal of the American Chemical Society. 137: 8368-8371. DOI: 10.1021/jacs.5b04295 |
0.68 |
|
| 2015 |
Weber M, Owens K, Sarpong R. Atropurpuran - Missing biosynthetic link leading to the hetidine and arcutine C20-diterpenoid alkaloids or an oxidative degradation product? Tetrahedron Letters. 56: 3600-3603. DOI: 10.1016/j.tetlet.2015.01.111 |
0.588 |
|
| 2015 |
Heller ST, Newton JN, Fu T, Sarpong R. One-pot Unsymmetrical Ketone Synthesis Employing a Pyrrole-Bearing Formal Carbonyl Dication Linchpin Reagent Angewandte Chemie - International Edition. DOI: 10.1002/anie.201502894 |
0.419 |
|
| 2014 |
Schultz EE, Lindsay VN, Sarpong R. Expedient synthesis of fused azepine derivatives using a sequential rhodium(II)-catalyzed cyclopropanation/1-aza-Cope rearrangement of dienyltriazoles. Angewandte Chemie (International Ed. in English). 53: 9904-8. PMID 25044869 DOI: 10.1002/Anie.201405356 |
0.793 |
|
| 2014 |
Hamlin AM, Lapointe D, Owens K, Sarpong R. Studies on C20-diterpenoid alkaloids: Synthesis of the hetidine framework and its application to the synthesis of dihydronavirine and the atisine skeleton Journal of Organic Chemistry. 79: 6783-6800. PMID 25004408 DOI: 10.1021/Jo501214B |
0.842 |
|
| 2014 |
Mercado-Marin EV, Garcia-Reynaga P, Romminger S, Pimenta EF, Romney DK, Lodewyk MW, Williams DE, Andersen RJ, Miller SJ, Tantillo DJ, Berlinck RG, Sarpong R. Total synthesis and isolation of citrinalin and cyclopiamine congeners. Nature. 509: 318-24. PMID 24828190 DOI: 10.1038/Nature13273 |
0.384 |
|
| 2014 |
Jones AC, May JA, Sarpong R, Stoltz BM. Toward a symphony of reactivity: cascades involving catalysis and sigmatropic rearrangements. Angewandte Chemie (International Ed. in English). 53: 2556-91. PMID 24677683 DOI: 10.1002/Anie.201302572 |
0.765 |
|
| 2014 |
Hamlin AM, Kisunzu JK, Sarpong R. Synthetic strategies toward hetidine and hetisine-type diterpenoid alkaloids Organic and Biomolecular Chemistry. 12: 1846-1860. PMID 24525557 DOI: 10.1039/C3Ob42541J |
0.801 |
|
| 2014 |
Beng TK, Wilkerson-Hill SM, Sarpong R. Direct access to functionalized azepanes by cross-coupling with α-halo eneformamides Organic Letters. 16: 916-919. PMID 24456197 DOI: 10.1021/Ol403671S |
0.783 |
|
| 2014 |
Murphy RA, Sarpong R. Heathcock-inspired strategies for the synthesis of fawcettimine-type Lycopodium alkaloids. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 42-56. PMID 24311383 DOI: 10.1002/Chem.201303975 |
0.598 |
|
| 2014 |
Marcus AP, Sarpong R. Correction to Synthesis of the Tetracyclic Core of Tetrapetalone A Enabled by a Pyrrole Reductive Alkyation Organic Letters. 16: 3420-3420. DOI: 10.1021/Ol501550U |
0.767 |
|
| 2014 |
Beng TK, Wilkerson-Hill SM, Sarpong R. Correction to Direct Access to Functionalized Azepanes by Cross-Coupling with α-Halo Eneformamides Organic Letters. 16: 3170-3170. DOI: 10.1021/Ol5012696 |
0.769 |
|
| 2014 |
Jones AC, May JA, Sarpong R, Stoltz BM. Bis hin zu einer Symphonie der Reaktivität: Kaskaden mit Katalysen und sigmatropen Umlagerungen Angewandte Chemie. 126: 2590-2628. DOI: 10.1002/Ange.201302572 |
0.707 |
|
| 2013 |
de Jesus Cortez F, Lapointe D, Hamlin AM, Simmons EM, Sarpong R. Synthetic studies on the icetexones: enantioselective formal syntheses of icetexone and epi-icetexone. Tetrahedron. 69. PMID 24249921 DOI: 10.1016/J.Tet.2013.04.049 |
0.843 |
|
| 2013 |
Mundal DA, Sarpong R. Synthetic studies toward the citrinadin A and B core architecture Organic Letters. 15: 4952-4955. PMID 24050750 DOI: 10.1021/Ol402177A |
0.349 |
|
| 2013 |
Kisunzu JK, Sarpong R. Hidden symmetry enables a 15-step total synthesis of pactamycin Angewandte Chemie - International Edition. 52: 10694-10696. PMID 24039046 DOI: 10.1002/Anie.201305464 |
0.821 |
|
| 2013 |
Heller ST, Kiho T, Narayan AR, Sarpong R. Protic-solvent-mediated cycloisomerization of quinoline and isoquinoline propargylic alcohols: syntheses of (±)-3-demethoxyerythratidinone and (±)-cocculidine. Angewandte Chemie (International Ed. in English). 52: 11129-33. PMID 24009078 DOI: 10.1002/Anie.201304687 |
0.781 |
|
| 2013 |
Hamlin AM, De Jesus Cortez F, Lapointe D, Sarpong R. Gallium(III)-catalyzed cycloisomerization approach to the diterpenoid alkaloids: Construction of the core structure for the hetidines and hetisines Angewandte Chemie - International Edition. 52: 4854-4857. PMID 23533012 DOI: 10.1002/Anie.201209030 |
0.812 |
|
| 2013 |
Schultz EE, Sarpong R. Application of in situ-generated Rh-bound trimethylenemethane variants to the synthesis of 3,4-fused pyrroles. Journal of the American Chemical Society. 135: 4696-9. PMID 23477843 DOI: 10.1021/Ja401380D |
0.675 |
|
| 2013 |
Lebold TP, Wood JL, Deitch J, Lodewyk MW, Tantillo DJ, Sarpong R. A divergent approach to the synthesis of the yohimbinoid alkaloids venenatine and alstovenine. Nature Chemistry. 5: 126-31. PMID 23344433 DOI: 10.1038/Nchem.1528 |
0.724 |
|
| 2013 |
Jeffrey JL, Bartlett ES, Sarpong R. Intramolecular C(sp3)-N coupling by oxidation of benzylic C,N-dianions Angewandte Chemie - International Edition. 52: 2194-2197. PMID 23325610 DOI: 10.1002/Anie.201209591 |
0.783 |
|
| 2013 |
Jeffrey JL, Bartlett ES, Sarpong R. Heterocycle Synthesis by a One-Pot Oxidative C(sp3)–N Coupling Reaction Synfacts. 9: 533-533. DOI: 10.1055/S-0033-1338326 |
0.424 |
|
| 2013 |
Jeffrey JL, Sarpong R. Intramolecular C(sp3)-H amination Chemical Science. 4: 4092-4106. DOI: 10.1039/C3Sc51420J |
0.773 |
|
| 2013 |
Cortez FDJ, Lapointe D, Hamlin AM, Simmons EM, Sarpong R. Synthetic studies on the icetexones: Enantioselective formal syntheses of icetexone and epi-icetexone Tetrahedron. 69: 5665-5676. DOI: 10.1016/j.tet.2013.04.049 |
0.822 |
|
| 2013 |
Sarpong R, Fischer DF. Total synthesis of the lycopodium alkaloid complanadine A Total Synthesis of Natural Products: At the Frontiers of Organic Chemistry. 259-272. DOI: 10.1007/978-3-642-34065-9_11 |
0.357 |
|
| 2013 |
Kisunzu JK, Sarpong R. Totalsynthese von Pactamycin in 15 Stufen: strategische Nutzung latenter Symmetrieelemente Angewandte Chemie. 125: 10890-10892. DOI: 10.1002/Ange.201305464 |
0.745 |
|
| 2012 |
Jeffrey JL, Sarpong R. Chichibabin-type direct alkylation of pyridyl alcohols with alkyl lithium reagents Organic Letters. 14: 5400-5403. PMID 23061536 DOI: 10.1021/Ol3024117 |
0.766 |
|
| 2012 |
Leal RA, Beaudry DR, Alzghari SK, Sarpong R. Synthesis of the pentacyclic skeleton of the indole alkaloid arboflorine Organic Letters. 14: 5350-5353. PMID 23020147 DOI: 10.1021/Ol302535R |
0.474 |
|
| 2012 |
Isaacs AK, Qi S, Sarpong R, Casida JE. Insect ryanodine receptor: distinct but coupled insecticide binding sites for [N-C(3)H(3)]chlorantraniliprole, flubendiamide, and [(3)H]ryanodine. Chemical Research in Toxicology. 25: 1571-3. PMID 22856329 DOI: 10.1021/Tx300326M |
0.764 |
|
| 2012 |
Heller ST, Schultz EE, Sarpong R. Chemoselective N-acylation of indoles and oxazolidinones with carbonylazoles. Angewandte Chemie (International Ed. in English). 51: 8304-8. PMID 22786619 DOI: 10.1002/Anie.201203976 |
0.546 |
|
| 2012 |
Fisher EL, Wilkerson-Hill SM, Sarpong R. Tungsten-catalyzed heterocycloisomerization approach to 4,5-dihydro-benzo[b]furans and -indoles Journal of the American Chemical Society. 134: 9946-9949. PMID 22663199 DOI: 10.1021/Ja3045647 |
0.806 |
|
| 2012 |
Lebold TP, Gallego GM, Marth CJ, Sarpong R. Synthesis of the bridging framework of phragmalin-type limonoids Organic Letters. 14: 2110-2113. PMID 22472049 DOI: 10.1021/Ol300647K |
0.784 |
|
| 2012 |
Heller ST, Fu T, Sarpong R. Dual Brønsted acid/nucleophilic activation of carbonylimidazole derivatives. Organic Letters. 14: 1970-3. PMID 22468924 DOI: 10.1021/Ol300339Q |
0.373 |
|
| 2012 |
Schultz EE, Pujanauski BG, Sarpong R. Synthetic studies toward lapidilectine-type Kopsia alkaloids. Organic Letters. 14: 648-51. PMID 22214219 DOI: 10.1021/Ol203302F |
0.822 |
|
| 2012 |
Murphy RA, Sarpong R. Direct methoxypyridine functionalization approach to magellanine-type Lycopodium alkaloids. Organic Letters. 14: 632-5. PMID 22201223 DOI: 10.1021/Ol203269F |
0.648 |
|
| 2012 |
Hardin Narayan AR, Sarpong R. Indolizinones as synthetic scaffolds: fundamental reactivity and the relay of stereochemical information. Organic & Biomolecular Chemistry. 10: 70-8. PMID 22072189 DOI: 10.1039/C1Ob06423A |
0.456 |
|
| 2012 |
Gallego GM, Sarpong R. Rh(I)-catalyzed enantioselective intramolecular hydroarylation of unactivated ketones with aryl pinacolboronic esters Chemical Science. 3: 1338-1342. DOI: 10.1039/C2Sc01068B |
0.786 |
|
| 2012 |
Sarpong R. Synthesis of the Lycopodium alkaloid lyconadin A: Discovery of a unique C-N bond forming reaction Strategies and Tactics in Organic Synthesis. 8: 291-315. DOI: 10.1016/B978-0-12-386540-3.00013-7 |
0.46 |
|
| 2011 |
Miller LC, Sarpong R. Divergent reactions on racemic mixtures. Chemical Society Reviews. 40: 4550-62. PMID 21629881 DOI: 10.1039/C1Cs15069C |
0.646 |
|
| 2011 |
Heller ST, Sarpong R. On the reactivity of imidazole carbamates and ureas and their use as esterification and amidation reagents Tetrahedron. 67: 8851-8859. DOI: 10.1016/J.Tet.2011.09.057 |
0.395 |
|
| 2010 |
Hardin Narayan AR, Sarpong R. Remarkable facilitation of hetero-cycloisomerizations with water and other polar protic solvents: metal-free synthesis of indolizines. Green Chemistry : An International Journal and Green Chemistry Resource : Gc. 12: 1556-1559. PMID 21572597 DOI: 10.1039/C0Gc00198H |
0.32 |
|
| 2010 |
Ford KA, Casida JE, Chandran D, Gulevich AG, Okrent RA, Durkin KA, Sarpong R, Bunnelle EM, Wildermuth MC. Neonicotinoid insecticides induce salicylate-associated plant defense responses. Proceedings of the National Academy of Sciences of the United States of America. 107: 17527-32. PMID 20876120 DOI: 10.1073/Pnas.1013020107 |
0.762 |
|
| 2010 |
Sarpong R. Natural product synthesis: Clearing the way to cortistatins Nature Chemistry. 2: 803-804. PMID 20861890 DOI: 10.1038/Nchem.802 |
0.478 |
|
| 2010 |
Heller ST, Sarpong R. Chemoselective esterification and amidation of carboxylic acids with imidazole carbamates and ureas. Organic Letters. 12: 4572-5. PMID 20857922 DOI: 10.1021/Ol1018882 |
0.36 |
|
| 2010 |
Marcus AP, Sarpong R. Synthesis of the tetracyclic core of tetrapetalone a enabled by a pyrrole reductive alkyation Organic Letters. 12: 4560-4563. PMID 20843020 DOI: 10.1021/Ol1018536 |
0.768 |
|
| 2010 |
Gruver JM, West SP, Collum DB, Sarpong R. Experimental characterization and computational study of unique C,N-chelated lithium dianions. Journal of the American Chemical Society. 132: 13212-3. PMID 20822143 DOI: 10.1021/Ja106852N |
0.737 |
|
| 2010 |
Lian Y, Miller LC, Born S, Sarpong R, Davies HM. Catalyst-controlled formal [4 + 3] cycloaddition applied to the total synthesis of (+)-barekoxide and (-)-barekol. Journal of the American Chemical Society. 132: 12422-5. PMID 20704267 DOI: 10.1021/Ja103916T |
0.714 |
|
| 2010 |
Simmons EM, Hardin-Narayan AR, Guo X, Sarpong R. Formal total synthesis of (±)-cortistatin A. Tetrahedron. 66: 4696-4700. PMID 20672014 DOI: 10.1016/J.Tet.2010.01.030 |
0.699 |
|
| 2010 |
Bisai V, Sarpong R. Methoxypyridines in the synthesis of lycopodium alkaloids: Total synthesis of (±)-lycoposerramine R Organic Letters. 12: 2551-2553. PMID 20441180 DOI: 10.1021/Ol100823T |
0.42 |
|
| 2010 |
Fischer DF, Sarpong R. Total synthesis of (+)-complanadine a using an iridium-catalyzed pyridine C-H functionalization Journal of the American Chemical Society. 132: 5926-5927. PMID 20387895 DOI: 10.1021/Ja101893B |
0.47 |
|
| 2010 |
De Jesus Cortez F, Sarpong R. Ga(IIl)-catalyzed cycloisomerization approach to (±)-icetexone and (±)-epi-icetexone Organic Letters. 12: 1428-1431. PMID 20192209 DOI: 10.1021/Ol902959V |
0.379 |
|
| 2010 |
Casida JE, Gulevich AG, Sarpong R, Bunnelle EM. S-Arachidonoyl-2-thioglycerol synthesis and use for fluorimetric and colorimetric assays of monoacylglycerol lipase. Bioorganic & Medicinal Chemistry. 18: 1942-7. PMID 20138526 DOI: 10.1016/J.Bmc.2010.01.034 |
0.783 |
|
| 2010 |
Sarpong R, Simmons E, Hardin-Narayan A, Guo X. Formal Synthesis of (±)-Cortistatin A Synfacts. 2010: 1339-1339. DOI: 10.1055/S-0030-1258877 |
0.634 |
|
| 2010 |
Sarpong R, Davies H, Lian Y, Miller L, Born S. Synthesis of (+)-Barekoxide and (-)-Barekol Synfacts. 2010: 1335-1335. DOI: 10.1055/S-0030-1258873 |
0.74 |
|
| 2010 |
Fischer DF, Sarpong R. Synthesis of (+)-Complanadine A Synfacts. 2010: 858-858. DOI: 10.1055/S-0030-1257768 |
0.469 |
|
| 2010 |
Larson KK, Sarpong R. Synthesis of Alkaloid (±)-G. B. 13 Synfacts. 2010: 131-131. DOI: 10.1055/S-0029-1219022 |
0.68 |
|
| 2010 |
Simmons EM, Hardin-Narayan AR, Guo X, Sarpong R. Formal total synthesis of (±)-cortistatin A Tetrahedron. 66: 4696-4700. DOI: 10.1016/j.tet.2010.01.030 |
0.602 |
|
| 2010 |
Hardin-Narayan AR, Simmons EM, Sarpong R. Synthetic strategies directed towards the cortistatin family of natural products European Journal of Organic Chemistry. 3553-3567. DOI: 10.1002/Ejoc.201000247 |
0.649 |
|
| 2009 |
Jeffrey JL, Sarpong R. An approach to the synthesis of dimeric resveratrol natural products via a palladium-catalyzed domino reaction. Tetrahedron Letters. 50: 1969-1972. PMID 20161322 DOI: 10.1016/J.Tetlet.2009.02.067 |
0.802 |
|
| 2009 |
Jeffrey JL, Sarpong R. Concise synthesis of pauciflorol F using a Larock annulation Organic Letters. 11: 5450-5453. PMID 19902905 DOI: 10.1021/Ol902141Z |
0.782 |
|
| 2009 |
Larson KK, Sarpong R. Total synthesis of alkaloid (±)-G. B. 13 Using a Rh(I)-catalyzed ketone hydroarylation and late-stage pyridine reduction Journal of the American Chemical Society. 131: 13244-13245. PMID 19754185 DOI: 10.1021/Ja9063487 |
0.745 |
|
| 2009 |
Simmons EM, Sarpong R. Structure, biosynthetic relationships and chemical synthesis of the icetexane diterpenoids Natural Product Reports. 26: 1195-1217. PMID 19693415 DOI: 10.1039/B908984E |
0.658 |
|
| 2009 |
West SP, Bisai A, Lim AD, Narayan RR, Sarpong R. Total synthesis of (+)-lyconadin A and related compounds via oxidative C-N bond formation Journal of the American Chemical Society. 131: 11187-11194. PMID 19591469 DOI: 10.1021/Ja903868N |
0.817 |
|
| 2009 |
Wood JL, Pujanauski BG, Sarpong R. Synthesis of the tetracyclic core of the neomangicols using a late-stage indene alkylation Organic Letters. 11: 3128-3131. PMID 19527042 DOI: 10.1021/Ol9010008 |
0.804 |
|
| 2009 |
Miller LC, Ndungu JM, Sarpong R. Parallel kinetic resolution approach to the cyathane and cyanthiwigin diterpenes using a cyclopropanation/Cope rearrangement. Angewandte Chemie (International Ed. in English). 48: 2398-402. PMID 19222082 DOI: 10.1002/Anie.200806154 |
0.584 |
|
| 2009 |
Jeffrey JL, Sarpong R. An approach to the synthesis of dimeric resveratrol natural products via a palladium-catalyzed domino reaction Tetrahedron Letters. 50: 1969-1972. DOI: 10.1016/j.tetlet.2009.02.067 |
0.796 |
|
| 2008 |
Bunnelle EM, Smith CR, Lee SK, Singaram SW, Rhodes AJ, Sarpong R. Pt-catalyzed cyclization/migration of propargylic alcohols for the synthesis of 3(2H)-furanones, pyrrolones, indolizines, and indolizinones. Tetrahedron. 64: 7008-7014. PMID 22593605 DOI: 10.1016/J.Tet.2008.02.103 |
0.81 |
|
| 2008 |
Simmons EM, Hardin AR, Guo X, Sarpong R. Rapid construction of the cortistatin pentacyclic core. Angewandte Chemie (International Ed. in English). 47: 6650-3. PMID 18637646 DOI: 10.1002/Anie.200802203 |
0.59 |
|
| 2008 |
Marcus AP, Lee AS, Davis RL, Tantillo DJ, Sarpong R. Pronounced steric effects of substituents in the nazarov cyclization of aryl dienyl ketones. Angewandte Chemie (International Ed. in English). 47: 6379-83. PMID 18618883 DOI: 10.1002/Anie.200801542 |
0.761 |
|
| 2008 |
Ly T, Liu Z, Pujanauski BG, Sarpong R, Julian RR. Surveying ubiquitin structure by noncovalent attachment of distance constrained bis(crown) ethers. Analytical Chemistry. 80: 5059-64. PMID 18498182 DOI: 10.1021/Ac800177S |
0.77 |
|
| 2008 |
Bisai A, West SP, Sarpong R. Unified strategy for the synthesis of the "miscellaneous" Lycopodium alkaloids: Total synthesis of (±)-lyconadin A Journal of the American Chemical Society. 130: 7222-7223. PMID 18479095 DOI: 10.1021/Ja8028069 |
0.852 |
|
| 2008 |
Bisai A, West SP, Sarpong R. Synthesis of (±)-Lyconadin A Synfacts. 2008: 1251-1251. DOI: 10.1055/S-0028-1087292 |
0.784 |
|
| 2008 |
Sarpong R. Book Review of Metal Vinylidenes and Allenylidenes in Catalysis: From Reactivity to Applications in Synthesis Metal Vinylidenes and Allenylidenes in Catalysis: From Reactivity to Applications in Synthesis . Edited by Christian Bruneau and Pierre Dixneuf (CNRS-Universé de Rennes I, France). Wiley-VCH Verlag GmbH & Co. KgaA: Weinheim. 2008. xviii + 338 pp. $200. ISBN 978-3-527-31892-6 . Journal of the American Chemical Society. 130: 14901-14901. DOI: 10.1021/Ja807249D |
0.335 |
|
| 2008 |
Bunnelle EM, Smith CR, Lee SK, Singaram SW, Rhodes AJ, Sarpong R. Pt-catalyzed cyclization/migration of propargylic alcohols for the synthesis of 3(2H)-furanones, pyrrolones, indolizines, and indolizinones Tetrahedron. 64: 7008-7014. DOI: 10.1016/j.tet.2008.02.103 |
0.791 |
|
| 2007 |
Hardin AR, Sarpong R. Electronic effects in the pt-catalyzed cycloisomerization of propargylic esters: synthesis of 2,3-disubstituted indolizines as a mechanistic probe. Organic Letters. 9: 4547-50. PMID 17845052 DOI: 10.1021/Ol701973S |
0.393 |
|
| 2007 |
Simmons EM, Yen JR, Sarpong R. Reconciling icetexane biosynthetic connections with their chemical synthesis: Total synthesis of (±)-5,6-dihydro-6α- hydroxysalviasperanol, (±)-brussonol, and (±)-abrotanone Organic Letters. 9: 2705-2708. PMID 17559223 DOI: 10.1021/Ol0712428 |
0.656 |
|
| 2007 |
Motamed M, Bunnelle EM, Singaram SW, Sarpong R. Pt(II)-catalyzed synthesis of 1,2-dihydropyridines from aziridinyl propargylic esters Organic Letters. 9: 2167-2170. PMID 17451249 DOI: 10.1021/Ol070658I |
0.809 |
|
| 2007 |
Smith CR, Bunnelle EM, Rhodes AJ, Sarpong R. Pt-catalyzed cyclization/1,2-migration for the synthesis of indolizines, pyrrolones, and indolizinones Organic Letters. 9: 1169-1171. PMID 17309277 DOI: 10.1021/Ol0701971 |
0.824 |
|
| 2007 |
Simmons EM, Yen JR, Sarpong R. Reconciling Icetexane Biosynthetic Connections with Their Chemical Synthesis: Total Synthesis of (.+-.)-5,6-Dihydro-6α-hydroxysalviasperanol (I), (.+-.)-Brussonol (II), and (.+-.)-Abrotanone (III). Cheminform. 38. DOI: 10.1002/chin.200744168 |
0.642 |
|
| 2006 |
Simmons EM, Sarpong R. Ga(III)-catalyzed cycloisomerization strategy for the synthesis of icetexane diterpenoids: Total synthesis of (±)-salviasperanol Organic Letters. 8: 2883-2886. PMID 16774281 DOI: 10.1021/Ol061037C |
0.724 |
|
| 2006 |
Pujanauski BG, Bhanu Prasad BA, Sarpong R. Pt-catalyzed tandem epoxide fragmentation/pentannulation of propargylic esters Journal of the American Chemical Society. 128: 6786-6787. PMID 16719448 DOI: 10.1021/Ja061549M |
0.817 |
|
| 2006 |
Ro DK, Paradise EM, Ouellet M, Fisher KJ, Newman KL, Ndungu JM, Ho KA, Eachus RA, Ham TS, Kirby J, Chang MC, Withers ST, Shiba Y, Sarpong R, Keasling JD. Production of the antimalarial drug precursor artemisinic acid in engineered yeast. Nature. 440: 940-3. PMID 16612385 DOI: 10.1038/Nature04640 |
0.303 |
|
| 2006 |
Sarpong R, Simmons E. Synthesis of (±)-Salviasperanol Synfacts. 2006: 1207-1207. DOI: 10.1055/S-2006-955601 |
0.63 |
|
| 2006 |
Yao T, Hong A, Sarpong R. Synthesis of multifunctionalized furans from diazoallenes: Rearrangement of 6-methylenebicyclo[3.1.0] hexanes Synthesis. 3605-3610. DOI: 10.1055/S-2006-950215 |
0.503 |
|
| 2005 |
Ndungu JM, Larson KK, Sarpong R. Development of an anomalous Heck reaction: skeletal rearrangement of divinyl and enyne carbinols. Organic Letters. 7: 5845-8. PMID 16354081 DOI: 10.1021/Ol052382P |
0.719 |
|
| 2005 |
Bhanu Prasad BA, Yoshimoto FK, Sarpong R. Pt-catalyzed pentannulations from in situ generated metallo-carbenoids utilizing propargylic esters Journal of the American Chemical Society. 127: 12468-12469. PMID 16144376 DOI: 10.1021/Ja053192C |
0.387 |
|
| 2005 |
Ndungu JM, Larson KK, Sarpong R. Development of an anomalous heck reaction: Skeletal rearrangement of divinyl and enyne carbinols Organic Letters. 7: 5845-5848. DOI: 10.1021/ol052382p |
0.669 |
|
| 2004 |
Su JT, Sarpong R, Stoltz BM, Goddard WA. Substituent effects and nearly degenerate transition states: rational design of substrates for the tandem Wolff-Cope reaction. Journal of the American Chemical Society. 126: 24-5. PMID 14709041 DOI: 10.1021/Ja037716P |
0.521 |
|
| 2004 |
Semmelhack MF, Sarpong R. Kinetic analysis of a reactive model enediyne Journal of Physical Organic Chemistry. 17: 807-813. DOI: 10.1002/Poc.798 |
0.548 |
|
| 2004 |
Su JT, Sarpong R, Stoltz BM, Goddard WA. Substituent Effects and Nearly Degenerate Transition States: Rational Design of Substrates for the Tandem Wolff-Cope Reaction Journal of the American Chemical Society. 126: 24-25. |
0.427 |
|
| 2003 |
Sarpong R, Su JT, Stoltz BM. The development of a facile tandem Wolff/Cope rearrangement for the synthesis of fused carbocyclic skeletons. Journal of the American Chemical Society. 125: 13624-5. PMID 14599176 DOI: 10.1021/Ja037587C |
0.586 |
|
| 2002 |
Garg NK, Sarpong R, Stoltz BM. The first total synthesis of dragmacidin d. Journal of the American Chemical Society. 124: 13179-84. PMID 12405846 DOI: 10.1021/Ja027822B |
0.701 |
|
| 2002 |
Semmelhack MF, Jaskowski M, Sarpong R, Ho DM. A simple synthesis and evaluation of the bicyclo[8.3.0] enediyne framework Tetrahedron Letters. 43: 4947-4950. DOI: 10.1016/S0040-4039(02)00940-1 |
0.636 |
|
| 2002 |
Semmelhack MF, Sarpong R, Bergman J, Ho DM. Evaluation of alkene isomerization as a trigger for enediyne activation Tetrahedron Letters. 43: 541-544. DOI: 10.1016/S0040-4039(01)02139-6 |
0.554 |
|
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