| Year |
Citation |
Score |
| 2023 |
Block E, Bechand B, Gundala S, Vattekkatte A, Wang K, Mousa SS, Godugu K, Yalcin M, Mousa SA. Correction: Block et al. Fluorinated Analogs of Organosulfur Compounds from Garlic (): Synthesis, Chemistry and Anti-Angiogenesis and Antithrombotic Studies. 2017, , 2081. Molecules (Basel, Switzerland). 28. PMID 36771183 DOI: 10.3390/molecules28031025 |
0.761 |
|
| 2018 |
Block E, Dethier B, Bechand B, Cotelesage JJH, George GN, Goto K, Mendoza Rengifo E, Pickering IJ, Sheridan R, Sneeden EY, Vogt L. Ajothiolanes: 3,4-Dimethylthiolane Natural Products from Garlic ( Allium sativum). Journal of Agricultural and Food Chemistry. PMID 30196701 DOI: 10.1021/Acs.Jafc.8B03638 |
0.751 |
|
| 2017 |
Block E, Bechand B, Gundala S, Vattekkatte A, Wang K, Mousa SS, Godugu K, Yalcin M, Mousa SA. Fluorinated Analog NMR s of Organosulfur Compounds from Garlic (Allium sativum): Synthesis, Chemistry and Anti-Angiogenesis and Antithrombotic Studies. Molecules (Basel, Switzerland). 22. PMID 29182588 DOI: 10.3390/Molecules22122081 |
0.768 |
|
| 2017 |
Block E, Batista VS, Matsunami H, Zhuang H, Ahmed L. The role of metals in mammalian olfaction of low molecular weight organosulfur compounds. Natural Product Reports. PMID 28471462 DOI: 10.1039/C7Np00016B |
0.377 |
|
| 2017 |
Block E. Fifty Years of Smelling Sulfur: From the Chemistry of Garlic to the Molecular Basis for Olfaction Phosphorus, Sulfur, Silicon, and Related Elements. 192: 141-144. DOI: 10.1080/10426507.2016.1247091 |
0.345 |
|
| 2016 |
Li S, Ahmed L, Zhang R, Pan Y, Matsunami H, Burger JL, Block E, Batista VS, Zhuang H. Smelling Sulfur: Copper and Silver Regulate the Response of Human Odorant Receptor OR2T11 to Low Molecular Weight Thiols. Journal of the American Chemical Society. PMID 27659093 DOI: 10.1021/Jacs.6B06983 |
0.396 |
|
| 2016 |
Block E, Booker S, Flores-Penalba S, George G, Gundala S, Landgraf B, Liu J, Lodge S, Pushie J, Rozovsky S, Vattekkatte A, Yaghi R, Zeng H. Trifluoroselenomethionine - a New Non-Natural Amino Acid. Chembiochem : a European Journal of Chemical Biology. PMID 27383291 DOI: 10.1002/Cbic.201600266 |
0.753 |
|
| 2016 |
Block E, Booker SJ, Flores-Penalba S, George G, Gundala S, Landgraf BJ, Li F, Lodge SN, Pushie J, Rozovsky S, Vattekkatte A, Yaghi R, Zeng H. Trifluoroselenomethionine -- a New Non-Natural Amino Acid Chembiochem. 17: 1738–1751. PMID 27383291 DOI: 10.1002/cbic.201600266 |
0.311 |
|
| 2015 |
Block E, Jang S, Matsunami H, Batista VS, Zhuang H. Reply to Turin et al.: Vibrational theory of olfaction is implausible. Proceedings of the National Academy of Sciences of the United States of America. 112: E3155. PMID 26045493 DOI: 10.1073/Pnas.1508443112 |
0.34 |
|
| 2015 |
Block E, Jang S, Matsunami H, Sekharan S, Dethier B, Ertem MZ, Gundala S, Pan Y, Li S, Li Z, Lodge SN, Ozbil M, Jiang H, Penalba SF, Batista VS, et al. Implausibility of the vibrational theory of olfaction. Proceedings of the National Academy of Sciences of the United States of America. 112: E2766-74. PMID 25901328 DOI: 10.1073/pnas.1503054112 |
0.713 |
|
| 2014 |
Sekharan S, Ertem MZ, Zhuang H, Block E, Matsunami H, Zhang R, Wei JN, Pan Y, Batista VS. QM/MM model of the mouse olfactory receptor MOR244-3 validated by site-directed mutagenesis experiments. Biophysical Journal. 107: L5-8. PMID 25185561 DOI: 10.1016/J.Bpj.2014.07.031 |
0.358 |
|
| 2013 |
Wang K, Groom M, Sheridan R, Zhang S, Block E. Liquid sulfur as a reagent: Synthesis of polysulfanes with 20 or more sulfur atoms with characterization by UPLC-(Ag+)-coordination ion spray-MS Journal of Sulfur Chemistry. 34: 55-66. DOI: 10.1080/17415993.2012.721368 |
0.429 |
|
| 2013 |
Block E. Fifty years of smelling sulfur Journal of Sulfur Chemistry. 34: 158-207. DOI: 10.1080/17415993.2012.717294 |
0.303 |
|
| 2013 |
Block E, Zhuang H. Smelling sulfur: Discovery of a sulfur-sensing olfactory receptor that requires copper Acs Symposium Series. 1152: 1-14. DOI: 10.1021/bk-2013-1152.ch001 |
0.24 |
|
| 2013 |
Wann DA, Bil A, Lane PD, Robertson HE, Rankin DWH, Block E. Gas-phase structures of dithietane derivatives, including an electron diffraction study of 1,3-dithietane 1,1,3,3-tetraoxide Structural Chemistry. 24: 827-835. DOI: 10.1007/S11224-012-0179-8 |
0.374 |
|
| 2012 |
Duan X, Block E, Li Z, Connelly T, Zhang J, Huang Z, Su X, Pan Y, Wu L, Chi Q, Thomas S, Zhang S, Ma M, Matsunami H, Chen GQ, et al. Crucial role of copper in detection of metal-coordinating odorants. Proceedings of the National Academy of Sciences of the United States of America. 109: 3492-7. PMID 22328155 DOI: 10.1073/Pnas.1111297109 |
0.372 |
|
| 2010 |
Block E, Dane AJ, Thomas S, Cody RB. Applications of direct analysis in real time mass spectrometry (DART-MS) in Allium chemistry. 2-propenesulfenic and 2-propenesulfinic acids, diallyl trisulfane S-oxide, and other reactive sulfur compounds from crushed garlic and other Alliums. Journal of Agricultural and Food Chemistry. 58: 4617-25. PMID 20225897 DOI: 10.1021/Jf1000106 |
0.322 |
|
| 2010 |
Evans DH, Gruhn NE, Jin J, Li B, Lorance E, Okumura N, Macías-Ruvalcaba NA, Zakai UI, Zhang SZ, Block E, Glass RS. Electrochemical and chemical oxidation of dithia-, diselena-, ditellura-, selenathia-, and tellurathiamesocycles and stability of the oxidized species. The Journal of Organic Chemistry. 75: 1997-2009. PMID 20180528 DOI: 10.1021/Jo9026484 |
0.604 |
|
| 2010 |
Kubec R, Cody RB, Dane AJ, Musah RA, Schraml J, Vattekkatte A, Block E. Applications of direct analysis in real time-mass spectrometry (DART-MS) in Allium chemistry. (Z)-butanethial S-oxide and 1-butenyl thiosulfinates and their S-(E)-1-butenylcysteine S-oxide precursor from Allium siculum. Journal of Agricultural and Food Chemistry. 58: 1121-8. PMID 20047275 DOI: 10.1021/Jf903733E |
0.313 |
|
| 2010 |
Block E, Cody RB, Dane AJ, Sheridan R, Vattekkatte A, Wang K. Allium chemistry: Use of new instrumental techniques to "see" reactive organosulfur species formed upon crushing garlic and onion Pure and Applied Chemistry. 82: 535-539. DOI: 10.1351/Pac-Con-09-08-12 |
0.346 |
|
| 2008 |
Glass RS, Berry MJ, Block E, Boakye HT, Carlson BA, Gailer J, George GN, Gladyshev VN, Hatfield DL, Jacobsen NE, Johnson S, Kahakachchi C, Kaminski R, Manley SA, Mix H, et al. Insights into the chemical biology of selenium Phosphorus, Sulfur and Silicon and the Related Elements. 183: 924-930. DOI: 10.1080/10426500801898366 |
0.668 |
|
| 2008 |
Block E, Glass RS, Gruhn N, Jin J, Lorance E, Zakai UI, Zhang SZ. Chemistry of mixed sulfur-, selenium-, or tellurium- and silicon-, or tin-containing heterocycles Phosphorus, Sulfur and Silicon and the Related Elements. 183: 856-862. DOI: 10.1080/10426500801898168 |
0.567 |
|
| 2007 |
Glass RS, Block E, Gruhn NE, Jin J, Lorance E, Zakai UI, Zhang SZ. Interaction of C-Si, C-Sn, and Si-Si sigma-bonds with chalcogen lone pairs. The Journal of Organic Chemistry. 72: 8290-7. PMID 17915922 DOI: 10.1021/Jo071215V |
0.575 |
|
| 2007 |
Block E, Glass RS, Dikarev EV, Gruhn NE, Jin J, Li B, Lorance E, Zakai UI, Zhang SZ. Synthesis, structure, reactions, and photoelectron spectra of new mixed sulfur-, selenium- Or tellurium and silicon- Or tin-containing heterocycles Heteroatom Chemistry. 18: 509-515. DOI: 10.1002/Hc.20333 |
0.623 |
|
| 2006 |
Block E, Dikarev EV, Glass RS, Jin J, Li B, Li X, Zhang SZ. Synthesis, structure, and chemistry of new, mixed group 14 and 16 heterocycles: nucleophile-induced ring contraction of mesocyclic dications. Journal of the American Chemical Society. 128: 14949-61. PMID 17105306 DOI: 10.1021/Ja065037J |
0.611 |
|
| 2006 |
Glass RS, Block E, Lorance E, Zakai UI, Gruhn NE, Jin J, Zhang SZ. The Si-Si effect on ionization of beta-disilanyl sulfides and selenides. Journal of the American Chemical Society. 128: 12685-92. PMID 17002362 DOI: 10.1021/Ja0573514 |
0.571 |
|
| 2005 |
Petrukhina MA, Henck C, Li B, Block E, Jin J, Zhang SZ, Clerac R. Spirocyclic sulfur and selenium ligands as molecular rigid rods in coordination of transition metal centers. Inorganic Chemistry. 44: 77-84. PMID 15627363 DOI: 10.1021/Ic040102G |
0.517 |
|
| 2005 |
Block E, Dikarev EV, Jin J, Li B, Petrukhina MA, Zhang SZ. Synthesis, structure, and chemistry of selenium-containing four-membered rings Pure and Applied Chemistry. 77: 2029-2032. DOI: 10.1351/Pac200577122029 |
0.539 |
|
| 2005 |
Block E, Hak RJ, Putman D, Zhang SZ. α,β-unsaturated α′-halomethylsulfones: Prepackaged Ramberg-Bäcklund reagents for tandem synthetic processes Phosphorus, Sulfur and Silicon and the Related Elements. 180: 1197-1202. DOI: 10.1080/10426500590910783 |
0.4 |
|
| 2005 |
Block E. Olefin Synthesis by Deoxygenation of Vicinal Diols Organic Reactions. 15: 457-566. DOI: 10.1002/0471264180.Or030.02 |
0.347 |
|
| 2005 |
Block E. Biological activity of allium compounds: Recent results Acta Horticulturae. 688: 41-57. |
0.286 |
|
| 2004 |
Dikarev EV, Shpanchenko RV, Andreini KW, Block E, Jin J, Petrukhina MA. Powder diffraction study of a coordination polymer comprised of rigid building blocks: [Rh2(O2CCH3)4.mu2-Se2C5H8-Se,Se']infinity. Inorganic Chemistry. 43: 5558-63. PMID 15332807 DOI: 10.1021/Ic049497U |
0.504 |
|
| 2004 |
Block E, Glass RS, Jacobsen NE, Johnson S, Kahakachchi C, Kami?ski R, Skowro?ska A, Boakye HT, Tyson JF, Uden PC. Identification and synthesis of a novel selenium-sulfur amino acid found in selenized yeast: Rapid indirect detection NMR methods for characterizing low-level organoselenium compounds in complex matrices. Journal of Agricultural and Food Chemistry. 52: 3761-71. PMID 15186094 DOI: 10.1021/Jf049887Z |
0.705 |
|
| 2004 |
Hile AG, Shan Z, Zhang SZ, Block E. Aversion of European starlings (Sturnus vulgaris) to garlic oil treated granules: garlic oil as an avian repellent. Garlic oil analysis by nuclear magnetic resonance spectroscopy. Journal of Agricultural and Food Chemistry. 52: 2192-6. PMID 15080619 DOI: 10.1021/Jf035181D |
0.556 |
|
| 2004 |
Block E, Jeon HR, Zhang SZ, Dikarev EV. Chloromethanesulfonylethene and dichloromethanesulfonylethene: new reagents for tandem Diels-Alder/Ramberg-Bäcklund reactions. Organic Letters. 6: 437-40. PMID 14748612 DOI: 10.1021/Ol0363523 |
0.697 |
|
| 2004 |
Sneeden EY, Harris HH, Pickering IJ, Prince RC, Johnson S, Li X, Block E, George GN. The sulfur chemistry of shiitake mushroom. Journal of the American Chemical Society. 126: 458-9. PMID 14719930 DOI: 10.1021/Ja039239G |
0.585 |
|
| 2004 |
Mousa SA, Mohamed S, O’Connor L, Block E. Sulfur- and Selenium-Containing Compounds Derived from Natural and Synthetic Sources in Angiogenesis Modulation. Blood. 104: 3924-3924. DOI: 10.1182/Blood.V104.11.3924.3924 |
0.317 |
|
| 2004 |
Uden PC, Boakye HT, Kahakachchi C, Hafezi R, Nolibos P, Block E, Johnson S, Tyson JF. Element selective characterization of stability and reactivity of selenium species in selenized yeast Journal of Analytical Atomic Spectrometry. 19: 65-73. DOI: 10.1039/B307508G |
0.584 |
|
| 2004 |
Block E, Jeon HR, Putman D, Zhang SZ. Prepackaged Ramberg-Bäcklund reagents: Useful tools for organic synthesis Tetrahedron. 60: 7525-7541. DOI: 10.1016/J.Tet.2004.06.032 |
0.707 |
|
| 2004 |
Groner P, Gillies CW, Gillies JZ, Zhang Y, Block E. Microwave structural studies of organoselenium compounds 1. Microwave spectra, molecular structure, and methyl barrier to internal rotation of dimethyl diselenide Journal of Molecular Spectroscopy. 226: 169-181. DOI: 10.1016/J.Jms.2004.04.001 |
0.379 |
|
| 2003 |
Dikarev EV, Becker RY, Block E, Shan Z, Haltiwanger RC, Petrukhina MA. The first coordination complexes of selenones: a structural comparison with complexes of sulfones. Inorganic Chemistry. 42: 7098-105. PMID 14577777 DOI: 10.1021/Ic0302130 |
0.598 |
|
| 2003 |
Lorance ED, Glass RS, Block E, Li X. Synthesis, electrochemistry, and gas-phase photoelectron spectroscopic and theoretical studies of 3,6-bis(perfluoroalkyl)-1,2-dithiins. The Journal of Organic Chemistry. 68: 8110-4. PMID 14535791 DOI: 10.1021/Jo034683N |
0.598 |
|
| 2003 |
Block E, Shan Z, Glass RS, Fabian J. Revised structure of a purported 1,2-dioxin: a combined experimental and theoretical study. The Journal of Organic Chemistry. 68: 4108-11. PMID 12737603 DOI: 10.1021/Jo034305I |
0.677 |
|
| 2003 |
Block E, Tries F, He C, Guo C, Thiruvazhi M, Toscano PJ. Perthio- and perseleno-1,3-butadienes, -but-1-ene-3-ynes, and -[3]-cumulenes: one-step syntheses from 1,4-dilithio-1,3-butadiyne. Organic Letters. 5: 1325-7. PMID 12688750 DOI: 10.1021/Ol034258G |
0.728 |
|
| 2003 |
Dikarev EV, Petrukhina MA, Li X, Block E. Small organoselenium molecules. 1. Dimethyl selenoxide: structure, complexation, and gas-phase transformation. Inorganic Chemistry. 42: 1966-72. PMID 12639131 DOI: 10.1021/Ic020556I |
0.412 |
|
| 2001 |
Dong Y, Lisk D, Block E, Ip C. Characterization of the biological activity of γ-Glutamyl-Se-methylselenocysteine: A novel, naturally occurring anticancer agent from garlic Cancer Research. 61: 2923-2928. PMID 11306469 |
0.247 |
|
| 2001 |
Block E, Birringer M, Jiang W, Nakahodo T, Thompson HJ, Toscano PJ, Uzar H, Zhang X, Zhu Z. Allium chemistry: synthesis, natural occurrence, biological activity, and chemistry of Se-alk(en)ylselenocysteines and their gamma-glutamyl derivatives and oxidation products. Journal of Agricultural and Food Chemistry. 49: 458-70. PMID 11305255 DOI: 10.1021/Jf001097B |
0.436 |
|
| 2001 |
Block E. Chemistry of analogous organoselenium and organosulfur compounds Phosphorus, Sulfur and Silicon and Related Elements. 171: 1-23. DOI: 10.1080/10426500108046637 |
0.446 |
|
| 2001 |
Uden PC, Hafezi R, Kotrebai M, Nolibos P, Tyson J, Block E. Anticarcinogenic organoselenium compounds - Chromatographic, atomic and molecular mass spectral speciation Phosphorus, Sulfur and Silicon and Related Elements. 171: 31-56. DOI: 10.1080/10426500108046627 |
0.37 |
|
| 2000 |
Ip C, Birringer M, Block E, Kotrebai M, Tyson JF, Uden PC, Lisk DJ. Chemical speciation influences comparative activity of selenium-enriched garlic and yeast in mammary cancer prevention Journal of Agricultural and Food Chemistry. 48: 2062-2070. PMID 10888499 DOI: 10.1021/Jf000051F |
0.378 |
|
| 2000 |
Kotrebai M, Birringer M, Tyson JF, Block E, Uden PC. Selenium speciation in enriched and natural samples by HPLC-ICP-MS and HPLC-ESI-MS with perfluorinated carboxylic acid ion-pairing agents Analyst. 125: 71-78. PMID 10885064 DOI: 10.1039/A906320J |
0.368 |
|
| 2000 |
Kotrebai M, Tyson JF, Block E, Uden PC. High-performance liquid chromatography of selenium compounds utilizing perfluorinated carboxylic acid ion-pairing agents and inductively coupled plasma and electrospray ionization mass spectrometric detection Journal of Chromatography A. 866: 51-63. PMID 10681009 DOI: 10.1016/S0021-9673(99)01060-2 |
0.406 |
|
| 2000 |
Xie N, Binstead RA, Block E, Chandler WD, Lee DG, Meyer TJ, Thiruvazhi M. Reduction of permanganate by thioanisole: Lewis acid catalysis Journal of Organic Chemistry. 65: 1008-1015. DOI: 10.1021/Jo9914162 |
0.743 |
|
| 2000 |
Block E, Birringer M, Deorazio R, Fabian J, Glass RS, Guo C, He C, Lorance E, Qian Q, Schroeder TB, Shan Z, Thiruvazhi M, Wilson GS, Zhang X. Synthesis, properties, oxidation, and electrochemistry of 1,2- dichalcogenins Journal of the American Chemical Society. 122: 5052-5064. DOI: 10.1021/Ja994134S |
0.775 |
|
| 2000 |
Glass RS, Gruhn NE, Lichtenberger DL, Lorance E, Pollard JR, Birringer M, Block E, Deorazio R, He C, Shan Z, Zhang X. Gas-phase photoelectron spectroscopic and theoretical studies of 1,2- dichalcogenins: Ionization energies, orbital assignments, and an explanation of their color Journal of the American Chemical Society. 122: 5065-5074. DOI: 10.1021/Ja9941330 |
0.66 |
|
| 1999 |
Block E, Birringer M, He C. 1,2-Dichalcogenins: Simple Syntheses of 1,2-Diselenins, 1,2-Dithiins, and 2-Selenathiin. Angewandte Chemie (International Ed. in English). 38: 1604-1607. PMID 29710998 DOI: 10.1002/(Sici)1521-3773(19990601)38:11<1604::Aid-Anie1604>3.0.Co;2-I |
0.363 |
|
| 1999 |
Page JE, Block E, Towers GHN. Visible-light photochemistry and phototoxicity of thiarubrines Photochemistry and Photobiology. 70: 159-165. DOI: 10.1111/J.1751-1097.1999.Tb07984.X |
0.356 |
|
| 1999 |
Block E. Recent advances in the chemistry of 1,2-dithiins Phosphorus, Sulfur and Silicon and Related Elements. 153: 173-192. DOI: 10.1080/10426509908546433 |
0.373 |
|
| 1999 |
Kotrebai M, Birringer M, Tyson JF, Block E, Uden PC. Identification of the principal selenium compounds in selenium-enriched natural sample extracts by ion-pair liquid chromatography with inductively coupled plasma- and electrospray ionization-mass spectrometric detection Analytical Communications. 36: 249-252. DOI: 10.1039/A902770J |
0.383 |
|
| 1999 |
Gillies JZ, Cotter E, Gillies CW, Warner HE, Block E. Rotational Spectra, Molecular Structure, and Electric Dipole Moment of Propanethial S-Oxide Journal of Physical Chemistry A. 103: 4948-4954. DOI: 10.1021/Jp9902506 |
0.388 |
|
| 1999 |
Kotrebai M, Bird SM, Tyson JF, Block E, Uden PC. Characterization of selenium species in biological extracts by enhanced ion-pair liquid chromatography with inductively coupled plasma-mass spectrometry and by referenced electrospray ionization-mass spectrometry Spectrochimica Acta, Part B: Atomic Spectroscopy. 54: 1573-1591. DOI: 10.1016/S0584-8547(99)00086-5 |
0.397 |
|
| 1999 |
Block E, Birringer M, He C. 1,2-Dichalcogenins: Simple syntheses of 1,2-diselenins, 1,2-dithiins, and 2-selenathiin Angewandte Chemie - International Edition. 38: 1604-1607. DOI: 10.1002/(SICI)1521-3773(19990601)38:11<1604::AID-ANIE1604>3.0.CO;2-I |
0.298 |
|
| 1999 |
Perez-Lourido P, Garcia-Vazquez JA, Romero J, Sousa A, Block E, Maresca KP, Zubieta J. Synthesis and structural characterization of neutral silver(I) complexes with arenephosphinothiols. Crystal structures of [Ag4{2-(Ph2P)-6-(Me3Si)C6H 6S}4] and [Ag4{2-(Ph2PO)-6-(Me3Si)C6H 3S}4] Inorganic Chemistry. 38: 538-544. |
0.248 |
|
| 1998 |
Calvey EM, White KD, Matusik JE, Sha D, Block E. Allium chemistry: identification of organosulfur compounds in ramp (Allium tricoccum) homogenates. Phytochemistry. 49: 359-64. PMID 9747536 DOI: 10.1016/S0031-9422(98)00191-5 |
0.377 |
|
| 1998 |
Uden PC, Bird SM, Kotrebai M, Nolibos P, Tyson JF, Block E, Denoyer E. Analytical selenoamino acid studies by chromatography with interfaced atomic mass spectrometry and atomic emission spectral detection Fresenius' Journal of Analytical Chemistry. 362: 447-456. DOI: 10.1007/S002160051105 |
0.435 |
|
| 1998 |
Block E. Garlic as a Functional Food: A Status Report Acs Symposium Series. 702: 125-143. |
0.185 |
|
| 1997 |
Bird SM, Ge H, Uden PC, Tyson JF, Block E, Denoyer E. High-performance liquid chromatography of selenoamino acids and organo selenium compounds. Speciation by inductively coupled plasma mass spectrometry Journal of Chromatography A. 789: 349-359. PMID 9440291 DOI: 10.1016/S0021-9673(97)00657-2 |
0.387 |
|
| 1997 |
Block E, Bird S, Tyson JF, Uden PC, Zhang X, Denoyer E. The search for anticarcinogenic organoselenium compounds from natural sources Paediatric and Perinatal Drug Therapy. 1: 1-10. DOI: 10.1080/10426509808545931 |
0.413 |
|
| 1997 |
Glass RS, Pollard JR, Schroeder TB, Lichtenberger DL, Block E, DeOrazio R, Guo C, Thiruvazhi M. Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins Phosphorus, Sulfur and Silicon and Related Elements. 120: 439-440. DOI: 10.1080/10426509708545587 |
0.764 |
|
| 1997 |
Block E, Glass RS, DeOrazio R, Lichtenberger DL, Pollard JR, Russell EE, Schroeder TB, Thiruvazhi M, Toscano PJ. Significant intramolecular sulfur-sulfur interactions in cis- and trans-2,3-dimethyl-5,6-dithiabicyclo-[2.1.1]hexane Synlett. 525-528. DOI: 10.1055/S-1997-6136 |
0.754 |
|
| 1997 |
Bird SM, Uden PC, Tyson JF, Block E, Denoyer E. Speciation of selenoamino acids and organoselenium compounds in selenium-enriched yeast using high-performance liquid chromatography-inductively coupled plasma mass spectrometry Journal of Analytical Atomic Spectrometry. 12: 785-788. DOI: 10.1039/A701429E |
0.382 |
|
| 1997 |
Block E, Gulati H, Putman D, Sha D, You N, Zhao SH. Allium Chemistry: Synthesis of 1-[Alk(en)ylsulfinyl]propyl Alk(en)yl Disulfides (Cepaenes), Antithrombotic Flavorants from Homogenates of Onion (Allium cepa) Journal of Agricultural and Food Chemistry. 45: 4414-4422. DOI: 10.1021/Jf9705126 |
0.453 |
|
| 1997 |
Calvey EM, Matusik JE, White KD, DeOrazio R, Sha D, Block E. Allium Chemistry: Supercritical Fluid Extraction and LC-APCI-MS of Thiosulfinates and Related Compounds from Homogenates of Garlic, Onion, and Ramp. Identification in Garlic and Ramp and Synthesis of 1-Propanesulfinothioic Acid S-Allyl Ester Journal of Agricultural and Food Chemistry. 45: 4406-4413. DOI: 10.1021/Jf970314E |
0.424 |
|
| 1997 |
Schroeder TB, Job C, Brown MF, Glass RS, You N, Block E. 1H-{125Te} indirect detection in nuclear magnetic resonance spectra of organotellurium compounds Magnetic Resonance in Chemistry. 35: 752-756. DOI: 10.1002/(Sici)1097-458X(199711)35:11<752::Aid-Omr167>3.0.Co;2-V |
0.541 |
|
| 1997 |
Calvey EM, Block E. Supercritical Fluid Extraction of Allium Species Acs Symposium Series. 660: 113-124. |
0.213 |
|
| 1996 |
Block E. Recent results in the organosulfur and organoselenium chemistry of genus Allium and Brassica plants: Relevance for cancer prevention Advances in Experimental Medicine and Biology. 401: 155-163. PMID 8886134 DOI: 10.1007/978-1-4613-0399-2_13 |
0.366 |
|
| 1996 |
Block E, Cai XJ, Uden PC, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Natural abundance of organoselenium compounds from garlic, onion and related plants and in human garlic breath Pure and Applied Chemistry. 68: 937-944. DOI: 10.1351/Pac199668040937 |
0.395 |
|
| 1996 |
Ge H, Cai XJ, Tyson JF, Uden PC, Denoyer ER, Block E. Identification of selenium species in selenium-enriched garlic, onion and broccoli using high-performance ion chromatography with inductively coupled plasma mass spectrometry detection Analytical Communications. 33: 279-281. DOI: 10.1039/Ac9963300279 |
0.352 |
|
| 1996 |
Block E, Gillies JZ, Gillies CW, Bazzi AA, Putman D, Revelle LK, Wang D, Zhang X. Allium chemistry: Microwave spectroscopic identification, mechanism of formation, synthesis, and reactions of (E,Z)-propanethial S-oxide, the lachrymatory factor of the onion (Allium cepa) Journal of the American Chemical Society. 118: 7492-7501. DOI: 10.1021/ja960722j |
0.324 |
|
| 1996 |
Block E, Page J, Toscano JP, Wang CX, Zhang X, DeOrazio R, Guo C, Sheridan RS, Neil Towers GH. Photochemistry of thiarubrine A and other 1,2-dithiins: Formation of 2,6-dithiabicyclo[3.1.0]hex-3-enes Journal of the American Chemical Society. 118: 4719-4720. DOI: 10.1021/ja960589v |
0.242 |
|
| 1996 |
Block E, Bayer T, Naganathan S, Zhao Shu-Hai. Allium chemistry: Synthesis and sigmatropic rearrangements of alk(en)yl 1-propenyl disulfide S-oxides from cut onion and garlic Journal of the American Chemical Society. 118: 2799-2810. DOI: 10.1021/Ja953444H |
0.68 |
|
| 1996 |
Block E, Thiruvazhi M, Toscano PJ, Bayer T, Grisoni S, Zhao Shu-Hai. Allium chemistry: Structure, synthesis, natural occurrence in onion (Allium cepa), and reactions of 2,3-dimethyl-5,6-dithiabicyclo[2.1.1]hexane S-oxides Journal of the American Chemical Society. 118: 2790-2798. DOI: 10.1021/Ja951134T |
0.716 |
|
| 1996 |
Gillies JZ, Gillies CW, Cotter EA, Block E, DeOrazio R. Microwave spectra, molecular structure, and electric dipole moment of 1,2-dithiin Journal of Molecular Spectroscopy. 180: 139-144. DOI: 10.1006/Jmsp.1996.0232 |
0.355 |
|
| 1995 |
Cai XJ, Block E, Uden PC, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Identification of selenoamino acids in ordinary and selenium-enriched garlic, onion, and broccoli using gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 43: 1754-1757. DOI: 10.1021/Jf00055A002 |
0.353 |
|
| 1995 |
Cai XJ, Block E, Uden PC, Quimby BD, Sullivan JJ. Allium chemistry: Identification of natural abundance organoselenium compounds in human breath after ingestion of garlic using gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 43: 1751-1753. DOI: 10.1021/Jf00055A001 |
0.378 |
|
| 1994 |
Calvey EM, Roach JAG, Block E. Supercritical fluid chromatography of garlic (allium sativum) extracts with mass spectrometric identification of allicin Journal of Chromatographic Science. 32: 93-96. PMID 8200919 DOI: 10.1093/Chromsci/32.3.93 |
0.361 |
|
| 1994 |
Block E, Deorazio R. Chemistry in a salad bowl: Comparative organosulfur chemistry of garlic, onion and shiitake mushrooms Pure and Applied Chemistry. 66: 2205-2206. DOI: 10.1351/Pac199466102205 |
0.388 |
|
| 1994 |
Cai XJ, Uden PC, Sullivan JJ, Quimby BD, Block E. Headspace-gas chromatography with atomic emission and mass selective detection for the determination of organoselenium compounds in elephant garlic Analytical Proceedings Including Analytical Communications. 31: 325-327. DOI: 10.1039/Ai9943100325 |
0.377 |
|
| 1994 |
Block E, De Orazio R, Thiruvazhi M. Simple total syntheses of biologically active pentathiadecane natural products, 2,4,5,7,9-pentathiadecane 2,2,9,9-tetraoxide (dysoxysulfone), from Dysoxylum richii, and 2,3,5,7,9-pentathiadecane 9,9-dioxide, the misidentified lenthionine precursor SE-3 from Shiitake mushroom (Lentinus edodes) Journal of Organic Chemistry. 59: 2273-2275. DOI: 10.1021/Jo00088A001 |
0.74 |
|
| 1994 |
Randle WM, Block E, Littlejohn MH, Putman D, Bussard ML. Onion (Allium cepa L.) thiosulfinates respond to increasing sulfur fertility Journal of Agricultural and Food Chemistry. 42: 2085-2088. DOI: 10.1021/Jf00046A003 |
0.381 |
|
| 1994 |
Cai XJ, Uden PC, Block E, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Identification of natural abundance organoselenium volatiles from garlic, elephant garlic, onion, and Chinese chive using headspace gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 42: 2081-2084. DOI: 10.1021/Jf00046A002 |
0.348 |
|
| 1994 |
Calvey EM, Matusik JE, White KD, Betz JM, Block E, Littlejohn MH, Naganathan S, Putman D. Off-line supercritical fluid extraction of thiosulfinates from garlic and onion Journal of Agricultural and Food Chemistry. 42: 1335-1341. DOI: 10.1021/Jf00042A017 |
0.683 |
|
| 1994 |
Block E, Guo C, Thiruvazhi M, Toscano PJ. Total synthesis of thiarubrine B [3-(3-buten-1-ynyl)-6-(1,3-pentadiynyl)-1,2-dithiin], the antibiotic principle of giant ragweed (Ambrosia trifida) Journal of the American Chemical Society. 116: 9403-9404. DOI: 10.1021/Ja00099A097 |
0.718 |
|
| 1993 |
Block E, Naganathan S, Putman D, Zhao SH. Organosulfur chemistry of garlic and onion: Recent results Pure and Applied Chemistry. 65: 625-632. DOI: 10.1351/Pac199365040625 |
0.68 |
|
| 1993 |
Block E, Thiruvazhi M. Allium chemistry: Synthesis of alk(en)yl 3,4-dimethyl-2-thienyl disulfides, components of distilled oils and extracts of Allium species Journal of Agricultural and Food Chemistry. 41: 2235-2237. DOI: 10.1021/Jf00036A001 |
0.724 |
|
| 1993 |
Block E, Naganathan S. Simple synthesis of endo-2-bromo-5-thiabicyclo[2.1.1]hexane† Heteroatom Chemistry. 4: 33-37. DOI: 10.1002/Hc.520040106 |
0.692 |
|
| 1992 |
Block E, Zhao SH. Allium chemistry: simple synthesis of antithrombotic cepaenes from onion and deoxycepaenes from oil of shallot by reaction 1-propenethiolate with sulfonyl halides Journal of Organic Chemistry. 57: 5815-5817. DOI: 10.1021/Jo00048A007 |
0.328 |
|
| 1992 |
Block E, Putman D, Zhao SH. Allium chemistry: GC-MS analysis of thiosulfinates and related compounds from onion, leek, scallion, shallot, chive, and Chinese chive Journal of Agricultural and Food Chemistry. 40: 2431-2438. DOI: 10.1021/Jf00024A018 |
0.306 |
|
| 1992 |
Block E, Naganathan S, Putman D, Zhao SH. Allium chemistry: HPLC analysis of thiosulfinates from onion, garlic, wild garlic (ramsoms), leek, scallion, shallot, elephant (great-headed) garlic, chive, and Chinese chive. Uniquely high allyl to methyl ratios in some garlic samples Journal of Agricultural and Food Chemistry. 40: 2418-2430. DOI: 10.1021/Jf00024A017 |
0.64 |
|
| 1992 |
Block E, Schwan A, Dixon DA. In pursuit of cyclopropanethione: cyclopropanethione S-oxide and S,S-dioxide Journal of the American Chemical Society. 114: 3492-3499. DOI: 10.1021/Ja00035A050 |
0.611 |
|
| 1992 |
Block E. The organosulfur chemistry of the genus Allium - Implications for the organic chemistry of sulfur Angewandte Chemie - International Edition in English. 31: 1135-1178. DOI: 10.1002/Anie.199211351 |
0.334 |
|
| 1991 |
Block E. The organosulfur chemistry of the onion Phosphorus, Sulfur, and Silicon and the Related Elements. 58: 3-15. DOI: 10.1080/10426509108040623 |
0.368 |
|
| 1991 |
Block E, Gernon M, Kang H, Ofori-Okai G, Zubieta J. Preparations, structures and reactions of molybdenum complexes of triorgano silylated pyridine-2-thiols Inorganic Chemistry. 30: 1736-1747. DOI: 10.1021/Ic00008A012 |
0.765 |
|
| 1991 |
Block E, Kang H, Zubieta J. Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and stmcture of [MoO(NNMePh)(2-SC5H3N-3-SiMe3)2] Inorganica Chimica Acta. 181: 227-231. DOI: 10.1016/S0020-1693(00)86815-2 |
0.31 |
|
| 1991 |
Block E, Ofori-Okai G, Kang H, Zubieta J. Molybdenum complexes with sterically-hindered thiolate ligands. The synthesis and structure of a seven coordinate complex with a molybdenum-diazenido core, [Mo(NNC6H5)(2-SC5H3N-3-SiMe3)3] Inorganica Chimica Acta. 190: 179-184. DOI: 10.1016/S0020-1693(00)80251-0 |
0.311 |
|
| 1990 |
Block E, Bayer T. (Z,Z)-d,l-2,3-Dimethyl-1,4-butanedithial S,S'-dioxide: a novel biologically active organosulfur compound from onion. Formation of vic-disulfoxides in onion extracts Journal of the American Chemical Society. 112: 4584-4585. DOI: 10.1021/Ja00167A089 |
0.302 |
|
| 1990 |
Block E, Brito M, Gernon M, McGowty D, Kang H, Zubieta J. Mercury(II) and methylmercury(II) complexes of novel sterically hindered thiolates: carbon-13 and mercury-199 NMR studies and the crystal and molecular structures of [MeHg(SC6H2-2,4,6-Pr-iso3)], [Hg(SC6H4-2-SiMe3)2], [Hg(2-SC5H3N-3-SiMe3)2], and [Hg{(2-SC6H4)2SiMe2}]2 Inorganic Chemistry. 29: 3172-3181. DOI: 10.1021/Ic00342A024 |
0.759 |
|
| 1990 |
Block E, Gernon M, Kang H, Liu S, Zubieta JA. Halido-thiolate complexes of Mo(III), Mo(IV) and Mo(V): Synthesis, characterization and crystal and molecular structures of [MoCl4{SC5H2NH-3,6-(SiMe2But)2}2],(Ph4P)[MoBr4(SC5H3NH-3-SiMe3)2], [MoBr3(SC5H3NH-3-SiMe3)3] and (Ph4P)[MoOBr3(SC5H3N-3-SiMe3)] Inorganica Chimica Acta. 167: 143-146. DOI: 10.1016/S0020-1693(00)80488-0 |
0.766 |
|
| 1989 |
Block E, Eswarakrishnan V, Gernon M, Ofori-Okai G, Saha C, Tang K, Zubieta J. o-lithiothiophenol equivalents: Generation, reactions, and applications in synthesis of hindered thiolate ligands Journal of the American Chemical Society. 111: 658-665. DOI: 10.1021/Ja00184A039 |
0.767 |
|
| 1989 |
Block E, Gernon M, Kang H, Ofori-Okai G, Zubieta J. Coordination chemistry of sterically hindered thiolate ligands. Preparation and structural characterization of the oligomeric homoleptic complexes [o-trimethylsilylbenzenethiolato]copper dodecamer and [o-trimethylsilylbenzenethiolato]silver octamer and a comparison to the structure of the cadmium mononuclear species (Et4N)2[Cd(SC6H4-o-SiMe3)4] Inorganic Chemistry. 28: 1263-1271. DOI: 10.1021/Ic00306A013 |
0.764 |
|
| 1988 |
Block E, Gernon M, Kang H, Liu S, Zubieta J. Synthesis and structural characterization of [Cu(SC6H4-o-SiMe3)]12, an unusual example of a ‘paddle-wheel’ dodecametallic thiolate cluster Journal of the Chemical Society, Chemical Communications. 1031-1033. DOI: 10.1039/C39880001031 |
0.759 |
|
| 1988 |
Block E, Gernon M, Kang H, Zubieta J. 3‐ and 3,6‐Silylated 2‐Pyridinethiols: New Hindered Bidentate Ligands and Their Novel Silver and Copper Clusters Angewandte Chemie. 27: 1342-1344. DOI: 10.1002/Anie.198813421 |
0.754 |
|
| 1987 |
Block E, Wall A. The chemistry of sulfines. 13. 2-Thiabicyclo[2.2.1]hept-5-ene and its S-oxides and 3-alkyl derivatives: sulfine and sulfene cyclopentadiene Diels-Alder adducts. Conversion of the cyclopentadiene-sulfine adducts into 2-oxa-3-thiabicyclo[3.3.0]oct-7-enes, novel bicyclic sultenes Journal of Organic Chemistry. 52: 809-818. DOI: 10.1021/Jo00381A020 |
0.615 |
|
| 1986 |
Block E, Eswarakrishnan V. A Simple Synthesis Of 4-Methylthio-1,2-Dithiolane The Photosynthesis Inhibitor Of The Green Alga Cham Globularis Phosphorus Sulfur and Silicon and the Related Elements. 26: 101-104. DOI: 10.1080/03086648608084576 |
0.31 |
|
| 1986 |
Block E, Ahmad S, Catalfamo JL, Jain MK, Apitz-Castro R. The chemistry of alkyl thiosulfinate esters. 9. Antithrombotic organosulfur compounds from garlic: structural, mechanistic, and synthetic studies Journal of the American Chemical Society. 108: 7045-7055. DOI: 10.1021/Ja00282A033 |
0.333 |
|
| 1986 |
Block E, Aslam M, Eswarakrishnan V, Gebreyes K, Hutchinson J, Iyer R, Laffitte JA, Wall A. .alpha.-Haloalkanesulfonyl bromides in organic synthesis. 5. Versatile reagents for the synthesis of conjugated polyenes, enones, and 1,3-oxathiole 1,1-dioxides Journal of the American Chemical Society. 108: 4568-4580. DOI: 10.1021/Ja00275A051 |
0.572 |
|
| 1986 |
BLOCK E, ASLAM M, ESWARAKRISHNAN V, GEBREYES K, HUTCHINSON J, IYER R, LAFFITTE J, WALL A. ChemInform Abstract: α-Haloalkanesulfonyl Bromides in Organic Synthesis. Part 5. Versatile Reagents for the Synthesis of Conjugated Polyenes, Enones, and 1,3-Oxathiole 1,1-Dioxides. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198648106 |
0.583 |
|
| 1985 |
Block E, Ahmad S. Organic synthesis with allylic sulfur compounds: reactions of the 13-thiabicyclo[8.2.1]-5-tridecene ring system Phosphorus Sulfur and Silicon and the Related Elements. 25: 139-145. DOI: 10.1080/03086648508072726 |
0.313 |
|
| 1985 |
Block E, Wall A, Zubieta J. The chemistry of sulfines. 10. 2-Thiabicyclo[2.2.1]hept-5-ene endo-2-oxide derivatives: stereospecific formation, rearrangement to bicyclic sultenes, and conversion to 5-alkylidene-2-cyclopentenones Journal of the American Chemical Society. 107: 1783-1784. DOI: 10.1021/Ja00292A066 |
0.602 |
|
| 1985 |
Block E, Wall A. Synthesis of methanethial S-oxide (sulfine) and alkanethial S,S-dioxides by fluorodesilylation. Stereochemistry of their cyclopentadiene Diels-Alder adducts Tetrahedron Letters. 26: 1425-1428. DOI: 10.1016/S0040-4039(00)99062-2 |
0.612 |
|
| 1985 |
Block E, Aslam M. Serendipitous synthesis of alkyl trimethylsilyldithioformates by trapping of bis(trimethylsilyl)thione with alkanesulfenic acids. Synthesis of bis- and tris(trimethylsilyl)methanethiols Tetrahedron Letters. 26: 2259-2262. DOI: 10.1016/S0040-4039(00)95068-8 |
0.317 |
|
| 1983 |
Block E, Aslam M, Eswarakrishnan V, Wall A. α-Haloalkanesulfonyl bromides in organic synthesis. II: A useful new 1,3-diene synthesis Journal of the American Chemical Society. 105: 6165-6167. DOI: 10.1021/Ja00357A041 |
0.577 |
|
| 1983 |
Block E, Aslam M, Eswarakrishnan V, Wall A. Bromomethanesulfonyl bromide in organic synthesis. A useful new 1,3-diene synthesis Cheminform. 14. DOI: 10.1002/Chin.198352118 |
0.58 |
|
| 1974 |
Block E, O'Connor J. Chemistry of alkyl thiosulfinate esters. VI. Preparation and spectral studies Journal of the American Chemical Society. 96: 3921-3929. DOI: 10.1021/Ja00819A033 |
0.313 |
|
| 1974 |
Block E, O'connor J. The Chemistry Of Alkyl Thiolsulfinate Esters Part 6, Preparation And Spectral Studies Cheminform. 5. DOI: 10.1002/Chin.197434202 |
0.313 |
|
| 1969 |
Corey EJ, Block E. Sulfur-bridged carbocycles. II. Extrusion of the sulfur bridge The Journal of Organic Chemistry. 34: 1233-1240. DOI: 10.1021/Jo01257A011 |
0.383 |
|
| 1969 |
Block E, Corey EJ. Sulfur-bridged carbocycles. III. Photocyclization of .beta.,.beta.'-diphenyldivinyl sulfide The Journal of Organic Chemistry. 34: 896-899. DOI: 10.1021/Jo01256A026 |
0.347 |
|
| 1966 |
Corey EJ, Block E. New Synthetic Approaches to Symmetrical Sulfur-Bridged Carbocycles The Journal of Organic Chemistry. 31: 1663-1668. DOI: 10.1021/Jo01344A001 |
0.387 |
|
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