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Patrick J. Walsh - Publications

Affiliations: 
Chemistry University of Pennsylvania, Philadelphia, PA, United States 
Area:
catalysis and organic and inorganic synthesis
Website:
http://webdev.chem.upenn.edu/chem/research/faculty.php?id=37

307 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Wu H, Chen S, Liu C, Zhao Q, Wang Z, Jin Q, Sun S, Guo J, He X, Walsh PJ, Shang Y. Construction of C-S and C-Se Bonds from Unstrained Ketone Precursors under Photoredox Catalysis. Angewandte Chemie (International Ed. in English). e202314790. PMID 38185472 DOI: 10.1002/anie.202314790  0.304
2023 Zhou F, Jin H, Zhang Y, Li J, Walsh PJ, Lin S. Base-Promoted Tandem Synthesis of 2-Substituted Indoles and -Fused Polycyclic Indoles. Organic Letters. PMID 37751201 DOI: 10.1021/acs.orglett.3c02609  0.393
2023 Luo Z, Li Z, Zhao H, Yang J, Xu L, Lei M, Fan Q, Walsh PJ. Borane-Catalyzed Tandem Cyclization/Hydrosilylation Towards Enantio- and Diastereoselective Construction of trans-2,3-Disubstituted-1,2,3,4-Tetrahydroquinoxalines. Angewandte Chemie (International Ed. in English). e202305449. PMID 37338222 DOI: 10.1002/anie.202305449  0.37
2023 Zheng Z, Pu Y, Adrio J, Walsh PJ. Sulfenate Anion Catalyzed Diastereoselective Synthesis of Aziridines. Angewandte Chemie (International Ed. in English). e202303069. PMID 37068049 DOI: 10.1002/anie.202303069  0.383
2023 Hu B, Zhao H, Wu Y, Walsh PJ. Palladium-Catalyzed Benzylic C(sp3)-H Carbonylative Arylation with Aryl Bromides. Angewandte Chemie (International Ed. in English). e202300073. PMID 37005225 DOI: 10.1002/anie.202300073  0.396
2022 Kou S, Huo J, Wang Y, Sun S, Xue F, Mao J, Zhang J, Chen L, Walsh PJ. Synthesis of Indoles via Domino Reactions of 2-Methoxytoluene and Nitriles. The Journal of Organic Chemistry. PMID 36520533 DOI: 10.1021/acs.joc.2c02128  0.367
2022 Lin T, Wang YE, Cui N, Li M, Wang R, Bai J, Fan Y, Xiong D, Xue F, Walsh PJ, Mao J. Nickel-Catalyzed Cross-Electrophile Coupling of 1,2,3-Benzotriazin-4(3)-ones with Aryl Bromides. The Journal of Organic Chemistry. PMID 36455282 DOI: 10.1021/acs.joc.2c02246  0.318
2022 Li J, Wang H, Jin H, Xiang Z, Chen L, Walsh PJ, Liang G. Base-Promoted Tandem Synthesis of 3,4-Dihydroisoquinolones. Organic Letters. PMID 36306529 DOI: 10.1021/acs.orglett.2c03167  0.306
2022 Zhao H, Zeng Q, Yang J, Xu B, Lei H, Xu L, Walsh PJ. Rhodium(I)-catalyzed directed trideuteromethylation of (hetero)arene C-H bonds with CDCOD. Organic & Biomolecular Chemistry. PMID 36125438 DOI: 10.1039/d2ob01581a  0.315
2022 Cui N, Lin T, Wang YE, Wu J, Han Y, Xu X, Xue F, Xiong D, Walsh PJ, Mao J. Nickel-Catalyzed Reductive Coupling of γ-Metalated Ketones with Unactivated Alkyl Bromides. Organic Letters. 24: 3987-3992. PMID 35639094 DOI: 10.1021/acs.orglett.2c01390  0.387
2022 Zhao H, Luo Z, Yang J, Li B, Han J, Xu L, Lai W, Walsh PJ. Ligand-Promoted Rh(I)-Catalyzed C2-Selective C-H Alkenylation and Polyenylation of Imidazoles with Alkenyl Carboxylic Acids. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 35388545 DOI: 10.1002/chem.202200441  0.338
2021 Gu Y, Zhang Z, Wang YE, Dai Z, Yuan Y, Xiong D, Li J, Walsh PJ, Mao J. Benzylic Aroylation of Toluenes Mediated by a LiN(SiMe)/Cs System. The Journal of Organic Chemistry. PMID 34958592 DOI: 10.1021/acs.joc.1c02446  0.406
2021 Wolf SE, Liu T, Govind S, Zhao H, Huang G, Zhang A, Wu Y, Chin J, Cheng K, Salami-Ranjbaran E, Gao F, Gao G, Jin Y, Pu Y, Toledo TG, ... ... Walsh PJ, et al. Design of a homologous series of molecular glassformers. The Journal of Chemical Physics. 155: 224503. PMID 34911316 DOI: 10.1063/5.0066410  0.406
2021 Zou D, Gan L, Yang F, Wang H, Pu Y, Li J, Walsh PJ. SET activation of nitroarenes by 2-azaallyl anions as a straightforward access to 2,5-dihydro-1,2,4-oxadiazoles. Nature Communications. 12: 7060. PMID 34862375 DOI: 10.1038/s41467-021-26767-x  0.369
2021 Qian P, Guan H, Wang YE, Lu Q, Zhang F, Xiong D, Walsh PJ, Mao J. Catalytic enantioselective reductive domino alkyl arylation of acrylates via nickel/photoredox catalysis. Nature Communications. 12: 6613. PMID 34785647 DOI: 10.1038/s41467-021-26794-8  0.37
2021 Zhao H, Hu B, Xu L, Walsh PJ. Palladium-catalyzed benzylic C(sp)-H carbonylative arylation of azaarylmethyl amines with aryl bromides. Chemical Science. 12: 10862-10870. PMID 34476065 DOI: 10.1039/d1sc02078a  0.403
2021 Panetti GB, Carroll PJ, Gau MR, Manor BC, Schelter EJ, Walsh PJ. Synthesis of an elusive, stable 2-azaallyl radical guided by electrochemical and reactivity studies of 2-azaallyl anions. Chemical Science. 12: 4405-4410. PMID 34163704 DOI: 10.1039/d0sc04822d  0.786
2021 Deng G, Duan S, Wang J, Chen Z, Liu T, Chen W, Zhang H, Yang X, Walsh PJ. Transition-metal-free allylation of 2-azaallyls with allyl ethers through polar and radical mechanisms. Nature Communications. 12: 3860. PMID 34162867 DOI: 10.1038/s41467-021-24027-6  0.342
2021 Shelp RA, Ciro A, Pu Y, Merchant RR, Hughes JME, Walsh PJ. Strain-release 2-azaallyl anion addition/borylation of [1.1.1]propellane: synthesis and functionalization of benzylamine bicyclo[1.1.1]pentyl boronates. Chemical Science. 12: 7066-7072. PMID 34123334 DOI: 10.1039/d1sc01349a  0.318
2021 Duan S, Deng G, Zi Y, Wu X, Tian X, Liu Z, Li M, Zhang H, Yang X, Walsh PJ. Nickel-catalyzed enantioselective vinylation of aryl 2-azaallyl anions. Chemical Science. 12: 6406-6412. PMID 34084440 DOI: 10.1039/d1sc00972a  0.391
2021 Yang Q, Wang YH, Qiao Y, Gau M, Carroll PJ, Walsh PJ, Schelter EJ. Photocatalytic C-H activation and the subtle role of chlorine radical complexation in reactivity. Science (New York, N.Y.). 372: 847-852. PMID 34016778 DOI: 10.1126/science.abd8408  0.56
2021 Panetti GB, Robinson JR, Schelter EJ, Walsh PJ. Expanding the Rare-Earth Metal BINOLate Catalytic Multitool beyond Enantioselective Organic Synthesis. Accounts of Chemical Research. PMID 34014657 DOI: 10.1021/acs.accounts.1c00148  0.811
2021 Walsh PJ, Xu X, Luo C, Zhao H, Pan Y, Zhang X, Li J, Xu L, Lei M. Rhodium(III)-Catalyzed C-H bond Functionalization of 2-Pyridones with Alkynes: Switchable Alkenylation, Alkenylation/Directing Group Migration and Rollover Annulation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33871117 DOI: 10.1002/chem.202101074  0.323
2021 Panetti GB, Sergentu DC, Gau MR, Carroll PJ, Autschbach J, Walsh PJ, Schelter EJ. Isolation and characterization of a covalent Ce-Aryl complex with an anomalous C chemical shift. Nature Communications. 12: 1713. PMID 33731719 DOI: 10.1038/s41467-021-21766-4  0.793
2021 Chen S, Yang L, Shang Y, Mao J, Walsh PJ. Base-Promoted Tandem Synthesis of 2-Azaaryl Tetrahydroquinolines. Organic Letters. PMID 33596086 DOI: 10.1021/acs.orglett.0c04306  0.329
2021 Wang C, Zhang H, Wells LA, Liu T, Meng T, Liu Q, Walsh PJ, Kozlowski MC, Jia T. Autocatalytic photoredox Chan-Lam coupling of free diaryl sulfoximines with arylboronic acids. Nature Communications. 12: 932. PMID 33568641 DOI: 10.1038/s41467-021-21156-w  0.306
2020 Wu C, McCollom SP, Zheng Z, Zhang J, Sha SC, Li M, Walsh PJ, Tomson NC. Aryl Fluoride Activation Through Palladium-Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study. Acs Catalysis. 10: 7934-7944. PMID 34221636 DOI: 10.1021/acscatal.0c01301  0.692
2020 Lin T, Gu Y, Qian P, Guan H, Walsh PJ, Mao J. Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides. Nature Communications. 11: 5638. PMID 33159055 DOI: 10.1038/s41467-020-19194-x  0.353
2020 Zhao H, Xu X, Yu H, Li B, Xu X, Li H, Xu L, Fan Q, Walsh PJ. Rh(I)-Catalyzed C6-Selective Decarbonylative Alkylation of 2-Pyridones with Alkyl Carboxylic Acids and Anhydrides. Organic Letters. PMID 32383597 DOI: 10.1021/Acs.Orglett.0C01277  0.42
2020 Caravan RL, Vansco MF, Au K, Khan MAH, Li YL, Winiberg FAF, Zuraski K, Lin YH, Chao W, Trongsiriwat N, Walsh PJ, Osborn DL, Percival CJ, Lin JJ, Shallcross DE, et al. Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate. Proceedings of the National Academy of Sciences of the United States of America. PMID 32321826 DOI: 10.1073/Pnas.1916711117  0.365
2020 Vansco MF, Caravan RL, Zuraski KL, Winiberg FAF, Au K, Trongsiriwat N, Walsh PJ, Osborn DL, Percival CJ, Khan MAH, Shallcross DE, Taatjes CA, Lester MI. Experimental Evidence of Dioxole Unimolecular Decay Pathway for Isoprene-Derived Criegee Intermediates. The Journal of Physical Chemistry. A. PMID 32255634 DOI: 10.1021/Acs.Jpca.0C02138  0.316
2020 Walsh PJ, Guan H, Zhang Q, Mao J. Nickel/Photoredox-Catalyzed Asymmetric Reductive Cross-Coupling of Racemic a-Chloro Esters with Aryl Iodides. Angewandte Chemie (International Ed. in English). PMID 31944527 DOI: 10.1002/Anie.201914175  0.426
2020 Liu Z, Li M, Deng G, Wei W, Feng P, Zi Q, Li T, Zhang H, Yang X, Walsh PJ. Transition-metal-free C(sp3)–H/C(sp3)–H dehydrogenative coupling of saturated heterocycles with N-benzyl imines Chemical Science. 11: 7619-7625. DOI: 10.1039/D0Sc00031K  0.369
2020 Wu C, McCollom SP, Zheng Z, Zhang J, Sha S, Li M, Walsh PJ, Tomson NC. Aryl Fluoride Activation through Palladium–Magnesium Bimetallic Cooperation: A Mechanistic and Computational Study Acs Catalysis. 10: 7934-7944. DOI: 10.1021/Acscatal.0C01301  0.717
2020 Yang W, Ling B, Hu B, Yin H, Mao J, Walsh PJ. Inside Cover: Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Umpolung 1,4‐Addition of Aryl Iodides to Enals (Angew. Chem. Int. Ed. 1/2020) Angewandte Chemie International Edition. 59: 2-2. DOI: 10.1002/Anie.201914768  0.366
2020 Yang W, Ling B, Hu B, Yin H, Mao J, Walsh PJ. Innentitelbild: Synergistic N‐Heterocyclic Carbene/Palladium‐Catalyzed Umpolung 1,4‐Addition of Aryl Iodides to Enals (Angew. Chem. 1/2020) Angewandte Chemie. 132: 2-2. DOI: 10.1002/Ange.201914768  0.472
2019 Zhao H, Xu X, Luo Z, Cao L, Li B, Li H, Xu L, Fan Q, Walsh PJ. Rhodium(i)-catalyzed C6-selective C-H alkenylation and polyenylation of 2-pyridones with alkenyl and conjugated polyenyl carboxylic acids. Chemical Science. 10: 10089-10096. PMID 32055363 DOI: 10.1039/C9Sc03672E  0.439
2019 Panetti GB, Robinson JR, Carroll PJ, Gau MR, Manor BC, Walsh PJ, Schelter EJ. Correction: Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex. Dalton Transactions (Cambridge, England : 2003). PMID 31647082 DOI: 10.1039/c9dt90225b  0.789
2019 Yang W, Ling B, Hu B, Yin H, Mao J, Walsh P. Synergistic N-Heterocyclic Carbene/Palladium-Catalyzed Umpolung 1,4-Addition of Aryl Iodides to Enals. Angewandte Chemie (International Ed. in English). PMID 31639258 DOI: 10.1002/Anie.201912584  0.444
2019 Guan H, Cao X, Walsh PJ, Mao J. One-Pot Aminoalkylation of Aldehydes: Diastereoselective Synthesis of Vicinal Diamines with Azaarylmethylamines. Organic Letters. PMID 31622105 DOI: 10.1021/Acs.Orglett.9B03287  0.462
2019 Ge L, Wang DX, Xing R, Ma D, Walsh PJ, Feng C. Photoredox-catalyzed oxo-amination of aryl cyclopropanes. Nature Communications. 10: 4367. PMID 31554813 DOI: 10.1038/S41467-019-12403-2  0.454
2019 Liu G, Walsh PJ, Mao J. Alkaline-Metal-Catalyzed One-Pot Aminobenzylation of Aldehydes with Toluenes. Organic Letters. PMID 31542933 DOI: 10.1021/Acs.Orglett.9B02737  0.441
2019 Vansco MF, Marchetti B, Trongsiriwat N, Bhagde T, Wang G, Walsh PJ, Klippenstein SJ, Lester MI. Synthesis, electronic spectroscopy and photochemistry of methacrolein oxide: A four carbon unsaturated Criegee intermediate from isoprene ozonolysis. Journal of the American Chemical Society. PMID 31446755 DOI: 10.1021/Jacs.9B05193  0.327
2019 Trongsiriwat N, Pu Y, Nieves-Quinones Y, Shelp RA, Kozlowski MC, Walsh PJ. Reactions of 2-Aryl-1,3-Dithianes and [1.1.1]Propellane. Angewandte Chemie (International Ed. in English). PMID 31291500 DOI: 10.1002/Anie.201905531  0.438
2019 Walsh PJ, Wang Z, Xu X, Liu G, Jiang R, Zheng Z, Mao J, Guan H. Synthesis of indoles via domino reaction of 2-fluorotoluenes and nitriles. Angewandte Chemie (International Ed. in English). PMID 31062472 DOI: 10.1002/Anie.201904658  0.437
2019 Jiang H, Sha SC, Jeong SA, Manor BC, Walsh PJ. Ni(NIXANTPHOS)-Catalyzed Mono-Arylation of Toluenes with Aryl Chlorides and Bromides. Organic Letters. PMID 30838860 DOI: 10.1021/Acs.Orglett.9B00294  0.439
2019 Wu C, Berritt S, Liang X, Walsh PJ. Palladium-Catalyzed Enantioselective Alkenylation of Sulfenate Anions. Organic Letters. PMID 30694063 DOI: 10.1021/Acs.Orglett.8B03943  0.408
2019 Walsh PJ, Deng G, Li M, Yu K, Liu C, Duan S, Chen W, Yang X, Zhang H, Liu Z. Synthesis of Benzofuran Derivatives via Cascade Radical Cyclization/Intermolecular Coupling of 2-Azaallyls. Angewandte Chemie (International Ed. in English). PMID 30624843 DOI: 10.1002/Anie.201812369  0.402
2019 Gantzel P, Walsh PJ. Synthesis and Crystal Structures of Lithium and Potassium Triazenide Complexes. Inorganic Chemistry. 37: 3450-3451. PMID 11670426 DOI: 10.1021/Ic9802911  0.329
2019 Panetti GB, Varela EJ, Gau MR, Schelter EJ, Walsh PJ. An investigation of the binding of (S)-monothioBINOLate to rare earth metal cations Phosphorus, Sulfur, and Silicon and the Related Elements. 194: 624-629. DOI: 10.1080/10426507.2019.1602773  0.775
2019 Zhou Y, Wang L, Li S, Ma S, Walsh PJ, Bian Q, Li F, Wang M, Zhong J. Enantioselective Addition of Alkynyl Esters and Ethers to Aldehydes Catalyzed by a Cyclopropyl Amino Alcohol Based Zinc Catalyst Synlett. 31: 60-64. DOI: 10.1055/S-0039-1690264  0.472
2019 Liang Q, Walsh PJ, Jia T. Copper-Catalyzed Intermolecular Difunctionalization of Styrenes with Thiosulfonates and Arylboronic Acids via a Radical Relay Pathway Acs Catalysis. 10: 2633-2639. DOI: 10.1021/Acscatal.9B04887  0.356
2019 Zheng Z, Trofymchuk OS, Kurogi T, Varela E, Mindiola DJ, Walsh PJ. Selenenate Anions (PhSeO − ) as Organocatalyst: Synthesis of trans ‐Stilbenes and a PPV Derivative Advanced Synthesis & Catalysis. 362: 659-666. DOI: 10.1002/Adsc.201901201  0.347
2019 Yu K, Li M, Deng G, Liu C, Wang J, Liu Z, Zhang H, Yang X, Walsh PJ. Front Cover Picture: An Efficient Route to Isochromene Derivatives via Cascade Radical Cyclization and Radical‐Radical Coupling (Adv. Synth. Catal. 18/2019) Advanced Synthesis & Catalysis. 361: 4147-4147. DOI: 10.1002/Adsc.201900926  0.344
2019 Yu K, Li M, Deng G, Liu C, Wang J, Liu Z, Zhang H, Yang X, Walsh PJ. An Efficient Route to Isochromene Derivatives via Cascade Radical Cyclization and Radical‐Radical Coupling Advanced Synthesis & Catalysis. 361: 4354-4359. DOI: 10.1002/Adsc.201900497  0.343
2018 Wang R, Ma M, Gong X, Fan X, Walsh PJ. Reductive Cross-Coupling of Aldehydes and Imines Mediated by Visible Light Photoredox Catalysis. Organic Letters. PMID 30484653 DOI: 10.1021/Acs.Orglett.8B03394  0.428
2018 Fan X, Gong X, Ma M, Wang R, Walsh PJ. Visible light-promoted CO fixation with imines to synthesize diaryl α-amino acids. Nature Communications. 9: 4936. PMID 30467333 DOI: 10.1038/S41467-018-07351-2  0.354
2018 Shelp R, Walsh PJ. Synthesis of BCP Benzylamines From 2-Azaallyl Anions and [1.1.1]Propellane. Angewandte Chemie (International Ed. in English). PMID 30291667 DOI: 10.1002/Anie.201810061  0.388
2018 Sha SC, Tcyrulnikov S, Li M, Fu Y, Kozlowski MC, Walsh PJ, Hu B. Cation-π Interactions in the Benzylic Arylation of Toluenes with Bi-metallic Catalysts. Journal of the American Chemical Society. PMID 30185030 DOI: 10.1021/Jacs.8B05143  0.41
2018 Panetti GB, Robinson JR, Carroll PJ, Gau MR, Manor BC, Walsh PJ, Schelter EJ. Synthesis of novel copper-rare earth BINOLate frameworks from a hydrogen bonding DBU-H rare earth BINOLate complex. Dalton Transactions (Cambridge, England : 2003). PMID 30183038 DOI: 10.1039/C8Dt03335H  0.794
2018 Wang Z, Zheng Z, Xu X, Mao J, Walsh PJ. One-pot aminobenzylation of aldehydes with toluenes. Nature Communications. 9: 3365. PMID 30135427 DOI: 10.1038/S41467-018-05638-Y  0.441
2018 Zhang S, Hu B, Zheng Z, Walsh PJ. Palladium-Catalyzed Triarylation of sp C-H Bonds in Heteroarylmethanes: Synthesis of Triaryl(heteroaryl)methanes. Advanced Synthesis & Catalysis. 360: 1493-1498. PMID 30093851 DOI: 10.1002/Adsc.201701347  0.477
2018 Barber VP, Pandit S, Green AM, Trongsiriwat N, Walsh PJ, Klippenstein SJ, Lester MI. Four Carbon Criegee Intermediate from Isoprene Ozonolysis: Methyl Vinyl Ketone Oxide Synthesis, Infrared Spectrum, and OH Production. Journal of the American Chemical Society. PMID 30074392 DOI: 10.1021/Jacs.8B06010  0.34
2018 Mao J, Zhang J, Zhang S, Walsh PJ. NIXANTPHOS: a highly active ligand for palladium catalyzed Buchwald-Hartwig amination of unactivated aryl chlorides. Dalton Transactions (Cambridge, England : 2003). PMID 29878002 DOI: 10.1039/C8Dt01852A  0.456
2018 Kim BS, Gutierrez O, Kozlowski MC, Walsh PJ. A Simple Procedure for the Synthesis of -Hydroxyallenamides via Homoallenylation of Aldehydes. Advanced Synthesis & Catalysis. 360: 1426-1432. PMID 29861707 DOI: 10.1002/Adsc.201800119  0.367
2018 Li M, Berritt S, Wang C, Yang X, Liu Y, Sha SC, Wang B, Wang R, Gao X, Li Z, Fan X, Tao Y, Walsh PJ. Sulfenate anions as organocatalysts for benzylic chloromethyl coupling polymerization via C=C bond formation. Nature Communications. 9: 1754. PMID 29717123 DOI: 10.1038/S41467-018-04095-X  0.447
2018 Jiang H, Bellomo A, Zhang M, Carroll PJ, Manor BC, Jia T, Walsh PJ. Palladium-Catalyzed Direct C-H Arylation of 3-(Methylsulfinyl)thiophenes. Organic Letters. PMID 29659294 DOI: 10.1021/Acs.Orglett.8B00599  0.45
2018 Wang R, Ma M, Gong X, Panetti GB, Fan X, Walsh PJ. Visible-Light-Mediated Umpolung Reactivity of Imines: Ketimine Reductions with CyNMe and Water. Organic Letters. PMID 29619830 DOI: 10.1021/Acs.Orglett.8B00778  0.794
2018 Lin T, Mi J, Song L, Gan J, Luo P, Mao J, Walsh PJ. Nickel-Catalyzed Desymmetrizing Cross-Electrophile Coupling of Cyclic Meso-Anhydrides. Organic Letters. PMID 29400970 DOI: 10.1021/Acs.Orglett.8B00114  0.389
2018 Li J, Wu C, Zhou B, Walsh PJ. Nickel-Catalyzed C(sp3)-H Arylation of Diarylmethane Derivatives with Aryl Fluorides. The Journal of Organic Chemistry. PMID 29384672 DOI: 10.1021/Acs.Joc.8B00016  0.5
2018 Liu Z, Li M, Wang B, Deng G, Chen W, Kim B, Zhang H, Yang X, Walsh PJ. Chemoselective synthesis of aryl(pyridinyl)methanol derivatives through Ni-NIXANTPHOS catalyzed α-arylation and tandem arylation/rearrangement of pyridylmethyl ethers Organic Chemistry Frontiers. 5: 1870-1876. DOI: 10.1039/C8Qo00207J  0.456
2018 Wang H, Chen S, Liu G, Guan H, Zhong D, Cai J, Zheng Z, Mao J, Walsh PJ. Synthesis of Diaryl Selenides via Palladium-Catalyzed Debenzylative Cross-Coupling of Aryl Benzyl Selenides with Aryl Bromides Organometallics. 37: 4086-4091. DOI: 10.1021/Acs.Organomet.8B00644  0.464
2018 Liang X, Wu C, Zheng Z, Walsh PJ. Nickel-Catalyzed Oxidative Coupling Reaction of Phenyl Benzyl Sulfoxides Organometallics. 37: 3132-3141. DOI: 10.1021/Acs.Organomet.8B00476  0.476
2018 Liu F, Zhong J, Zhou Y, Gao Z, Walsh PJ, Wang X, Ma S, Hou S, Liu S, Wang M, Wang M, Bian Q. Frontispiece: Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs Chemistry - a European Journal. 24. DOI: 10.1002/Chem.201880963  0.384
2018 Duan S, Li M, Ma X, Chen W, Li L, Zhang H, Yang X, Walsh PJ. Palladium-Catalyzed Alkenylation of Azaarylmethylamines with Vinyl Halides Advanced Synthesis & Catalysis. 360: 4837-4842. DOI: 10.1002/Adsc.201801045  0.496
2018 Trongsiriwat N, Li M, Pascual‐Escudero A, Yucel B, Walsh PJ. Palladium‐Catalyzed Allylic Alkylation of 2‐Aryl‐1,3‐Dithianes, an Umpolung Synthesis of β,γ‐Unsaturated Ketones Advanced Synthesis & Catalysis. 361: 502-509. DOI: 10.1002/Adsc.201801035  0.377
2018 Trofymchuk OS, Zheng Z, Kurogi T, Mindiola DJ, Walsh PJ. Selenolate Anion as an Organocatalyst: Reactions and Mechanistic Studies Advanced Synthesis & Catalysis. 360: 1685-1692. DOI: 10.1002/Adsc.201701568  0.363
2017 Gao G, Fu Y, Li M, Wang B, Zheng B, Hou S, Walsh PJ. Arylation of Azaarylmethylamines with Aryl Chlorides and a NiBr/NIXANTPHOS-based Catalyst. Advanced Synthesis & Catalysis. 359: 2890-2894. PMID 29531521 DOI: 10.1002/Adsc.201700438  0.427
2017 Ablajan K, Panetti GB, Yang X, Kim BS, Walsh PJ. Synthesis of Diarylated 4-Pyridylmethyl Ethers via Palladium-Catalyzed Cross-Coupling Reactions. Advanced Synthesis & Catalysis. 359: 1927-1932. PMID 29230153 DOI: 10.1002/Adsc.201700380  0.831
2017 Liu F, Zhong J, Zhou Y, Gao Z, Walsh PJ, Wang X, Ma S, Hou S, Liu S, Wang M, Wang M, Bian Q. Cobalt-Catalyzed Enantioselective Negishi Cross-Coupling of Racemic α-Bromo Esters with Arylzincs. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29194860 DOI: 10.1002/Chem.201705463  0.485
2017 Li M, Berritt S, Matuszewski L, Deng G, Pascual-Escudero A, Panetti GB, Poznik M, Yang X, Chruma JJ, Walsh PJ. Transition-Metal-Free Radical C(sp3)-C(sp2) and C(sp3)-C(sp3) Coupling Enabled by 2-Azaallyls as Super-Electron-Donors and Coupling-Partners. Journal of the American Chemical Society. PMID 29019654 DOI: 10.1021/Jacs.7B09394  0.806
2017 Liu T, Exarhos AL, Alguire EC, Gao F, Salami-Ranjbaran E, Cheng K, Jia T, Subotnik JE, Walsh PJ, Kikkawa JM, Fakhraai Z. Birefringent Stable Glass with Predominantly Isotropic Molecular Orientation. Physical Review Letters. 119: 095502. PMID 28949582 DOI: 10.1103/Physrevlett.119.095502  0.434
2017 Li M, Gutierrez O, Berritt S, Pascual-Escudero A, Yeşilçimen A, Yang X, Adrio J, Huang G, Nakamaru-Ogiso E, Kozlowski MC, Walsh PJ. Transition-metal-free chemo- and regioselective vinylation of azaallyls. Nature Chemistry. 9: 997-1004. PMID 28937664 DOI: 10.1038/Nchem.2760  0.391
2017 Fan X, Walsh PJ. Chelation-Controlled Additions to Chiral α- and β-Silyloxy, α-Halo, and β-Vinyl Carbonyl Compounds. Accounts of Chemical Research. PMID 28809470 DOI: 10.1021/Acs.Accounts.7B00319  0.465
2017 Jia T, Zhang M, McCollom SP, Bellomo A, Montel S, Mao J, Dreher SD, Welch CJ, Regalado EL, Williamson RT, Manor BC, Tomson NC, Walsh PJ. Palladium-Catalyzed Enantioselective Arylation of Aryl Sulfenate Anions: A Combined Experimental and Computational Study. Journal of the American Chemical Society. PMID 28537724 DOI: 10.1021/Jacs.7B03623  0.743
2017 Zhang S, Kim BS, Wu C, Mao J, Walsh PJ. Palladium-catalysed synthesis of triaryl(heteroaryl)methanes. Nature Communications. 8: 14641. PMID 28290445 DOI: 10.1038/Ncomms14641  0.484
2017 Gao G, Zheng B, Fu Y, Li M, Wang B, Chen X, Zhang Y, Liu J, Hou S, Walsh PJ. Palladium-Catalyzed Chemoselective α-Arylation of Methyl Sulfones with Aryl Chlorides Asian Journal of Organic Chemistry. 6: 654-657. DOI: 10.1002/Ajoc.201700075  0.474
2016 Robinson JR, Qiao Y, Gu J, Carroll PJ, Walsh PJ, Schelter EJ. The role of dynamic ligand exchange in the oxidation chemistry of cerium(iii). Chemical Science. 7: 4537-4547. PMID 30155100 DOI: 10.1039/C5Sc04897D  0.6
2016 Jiménez J, Kim BS, Walsh PJ. Tandem C(sp(3))-H Arylation/Oxidation and Arylation/Allylic Substitution of Isoindolinones. Advanced Synthesis & Catalysis. 358: 2829-2837. PMID 28652858 DOI: 10.1002/Adsc.201600654  0.498
2016 Li M, Yucel B, Jiménez J, Rotella M, Fu Y, Walsh PJ. Umpolung Synthesis of Diarylmethylamines via Palladium-Catalyzed Arylation of N-Benzyl Aldimines. Advanced Synthesis & Catalysis. 358: 1910-1915. PMID 28190996 DOI: 10.1002/Adsc.201600075  0.455
2016 Zheng B, Li M, Gao G, He Y, Walsh PJ. Palladium-Catalyzed α-Arylation of Methyl Sulfonamides with Aryl Chlorides. Advanced Synthesis & Catalysis. 358: 2156-2162. PMID 28070178 DOI: 10.1002/Adsc.201600090  0.472
2016 Cao X, Sha SC, Li M, Kim BS, Morgan C, Huang R, Yang X, Walsh PJ. Nickel-Catalyzed Arylation of Heteroaryl-containing Diarylmethanes: Exceptional Reactivity of the Ni(NIXANTPHOS)-based Catalyst. Chemical Science (Royal Society of Chemistry : 2010). 7: 611-618. PMID 27213035 DOI: 10.1039/C5Sc03704B  0.417
2016 Yang X, Kim BS, Li M, Walsh PJ. Palladium-Catalyzed Selective α-Alkenylation of Pyridylmethyl Ethers with Vinyl Bromides. Organic Letters. PMID 27160421 DOI: 10.1021/Acs.Orglett.6B00815  0.437
2016 Gao F, Kim BS, Walsh PJ. Chemoselective Palladium-Catalyzed Deprotonative Arylation/[1,2]-Wittig Rearrangement of Pyridylmethyl Ethers. Chemical Science (Royal Society of Chemistry : 2010). 7: 976-983. PMID 27014434 DOI: 10.1039/C5Sc02739J  0.458
2016 Rivero AR, Kim BS, Walsh PJ. Palladium-Catalyzed Benzylic Arylation of Pyridylmethyl Silyl Ethers: One-Pot Synthesis of Aryl(pyridyl)methanols. Organic Letters. PMID 27004592 DOI: 10.1021/Acs.Orglett.6B00450  0.503
2016 Zhang J, Sha SC, Bellomo A, Trongsiriwat N, Gao F, Tomson NC, Walsh PJ. Positional Selectivity in C-H Functionalizations of 2-Benzyl Furans with Bimetallic Catalysts. Journal of the American Chemical Society. PMID 26937718 DOI: 10.1021/Jacs.6B01578  0.728
2016 Jiang H, Jia T, Zhang M, Walsh PJ. Palladium-Catalyzed Arylation of Aryl Sulfenate Anions with Aryl Bromides under Mild Conditions: Synthesis of Diaryl Sulfoxides. Organic Letters. PMID 26878149 DOI: 10.1021/Acs.Orglett.6B00073  0.476
2016 Li M, González-Esguevillas M, Berritt S, Yang X, Bellomo A, Walsh PJ. Palladium-Catalyzed C-H Arylation of α,β-Unsaturated Imines: Catalyst-Controlled Synthesis of Enamine and Allylic Amine Derivatives. Angewandte Chemie (International Ed. in English). PMID 26846375 DOI: 10.1002/Anie.201509757  0.473
2016 Hao W, Wei J, Chi Y, Walsh PJ, Xi Z. A DFT Study on the Conversion of Aryl Iodides to Alkyl Iodides: Reductive Elimination of R-I from Alkylpalladium Iodide Complexes with Accessible β-Hydrogens. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26807680 DOI: 10.1002/Chem.201503910  0.42
2016 Sha SC, Jiang H, Mao J, Bellomo A, Jeong SA, Walsh PJ. Nickel-Catalyzed Allylic Alkylation with Diarylmethane Pronucleophiles: Reaction Development and Mechanistic Insights. Angewandte Chemie (International Ed. in English). 55: 1070-4. PMID 26756444 DOI: 10.1002/Anie.201507494  0.486
2016 Mao J, Zhang J, Jiang H, Bellomo A, Zhang M, Gao Z, Dreher SD, Walsh PJ. Palladium-Catalyzed Asymmetric Allylic Alkylations with Toluene Derivatives as Pronucleophiles. Angewandte Chemie (International Ed. in English). PMID 26756125 DOI: 10.1002/Anie.201509917  0.468
2016 Salvi L, Kim JG, Walsh PJ. Correction to "Practical Catalytic Asymmetric Synthesis of Diaryl-, Aryl Heteroaryl-, and Diheteroarylmethanols". Journal of the American Chemical Society. PMID 26727268 DOI: 10.1021/Jacs.5B12244  0.773
2016 Zheng B, Li M, Gao G, He Y, Walsh PJ. Palladium-Catalyzed α-Arylation of Methyl Sulfonamides with Aryl Chlorides Advanced Synthesis and Catalysis. 358: 2156-2162. DOI: 10.1002/adsc.201600090  0.383
2015 Kim BS, Jiménez J, Gao F, Walsh PJ. Palladium-Catalyzed Benzylic C-H Arylation of Azaarylmethylamines. Organic Letters. PMID 26576005 DOI: 10.1021/Acs.Orglett.5B02898  0.405
2015 Jia T, Zhang M, Jiang H, Wang CY, Walsh PJ. Palladium-Catalyzed Arylation of Alkyl Sulfenate Anions. Journal of the American Chemical Society. PMID 26460506 DOI: 10.1021/Jacs.5B08117  0.51
2015 Liu T, Cheng K, Salami-Ranjbaran E, Gao F, Li C, Tong X, Lin YC, Zhang Y, Zhang W, Klinge L, Walsh PJ, Fakhraai Z. The effect of chemical structure on the stability of physical vapor deposited glasses of 1,3,5-triarylbenzene. The Journal of Chemical Physics. 143: 084506. PMID 26328855 DOI: 10.1063/1.4928521  0.462
2015 Liu T, Cheng K, Salami-Ranjbaran E, Gao F, Glor EC, Li M, Walsh PJ, Fakhraai Z. Synthesis and high-throughput characterization of structural analogues of molecular glassformers: 1,3,5-trisarylbenzenes. Soft Matter. PMID 26280737 DOI: 10.1039/C5Sm01044F  0.502
2015 Zhang M, Jia T, Wang CY, Walsh PJ. Organocatalytic Synthesis of Alkynes. Journal of the American Chemical Society. PMID 26207699 DOI: 10.1021/Jacs.5B06137  0.408
2015 Hussain N, Kim BS, Walsh PJ. Palladium-Catalyzed C(sp(3) )H Arylation of N-Boc Benzylalkylamines via a Deprotonative Cross-Coupling Process. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26129922 DOI: 10.1002/Chem.201502017  0.421
2015 Mao J, Eberle K, Zhang J, Rodriguez C, Xi Z, Pericàs MA, Walsh PJ. Synthesis of triarylmethanols via tandem arylation/oxidation of diarylmethanes. Tetrahedron Letters. 56: 3604-3607. PMID 26034337 DOI: 10.1016/J.Tetlet.2015.01.189  0.635
2015 Robinson JR, Gu J, Carroll PJ, Schelter EJ, Walsh PJ. Exchange Processes in Shibasaki's Rare Earth Alkali Metal BINOLate Frameworks and Their Relevance in Multifunctional Asymmetric Catalysis. Journal of the American Chemical Society. 137: 7135-44. PMID 25968561 DOI: 10.1021/Jacs.5B02201  0.625
2015 Jia T, Zhang M, Sagamanova IK, Wang CY, Walsh PJ. Palladium catalyzed diaryl sulfoxide generation from aryl benzyl sulfoxides and aryl chlorides. Organic Letters. 17: 1168-71. PMID 25686150 DOI: 10.1021/Acs.Orglett.5B00092  0.485
2015 Zhang M, Jia T, Sagamanova IK, Pericás MA, Walsh PJ. tert-Butyl phenyl sulfoxide: a traceless sulfenate anion precatalyst. Organic Letters. 17: 1164-7. PMID 25686008 DOI: 10.1021/Acs.Orglett.5B00117  0.605
2015 Sha SC, Zhang J, Walsh PJ. Palladium-catalyzed α-arylation of aryl acetic acid derivatives via dienolate intermediates with aryl chlorides and bromides. Organic Letters. 17: 410-3. PMID 25582024 DOI: 10.1021/Ol503545J  0.433
2015 Knochel P, Fernandez S, Sha S-, Zhang J, Walsh PJ. Palladium-Catalyzed α-Arylation of Aryl Acetic Acid Derivatives Synfacts. 11: 425-425. DOI: 10.1055/S-0034-1380312  0.409
2015 Hao W, Wang H, Walsh PJ, Xi Z. Combining Pd(π-allyl)Cp and PPh3 as a unique catalyst for efficient synthesis of alkyliodo indoles via C(sp3)-I reductive elimination Organic Chemistry Frontiers. 2: 1080-1084. DOI: 10.1039/C5Qo00197H  0.452
2015 Rojas Cabrera H, Huelgas G, Hernández Pérez JM, Walsh PJ, Somanathan R, Anaya De Parrodi C. Homochiral l-prolinamido-sulfonamides and their use as organocatalysts in aldol reactions Tetrahedron Asymmetry. 26: 163-172. DOI: 10.1016/J.Tetasy.2015.01.009  0.397
2014 Yucel B, Walsh PJ. Reversed-Polarity Synthesis of Diaryl Ketones through Palladium-Catalyzed Direct Arylation of 2-Aryl-1,3-dithianes. Advanced Synthesis & Catalysis. 356: 3659-3667. PMID 26185491 DOI: 10.1002/Adsc.201400695  0.495
2014 Frensch G, Hussain N, Marques FA, Walsh PJ. Palladium-Catalyzed Direct α-Aryation of Benzyl Thioethers with Aryl Bromides. Advanced Synthesis & Catalysis. 356: 2517-2524. PMID 25685127 DOI: 10.1002/Adsc.201400679  0.458
2014 Mao J, Liu F, Wang M, Wu L, Zheng B, Liu S, Zhong J, Bian Q, Walsh PJ. Cobalt-bisoxazoline-catalyzed asymmetric Kumada cross-coupling of racemic α-bromo esters with aryl Grignard reagents. Journal of the American Chemical Society. 136: 17662-8. PMID 25479180 DOI: 10.1021/Ja5109084  0.469
2014 Li M, Yücel B, Adrio J, Bellomo A, Walsh PJ. Synthesis of diarylmethylamines via palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions. Chemical Science (Royal Society of Chemistry : 2010). 5: 2383-2391. PMID 25396041 DOI: 10.1039/C3Sc53526F  0.488
2014 Raffier L, Gutierrez O, Stanton GR, Kozlowski MC, Walsh PJ. Alkenes as Chelating Groups in Diastereoselective Additions of Organometallics to Ketones. Organometallics. 33: 5371-5377. PMID 25328269 DOI: 10.1021/Om5007006  0.768
2014 Mao J, Jia T, Frensch G, Walsh PJ. Palladium-catalyzed debenzylative cross-coupling of aryl benzyl sulfides with aryl bromides: synthesis of diaryl sulfides. Organic Letters. 16: 5304-7. PMID 25298227 DOI: 10.1021/Ol502470E  0.485
2014 Zhang M, Jia T, Yin H, Carroll PJ, Schelter EJ, Walsh PJ. A new class of organocatalysts: sulfenate anions. Angewandte Chemie (International Ed. in English). 53: 10755-8. PMID 25111259 DOI: 10.1002/Anie.201405996  0.638
2014 Li M, Berritt S, Walsh PJ. Palladium-catalyzed regioselective arylation of 1,1,3-triaryl-2-azaallyl anions with aryl chlorides. Organic Letters. 16: 4312-5. PMID 25093713 DOI: 10.1021/Ol502043J  0.489
2014 Gao F, Kim BS, Walsh PJ. Room-temperature palladium-catalyzed direct 2-arylation of benzoxazoles with aryl and heteroaryl bromides. Chemical Communications (Cambridge, England). 50: 10661-4. PMID 25078988 DOI: 10.1039/C4Cc05307A  0.421
2014 Kim BS, Hussain MM, Hussain N, Walsh PJ. Palladium-catalyzed chemoselective allylic substitution, Suzuki-Miyaura cross-coupling, and allene formation of bifunctional 2-B(pin)-substituted allylic acetate derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11726-39. PMID 25077980 DOI: 10.1002/Chem.201402353  0.666
2014 Kim BS, Hussain MM, Norrby PO, Walsh PJ. Breaking Conjugation: Unusual Regioselectivity with 2-Substituted Allylic Substrates in the Tsuji-Trost Reaction. Chemical Science (Royal Society of Chemistry : 2010). 5: 1241-1250. PMID 24910767 DOI: 10.1039/C3Sc53035C  0.777
2014 Robinson JR, Fan X, Yadav J, Carroll PJ, Wooten AJ, Pericàs MA, Schelter EJ, Walsh PJ. Air- and water-tolerant rare earth guanidinium BINOLate complexes as practical precatalysts in multifunctional asymmetric catalysis. Journal of the American Chemical Society. 136: 8034-41. PMID 24796452 DOI: 10.1021/Ja502568G  0.731
2014 Zheng B, Jia T, Walsh PJ. A General and Practical Palladium-Catalyzed Direct α-Arylation of Amides with Aryl Halides. Advanced Synthesis & Catalysis. 356: 165-178. PMID 24765060 DOI: 10.1002/Adsc.201300851  0.458
2014 Zhang J, Bellomo A, Trongsiriwat N, Jia T, Carroll PJ, Dreher SD, Tudge MT, Yin H, Robinson JR, Schelter EJ, Walsh PJ. NiXantphos: a deprotonatable ligand for room-temperature palladium-catalyzed cross-couplings of aryl chlorides. Journal of the American Chemical Society. 136: 6276-87. PMID 24745758 DOI: 10.1021/Ja411855D  0.672
2014 Yadav J, Stanton GR, Fan X, Robinson JR, Schelter EJ, Walsh PJ, Pericas MA. Asymmetric allylation of ketones and subsequent tandem reactions catalyzed by a novel polymer-supported titanium-BINOLate complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7122-7. PMID 24737394 DOI: 10.1002/Chem.201400204  0.839
2014 Hussain N, Frensch G, Zhang J, Walsh PJ. Chemo- and regioselective C(sp³)-H arylation of unactivated allylarenes by deprotonative cross-coupling. Angewandte Chemie (International Ed. in English). 53: 3693-7. PMID 24574070 DOI: 10.1002/Anie.201309084  0.46
2014 Yin H, Robinson JR, Carroll PJ, Walsh PJ, Schelter EJ. κ²-Coordination of 18-crown-6 to Ce(III) cations: solution dynamics and reactivity. Chemical Communications (Cambridge, England). 50: 3470-2. PMID 24553458 DOI: 10.1039/C4Cc00448E  0.539
2014 Montel S, Raffier L, He Y, Walsh PJ. Palladium-catalyzed α-arylation of benzylic phosphonates. Organic Letters. 16: 1446-9. PMID 24520897 DOI: 10.1021/Ol5002413  0.465
2014 Williams UJ, Robinson JR, Lewis AJ, Carroll PJ, Walsh PJ, Schelter EJ. Synthesis, bonding, and reactivity of a cerium(IV) fluoride complex. Inorganic Chemistry. 53: 27-9. PMID 24313793 DOI: 10.1021/Ic402769U  0.601
2014 Montel S, Jia T, Walsh PJ. Palladium-catalyzed α-arylation of benzylic phosphine oxides. Organic Letters. 16: 130-3. PMID 24295336 DOI: 10.1021/Ol403124G  0.42
2014 Jia T, Bellomo A, Montel S, Zhang M, El Baina K, Zheng B, Walsh PJ. Diaryl sulfoxides from aryl benzyl sulfoxides: a single palladium-catalyzed triple relay process. Angewandte Chemie (International Ed. in English). 53: 260-4. PMID 24273189 DOI: 10.1002/Anie.201307172  0.466
2014 Raffier L, Stanton GR, Walsh PJ. Chelation-Controlled Addition of Dialkylzinc Reagents to Aldehydes Synfacts. 10: 311-311. DOI: 10.1055/S-0033-1340762  0.328
2014 Piro NA, Robinson JR, Walsh PJ, Schelter EJ. The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis Coordination Chemistry Reviews. 260: 21-36. DOI: 10.1016/J.Ccr.2013.08.034  0.58
2014 Yucel B, Walsh PJ. Reversed-polarity synthesis of diaryl ketones through palladium-catalyzed direct arylation of 2-Aryl-1,3-dithianes Iubmb Life. 356: 3659-3667. DOI: 10.1002/adsc.201400695  0.322
2014 Robinson JR, Yadav J, Fan X, Stanton GR, Schelter EJ, Pericàs MA, Walsh PJ. Back Cover Picture: Non-Covalent Immobilization of Rare Earth Heterobimetallic Frameworks and their Reactivity in an Asymmetric Michael Addition (Adv. Synth. Catal. 6/2014) Advanced Synthesis & Catalysis. 356: 1380-1380. DOI: 10.1002/Adsc.201400298  0.792
2014 Robinson JR, Yadav J, Fan X, Stanton GR, Schelter EJ, Pericàs MA, Walsh PJ. Non-covalent immobilization of rare earth heterobimetallic frameworks and their reactivity in an asymmetric Michael addition Advanced Synthesis and Catalysis. 356: 1243-1254. DOI: 10.1002/Adsc.201400087  0.794
2014 Hussain MM, Walsh PJ. Discussion Addendum for: Applications of (2S)‐(–)‐3‐exo‐Morpholinoisoborneol [(–)MIB] in Organic Synthesis Organic Syntheses. 25-40. DOI: 10.1002/0471264229.Os090.03  0.603
2013 Robinson JR, Gordon Z, Booth CH, Carroll PJ, Walsh PJ, Schelter EJ. Tuning reactivity and electronic properties through ligand reorganization within a cerium heterobimetallic framework. Journal of the American Chemical Society. 135: 19016-24. PMID 24274665 DOI: 10.1021/Ja410688W  0.592
2013 Raffier L, Stanton GR, Walsh PJ. Chelation-controlled additions to α-silyloxy aldehydes: an autocatalytic approach. Organic Letters. 15: 6174-7. PMID 24252100 DOI: 10.1021/Ol4030259  0.761
2013 Sha SC, Zhang J, Carroll PJ, Walsh PJ. Raising the pKa limit of "soft" nucleophiles in palladium-catalyzed allylic substitutions: application of diarylmethane pronucleophiles. Journal of the American Chemical Society. 135: 17602-9. PMID 24147620 DOI: 10.1021/Ja409511N  0.463
2013 Zheng B, Jia T, Walsh PJ. Palladium-catalyzed direct intermolecular α-arylation of amides with aryl chlorides. Organic Letters. 15: 4190-3. PMID 23909856 DOI: 10.1021/Ol4019002  0.468
2013 Cheng K, Walsh PJ. Arylation of aldehyde homoenolates with aryl bromides. Organic Letters. 15: 2298-301. PMID 23614790 DOI: 10.1021/Ol4008876  0.596
2013 Zheng B, Jia T, Walsh PJ. Palladium-catalyzed direct α-arylation of methyl sulfones with aryl bromides. Organic Letters. 15: 1690-3. PMID 23517309 DOI: 10.1021/Ol400472V  0.455
2013 Robinson JR, Booth CH, Carroll PJ, Walsh PJ, Schelter EJ. Dimeric rare-earth BINOLate complexes: activation of 1,4-benzoquinone through Lewis acid promoted potential shifts. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 5996-6004. PMID 23495100 DOI: 10.1002/Chem.201300026  0.585
2013 Jia T, Bellomo A, Baina KE, Dreher SD, Walsh PJ. Palladium-catalyzed direct arylation of methyl sulfoxides with aryl halides. Journal of the American Chemical Society. 135: 3740-3. PMID 23419158 DOI: 10.1021/Ja4009776  0.435
2013 Dreher S, Walsh P, McGrew G, Stanciu C, Zhang J, Carroll P. Palladium-Catalyzed Direct Arylation of Chromium-Activated Benzylic C-H Groups Synfacts. 9: 0350-0350. DOI: 10.1055/S-0032-1318318  0.794
2013 Hussain N, Hussain MM, Carroll PJ, Walsh PJ. Chemo- and diastereoselective tandem dual oxidation of B(pin)-substituted allylic alcohols: Synthesis of B(pin)-substituted epoxy alcohols, 2-keto-anti-1,3-diols and dihydroxy-tetrahydrofuran-3-ones Chemical Science. 4: 3946-3957. DOI: 10.1039/C3Sc51616D  0.626
2013 Bellomo A, Zhang J, Trongsiriwat N, Walsh PJ. Additive effects on palladium-catalyzed deprotonative-cross-coupling processes (DCCP) of sp3 C-H bonds in diarylmethanes Chemical Science. 4: 849-857. DOI: 10.1039/C2Sc21673F  0.427
2013 Nieto I, Wooten AJ, Robinson JR, Carroll PJ, Schelter EJ, Walsh PJ. Synthesis and catalytic activity of heterobimetallic rare earth-zinc ethyl BINOLate analogues of shibasaki's catalysts Organometallics. 32: 7431-7439. DOI: 10.1021/Om4009444  0.642
2013 Robinson JR, Carroll PJ, Walsh PJ, Schelter EJ. Uranium(IV) BINOLate heterobimetallics: Synthesis and reactivity in an asymmetric Diels-Alder reaction Organometallics. 32: 1493-1499. DOI: 10.1021/Om3011849  0.67
2013 Stanton GR, Goellue M, Platoff RM, Rich CE, Carroll PJ, Walsh PJ. ChemInform Abstract: Synthesis of Chiral N-Sulfonyl and N-Phosphinoyl α-Halo Aldimine Precursors. Cheminform. 44: no-no. DOI: 10.1002/chin.201334069  0.733
2013 Stanton GR, Norrby P, Carroll PJ, Walsh PJ. ChemInform Abstract: Chelation-Controlled Addition of Organozincs to α-Chloro Aldimines. Cheminform. 44: no-no. DOI: 10.1002/chin.201315021  0.775
2013 Stanton GR, Göllü M, Platoff RM, Rich CE, Carroll PJ, Walsh PJ. Synthesis of chiral N-sulfonyl and N-phosphinoyl α-halo aldimine precursors Advanced Synthesis and Catalysis. 355: 757-764. DOI: 10.1002/Adsc.201200864  0.768
2012 McGrew GI, Stanciu C, Zhang J, Carroll PJ, Dreher SD, Walsh PJ. Asymmetric cross-coupling of aryl triflates to the benzylic position of benzylamines. Angewandte Chemie (International Ed. in English). 51: 11510-3. PMID 23037512 DOI: 10.1002/Anie.201201874  0.807
2012 Stanton GR, Norrby PO, Carroll PJ, Walsh PJ. Chelation-controlled addition of organozincs to α-chloro aldimines. Journal of the American Chemical Society. 134: 17599-604. PMID 23003333 DOI: 10.1021/Ja306781Z  0.807
2012 Robinson JR, Carroll PJ, Walsh PJ, Schelter EJ. The impact of ligand reorganization on cerium(III) oxidation chemistry. Angewandte Chemie (International Ed. in English). 51: 10159-63. PMID 22936400 DOI: 10.1002/Anie.201203481  0.555
2012 Zhang J, Bellomo A, Creamer AD, Dreher SD, Walsh PJ. Palladium-catalyzed C(sp3)-H arylation of diarylmethanes at room temperature: synthesis of triarylmethanes via deprotonative-cross-coupling processes. Journal of the American Chemical Society. 134: 13765-72. PMID 22816972 DOI: 10.1021/Ja3047816  0.45
2012 Kim HY, Walsh PJ. Efficient approaches to the stereoselective synthesis of cyclopropyl alcohols. Accounts of Chemical Research. 45: 1533-47. PMID 22725974 DOI: 10.1021/Ar300052S  0.614
2012 Stanton GR, Kauffman MC, Walsh PJ. Diastereoselective chelation-controlled additions to β-silyloxy aldehydes. Organic Letters. 14: 3368-71. PMID 22721430 DOI: 10.1021/Ol301354W  0.758
2012 Kim HY, Walsh PJ. Tandem catalytic enantio-and diastereoselective synthesis of cyclopropyl alcohols using aryl aldehydes Journal of Physical Organic Chemistry. 25: 933-938. DOI: 10.1002/Poc.2965  0.614
2012 Stanton GR, Kauffman MC, Walsh PJ. ChemInform Abstract: Diastereoselective Chelation-Controlled Additions to β-Silyloxy Aldehydes. Cheminform. 43: no-no. DOI: 10.1002/chin.201242054  0.72
2012 Robinson JR, Carroll PJ, Walsh PJ, Schelter EJ. Back Cover: The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry (Angew. Chem. Int. Ed. 40/2012) Angewandte Chemie International Edition. 51: 10196-10196. DOI: 10.1002/Anie.201206981  0.553
2012 Robinson JR, Carroll PJ, Walsh PJ, Schelter EJ. Rücktitelbild: The Impact of Ligand Reorganization on Cerium(III) Oxidation Chemistry (Angew. Chem. 40/2012) Angewandte Chemie. 124: 10342-10342. DOI: 10.1002/Ange.201206981  0.555
2012 Valenta P, Drucker NA, Walsh PJ. Enals via a simple two-carbon homologation of aldehydes and ketones Organic Syntheses. 89: 527-536. DOI: 10.1002/0471264229.Os089.51  0.584
2011 Hussain N, Hussain MM, Ziauddin M, Triyawatanyu P, Walsh PJ. Stereoselective vinylation of aryl N-(2-pyridylsulfonyl) aldimines with 1-alkenyl-1,1-heterobimetallic reagents. Organic Letters. 13: 6464-7. PMID 22085226 DOI: 10.1021/Ol202766G  0.635
2011 Zhang J, Stanciu C, Wang B, Hussain MM, Da CS, Carroll PJ, Dreher SD, Walsh PJ. Palladium-catalyzed allylic substitution with (η6-arene-CH2Z)Cr(CO)(3)-based nucleophiles. Journal of the American Chemical Society. 133: 20552-60. PMID 22047504 DOI: 10.1021/Ja208935U  0.677
2011 Hernández-Toribio J, Hussain MM, Cheng K, Carroll PJ, Walsh PJ. Diastereoselective aziridination of 2-B(pin)-substituted allylic alcohols: an efficient approach to novel organoboron compounds. Organic Letters. 13: 6094-7. PMID 22026754 DOI: 10.1021/Ol202588G  0.697
2011 Hussain MM, Hernández Toribio J, Carroll PJ, Walsh PJ. Synthesis of 2-keto-anti-1,3-diols by chemoselective tandem oxidation of 2-B(pin)-substituted allylic alcohols. Angewandte Chemie (International Ed. in English). 50: 6337-40. PMID 21618673 DOI: 10.1002/Anie.201005742  0.599
2011 Stanton GR, Koz G, Walsh PJ. Highly diastereoselective chelation-controlled additions to α-silyloxy ketones. Journal of the American Chemical Society. 133: 7969-76. PMID 21534530 DOI: 10.1021/Ja201629D  0.779
2011 Cheng K, Carroll PJ, Walsh PJ. Diasteroselective preparation of cyclopropanols using methylene bis(iodozinc). Organic Letters. 13: 2346-9. PMID 21462964 DOI: 10.1021/Ol200597H  0.555
2011 Hussain MM, Toribio JH, Carroll PJ, Walsh PJ. Synthesis of 2-Keto-anti-1,3-Diolsby Chemoselective Tandem Oxidation Synfacts. 2011: 989-989. DOI: 10.1055/S-0030-1261005  0.316
2011 Cheng K, Carroll PJ, Walsh PJ. Diastereoselective Preparation of Cyclopropanols Synfacts. 2011: 769-769. DOI: 10.1055/S-0030-1260497  0.548
2011 Huelgas G, Larochelle LK, Rivas L, Luchinina Y, Toscano RA, Carroll PJ, Walsh PJ, Anaya De Parrodi C. New ligands and structural insights into the catalytic asymmetric addition of organozinc reagents to ketones Tetrahedron. 67: 4467-4474. DOI: 10.1016/J.Tet.2011.04.022  0.402
2010 Valenta P, Carroll PJ, Walsh PJ. Stereoselective synthesis of β-hydroxy enamines, aminocyclopropanes, and 1,3-amino alcohols via asymmetric catalysis. Journal of the American Chemical Society. 132: 14179-90. PMID 20853837 DOI: 10.1021/Ja105435Y  0.699
2010 McGrew GI, Temaismithi J, Carroll PJ, Walsh PJ. Synthesis of polyarylated methanes through cross-coupling of tricarbonylchromium-activated benzyllithiums. Angewandte Chemie (International Ed. in English). 49: 5541-4. PMID 20602381 DOI: 10.1002/Anie.201000957  0.8
2010 Stanton GR, Johnson CN, Walsh PJ. Overriding Felkin control: a general method for highly diastereoselective chelation-controlled additions to alpha-silyloxy aldehydes. Journal of the American Chemical Society. 132: 4399-408. PMID 20218659 DOI: 10.1021/Ja910717P  0.766
2010 Hussain MM, Walsh PJ. Allylic substitution versus Suzuki cross-coupling: capitalizing on chemoselectivity with bifunctional substrates. Angewandte Chemie (International Ed. in English). 49: 1834-7. PMID 20135655 DOI: 10.1002/Anie.200905399  0.658
2010 Kim HY, Salvi L, Carroll PJ, Walsh PJ. One-pot catalytic enantio- and diastereoselective syntheses of anti-, syn-cis-disubstituted, and syn-vinyl cyclopropyl alcohols. Journal of the American Chemical Society. 132: 402-12. PMID 19954146 DOI: 10.1021/Ja907781T  0.563
2010 Walsh P, Valenta P, Carroll P. Synthesis of PRC200-SS Synfacts. 2011: 0003-0003. DOI: 10.1055/S-0030-1258976  0.609
2010 WALSH PJ, SHARPLESS KB. ChemInform Abstract: Asymmetric Dihydroxylation (AD) of α,β-Unsaturated Ketones. Cheminform. 25: no-no. DOI: 10.1002/chin.199411088  0.398
2010 WALSH PJ, BENNANI YL, SHARPLESS KB. ChemInform Abstract: Asymmetric Dihydroxylation (AD)/Cyclization of N-DiBoc Allylic and Homoallylic Amines: Selective Differentiation of the Hydroxyl Groups. Cheminform. 24: no-no. DOI: 10.1002/chin.199352069  0.435
2010 BARANGER AM, WALSH PJ, BERGMAN RG. ChemInform Abstract: Variable Regiochemistry in the Stoichiometric and Catalytic Hydroamination of Alkynes by Imidozirconium Complexes Caused by an Unusual Dependence of the Rate Law on Alkyne Structure and Temperature. Cheminform. 24: no-no. DOI: 10.1002/chin.199335131  0.66
2010 WALSH PJ, BARANGER AM, BERGMAN RG. ChemInform Abstract: Stoichiometric and Catalytic Hydroamination of Alkynes and Allene by Zirconium Bisamides Cp2Zr(NHR)2. Cheminform. 23: no-no. DOI: 10.1002/chin.199226089  0.715
2010 WALSH PJ, CARNEY MJ, BERGMAN RG. ChemInform Abstract: Generation, Dative Ligand Trapping, and N-N Bond Cleavage Reactions of the First Monomeric η1-Hydrazido Zirconocene Complex, Cp2Zr=NNPh2. A Zirconium-Mediated Synthesis of Indoles. Cheminform. 22: no-no. DOI: 10.1002/chin.199144161  0.449
2009 Salvi L, Kim JG, Walsh PJ. Practical catalytic asymmetric synthesis of diaryl-, aryl heteroaryl-, and diheteroarylmethanols. Journal of the American Chemical Society. 131: 12483-93. PMID 19653691 DOI: 10.1021/Ja9046747  0.811
2009 Kerrigan MH, Jeon SJ, Chen YK, Salvi L, Carroll PJ, Walsh PJ. One-pot multicomponent coupling methods for the synthesis of diastereo- and enantioenriched (Z)-trisubstituted allylic alcohols. Journal of the American Chemical Society. 131: 8434-45. PMID 19476375 DOI: 10.1021/Ja809821X  0.73
2009 Cheng K, Kelly AR, Kohn RA, Dweck JF, Walsh PJ. One-pot catalytic asymmetric synthesis of pyranones. Organic Letters. 11: 2703-6. PMID 19456165 DOI: 10.1021/Ol900905R  0.762
2009 Valenta P, Drucker NA, Bode JW, Walsh PJ. Simple one-pot conversion of aldehydes and ketones to enals. Organic Letters. 11: 2117-9. PMID 19419211 DOI: 10.1021/Ol9005757  0.647
2009 Anaya de Parrodi C, Walsh PJ. All kinds of reactivity: recent breakthroughs in metal-catalyzed alkyne chemistry. Angewandte Chemie (International Ed. in English). 48: 4679-82. PMID 19396849 DOI: 10.1002/Anie.200900900  0.446
2009 Hussain MM, Li H, Hussain N, Ureña M, Carroll PJ, Walsh PJ. Applications of 1-alkenyl-1,1-heterobimetallics in the stereoselective synthesis of cyclopropylboronate esters, trisubstituted cyclopropanols and 2,3-disubstituted cyclobutanones. Journal of the American Chemical Society. 131: 6516-24. PMID 19382808 DOI: 10.1021/Ja900147S  0.658
2009 Kim HY, Salvi L, Carroll PJ, Walsh PJ. Highly enantio- and diastereoselective one-pot methods for the synthesis of halocyclopropyl alcohols. Journal of the American Chemical Society. 131: 954-62. PMID 19154172 DOI: 10.1021/Ja806989N  0.574
2009 Hussain MM, Li H, Hussain N, Ureña M, Carroll PJ, Walsh PJ. 1-Alkenyl-1,1-Heterobimetallics: Useful Synthetic Intermediates Synfacts. 2009: 762-762. DOI: 10.1055/S-0029-1217276  0.316
2009 Santacruz E, Huelgas G, Angulo SK, Mastranzo VM, Hernández-Ortega S, Aviña JA, Juaristi E, Parrodi CAd, Walsh PJ. Catalytic asymmetric hydrosilylation of acetophenone with new chiral thiourea ligands containing the (S)-α-phenylethyl group Tetrahedron Asymmetry. 20: 2788-2794. DOI: 10.1016/J.Tetasy.2009.11.027  0.426
2008 Hussain MM, Walsh PJ. Tandem reactions for streamlining synthesis: enantio- and diastereoselective one-pot generation of functionalized epoxy alcohols. Accounts of Chemical Research. 41: 883-93. PMID 18710197 DOI: 10.1021/Ar800006H  0.624
2008 Wooten AJ, Carroll PJ, Walsh PJ. Insight into substrate binding in Shibasaki's Li3(THF)n(BINOLate)3Ln complexes and implications in catalysis. Journal of the American Chemical Society. 130: 7407-19. PMID 18479140 DOI: 10.1021/Ja7107933  0.383
2008 Kelly AR, Kerrigan MH, Walsh PJ. Addition/oxidative rearrangement of 3-furfurals and 3-furyl imines: new approaches to substituted furans and pyrroles. Journal of the American Chemical Society. 130: 4097-104. PMID 18314989 DOI: 10.1021/Ja710988Q  0.704
2008 Li H, Carroll PJ, Walsh PJ. Generation and tandem reactions of 1-alkenyl-1,1-heterobimetallics: practical and versatile reagents for organic synthesis. Journal of the American Chemical Society. 130: 3521-31. PMID 18302376 DOI: 10.1021/Ja077664U  0.467
2007 Salvi L, Jeon SJ, Fisher EL, Carroll PJ, Walsh PJ. Catalytic asymmetric generation of (Z)-disubstituted allylic alcohols Journal of the American Chemical Society. 129: 16119-16125. PMID 18052173 DOI: 10.1021/Ja0762285  0.625
2007 Nuricumbo-Escobar JJ, Campos-Alvarado C, Ríos-Moreno G, Morales-Morales D, Walsh PJ, Parra-Hake M. Binuclear palladium(I) and palladium(II) complexes of ortho-functionalized 1,3-bis(aryl)triazenido ligands. Inorganic Chemistry. 46: 6182-9. PMID 17580936 DOI: 10.1021/Ic700516P  0.311
2007 Walsh PJ, Li H, de Parrodi CA. A green chemistry approach to asymmetric catalysis: solvent-free and highly concentrated reactions. Chemical Reviews. 107: 2503-45. PMID 17530908 DOI: 10.1021/Cr0509556  0.424
2007 Wooten AJ, Kim JG, Walsh PJ. Highly concentrated catalytic asymmetric allylation of ketones. Organic Letters. 9: 381-4. PMID 17249767 DOI: 10.1021/Ol062264H  0.792
2007 Walsh P, Wooten A, Kim J. Ti(IV)-BINOL-Catalyzed Highly Concentrated Asymmetric Allylation of Ketones Synfacts. 2007: 0418-0418. DOI: 10.1055/s-2007-968329  0.696
2007 Wooten AJ, Salvi L, Carroll PJ, Walsh PJ. Characterization of dimeric and tetrameric μ-hydroxide ytterbium(III) binaphtholate complexes Advanced Synthesis and Catalysis. 349: 561-565. DOI: 10.1002/Adsc.200600600  0.32
2006 Kim JG, Camp EH, Walsh PJ. Catalytic asymmetric methallylation of ketones with an (H8-BINOLate)Ti-based catalyst. Organic Letters. 8: 4413-6. PMID 16986913 DOI: 10.1021/Ol061417Y  0.798
2006 Jeon SJ, Fisher EL, Carroll PJ, Walsh PJ. Direct, stereospecific generation of (Z)-disubstituted allylic alcohols Journal of the American Chemical Society. 128: 9618-9619. PMID 16866501 DOI: 10.1021/Ja061973N  0.622
2006 Kim JG, Walsh PJ. From aryl bromides to enantioenriched benzylic alcohols in a single flask: Catalytic asymmetric arylation of aldehydes. Angewandte Chemie (International Ed. in English). 45: 4175-8. PMID 16721894 DOI: 10.1002/Anie.200600741  0.779
2006 Wooten A, Carroll PJ, Maestri AG, Walsh PJ. Unprecedented alkene complex of zinc(II): structures and bonding of divinylzinc complexes. Journal of the American Chemical Society. 128: 4624-31. PMID 16594699 DOI: 10.1021/Ja058700X  0.324
2006 Walsh P, Kim J, Camp E. (H8-BINOLate)Ti-Based Catalyzed Asymmetric Methallylation of Ketones Synfacts. 2006: 1250-1250. DOI: 10.1055/s-2006-955638  0.673
2006 Walsh P, Jeon S, Fisher E, Carroll P. Direct Preparation of (Z)-Disubstituted Allylic Alcohols Synfacts. 2006: 1056-1056. DOI: 10.1055/S-2006-949303  0.56
2006 Jeon S-, Li H, Walsh PJ. Solvent-Free Asymmetric Alkylzinc Additions to Ketones Synfacts. 2006: 157-157. DOI: 10.1055/S-2005-924789  0.36
2005 Jeon SJ, Li H, Walsh PJ. A green chemistry approach to a more efficient asymmetric catalyst: solvent-free and highly concentrated alkyl additions to ketones. Journal of the American Chemical Society. 127: 16416-25. PMID 16305227 DOI: 10.1021/Ja052200M  0.636
2005 Kelly AR, Lurain AE, Walsh PJ. Highly enantio- and diastereoselective one-pot synthesis of acyclic epoxy alcohols and allylic epoxy alcohols. Journal of the American Chemical Society. 127: 14668-74. PMID 16231920 DOI: 10.1021/Ja051291K  0.811
2005 Kim HY, Lurain AE, García-García P, Carroll PJ, Walsh PJ. Highly enantio- and diastereoselective tandem generation of cyclopropyl alcohols with up to four contiguous stereocenters. Journal of the American Chemical Society. 127: 13138-9. PMID 16173729 DOI: 10.1021/Ja0539239  0.81
2005 Li H, Walsh PJ. Catalytic asymmetric vinylation and dienylation of ketones. Journal of the American Chemical Society. 127: 8355-61. PMID 15941269 DOI: 10.1021/Ja0425740  0.507
2005 Jeon SJ, Chen YK, Walsh PJ. Catalytic asymmetric synthesis of hydroxy enol ethers: approach to a two-carbon homologation of aldehydes. Organic Letters. 7: 1729-32. PMID 15844892 DOI: 10.1021/Ol050255N  0.764
2005 Lurain AE, Carroll PJ, Walsh PJ. One-pot asymmetric synthesis of acyclic chiral epoxy alcohols via tandem vinylation-epoxidation with dioxygen. The Journal of Organic Chemistry. 70: 1262-8. PMID 15704959 DOI: 10.1021/Jo048345D  0.836
2005 Jeon SJ, Li H, García C, LaRochelle LK, Walsh PJ. Catalytic asymmetric addition of alkylzinc and functionalized alkylzinc reagents to ketones. The Journal of Organic Chemistry. 70: 448-55. PMID 15651785 DOI: 10.1021/Jo048683E  0.64
2005 Kim HY, Lurain AE, García-García P, Carroll PJ, Walsh PJ. Enantio- and Diastereoselective Tandem Preparation of Cyclopropyl Alcohols Synfacts. 2005: 330-330. DOI: 10.1055/S-2005-921627  0.335
2005 Jeon S, Chen Y, Walsh P. Catalytic Asymmetric Addition of Ethoxyvinyl­-zinc to Aldehydes: Two-Carbon Homologation Synfacts. 2005: 67-67. DOI: 10.1055/S-2005-869926  0.333
2005 Anaya de Parrodi C, Walsh PJ. trans-1,2-Diaminocyclopentane-Based Catalyst for the Asymmetric Addition of Alkyl-, Aryl-, and Vinyl Groups to Ketones. Cheminform. 36. DOI: 10.1055/S-2004-832826  0.456
2005 Costa AM, García C, Carroll PJ, Walsh PJ. Dramatic catalyst evolution in the asymmetric addition of diethylzinc to benzaldehyde Tetrahedron. 61: 6442-6446. DOI: 10.1016/J.Tet.2005.03.109  0.426
2005 Li H, Walsh PJ. Catalytic Asymmetric Vinylation and Dienylation of Ketones. Cheminform. 36. DOI: 10.1002/chin.200544031  0.36
2005 Chen YK, Jeon S, Walsh PJ, Nugent WA. (2S)‐(−)‐3‐exo‐(Morpholino)Isoborneol [(−)‐MIB] Organic Syntheses. 87-92. DOI: 10.1002/0471264229.Os082.14  0.676
2004 Lurain AE, Maestri A, Kelly AR, Carroll PJ, Walsh PJ. Highly enantio- and diastereoselective one-pot synthesis of acyclic epoxy alcohols with three contiguous stereocenters. Journal of the American Chemical Society. 126: 13608-9. PMID 15493905 DOI: 10.1021/Ja046750G  0.823
2004 Kim JG, Waltz KM, Garcia IF, Kwiatkowski D, Walsh PJ. Catalytic asymmetric allylation of ketones and a tandem asymmetric allylation/diastereoselective epoxidation of cyclic enones. Journal of the American Chemical Society. 126: 12580-5. PMID 15453790 DOI: 10.1021/Ja047758T  0.802
2004 Chan V, Kim JG, Jimeno C, Carroll PJ, Walsh PJ. Dynamic kinetic resolution of atropisomeric amides. Organic Letters. 6: 2051-3. PMID 15176816 DOI: 10.1021/Ol0492952  0.812
2004 Li H, Walsh PJ. Catalytic asymmetric vinylation of ketones. Journal of the American Chemical Society. 126: 6538-9. PMID 15161266 DOI: 10.1021/Ja049206G  0.509
2004 Li H, García C, Walsh PJ. Catalytic asymmetric addition of diphenylzinc to cyclic alpha,beta-unsaturated ketones. Proceedings of the National Academy of Sciences of the United States of America. 101: 5425-7. PMID 15067130 DOI: 10.1073/Pnas.0307119101  0.434
2004 Chen YK, Walsh PJ. A one-pot multicomponent coupling reaction for the stereocontrolled synthesis of (Z)-trisubstituted allylic alcohols. Journal of the American Chemical Society. 126: 3702-3. PMID 15038709 DOI: 10.1021/Ja0396145  0.65
2004 García C, Walsh PJ. Highly enantioselective catalytic phenylation of ketones with a constrained geometry titanium catalyst. Organic Letters. 5: 3641-4. PMID 14507193 DOI: 10.1021/Ol0352963  0.463
2004 Betancort JM, Garcia C, Walsh PJ. Development of the First Practical Catalyst for the Asymmetric Addition of Alkyl- and Arylzinc Reagents to Ketones Cheminform. 35. DOI: 10.1055/S-2004-817779  0.475
2004 Waltz KM, Carroll PJ, Walsh PJ. Solid state structures and solution behavior of titanium(IV) octahydrobinaphtholate complexes. Examination of nonlinear behavior in the asymmetric addition of ethyl groups to benzaldehyde Organometallics. 23: 127-134. DOI: 10.1021/Om034107H  0.386
2004 Blum SA, Walsh PJ, Bergman RG. Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes [J. Am. Chem. Soc.2003,125, 14276−14277]. Journal of the American Chemical Society. 126: 9148-9148. DOI: 10.1021/Ja0408146  0.665
2004 Jimeno C, Rios R, Carroll PJ, Walsh PJ. Rapid, highly diastereoselective addition of dialkylzinc reagents to atropisomeric 2-formyl arylamides Tetrahedron. 60: 4543-4548. DOI: 10.1016/J.Tet.2003.12.071  0.75
2004 Mastranzo VM, Quintero L, Anaya de Parrodi C, Juaristi E, Walsh PJ. Use of diamines containing the α-phenylethyl group as chiral ligands in the asymmetric hydrosilylation of prochiral ketones Tetrahedron. 60: 1781-1789. DOI: 10.1016/J.Tet.2003.12.039  0.432
2004 Li H, Walsh PJ. Catalytic Asymmetric Vinylation of Ketones. Cheminform. 35. DOI: 10.1002/chin.200439048  0.358
2004 Jimeno C, Rios R, Carroll PJ, Walsh PJ. Rapid, Highly Diastereoselective Addition of Dialkylzinc Reagents to Atropisomeric 2-Formyl Arylamides. Cheminform. 35. DOI: 10.1002/chin.200436074  0.708
2004 Walsh PJ. Titanium-Catalyzed Enantioselective Additions of Alkyl Groups to Aldehydes: Mechanistic Studies and New Concepts in Asymmetric Catalysis Cheminform. 35. DOI: 10.1002/chin.200403262  0.322
2004 Lurain AE, Walsh PJ. A Catalytic Asymmetric Method for the Synthesis of γ-Unsaturated β-Amino Acid Derivatives. Cheminform. 35. DOI: 10.1002/chin.200402104  0.798
2003 Blum SA, Walsh PJ, Bergman RG. Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes. Journal of the American Chemical Society. 125: 14276-7. PMID 14624566 DOI: 10.1021/Ja037267T  0.727
2003 Walsh PJ. Titanium-catalyzed enantioselective additions of alkyl groups to aldehydes: mechanistic studies and new concepts in asymmetric catalysis. Accounts of Chemical Research. 36: 739-49. PMID 14567707 DOI: 10.1021/Ar0300219  0.467
2003 Lurain AE, Walsh PJ. A catalytic asymmetric method for the synthesis of gamma-unsaturated beta-amino acid derivatives. Journal of the American Chemical Society. 125: 10677-83. PMID 12940753 DOI: 10.1021/Ja035213D  0.809
2003 Walsh PJ, Lurain AE, Balsells J. Use of achiral and meso ligands to convey asymmetry in enantioselective catalysis. Chemical Reviews. 103: 3297-344. PMID 12914499 DOI: 10.1021/Cr0000630  0.791
2003 Jeon SJ, Walsh PJ. Asymmetric addition of alkylzinc reagents to cyclic alpha,beta-unsaturated ketones and a tandem enantioselective addition/diastereoselective epoxidation with dioxygen. Journal of the American Chemical Society. 125: 9544-5. PMID 12903993 DOI: 10.1021/Ja036302T  0.638
2003 Honda A, Waltz KM, Carroll PJ, Walsh PJ. Atropisomeric amides: Achiral ligands with chiral conformations. Chirality. 15: 615-21. PMID 12840827 DOI: 10.1002/Chir.10259  0.359
2003 García C, Libra ER, Carroll PJ, Walsh PJ. A one-pot diastereoselective synthesis of cis-3-hexene-1,6-diols via an unusually reactive organozinc intermediate. Journal of the American Chemical Society. 125: 3210-1. PMID 12630865 DOI: 10.1021/Ja029449D  0.459
2003 Rı́os-Moreno G, Aguirre G, Parra-Hake M, Walsh PJ. Synthesis, characterization, and structure of dinuclear copper(I) and silver(I) complexes of ortho-functionalized 1,3-bis(aryl)triazenide ligands Polyhedron. 22: 563-568. DOI: 10.1016/S0277-5387(02)01413-4  0.383
2002 Buono F, Walsh PJ, Blackmond DG. Rationalization of anomalous nonlinear effects in the alkylation of substituted benzaldehydes Journal of the American Chemical Society. 124: 13652-13653. PMID 12431076 DOI: 10.1021/Ja027406R  0.349
2002 Chen YK, Lurain AE, Walsh PJ. A general, highly enantioselective method for the synthesis of D and L alpha-amino acids and allylic amines. Journal of the American Chemical Society. 124: 12225-31. PMID 12371863 DOI: 10.1021/Ja027271P  0.824
2002 Waltz KM, Gavenonis J, Walsh PJ. A simple, reliable, catalytic asymmetric allylation of ketones. Angewandte Chemie (International Ed. in English). 41: 3697-9; 3522. PMID 12370935 DOI: 10.1002/1521-3773(20021004)41:19<3697::Aid-Anie3697>3.0.Co;2-U  0.809
2002 García C, LaRochelle LK, Walsh PJ. A practical catalytic asymmetric addition of alkyl groups to ketones. Journal of the American Chemical Society. 124: 10970-1. PMID 12224931 DOI: 10.1021/Ja026568K  0.497
2002 Balsells J, Davis TJ, Carroll P, Walsh PJ. Insight into the mechanism of the asymmetric addition of alkyl groups to aldehydes catalyzed by titanium-BINOLate species. Journal of the American Chemical Society. 124: 10336-48. PMID 12197736 DOI: 10.1021/Ja0171658  0.359
2002 Rios R, Jimeno C, Carroll PJ, Walsh PJ. Kinetic resolution of atropisomeric amides. Journal of the American Chemical Society. 124: 10272-3. PMID 12197717 DOI: 10.1021/Ja026436R  0.728
2002 Costa AM, Jimeno C, Gavenonis J, Carroll PJ, Walsh PJ. Optimization of catalyst enantioselectivity and activity using achiral and meso ligands. Journal of the American Chemical Society. 124: 6929-41. PMID 12059216 DOI: 10.1021/Ja0166601  0.809
2002 Balsells J, Carroll PJ, Walsh PJ. Achiral tetrahydrosalen ligands for the synthesis of C(2)-symmetric titanium complexes: a structure and diastereoselectivity study. Inorganic Chemistry. 40: 5568-74. PMID 11599955 DOI: 10.1021/Ic010456X  0.384
2002 Chen YK, Lurain AE, Walsh PJ. A general, highly enantioselective method for the synthesis of D and L α-amino acids and allylic amines Journal of the American Chemical Society. 124: 12225-12231. DOI: 10.1021/ja027271p  0.795
2002 Gama A, Flores-López LZ, Aguirre G, Parra-Hake M, Somanathan R, Walsh PJ. Steric effects in the design of chiral Schiff base–titanium complexes: new catalysts for asymmetric trimethylsilylcyanation of aldehydes Tetrahedron: Asymmetry. 13: 149-154. DOI: 10.1016/S0957-4166(02)00073-3  0.479
2001 Chen YK, Costa AM, Walsh PJ. Substrate dependence of nonlinear effects: mechanistic probe and practical applications. Journal of the American Chemical Society. 123: 5378-9. PMID 11457413 DOI: 10.1021/Ja0158004  0.512
2001 Davis TJ, Balsells J, Carroll PJ, Walsh PJ. Optimization of asymmetric catalysts using achiral ligands: metal geometry-induced ligand asymmetry. Organic Letters. 3: 2161-4. PMID 11440569 DOI: 10.1021/Ol016003D  0.372
2001 Davis TJ, Balsells J, Carroll PJ, Walsh PJ. Snapshots of titanium BINOLate complexes with diverse solid state structures. Organic Letters. 3: 699-702. PMID 11259040 DOI: 10.1021/Ol0070381  0.344
2001 Balsells J, Costa AM, Walsh PJ. Temperature-dependent nonlinear effects and catalyst evolution in the asymmetric addition of diethylzinc to benzaldehyde Israel Journal of Chemistry. 41: 251-262. DOI: 10.1560/Lm1C-Rrq5-12Aj-Njjc  0.378
2001 Ng K, Somanathan R, Walsh PJ. Synthesis of homochiral pentadentate sulfonamide-based ligands Tetrahedron: Asymmetry. 12: 1719-1722. DOI: 10.1016/S0957-4166(01)00292-0  0.401
2000 Balsells J, Walsh PJ. Asymmetric cyclopropanation of allylic alcohols employing Sulfonamide/Schiff base ligands Journal of Organic Chemistry. 65: 5005-5008. PMID 10956484 DOI: 10.1021/Jo991704Y  0.378
2000 Royo E, Betancort JM, Davis TJ, Carroll P, Walsh PJ. Synthesis, structure, and catalytic properties of bis[bis(sulfonamido)] titanium complexes Organometallics. 19: 4840-4851. DOI: 10.1021/Om000443B  0.426
2000 Flores-Lopéz LZ, Parra-Hake M, Somanathan R, Walsh PJ. Structure/Enantioselectivity Study of the Asymmetric Addition of Trimethylsilylcyanide to Benzaldehyde Catalyzed by Ti(IV)−Schiff Base Complexes Organometallics. 19: 2153-2160. DOI: 10.1021/Om000127X  0.428
2000 and JB, Walsh PJ. The Use of Achiral Ligands to Convey Asymmetry: Chiral Environment Amplification Journal of the American Chemical Society. 122: 1802-1803. DOI: 10.1021/Ja992892C  0.326
1999 Nanthakumar A, Miura J, Diltz S, Lee CK, Aguirre G, Ortega F, Ziller JW, Walsh PJ. Synthesis and Structure of Asymmetric Bis(sulfonamide) Based Copper(II) Complexes: Influence of Diastereomeric Interactions in the Solid State. Inorganic Chemistry. 38: 3010-3013. PMID 11671053 DOI: 10.1021/Ic981093C  0.331
1999 Pritchett S, Gantzel P, Walsh PJ. Synthesis and Structural Study of Titanium Bis(sulfonamido) Bis(amide) Complexes Organometallics. 18: 823-831. DOI: 10.1021/Om9807755  0.365
1999 Rodrı́guez J, Parra-Hake M, Aguirre G, Ortega F, Walsh PJ. Synthesis and structure of a dinuclear copper complex of a bis(bidentate)triazenide ligand Polyhedron. 18: 3051-3055. DOI: 10.1016/S0277-5387(99)00231-4  0.368
1999 Meprathu BV, Diltz S, Walsh PJ, Protasiewicz JD. Hypervalent iodine nitrene precursors bearing N-heterocyclic rings Tetrahedron Letters. 40: 5459-5460. DOI: 10.1016/S0040-4039(99)01065-5  0.378
1998 Pritchett S, Woodmansee DH, Gantzel P, Walsh PJ. Synthesis and crystal structures of Bis(sulfonamido) titanium bis(alkoxide) complexes: Mechanistic implications in the bis(sulfonamide) catalyzed asymmetric addition of dialkylzinc reagents to aldehydes [12] Journal of the American Chemical Society. 120: 6423-6424. DOI: 10.1021/Ja973557W  0.403
1998 Westhusin S, Gantzel P, Walsh PJ. Synthesis and Crystal Structures of Magnesium and Calcium Triazenide Complexes Inorganic Chemistry. 37: 5956-5959. DOI: 10.1021/Ic980580P  0.31
1998 Balsells J, Mejorado L, Phillips M, Ortega F, Aguirre G, Somanathan R, Walsh PJ. Synthesis of chiral sulfonamide/Schiff base ligands Tetrahedron Asymmetry. 9: 4135-4142. DOI: 10.1016/S0957-4166(98)00431-5  0.443
1998 Pritchett S, Woodmansee DH, Davis TJ, Walsh PJ. Improved methodology for the asymmetric alkylation of aldehydes employing bis(sulfonamide) complexes Tetrahedron Letters. 39: 5941-5942. DOI: 10.1016/S0040-4039(98)01220-9  0.437
1998 Larter ML, Phillips M, Ortega F, Aguirre G, Somanathan R, Walsh PJ. Synthesis of racemic cis and trans 2,4,5-tripyridylimidazolines Tetrahedron Letters. 39: 4785-4788. DOI: 10.1016/S0040-4039(98)00957-5  0.317
1997 Pritchett S, Gantzel P, Walsh PJ. Synthesis and Crystal Structures of Chiral Titanium Bis(sulfonamido) Bis(amide) Complexes:  Differences in Ligand Hapticity Caused by Crystal Packing Forces Organometallics. 16: 5130-5132. DOI: 10.1021/Om970695L  0.341
1997 Diltz S, Aguirre G, Ortega F, Walsh PJ. Synthesis of chiral heteroaromatic tetradentate sulfonamide based ligands Tetrahedron: Asymmetry. 8: 3559-3562. DOI: 10.1016/S0957-4166(97)00517-X  0.416
1997 Ho DE, Betancort JM, Woodmansee DH, Larter ML, Walsh PJ. Synthesis of new chiral tetradentate sulfonamide based ligands Tetrahedron Letters. 38: 3867-3870. DOI: 10.1016/S0040-4039(97)00796-X  0.462
1997 Guo C, Qiu J, Zhang X, Verdugo D, Larter ML, Christie R, Kenney P, Walsh PJ. Enantioselective addition of diethylzinc to benzaldehyde catalyzed by chiral titanate complexes with helical ligands Tetrahedron. 53: 4145-4158. DOI: 10.1016/S0040-4020(97)00134-8  0.45
1995 Hanna TA, Baranger AM, Walsh PJ, Bergman RG. Formation of .alpha.,.beta.-Unsaturated Imines and Successful Trapping of Oxozirconocene in a [4 + 2] Azaoxametallacyclohexene Retrocycloaddition Journal of the American Chemical Society. 117: 3292-3293. DOI: 10.1021/Ja00116A042  0.647
1995 Meyer KE, Walsh PJ, Bergman RG. A Mechanistic Study of the Cycloaddition-Cycloreversion Reactions of Zirconium-Imido Complex Cp2Zr(N-t-Bu)(THF) with Organic Imines and Organic Azides Journal of the American Chemical Society. 117: 974-985. DOI: 10.1021/Ja00108A014  0.463
1994 Meyer KE, Walsh PJ, Bergman RG. Zirconium-Mediated Imine Metathesis. Synthesis of 2,4-Diaza-1-zirconiacyclobutanes and the Mechanism of Their Reactions with Imines and Alkynes Journal of the American Chemical Society. 116: 2669-2670. DOI: 10.1021/Ja00085A077  0.549
1994 Walsh PJ, Tong Ho P, King SB, Sharpless KB. Asymmetric dihydroxylation of olefins containing sulfur: Chemoselective oxidation of CC double bonds in the presence of sulfides, 1,3-dithianes, and disulfides Tetrahedron Letters. 35: 5129-5132. DOI: 10.1016/S0040-4039(00)77045-6  0.541
1993 Walsh PJ, Sharpless KB. Asymmetric Dihydroxylation (AD) of α,β-Unsaturated Ketones Synlett. 1993: 605-606. DOI: 10.1055/S-1993-22548  0.464
1993 Walsh PJ, Hollander FJ, Bergman RG. Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivity Organometallics. 12: 3705-3723. DOI: 10.1021/Om00033A049  0.452
1993 Baranger AM, Walsh PJ, Bergman RG. Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature Journal of the American Chemical Society. 115: 2753-2763. DOI: 10.1021/Ja00060A025  0.728
1993 Walsh PJ, Bennani YL, Sharpless KB. Asymmetric dihydroxylation (AD)/cyclization of N-diBoc allylic and homoallylic amines: Selective differentiation of the hydroxyl groups Tetrahedron Letters. 34: 5545-5548. DOI: 10.1016/S0040-4039(00)73877-9  0.548
1993 Arrington MP, Bennani YL, Göbel T, Walsh P, Zhao SH, Sharpless KB. Modified cinchona alkaloid ligands: Improved selectivities in the osmium tetroxide catalyzed asymmetric dihydroxylation (AD) of terminal olefins Tetrahedron Letters. 34: 7375-7378. DOI: 10.1016/S0040-4039(00)60129-6  0.561
1992 Carney MJ, Walsh PJ, Hollander FJ, Bergman RG. Generation of the highly reactive intermediates Cp*2Zr:O and Cp*2Zr:S: trapping reactions with alkynes, nitriles, and dative ligands Organometallics. 11: 761-777. DOI: 10.1021/Om00038A040  0.498
1992 Walsh PJ, Baranger AM, Bergman RG. Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2 Journal of the American Chemical Society. 114: 1708-1719. DOI: 10.1021/Ja00031A026  0.723
1992 Walsh PJ, Hollander FJ, Bergman RG. Insertion of alkynes into zirconium-nitrogen bonds leading to 2,3-diazametallacyclopentenes. Generation and reactivity of Cp2Zr(N2Ph2) Journal of Organometallic Chemistry. 428: 13-47. DOI: 10.1016/0022-328X(92)83217-6  0.518
1991 Walsh PJ, Carney MJ, Bergman RG. Generation, dative ligand trapping, and nitrogen-nitrogen bond cleavage reactions of the first monomeric .eta.1-hydrazido zirconocene complex, (Cp2Zr:NNPh2). A zirconium mediated synthesis of indoles Journal of the American Chemical Society. 113: 6343-6345. DOI: 10.1021/Ja00016A101  0.548
1990 Carney MJ, Walsh PJ, Bergman RG. Room temperature generation of reactive intermediates Cp*Zr:O and Cp*2Zr:S: trapping reactions with unsaturated organic molecules and dative ligands Journal of the American Chemical Society. 112: 6426-6428. DOI: 10.1021/Ja00173A057  0.538
1990 Walsh PJ, Hollander FJ, Bergman RG. Generation and trapping of the diphenylhydrazido(2-) complex Cp2Zr(N2Ph2). Insertion of internal alkynes into a metal-nitrogen bond, leading to 2,3-diazametallacyclopentenes Journal of the American Chemical Society. 112: 894-896. DOI: 10.1021/Ja00158A074  0.45
1990 CARNEY MJ, WALSH PJ, BERGMAN RG. ChemInform Abstract: Room Temperature Generation of Reactive Intermediates Cp*2Zr=O and Cp*2Zr=S: Trapping Reactions with Unsaturated Organic Molecules and Dative Ligands. Cheminform. 21. DOI: 10.1002/chin.199049233  0.4
1990 WALSH PJ, HOLLANDER FJ, BERGMAN RG. ChemInform Abstract: Generation and Trapping of the Diphenylhydrazido(2-) Complex Cp2Zr(N2Ph2). Insertion of Internal Alkynes into a Metal-Nitrogen Bond, Leading to 2,3-Diazametallacyclopentenes. Cheminform. 21. DOI: 10.1002/chin.199017232  0.389
1990 CARNEY MJ, WALSH PJ, HOLLANDER FJ, BERGMAN RG. ChemInform Abstract: A Reactive Organometallic Oxo Intermediate, Cp*2Zr=O: Generation and Subsequent Trapping Reactions Forming Alkyne and Nitrile Addition Products. Cheminform. 21. DOI: 10.1002/chin.199008248  0.416
1989 Carney MJ, Walsh PJ, Hollander FJ, Bergman RG. A reactive organometallic oxo intermediate, Cp*2Zr:O: generation and subsequent trapping reactions forming alkyne and nitrile addition products Journal of the American Chemical Society. 111: 8751-8753. DOI: 10.1021/Ja00205A045  0.475
1989 WALSH PJ, HOLLANDER FJ, BERGMAN RG. ChemInform Abstract: Generation, Alkyne Cycloaddition, Arene C-H Activation, N-H Activation, and Dative Ligand Trapping Reactions of the First Monomeric Imidozirconocene (Cp2Zr=NR) Complexes. Cheminform. 20. DOI: 10.1002/chin.198915250  0.425
1988 Walsh PJ, Hollander FJ, Bergman RG. Generation, alkyne cycloaddition, arene carbon-hydrogen activation, nitrogen-hydrogen activation and dative ligand trapping reactions of the first monomeric imidozirconocene (Cp2Zr:NR) complexes Journal of the American Chemical Society. 110: 8729-8731. DOI: 10.1021/Ja00234A043  0.495
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