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Mark Crimmin - Publications

Affiliations: 
Chemistry Imperial College London, London, England, United Kingdom 
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54 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Farley SES, Mulryan D, Rekhroukh F, Phanopoulos A, Crimmin MR. Catalytic HF Shuttling between Fluoroalkanes and Alkynes. Angewandte Chemie (International Ed. in English). e202317550. PMID 38069591 DOI: 10.1002/anie.202317550  0.704
2023 Parr JM, White AJP, Crimmin MR. Calcium-stabilised transition metal bis(formyl) complexes: structure and bonding. Chemical Communications (Cambridge, England). PMID 37462072 DOI: 10.1039/d3cc03009a  0.354
2023 Baker GJ, White AJP, Casely IJ, Grainger D, Crimmin MR. Catalytic, -Selective, Semi-Hydrogenation of Alkynes with a Zinc-Anilide Complex. Journal of the American Chemical Society. PMID 36972405 DOI: 10.1021/jacs.3c02301  0.335
2023 Parr JM, Phanopoulos A, Vickneswaran A, Crimmin MR. Understanding the role of ring strain in β-alkyl migration at Mg and Zn centres. Chemical Science. 14: 1590-1597. PMID 36794202 DOI: 10.1039/d2sc06288g  0.707
2022 Garçon M, Phanopoulos A, White A, Crimmin MR. Reversible Dihydrogen Activation and Catalytic H/D Exchange with Group 10 Heterometallic Complexes. Angewandte Chemie (International Ed. in English). PMID 36350647 DOI: 10.1002/anie.202213001  0.737
2022 Garçon M, Phanopoulos A, Sackman G, Richardson C, White A, Cooper R, Edwards A, Crimmin MR. The Continuum Between Hexagonal Planar and Trigonal Planar Geometries. Angewandte Chemie (International Ed. in English). PMID 36094744 DOI: 10.1002/anie.202211948  0.711
2021 Phillips N, Kong R, White A, Crimmin MR. Slippage between η2 and η1 Coordination in Group 11 Borataalkene Complexes: Models for Alkene Activation. Angewandte Chemie (International Ed. in English). PMID 33605521 DOI: 10.1002/anie.202100919  0.32
2020 Batuecas M, Gorgas N, Crimmin MR. Catalytic C-H to C-M (M = Al, Mg) bond transformations with heterometallic complexes. Chemical Science. 12: 1993-2000. PMID 34163961 DOI: 10.1039/d0sc03695a  0.303
2019 Bakewell C, White AJP, Crimmin MR. Reversible alkene binding and allylic C-H activation with an aluminium(i) complex. Chemical Science. 10: 2452-2458. PMID 30881673 DOI: 10.1039/c8sc04865g  0.323
2017 Zhurakovskyi O, Türkmen YE, Löffler LE, Moorthie VA, Chen CC, Shaw MA, Crimmin MR, Ferrara M, Ahmad M, Ostovar M, Matlock JV, Aggarwal VK. Enantioselective Synthesis of the Cyclopiazonic Acid Family Using Sulfur Ylides. Angewandte Chemie (International Ed. in English). PMID 29265694 DOI: 10.1002/Anie.201712065  0.427
2017 Hicken A, White AJ, Crimmin MR. Reversible Coordination of Boron-, Aluminum-, Zinc-, Magnesium-, and Calcium-Hydrogen Bonds to Bent {CuL2} Fragments: Heavy σ Complexes of the Lightest Coinage Metal. Inorganic Chemistry. PMID 28328213 DOI: 10.1021/acs.inorgchem.7b00182  0.355
2017 Pike SD, Crimmin MR, Chaplin AB. Organometallic chemistry using partially fluorinated benzenes. Chemical Communications (Cambridge, England). 53: 3615-3633. PMID 28304406 DOI: 10.1039/c6cc09575e  0.313
2017 Phanopoulos A, Warren M, White AJ, Horton A, Crimmin MR. Isolation of an unusual [Cu6] nanocluster through sequential addition of copper(i) to a polynucleating ligand. Dalton Transactions (Cambridge, England : 2003). PMID 28133681 DOI: 10.1039/C6Dt04703C  0.687
2017 Phanopoulos A, Leung AH, Yow S, Palomas D, White AJ, Hellgardt K, Horton A, Crimmin MR. Binuclear β-diketiminate complexes of copper(i). Dalton Transactions (Cambridge, England : 2003). PMID 28133666 DOI: 10.1039/C6Dt04246E  0.73
2014 Arrowsmith M, Crimmin MR, Hill MS, Lomas SL, Heng MS, Hitchcock PB, Kociok-Köhn G. Catalytic hydroacetylenation of carbodiimides with homoleptic alkaline earth hexamethyldisilazides. Dalton Transactions (Cambridge, England : 2003). 43: 14249-56. PMID 24434957 DOI: 10.1039/C3Dt53542H  0.558
2014 Zhao C, Crimmin MR, Toste FD, Bergman RG. Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization. Accounts of Chemical Research. 47: 517-29. PMID 24359109 DOI: 10.1021/Ar400176X  0.582
2013 Nako AE, Gates SJ, White AJ, Crimmin MR. Preparation and properties of a series of structurally diverse aluminium hydrides supported by β-diketiminate and bis(amide) ligands. Dalton Transactions (Cambridge, England : 2003). 42: 15199-206. PMID 23999557 DOI: 10.1039/c3dt52148f  0.32
2013 Arrowsmith M, Crimmin MR, Hill MS, Kociok-Köhn G. Beryllium derivatives of a phenyl-substituted β-diketiminate: a well-defined ring opening reaction of tetrahydrofuran. Dalton Transactions (Cambridge, England : 2003). 42: 9720-6. PMID 23685744 DOI: 10.1039/C3Dt51021B  0.435
2013 Arrowsmith M, Crimmin MR, Hill MS, Lomas SL, MacDougall DJ, Mahon MF. Catalytic and stoichiometric cumulene formation within dimeric group 2 acetylides Organometallics. 32: 4961-4972. DOI: 10.1021/Om400678D  0.577
2013 Crimmin MR, Hill MS. Homogeneous catalysis with organometallic complexes of group 2 Topics in Organometallic Chemistry. 45: 191-242. DOI: 10.1007/978-3-642-36270-5-6  0.459
2012 Crimmin MR, White AJ. Wittig-olefination via an yttrium-coordinated betaine. Chemical Communications (Cambridge, England). 48: 1745-7. PMID 22215124 DOI: 10.1039/c2cc16431k  0.324
2011 Tomson NC, Crimmin MR, Petrenko T, Rosebrugh LE, Sproules S, Boyd WC, Bergman RG, DeBeer S, Toste FD, Wieghardt K. A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni). Journal of the American Chemical Society. 133: 18785-801. PMID 22047035 DOI: 10.1021/Ja206042K  0.728
2011 Crimmin MR, Bergman RG, Toste FD. Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes. Angewandte Chemie (International Ed. in English). 50: 4484-7. PMID 21480451 DOI: 10.1002/Anie.201100816  0.476
2011 Crimmin MR, Colby DA, Ellman JA, Bergman RG. Synthesis and coordination chemistry of tri-substituted benzamidrazones. Dalton Transactions (Cambridge, England : 2003). 40: 514-22. PMID 21109860 DOI: 10.1039/C0Dt01267J  0.489
2011 Bergman R, Toste F, Boyd W, Crimmin M, Rosebrugh L, Schomaker J. Enantioselective Synthesis ofC2andC1Dienes Synfacts. 2011: 0183-0183. DOI: 10.1055/S-0030-1259337  0.683
2011 Arrowsmith M, Crimmin MR, Barrett AGM, Hill MS, Kociok-Köhn G, Procopiou PA. Cation charge density and precatalyst selection in group 2-catalyzed aminoalkene hydroamination Organometallics. 30: 1493-1506. DOI: 10.1021/Om101063M  0.528
2011 Crimmin MR, Rosebrugh LE, Tomson NC, Weyhermüller T, Bergman RG, Toste FD, Wieghardt K. [(TMEDA)Co(NO) 2][BPh 4]: A versatile synthetic entry point to four and five coordinate {Co(NO) 2} 10 complexes Journal of Organometallic Chemistry. 696: 3974-3981. DOI: 10.1016/J.Jorganchem.2011.04.038  0.72
2010 Boyd WC, Crimmin MR, Rosebrugh LE, Schomaker JM, Bergman RG, Toste FD. Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes. Journal of the American Chemical Society. 132: 16365-7. PMID 21033667 DOI: 10.1021/Ja107968C  0.712
2010 Barrett AG, Crimmin MR, Hill MS, Hitchcock PB, Lomas SL, Mahon MF, Procopiou PA. Carbodiimide insertion reactions of homoleptic heavier alkaline earth amides and phosphides. Dalton Transactions (Cambridge, England : 2003). 39: 7393-400. PMID 20607197 DOI: 10.1039/C0Dt00089B  0.721
2010 Barrett AGM, Crimmin MR, Hill MS, Procopiou PA. Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium Proceedings of the Royal Society a: Mathematical, Physical and Engineering Sciences. 466: 927-963. DOI: 10.1098/Rspa.2009.0558  0.501
2010 Crimmin MR, Hill MS, Hitchcock PB, Mahon MF. Synthesis of β-diketiminato calcium silylamides and their reactions with triethylaluminium New Journal of Chemistry. 34: 1572-1578. DOI: 10.1039/C0Nj00042F  0.57
2009 Crimmin MR, Barrett AG, Hill MS, MacDougall DJ, Mahon MF, Procopiou PA. Beta-diketiminate C-H activation with heavier group 2 alkyls. Dalton Transactions (Cambridge, England : 2003). 9715-7. PMID 19885513 DOI: 10.1039/B917466B  0.681
2009 Barrett AG, Brinkmann C, Crimmin MR, Hill MS, Hunt P, Procopiou PA. Heavier group 2 metals and intermolecular hydroamination: a computational and synthetic assessment. Journal of the American Chemical Society. 131: 12906-7. PMID 19705841 DOI: 10.1021/Ja905615A  0.659
2009 Crimmin MR, Arrowsmith M, Barrett AG, Casely IJ, Hill MS, Procopiou PA. Intramolecular hydroamination of aminoalkenes by calcium and magnesium complexes: a synthetic and mechanistic study. Journal of the American Chemical Society. 131: 9670-85. PMID 19552442 DOI: 10.1021/Ja9003377  0.712
2009 Barrett AG, Crimmin MR, Hill MS, Hitchcock PB, Lomas SL, Procopiou PA, Suntharalingam K. Catalytic 2,3,4-hexatriene formation by terminal alkyne coupling at calcium. Chemical Communications (Cambridge, England). 2299-301. PMID 19377665 DOI: 10.1039/B818848C  0.664
2009 Barrett AG, Casely IJ, Crimmin MR, Hill MS, Lachs JR, Mahon MF, Procopiou PA. Beta-diketiminato calcium and magnesium amides; model complexes for hydroamination catalysis. Inorganic Chemistry. 48: 4445-53. PMID 19326917 DOI: 10.1021/Ic900091X  0.699
2008 Crimmin MR, Barrett AG, Hill MS, MacDougall DJ, Mahon MF, Procopiou PA. Bis(trimethylsilyl)methyl derivatives of calcium, strontium and barium: potentially useful dialkyls of the heavy alkaline earth elements. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 11292-5. PMID 18973163 DOI: 10.1002/Chem.200801957  0.632
2008 Barrett AG, Boorman TC, Crimmin MR, Hill MS, Kociok-Köhn G, Procopiou PA. Heavier group 2 element-catalysed hydroamination of isocyanates. Chemical Communications (Cambridge, England). 5206-8. PMID 18956070 DOI: 10.1039/B809649J  0.682
2008 Barrett AG, Crimmin MR, Hill MS, Hitchcock PB, Procopiou PA. Insertion reactions of beta-diketiminate-stabilised calcium amides with 1,3-dialkylcarbodiimides. Dalton Transactions (Cambridge, England : 2003). 4474-81. PMID 18698451 DOI: 10.1039/B717383K  0.663
2008 Barrett AG, Crimmin MR, Hill MS, Hitchcock PB, Kociok-Köhn G, Procopiou PA. Triazenide complexes of the heavier alkaline earths: synthesis, characterization, and suitability for hydroamination catalysis. Inorganic Chemistry. 47: 7366-76. PMID 18620384 DOI: 10.1021/Ic800789X  0.691
2008 Barrett AG, Crimmin MR, Hill MS, Kociok-Köhn G, Lachs JR, Procopiou PA. Reversibility in the protonolysis of a beta-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine. Dalton Transactions (Cambridge, England : 2003). 1292-4. PMID 18305840 DOI: 10.1039/B717402K  0.663
2008 Barrett AGM, Crimmin MR, Hill MS, Hitchcock PB, Lomas SL, Mahon MF, Procopiou PA, Suntharalingam K. β-diketiminato calcium acetylides: Synthesis, solution dimerization, and catalytic carbon-carbon bond formation Organometallics. 27: 6300-6306. DOI: 10.1021/Om800738R  0.559
2008 Barrett AGM, Crimmin MR, Hill MS, Kociok-Köhn G, MacDougall DJ, Mahon MF, Procopiou PA. Synthesis, characterization, and solution lability of N-heterocyclic carbene adducts of the heavier group 2 bis(trimethylsilyl)amides Organometallics. 27: 3939-3946. DOI: 10.1021/Om800299J  0.556
2008 Crimmin MR, Barrett AGM, Hill MS, Hitchcock PB, Procopiou PA. Heavier group 2 element catalyzed hydrophosphination of carbodiimides Organometallics. 27: 497-499. DOI: 10.1021/Om7011198  0.489
2008 Lachs JR, Barrett AGM, Crimmin MR, Kociok-Köhn G, Hill MS, Mahon MF, Procopiou PA. Heavier group-2-element catalyzed hydroamination of carbodiimides European Journal of Inorganic Chemistry. 4173-4179. DOI: 10.1002/Ejic.200800613  0.573
2007 Crimmin MR, Barrett AG, Hill MS, Hitchcock PB, Procopiou PA. Bis(diphenylphosphido) derivatives of the heavier group 2 elements. Inorganic Chemistry. 46: 10410-5. PMID 17979275 DOI: 10.1021/Ic701608X  0.686
2007 Barrett AG, Crimmin MR, Hill MS, Hitchcock PB, Procopiou PA. Trifluoromethyl coordination and C-F bond activation at calcium. Angewandte Chemie (International Ed. in English). 46: 6339-42. PMID 17640022 DOI: 10.1002/Anie.200701945  0.646
2007 Crimmin MR, Barrett AG, Hill MS, Procopiou PA. Heavier alkaline Earth amides as catalysts for the Tischenko reaction. Organic Letters. 9: 331-3. PMID 17217297 DOI: 10.1021/Ol0627247  0.689
2007 Crimmin MR, Barrett AGM, Hill MS, Hitchcock PB, Procopiou PA. Calcium-catalyzed intermolecular hydrophosphination Organometallics. 26: 2953-2956. DOI: 10.1021/Om070200K  0.548
2007 Barrett AGM, Crimmin MR, Hill MS, Hitchcock PB, Procopiou PA. Reactions of β-diketiminate-stabilized calcium amides with 9-borabicyclo[3.3.1]nonane (9-BBN) Organometallics. 26: 4076-4079. DOI: 10.1021/Om070083T  0.483
2006 Avent AG, Crimmin MR, Hill MS, Hitchcock PB. Reactivity of [HC{(C(Me)N(Dipp))}2Ca{N(SiMe3) 2}(THF)] (Dipp = C6H3iPr 2-2,6) with C-H acids: Synthesis of heteroleptic calcium η5-organometallics Journal of Organometallic Chemistry. 691: 1242-1250. DOI: 10.1016/J.Jorganchem.2005.11.065  0.571
2005 Crimmin MR, Casely IJ, Hill MS. Calcium-mediated intramolecular hydroamination catalysis. Journal of the American Chemical Society. 127: 2042-3. PMID 15713071 DOI: 10.1021/Ja043576N  0.558
2005 Avent AG, Crimmin MR, Hill MS, Hitchcock PB. Kinetic stability of heteroleptic (beta-diketiminato) heavier alkaline-earth (Ca, Sr, Ba) amides. Dalton Transactions (Cambridge, England : 2003). 278-84. PMID 15616716 DOI: 10.1039/B415468A  0.595
2004 Avent AG, Crimmin MR, Hill MS, Hitchcock PB. Solution- and solid-state characterisation of a configurationally-stable beta-diketiminato-supported calcium primary amide. Dalton Transactions (Cambridge, England : 2003). 3166-8. PMID 15483692 DOI: 10.1039/B412060D  0.494
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