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Bakthan Singaram - Publications

Affiliations: 
Chemistry & Biochemistry University of California, Santa Cruz, Santa Cruz, CA, United States 
Area:
asymmetric and/or enantioselective methods, development of an optical glucose sensor
Website:
http://www.chemistry.ucsc.edu/faculty/singleton.php?&singleton=true&cruz_id=singaram

253 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Amberchan G, Snelling RA, Moya E, Landi M, Lutz K, Gatihi R, Singaram B. Reaction of Diisobutylaluminum Borohydride, a Binary Hydride, with Selected Organic Compounds Containing Representative Functional Groups. The Journal of Organic Chemistry. PMID 33843216 DOI: 10.1021/acs.joc.0c03062  0.469
2019 Hauser JL, Amberchan G, Tso M, Manley R, Bustillo K, Cooper J, Golden JH, Singaram B, Oliver SRJ. A Mesoporous Aluminosilicate Nanoparticle-Supported Nickel–Boron Composite for the Catalytic Reduction of Nitroarenes Acs Applied Nano Materials. 2: 1472-1483. DOI: 10.1021/acsanm.8b02351  0.204
2018 C P P, Joseph E, A A, D S N, Ibnusaud I, Raskatov J, Singaram B. Stabilization of NaBH4 in Methanol Using a Catalytic Amount of NaOMe. Reduction of Esters and Lactones at Room Temperature without Solvent-Induced Loss of Hydride. The Journal of Organic Chemistry. PMID 29341612 DOI: 10.1021/Acs.Joc.7B02993  0.523
2017 Resendez A, Halim MA, Singh J, Webb DL, Singaram B. Boronic acid recognition of non-interacting carbohydrates for biomedical applications: increasing fluorescence signals of minimally interacting aldoses and sucralose. Organic & Biomolecular Chemistry. PMID 29130464 DOI: 10.1039/C7Ob01893B  0.475
2017 Snelling RA, Amberchan G, Resendez A, Murphy CL, Porter L, Singaram B. Diisobutylaluminum borohydride: An efficient reagent for the reduction of tertiary amides to the corresponding amines under ambient conditions Tetrahedron Letters. 58: 4073-4077. DOI: 10.1016/J.Tetlet.2017.09.030  0.494
2016 Resendez A, Panescu P, Zuniga R, Banda I, Joseph J, Webb DL, Singaram B. Rapid Multi-Well Assay for the Analysis of Sugar Gut Permeability Markers: Discrimination of Sugar Alcohols With a Fluorescent Probe Array Based on Boronic Acid Appended Viologens. Analytical Chemistry. PMID 27116118 DOI: 10.1021/Acs.Analchem.6B00880  0.397
2016 Bailey CL, Joh AY, Hurley ZQ, Anderson CL, Singaram B. Controlled Reduction of Tertiary Amides to The Corresponding Alcohols, Aldehydes, or Amines Using Dialkylboranes and Aminoborohydride Reagents. The Journal of Organic Chemistry. PMID 27035215 DOI: 10.1021/acs.joc.6b00276  0.463
2016 Nascimento RA, Ozel RE, Mak WH, Mulato M, Singaram B, Pourmand N. Single cell 'Glucose Nanosensor' verifies elevated glucose levels in individual cancer cells. Nano Letters. PMID 26752097 DOI: 10.1021/Acs.Nanolett.5B04495  0.362
2016 Resendez A, Wessling RA, Singaram B. CHAPTER 5: Boronic acid functionalized viologens as saccharide sensors Monographs in Supramolecular Chemistry. 2016: 128-181. DOI: 10.1039/9781782622123-00128  0.279
2015 González E, Muñoz-Hernández L, Alicea E, Singaram B, Kabalka GW, Soderquist JA. Cyclohexenylboration of Aldehydes and Ketones with the Borabicyclo[3.3.2]decanes (BBDs). Organic Letters. 17: 4368-71. PMID 26284657 DOI: 10.1021/Acs.Orglett.5B02194  0.677
2015 Resendez A, Abdul Halim M, Landhage CM, Hellström PM, Singaram B, Webb DL. Rapid small intestinal permeability assay based on riboflavin and lactulose detected by bis-boronic acid appended benzyl viologens. Clinica Chimica Acta; International Journal of Clinical Chemistry. 439: 115-21. PMID 25300228 DOI: 10.1016/J.Cca.2014.09.031  0.406
2015 Snelling R, Saavedra JZ, Bayrasy P, Abdollahian Y, Singaram B. Binary reducing agents containing dichloroindium hydride for the selective, partial, or tandem reductions of bifunctional compounds consisting of halo-nitriles, halo-esters and halo-carboxylic acids Organic Chemistry Frontiers. 2: 133-140. DOI: 10.1039/C4Qo00308J  0.826
2015 Bailey CL, Clary JW, Tansakul C, Klabunde L, Anderson CL, Joh AY, Lill AT, Peer N, Braslau R, Singaram B. Reduction of Weinreb amides to aldehydes under ambient conditions with magnesium borohydride reagents Dedicated to the memory of Professor Sheldon Shore Tetrahedron Letters. 56: 706-709. DOI: 10.1016/J.Tetlet.2014.12.066  0.817
2015 Murphy CL, Hall A, Roberts EJ, Ryan MD, Clary JW, Singaram B. Preparation and reactions of 4-iodobutyl pinacolborate. Synthesis of substituted alkyl and aryl pinacolboronates via 4-iodobutyl pinacolborate utilizing tetrahydrofuran as the leaving group Tetrahedron Letters. 56: 3032-3033. DOI: 10.1016/J.Tetlet.2014.12.033  0.819
2015 Resendez A, Abdul Halim M, Landhage CM, Hellström PM, Singaram B, Webb DL. Rapid small intestinal permeability assay based on riboflavin and lactulose detected by bis-boronic acid appended benzyl viologens Clinica Chimica Acta. 439: 115-121. DOI: 10.1016/j.cca.2014.09.031  0.296
2014 Resendez A, Halim MA, Hellström PM, Singaram B, Webb D. Su1875 Rapid Small Intestinal Permeability Assay Based on Riboflavin and Lactulose Detected by BIS-Boronic Acid Appended Benzyl Viologens (BBV) Gastroenterology. 146: S-491. DOI: 10.1016/S0016-5085(14)61764-9  0.397
2013 Vilozny B, Wollenberg AL, Actis P, Hwang D, Singaram B, Pourmand N. Carbohydrate-actuated nanofluidic diode: switchable current rectification in a nanopipette. Nanoscale. 5: 9214-21. PMID 23934399 DOI: 10.1039/C3Nr02105J  0.745
2013 Vilozny B, Wollenberg AL, Actis P, Hwang D, Singaram B, Pourmand N. Carbohydrate-actuated nanofluidic diode: Switchable current rectification in a nanopipette Nanoscale. 5: 9214-9221. DOI: 10.1039/c3nr02105j  0.713
2012 Hirayama LC, Haddad TD, Oliver AG, Singaram B. Direct synthesis of B-allyl and B-allenyldiisopinocampheylborane reagents using allyl or propargyl halides and indium metal under Barbier-type conditions. The Journal of Organic Chemistry. 77: 4342-53. PMID 22497595 DOI: 10.1021/Jo300260A  0.83
2012 Saavedra JZ, Resendez A, Rovira A, Eagon S, Haddenham D, Singaram B. Reaction of InCl3 with various reducing agents: InCl3-NaBH4-mediated reduction of aromatic and aliphatic nitriles to primary amines. The Journal of Organic Chemistry. 77: 221-8. PMID 22148510 DOI: 10.1021/Jo201809A  0.815
2012 Haddad TD, Hirayama LC, Buckley JJ, Singaram B. Indium-mediated asymmetric Barbier-type propargylations: Additions to aldehydes and ketones and mechanistic investigation of the organoindium reagents Journal of Organic Chemistry. 77: 889-898. PMID 22148263 DOI: 10.1021/Jo201980B  0.831
2012 Saavedra JZ, Bayrasy P, Resendez A, Snelling R, Anderson MH, Singaram B. Synthesis of dichloroindium hydride and exploration of its reactivity with organic functional groups. Tandem, selective and partial reductions of halo-nitriles Arkivoc. 2012: 167-189. DOI: 10.3998/Ark.5550190.0013.711  0.793
2012 Bailey CL, Murphy CL, Clary JW, Eagon S, Gould N, Singaram B. Reaction of grignard reagents with diisopropylaminoborane. Synthesis of alkyl, aryl, heteroaryl and allyl boronic acids from organo(diisopropyl)- aminoborane by a simple hydrolysis Heterocycles. 86: 331-341. DOI: 10.3987/Com-12-S(N)14  0.825
2012 Cordes DB, Singaram B. A unique, two-component sensing system for fluorescence detection of glucose and other carbohydrates Pure and Applied Chemistry. 84: 2183-2202. DOI: 10.1351/Pac-Con-11-10-36  0.689
2012 Zhang A, Wheeler D, Ling Y, Wang G, Yang X, Vilozny B, Singaram B, Gu C, Li Y. Novel molecular specific detection of glucose using a raman probe molecule with surface enhanced raman scattering Science of Advanced Materials. 4: 1047-1054. DOI: 10.1166/Sam.2012.1400  0.752
2012 Saavedra JZ, Resendez A, Rovira A, Eagon S, Haddenham D, Singaram B. Reaction of InCl 3 with various reducing agents: InCl 3-NaBH 4-mediated reduction of aromatic and aliphatic nitriles to primary amines Journal of Organic Chemistry. 77: 221-228. DOI: 10.1021/jo201809a  0.793
2012 Goralski CT, Singaram B. The hydroboration of enamines Arkivoc. 2012: 88-113.  0.364
2011 Clary JW, Rettenmaier TJ, Snelling R, Bryks W, Banwell J, Wipke WT, Singaram B. Hydride as a leaving group in the reaction of pinacolborane with halides under ambient Grignard and Barbier conditions. One-pot synthesis of alkyl, aryl, heteroaryl, vinyl, and allyl pinacolboronic esters. The Journal of Organic Chemistry. 76: 9602-10. PMID 22040316 DOI: 10.1021/Jo201093U  0.828
2011 Binder CM, Singaram B. Asymmetric addition of diorganozinc reagents to aldehydes and ketones Organic Preparations and Procedures International. 43: 139-208. DOI: 10.1080/00304948.2011.564538  0.835
2011 Vilozny B, Schiller A, Wessling RA, Singaram B. Multiwell plates loaded with fluorescent hydrogel sensors for measuring pH and glucose concentration Journal of Materials Chemistry. 21: 7589-7595. DOI: 10.1039/C0Jm04257A  0.766
2011 Bowyer WJ, Singaram B, Sessler AM. Nature of the intermediates formed during indium mediated allylation under Barbier conditions. Spectroscopic and experimental data on allylindium species Tetrahedron. 67: 7449-7460. DOI: 10.1016/J.Tet.2011.06.041  0.364
2011 Haddenham D, Bailey CL, Vu C, Nepomuceno G, Eagon S, Pasumansky L, Singaram B. Lithium aminoborohydrides 17. Palladium catalyzed borylation of aryl iodides, bromides, and triflates with diisopropylaminoborane prepared from lithium diisopropylaminoborohydride Tetrahedron. 67: 576-583. DOI: 10.1016/J.Tet.2010.11.065  0.826
2010 Eagon S, DeLieto C, McDonald WJ, Haddenham D, Saavedra J, Kim J, Singaram B. Mild and expedient asymmetric reductions of α,β-unsaturated alkenyl and alkynyl ketones by TarB-NO2 and mechanistic investigations of ketone reduction. The Journal of Organic Chemistry. 75: 7717-25. PMID 21033682 DOI: 10.1021/Jo101530F  0.817
2010 Haddad TD, Hirayama LC, Singaram B. Indium-mediated asymmetric Barbier-type allylations: Additions to aldehydes and ketones and mechanistic investigation of the organoindium reagents Journal of Organic Chemistry. 75: 642-649. PMID 20027999 DOI: 10.1021/jo902173j  0.835
2010 Eagon S, Delieto C, McDonald WJ, Haddenham D, Saavedra J, Kim J, Singaram B. Mild and expedient asymmetric reductions of α,β-unsaturated alkenyl and alkynyl ketones by TarB-NO2 and mechanistic investigations of ketone reduction Journal of Organic Chemistry. 75: 7717-7725. DOI: 10.1021/jo101530f  0.784
2010 Eagon S, Ball-Jones N, Haddenham D, Saavedra J, Delieto C, Buckman M, Singaram B. Enantioselective reduction of α-substituted ketones mediated by the boronate ester TarB-NO2 Tetrahedron Letters. 51: 6418-6421. DOI: 10.1016/J.Tetlet.2010.09.146  0.817
2010 Brown HC, Murali D, Singaram B. ChemInform Abstract: Boranes in Synthesis. Part 8. Chiral Synthesis via Organoboranes. Part 45. Asymmetric Hydroboration of 1-Cyclopentenol Derivatives Using Diisopinocampheylborane. Synthesis of Optically Active Cyclopentane-1,2-diol Derivatives of High Cheminform. 30: no-no. DOI: 10.1002/chin.199941044  0.477
2010 RANGAISHENVI MV, SINGARAM B, BROWN HC. ChemInform Abstract: Chiral Synthesis via Organoboranes. Part 30. Facile Synthesis, by the Matteson Asymmetric Homologation Procedure, of α-Methyl Boronic Acids not Available from Asymmetric Hydroboration and Their Conversion into the Corresponding Aldehy Cheminform. 22: no-no. DOI: 10.1002/chin.199139067  0.512
2009 Kim J, Bruning J, Park KE, Lee DJ, Singaram B. Highly enantioselective and regioselective carbonyl reduction of cyclic alpha,beta-unsaturated ketones using TarB-NO2 and sodium borohydride. Organic Letters. 11: 4358-61. PMID 19711968 DOI: 10.1021/Ol901677B  0.544
2009 Vilozny B, Schiller A, Wessling RA, Singaram B. Enzyme assays with boronic acid appended bipyridinium salts Analytica Chimica Acta. 649: 246-251. PMID 19699401 DOI: 10.1016/J.Aca.2009.07.032  0.769
2009 Sharrett Z, Gamsey S, Hirayama L, Vilozny B, Suri JT, Wessling RA, Singaram B. Exploring the use of APTS as a fluorescent reporter dye for continuous glucose sensing Organic and Biomolecular Chemistry. 7: 1461-1470. PMID 19300833 DOI: 10.1039/B821934F  0.782
2009 Binder CM, Bautista A, Zaidlewicz M, Krzemiński MP, Oliver A, Singaram B. Dual stereoselectivity in the dialkylzinc reaction using (-)-β-pinene derived amino alcohol chiral auxiliaries Journal of Organic Chemistry. 74: 2337-2343. PMID 19216500 DOI: 10.1021/Jo802371Z  0.804
2009 Haddenham D, Pasumansky L, DeSoto J, Eagon S, Singaram B. Reductions of aliphatic and aromatic nitriles to primary amines with diisopropylaminoborane Journal of Organic Chemistry. 74: 1964-1970. PMID 19191712 DOI: 10.1021/Jo8023329  0.802
2008 Binder CM, Dixon DD, Almaraz E, Tius MA, Singaram B. A Simple Procedure for C-C Bond Cleavage of Aromatic and Aliphatic Epoxides with Aqueous Sodium Periodate Under Ambient Conditions. Tetrahedron Letters. 49: 2764-2767. PMID 19946457 DOI: 10.1016/J.Tetlet.2008.02.142  0.797
2008 Schiller A, Vilozny B, Wessling RA, Singaram B. Recognition of phospho sugars and nucleotides with an array of boronic acid appended bipyridinium salts Analytica Chimica Acta. 627: 203-211. PMID 18809074 DOI: 10.1016/J.Aca.2008.08.011  0.767
2008 Pasumansky L, Haddenham D, Clary JW, Fisher GB, Goralski CT, Singaram B. Lithium aminoborohydrides 16. Synthesis and reactions of monomeric and dimeric aminoboranes. The Journal of Organic Chemistry. 73: 1898-905. PMID 18215062 DOI: 10.1021/Jo702271C  0.824
2008 Eagon S, Kim J, Singaram B. Mild and practical reductions of prochiral ketones to chiral alcohols using the chiral boronic ester TarB-H Synthesis. 3874-3876. DOI: 10.1055/S-0028-1083605  0.819
2008 Binder CM, Dixon DD, Almaraz E, Tius MA, Singaram B. A simple procedure for C-C bond cleavage of aromatic and aliphatic epoxides with aqueous sodium periodate under ambient conditions Tetrahedron Letters. 49: 2764-2767. DOI: 10.1016/j.tetlet.2008.02.142  0.775
2008 Haddad TD, Hirayama LC, Taynton P, Singaram B. Asymmetric indium-mediated Barbier-type allylation reactions with ketones to form homoallylic alcohol products Tetrahedron Letters. 49: 508-511. DOI: 10.1016/J.Tetlet.2007.11.089  0.824
2008 Sharrett Z, Gamsey S, Levine P, Cunningham-Bryant D, Vilozny B, Schiller A, Wessling RA, Singaram B. Boronic acid-appended bis-viologens as a new family of viologen quenchers for glucose sensing Tetrahedron Letters. 49: 300-304. DOI: 10.1016/J.Tetlet.2007.11.053  0.797
2008 Eagon S, Kim J, Yan K, Haddenham D, Singaram B. ChemInform Abstract: Asymmetric Reductions Using the Chiral Boronic Ester TarB—H: A Practical and Inexpensive Procedure for Synthesizing Chiral Alcohols. Cheminform. 39. DOI: 10.1002/CHIN.200814031  0.81
2007 Schiller A, Wessling RA, Singaram B. A fluorescent sensor array for saccharides based on boronic acid appended bipyridinium salts Angewandte Chemie - International Edition. 46: 6457-6459. PMID 17654643 DOI: 10.1002/Anie.200701888  0.392
2007 Cordes DB, Miller A, Gamsey S, Singaram B. Simultaneous use of multiple fluorescent reporter dyes for glucose sensing in aqueous solution Analytical and Bioanalytical Chemistry. 387: 2767-2773. PMID 17318525 DOI: 10.1007/S00216-007-1128-Z  0.789
2007 Gamsey S, Miller A, Olmstead MM, Beavers CM, Hirayama LC, Pradhan S, Wessling RA, Singaram B. Boronic acid-based bipyridinium salts as tunable receptors for monosaccharides and α-hydroxycarboxylates Journal of the American Chemical Society. 129: 1278-1286. PMID 17263411 DOI: 10.1021/Ja066567I  0.795
2007 Pasumansky L, Collins CJ, Pratt LM, Nguyên NV, Ramachandran B, Singaram B. Solvent and temperature effects on the reduction and amination reactions of electrophiles by lithium dialkylaminoborohydrides. The Journal of Organic Chemistry. 72: 971-6. PMID 17253818 DOI: 10.1021/Jo062154O  0.806
2007 Goralski CT, Hasha DL, Singaram B, Steiner D. Scale-up of the preparation of (1R,2R,4S)-1-methyl-4-(1-methylethenyl)-2- (4-morpholinyl)cyclohexanol Organic Process Research and Development. 11: 776-779. DOI: 10.1021/Op700092N  0.412
2007 Pasumansky L, Collins CJ, Pratt LM, Ngân VN, Ramachandran B, Singaram B. Solvent and temperature effects on the reduction and amination reactions of electrophiles by lithium dialkylaminoborohydrides Journal of Organic Chemistry. 72: 971-976. DOI: 10.1021/jo062154o  0.802
2007 Eagon S, Kim J, Yan K, Haddenham D, Singaram B. Asymmetric reductions using the chiral boronic ester TarB-H: a practical and inexpensive procedure for synthesizing chiral alcohols Tetrahedron Letters. 48: 9025-9029. DOI: 10.1016/J.Tetlet.2007.10.075  0.817
2007 Sharrett Z, Gamsey S, Fat J, Cunningham-Bryant D, Wessling RA, Singaram B. The effect of boronic acid acidity on performance of viologen-based boronic acids in a two-component optical glucose-sensing system Tetrahedron Letters. 48: 5125-5129. DOI: 10.1016/J.Tetlet.2007.05.075  0.798
2006 Tassicker RJ, Marshall PK, Liebeck TA, Keville MA, Singaram BM, Richards FH. Predictive and pre-natal testing for Huntington Disease in Australia: results and challenges encountered during a 10-year period (1994-2003). Clinical Genetics. 70: 480-9. PMID 17100992 DOI: 10.1111/j.1399-0004.2006.00701.x  0.181
2006 Gamsey S, Suri JT, Wessling RA, Singaram B. Continuous glucose detection using boronic acid-substituted viologens in fluorescent hydrogels: Linker effects and extension to fiber optics Langmuir. 22: 9067-9074. PMID 17014156 DOI: 10.1021/La0617053  0.791
2006 Thoniyot P, Cappuccio FE, Gamsey S, Cordes DB, Wessling RA, Singaram B. Continuous glucose sensing with fluorescent thin-film hydrogels. 2. Fiber optic sensor fabrication and in vitro testing Diabetes Technology and Therapeutics. 8: 279-287. PMID 16800749 DOI: 10.1089/Dia.2006.8.279  0.774
2006 Olmstead MM, Fettinger JC, Gamsey S, Clary JW, Singaram B. Three chiral vinyldioxazaborocanes. Acta Crystallographica. Section C, Crystal Structure Communications. 62: o333-5. PMID 16763320 DOI: 10.1107/S0108270106013527  0.792
2006 Cordes DB, Gamsey S, Singaram B. Fluorescent quantum dots with boronic acid substituted viologens to sense glucose in aqueous solution Angewandte Chemie - International Edition. 45: 3829-3832. PMID 16646092 DOI: 10.1002/Anie.200504390  0.79
2006 Hirayama LC, Dunham KK, Singaram B. Asymmetric indium-mediated synthesis of homopropargylic alcohols Tetrahedron Letters. 47: 5173-5176. DOI: 10.1055/S-2006-949314  0.795
2006 Goralski CT, Singaram B. Special feature section: Hydride reductions Organic Process Research and Development. 10: 947-948. DOI: 10.1021/Op0601363  0.314
2006 Kim J, Suri JT, Cordes DB, Singaram B. Asymmetric reductions involving borohydrides: A practical asymmetric reduction of ketones mediated by (L)-TarB-NO2: A chiral Lewis acid Organic Process Research and Development. 10: 949-958. DOI: 10.1021/Op060079D  0.818
2006 Pasumansky L, Goralski CT, Singaram B. Lithium aminoborohydrides: Powerful, selective, air-stable reducing agents Organic Process Research and Development. 10: 959-970. DOI: 10.1021/Op0600759  0.807
2006 Kim J, Singaram B. Enantioselective reduction of aliphatic ketones using NaBH4 and TarB-NO2, a chiral boronic ester Tetrahedron Letters. 47: 3901-3903. DOI: 10.1016/j.tetlet.2006.03.162  0.427
2006 Cordes DB, Kwong TJ, Morgan KA, Singaram B. Chiral styrene oxides from α-haloacetophenones using NaBH4 and TarB-NO2, a chiral Lewis acid Tetrahedron Letters. 47: 349-351. DOI: 10.1016/J.Tetlet.2005.11.011  0.706
2006 Watts CC, Thoniyot P, Cappuccio F, Verhagen J, Gallagher B, Singaram B. Catalytic asymmetric transfer hydrogenation of ketones using terpene-based chiral β-amino alcohols Tetrahedron Asymmetry. 17: 1301-1307. DOI: 10.1016/J.Tetasy.2006.04.025  0.812
2006 Gamsey S, Baxter NA, Sharrett Z, Cordes DB, Olmstead MM, Wessling RA, Singaram B. The effect of boronic acid-positioning in an optical glucose-sensing ensemble Tetrahedron. 62: 6321-6331. DOI: 10.1016/J.Tet.2006.04.047  0.807
2005 Cordes DB, Gamsey S, Sharrett Z, Miller A, Thoniyot P, Wessling RA, Singaram B. The interaction of boronic acid-substituted viologens with pyranine: The effects of quencher charge on fluorescence quenching and glucose response Langmuir. 21: 6540-6547. PMID 15982064 DOI: 10.1021/La050219X  0.795
2005 Cordes DB, Miller A, Gamsey S, Sharrett Z, Thoniyot P, Wessling R, Singaram B. Optical glucose detection across the visible spectrum using anionic fluorescent dyes and a viologen quencher in a two-component saccharide sensing system Organic and Biomolecular Chemistry. 3: 1708-1713. PMID 15858654 DOI: 10.1039/B418953A  0.796
2005 Hirayama LC, Gamsey S, Knueppel D, Steiner D, Delatorre K, Singaram B. Indium-mediated Barbier-type allylation of aldehydes as a convenient method for the highly enantioselective synthesis of homoallylic alcohols Tetrahedron Letters. 46: 2315-2318. DOI: 10.1016/J.Tetlet.2005.01.169  0.822
2005 Watts CC, Thoniyot P, Hirayama LC, Romano T, Singaram B. Enantioselective alkynylations of aromatic and aliphatic aldehydes catalyzed by terpene derived chiral amino alcohols Tetrahedron Asymmetry. 16: 1829-1835. DOI: 10.1016/J.Tetasy.2005.03.036  0.815
2005 Gamsey S, DeLaTorre K, Singaram B. Asymmetric hydrogenation of chiral vinyloxazaborolidines under ambient conditions Tetrahedron Asymmetry. 16: 711-715. DOI: 10.1016/J.Tetasy.2004.11.091  0.758
2005 Cordes DB, Nguyen TM, Kwong TJ, Suri JT, Luibrand RT, Singaram B. Asymmetric reduction of ketones under mild conditions using NaBH 4 and TarB-NO2: An efficient and unusual chiral acyloxyborohydride reducing system European Journal of Organic Chemistry. 5289-5295. DOI: 10.1002/Ejoc.200500397  0.831
2005 Pasumansky L, Singaram B, Goralski CT. Recent advances in the chemistry of lithium aminoborohydrides Aldrichimica Acta. 38: 61-65.  0.767
2004 Cappuccio FE, Suri JT, Cordes DB, Wessling RA, Singaram B. Evaluation of pyranine derivatives in boronic acid based saccharide sensing: Significance of charge interaction between dye and quencher in solution and hydrogel Journal of Fluorescence. 14: 521-533. PMID 15617260 DOI: 10.1023/B:Jofl.0000039340.94188.2A  0.79
2004 Olmstead MM, Suri JT, Singaram B. N,N′-dibenzyl-4,7-phenanthrolinium dibromide methanol solvate Acta Crystallographica Section E: Structure Reports Online. 60: o275-o277. DOI: 10.1107/S1600536804001370  0.775
2004 Olmstead MM, Suri JT, Singaram B. N-[2-(hydroxymethoxyboryl)benzyl]-4,7-phenanthrolinium bromide methanol solvate Acta Crystallographica Section E: Structure Reports Online. 60: o278-o280. DOI: 10.1107/S1600536804001369  0.787
2004 Pasumansky L, Hernández AR, Gamsey S, Goralski CT, Singaram B. Synthesis of aminopyridines from 2-fluoropyridine and lithium amides Tetrahedron Letters. 45: 6417-6420. DOI: 10.1016/J.Tetlet.2004.06.132  0.81
2003 Suri JT, Cordes DB, Cappuccio FE, Wessling RA, Singaram B. Continuous Glucose Sensing with a Fluorescent Thin-Film Hydrogel Angewandte Chemie - International Edition. 42: 5857-5859. PMID 14673918 DOI: 10.1002/Anie.200352405  0.764
2003 Thomas S, Roberts S, Pasumansky L, Gamsey S, Singaram B. Aminoborohydrides 15. The first mild and efficient method for generating 2-(dialkylamino)-pyridines from 2-fluoropyridine. Organic Letters. 5: 3867-70. PMID 14535730 DOI: 10.1021/Ol035430J  0.807
2003 Thomas S, Roberts S, Pasumansky L, Gamsey S, Singaram B. Aminoborohydrides 15. The First Mild and Efficient Method for Generating 2-(Dialkylamino)-pyridines from 2-Fluoropyridine Organic Letters. 5: 3867-3870. DOI: 10.1021/ol035430j  0.77
2003 Suri JT, Cordes DB, Cappuccio FE, Wessling RA, Singaram B. Monosaccharide detection with 4,7-phenanthrolinium salts: Charge-induced fluorescence sensing Langmuir. 19: 5145-5152. DOI: 10.1021/La034270H  0.795
2002 Richards FH, Tassicker RJ, Kromberg JGR, Singaram BM. Predictive genetic testing in children Medical Journal of Australia. 176: 507. PMID 12065022 DOI: 10.5694/J.1326-5377.2001.TB143625.X  0.162
2002 Steiner D, Ivison L, Goralski CT, Appell RB, Gojkovic JR, Singaram B. A facile and efficient method for the kinetic separation of commercially available cis- and trans-limonene epoxide Tetrahedron Asymmetry. 13: 2359-2363. DOI: 10.1016/S0957-4166(02)00646-8  0.391
2002 Steiner D, Sethofer SG, Goralski CT, Singaram B. Asymmetric addition of diethylzinc to aldehydes catalyzed by β-amino alcohols derived from limonene oxide Tetrahedron Asymmetry. 13: 1477-1483. DOI: 10.1016/S0957-4166(02)00342-7  0.491
2002 Suri JT, Vu T, Hernandez A, Congdon J, Singaram B. Enantioselective reduction of aryl ketones using LiBH4 and TarB-X: A chiral Lewis acid Tetrahedron Letters. 43: 3649-3652. DOI: 10.1016/S0040-4039(02)00652-4  0.809
2002 Camara JN, Suri JT, Cappuccio FE, Wessling RA, Singaram B. Boronic acid substituted viologen based optical sugar sensors: Modulated quenching with viologen as a method for monosaccharide detection Tetrahedron Letters. 43: 1139-1141. DOI: 10.1016/S0040-4039(01)02366-8  0.781
2001 Thomas S, Huynh T, Enriquez-Rios V, Singaram B. Aminoborohydrides. 14. Lithium aminoborohydrides in the selective reduction or amination of alkyl methanesulfonate esters Organic Letters. 3: 3915-3918. PMID 11720568 DOI: 10.1021/Ol0167659  0.663
2001 Thomas S, Collins CJ, Cuzens JR, Spiciarich D, Goralski CT, Singaram B. Aminoborohydrides. 12. Novel tandem SNAr amination-reduction reactions of 2-halobenzonitriles with lithium N,N-dialkylaminoborohydrides Journal of Organic Chemistry. 66: 1999-2004. PMID 11300892 DOI: 10.1021/jo001388j  0.662
2001 Collins CJ, Singaram B. Aminoborohydrides. 13. Facile reduction of N-alkyl lactams with 9-borabicyclo[3.3.1]nonane (9-BBN) and lithium aminoborohydrides (LAB) reagents Arkivoc. 2001: 59-75. DOI: 10.3998/Ark.5550190.0002.407  0.667
2001 Chrisman W, Camara JN, Marcellini K, Singaram B, Goralski CT, Hasha DL, Rudolf PR, Nicholson LW, Borodychuk KK. A simple and convenient synthesis of β-amino alcohol chiral auxiliaries based on limonene oxide Tetrahedron Letters. 42: 5805-5807. DOI: 10.1016/S0040-4039(01)01135-2  0.805
2001 Thomas S, Collins CJ, Goralski CT, Singaram B. ChemInform Abstract: Two in One Reagents Cheminform. 32: no-no. DOI: 10.1002/chin.200101273  0.573
2001 Nöth H, Schlegel A, Singaram B, Knizek J, Mayer P, Seifert T. Synthesis and structures of aminoalkoxyalanes European Journal of Inorganic Chemistry. 173-180. DOI: 10.1002/1099-0682(20011)2001:1<173::Aid-Ejic173>3.0.Co;2-E  0.441
2001 Goralski CT, Singaram B, Collins CJ, Cuzens JR, Lanz M. Lithium aminoborohydrides: Reagents with multiple personalities Acs Symposium Series. 783: 18-32.  0.499
2000 Murali D, Singaram B, Brown HC. Asymmetric hydroboration of [E]- and [Z]-2-methoxy-2-butenes. Synthesis of (-)-[2R,3R]-butane-2,3-diol in >97% ee Tetrahedron Asymmetry. 11: 4831-4834. DOI: 10.1016/S0957-4166(00)00485-7  0.463
2000 Thomas S, Collins CJ, Goralski CT, Singaram B. Two reagents in one Chemical Innovation. 30: 30-X.  0.692
1999 Flaniken JM, Collins CJ, Lanz M, Singaram B. Aminoborohydrides. 11. Facile reduction of N-alkyl lactams to the corresponding amines using lithium aminoborohydrides Organic Letters. 1: 799-801. PMID 16118886 DOI: 10.1021/Ol990145E  0.648
1999 Collins CJ, Lanz M, Goralski CT, Singaram B. Aminoborohydrides. 10. The synthesis of tertiary amine-boranes from various benzyl halides and lithium N,N-dialkylaminoborohydrides Journal of Organic Chemistry. 64: 2574-2576. DOI: 10.1021/Jo982176D  0.593
1999 Collins CJ, Lanz M, Singaram B. Facile reduction of tertiary lactams to cyclic amines with 9- borabicyclo[3.3.1]nonane (9-BBN) Tetrahedron Letters. 40: 3673-3676. DOI: 10.1016/S0040-4039(99)00556-0  0.602
1999 McBride CM, Chrisman W, Harris CE, Singaram B. Efficient synthesis of substituted benzenes from 1,3-dienes or 1,4 cyclohexadienes with KMnO4 under mild conditions Tetrahedron Letters. 40: 45-48. DOI: 10.1016/S0040-4039(98)80015-4  0.41
1999 Brown HC, Murali D, Singaram B. Chiral synthesis via organoboranes. 45. Asymmetric hydroboration of 1-cyclopentenol derivatives using diisopinocampheylborane. Synthesis of optically active cyclopentane-1,2-diol derivatives of high optical purity Journal of Organometallic Chemistry. 581: 116-121. DOI: 10.1016/S0022-328X(99)00047-9  0.53
1999 Brown HC, Murali D, Singaram B. Chiral synthesis via organoboranes. 45. Asymmetric hydroboration of 1-cyclopentenol derivatives using diisopinocampheylborane. Synthesis of optically active cyclopentane-1,2-diol derivatives of high optical purity Journal of Organometallic Chemistry. 581: 116-121.  0.332
1997 Goralski CT, Chrisman W, Hasha DL, Nicholson LW, Rudolf PR, Zakett D, Singaram B. Boranes in synthesis - VII. Synthesis of 2-dialkylamino-6,6- dimethylbicyclo[3.1.1]heptan-3-ols from (R)-(+)-nopinone. Chiral auxiliaries for the addition of diethylzinc to aromatic aldehydes Tetrahedron Asymmetry. 8: 3863-3871. DOI: 10.1016/S0957-4166(97)00566-1  0.472
1997 Kotha S, Brahmachary E, Kuki A, Lang K, Anglos D, Singaram B, Chrisman W. Synthesis of a novel constrained α-amino acid with quinoxaline side chain : 7-Amino-6,7-dihydro-8H-cyclopenta[g]quinoxaline-7-carbox-ylic acid Tetrahedron Letters. 38: 9031-9034. DOI: 10.1016/S0040-4039(97)10427-0  0.577
1997 Kotha S, Brahmachary E, Kuki A, Lang K, Anglos D, Singaram B, Chrisman W. Synthesis of a novel constrained α-amino acid with quinoxaline side chain: 7-amino-6,7-dihydro-8H-cyclopenta[g]quinoxaline-7-carboxylic acid Tetrahedron Letters. 38: 9031-9034. DOI: 10.1016/S0040-4039(97)10427-0  0.526
1997 Chrisman W, Singaram B. The effect of different amine bases in the Swern oxidation of β-amino alcohols Tetrahedron Letters. 38: 2053-2056. DOI: 10.1016/S0040-4039(97)00283-9  0.491
1997 Godjoian G, Singaram B. Controlled reduction of tertiary amides to the corresponding aldehydes or amines using dialkylboranes Tetrahedron Letters. 38: 1717-1720. DOI: 10.1016/S0040-4039(97)00179-2  0.496
1997 Harris CE, Chrisman W, Bickford SA, Lee LY, Torreblanca AE, Singaram B. Enamine oxidations. 2. Selective oxidative cleavage of β,β-disubstituted enamines using alumina supported permanganate. Synthesis of one-carbon dehomologated carbonyl compounds from enamines Tetrahedron Letters. 38: 981-984. DOI: 10.1016/S0040-4039(96)02504-X  0.427
1997 Collins CJ, Fisher GB, Reem A, Goralski CT, Singaram B. Aminoborohydrides. 9. Selective reductions of aldehydes, ketones, esters, and epoxides in the presence of a nitrile ising lithium N,N-dialkylaminoborohydrides Tetrahedron Letters. 38: 529-532. DOI: 10.1016/S0040-4039(96)02410-0  0.64
1997 Nakamura H, Aoyagi K, Singaram B, Cai J, Nemoto H, Yamamoto Y. A Novel[3+2] Annelation betweenortho-Carboranyltrimethylsilane and Conjugated Carbonyl Compounds Angewandte Chemie International Edition in English. 36: 367-369. DOI: 10.1002/Anie.199703671  0.492
1997 Nakamura H, Aoyagi K, Singaram B, Cai J, Nemoto H, Yamamoto Y. Eine neuartige [3+2]-Anellierung einesortho-Carboranyltrimethylsilans an konjugierte Carbonylverbindungen Angewandte Chemie. 109: 399-401. DOI: 10.1002/Ange.19971090423  0.443
1997 Nakamura H, Aoyagi K, Singaram B, Cai J, Nemoto H, Yamamoto Y. A novel [3+2] annelation between ortho-carboranyltrimethylsilane and conjugated carbonyl compounds Angewandte Chemie - International Edition in English. 36: 367-369.  0.275
1996 Cai J, Nemoto H, Nakamura H, Singaram B, Yamamoto Y. Tetrabutylammonium Fluoride Promoted Regiospecific Reactions of Trimethylsilyl-o-Carborane with Aldehydes Chemistry Letters. 25: 791-792. DOI: 10.1246/Cl.1996.791  0.518
1996 Singaram B, Jackson TC, Harrison J. Synthesis of Alkylborohydrides by Addition of Alkoxides, Amides and Thiolates to the Corresponding Alkylboranes Synlett. 1996: 383-384. DOI: 10.1055/S-1996-5425  0.471
1996 Ramachandran PV, Rangaishenvi MV, Singaram B, Goralski CT, Brown HC. Organoboranes for Synthesis. 16. A Convenient Synthesis of Enantiomerically Pure Isopinocampheylamine, a Chiral Derivatizing Agent for Gas Chromatographic Analysis of Optically Active Carboxylic Acids The Journal of Organic Chemistry. 61: 341-345. DOI: 10.1021/Jo9512158  0.534
1996 Cai J, Nemoto H, Singaram B, Yamamoto Y. Facile reaction of o-carboranyllithium reagents with functionalized alkyl halides Tetrahedron Letters. 37: 3383-3386. DOI: 10.1016/0040-4039(96)00552-7  0.534
1996 Nicholson LW, Pfeiffer CD, Goralski CT, Singaram B. High-performance liquid chromatographic separation of β-amino alcohols II. Separation of trans-2-(dialkylamino)cyclohexanols on an amylose-based chiral stationary phase Journal of Chromatography A. 719: 315-320. DOI: 10.1016/0021-9673(95)00736-9  0.43
1996 Cai J, Nemoto H, Nakamura H, Singaram B, Yamamoto Y. Tetrabutylammonium fluoride promoted regiospecific reactions of trimethylsilyl-o-carborane with aldehydes Chemistry Letters. 791-792.  0.32
1996 Godjoian G, Fisher GB, Goralski CT, Singaram B. Synthesis, Characterization, and Synthetic Utility of Lithium Aminoborohydrides. A New Class of Powerful, Selective, Air-Stable Reducing Agents Acs Symposium Series. 641: 153-166.  0.285
1996 Ramachandran PV, Rangaishenvi MV, Singaram B, Goralski CT, Brown HC. Organoboranes for synthesis. 16. A convenient synthesis of enantiomerically pure isopinocampheylamine, a chiral derivatizing agent for gas chromatographic analysis of optically active carboxylic acids Journal of Organic Chemistry. 61: 341-345.  0.365
1995 Fisher GB, Goralski CT, Nicholson LW, Hasha DL, Zakett D, Singaram B. Boranes in synthesis. 5. The hydroboration of enamines with mono- and dialkylboranes. Asymmetric synthesis of β-amino alcohols of moderate enantiomeric purity from aldehyde enamines Journal of Organic Chemistry. 60: 2026-2034. DOI: 10.1021/Jo00112A026  0.489
1995 Harris CE, Lee LY, Dorr H, Singaram B. A facile dehomologation of α-substituted aldehydes to the corresponding ketones Tetrahedron Letters. 36: 2921-2924. DOI: 10.1016/0040-4039(95)00467-Q  0.371
1995 Alvarez SG, Fisher GB, Singaram B. Aminoborohydrides. 8. A facile reduction of aliphatic and benzylic azides to the corresponding amines in high yield and purity using lithium N,N-dimethylaminoborohydride Tetrahedron Letters. 36: 2567-2570. DOI: 10.1016/0040-4039(95)00341-9  0.464
1994 Harris CE, Fisher GB, Beardsley D, Lee L, Goralski CT, Nicholson LW, Singaram B. Boranes in Synthesis. 6. A New Synthesis of .beta.-Amino Alcohols from Epoxides. Use of Lithium Amides and Aminoborane Catalysts To Synthesize .beta.-Amino Alcohols from Terminal and Internal Epoxides in High Yield Journal of Organic Chemistry. 59: 7746-7751. DOI: 10.1021/Jo00104A034  0.455
1994 Harrison J, Alvarez SG, Godjoian G, Singaram B. Aminoborohydrides. 7. A general synthesis of alkyl-substituted borohydrides from the corresponding organoborane by means of lithium hydride transfer from lithium aminoborohydride Journal of Organic Chemistry. 59: 7193-7194. DOI: 10.1021/Jo00103A004  0.467
1994 Belisle CM, Young YM, Singaram B. Catalytic reaction. 1. catalytic 1,4-hydrogenation of α,β-unsaturated aldehydes and ketones using SC-1 nickel boride Tetrahedron Letters. 35: 5595-5598. DOI: 10.1016/S0040-4039(00)77255-8  0.481
1994 Harrison J, Fuller JC, Goralski CT, Singaram B. Aminoborohydrides. 5. Reduction of alkylcyclohexanones to the corresponding alcohols with unique steric selectivity Tetrahedron Letters. 35: 5201-5204. DOI: 10.1016/S0040-4039(00)77063-8  0.474
1994 Goralski CT, Hasha DL, Nicholson LW, Singaram B. Boranes in synthesis. 4. Hydroboration of enamines derived from 2-norbornanone. Synthesis of endo-3-(dialkylamino)-exo-2-norbornanols and endo-2-(dialkylamino)norbornanes Tetrahedron Letters. 35: 5165-5168. DOI: 10.1016/S0040-4039(00)77054-7  0.36
1994 Goralski CT, Hasha DL, Nicholson LW, Zakett D, Fisher GB, Singaram B. Boranes in synthesis. 3. Conversion of the morpholine and pyrrolidine enamines of symmetrical dialkylketones to the corresponding threo-β-amino alcohols via hydroboration/oxidation Tetrahedron Letters. 35: 3251-3254. DOI: 10.1016/S0040-4039(00)76877-8  0.356
1994 Fuller JC, Stangeland EL, Jackson TC, Singaram B. Lithium aluminum hydride-N-methylpyrrolidine complex. 1. Synthesis and reactivity of lithium aluminum hydride-N-methyplyrrolidine complex. An air and thermally stable reducing agent derived from lithium aluminum hydride Tetrahedron Letters. 35: 1515-1518. DOI: 10.1016/S0040-4039(00)76746-3  0.489
1994 Beardsley DA, Fisher GB, Goralski CT, Nicholson LW, Singaram B. Boranes in synthesis. 2. Asymmetric synthesis of β-amino alcohols. A facile conversion of 2-amino acetophenones to the corresponding β-amino alcohols in high enantiomeric purity Tetrahedron Letters. 35: 1511-1514. DOI: 10.1016/S0040-4039(00)76745-1  0.491
1994 Fuller JC, Belisle CM, Goralski CT, Singaram B. Aminoborohydrides. 6. Diastereoselective reduction of the carbon-nitrogen double bond in chiral imines using lithium diethylaminoborohydride and lithium diisopropylaminoborohydride Tetrahedron Letters. 35: 5389-5392. DOI: 10.1016/S0040-4039(00)73507-6  0.492
1994 Fuller JC, Williamson SM, Singaram B. Reduction of α,β-unsaturated carbonyl compounds with sodium borohydride in the diethyl ether/methanol/pentafluorophenol solvent system. Use of N, N, N', N'-tetramethylethylenediamine and 1-hexene as borane scavengers Journal of Fluorine Chemistry. 68: 265-268. DOI: 10.1016/0022-1139(93)05005-L  0.457
1994 Fuller JC, Karpinski ML, Williamson SM, Singaram B. A fluorine-mediated boron reducing agent - sodium tris(pentafluorophenoxy)borohydride. Preparation and reaction with selected organic compounds containing representative functional groups. Facile diastereoselective reduction of substituted cyclohexanones [1] Journal of Fluorine Chemistry. 66: 123-128. DOI: 10.1016/0022-1139(93)03007-9  0.521
1994 Nicholson LW, Pfeiffer CD, Goralski CT, Singaram B, Fisher GB. High-performance liquid chromatographic separation of β-amino alcohols. I. Separation of (R,S)-1-(dialkylamino)-2-alkanols on an amylose-based chiral stationary phase Journal of Chromatography A. 687: 241-248. DOI: 10.1016/0021-9673(94)00795-0  0.421
1994 Harris CE, Fisher GB, Beardsley D, Lee L, Goralski CT, Nicholson LW, Singaram B. Boranes in synthesis. 6. A new synthesis of β-amino alcohols from epoxides. Use of lithium amides and aminoborane catalysts to synthesize β-amino alcohols from terminal and internal epoxides in high yield Journal of Organic Chemistry. 59: 7746-7751.  0.392
1994 Fisher GB, Fuller JC, Harrison J, Alvarez SG, Burkhardt ER, Goralski CT, Singaram B. Aminoborohydrides. 4. The synthesis and characterization of lithium aminoborohydrides: A new class of powerful, selective, air-stable reducing agents Journal of Organic Chemistry. 59: 6378-6385.  0.272
1993 Fisher GB, Juarez-Brambila JJ, Gorakki CT, Wipke WT, Singaram B. Novel conversion of aldehydes to boronic esters. Simultaneous IGOR2 computer generation and experimental observation of an unusual rearrangement of 0α-aminoboranes Journal of the American Chemical Society. 115: 440-444. DOI: 10.1021/Ja00055A012  0.439
1993 Nguyen T, Sherman D, Ball D, Solow M, Singaram B. Enantiospecific synthesis of N-benzyl-2-alkyl pyrrolidines and piperidines mediated by chiral organoborane reagents Tetrahedron: Asymmetry. 4: 189-192. DOI: 10.1016/S0957-4166(00)82334-4  0.464
1993 Fisher GB, Fuller JC, Harrison J, Goralski CT, Singaram B. Aminoborohydrides. 3. A facile reduction of tertiary amides to the corresponding amines and alcohols in high purity using lithium aminoborohydrides. Sterically controlled selective CN or CO bond cleavage Tetrahedron Letters. 34: 1091-1094. DOI: 10.1016/S0040-4039(00)77498-3  0.495
1993 Fisher GB, Goralski CT, Nicholson LW, Singaram B. Boranes in Synthesis. 1. Asymmetric synthesis of β-amino alcohols. A facile conversion of enamines to the corresponding β-amino alcohols in high enantiomeric purity Tetrahedron Letters. 34: 7693-7696. DOI: 10.1016/S0040-4039(00)61541-1  0.368
1993 Fuller JC, Stangeland EL, Goralski CT, Singaram B. Aminoborohydrides. 2. Regiospecific reductions of α,β-unsaturated carbonyl compounds with lithium pyrrolidinoborohydride. A facile conversion of α,β-unsaturated aldehydes and ketones to the corresponding allylic alcohols in high purity Tetrahedron Letters. 34: 257-260. DOI: 10.1016/S0040-4039(00)60561-0  0.493
1993 Pelter A, Buss D, Colclough E, Singaram B. Hindered organoboron groups in organic chemistry. 23. The interactions of dimesitylboron stabilised carbanions with aromatic ketones and aldehydes to give alkenes Tetrahedron. 49: 7077-7103. DOI: 10.1016/S0040-4020(01)87981-3  0.702
1993 Hubbard JL, Fuller JC, Jackson TC, Singaram B. Reaction of trialkylboranes with sodium diethyldihydroaluminate in the presence of 1,4-diazabicyclo[2.2.2]octane. a convenient, general method for preparation of sodium trialkylborohydrides Tetrahedron. 49: 8311-8316. DOI: 10.1016/S0040-4020(01)81914-1  0.474
1993 Pelter A, Singaram B, Warren L, Wilson JW. Hindered organoboron groups in organic chemistry. 18. The production of boron stabilised carbanions Tetrahedron. 49: 2965-2978. DOI: 10.1016/S0040-4020(01)80391-4  0.596
1992 Inbasekaran V, Singaram B. Giant sized oligodendroglioma of posterior fossa. Journal of the Indian Medical Association. 90: 246, 248. PMID 1460319  0.163
1992 Brown HC, Dhar RK, Ganesan K, Singaram B. Enolboration. 2. Dicyclohexylchloroborane/triethylamine as a convenient reagent for regio- and stereoselective enolboration of representative classes of ketones The Journal of Organic Chemistry. 57: 2716-2721. DOI: 10.1021/Jo00035A033  0.564
1992 Joshi NN, Pyun C, Mahindroo VK, Singaram B, Brown HC. Chiral synthesis via organoboranes. 33. The controlled reaction of B-alkyldiisopinocampheylboranes with aldehydes providing a convenient procedure for the enantiomeric enrichment of the boronic ester products through kinetic resolution The Journal of Organic Chemistry. 57: 504-511. DOI: 10.1021/Jo00028A021  0.59
1992 Brown HC, Dhar RK, Ganesan K, Singaram B. Enolboration. 1. Dicyclohexylchloroborane/triethylamine as a convenient reagent for enolboration of ketones and other carbonyl derivatives The Journal of Organic Chemistry. 57: 499-504. DOI: 10.1021/Jo00028A020  0.573
1992 Golden JH, Schreier C, Singaram B, Williamson SM. Disproportionation of alkoxyborohydrides: A 11B NMR study of the reaction between sodium borohydride and fluorinated alcohols and phenols. The preparation of tris(fluoroalkoxy)- and tris(fluorophenoxy)borohydrides Inorganic Chemistry. 31: 1533-1535. DOI: 10.1021/Ic00034A041  0.472
1992 Fisher GB, Harrison J, Fuller JC, Goralski CT, Singaram B. Synthesis and characterization of lithium aminoborohydrides: A new class of powerful reducing agents Tetrahedron Letters. 33: 4533-4536. DOI: 10.1016/S0040-4039(00)61305-9  0.265
1992 Singaram B. Facile and convenient synthesis of B‐amino‐9‐borabicyclo[3.3.1]nonanes. Aminoboration of lsocyanates Heteroatom Chemistry. 3: 245-249. DOI: 10.1002/Hc.520030309  0.482
1992 Brown HC, Dhar RK, Ganesan K, Singaram B. Enolboration. 1. Dicyclohexylchloroborane/triethylamine as a convenient reagent for enolboration of ketones and other carbonyl derivatives Journal of Organic Chemistry. 57: 499-504.  0.419
1992 Joshi NN, Pyun C, Mahindroo VK, Singaram B, Brown HC. Chiral synthesis via organoboranes. 33. The controlled reaction of B-alkyldiisopinocampheylboranes with aldehydes providing a convenient procedure for the enantiomeric enrichment of the boronic ester products through kinetic resolution Journal of Organic Chemistry. 57: 504-511.  0.4
1992 Brown HC, Dhar RK, Ganesan K, Singaram B. Enolboration. 2. Dicyclohexylchloroborane/triethylamine as a convenient reagent for regio- and stereoselective enolboration of representative classes of ketones Journal of Organic Chemistry. 57: 2716-2721.  0.333
1991 Rangaishenvi MV, Singaram B, Brown HC. Chiral synthesis via organoboranes. 30. Facile synthesis, by the Matteson asymmetric homologation procedure, of .alpha.-methyl boronic acids not available from asymmetric hydroboration and their conversion into the corresponding aldehydes, ketones, carboxylic acids, and amines of high enantiomeric purity Journal of Organic Chemistry. 56: 3286-3294. DOI: 10.1021/Jo00010A022  0.606
1991 Singaram B, Rangaishenvi MV, Brown HC, Goralski CT, Hasha DL. Hydroboration. 86. Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes Journal of Organic Chemistry. 56: 1543-1549. DOI: 10.1021/Jo00004A038  0.599
1991 Brown HC, Mahindroo VK, Bhat NG, Singaram B. Chiral synthesis via organoboranes. 29. A general synthesis of .alpha.-chiral monosubstituted acetylenes and their trimethylsilyl derivatives from enantiomerically pure boronic esters The Journal of Organic Chemistry. 56: 1500-1505. DOI: 10.1021/Jo00004A030  0.568
1991 Brown HC, Salunkhe AM, Singaram B. Chiral synthesis via organoboranes. 28. Reaction of .alpha.-chiral organyldichloroboranes with organyl azides providing a synthesis of secondary amines with exceptionally high enantiomeric purities The Journal of Organic Chemistry. 56: 1170-1175. DOI: 10.1021/Jo00003A046  0.569
1991 Singaram B, Goralski CT, Fisher GB. Unusual directive effects in the hydroboration of β,β-disubstituted enamines. Conversion of α-substituted aldehydes to the corresponding alkenes and β-amino alcohols Journal of Organic Chemistry. 56: 5691-5696.  0.321
1991 Brown HC, Mahindroo VK, Bhat NG, Singaram B. Chiral synthesis via organoboranes. 29. A general synthesis of aα-chiral monosubstituted acetylenes and their trimethylsilyl derivatives from enantiomerically pure boronic esters Journal of Organic Chemistry. 56: 1500-1505.  0.399
1991 Brown HC, Salunkhe AM, Singaram B. Chiral synthesis via organoboranes. 28. Reaction of α-chiral organyldichloroboranes with organyl azides providing a synthesis of secondary amines with exceptionally high enantiomeric purities Journal of Organic Chemistry. 56: 1170-1175.  0.429
1991 Singaram B, Rangaishenvi MV, Brown HC, Goralski CT, Hasha DL. Hydroboration. 86. Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either (Z)- or (E)-alkenes Journal of Organic Chemistry. 56: 1543-1549.  0.374
1991 Rangaishenvi MV, Singaram B, Brown HC. Chiral synthesis via organoboranes. 30. Facile synthesis, by the Matteson asymmetric homologation procedure, of α-methyl boronic acids not available from asymmetric hydroboration and their conversion into the corresponding aldehydes, ketones, carboxylic acids, and amines of high enantiomeric purity Journal of Organic Chemistry. 56: 3286-3294.  0.444
1989 Brown HC, Dhar RK, Bakshi RK, Pandiarajan PK, Singaram B. Major effect of the leaving group in dialkylboron chlorides and triflates in controlling the stereospecific conversion of ketones into either [E]- or [Z]-enol borinates Journal of the American Chemical Society. 111: 3441-3442. DOI: 10.1021/Ja00191A058  0.46
1989 Brown HC, Joshi NN, Pyun C, Singaram B. Chiral synthesis via organoboranes. 20. Conversion of boronic esters of essentially 100% optical purity to B-alkyl-9-borabicyclo[3.3.1]nonanes of very high optical purity. Synthesis of optically active homologated esters, nitriles, and ketones Journal of the American Chemical Society. 111: 1754-1758. DOI: 10.1021/Ja00187A030  0.509
1989 Singaram B, Goralski CT, Rangaishenvi MV, Brown HC. Convenient conversion of aldehydes and ketones into the corresponding alkenes via hydroboration of their enamines. A remarkably simple synthesis of either [Z]- or [E]-alkenes Journal of the American Chemical Society. 111: 384-386. DOI: 10.1021/Ja00183A068  0.462
1989 BROWN HC, JOSHI NN, PYUN C, SINGARAM B. ChemInform Abstract: Chiral Synthesis via Organoboranes. Part 20. Conversion of Boronic Esters of Essentially 100% Optical Purity to B-Alkyl-9-borabicyclo(3.3.1)nonanes of Very High Optical Purity. Synthesis of Optically Active Homologated Esters, Nitrile Cheminform. 20. DOI: 10.1002/chin.198923060  0.438
1989 Brown HC, Joshi NN, Pyun C, Singaram B. Chiral synthesis via organoboranes. 20. Conversion of boronic esters of essentially 100% optical purity to B-alkyl-9-borabicyclo[3.3.1]nonanes of very high optical purity. Synthesis of optically active homologated esters, nitriles, and ketones Journal of the American Chemical Society. 111: 1754-1758.  0.331
1989 Brown HC, Dhar RK, Bakshi RK, Pandiarajan PK, Singaram B, Wetherill RB. Major effect of the leaving group in dialkylboron chlorides and triflates in controlling the stereospecific conversion of ketones into either (E)- or (Z)-enol borinates Journal of the American Chemical Society. 111: 3441-3442.  0.286
1988 Brown HC, Bakshi RK, Singaram B. Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities Journal of the American Chemical Society. 110: 1529-1534. DOI: 10.1021/Ja00213A028  0.549
1988 Brown HC, Singaram B. The development of a simple general procedure for synthesis of pure enantiomers via chiral organoboranes Accounts of Chemical Research. 21: 287-293. DOI: 10.1021/Ar00152A001  0.521
1988 Brown HC, Singaram B. Substitution with retention in organoboranes and utilization of the phenomenon for a general synthesis of pure enantiomers Proceedings of the Indian Academy of Sciences - Chemical Sciences. 100: 119-142. DOI: 10.1007/BF02839445  0.485
1988 Brown HC, Bakshi RK, Singaram B. Chiral synthesis via organoboranes. 12. Conversion of boronic esters of essentially 100% optical purity into monoalkylthexylboranes providing convenient synthetic routes to trans-olefins, cis-olefins, alkynes, and ketones of very high enantiomeric purities Journal of the American Chemical Society. 110: 1529-1534.  0.386
1988 Brown HC, Singaram B. Development of a simple general procedure for synthesis of pure enantiomers via chiral organoboranes Accounts Chemical Research. 21: 287-293.  0.347
1987 Brown HC, Singaram B. Organoboranes for synthesis—substitution with retention Pure and Applied Chemistry. 59: 879-894. DOI: 10.1351/Pac198759070879  0.311
1987 Goralski CT, Singaram B, Brown HC. Hydroboration. 81. Synthesis of 2-(dialkylamino)boronic esters and acids via hydroboration of enamines. A convenient preparation of .beta.-dialkylamino alcohols Journal of Organic Chemistry. 52: 4014-4019. DOI: 10.1021/Jo00227A014  0.549
1987 Goralski CT, Singaram B, Brown HC. Hydroboration. 81. Synthesis of 2-(dialkylamino)boronic esters and acids via hydroboration of enamines. A convenient preparation of β-dialkylamino alcohols Journal of Organic Chemistry. 52: 4014-4019.  0.405
1986 Cole TE, Bakshi RK, Srebnik M, Singaram B, Brown HC. Organoboranes. 49. An examination of convenient procedures for the generation of borane and monoalkyl- and dialkylboranes from lithium borohydride and monoalkyl- and dialkylborohydrides Organometallics. 5: 2303-2307. DOI: 10.1021/Om00142A021  0.461
1986 Brown HC, Kim KW, Cole TE, Singaram B. Chiral synthesis via organoboranes. 8. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of primary amines of very high enantiomeric purities Journal of the American Chemical Society. 108: 6761-6764. DOI: 10.1021/Ja00281A050  0.55
1986 BROWN HC, NAIK RG, BAKSHI RK, PYUN C, SINGARAM B. ChemInform Abstract: Chiral Synthesis via Organoboranes. Part 4. Synthetic Utility of Boronic Esters of Essentially 100% Optical Purity. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198627226  0.538
1986 BROWN HC, IMAI T, PERUMAL PT, SINGARAM B. ChemInform Abstract: Organoboranes. Part 41. Reaction of Organoboranes with (Dichloromethyl)lithium. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198610291  0.529
1986 BROWN HC, NAIK RG, SINGARAM B, PYUN C. ChemInform Abstract: Organoboranes. Part 42. One-Carbon Homologation of Organoboranes. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198609196  0.427
1986 Brown HC, Kim KW, Cole TE, Singaram B. Chiral synthesis via organoboranes. 8. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of primary amines of very high enantiomeric purities Journal of the American Chemical Society. 108: 6761-6764.  0.388
1986 Cole TE, Bakshi RK, Srebnik M, Singaram B, Brown HC. Organoboranes. 49. An examination of convenient procedures for the generation of borane and monoalkyl- and dialkylboranes from lithium borohydride and monoalkyl- and dialkylborohydrides Organometallics. 5: 2303-2307.  0.265
1985 Brown HC, Naik RG, Singaram B, Pyun C. Organoboranes. 42. One-carbon homologation of organoboranes. Synthesis of homologated boronic acids and esters from boronic esters Organometallics. 4: 1925-1929. DOI: 10.1021/Om00130A002  0.534
1985 Brown HC, Naik RG, Bakshi RK, Pyun C, Singaram B. Chiral synthesis via organoboranes. 4. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of homologated boronic acids and esters of very high enantiomeric purities The Journal of Organic Chemistry. 50: 5586-5592. DOI: 10.1021/Jo00350A031  0.571
1985 Brown HC, Imai T, Perumal PT, Singaram B. Organoboranes. 41. Reaction of organoboranes with (dichloromethyl)lithium. Scope and limitations. Synthesis of homologated primary and secondary alcohols Journal of Organic Chemistry. 50: 4032-4036. DOI: 10.1021/Jo00221A014  0.55
1985 Brown HC, Imai T, Desai MC, Singaram B. Chiral synthesis via organoboranes. 3. Conversion of boronic esters of essentially 100% optical purity to aldehydes, acids, and homologated alcohols of very high enantiomeric purities Journal of the American Chemical Society. 107: 4980-4983. DOI: 10.1021/Ja00303A026  0.514
1985 Brown HC, Singaram B, Cole TE. Chiral synthesis via organoboranes. 2. Rapid reaction of boronic esters of very high optical purity with lithium aluminum hydride. Facile reaction of essentially optically pure borinic esters with lithium monoethoxyaluminohydride. A novel and quantitative synthesis of lithium monoalkyl- and dialkylborohydrides of essentially 100% optical purity Journal of the American Chemical Society. 107: 460-464. DOI: 10.1021/Ja00288A031  0.542
1985 Brown HC, Imai T, Desai MC, Singaram B. Chiral Synthesis Via Organoboranes. 3. Conversion Of Boronic Esters Of Essentially 100% Optical Purity To Aldehydes, Acids, And Homologated Alcohols Of Very High Enantiomeric Purities Cheminform. 16. DOI: 10.1002/Chin.198549234  0.574
1985 BROWN HC, SINGARAM B, COLE TE. ChemInform Abstract: CHIRAL SYNTHESIS VIA ORGANOBORANES. 2. RAPID REACTION OF BORONIC ESTERS OF VERY HIGH OPTICAL PURITY WITH LITHIUM ALUMINUM HYDRIDE. FACILE REACTION OF ESSENTIALLY OPTICALLY PURE BORINIC ESTERS WITH LITHIUM MONOETHOXYALUMINOHYDRIDE. A N Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198521284  0.56
1985 SINGARAM B, COLE TE, BROWN HC. ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI-METAL HYDRIDES. 25. FACILE REACTION OF BORINIC ESTERS WITH LITHIUM MONOETHOXYALUMINOHYDRIDE TO FORM LITHIUM DIALKYLBOROHYDRIDES Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198504239  0.523
1985 Brown HC, Imai T, Perumal PT, Singaram B. Organoboranes. 41. Reaction of organoboranes with (dichloromethyl)lithium. Scope and limitations. Synthesis of homologated primary and secondary alcohols Journal of Organic Chemistry. 50: 4032-4036.  0.385
1985 Brown HC, Naik RG, Singaram B, Pyun C. Organoboranes. 42. One-carbon homologation of organoboranes. Synthesis of homologated boronic acids and esters from boronic esters Organometallics. 4: 1925-1929.  0.366
1985 Brown HC, Naik RG, Bakshi RK, Pyun C, Singaram B. Chiral synthesis via organoboranes. 4. Synthetic utility of boronic esters of essentially 100% optical purity. Synthesis of homologated boronic acids and esters of very high enantiomeric purities Journal of Organic Chemistry. 50: 5586-5592.  0.416
1985 Brown HC, Singaram B, Cole TE. Chiral synthesis via organoboranes. 2. Rapid reaction of boronic esters of very high optical purity with lithium aluminum hydride. Facile reaction of essentially optically pure borinic esters with lithium monoethoxyaluminohydride. A novel and quantitative synthesis of lithium monoalkyl- and dialkylborohydrides of essentially 100% optical purity Journal of the American Chemical Society. 107: 460-464.  0.377
1985 Brown HC, Imai T, Desai MC, Singaram B. Chiral synthesis via organoboranes. 3. Conversion of boronic esters of essentially 100% optical purity to aldehydes, acids, and homologated alcohols of very high enantiomeric purities Journal of the American Chemical Society. 107: 4980-4983.  0.42
1984 Singaram B, Cole TE, Brown HC. Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides Organometallics. 3: 774-777. DOI: 10.1021/Om00083A022  0.561
1984 Brown HC, Singaram B. Improved procedures for the synthesis of diisopinocampheylborane of high optical purity The Journal of Organic Chemistry. 49: 945-947. DOI: 10.1021/Jo00179A041  0.475
1984 Brown HC, Singaram B. Hydroboration. 68. Chiral synthesis via organoboranes. 1. A simple procedure to achieve products of essentially 100% optical purity in hydroboration of alkenes with monoisopinocampheylborane. Synthesis of boronic esters and derived products of very high enantiomeric purities Journal of the American Chemical Society. 106: 1797-1800. DOI: 10.1021/Ja00318A040  0.535
1984 Molander GA, Singaram B, Brown HC. Conjugate addition-elimination in the reaction of B-1-alkenyl-9-borabicyclo[3.3.1]nonanes with 4-methoxy-3-buten-2-one. A convenient new route to conjugated dienones The Journal of Organic Chemistry. 49: 5024-5025. DOI: 10.1002/Chin.198519153  0.632
1984 Singaram B, Cole TE, Brown HC. Addition compounds of alkali-metal hydrides. 26. Facile reaction of borinic esters with lithium monoethoxyaluminohydride to form lithium dialkylborohydrides Organometallics. 3: 1520-1523.  0.34
1984 Brown HC, Singaram B. Improved procedures for the synthesis of diisopinocampheylborane of high optical purity Journal of Organic Chemistry. 49: 945-947.  0.285
1984 Molander GA, Singaram B, Brown HC. Conjugate addition-elimination in the reaction of B-1-alkenyl-9-borabicyclo[3.3.1]nonanes with 4-methoxy-3-buten-2-one. A convenient new route to conjugated dienones Journal of Organic Chemistry. 49: 5024-5025.  0.365
1984 Singaram B, Cole TE, Brown HC. Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides Organometallics. 3: 774-777.  0.403
1984 Brown HC, Singaram B. Chiral synthesis via organoboranes. 1. A simple procedure to achieve products of essentially 100% optical purity in hydroboration of alkenes with monoisopinocampheylborane. Synthesis of boronic esters and derived products of very high enantiomeric purities Journal of the American Chemical Society. 106: 1797-1800.  0.367
1983 Garad MV, Pelter A, Singaram B, Wilson JW. The dimesitylboron group in organic synthesis. 5. Hetero-atom substituted dimesitylborylmethanes Tetrahedron Letters. 24: 637-638. DOI: 10.1016/S0040-4039(00)81485-9  0.668
1983 Pelter A, Singaram B, Wilson JW. The dimesitylboron group in organic synthesis. 4. The 'boron Wittig' reaction Tetrahedron Letters. 24: 635-636. DOI: 10.1016/S0040-4039(00)81484-7  0.71
1983 Pelter A, Singaram B, Wilson JW. The dimesitylboron group in organic synthesis. 3. Reactions of allyldimesitylborane Tetrahedron Letters. 24: 631-634. DOI: 10.1016/S0040-4039(00)81483-5  0.711
1983 Pelter A, Singaram B, Williams L, Wilson JW. The dimesitylboron group in organic synthesis 1. Introduction Tetrahedron Letters. 24: 623-626. DOI: 10.1016/S0040-4039(00)81481-1  0.654
1983 PELTER A, SINGARAM B, WILLIAMS L, WILSON JW. ChemInform Abstract: The Dimesitylboron Group in Organic Synthesis. Part 1. Introduction. Part 2. The C-Alkylation of Alkyldimesitylboranes. Part 3. Reactions of Allyldimesitylborane. Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198323269  0.681
1983 PELTER A, SINGARAM B, WILSON JW, GARAD MV, PELTER A, SINGARAM B, WILSON JW. ChemInform Abstract: The Dimesitylboron Group in Organic Synthesis. Part 4. The "Boron Wittig" Reaction. The Dimesitylboron Group in Organic Synthesis. Part 5. Hetero-atom Substituted Dimesitylborylmethanes. Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198323268  0.67
1983 Pelter A, Singaram B. The reactions of furfuryl alcohols with maleic anhydride Journal of the Chemical Society, Perkin Transactions 1. 1383-1386.  0.648
1982 Brown HC, Mandal AK, Yoon NM, Singaram B, Schwier JR, Jadhav PK. Organoboranes. 27. Exploration of synthetic procedures for the preparation of monoisopinocampheylborane The Journal of Organic Chemistry. 47: 5069-5074. DOI: 10.1021/Jo00147A005  0.467
1982 Peter A, Singaram B. Reactions of furfuryl alcohols with maleic anhydride Tetrahedron Letters. 23: 245-248. DOI: 10.1016/S0040-4039(00)86798-2  0.445
1982 Brown HC, Singaram B, Singaram S. Investigations in the synthesis of alkyl-substituted borohydrides Journal of Organometallic Chemistry. 239: 43-64. DOI: 10.1016/S0022-328X(00)94102-0  0.56
1982 BROWN HC, SINGARAM B, MATHEW PC. ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI-METAL HYDRIDES. 21. RAPID REACTION OF DIALKYL- AND MONOALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM DIALKYL- AND MONOALKY Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198219281  0.536
1982 Brown HC, Mandai AK, Yoon NM, Singaram B, Schwier JR, Jadhav PK. Organoboranes. 27. Exploration of synthetic procedures for the preparation of monoisopinocampheylborane Journal of Organic Chemistry. 47: 5069-5074.  0.645
1981 Brown HC, Singaram B, Mathew PC. Addition compounds of alkali-metal hydrides. 21. Rapid reaction of dialkyl- and monoalkylboranes with lithium aluminum hydride in the presence of triethylenediamine. A facile and quantitative synthesis of lithium dialkyl- and monoalkylborohydrides The Journal of Organic Chemistry. 46: 4541-4544. DOI: 10.1021/Jo00335A044  0.53
1981 Brown HC, Singaram B, Mathew CP. Addition compounds of alkali metal hydrides. 20. Reaction of representative mono- and dialkylboranes with saline hydrides to form the corresponding alkylborohydrides The Journal of Organic Chemistry. 46: 2712-2717. DOI: 10.1021/Jo00326A022  0.497
1981 Brown HC, Hubbard JL, Singaram B. Addition compounds of alkali metal hydrides-XIX1 1 Part XVIII in this series: see Ref 16. Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylene-diamine. A facile and quantitative synthesis of lithium trialkylborohydrides, including derivatives with exceptionally large steric requirements Tetrahedron. 37: 2359-2362. DOI: 10.1016/S0040-4020(01)88889-X  0.514
1981 BROWN HC, HUBBARD JL, SINGARAM B. ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI METAL HYDRIDES. XIX. RAPID REACTION OF TRIALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM TRIALKYLBOROHYDRIDES, INCLUDING DE Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198141232  0.534
1981 SINGARAM B, MOLANDER GA, BROWN HC. ChemInform Abstract: REACTION OF B-(1-ALKENYL)-DIALKYLBORANES WITH ISOCYANATES Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198120182  0.609
1981 Brown HC, Singaram B, Mathew PC. Addition compounds of alkali-metal hydrides. 21. Rapid reaction of dialkyl- and monoalkylboranes with lithium aluminum hydride in the presence of triethylenediamine. A facile and quantitative synthesis of lithium dialkyl- and monoalkylborohydrides Journal of Organic Chemistry. 46: 4541-4544.  0.36
1981 Brown HC, Singaram B, Mathew CP. Addition compounds of alkali metal hydrides. 20. Reaction of representative mono- and dialkylboranes with saline hydrides to form the corresponding alkylborohydrides Journal of Organic Chemistry. 46: 2712-2717.  0.315
1980 Brown HC, Singaram B. Molecular addition compounds. 7. Synthesis of addition compounds of boron trifluoride, borane, and alane with N,N,N'N'-tetramethylethylenediamine and triethylenediamine by precipitation from ether solvents Inorganic Chemistry. 19: 455-457. DOI: 10.1021/ic50204a034  0.4
1980 Brown HC, Singaram B. Molecular addition compounds. 7. Synthesis of addition compounds of boron trifluoride, borane, and alane with N,N,N′,N′-tetramethylethylenediamine and triethylenediamine by precipitation from ether solvents Inorganic Chemistry. 19: 455-457.  0.307
1979 Brown HC, Hubbard JL, Singaram B. Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylenediamine. Facile and quantitative synthesis of lithium trialkylborohydrides including derivatives with exceptionally large steric requirements The Journal of Organic Chemistry. 44: 5004-5005. DOI: 10.1021/Jo00394A067  0.568
1979 BROWN HC, SINGARAM B. ChemInform Abstract: MOLECULAR ADDITION COMPOUNDS. 6. ADDITION COMPOUNDS OF ETHYLENEDIAMINE WITH BORON TRIFLUORIDE AND DIALKYLBORANES Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197915291  0.377
1979 Brown HC, Schwier JR, Singaram B. An improved synthesis of monoalkylborane derivatives via bis(thexylborane)-N,N,N,N-tetramethylethylenediamine Journal of Organic Chemistry. 44: 465-466.  0.254
1979 Brown HC, Singaram B, Schwier JR. Molecular addition compounds. 5. Interaction of N,N,N′,N′-tetramethylethylenediamine with boron trifluoride and monoalkylboranes Inorganic Chemistry. 18: 51-53.  0.249
1979 Brown HC, Singaram B. Molecular addition compounds. 6. Addition compounds of ethylenediamine with boron trifluoride and dialkylboranes Inorganic Chemistry. 18: 53-55.  0.242
1979 Brown HC, Hubbard JL, Singaram B. Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylenediamine. Facile and quantitative synthesis of lithium trialkylborohydrides including derivatives with exceptionally large steric requirements Journal of Organic Chemistry. 44: 5004-5005.  0.411
1978 Brown HC, Schwier JR, Singaram B. Simple synthesis of monoisopinocampheylborane of high optical purity The Journal of Organic Chemistry. 43: 4395-4397. DOI: 10.1021/Jo00416A042  0.48
1978 Singaram B, Schwier JR. Molecular addition compounds of N,N,N′,N′-tetramethylethylenediamine with boron trifluoride and monoalkylboranes Journal of Organometallic Chemistry. 156: C1-C4. DOI: 10.1016/S0022-328X(00)84886-X  0.249
1978 SINGARAM B, SARASWATHI GN, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES- PART LIII. (-)-CARVOTANACETONE Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197813315  0.769
1978 SINGARAM B, SARASWATHI GN, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES- PART LII. TRANSFORMATIONS OF (.+-.)- AND (+)-SYLVESTRENE E NITROSOCHLORIDES Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197813314  0.751
1978 Brown HC, Schwier JR, Singaram B. Simple synthesis of monoisopinocampheylborane of high optical purity Journal of Organic Chemistry. 43: 4395-4397.  0.292
1977 Carman R, Mathew P, Saraswathi G, Singaram B, Verghese J. Amino oximes from p-Menth-1-ene, Limonene and α-Pinene Australian Journal of Chemistry. 30: 1323. DOI: 10.1071/Ch9771323  0.791
1977 Brecknell D, Carman R, Singaram B, Verghese J. Sylvestrene nitrosochloride and derived amino oximes Australian Journal of Chemistry. 30: 195. DOI: 10.1071/Ch9770195  0.773
1977 SINGARAM B, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES- PART XLII - ADDITION OF NITROSYL CHLORIDE TO (.+-.)-α-TERPINYL ACETATE Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/CHIN.197737313  0.333
1977 SINGARAM B, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES- PART XLVI. SYNTHESIS OF α- AND β-PHELLANDRENES Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/CHIN.197726352  0.302
1976 Singaram B, Verghese J. Studies in terpenoids. Part XLIV. Structure of the adduct from p-mentha-1,5-diene and β-naphthol, and its isomer Journal of the Chemical Society, Perkin Transactions 1. 1254-1257. DOI: 10.1039/P19760001254  0.777
1976 SINGARAM B, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES- PART XL. STEREOCHEMISTRY AND MECHANISM OF THE REACTIONS OF TERPENE HALIDES WITH SILVER NITRATE IN DIMETHYL SULFOXIDE Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/CHIN.197646316  0.367
1974 Carman R, Singaram B, Verghese J. γ-Terpinene nitrosochloride Australian Journal of Chemistry. 27: 909. DOI: 10.1071/Ch9740909  0.759
1974 CARMAN RM, SINGARAM B, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES PART 38, HALOGENATED TERPENOIDS PART 13, GAMMA-TERPINENE NITROSOCHLORIDE Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197429406  0.759
1974 CARMAN RM, SINGARAM B, VERGHESE J. ChemInform Abstract: STUDIES IN TERPENES PART 36, ALPHA-TERPINENE NITROSITE Chemischer Informationsdienst. 5. DOI: 10.1002/Chin.197419426  0.752
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