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Hans-Herbert Brintzinger - Publications

Affiliations: 
Chemistry University of Konstanz, Konstanz, Germany 
 1965-1973 Chemistry University of Michigan, Ann Arbor, Ann Arbor, MI 
Area:
reactivities of organometallic compounds, e.g. as catalysts for polymerization reactions
Website:
http://www.chemie.uni-konstanz.de/~agbri/brintzinger.html

126 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Panchenko VN, Babushkin DE, Bercaw JE, Brintzinger HH. Catalyst Speciation During -Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy-Formation and Partial Re-Activation of Zr-Allyl Intermediates. Polymers. 11. PMID 31146475 DOI: 10.3390/Polym11060936  0.637
2014 Babushkin DE, Panchenko VN, Brintzinger HH. Zirconium allyl complexes as participants in zirconocene-catalyzed α-olefin polymerizations. Angewandte Chemie (International Ed. in English). 53: 9645-9. PMID 25044470 DOI: 10.1002/Anie.201403673  0.343
2013 Lenton TN, Bercaw JE, Panchenko VN, Zakharov VA, Babushkin DE, Soshnikov IE, Talsi EP, Brintzinger HH. Formation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: an EPR- and NMR-spectroscopic study. Journal of the American Chemical Society. 135: 10710-9. PMID 23745750 DOI: 10.1021/Ja403170U  0.771
2011 Baldwin SM, Bercaw JE, Henling LM, Day MW, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides: NMR-spectroscopic identification, crystallographic structure determination, and interconversion with other zirconocene cations. Journal of the American Chemical Society. 133: 1805-13. PMID 21244016 DOI: 10.1021/Ja1050428  0.801
2010 Baldwin SM, Bercaw JE, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides as participants in olefin polymerization catalysis. Journal of the American Chemical Society. 132: 13969-71. PMID 20860389 DOI: 10.1021/Ja105040R  0.798
2008 Baldwin SM, Bercaw JE, Brintzinger HH. Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy. Journal of the American Chemical Society. 130: 17423-33. PMID 19032092 DOI: 10.1021/Ja8054723  0.776
2008 Babushkin DE, Panchenko VN, Timofeeva MN, Zakharov VA, Brintzinger HH. Novel zirconocene hydride complexes in homogeneous and in SiO 2-supported olefin-polymerization catalysts modified with diisobutylaluminum hydride or triisobutylaluminum Macromolecular Chemistry and Physics. 209: 1210-1219. DOI: 10.1002/Macp.200800084  0.382
2007 Babushkin DE, Brintzinger HH. Modification of methylaluminoxane-activated ansa-zirconocene catalysts with triisobutylaluminum-transformations of reactive cations studied by NMR spectroscopy. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 5294-9. PMID 17385201 DOI: 10.1002/Chem.200601801  0.341
2006 Babushkin DE, Naundorf C, Brintzinger HH. Distinct methylalumoxane(MAO)-derived Me-MAO- anions in contact with a zirconocenium cation--a 13C-NMR study. Dalton Transactions (Cambridge, England : 2003). 4539-44. PMID 17016564 DOI: 10.1039/B611028M  0.313
2006 Wieser U, Schaper F, Brintzinger HH. Methylalumoxane (MAO)-derived MeMAO- anions in zirconocene-based polymerization catalyst systems - A UV-vis spectroscopic study Macromolecular Symposia. 236: 63-68. DOI: 10.1002/Masy.200690068  0.576
2005 Bryliakov KP, Kravtsov EA, Pennington DA, Lancaster SJ, Bochmann M, Brintzinger HH, Talsi EP. Active intermediates in ethylene polymerization over titanium bis(phenoxyimine) catalysts Organometallics. 24: 5660-5664. DOI: 10.1021/Om0505920  0.389
2005 Bryliakov KP, Babushkin DE, Talsi EP, Voskoboynikov AZ, Gritzo H, Schröder L, Damrau HRH, Wieser U, Schaper F, Brintzinger HH. Ansa-titanocene catalysts for α-Olefin polymerization. Syntheses, structures, and reactions with methylaluminoxane and boron-based activators Organometallics. 24: 894-904. DOI: 10.1021/Om0492496  0.665
2005 Schröder L, Brintzinger HH, Babushkin DE, Fischer D, Mülhaupt R. Rac-Me2Si(2-Me-4-t-Bu-C5H2) 2ZrMe+: An alkyl zirconocenium cation stabilized by steric shielding against interaction with ancillary ligands Organometallics. 24: 867-871. DOI: 10.1021/Om049139Z  0.337
2005 Bhriain NN, Brintzinger HH, Ruchatz D, Fink G. Polymeryl exchange between cmsa-zirconocene catalysts for norbornene-ethene copolymerization and aluminum or zinc alkyls Macromolecules. 38: 2056-2063. DOI: 10.1021/Ma0401166  0.368
2005 Kettunen M, Vedder C, Brintzinger HH, Mutikainen I, Leskelä M, Repo T. Alternative coordination modes in palladium(II)-diimino-bispyridine complexes with an axially chiral biphenyl backbone European Journal of Inorganic Chemistry. 1081-1089. DOI: 10.1002/Ejic.200400913  0.362
2005 Vedder C, Schaper F, Brintzinger HH, Kettunen M, Babik S, Fink G. Chiral iron(II) and cobalt(II) complexes with biphenyl-bridged bis(pyridylimine) ligands - Syntheses, structures and reactivities European Journal of Inorganic Chemistry. 1071-1080. DOI: 10.1002/Ejic.200400912  0.627
2004 Gritzo H, Schaper F, Brintzinger HH. Bis(η3-indenyl)bis(tetrahydrofuran)magnesium(II) Acta Crystallographica Section E: Structure Reports Online. 60: m1108-m1110. DOI: 10.1107/S1600536804016149  0.557
2004 Schaper F, Wrobel O, Schwörer R, Brintzinger HH. Me2Si(C5Me4)2Cr: Synthesis and crystal structure of a ligand-free ansa-chromocene Organometallics. 23: 3552-3555. DOI: 10.1021/Om049901X  0.607
2004 Kettunen M, Vedder C, Schaper F, Leskelä M, Mutikainen I, Brintzinger HH. Chiral zirconium complexes with bianiline-based N4-donor ligands Organometallics. 23: 3800-3807. DOI: 10.1021/Om040011R  0.619
2004 Wrobel O, Schaper F, Brintzinger HH. Bulky siloxyaluminum alkyls as models for Al2Me6-treated silica gel surfaces. Characterization of a dimethylaniline-stabilized dimethylaluminum cation Organometallics. 23: 900-905. DOI: 10.1021/Om030589L  0.603
2003 Wrobel O, Schaper F, Wieser U, Gregorius H, Brintzinger HH. Siloxyaluminum alkyl cations: Syntheses, structures, and reactions related to activation of zirconocene catalysts on silica gel surfaces Organometallics. 22: 1320-1325. DOI: 10.1021/Om0207515  0.577
2002 Babushkin DE, Brintzinger HH. Activation of dimethyl zirconocene by methylaluminoxane (MAO)-size estimate for Me-MAO(-) anions by pulsed field-gradient NMR. Journal of the American Chemical Society. 124: 12869-73. PMID 12392434 DOI: 10.1021/Ja020646M  0.361
2002 Selg P, Brintzinger HH, Schultz M, Andersen RA. Solution infrared spectroscopic studies on equilibrium reactions of CO with the decamethylmetallocenes Cp*2MII, where MII = Mg, Ca, Sr, Ba, Sm, Eu, Yb Organometallics. 21: 3100-3107. DOI: 10.1021/Om011045R  0.308
2002 Wieser U, Schaper F, Brintzinger HH, Mäkelä NI, Knuuttila HR, Leskelä M. Effects of an interannular bridge on spectral and electronic properties of bis(cyclopentadienyl)- and bis(indenyl)zirconium (IV) complexes Organometallics. 21: 541-545. DOI: 10.1021/Om010770Z  0.587
2002 Wieser U, Babushkin D, Brintzinger HH. Methyl-versus-chloride exchange as a measure of electron density at the metal center of ring-substituted zirconocene complexes Organometallics. 21: 920-923. DOI: 10.1021/Om0107688  0.371
2002 Schaper F, Geyer A, Brintzinger HH. Displacement of H3CB(C6F5)3 - anions from zirconocene methyl cations by neutral ligand molecules: Equilibria, kinetics, and mechanisms Organometallics. 21: 473-483. DOI: 10.1021/Om010671L  0.626
2002 Hüttenhofer M, Schaper F, Brintzinger HH. 8-sila-4-stanna-s-tetrahydroindacenes as synthons for Me2Si-bridged zirconocenes: Formation from biscyclopentadienyl silanes by reaction with aminostannanes Journal of Organometallic Chemistry. 660: 85-90. DOI: 10.1016/S0022-328X(02)01775-8  0.617
2002 Royo E, Brintzinger HH. Mass spectrometry of polystyrene and polypropene ruthenium complexes. A new tool for polymer characterization Journal of Organometallic Chemistry. 663: 213-220. DOI: 10.1016/S0022-328X(02)01770-9  0.301
2002 Hüttenhofer M, Weeber A, Brintzinger HH. Mechanisms of Sn-to-Zr cyclopentadienyl transfer in the formation of Me2Si-bridged zirconocenes from sila-stanna-tetrahydro-s-indacenes Journal of Organometallic Chemistry. 663: 58-62. DOI: 10.1016/S0022-328X(02)01653-4  0.357
2001 Schaper F, Brintzinger H. Tetrahydrothiophene tris(pentafluorophenyl)borane Acta Crystallographica Section E Structure Reports Online. 58: o77-o78. DOI: 10.1107/S160053680102027X  0.56
2001 Damrau HRH, Royo E, Obert S, Schaper F, Weeber A, Brintzinger HH. Racemo-selective synthesis of ansa-zirconocene derivates from zirconium biphenolate complexes Organometallics. 20: 5258-5265. DOI: 10.1021/Om010605J  0.625
2001 Beck S, Lieber S, Schaper F, Geyer A, Brintzinger HH. Anion exchange in alkyl-zirconocene borate ion pairs. Are solvated alkyl-zirconocene cations relevant intermediates? Journal of the American Chemical Society. 123: 1483-1489. DOI: 10.1021/Ja003531W  0.548
2000 Schaper F, Brintzinger HH. [{Me(4)C(2)(C(5)H(4))(2)}Zr(BH(4))(2)], a bis(tetrahydroborate) complex of a bridged zirconocene. Acta Crystallographica. Section C, Crystal Structure Communications. 56: E78. PMID 15263202 DOI: 10.1107/S0108270100002250  0.569
2000 Weeber A, Harder S, Brintzinger HH, Knoll K. Homoleptic and Heteroleptic Barium Benzyl Complexes: Synthesis and Reactivity as Initiators for Anionic Styrene Polymerizations Organometallics. 19: 1325-1332. DOI: 10.1021/Om990705D  0.645
2000 Lieber S, Prosenc MH, Brintzinger HH. Zirconocene allyl complexes: Dynamics in solution, reaction with aluminum alkyls, B(C6F5)3-induced propene insertion, and density-functional calculations on possible formation and reaction pathways Organometallics. 19: 377-387. DOI: 10.1021/Om9906058  0.466
2000 Schneider N, Schaper F, Schmidt K, Kirsten R, Geyer A, Brintzinger HH. Zirconocene complexes with cyclopenta[l]phenanthrene ligands: syntheses, structural dynamics, and properties as olefin polymerization catalysts Organometallics. 19: 3597-3604. DOI: 10.1021/Om000149J  0.577
2000 Lieber S, Brintzinger HH. Propene polymerization with catalyst mixtures containing different ansa-zirconocenes: chain transfer to alkylaluminum cocatalysts and formation of stereoblock polymers Macromolecules. 33: 9192-9199. DOI: 10.1021/Ma000691J  0.309
1999 Ringwald M, Stürmer R, Brintzinger HH. Asymmetric thermal transformation, a new way to enantiopure biphenyl- bridged titanocene and zirconocene complexes: Efficient catalysts for asymmetric imine hydrogenation Journal of the American Chemical Society. 121: 1524-1527. DOI: 10.1021/Ja983524W  0.372
1999 Brintzinger HH, Prosenc MH, Schaper F, Weeber A, Wieser U. Alternative force field models for ansa-zirconocene complexes - Vibrational and structural studies on Me2Si-bridged and tert-butyl- substituted representatives Journal of Molecular Structure. 485: 409-419. DOI: 10.1016/S0022-2860(99)00184-2  0.597
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-Zirconocene via a Novel S -Symmetric Spirobis(silastannaindacene) Compound. Angewandte Chemie (International Ed. in English). 37: 2268-2270. PMID 29711458 DOI: 10.1002/(Sici)1521-3773(19980904)37:16<2268::Aid-Anie2268>3.0.Co;2-Y  0.595
1998 Leyser N, Schmidt K, Brintzinger HH. Phosphonium-bridged alkali and alkaline-earth metallocene complexes Organometallics. 17: 2155-2161. DOI: 10.1021/Om971122B  0.375
1998 Beck S, Prosenc MH, Brintzinger HH. Displacement of weakly coordinating anions from zirconocene alkyl cations by trialkyl phosphines: A model for olefin coordination in homogeneous Ziegler-Natta catalysis Journal of Molecular Catalysis a: Chemical. 128: 41-52. DOI: 10.1016/S1381-1169(97)00161-1  0.362
1998 Damrau HRH, Geyer A, Prosenc MH, Weeber A, Schaper F, Brintzinger HH. Ansa-Metallocene derivatives1: XLI. Chiral ansa-Magnesocene complexes-syntheses, crystal structures and structural dynamics in solution Journal of Organometallic Chemistry. 553: 331-343. DOI: 10.1016/S0022-328X(97)00618-9  0.627
1998 Beck S, Brintzinger HH, Suhm J, Mülhaupt R. Propene polymerization with rac-Me2Si(2-Me-Benz[e]Ind)2ZrX2 [X = Cl, Me] using different cation-generating reagents Macromolecular Rapid Communications. 19: 235-239. DOI: 10.1002/(Sici)1521-3927(19980501)19:5<235::Aid-Marc235>3.0.Co;2-S  0.334
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthesis of an ansa-zirconocene via a novel S4-symmetric spirobis(silastannaindacene) compound Angewandte Chemie - International Edition. 37: 2268-2270. DOI: 10.1002/(SICI)1521-3773(19980904)37:16<2268::AID-ANIE2268>3.0.CO;2-Y  0.453
1998 Hüttenhofer M, Schaper F, Brintzinger HH. Synthese eines Ansa-Zirconocens über eine neueS4-symmetrische Spirobis(silastannaindacen)-Verbindung Angewandte Chemie. 110: 2378-2380. DOI: 10.1002/(Sici)1521-3757(19980817)110:16<2378::Aid-Ange2378>3.0.Co;2-W  0.503
1997 Dorer B, Prosenc MH, Rief U, Brintzinger HH. ansa-vanadocene complexes - Syntheses, structures and ligand exchange reactions Collection of Czechoslovak Chemical Communications. 62: 265-278. DOI: 10.1135/Cccc19970265  0.486
1997 Prosenc MH, Brintzinger HH. Zirconium-alkyl isomerizations in zirconocene-catalyzed olefin polymerization: A density functional study Organometallics. 16: 3889-3894. DOI: 10.1021/Om970227B  0.426
1997 Schneider N, Huttenloch ME, Stehling U, Kirsten R, Schaper F, Brintzinger HH. Ansa-Zirconocene complexes with modified benzindenyl ligands: syntheses, crystal structure, and properties as propene polymerization catalysts Organometallics. 16: 3413-3420. DOI: 10.1021/Om970131H  0.58
1997 Schmidt K, Reinmuth A, Rief U, Diebold J, Brintzinger HH. Photochemical isomerization of Me2Si-bridged zirconocene complexes. Application to stereoselective syntheses of ansa-zirconocene binaphtholate stereoisomers Organometallics. 16: 1724-1728. DOI: 10.1021/Om961089D  0.375
1997 Schneider MJ, Suhm J, Mülhaupt R, Prosenc MH, Brintzinger HH. Influence of indenyl ligand substitution pattern on metallocene-catalyzed ethene copolymerization with 1-octene Macromolecules. 30: 3164-3168. DOI: 10.1021/Ma961844Z  0.375
1997 Sacchi MC, Barsties E, Tritto I, Locatelli P, Brintzinger HH, Stehling U. Stereochemistry of first monomer insertion into metal-methyl bond: A tool for evaluating ligand-monomer interactions in propene polymerization with metallocene catalysts Macromolecules. 30: X-3957. DOI: 10.1021/Ma960720J  0.404
1997 Langhauser F, Fischer D, Kerth Ju, Schweier Gu, Barsties E, Brintzinger H, Schaible S, Roell W. Supported metallocene complexes having heterofunctional groups in the cyclopentadienyl system as catalyst systems Journal of Molecular Catalysis a-Chemical. 125: 174. DOI: 10.1016/S1381-1169(98)80087-3  0.376
1997 Schneider N, Prosenc MH, Brintzinger HH. Cyclopenta[l]phenanthrene titanium trichloride derivatives: Syntheses, crystal structure and properties as catalysts for styrene polymerization Journal of Organometallic Chemistry. 545: 291-295. DOI: 10.1016/S0022-328X(97)00251-9  0.384
1997 Huttenloch ME, Dorer B, Rief U, Prosenc MH, Schmidt K, Brintzinger HH. Ansa-metallocene derivatives XXXIX: Biphenyl-bridged metallocene complexes of titanium, zirconium, and vanadium: Syntheses, crystal structures and enantioseparation Journal of Organometallic Chemistry. 541: 219-232. DOI: 10.1016/S0022-328X(97)00064-8  0.379
1997 Schaper F, Rentzsch M, Prosenc MH, Rief U, Schmidt K, Brintzinger HH. ansa-Metallocene derivatives XXXVI. Dimethylsilyl-bridged permethyl chromocene carbonyl complexes - Syntheses, crystal structures and interconversion reactions Journal of Organometallic Chemistry. 534: 67-79. DOI: 10.1016/S0022-328X(96)06895-7  0.643
1996 Hüttenhofer M, Prosenc MH, Rief U, Schaper F, Brintzinger HH. Substituted silastannatetrahydro-s-indacenes as cyclopentadienyl transfer agents in the synthesis of silanediyl-bridged zirconocene complexes Organometallics. 15: 4816-4822. DOI: 10.1021/Om960305F  0.576
1996 Bühl M, Hopp G, Von Philipsborn W, Beck S, Prosenc MH, Rief U, Brintzinger HH. Zirconium-91 chemical shifts and line widths as indicators of coordination geometry distortions in zirconocene complexes Organometallics. 15: 778-785. DOI: 10.1021/Om950757C  0.327
1996 Leclerc MK, Brintzinger HH. Zr-alkyl isomerization in ansa-zirconocene-catalyzed olefin polymerizations. Contributions to stereoerror formation and chain termination Journal of the American Chemical Society. 118: 9024-9032. DOI: 10.1021/Ja961157N  0.301
1996 Beck S, Prosenc MH, Brintzinger HH, Goretzki R, Herfert N, Fink G. Binuclear zirconocene cations with μ-CH3-bridges in homogeneous Ziegler-Natta catalyst systems Journal of Molecular Catalysis a: Chemical. 111: 67-79. DOI: 10.1016/1381-1169(96)00168-9  0.351
1996 Barsties E, Schaible S, Prosenc MH, Rief U, Röll W, Weyand O, Dorer B, Brintzinger HH. ansa-metallocene derivatives XXXIII. 2-Dimethylamino-substituted bis-indenyl zirconium dichloride complexes with and without a dimethylsilyl bridge: Syntheses, crystal structures and properties in propene polymerization catalysis Journal of Organometallic Chemistry. 520: 63-68. DOI: 10.1016/0022-328X(96)06263-8  0.443
1996 Mansel S, Rief U, Prosenc MH, Kirsten R, Brintzinger HH. ansa-Metallocene derivatives XXXII. Zirconocene complexes with a spirosilane bridge: Syntheses, crystal structures and properties as olefin polymerization catalysts Journal of Organometallic Chemistry. 512: 225-236. DOI: 10.1016/0022-328X(95)06073-6  0.421
1995 Leclerc MK, Brintzinger HH. Origins of stereoselectivity and stereoerror formation in ansa-zirconocene-catalyzed isotactic propene polymerization. A deuterium labeling study Journal of the American Chemical Society. 117: 1651-1652. DOI: 10.1021/Ja00110A027  0.308
1995 Jüngling S, Mülhaupt R, Stehling U, Brintzinger H, Fischer D, Langhauser F. The role of dormant sites in propene polymerization using methylalumoxane activated metallocene catalysts Macromolecular Symposia. 97: 205-216. DOI: 10.1002/Masy.19950970121  0.332
1995 Brintzinger H. Corrigendum : ["Stereospecific Olefin Polymerization with Chiral Metallocene Catalysts" by H. H. Brintzinger et al. (Angew. Chem. Int. Ed. Engl. 1995, 34, 1143-1170)] Angewandte Chemie. 34: 1368-1368. DOI: 10.1002/Anie.199513681  0.315
1995 Selg P, Brintzinger HH, Andersen RA, Horváth IT. Coordination of CO to the alkaline earth metallocene [(Me5C5)2Ca] Angewandte Chemie (International Edition in English). 34: 791-793. DOI: 10.1002/Anie.199507911  0.362
1993 Scott P, Rief U, Diebold J, Brintzinger HH. Homo- and heterobimetallic bis(fulvalene) complexes from bis(cyclopentadienyl)- and bis(indenyl)-substituted ferrocenes Organometallics. 12: 3094-3101. DOI: 10.1021/Om00032A036  0.427
1993 Mengele W, Diebold J, Troll G, Röll W, Brintzinger HH. ansa-metallocene derivatives. 27. Chiral zirconocene complexes with two dimethylsilylene bridges Organometallics. 12: 1931-1935. DOI: 10.1021/Om00029A057  0.376
1993 Katz TJ, Gilbert AM, Huttenloch ME, Min-Min G, Brintzinger HH. Palladium-catalyzed coupling of 2,2t - ́dihalobiaryls with metallated cyclopentenes. An easy synthesis for spiro[cyclopentene-1,9-[9H]fluorene]s Tetrahedron Letters. 34: 3551-3554. DOI: 10.1016/S0040-4039(00)73633-1  0.374
1993 Rieger B, Reinmuth A, Röll W, Brintzinger HH. Highly isotactic polypropene prepared with rac-dimethylsilyl-bis (2-methyl-4-t-butyl-cyclopentadienyl) zirconiumdichloride: An NMR investigation of the polymer microstructure Journal of Molecular Catalysis. 82: 67-73. DOI: 10.1016/0304-5102(93)80071-2  0.302
1993 Niemann U, Diebold J, Troll C, Rief U, Brintzinger HH. Zirconocene dipicolinate and related dicarboxylate complexes: Coordination geometries and reactivities Journal of Organometallic Chemistry. 456: 195-204. DOI: 10.1016/0022-328X(93)80426-C  0.433
1993 Hortmann K, Diebold J, Brintzinger HH. Ketene acetal metallocene complexes. Crystal structure of (C5H5) 2Ti(Cl)OC(OCH3)C(CH3)2 Journal of Organometallic Chemistry. 445: 107-109. DOI: 10.1016/0022-328X(93)80194-G  0.4
1992 Dorer B, Diebold J, Weyand O, Brintzinger HH. ansa-Metallocene derivatives. XXV. Synthesis, crystal structure and reactions of a tetramethylethano-bridged vanadocene dichloride, (CH3)4C2(C5H4)2VCl2 Journal of Organometallic Chemistry. 427: 245-255. DOI: 10.1016/0022-328X(92)83088-Y  0.384
1991 Burger P, Brintzinger HH. ansa-Metallocene derivatives. XXI. Syntheses of etheno-bridged ansa-titanocene derivatives by the McMurry reaction Journal of Organometallic Chemistry. 407: 207-213. DOI: 10.1016/0022-328X(91)86118-A  0.588
1991 Burger P, Hortmann K, Diebold J, Brintzinger HH. ansa-Metallocene derivatives. XXIII . Aryl-substituted titanocene and zirconocene complexes with interannular tetramethylethano- or dimethylsilano-bridges. Crystal structures of representative examples Journal of Organometallic Chemistry. 417: 9-27. DOI: 10.1016/0022-328X(91)80157-F  0.571
1990 Gutmann S, Burger P, Prosenc MH, Brintzinger HH. ansa-Metallocene derivatives XX. An assignment of 1H- and 13C-NMR signals in ansa-metallocene complexes with 16-electron and 18-electron configuration Journal of Organometallic Chemistry. 397: 21-28. DOI: 10.1016/0022-328X(90)85310-U  0.519
1990 Krauledat H, Brintzinger H. Isotopeneffekte bei der α-Olefineinschiebung in Zirconocen-Polymerisationskatalysatoren : Hinweise auf einen Übergangszustand mit α-agostischer Wechselwirkung Angewandte Chemie. 102: 1459-1460. DOI: 10.1002/Ange.19901021219  0.301
1989 Mönkeberg S, van Raaij E, Kiesele H, Brintzinger HH. CO-induced ring-slippage reactions of molybdenocene and tungstenocene carbonyl complexes. Electrochemical and elevated-pressure infrared evidence for an electron-transfer catalysis Journal of Organometallic Chemistry. 365: 285-295. DOI: 10.1016/0022-328X(89)87027-5  0.416
1989 Wiesenfeldt H, Reinmuth A, Barsties E, Evertz K, Brintzinger HH. ansa-Metallocene derivatives. XVII. Racemic and meso diastereomers of group IV metallocene derivatives with symmetrically substituted, dimethylsilanediyl-bridged ligand frameworks. Crystal structure of R,S-Me2Si(3-t-Bu-5-MeC5H2)2ZrCl2 Journal of Organometallic Chemistry. 369: 359-370. DOI: 10.1016/0022-328X(89)85186-1  0.349
1989 Gutmann S, Burger P, Hund HU, Hofmann J, Brintzinger HH. ansa-Metallocene derivatives. XVI. Chiral titanocene and zirconocene derivatives with symmetrically substituted, tetramethylethanediyl-bridged ligand frameworks. Crystal structures of representative examples Journal of Organometallic Chemistry. 369: 343-357. DOI: 10.1016/0022-328X(89)85185-X  0.569
1989 Luinstra GA, Teuben JH, Brintzinger HH. IR studies at elevated gas pressures III. Kinetics of the CO induced disproportionation of (C5(CH3)5)2TiX (X = Cl, Br, I) Journal of Organometallic Chemistry. 375: 183-190. DOI: 10.1016/0022-328X(89)85112-5  0.78
1989 Burger P, Hund HU, Evertz K, Brintzinger HH. ansa-Metallocene derivatives XVIII. Chiral titanocene derivatives accessible from substituted dihydropentalene and azulene precursors Journal of Organometallic Chemistry. 378: 153-161. DOI: 10.1016/0022-328X(89)80004-X  0.536
1988 van Raaij EU, Brintzinger HH. ansa-Metallocene derivatives. XV. Reversible coordination of a second CO ligand to (C5H5)2Cr(CO) and its tetramethylethanediyl-bridged analogue. Evidence for an electron-transfer catalysed ring-slippage reaction. IR studies at elevated gas pressure. II Journal of Organometallic Chemistry. 356: 315-323. DOI: 10.1016/0022-328X(88)83149-8  0.425
1988 van Raaij EU, Mönkeberg S, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. XIV. Electrochemical reactions of unbridged and of tetramethylethanediyl-bridged chromocene carbonyl complexes Journal of Organometallic Chemistry. 356: 307-314. DOI: 10.1016/0022-328X(88)83148-6  0.377
1988 Meirim MG, Neuse EW, Rhemtula M, Schmitt S, Brintzinger HH. Aqueous-phase synthesis of di-(η5-cyclopentadienyl)salicylato- anddi-(η5-cyclopentadienyl)phthalatotitanium(IV) complexes Transition Metal Chemistry. 13: 272-276. DOI: 10.1007/Bf01025672  0.424
1987 Schäfer A, Karl E, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. XII. Diastereomeric derivatisation and enantiomer separation of ethylenebis(tetrahydronindenyl)-titanium and -zirconium dichlorides Journal of Organometallic Chemistry. 328: 87-99. DOI: 10.1016/S0022-328X(00)99770-5  0.312
1987 Van Raaij EU, David Schmulbach C, Brintzinger HH. Equilibria and kinetics in the CO-induced, reversible disproportionation of ((C5H5)2TiCl)2 to (C5H5)2TiCl2 and (C5H52Ti(CO)2. An IR study at elevated CO gas pressures Journal of Organometallic Chemistry. 328: 275-285. DOI: 10.1016/0022-328X(87)80245-0  0.372
1987 Röll W, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. XI. Synthesis and crystal structure of a chiral ansa-titanocene derivative with trimethylene-bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 322: 65-70. DOI: 10.1016/0022-328X(85)80104-2  0.388
1986 Wochner F, Brintzinger HH. ansa-metallocene derivatives. X. Hydrogenolysis of the zirconium-alkyl bond in bridged and unbridged alkyl zirconocene derivatives. Evidence for direct and ring-mediated hydrogen transfer reactions Journal of Organometallic Chemistry. 309: 65-75. DOI: 10.1016/S0022-328X(00)99574-3  0.426
1986 Leik R, Zsolnai L, Huttner G, Neuse EW, Brintzinger HH. Dicyclopentadienyltitanium(IV) pyridine-2,6-dicarboxylate complexes. Synthesis and structural characterization as pentacoordinate titanocene derivatives Journal of Organometallic Chemistry. 312: 177-182. DOI: 10.1016/0022-328X(86)80296-0  0.417
1985 Schwemlein H, Tritschler W, Kiesele H, Brintzinger HH. ansa-Metallocene derivatives. IX. Electrochemical reactions of tetramethylethylene-bridged titanocene dichloride and dicarbonyl derivatives Journal of Organometallic Chemistry. 293: 353-364. DOI: 10.1016/0022-328X(85)80304-1  0.369
1985 Wochner F, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. VIII. Syntheses and crystal structures of ethylene-bridged titanocene and zirconocene derivatives with permethylated ring ligands Journal of Organometallic Chemistry. 288: 69-77. DOI: 10.1016/0022-328X(85)80105-4  0.395
1983 Schwemlein H, Zsolnai L, Huttner G, Brintzinger HH. ansa-metallocene derivatives. VI. Synthesis and molecular structure of a stable tetramethylethylene-bridged chromocene carbonyl complex, (CH3)4C2(C5H4)2Cr(CO) Journal of Organometallic Chemistry. 256: 285-289. DOI: 10.1016/S0022-328X(00)99205-2  0.415
1983 Schwemlein H, Brintzinger HH. ansa-Metallocene derivatives. V. Synthesis of tetramethylethylene-bridged titanocene and zirconocene derivatives via reductive fulvene coupling Journal of Organometallic Chemistry. 254: 69-73. DOI: 10.1016/0022-328X(83)85118-3  0.359
1982 Wild FRWP, Zsolnai L, Huttner G, Brintzinger HH. ansa-Metallocene Derivatives. IV. Synthesis and molecular structures of chiral ansa-titanocene derivatives with bridged tetrahydroindenyl ligands Journal of Organometallic Chemistry. 232: 233-247. DOI: 10.1016/S0022-328X(82)80018-1  0.39
1982 Wochner F, Keller E, Brintzinger HH. Molecular structure and chemical properties of a binuclear cyclopentadienylcobalt nitrosyl cation Journal of Organometallic Chemistry. 236: 267-272. DOI: 10.1016/S0022-328X(00)87082-5  0.328
1981 Lee WS, Koola JD, Brintzinger HH. Benzene complexes in cyclopentadienylcobalt(I) reaction systems Journal of Organometallic Chemistry. 206: C4-C6. DOI: 10.1016/S0022-328X(00)93472-7  0.398
1981 Smith JA, Brintzinger HH. Ansa-metallocene derivatives. III. Influence of an interannular ethylene bridge on the reactivity of titanocene derivatives Journal of Organometallic Chemistry. 218: 159-167. DOI: 10.1016/S0022-328X(00)86097-0  0.315
1981 Lee WS, Brintzinger HH. Generation of reactive cyclopentadienylcobalt(I) derivatives by reduction of dicyclopentadienyldicobalt tetraiodide Journal of Organometallic Chemistry. 209: 401-406. DOI: 10.1016/S0022-328X(00)81196-1  0.383
1979 Brintzinger HH. Mechanisms of dihydrogen activation by zirconocene alkyl and hydride derivatives. A molecular orbital analysis of a 'direct hydrogen transfer' reaction mode Journal of Organometallic Chemistry. 171: 337-344. DOI: 10.1016/S0022-328X(00)82657-1  0.413
1979 Smith JA, von Seyerl J, Huttner G, Brintzinger HH. ansa-Metallocene derivatives. Molecular structure and proton magnetic resonance spectra or methylene- and ethylene-bridged dicyclopentadienyltitanium compounds Journal of Organometallic Chemistry. 173: 175-185. DOI: 10.1016/S0022-328X(00)81287-5  0.364
1979 Otto EEH, Brintzinger HH. Ligand exchange and ligand migration reactions involving dicyclopentadienylniobium(III) carbonyl derivatives Journal of Organometallic Chemistry. 170: 209-216. DOI: 10.1016/S0022-328X(00)81085-2  0.404
1978 Wild FRWP, Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. III. Silica-gel-supported iron and cobalt derivatives Journal of Organometallic Chemistry. 148: 73-80. DOI: 10.1016/S0022-328X(00)90952-5  0.382
1978 Otto EEH, Brintzinger HH. Reactive intermediates derived from dicyclopentadienyl niobium(III) carbonyl compounds Journal of Organometallic Chemistry. 148: 29-33. DOI: 10.1016/S0022-328X(00)90947-1  0.407
1978 Huttner G, Brintzinger HH, Bell LG, Friedrich P, Bejenke V, Neugebauer D. The structure of (C5H52W(CO)2 a compound containing a bent trihapto-cyclopentadienyl ligand Journal of Organometallic Chemistry. 145: 329-333. DOI: 10.1016/S0022-328X(00)81301-7  0.358
1977 Gubitosa G, Boldt M, Brintzinger HH. Supported cyclopentadienyl metal carbonyl complexes. 1. Mononuclear iron(II) and cobalt(I) derivatives stabilized by attachment to a polystyrene support [1] Journal of the American Chemical Society. 99: 5174-5175. DOI: 10.1021/Ja00457A044  0.321
1977 Gubitosa G, Brintzinger HH. Supported cyclopentadienylmetal carbonyl complexes. II. Polystyrene-supported carbonyl and nitrosyl derivatives of group VI transition metals Journal of Organometallic Chemistry. 140: 187-193. DOI: 10.1016/S0022-328X(00)93194-2  0.355
1977 Lee WS, Brintzinger HH. Reactive intermediates in the photolysis of cyclopentadienylcobalt(I) dicarbonyl and in the reduction of cyclopentadienylcobalt(III) carbonyl diiodide Journal of Organometallic Chemistry. 127: 87-92. DOI: 10.1016/S0022-328X(00)84198-4  0.322
1977 Weber SR, Brintzinger HH. Reactions of bis(hexamethylbenzene)iron(0) with carbon monoxide and with unsaturated hydrocarbons Journal of Organometallic Chemistry. 127: 45-54. DOI: 10.1016/S0022-328X(00)84196-0  0.392
1975 Tang Wong KL, Brintzinger HH. Reactivity patterns of chromocene, molybdenocene, and tungstenocene reaction systems. I. Carbonyl complex formation as a probe of coordinative unsaturation Journal of the American Chemical Society. 97: 5143-5146. DOI: 10.1021/Ja00851A020  0.401
1974 Tang Wong KL, Thomas JL, Brintzinger HH. Photogeneration of coordinatively unsaturated sandwich compounds of molybdenum and tungsten from their carbonyl complexes [35] Journal of the American Chemical Society. 96: 3694-3695. DOI: 10.1021/Ja00818A077  0.374
1972 Bercaw JE, Marvich RH, Bell LG, Brintzinger HH. Titanocene as an intermediate in reactions involving molecular hydrogen and nitrogen Journal of the American Chemical Society. 94: 1219-1238. DOI: 10.1021/Ja00759A032  0.633
1972 BERCAW JE, MARVICH RH, BELL LG, BRINTZINGER HH. ChemInform Abstract: TITANOCEN ALS ZWISCHENPRODUKT IN RK. MIT MOLEKULAREM SAUERSTOFF UND STICKSTOFF Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197220366  0.555
1971 Bercaw JE, Brintzinger HH. Bis(pentamethylcyclopentadienyl)titanium(II). Isolation and reactions with hydrogen, nitrogen, and carbon monoxide [1] Journal of the American Chemical Society. 93: 2045-2046. DOI: 10.1021/Ja00737A033  0.625
1971 BERCAW JE, BRINTZINGER HH. ChemInform Abstract: BIS-(PENTAMETHYLCYCLOPENTADIENYL)-TITAN(II), ISOLIERUNG UND REAKTIONEN MIT WASSERSTOFF, STICKSTOFF UND KOHLENMONOXID Chemischer Informationsdienst. Organische Chemie. 2: no-no. DOI: 10.1002/Chin.197128032  0.579
1970 Brintzinger H, Bercaw JE. Nature of so-called titanocene, (C10H10Ti)2 Journal of the American Chemical Society. 92: 6182-6185. DOI: 10.1021/Ja00724A013  0.566
1970 BRINTZINGER HH, BERCAW JE. ChemInform Abstract: STRUKTUR DES SOGENANNTEN TITANOCENS (C10H10TI)2 Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197052061  0.55
1970 BERCAW JE, BRINTZINGER HH. ChemInform Abstract: DI-MY-HYDRIDO-BIS-(DICYCLOPENTADIENYLTITAN(III)), EIN UEBERGANGSMETALLKOMPLEX MIT EINER DIBORAN-ARTIGEN DOPPELTEN WASSERSTOFFBRUECKENBINDUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197013346  0.615
1969 Bercaw JE, Brintzinger HH. Di-μ-hydrido-bis(dicyclopentadienyltitanium(III)), a transition metal complex with a diborane-like double hydrogen bridge Journal of the American Chemical Society. 91: 7301-7306. DOI: 10.1021/Ja01054A018  0.647
1967 Brintzinger H. Hydride, alkyl, and alyl complexes of bis(.pi.-cyclopentadienyl)thitanium(III) Journal of the American Chemical Society. 89: 6871-6877. DOI: 10.1021/Ja01002A011  0.419
1967 Brintzinger HH. Hydride, alkyl, and allyl complexes of bis (π-cyclopentadienyl ) titanium(III) Journal of the American Chemical Society. 89: 6871-6877.  0.337
1966 Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. II. Di-μ-imino-bis(dicyclopentadienyltitanium(III)) as a product of the reaction between di-μ-hydrido-bis(dicyclopentadienyltitanium(III)) and molecular nitrogen [40] Journal of the American Chemical Society. 88: 4307-4308. DOI: 10.1021/Ja00970A067  0.398
1966 Brintzinger H. Formation of ammonia by insertion of molecular nitrogen into metal-hydride bonds. I. The formation of dimeric dicyclopentadienyltitanium(III) hydride as an intermediate in the vol'pin-shur nitrogen-fixing system [39] Journal of the American Chemical Society. 88: 4305-4307. DOI: 10.1021/Ja00970A066  0.332
1966 Brintzinger H, Hammes GG. Inner- and outer-sphere complex formation in aqueous solutions of nickel(II)-methyl phosphate Inorganic Chemistry. 5: 1286-1287. DOI: 10.1021/Ic50041A050  0.339
1959 BRINTZINGER H, FALLAB S, ERLENMEYER H. [Metal specificity of hexokinase]. Experientia. 15: 96-7. PMID 13652940 DOI: 10.1007/BF02166692  0.663
1955 Brintzinger H, Fallab S, Erlenmeyer H. Über Dipyridyl-Metallkomplexe III. Austausch und Racemisierung. Metallionen und biologische Wirkung, 33. Mitteilung Helvetica Chimica Acta. 38: 557-559. DOI: 10.1002/Hlca.19550380302  0.73
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