Russell N. Grimes - Publications

Affiliations: 
Chemistry University of Virginia, Charlottesville, VA 
Area:
synthesis and study of polyhedral molecular cage compounds of boron
Website:
http://chemistry.as.virginia.edu/grimes

213 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2004 Fabrizi De Biani F, Corsini M, Zanello P, Yao H, Bluhm ME, Grimes RN. Electronic properties of mononuclear, dinuclear, and polynuclear cobaltacarboranes: electrochemical and spectroelectrochemical studies. Journal of the American Chemical Society. 126: 11360-9. PMID 15355119 DOI: 10.1021/Ja047966L  0.806
2003 Yao H, Sabat M, Grimes RN, Fabrizi de Biani F, Zanello P. Metallacarborane-based nanostructures: a carbon-wired planar octagon. Angewandte Chemie (International Ed. in English). 42: 1002-5. PMID 12616549 DOI: 10.1002/Anie.200390255  0.597
2003 Grimes RN. Synthesis and properties of linear, branched, and cyclic metallacarborane oligomers Pure and Applied Chemistry. 75: 1211-1218. DOI: 10.1351/Pac200375091211  0.324
2003 Yao H, Grimes RN, Corsini M, Zanello P. Polynuclear Metallacarborane-Hydrocarbon assemblies: Metallacaraborane dendrimers Organometallics. 22: 4381-4383. DOI: 10.1021/Om034057G  0.644
2003 Yao H, Grimes RN. Cp-functionalized building blocks for polymetallacarborane assemblies. Multinuclear cobaltacarborane complexes on fulvalene and 1,3,5-tris(cyclopentadienyl)benzene scaffolds Organometallics. 22: 4539-4546. DOI: 10.1021/Om030503O  0.476
2003 Yao H, Sabat M, Grimes RN, Zanello P, Fabrizi de Biani F. Alkynyl-linked poly(cobaltacarboranes). Directed synthesis, structures, and electrochemistry of linear complexes and benzene-centered pinwheels Organometallics. 22: 2581-2593. DOI: 10.1021/Om0301379  0.725
2003 Yao H, Grimes RN. Small cobaltacarborane clusters in synthesis. Peralkylation, perhalogenation, and macrocycle construction Journal of Organometallic Chemistry. 680: 51-60. DOI: 10.1016/S0022-328X(03)00164-5  0.695
2002 Grimes RN. Putting small metallacarboranes to work: A review Collection of Czechoslovak Chemical Communications. 67: 728-750. DOI: 10.1135/Cccc20020728  0.364
2002 Russell JM, Sabat M, Grimes RN. Radical substitution at boron in small cobaltacarboranes. Conversion of η5-C5Me5 to η4-C5Me5R complexes Organometallics. 21: 5613-5621. DOI: 10.1021/Om020716Y  0.492
2002 Yao H, Sabat M, Grimes RN. Wired multidecker sandwich assemblies. Stepwise construction of a hexanuclear benzene-centered tris(alkynyl triple-decker) complex1 Organometallics. 21: 2833-2835. DOI: 10.1021/Om020289O  0.702
2002 Fabrizi de Biani Fi, Fontani M, Ruiz E, Zanello P, Russell JM, Grimes RN. Electronic interactions in (η6-arene) ferracarboranes Organometallics. 21: 4129-4137. DOI: 10.1021/Om0201617  0.465
2002 Russell JM, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 59. Synthesis and linkage of boron-functionalized ferracarborane clusters Organometallics. 21: 4113-4128. DOI: 10.1021/Om020158N  0.483
2002 Weiss R, Grimes RN. Sources of line width in boron-11 nuclear magnetic resonance spectra. Scalar relaxation and boron-boron coupling in tetraborane(10) and pentaborane(9) Cheminform. 9. DOI: 10.1002/Chin.197823015  0.463
2001 Schanz HJ, Sabat M, Grimes RN. nido↔closo Interconversion of Six-Vertex Metallacarboranes: Access to CoC B and CoC B Clusters with Nonadjacent Carbon Atoms. Angewandte Chemie (International Ed. in English). 40: 2705-2707. PMID 29712332 DOI: 10.1002/1521-3773(20010716)40:14<2705::Aid-Anie2705>3.0.Co;2-J  0.784
2001 Schanz HJ, Sabat M, Grimes RN. nido<-->closo Interconversion of Six-Vertex Metallacarboranes: Access to CoC(2)B(3) and CoC(2)B(4) Clusters with Nonadjacent Carbon Atoms Organotransition-Metal Metallacarboranes, part 57. This work was supported in part by the National Science Foundation (grant CHE 9980708) and the Alexander von Humboldt Foundation (Feodor Lynen postdoctoral fellowship to H.-J. Schanz). Part 56: M. Bluhm, H. Pritzkow, W. Siebert, R. N. Grimes, Angew. Chem. 2000, 112, 4736; Angew. Chem. Int. Ed. 2000, 39, 4562. Angewandte Chemie (International Ed. in English). 40: 2705-2707. PMID 11458381 DOI: 10.1002/1521-3773(20010716)40:14<2705::AID-ANIE2705>3.0.CO;2-J  0.789
2001 Malaba D, Sabat M, Grimes RN. Alkynyl substitution and linkage in cobaltacarborane sandwich complexes European Journal of Inorganic Chemistry. 2557-2562. DOI: 10.1002/1099-0682(200109)2001:10<2557::Aid-Ejic2557>3.0.Co;2-H  0.8
2000 Bluhm M, Pritzkow H, Siebert W, Grimes RN. Benzene-Centered Tri- and Tetrametallacarborane Sandwich Complexes Organotransition-Metal Metallacarboranes, part 56. This work was supported in part by the National Science Foundation (grant CHE 9980708 to R.N.G.) and the Deutsche Forschungsgemeinschaft (SFB 247, to W.S. for M.B.). Part 55: T. Dodge, M. A. Curtis, J. M. Russell, M. Sabat, M. G. Finn, R. N. Grimes, J. Am. Chem. Soc. 2000, 122, 10 573. Angewandte Chemie (International Ed. in English). 39: 4562-4564. PMID 11169670 DOI: 10.1002/1521-3773(20001215)39:24<4562::Aid-Anie4562>3.0.Co;2-8  0.752
2000 Hall IH, Lackey CB, Kistler TD, Durham RW, Russell JM, Grimes RN. Antitumor activity of mono- and dimetallic transition metal carborane complexes of Ta, Fe, Co, Mo, or W. Anticancer Research. 20: 2345-54. PMID 10953295  0.33
2000 Grimes RN. Metal-carborane multidecker sandwiches as building blocks for metallopolymers and nanostructured materials Molecular Crystals and Liquid Crystals Science and Technology Section a: Molecular Crystals and Liquid Crystals. 342: 7-14. DOI: 10.1080/10587250008038238  0.45
2000 Stockman KE, Boring EA, Sabat M, Finn MG, Grimes RN. Small carborane ligands as tailorable Cp surrogates. Halogenation, alkylation, and arylation at metal and cage positions on CpX2M(Et2C2B4H4) complexes (M = Ta, Nb) Organometallics. 19: 2200-2207. DOI: 10.1021/Om000090G  0.811
2000 Dodge T, Curtis MA, Russell JM, Sabat M, Finn MG, Grimes RN. Titanium and zirconium Et2C2B4H4-Metal-Phosphine complexes: Synthesis, characterization, and ethylene polymerization activity Journal of the American Chemical Society. 122: 10573-10580. DOI: 10.1021/Ja001366E  0.794
2000 Grimes RN. Metallacarboranes in the new millennium Coordination Chemistry Reviews. 200: 773-811. DOI: 10.1016/S0010-8545(00)00262-9  0.301
1999 Parker KG, Russell JM, Sabat M, Grimes RN. A novel heterooctametallic metallacarborane tetramer Collection of Czechoslovak Chemical Communications. 64: 819-828. DOI: 10.1135/Cccc19990819  0.496
1999 Chin TT, Grimes RN, Geiger WE. A delocalized analogue of the bicobaltocene cation derived from reduction of a d6d6 (fulvalenediyl)bis(cobaltacarborane) complex: Electrochemistry, ESR, optical spectroscopy, and IR spectroscopy of the carborane group Inorganic Chemistry. 38: 93-99. DOI: 10.1021/Ic980382Y  0.329
1999 Grimes RN. Small carborane ligands as spectators and as players Journal of Organometallic Chemistry. 581: 1-12. DOI: 10.1016/S0022-328X(99)00050-9  0.43
1998 Curtis MA, Houser EJ, Sabat M, Grimes RN. New Metallacarborane Chemistry: Molybdenum and Tungsten Carbonyl Multidecker Sandwiches. Cluster Dimers Linked via Metal-Metal Bonds(1). Inorganic Chemistry. 37: 102-111. PMID 11670267 DOI: 10.1021/Ic971297D  0.812
1998 Boring E, Sabat M, Finn MG, Grimes RN. Alkene and alkyne insertion reactions with tantalum metallacarborane complexes: The Et2C2B4H4 2- carborane ligand as a spectator and participant1 Organometallics. 17: 3865-3874. DOI: 10.1021/Om980242W  0.783
1998 Curtis MA, Finn MG, Grimes RN. A hydridotantalum(V)-carborane analogue of Schwartz's reagent: Synthesis and reactivity Journal of Organometallic Chemistry. 550: 469-472. DOI: 10.1016/S0022-328X(97)00555-X  0.664
1997 Curtis MA, Müller T, Beez V, Pritzkow H, Siebert W, Grimes RN. Apically Linked Small Metallacarborane Clusters. Directed Synthesis and Structural Characterization of 7,7'-[CpCo(2,3-Et(2)C(2)B(4)H(3)](2) and [CpCo(2,3-Et(2)C(2)B(4)H(3)-7)](2)X Complexes (X = MeCH, HC=CH, C&tbd1;C)(,)(1). Inorganic Chemistry. 36: 3602-3608. PMID 11670050 DOI: 10.1021/Ic970221E  0.631
1997 Boring E, Sabat M, Finn MG, Grimes RN. Insertion reactions of tantalum (V) carborane alkyl and aryl complexes with nitriles and isonitriles. Thermal and photochemical isomerization of η2-iminoacyl isomers1 Organometallics. 16: 3993-4000. DOI: 10.1021/Om9703447  0.817
1996 Franz DA, Houser EJ, Sabat M, Grimes RN. Organotransition-Metal Metallacarboranes. 46. Multidecker Sandwiches of the Cobalt Group Metals(,)(1). Inorganic Chemistry. 35: 7027-7034. PMID 11666883 DOI: 10.1021/Ic9606587  0.803
1996 Curtis MA, Sabat M, Grimes RN. "Recapitation" of nido-Metallacarboranes as a Synthetic Tool: Preparation of Apically Substituted CoC(2)B(4) Clusters via Boron Insertion(1). Inorganic Chemistry. 35: 6703-6707. PMID 11666832 DOI: 10.1021/Ic960691T  0.639
1996 Houser EJ, Curtis MA, Sabat M, Grimes RN. Organotransition-metal metallacarboranes 45. Synthesis and structure of hydridoruthenacarborane double-decker and triple-decker sandwich complexes Journal of Organometallic Chemistry.. 536: 115-121. DOI: 10.1016/S0022-328X(96)06645-4  0.643
1996 Grimes RN. Metal-carborane multidecker sandwich complexes as building blocks for new materials Applied Organometallic Chemistry. 10: 209-225. DOI: 10.1002/(Sici)1099-0739(199604)10:3/4<209::Aid-Aoc469>3.0.Co;2-Q  0.387
1995 Wang X, Sabat M, Grimes RN. Organotransition-Metal Metallacarboranes. Xil: Synthesis And Structure Of B-B- And Cp*-Cp*-Linked Cobaltacarborane Clusters Organometallics. 14: 4668-4675. DOI: 10.1021/Om00010A034  0.678
1995 Stockman KE, Garrett DL, Grimes RN. Organotransition-metal metallacarboranes. 40. Regiospecific halogenation of transition-metal small carborane complexes Organometallics. 14: 4661-4667. DOI: 10.1021/Om00010A033  0.345
1995 Greiwe P, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 39. Arene-capped ruthenium-carborane tetradecker sandwich complexes Organometallics. 14: 3683-3692. DOI: 10.1021/Om00008A015  0.377
1995 Stockman KE, Houseknecht KL, Boring EA, Sabat M, Finn MG, Grimes RN. Organotransition-Metal Metallacarboranes. 38. C2B3 and C2B4 Carborane Ligands as Cyclopentadienyl Analogs: Early Transition Metal Complexes Organometallics. 14: 3014-3029. DOI: 10.1021/Om00006A052  0.795
1995 Wang X, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 43. Directed synthesis of carborane-endcapped multidecker sandwiches Journal of the American Chemical Society. 117: 12218-12226. DOI: 10.1021/Ja00154A024  0.661
1995 Wang X, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 44. Construction of pentadecker and hexadecker sandwiches from triple-decker building blocks Journal of the American Chemical Society. 117: 12227-12234. DOI: 10.1021/Ja00154A023  0.643
1995 Houseknecht KL, Stockman KE, Sabat M, Finn MG, Grimes RN. Organotransition-Metal Metallacarboranes. 36. A Remarkably Stable Transition-Metal-Benzyne Complex: Synthesis and Structure of Cp(PMe3)(.eta.2-C6H4)Ta(Et2C2B4H4) Journal of the American Chemical Society. 117: 1163-1164. DOI: 10.1021/Ja00108A047  0.453
1995 Wang X, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 42. Synthesis and cluster fusion of iron-centered tetradecker sandwiches Inorganic Chemistry. 34: 6509-6513. DOI: 10.1021/Ic00130A017  0.649
1995 Stephan M, Müller P, Zenneck U, Pritzkow H, Siebert W, Grimes RN. Organotransition-metal metallacarboranes. 37. Paramagnetic iron-cobalt and dicobalt triple-decker sandwich complexes Inorganic Chemistry. 34: 2058-2067. DOI: 10.1021/Ic00112A018  0.761
1995 Grimes RN. Cluster forming and cage fusion in metallacarborane chemistry Coordination Chemistry Reviews. 143: 71-96. DOI: 10.1016/0010-8545(94)07006-6  0.411
1995 Stockman KE, Houseknecht KL, Boring EA, Sabat M, Finn MG, Grimes RN. C2B3 and C2B4 carborane ligands as cyclopentadienyl analogues: Early transition metal complexes Organometallics. 14: 3014-3029.  0.798
1995 Houseknecht KL, Stockman KE, Sabat M, Finn MG, Grimes RN. A remarkably stable transition-metal-benzyne complex: Synthesis and structure of Cp(PMe3)(η2-C6H4)Ta(Et 2C2B4H4)1 Journal of the American Chemical Society. 117: 1163-1164.  0.368
1994 Wang X, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 34. Synthesis and structure of a hexadecker sandwich Journal of the American Chemical Society. 116: 2687-2688. DOI: 10.1021/Ja00085A086  0.664
1994 Stephan M, Hauss J, Zenneck U, Siebert W, Grimes RN. Organotransition-Metal Metallacarboranes. Xxxv: Electrochemistry, Esr, Andcorrelated Nmr Spectorscopy Of Paramagnetic Mono- And Dinuclear Cp*Coc2B4 C Lusters Inorganic Chemistry. 33: 4211-4215. DOI: 10.1021/Ic00097A004  0.77
1993 Robert Pipal J, Grimes RN. Organotransition-metal metallacarboranes electrochemistry of polymetallacarborane staircase oligomers Organometallics. 12: 4459-4463. DOI: 10.1021/Om00035A033  0.315
1993 Robert Pipal J, Grimes RN. Organotransition-metal metallacarboranes. 32. Electrochemical and electron spin resonance studies of tetradecker sandwich complexes Organometallics. 12: 4452-4458. DOI: 10.1021/Om00035A032  0.31
1993 Meng X, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 31. Metallacarborane staircase oligomers. Stepwise assembly via tetradecker stacking reactions Journal of the American Chemical Society. 115: 6143-6151. DOI: 10.1021/Ja00067A033  0.654
1993 Meng X, Waterworth S, Sabat M, Grimes RN. Cobaltocenium metallacarboranide mixed-sandwich salts, Cp2Co+(Et2C2B4H4)2M- (M = CoIII, ironIII) and Cp2Co+(Et2C2B3H4-X)CoIII(Et2C2B4H4)- (X = H, Me) Inorganic Chemistry. 32: 3188-3192. DOI: 10.1021/Ic00066A033  0.773
1993 Piepgrass KW, Curtis MA, Wang X, Meng X, Sabat M, Grimes RN. Carbon-rich metallacarboranes. 15. Novel metal-promoted cluster fusion reactions Inorganic Chemistry. 32: 2156-2163. DOI: 10.1021/Ic00062A046  0.813
1992 Piepgrass KW, Stockman KE, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 24. (C5Me5)Co(Et2C2B3H4-R) metallacarborane sandwich complexes as versatile synthons. Introduction of electron-withdrawing substituents Organometallics. 11: 2404-2413. DOI: 10.1021/Om00043A022  0.793
1992 Piepgrass KW, Grimes RN. Organotransition-metal metallacarboranes. 23. (C5Me5)Co(Et2C2B3H4-R) metallacarborane sandwich complexes as versatile synthons. Introduction of organomethyl functional groups at boron Organometallics. 11: 2397-2403. DOI: 10.1021/Om00043A021  0.79
1992 Merkert JW, Davis JH, Geiger WE, Grimes RN. Delocalization in bimetallic triple-decker complexes: Electrochemistry, ESR spectroscopy, and spectroelectrochemistry of (p-MeC6H4CHMe2)2Ru 2(Et2C2B3H3) and CpCo(Et2C2B3H3)Ru(p-MeC 6H4CHMe2) and derived ions Journal of the American Chemical Society. 114: 9846-9851. DOI: 10.1021/Ja00051A017  0.54
1992 Stockman KE, Sabat M, Finn MG, Grimes RN. Organotransition-metal metallacarboranes. 26. Carborane ligands in organometallic chemistry: a new class of Fischer carbene complexes Journal of the American Chemical Society. 114: 8733-8735. DOI: 10.1021/Ja00048A075  0.387
1992 Stephan M, Davis JH, Meng X, Chase KJ, Hauss J, Zenneck U, Pritzkow H, Siebert W, Grimes RN. Organotransition-metal metallacarboranes. 25.1 redox chemistry and electronic studies of mono- and dinuclear iron(II)/iron(III) sandwich complexes Journal of the American Chemical Society. 114: 5214-5221. DOI: 10.1021/Ja00039A037  0.793
1992 Piepgrass KW, Meng X, Hölscher M, Sabat M, Grimes RN. Tetradecker metallacarborane sandwiches: Synthesis via double-decker stacking and structural characterization of Co-Co-Co, Co-Ni-Co, and Co-Ru-Co complexes Inorganic Chemistry. 31: 5202-5210. DOI: 10.1021/Ic00051A010  0.78
1992 Benvenuto MA, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 29. Synthesis of selectively C- and B-substituted double- and triple-decker sandwiches. (.eta.5-C5Me5)CoIII(.eta.5-R2C2B3R'3H2) cobaltocenium analogs Inorganic Chemistry. 31: 3904-3909. DOI: 10.1021/Ic00045A010  0.364
1992 Benvenuto MA, Grimes RN. Organotransition-metal metallacarboranes. XXVIII : Controlled substitution at cage carbon atoms in CoC2B4 clusters. Linkage of bis(cobaltacarborane) sandwich complexes via carbon-bound bridging groups Inorganic Chemistry. 31: 3897-3903. DOI: 10.1021/Ic00045A009  0.386
1992 Benvenuto MA, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 29. Synthesis of selectively C- and B-substituted double- and triple-decker sandwiches. (η5-C5Me5)CoIII(η 5-R2C2B3R′3H 2) cobaltocenium analogues Inorganic Chemistry. 31: 3904-3909.  0.305
1991 Grimes R. Small carboranes as building blocks in designed organometallic synthesis Pure and Applied Chemistry. 63: 369-372. DOI: 10.1351/Pac199163030369  0.369
1991 Chase KJ, Bryan RF, Woode MK, Grimes RN. Organotransition-metal metallacarboranes. 21. Transition-metal sandwich complexes of heterocyclic ligands. Carborane-stabilized .eta.5-pyrrolyl and .eta.5-phospholyl double-decker and triple-decker compounds: synthesis, structure, and electrochemistry Organometallics. 10: 2631-2642. DOI: 10.1021/Om00054A024  0.394
1991 Fessenbecker A, Stephan M, Grimes RN, Pritzkow H, Zenneck U, Siebert W. Organotransition-metal metallacarboranes. 19. Indenyliron(II) and -iron(III) complexes and related species. .eta.6 .fwdarw. .eta.5 Haptotropic rearrangement, electrochemistry, and polyhedral expansion of (arene)Fe(Et2C2B4H4) clusters Journal of the American Chemical Society. 113: 3061-3069. DOI: 10.1021/Ja00008A039  0.756
1991 Piepgrass KW, Davis JH, Sabat M, Grimes RN. Organotransition-metal metallacarboranes. 17. Electronic control of metallacarborane stacking reactions. Directed synthesis of Cp*Co(C2B3)M(C2B3)CoCp* tetradecker sandwiches Journal of the American Chemical Society. 113: 681-683. DOI: 10.1021/Ja00002A050  0.787
1991 Piepgrass KW, Davis JH Jr., Sabat M, Grimes RN. Unusual Organic Chemistry on a Metallacarborane Substrate: Formation of a B-Vinyl Ester from Acetyl Chloride J. Am. Chem. Soc.. 113: 680. DOI: 10.1021/Ja00002A049  0.775
1991 Benvenuto MA, Grimes RN. Organotransition-metal metallacarboranes. 20. Fluoride-catalyzed carbon-silicon bond cleavage in Cp*Co(Me3Si)2C2B4H4. Synthesis of parent Cp*CoC2B4H6 and conversion to C-substituted Cp*CoRR'C2B4H4 derivatives Inorganic Chemistry. 30: 2836-2838. DOI: 10.1021/Ic00014A004  0.338
1991 Davis JH, Benvenuto MA, Grimes RN. Organotransition-metal metallacarboranes. 18. .eta.6,.eta.5-Benzyltetramethylcyclopentadienide(1-) as a bridging ligand in multilevel iron-cobalt sandwich complexes Inorganic Chemistry. 30: 1765-1770. DOI: 10.1021/Ic00008A016  0.611
1990 Attwood MD, Davis JH, Grimes RN. Organotransition-metal metallacarboranes. 16. Directed synthesis of arene-linked metal sandwich complexes via controlled substitution on boron Organometallics. 9: 1177-1181. DOI: 10.1021/Om00118A044  0.616
1990 Davis JH, Attwood MD, Grimes RN. Organotransition-metal metallacarboranes. 15. Regiospecific B-alkylation of (arene)M(Et2C2B3H5) (M = iron, ruthenium) and (C5Me5)Co(Et2C2B3H5) sandwich complexes Organometallics. 9: 1171-1176. DOI: 10.1021/Om00118A043  0.634
1990 Fessenbecker A, Attwood MD, Grimes RN, Stephan M, Pritzkow H, Zenneck U, Siebert W. Tetradecker LM(C3B2)Co(C2B3)CoCp sandwich complexes [LM = Cp*Co, Cp*Rh, or (cymene)Ru]. Designed synthesis and electronic properties Inorganic Chemistry. 29: 5164-5168. DOI: 10.1021/Ic00351A007  0.791
1990 Fessenbecker A, Attwood MD, Bryan RF, Grimes RN, Woode MK, Stephan M, Zenneck U, Siebert W. Triple-decker sandwich complexes of cobalt, rhodium, and ruthenium bridged by C2B3 or C3B2 rings: Synthesis, structure, and electrochemistry Inorganic Chemistry. 29: 5157-5163. DOI: 10.1021/Ic00351A006  0.779
1990 Fonda KK, Grimes RN. Synthesis of R2R′2C4B8H8 tetracarbon carboranes from (η6-cyclooctatriene)iron(dicarbahexaborane) complexes via mixed-ligand thermal fusion Polyhedron. 9: 949-955. DOI: 10.1016/S0277-5387(00)84296-5  0.458
1989 Chase KJ, Grimes RN. Organotransition metal metallocarboranes. 14. Pyrrolyl-transition metal-carboranyl double-decker and triple-decker sandwich complexes Organometallics. 8: 2492-2493. DOI: 10.1021/Om00112A039  0.347
1989 Merkert JM, Geiger WE, Davis JH, Attwood MD, Grimes RN. Carborane-stabilized M(III) complexes of mononuclear and dinuclear arene complexes (M = iron, ruthenium) Organometallics. 8: 1580-1581. DOI: 10.1021/Om00108A041  0.546
1989 Attwood MD, Fonda KK, Grimes RN, Brodt G, Hu D, Zenneck U, Siebert W. Dihydrodiborolyl-transition metal-carboranyl triple-decker sandwich complexes Organometallics. 8: 1300-1303. DOI: 10.1021/Om00107A027  0.35
1989 Davis JH, Sinn E, Grimes RN. Fulvalene- and polyarene-transition metal-carborane complexes as building blocks for multilevel arrays. Stepwise synthesis and structural characterization of polymetallic linked sandwiches Journal of the American Chemical Society. 111: 4784-4790. DOI: 10.1021/Ja00195A035  0.478
1988 Davis JH, Grimes RN. nido-Carborane building-block reagents. 4. Regiospecific substitution at boron in 2,3-R2C2B4H6 Cages. Evidence for intramolecular C-H⋯Hbridge interactions in 2,3-R2C2B4H5-4-R′ derivatives Inorganic Chemistry. 27: 4213-4219. DOI: 10.1021/Ic00296A024  0.358
1988 Boyter HA, Grimes RN. Nido-Carborane building-block reagents. 3. Cyclic and open-chain oligomers incorporating -CB/sub 4/H/sub 6/C - units. Crown carboranes Inorganic Chemistry. 27: 3080-3084. DOI: 10.1021/Ic00291A008  0.355
1988 Fessler ME, Spencer JT, Lomax JF, Grimes RN. nido-Carborane building-block reagents. 1. Polycyclic arene RR′C2B4H6 derivatives: Synthesis via indenyl and fluorenyl alkynes and metal-promoted oxidative fusion Inorganic Chemistry. 27: 3069-3075. DOI: 10.1021/Ic00291A006  0.549
1987 Grimes RN. Designed synthesis of multi-functional carboranes and organotransition metal-carborane complexes Pure and Applied Chemistry. 59: 847-856. DOI: 10.1351/Pac198759070847  0.445
1987 Spencer JT, Pourian MR, Butcher RJ, Sinn E, Grimes RN. Additions and Corrections - Organotransition-Metal Metallacarboranes. 10. ð-Complexation ofnido(PhCH2)2C2B4H6at the C2B3and C6Rings. Synthesis and Crystal Structures ofnido-2,3-[(CO)3Cr(ç6-C6H5)CH2]2- 2,3-C2B4H6and (PhCH2)4C4B8H8, a Nonfluxional C4B8Cluster Organometallics. 6: 2019-2019. DOI: 10.1021/Om00152A601  0.645
1987 Spencer JT, Pourian MR, Butcher RJ, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 10. .pi.-Complexation of nido-(PhCH2)2C2B4H6 at the C2B3 and C6 rings. Synthesis and crystal structures of nido-2,3-[(CO)3Cr(.eta.6-C6H5)CH2]2-2,3-C2B4H6 and (PhCH2)4C4B8H8, a nonfluxional C4B8 cluster Organometallics. 6: 335-343. DOI: 10.1021/Om00145A016  0.633
1987 Spencer JT, Grimes RN. Organotransition-metal metallacarboranes. 9. nido-2,3-dibenzyl-2,3-dicarbahexaborane(8) [(PhCH2)2C2B4H6], a versatile multifunctional nido-carborane: Iron-polyarene sandwich compounds and chromium tricarbonyl π-complexes Organometallics. 6: 328-335. DOI: 10.1021/Om00145A015  0.58
1987 Spencer JT, Grimes RN. Organotransition-metal metallacarboranes. 8. Mono-, di-, and triiron polyarene sandwich complexes of Et2C2B4H4 2-containing fluorene, 9,10-dihydroanthracene, or [2.2]paracyclophane ligands Organometallics. 6: 323-328. DOI: 10.1021/Om00145A014  0.601
1987 Fessler ME, Whelan T, Spencer JT, Grimes RN. Bridge deprotonation of nido-2,3-RR′C2B4H6 carboranes and B5H9: A kinetic study Journal of the American Chemical Society. 109: 7416-7420. DOI: 10.1021/Ja00258A027  0.744
1987 Whelan T, Spencer JT, Pourian MR, Grimes RN. Organo transition-metal metallocarboranes. 11. Chromium tricarbonyl .eta.6-complexes of nido-2,3-(PhCH2)2C2B4H6: metal complexation and oxidative fusion Inorganic Chemistry. 26: 3116-3119. DOI: 10.1021/Ic00266A012  0.781
1987 Spencer JT, Pourian MR, Butcher RJ, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 10. π-Complexation of nido-(PhCH2)2C2B4H6 at the C2B3 and C6 Rings. Synthesis and crystal structures of nido-2,3-[(CO)3Cr(η6-C6H 5)CH2]2-2,3-C2B4H ... Organometallics. 6: 335-343.  0.37
1986 Swisher RG, Grimes RN. Arene- And Cycloalkene-Transition Metal-Carborane Sandwich Complexes Organometallic Syntheses. 104-108. DOI: 10.1016/B978-0-444-42607-9.50030-9  0.354
1985 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 7. Complexes of polycyclic arenes: Preparation and structures of (η6-arene)ferracarborane sandwiches of naphthalene and phenanthrene Organometallics. 4: 896-901. DOI: 10.1021/Om00124A017  0.412
1985 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 6. Synthesis of (CH2)n-bridged (.eta.6-arene)ferracarboranes: ferrocenophane analogs. Structure of [cyclic] [.eta.6-C6H5(CH2)3]Fe(C2B4H5) Organometallics. 4: 890-895. DOI: 10.1021/Om00124A016  0.436
1985 Swisher RG, Sinn E, Butcher RJ, Grimes RN. Organotransition-metal metallacarboranes. 5. Studies on (.eta.6-arene)(carborane)iron complexes of benzene and biphenyl. Crystal structures of (.eta.6-C6H5C6H5)Fe(Et2C2B4H4) and 1,2-[(.eta.6-C6H6)Fe(Et2C2B4H3)]2CH(CH3)CH2, a hydrocarbon-linked bis(ferracarborane) Organometallics. 4: 882-890. DOI: 10.1021/Om00124A015  0.431
1985 Brewer CT, Grimes RN. Metal-promoted fusion and linkage of B5H8-, 1-XB5H7- (X = D, CH3), B10H13-, and (.eta.5-C5H5)CoB4H7-. Facile routes to B10H14 and (.eta.5-C5H5)2Co2B8H10 isomers Journal of the American Chemical Society. 107: 3552-3557. DOI: 10.1021/Ja00298A025  0.419
1985 Wang ZT, Sinn E, Grimes RN. Carbon-rich metallacarboranes. 14. Synthesis and structure of mixed-ligand cobalt and iron complexes derived from (C2H5)4C4B8H 8 2- and (C2H5)2C2B4H 5 - Inorganic Chemistry. 24: 834-839. DOI: 10.1021/Ic00200A007  0.438
1985 Wang ZT, Sinn E, Grimes RN. Carbon-rich metallacarboranes. 13. Synthesis and structure of bis(carboranyl)cobalt complexes derived from (C2H5)4C4B8H 8 2- Inorganic Chemistry. 24: 826-833. DOI: 10.1021/Ic00200A006  0.432
1985 Brewer CT, Swisher RG, Sinn E, Grimes RN. Metal-promoted fusion of B6H9 -. Directed synthesis and structural characterization of dodecaborane(16), B12H16 Journal of the American Chemical Society. 107: 3558-3564. DOI: 10.1002/Chin.198540035  0.337
1985 Venable TL, Sinn E, Grimes RN. 1‐(η5‐CYCLOPENTADIENYL)‐ AND 1‐(η5‐PENTAMETHYLCYCLOPENTADIENYL)COBALTA‐NIDO‐PENTABORANE SANDWICH COMPLEXES CONTAINING A SQUARE CYCLIC B4H82‐ LIGAND ANALOGOUS TO C4H42‐: STRUCTURAL AND SPECTROSCOPIC STUDIES Cheminform. 16. DOI: 10.1002/Chin.198504273  0.351
1985 Brewer CT, Grimes RN. Metal-promoted fusion and linkage of B5H8 - , 1-XB5H7 (X = D, CH3), B10H13 -, and (η5-C5H5)CoB4H7 -. Facile routes to B10H14 and (η5-C5H5) ... Journal of the American Chemical Society. 107: 3552-3557.  0.307
1985 Swisher RG, Sinn E, Butcher RJ, Grimes RN. Organotransition-metal metallacarboranes. 5. Studies on (η6-arene)(carborane)iron complexes of benzene and biphenyl. Crystal structures of (η6-C6H5-C6H 5)Fe(Et2C2B4H4) and 1,2-[(η6-C6H6)Fe(Et2C ... Organometallics. 4: 882-890.  0.316
1985 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 6. Synthesis of (CH2)n-bridged (η6-arene)ferracarboranes: Ferrocenophane analogues. Structure of η6-C5H5(CH2) 2Fe(C2B4H5) Organometallics. 4: 890-895.  0.326
1984 Venable TL, Sinn E, Grimes RN. 1-[(η5-C5R5)Co]B4H 8 (R = H or Me) sandwich complexes containing a square cyclic B4H82- ligand analogous to C4H42-: Structural and spectroscopic studies Journal of the Chemical Society, Dalton Transactions. 2275-2279. DOI: 10.1039/Dt9840002275  0.45
1984 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 4. Stable .eta.8-C8H8 and .eta.7-C7H7 complexes of titanium, vanadium, and chromium: synthesis and crystal structures of (.eta.8-C8H8)M(Et2C2B4H4) (M = Ti, V) and (.eta.7-C7H7)Cr(Et2C2B4H4) Organometallics. 3: 599-605. DOI: 10.1021/Om00082A017  0.447
1984 Brewer CT, Grimes RN. Metal-induced oxidative fusion of boranes. Synthesis of dodecaborane(16), the first neutral dodecaborane Journal of the American Chemical Society. 106: 2722-2723. DOI: 10.1021/Ja00321A053  0.301
1984 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 4. Stable η8-C8H8 and η7-C7H7 complexes of titanium, vanadium, and chromium: Synthesis and crystal structures of (η8-C8H8)M[(C2H 5)2C2B4H4] (M = Ti, V) .. Organometallics. 3: 599-605.  0.341
1983 Maynard RB, Swisher RG, Grimes RN. Organotransition-metal metallacarboranes. 1. Iron complexes derived from C8H82-. Structure of (.eta.6-C8H10)Fe[2,3-(CH3)2C2B4H4] Organometallics. 14: 500-505. DOI: 10.1021/Om00076A005  0.436
1983 Swisher RG, Sinn E, Brewer GA, Grimes RN. Organotransition metal metallacarboranes. 3. The .eta.8 coordination of planar C8H82- to vanadium. Structural characterization of (.eta.8-C8H8)V(Et2C2B4H4) Journal of the American Chemical Society. 105: 2079-2080. DOI: 10.1021/Ja00345A076  0.448
1983 Maynard RB, Wang ZT, Sinn E, Grimes RN. Carbon-rich metallacarboranes. 12. Synthesis and structures of chromium(III) complexes with "nonconforming" cage geometries Inorganic Chemistry. 22: 873-878. DOI: 10.1021/Ic00148A007  0.32
1983 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 2. Synthesis and structures of (.eta.6-arene)Fe[(C2H5)2C2B4H4] complexes Organometallics. 2: 506-514. DOI: 10.1002/Chin.198329282  0.461
1983 Maynard RB, Wang Z‐, Sinn E, Grimes RN. Carbon‐Rich Metallacarboranes. Part 12. Synthesis and Structures of Chromium(III) Complexes with "Nonconforming" Cage Geometries. Cheminform. 14. DOI: 10.1002/Chin.198326293  0.322
1983 Swisher RG, Sinn E, Grimes RN. Organotransition-metal metallacarboranes. 2. Synthesis and structures of (η6-Arene)Fe[(C2H5)2C 2B4H4] complexes Organometallics. 2: 506-514.  0.367
1983 Maynard RB, Swisher RG, Grimes RN. Organotransition-metal metallacarboranes. 1. Iron complexes derived from C8H8 2-. Structure of (η6-C8H10)Fe[2,3-(CH3) 2C2B4H4] Organometallics. 2: 500-505.  0.327
1982 Grimes RN. Metallacarboranes and Metal-Boron Clusters in Organometallic Synthesis Pure and Applied Chem.. 54: 43. DOI: 10.1351/Pac198254010043  0.473
1982 Finster D, Grimes R. Additions and Corrections - Electron-Rich Carboranes. Studies of a Stereochemically Novel System, (CH3)4C4B7H9, an 11-Vertex Arachno Cluster Journal of the American Chemical Society. 104: 6887-6887. DOI: 10.1021/Ja00388A602  0.785
1982 Borodinsky L, Sinn E, Grimes RN. Borane-commo-carboranes. 2. Crystal and molecular structures of [2,3-(C2H5)2C2B4H4]-5-Co[B9H12-1-O(CH2)4], [2,3-(CH3)2C2B3H5]-5-CO[B9H12-1-O(CH2)4], and [1,2-(C2H5)2C2B7H7]-6-Co[B9H12-2-O(CH2)4] Inorganic Chemistry. 21: 1928-1936. DOI: 10.1021/Ic00135A044  0.799
1982 Borodinsky L, Grimes RN. Boranometallacarboranes. 1. Synthesis and characterization of borane-cobalt-carborane sandwich complexes Inorganic Chemistry. 21: 1921-1927. DOI: 10.1021/Ic00135A043  0.789
1982 Borodinsky L, Sinn E, Grimes RN. Crystal and molecular structure of (C2H5)3NH+[Co(1,2-C 2B9H11)2]- Inorganic Chemistry. 21: 1686-1689. DOI: 10.1021/Ic00134A087  0.8
1982 Leon Venable T, Sinn E, Grimes RN. Crystal and molecular structure of [η5-C5(CH3)5]3Co 3B4H4, an electron-hyperdeficient cluster with severe intramolecular ligand-ligand crowding Inorganic Chemistry. 21: 904-908. DOI: 10.1021/Ic00133A011  0.405
1982 Venable TL, Sinn E, Grimes RN. Cobaltaborane analogs of decaborane (B10H14). Crystal and molecular structures of 6-[.eta.5-C5(CH3)5]CoB9H13, 6,9-[.eta.5-C5(CH3)5]2]2Co2B8H12, 5,7-[.eta.5-C5(CH3)5]5]2Co2B8H12, and 6-Cl-5,7-[.eta.5-C5(CH3)5]2Co2B8H11 Inorganic Chemistry. 21: 895-904. DOI: 10.1021/Ic00133A010  0.411
1982 Borodinsky L, Sinn E, Grimes RN. Crystal And Molecular Structure Of (C2H5)3Nh+(Co(1,2-C2B9H11)2) Cheminform. 13. DOI: 10.1002/Chin.198229065  0.796
1982 Venable TL, Sinn E, Grimes RN. COBALTABORANE ANALOGS OF DECABORANE (B10H14). CRYSTAL AND MOLECULAR STRUCTURES OF 6-(η5-C5(CH3)5)COB9H13, 6,9-(η5-C5(CH3)5)2)2CO2B8H12 5,7-(η5-C5(CH3)5)5)2CO2B8H12, AND 6-CL-5,7-(η5-C5(CH3)5)2CO2B8H11 Cheminform. 13. DOI: 10.1002/Chin.198224077  0.417
1982 Maynard RB, Sinn E, Grimes RN. Tetracarbon Metallacarboranes. Part 11. 11-Vertex Nido Cages: Structures of Two Isomers of (η5-C5H5)Co(CH3)4C4B6H6. Cheminform. 13. DOI: 10.1002/Chin.198206283  0.405
1981 Finster DC, Grimes RN. Electron-rich carboranes. Studies of a stereochemically novel system, (CH3)4C4B7H9, an 11-vertex arachno cluster Journal of the American Chemical Society. 103: 2675-2683. DOI: 10.1021/Ja00400A031  0.37
1981 Maynard RB, Sinn E, Grimes RN. Tetracarbon metallacarboranes. 11. 11-Vertex nido cages: structures of two isomers of (.eta.5-C5H5)Co(CH3)4C4B6H6 Inorganic Chemistry. 20: 3858-3863. DOI: 10.1021/Ic50225A051  0.401
1981 Finster DC, Grimes RN. Mercury-bridged cobaltacarborane complexes containing boron-mercury-boron three-center bonds. Synthesis and structure of .mu..mu.'-[(.eta.5-C5R5)Co(CH3)2C2B3H4]2Hg and .mu.-[(.eta.5-C5R5)Co(CH3)2C2B3H4]HgCl (R = hydrogen, methyl) and related compounds Inorganic Chemistry. 20: 863-871. DOI: 10.1021/Ic50217A045  0.412
1981 Borodinsky L, Grimes RN. Boranametallacarboranes. 1. Synthesis and Characterization of (Borane) Cobalt (Carborane) Sandwich Complexes Cheminform. 13. DOI: 10.1002/Chin.198234269  0.814
1981 Borodinsky L, Sinn E, Grimes RN. Boranametallacarboranes. 2. Crystal and Molecular Structures of (2, 3- (C2H5)2C2B4H4)-5-Co(B9H12-1-O(CH2)4), (2,3-(CH3)2C2B3H5)-5-Co(B9H12-1-O(CH2)4), and (1,2-(C2H5)2C2B7H7)-6-Co(B9H12-2-O(CH2)4) Cheminform. 13. DOI: 10.1002/Chin.198234058  0.799
1981 Maynard RB, Sinn E, Grimes RN. Tetracarbon metallacarboranes. 10. On the thermodynamically favored geometry of large nido cages. Structure of the thermal rearrangement product (isomer III) of (η5-C5H5)Co(CH3) 4C4B7H7 Inorganic Chemistry. 20: 1201-1206. DOI: 10.1002/Chin.198128090  0.408
1981 Finster DC, Sinn E, Grimes RN. Intramolecular B-B linkage between polyhedral cages in a commo-metallacarborane. Synthesis and structure of a fluxional metal-boron cluster, [η5-C5(CH3)5]2Co 3(CH3)4C4B8H7 Journal of the American Chemical Society. 103: 1399-1407.  0.363
1981 Finster DC, Grimes RN. Mercury-bridged cobaltacarborane complexes containing B-Hg-B three-center bonds. Synthesis and structure of μ,μ′-[(η5-C5R5)Co(CH 3)2C2B3H4]2Hg Inorganic Chemistry. 20: 863-871.  0.332
1980 Finster DC, Sinn E, Grimes RN. Intramolecular B-B Linkage Between Polyhedral Cages in a Commo-Metallacarborane. Synthesis and Structure of a Fluxional Metal-Boron Cluster, (n(5)-C5(CH3)5)2Co3(CH3)4C4B8H7. Cheminform. 12. DOI: 10.1021/Ja00396A019  0.462
1980 Hosmane NS, Grimes RN. Transition-metal-promoted oxidative fusion with carborane and borane anions. Synthesis of C4Bn (n = 8-11) carborane systems in the presence of B5H8 - and B3H8 - ions Inorganic Chemistry. 19: 3482-3487. DOI: 10.1021/Ic50213A054  0.504
1980 Grimes RN, Maxwell WM, Maynard RB, Sinn E. Structural investigation of a B-ferrocenyl-substituted tetracarbon carborane, 4[(.eta.5-C5H5)Fe(.eta.5-C5H4)]-2,3,7,8-(CH3)4C4B8H7 Inorganic Chemistry. 19: 2981-2985. DOI: 10.1021/Ic50212A027  0.415
1980 Grimes RN, Sinn E, Maynard RB. Small metallacarboranes with metal-metal bonds. Crystal and molecular structures of 2,3-(CH3)2-1,2,4,5-(.eta.5-C5H5)2Co2C2B3H3 and 2,3-(CH3)2-1,2,4,5-(.eta.5-C5H5)2CoFe(H)C2B3H3 Inorganic Chemistry. 19: 2384-2391. DOI: 10.1021/Ic50210A042  0.443
1980 Grimes RN, Sinn E, Pipal JR. Tetracarbon metallacarboranes. 9. New types of nido cage geometry. Crystal and molecular structures of [(C6H5)2PCH2]2Ni(CH3)4C4D8H8 (isomer 1) and (.eta.5-C5H5)Co(CH3)4C4B7H7 (isomer 2) Inorganic Chemistry. 19: 2087-2095. DOI: 10.1021/Ic50209A051  0.405
1980 Grimes RN, Maxwell WM, Maynard RB, Sinn E. STRUCTURAL INVESTIGATION OF A B-FERROCENYL-SUBSTITUTED TETRACARBON CARBORANE, 4((η5-C5H5)FE(η5-C5H4))-2,3,7,8-(CH3)4C4B8H7 Cheminform. 11. DOI: 10.1002/Chin.198052078  0.419
1980 Grimes RN, Sinn E, Maynard RB. Small metallacarboranes with metal-metal bonds. Crystal and molecular structures of 2,3-(CH3)2-1,2,4,5-(η5-C5H 5)2Co2C2B3H3 and 2,3-(CH3)2-1,2,4,5-(η5-C5H 5)2CoFe(H)C2B3H3 Inorganic Chemistry. 19: 2384-2391. DOI: 10.1002/Chin.198045071  0.446
1980 Grimes RN, Sinn E, Pipal JR. Tetracarbon metallacarboranes. 9. New types of nido cage geometry. Crystal and molecular structures of [(C6H5)2PCH2]2Ni(CH 3)4C4B8H8 (Isomer 1) and (η5-C5H5)Co(CH3) 4C4B7H7 (isomer 2) Inorganic Chemistry. 19: 2087-2095. DOI: 10.1002/Chin.198041070  0.407
1980 Grimes RN, Maxwell WM, Maynard RB, Sinn E. Structural investigation of a B-ferrocenyl-substituted tetracarbon carborane, 4-[(η5-C5H5)Fe(η5-C 5H4)]-2,3,7,8-(CH3)4C 4B8H7 Inorganic Chemistry. 19: 2981-2985.  0.329
1979 Bowser JR, Bonny A, Robert Pipal J, Grimes RN. Nickel-boron "hybrid" clusters. Synthesis of polyhedral nickelaboranes and nickelacarboranes from small borane and carborane anions. Crystal structure of (η5-C5H5)4Ni4B 4H4 Journal of the American Chemical Society. 101: 6229-6236. DOI: 10.1021/Ja00515A012  0.795
1979 Grimes RN, Pipal JR, Sinn E. Tetracarbon metallocarboranes. 8. Structure of a 12-vertex arachno carborane, .sigma.-(.eta.5-C5H5)Co(.eta.5-C5H4)+-Me4C4B8H8-, an analog of B12H126- and C2B10H124-. Mechanisms of carborane fluxional behavior and metallocarborane formation from the Me4C4B8H82- ion Journal of the American Chemical Society. 101: 4172-4180. DOI: 10.1021/Ja00509A025  0.387
1979 Hosmane NS, Grimes RN. Improved synthetic routes to small carboranes. Bench-scale preparation of nido-2,3-C2B4H8 derivatives from B5H9 and from B3H8 - salts Inorganic Chemistry. 18: 3294-3297. DOI: 10.1021/Ic50202A002  0.501
1979 Weiss R, Grimes RN. Polyhedral ferraboranes derived from the B5H8 - ion. Analogues of ferrocene, hexaborane(10), and nido-B11H15 Inorganic Chemistry. 18: 3291-3294. DOI: 10.1021/Ic50202A001  0.48
1979 Hosmane NS, Grimes RN. Linked and mercury-bridged nido-carboranes. High-yield synthesis of .mu.,.mu.'-[(CH3)2C2B4H5]2Hg, conversion to 5,5'-[(CH3)2C2B4H5]2, cleavage, and oxidative addition of benzene. Synthesis of .mu.,.mu.'-(B5H8)2Hg Inorganic Chemistry. 18: 2886-2891. DOI: 10.1021/Ic50200A052  0.576
1979 Maxwell WM, Grimes RN. Tetracarbon metallacarboranes. 7. Cobalt systems derived from (CH3)4C4B8H8. Synthesis and interconversion of 11-, 12-, and 13-vertex nido cages Inorganic Chemistry. 18: 2174-2178. DOI: 10.1021/Ic50198A025  0.394
1979 Pipal JR, Grimes RN. Tetracarbon metallacarboranes. 6. Stereochemical relationships between Co2C4B6 cage isomers formed by oxidative fusion. Crystal structure of (η5-C5H5)2Co2(CH 3)4C4B6H6, Isomer V Inorganic Chemistry. 18: 1936-1940. DOI: 10.1021/Ic50197A043  0.401
1979 Pipal JR, Grimes RN. Crystal and molecular structure of an iron dihydrogen metallocarborane, [2,3-(CH3)2C2B4H4] 2FeH2. Steric aspects of the oxidative fusion process Inorganic Chemistry. 18: 263-267. DOI: 10.1021/Ic50192A011  0.342
1979 Pipal JR, Grimes RN. Crystal structure of a tetracobalt tetraboron cluster, (.eta.5-C5H5)4Co4B4H4. Structural patterns in eight-vertex polyhedra Inorganic Chemistry. 18: 257-263. DOI: 10.1021/Ic50192A010  0.353
1979 Pipal JR, Grimes RN. Crystal structure of a closo six-vertex metalloboron cluster, 1,2-(.eta.5-C5H5)2Co2B4H6, with hydrogen atoms bridging Co2B triangular faces Inorganic Chemistry. 10: 252-257. DOI: 10.1021/Ic50192A009  0.351
1979 Grimes RN. Metal sandwich complexes of cyclic planar and pyramidal ligands contaning boron Coordination Chemistry Reviews. 28: 47-96. DOI: 10.1016/S0010-8545(00)80361-6  0.392
1979 Hosmane NS, Grimes RN. Linked and mercury-bridged nido-carboranes. High-yield synthesis of .mu.,.mu.'-[(CH3)2C2B4H5]2Hg, conversion to 5,5'-[(CH3)2C2B4H5]2, cleavage, and oxidative addition of benzene. Synthesis of .mu.,.mu.'-(B5H8)2Hg Cheminform. 11. DOI: 10.1002/Chin.198002285  0.625
1979 Hosmane NS, Grimes RN. Linked and mercury-bridged nido-carboranes. High-yield synthesis of μ,μ′-[(CH3)2C2B4H 5]2Hg, conversion to 5,5′-[(CH3)2C2B4H 5]2, cleavage, and oxidative addition of benzene. Synthesis of μ,μ′-(B5H8)2Hg Inorganic Chemistry. 18: 2886-2891.  0.306
1978 Wong K, Bowser JR, Pipal JR, Grimes RN. Tetracarbon metallocarboranes. 5. A new synthetic route: synthesis of Co2C4B6 and CoC4B7 nido cage systems by fusion of dicarbon cobaltacarboranes in ethanolic potassium hydroxide. Crystal structure of (.eta.5-C5H5)2Co2C4B6H10 Journal of the American Chemical Society. 100: 5045-5051. DOI: 10.1021/Ja00484A022  0.515
1978 Bowser JR, Grimes RN. Tetrametallic nickel-boron clusters, (.eta.5-C5H5)4Ni4B4H4 and (.eta.5-C5H5)4Ni4B5H5. Synthesis of metalloboron cluster systems by transition metal aggregation on a small borane framework Journal of the American Chemical Society. 100: 4623-4624. DOI: 10.1021/Ja00482A065  0.409
1978 Pipal JR, Grimes RN. Tetracarbon metallocarboranes. 4. Structure of the nido system (η5-C5H5)Co(CH3) 4C4B7H6OC2H5. The problem of the structural diversity of electronically analogous cage systems Journal of the American Chemical Society. 100: 3083-3088. DOI: 10.1021/Ja00478A021  0.39
1978 Weiss R, Grimes RN. Sources of line width in boron-11 nuclear magnetic resonance spectra. Scalar relaxation and boron-boron coupling in tetraborane(10) and pentaborane(9) Journal of the American Chemical Society. 100: 1401-1405. DOI: 10.1021/Ja00473A014  0.463
1978 Weiss R, Bowser JR, Grimes RN. Studies of 2-(.eta.5-C5H5)CoB4H8, a cobaltaborane analog of pentaborane(9) Inorganic Chemistry. 17: 1522-1527. DOI: 10.1021/Ic50184A027  0.394
1978 Pipal JR, Maxwell WM, Grimes RN. Synthesis and structure of a cobaltocenium cobaltacarborane zwitterion. Cobaltocenium and tetrahydrofuran derivatives of nido,closo-[2,3-(CH3)2C2B3H 5]CoH[2,3-(CH3)2C2B 4H4] Inorganic Chemistry. 17: 1447-1452. DOI: 10.1021/Ic50184A011  0.422
1978 Pipal JR, Grimes RN. Crystal structure of a novel triple-decked sandwich metallocarborane, μ(2,3)-1,3-C3H4-1,7,2,3-(η5-C 5H5)2Co2C2B 3H3, a complex containing a bicyclic planar carborane ligand related to pentalene. Partial incorporation of a cyclopentadienyl ring into a polyhedral borane cage Inorganic Chemistry. 17: 10-14. DOI: 10.1021/Ic50179A003  0.45
1978 Pipal JR, Grimes RN. Tetracarbon metallocarboranes. 3. Crystal structure of a closo 14-vertex cage, 1,14,2,5,9,12-(η5-C5H5)2Fe 2(CH3)4C4B8H8, a bicapped hexagonal antiprism Inorganic Chemistry. 17: 6-10. DOI: 10.1021/Ic50179A002  0.394
1978 Wong K, Bowser JR, Pipal JR, Grimes RN. Tetracarbon metallocarboranes. 5. A new synthetic route: synthesis of Co2C4B6 and CoC4B7 nido cage systems by fusion of dicarbon cobaltacarboranes in ethanolic potassium hydroxide. Crystal structure of (.eta.5-C5H5)2Co2C4B6H10 Cheminform. 9. DOI: 10.1002/Chin.197847276  0.515
1978 BOWSER JR, GRIMES RN. ChemInform Abstract: TETRAMETALLIC NICKEL-BORON CLUSTERS, (η5-C5H5)4NI4B4H4 AND (η5-C5H5)4NI4B5H5. SYNTHESIS OF METALLOBORON CLUSTER SYSTEMS BY TRANSITION METAL AGGREGATION ON A SMALL BORANE FRAMEWORK Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197842306  0.302
1978 PIPAL JR, GRIMES RN. ChemInform Abstract: Crystal Structure of a Novel Triple-Decked Sandwich Metallocarborane, μ(2,3)-l,3-C3H4-l,7,2,3-(η5-C5H5)2Co2C2B3H3, a Complex Containing a Bicyclic Planar Carborane Ligand Related to Pentalene. Partial Incorporation of a Cyclopentadien Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197815045  0.301
1978 Bowser JR, Grimes RN. Tetrametallic nickel-boron clusters, (η5-C5H5)4Ni4B 4H4 and (η5-C5H5)4Ni4B 5H5. Synthesis of metalloboron cluster systems by transition metal aggregation on a small borane framework [21] Journal of the American Chemical Society. 100: 4623-4624.  0.313
1977 Weiss R, Grimes RN. New ferraboranes. Structural analogs of hexaborane(10) and ferrocene. A complex of cyclic B5H10-, a counterpart of C5H5- Journal of the American Chemical Society. 99: 8087-8088. DOI: 10.1021/Ja00466A071  0.621
1977 Miller VR, Weiss R, Grimes RN. Polyhedral cobaltaboranes. Versatile replacement of borane(1) groups by (.eta.5-cyclopentadienyl)cobalt units in boron hydride frameworks. Borane-metal cluster hybrid molecules Journal of the American Chemical Society. 99: 5646-5651. DOI: 10.1021/Ja00459A020  0.323
1977 Maxwell WM, Bryan RF, Grimes RN. Tetracarbon metallocarboranes. 1. Iron, nickel, and molybdenum complexes derived from tetramethyltetracarbadodecaborane(12). Crystal structure of (.eta.5-C5H5)Fe(CH3)4C4B7H8 Journal of the American Chemical Society. 99: 4008-4015. DOI: 10.1021/Ja00454A020  0.409
1977 Pipal JR, Grimes RN. Structures of metalloboron clusters. X-ray studies of octahedral (.eta.5-C5H5)3Co3B3H5 and capped octahedral (.eta.5-C5H5)3Co3B4H4, a boron analog of tricobalt carbon clusters Inorganic Chemistry. 16: 3255-3262. DOI: 10.1021/Ic50178A054  0.382
1977 Maxwell WM, Wong K, Grimes RN. New chemistry of the iron dihydrogen metallocarborane [2,3-(CH3)2C2B4H4]2FeH2. Reaction with carbon monoxide and cage insertion of germanium, tin, and cobalt Inorganic Chemistry. 16: 3094-3099. DOI: 10.1021/Ic50178A021  0.526
1977 Wong KS, Grimes RN. Small metallocarboranes of tin and lead Inorganic Chemistry. 16: 2053-2057. DOI: 10.1021/Ic50174A047  0.416
1977 Freyberg DP, Weiss R, Sinn E, Grimes RN. Crystal and molecular structure of a tetracarbon carborane, (CH3)4C4B8H8, a new type of nido cage system Inorganic Chemistry. 16: 1847-1851. DOI: 10.1021/Ic50174A004  0.368
1977 Weiss R, Grimes RN. New ferraboranes. Structural analogs of hexaborane(10) and ferrocene. A complex of cyclic B5H10-, a counterpart of C5H5- Cheminform. 9. DOI: 10.1002/Chin.197810284  0.615
1977 Miller VR, Weiss R, Grimes RN. POLYHEDRAL COBALTABORANES. VERSATILE REPLACEMENT OF BORANE(1) GROUPS BY (η5-CYCLOPENTADIENYL)COBALT UNITS IN BORON HYDRIDE FRAMEWORKS. BORANE-METAL CLUSTER HYBRID MOLECULES Cheminform. 8. DOI: 10.1002/Chin.197748335  0.337
1977 Maxwell WM, Weiss R, Sinn E, Grimes RN. Tetracarbon metallocarboranes. 2. Thermal rearrangement of 14-vertex cage systems. Crystal structures of three tetracarbon diferracarborane isomers, (η5-C5H5)2Fe2(CH 3)4C4B8H8 Journal of the American Chemical Society. 99: 4016-4029. DOI: 10.1002/Chin.197737049  0.395
1977 Maxwell WM, Bryan RF, Grimes RN. TETRACARBON METALLOCARBORANES. 1. IRON, NICKEL, AND MOLYBDENUM COMPLEXES DERIVED FROM TETRAMETHYLTETRACARBADODECABORANE(12). CRYSTAL STRUCTURE OF (η5-C5H5)FE(CH3)4C4B7H8 Cheminform. 8. DOI: 10.1002/Chin.197737048  0.412
1977 Maxwell WM, Bryan RF, Grimes RN. Tetracarbon metallocarboranes. 1. Iron, nickel, and molybdenum complexes derived from (CH3)4C4B8H8. Crystal Structure of (η5-C5H5)Fe(CH3) 4C4B7H8 Journal of the American Chemical Society. 99: 4008-4015.  0.303
1977 Weiss R, Grimes RN. New ferraboranes. Structural analogues of hexaborane(10) and ferrocene. A complex of cyclic B5H10 -, a counterpart of C5H5 - [28] Journal of the American Chemical Society. 99: 8087-8088.  0.319
1976 Maxwell WM, Miller VR, Grimes RN. Cobalt-hydrogen metallocarboranes. Synthesis of closo-[(CH3)2C2B4H4] 2CoH and nido,closo-[(CH3)2C2B3H 5]CoH[(CH3)2C2B4H 4] and their conversion to new cobalt-cobalt bonded metallocarboranes Journal of the American Chemical Society. 98: 4818-4823. DOI: 10.1021/Ja00432A022  0.403
1976 Miller VR, Grimes RN. Cobalt-Boron Clusters J. Am. Chem. Soc. 98: 1600. DOI: 10.1021/Ja00422A064  0.428
1976 Grimes RN, Zalkin A, Robinson WT. Crystal and molecular structures of two thermally interconvertible metallocarborane isomers, 1,8,5,6- And 1,7,5,6-(η5-C5H5)2Co 2C2B5H7. Reversible metal-metal bond formation in a polyhedral surface Inorganic Chemistry. 15: 2274-2278. DOI: 10.1021/Ic50163A056  0.415
1976 Maxwell WM, Miller VR, Grimes RN. Iron-hydrogen and iron-cobalt metallocarboranes. Synthesis and chemistry of [(CH3)2C2B4H4] 2FIIH2 and a novel tetracarbon carborane system, (CH3)4C4B8H8 Inorganic Chemistry. 15: 1343-1348. DOI: 10.1021/Ic50160A020  0.37
1976 Weiss R, Grimes RN. Substituent NMR effects in triple-decked sandwich metallocarboranes Journal of Organometallic Chemistry. 113: 29-43. DOI: 10.1016/S0022-328X(00)91758-3  0.449
1975 Maxwell WM, Grimes RN. A mixed-metal trimetallic metallocarborane, [{(CO)3Fe} 25-C5H5) CoMe 2C2B4H4] Journal of the Chemical Society, Chemical Communications. 943-944. DOI: 10.1039/C39750000943  0.425
1975 Magee CP, Sneddon LG, Beer DC, Grimes RN. Bridge Insertion Reactions of the 2,3-C2B4H7(-) Ion with Aluminum, Gallium, and Transition Metal Reagents J. Organometal. Chem.. 86: 159. DOI: 10.1016/S0022-328X(00)89607-2  0.442
1974 Grimes RN. SMALL METALLOBORON CAGE COMPOUNDS AS ANALOGUES OF METAL CLUSTERS. UNIFYING CONCEPTS OF BONDING. Annals of the New York Academy of Sciences. 239: 180-192. PMID 28976579 DOI: 10.1111/J.1749-6632.1974.Tb25326.X  0.312
1974 Greenwood NN, Savory CG, Grimes RN, Sneddon LG, Davison A, Wreford SS. Preparation of a stable small ferraborane, B4H 8Fe(CO)3 Journal of the Chemical Society, Chemical Communications. 718. DOI: 10.1039/C39740000718  0.505
1974 Miller VR, Sneddon LG, Beer DC, Grimes RN. Direct insertion of transition metals into polyhedral carboranes. Structurally novel mono-, di-, and trimetallic small cage systems Journal of the American Chemical Society. 96: 3090-3098. DOI: 10.1021/Ja00817A013  0.537
1974 Grimes RN, Beer DC, Sneddon LG, Miller VR, Weiss R. Small cobalt and nickel metallocarboranes from 2,3-dicarbahexaborane(8) and 1,6-dicarbahexaborane(6). Sandwich complexes of the cyclic C2B3H72- and C2B3H54- ligands Inorganic Chemistry. 13: 1138-1146. DOI: 10.1021/Ic50135A025  0.558
1974 Grimes RN. Recent studies of metalloboron cage compounds derived from the small carboranes Pure and Applied Chemistry. 39: 455-474. DOI: 10.1002/Chin.197520395  0.34
1974 GREENWOOD NN, SAVORY CG, GRIMES RN, SNEDDON LG, DAVISON A, WREFORD SS. ChemInform Abstract: PREPARATION OF A STABLE SMALL FERRABORANE, B4H8FE(CO)3 Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197449420  0.489
1973 Sneddon LG, Beer DC, Grimes RN. Iron(II) and -(III) metallocarboranes derived from nido-dicarbahexaborane(8) and closo dicarbaheptaborane(7) Journal of the American Chemical Society. 95: 6623-6629. DOI: 10.1021/Ja00801A016  0.478
1973 Miller VR, Grimes RN. Preparation of stable closo- and nideo-cobaltaboranes from sodium(+) octahydropentaborate(-). Complexes of the formal octahydrotetraborate(2-) and hexahydrotetraborate(4-) ligands Journal of the American Chemical Society. 95: 5078-5080. DOI: 10.1021/Ja00796A066  0.344
1973 Beer DC, Miller VR, Sneddon LG, Grimes RN, Mathew M, Palenik GJ. Triple-decked sandwich compounds. Planar C2B3H54- cyclocarborane ligands analogous to C5H5- Journal of the American Chemical Society. 95: 3046-3048. DOI: 10.1021/Ja00790A070  0.6
1973 Brennan JP, Grimes RN, Schaeffer R, Sneddon LG. Crystal and molecular structure of dicarbacyclopentaboranyliron tricarbonyl Inorganic Chemistry. 12: 2266-2268. DOI: 10.1021/Ic50128A011  0.636
1973 Tabereaux A, Grimes RN. Tin- and lead-bridged carboranes. Further studies on silicon- and germanium-bridged C2B4H8 derivatives Inorganic Chemistry. 12: 792-798. DOI: 10.1021/Ic50122A018  0.767
1973 Miller VR, Grimes RN. Preparation of Stable Closo- and Nido-Cobaltaboranes from Na(+)B5H8(-). Complexes of the Formal B4H8(2-) and B4H8(2) and B4H6(4-) Ligands. Cheminform. 4. DOI: 10.1002/Chin.197340404  0.441
1973 BEER DC, MILLER VR, SNEDDON LG, GRIMES RN, MATHEW M, PALENIK GJ. ChemInform Abstract: TRIPELDECKERSANDWICH-VERBINDUNGEN ZU C5H5(-) ANALOGE PLANARE C2B3H5(4-)-CYCLOCARBORANLIGANDEN Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197328389  0.595
1973 Tabereaux A, Grimes RN. Zinn- Und Blei-Brueckencarborane, Weitere Untersuchungen An Silicium- Und Germanium-Bruecken-C2B4H8-Derivaten Cheminform. 4. DOI: 10.1002/Chin.197323316  0.755
1973 Brennan JP, Grimes RN, Schaeffer R, Sneddon LG. Crystal and molecular structure of dicarbacyclopentaboranyliron tricarbonyl Inorganic Chemistry. 12: 2266-2268.  0.48
1972 Sneddon LG, Grimes RN. Novel iron carborane .mu. and .pi. complexes derived from nido-C2B4H8. Paramagnetic small carborane sandwich compound Journal of the American Chemical Society. 94: 7161-7162. DOI: 10.1021/Ja00775A054  0.597
1972 Tabereaux A, Grimes RN. Synthesis and Rearrangement of mu, mu'-SiH2(C2B4H7)2, a Bis-Carboranyl Silane Linked by a Silicon Atom Common to Two Three-Center B-Si-B Bonds. Journal of the American Chemical Society. 94: 4768-4770. DOI: 10.1021/Ja00768A076  0.793
1972 Grimes RN, Rademaker WJ, Denniston ML, Bryan RF, Greene PT. Carboranes containing gallium and indium cage heteroatoms. Synthesis, molecular structure, and reactions Journal of the American Chemical Society. 94: 1865-1869. DOI: 10.1021/Ja00761A013  0.393
1972 SNEDDON LG, GRIMES RN. ChemInform Abstract: NEUE MY- UND PI-EISEN-CARBORAN-KOMPLEXE AUS NIDO-C2B4H8, EINE SANDWICH-VERBINDUNG MIT EINEM PARAMAGNETISCHEN NIEDRIGEN CARBORAN Chemischer Informationsdienst. 3: no-no. DOI: 10.1002/Chin.197251418  0.5
1972 Tabereaux A, Grimes RN. Darst. Und Umlagerung Von My,My′-Silylen-Bis-(2,3-Dicarba-Nido-Hexaboranyl) Mit Einem Gemeinsamen Si-Atom Fuer Zwei Bor-Silicium-Bor-Zentren Cheminform. 3. DOI: 10.1002/Chin.197238299  0.754
1971 Thompson ML, Grimes RN. Tricarba-'closo'-octaborane(7), a Polyhedral Carborane Containing a Bare Carbon Atom. Journal of the American Chemical Society. 93: 6677-6679. DOI: 10.1021/Ja00753A060  0.301
1971 Grimes RN. Small carborane metallocene analogs. Iron .pi.-complexes containing the formal nido-C2B4H62- and cyclo-C2B3H72- ligands Journal of the American Chemical Society. 93: 261-262. DOI: 10.1021/Ja00730A050  0.322
1971 Ledoux WA, Grimes RN. Reactions of Boranes and Carboranes with Silanes, Organosilanes, and Related Compounds Journal of Organometallic Chemistry. 93: 387. DOI: 10.1016/S0022-328X(00)81572-7  0.406
1970 Franz DA, Grimes RN. Neues Carborankaefigsyst., 1,2-C2B3H7 Cheminform. 1. DOI: 10.1002/Chin.197022306  0.374
1969 Howard JW, Grimes RN. Small carborane-transition metal complex, (.pi.-2-CH3C3B3H5)Mn(CO)3 Journal of the American Chemical Society. 91: 6499-6500. DOI: 10.1021/Ja01051A059  0.349
1969 Franz DA, Howard JW, Grimes RN. Deuterium Tracer Studies of Tricarbahexaborane(7) Formation. Synthesis of the 2,4-(CH3)2C3B3H4(-) Ion and 2,4-(CH3)2-mu-D-C3B3H4 Journal of the American Chemical Society. 91: 4010. DOI: 10.1021/Ja01042A088  0.353
1967 Hawthorne MF, Pilling RL, Grimes RN. The Mechanism of B10H10-2Formation from B10H12(ligand)2Species Journal of the American Chemical Society. 89: 1067-1074. DOI: 10.1021/Ja00981A005  0.446
1967 Grimes RN. Studies of Methyl Derivatives of 1,2-Dicarbaclovo-pentaborane(5) Journal of Organometallic Chemistry. 8: 45. DOI: 10.1016/S0022-328X(00)84702-6  0.408
1964 Hawthorne MF, Pilling RL, Grimes RN. A Mechanism Study of B10H10-2Formation Journal of the American Chemical Society. 86: 5338-5339. DOI: 10.1021/Ja01077A063  0.395
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