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Charles W. Machan, Ph.D. - Publications

Affiliations: 
2016 Chemistry University of Virginia, Charlottesville, VA 
Area:
Inorganic Chemistry
Website:
http://machangroup.virginia.edu
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48 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Reid AG, Moberg ME, Koellner CA, Machan CW, Thornton DA, Dickenson JC, Stober JJ, Turner DA, Tarring TJ, Brown CA, Harrison DP. Sterically attenuated electronic communication in cobalt complexes of meridional isoquinoline-derived ligands for applications in electrocatalysis. The Journal of Chemical Physics. 159. PMID 37982482 DOI: 10.1063/5.0174177  0.494
2022 Reid AG, Hooe SL, Moreno JJ, Dickie DA, Machan CW. Homogeneous Electrocatalytic Reduction of CO by a CrNO Complex: Electronic Coupling with a Redox-Active Terpyridine Fragment Favors Selectivity for CO. Inorganic Chemistry. PMID 36260749 DOI: 10.1021/acs.inorgchem.2c02013  0.418
2022 Moreno JJ, Hooe SL, Machan CW. Correction to DFT Study on the Electrocatalytic Reduction of CO to CO by a Molecular Chromium Complex. Inorganic Chemistry. 61: 7671. PMID 35486822 DOI: 10.1021/acs.inorgchem.2c01180  0.306
2022 Hooe SL, Moreno JJ, Reid AG, Cook EN, Machan CW. Mediated Inner-Sphere Electron Transfer Induces Homogeneous Reduction of CO via Through-Space Electronic Conjugation. Angewandte Chemie (International Ed. in English). 61: e202109645. PMID 34695281 DOI: 10.1002/anie.202109645  0.344
2021 Cook EN, Dickie DA, Machan CW. Catalytic Reduction of Dioxygen to Water by a Bioinspired Non-Heme Iron Complex via a 2+2 Mechanism. Journal of the American Chemical Society. 143: 16411-16418. PMID 34606274 DOI: 10.1021/jacs.1c04572  0.353
2021 Nichols AW, Cook EN, Gan YJ, Miedaner PR, Dressel JM, Dickie DA, Shafaat HS, Machan CW. Pendent Relay Enhances HO Selectivity during Dioxygen Reduction Mediated by Bipyridine-Based Co-NO Complexes. Journal of the American Chemical Society. PMID 34380313 DOI: 10.1021/jacs.1c03381  0.314
2021 Moreno JJ, Hooe SL, Machan CW. DFT Study on the Electrocatalytic Reduction of CO to CO by a Molecular Chromium Complex. Inorganic Chemistry. 60: 3635-3650. PMID 33657314 DOI: 10.1021/acs.inorgchem.0c03136  0.333
2020 Nichols AW, Hooe SL, Kuehner JS, Dickie DA, Machan CW. Electrocatalytic CO Reduction to Formate with Molecular Fe(III) Complexes Containing Pendent Proton Relays. Inorganic Chemistry. 59: 5854-5864. PMID 32324404 DOI: 10.1021/Acs.Inorgchem.9B03341  0.432
2020 Jiang C, Nichols AW, Walzer JF, Machan CW. Electrochemical CO Reduction in a Continuous Non-Aqueous Flow Cell with [Ni(cyclam)]. Inorganic Chemistry. PMID 31935070 DOI: 10.1021/Acs.Inorgchem.9B03171  0.347
2019 Lieske LE, Freeman LA, Wang G, Dickie DA, Gilliard RJ, Machan CW. Corrigendum: Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 9117. PMID 31355518 DOI: 10.1002/Chem.201902410  0.361
2019 Nichols AW, Machan CW. Secondary-Sphere Effects in Molecular Electrocatalytic CO Reduction. Frontiers in Chemistry. 7: 397. PMID 31263689 DOI: 10.3389/Fchem.2019.00397  0.435
2019 Lieske LE, Hooe SL, Nichols AW, Machan CW. Electrocatalytic reduction of dioxygen by Mn(iii) meso-tetra(N-methylpyridinium-4-yl)porphyrin in universal buffer. Dalton Transactions (Cambridge, England : 2003). PMID 31116202 DOI: 10.1039/C9Dt01436E  0.373
2019 Jiang C, Nichols AW, Machan CW. A look at periodic trends in d-block molecular electrocatalysts for CO reduction. Dalton Transactions (Cambridge, England : 2003). PMID 31020284 DOI: 10.1039/C9Dt00491B  0.468
2019 Lieske LE, Freeman LA, Wang G, Dickie DA, Gilliard RJ, Machan C. Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30791170 DOI: 10.1002/Chem.201900316  0.37
2019 Hooe SL, Machan CW. Dioxygen Reduction to Hydrogen Peroxide by a Molecular Mn Complex: Mechanistic Divergence Between Homogeneous and Heterogeneous Reductants. Journal of the American Chemical Society. PMID 30712355 DOI: 10.1021/Jacs.8B13373  0.412
2019 Hooe SL, Dressel JM, Dickie DA, Machan CW. Highly Efficient Electrocatalytic Reduction of CO2 to CO by a Molecular Chromium Complex Acs Catalysis. 10: 1146-1151. DOI: 10.1021/Acscatal.9B04687  0.444
2019 Machan CW. Recent advances in spectroelectrochemistry related to molecular catalytic processes Current Opinion in Electrochemistry. 15: 42-49. DOI: 10.1016/J.Coelec.2019.03.010  0.375
2018 Li F, Meyer RL, Carpenter SH, VanGelder LE, Nichols AW, Machan CW, Neidig ML, Matson EM. Nitric oxide activation facilitated by cooperative multimetallic electron transfer within an iron-functionalized polyoxovanadate-alkoxide cluster. Chemical Science. 9: 6379-6389. PMID 30310566 DOI: 10.1039/C8Sc00987B  0.339
2018 Heyer AJ, Shivokevich PJ, Hooe SL, Welch KD, Harman WD, Machan CW. Reversible modulation of the redox characteristics of acid-sensitive molybdenum and tungsten scorpionate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 29623324 DOI: 10.1039/C8Dt00598B  0.417
2018 Nichols AW, Chatterjee S, Sabat M, Machan CW. Electrocatalytic Reduction of CO2 to Formate by an Iron Schiff Base Complex. Inorganic Chemistry. PMID 29384368 DOI: 10.1021/Acs.Inorgchem.7B02955  0.425
2018 Lieske LE, Rheingold A, Machan CW. Electrochemical reduction of carbon dioxide with a molecular polypyridyl nickel complex Sustainable Energy & Fuels. 2: 1269-1277. DOI: 10.1039/C8Se00027A  0.52
2017 Hooe S, Rheingold AL, Machan CW. Electrocatalytic Reduction of Dioxygen to Hydrogen Peroxide by a Molecular Manganese Complex with a Bipyridine-Containing Schiff Base Ligand. Journal of the American Chemical Society. PMID 29216711 DOI: 10.1021/Jacs.7B09027  0.54
2017 Huynh MT, Mora SJ, Villalba M, Tejeda-Ferrari ME, Liddell PA, Cherry BR, Teillout AL, Machan CW, Kubiak CP, Gust D, Moore TA, Hammes-Schiffer S, Moore AL. Concerted One-Electron Two-Proton Transfer Processes in Models Inspired by the Tyr-His Couple of Photosystem II. Acs Central Science. 3: 372-380. PMID 28573198 DOI: 10.1021/Acscentsci.7B00125  0.536
2017 Gianneschi NC, Sahu S, Cheung PL, Machan C, Chabolla S, Kubiak C. Charged Macromolecular Rhenium Bipyridine Catalysts with Tunable CO2 Reduction Potentials. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28467613 DOI: 10.1002/Chem.201701901  0.66
2017 Chabolla SA, Machan CW, Yin J, Dellamary EA, Sahu S, Gianneschi NC, Gilson MK, Tezcan FA, Kubiak CP. Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups. Faraday Discussions. PMID 28374024 DOI: 10.1039/C7Fd00003K  0.678
2016 Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM. Rapid Synthesis of Redox-Active Dodecaborane B12(OR)12 Clusters Under Ambient Conditions. Inorganic Chemistry Frontiers. 3: 711-717. PMID 27885335 DOI: 10.1039/C5Qi00263J  0.681
2016 Machan CW, Kubiak CP. Electrocatalytic reduction of carbon dioxide with Mn(terpyridine) carbonyl complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27711804 DOI: 10.1039/C6Dt03243E  0.597
2016 Machan CW, Kubiak CP. Interrogating heterobimetallic co-catalytic responses for the electrocatalytic reduction of CO2 using supramolecular assembly. Dalton Transactions (Cambridge, England : 2003). PMID 27389806 DOI: 10.1039/C6Dt01956K  0.587
2016 Machan CW, Yin J, Chabolla SA, Gilson MK, Kubiak CP. Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 through Supramolecular Assembly with Amino Acid-Modified Ligands. Journal of the American Chemical Society. 138: 8184-93. PMID 27258781 DOI: 10.1021/Jacs.6B03774  0.609
2016 Cheung PL, Machan CW, Malkhasian AY, Agarwal J, Kubiak CP. Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3. Inorganic Chemistry. 55: 3192-8. PMID 26996527 DOI: 10.1021/Acs.Inorgchem.6B00379  0.588
2016 Stanton CJ, Machan CW, Vandezande JE, Jin T, Majetich GF, Schaefer HF, Kubiak CP, Li G, Agarwal J. Re(I) NHC Complexes for Electrocatalytic Conversion of CO2. Inorganic Chemistry. PMID 26950549 DOI: 10.1021/Acs.Inorgchem.6B00079  0.618
2016 Wixtrom AI, Shao Y, Jung D, Machan CW, Kevork SN, Qian EA, Axtell JC, Khan SI, Kubiak CP, Spokoyny AM. Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions Inorganic Chemistry Frontiers. 3: 711-717. DOI: 10.1039/c5qi00263j  0.663
2016 Clark ML, Rudshteyn B, Ge A, Chabolla SA, MacHan CW, Psciuk BT, Song J, Canzi G, Lian T, Batista VS, Kubiak CP. Orientation of cyano-substituted bipyridine Re(I) fac-tricarbonyl electrocatalysts bound to conducting au surfaces Journal of Physical Chemistry C. 120: 1657-1665. DOI: 10.1021/Acs.Jpcc.5B10912  0.745
2015 Machan CW, Sampson MD, Kubiak CP. Correction to "A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate". Journal of the American Chemical Society. 137: 11540. PMID 26312499 DOI: 10.1021/Jacs.5B07872  0.536
2015 Machan CW, Stanton CJ, Vandezande JE, Majetich GF, Schaefer HF, Kubiak CP, Agarwal J. Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2'-bipyridine)(CO)3: CN Coordination Alters Mechanism. Inorganic Chemistry. 54: 8849-56. PMID 26288172 DOI: 10.1021/Acs.Inorgchem.5B01715  0.608
2015 Machan CW, Sampson MD, Kubiak CP. A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate. Journal of the American Chemical Society. PMID 26087401 DOI: 10.1021/Jacs.5B03913  0.67
2015 Machan CW, Chabolla SA, Kubiak CP. Reductive Disproportionation of Carbon Dioxide by an Alkyl-Functionalized Pyridine Monoimine Re(I) fac-Tricarbonyl Electrocatalyst Organometallics. 34: 4678-4683. DOI: 10.1021/Acs.Organomet.5B00406  0.665
2014 Vollmer MV, Machan CW, Clark ML, Antholine WE, Agarwal J, Schaefer HF, Kubiak CP, Walensky JR. Synthesis, Spectroscopy, and Electrochemistry of (α-Diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction. Organometallics. 34: 3-12. PMID 25892841 DOI: 10.1021/Om500838Z  0.644
2014 Machan CW, Chabolla SA, Yin J, Gilson MK, Tezcan FA, Kubiak CP. Supramolecular assembly promotes the electrocatalytic reduction of carbon dioxide by Re(I) bipyridine catalysts at a lower overpotential. Journal of the American Chemical Society. 136: 14598-607. PMID 25226161 DOI: 10.1021/Ja5085282  0.655
2014 Machan CW, Sampson MD, Chabolla SA, Dang T, Kubiak CP. Developing a mechanistic understanding of molecular electrocatalysts for CO2 reduction using infrared spectroelectrochemistry Organometallics. 33: 4550-4559. DOI: 10.1021/Om500044A  0.564
2014 Chabolla SA, Dellamary EA, Machan CW, Tezcan FA, Kubiak CP. Combined steric and electronic effects of positional substitution on dimethyl-bipyridine rhenium(I)tricarbonyl electrocatalysts for the reduction of CO2 Inorganica Chimica Acta. 422: 109-113. DOI: 10.1016/J.Ica.2014.07.007  0.597
2013 Kennedy RD, Machan CW, McGuirk CM, Rosen MS, Stern CL, Sarjeant AA, Mirkin CA. General strategy for the synthesis of rigid weak-link approach platinum(II) complexes: tweezers, triple-layer complexes, and macrocycles. Inorganic Chemistry. 52: 5876-88. PMID 23639203 DOI: 10.1021/Ic302855F  0.778
2012 Machan CW, Adelhardt M, Sarjeant AA, Stern CL, Sutter J, Meyer K, Mirkin CA. One-pot synthesis of an Fe(II) bis-terpyridine complex with allosterically regulated electronic properties. Journal of the American Chemical Society. 134: 16921-4. PMID 23016834 DOI: 10.1021/Ja3045019  0.562
2012 Machan CW, Lifschitz AM, Stern CL, Sarjeant AA, Mirkin CA. Crystallographic snapshots of the bond-breaking isomerization reactions involving nickel(II) complexes with hemilabile ligands. Angewandte Chemie (International Ed. in English). 51: 1469-72. PMID 22213388 DOI: 10.1002/Anie.201107620  0.783
2011 Spokoyny AM, Machan CW, Clingerman DJ, Rosen MS, Wiester MJ, Kennedy RD, Stern CL, Sarjeant AA, Mirkin CA. A coordination chemistry dichotomy for icosahedral carborane-based ligands. Nature Chemistry. 3: 590-6. PMID 21778977 DOI: 10.1038/Nchem.1088  0.688
2011 Machan CW, Spokoyny AM, Jones MR, Sarjeant AA, Stern CL, Mirkin CA. Plasticity of the nickel(II) coordination environment in complexes with hemilabile phosphino thioether ligands. Journal of the American Chemical Society. 133: 3023-33. PMID 21319748 DOI: 10.1021/Ja109624M  0.774
2011 Rosen MS, Spokoyny AM, Machan CW, Stern C, Sarjeant A, Mirkin CA. Chelating effect as a driving force for the selective formation of heteroligated Pt(II) complexes with bidentate phosphino-chalcoether ligands. Inorganic Chemistry. 50: 1411-9. PMID 21189032 DOI: 10.1021/Ic101973S  0.805
2010 Spokoyny AM, Li TC, Farha OK, Machan CW, She C, Stern CL, Marks TJ, Hupp JT, Mirkin CA. Electronic tuning of nickel-based bis(dicarbollide) redox shuttles in dye-sensitized solar cells. Angewandte Chemie (International Ed. in English). 49: 5339-43. PMID 20586090 DOI: 10.1002/Anie.201002181  0.656
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