Gerard (Ged) F.R. Parkin - Publications

Affiliations: 
Columbia University, New York, NY 
Area:
main group and transition metal chemistry
Website:
http://www.columbia.edu/cu/chemistry/groups/parkin/parkin.htm

318 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Sattler W, Shlian DG, Sambade D, Parkin G. Synthesis and structural characterization of bis(2-pyridylthio)(p-tolylthio)methyl zinc complexes and the catalytic hydrosilylation of CO2 Polyhedron. 187: 114542. DOI: 10.1016/J.Poly.2020.114542  0.683
2019 Quinlivan PJ, Chaijan MR, Palmer JH, Shlian DG, Parkin G. Coordination of 1-methyl-1,3-dihydro-2-benzimidazole-2-selone to zinc and cadmium: Monotonic and non-monotonic bond length variations for [H(sebenzim)]MCl complexes (M = Zn, Cd, Hg). Polyhedron. 164: 185-194. PMID 31333278 DOI: 10.1016/J.Poly.2019.01.018  0.45
2019 Quinlivan PJ, Shlian DG, Amemiya E, Parkin G. Reactivity of the carbodiphosphorane, (PhP)C, towards main group metal alkyl compounds: coordination and cyclometalation. Dalton Transactions (Cambridge, England : 2003). 48: 9139-9151. PMID 31145405 DOI: 10.1039/C9Dt00678H  0.409
2019 Fillebeen T, Hascall T, Parkin G. Bis- and Tris(pyrazolyl)hydroborato Ligands with Bulky Triptycyl Substituents: The Synthesis and Structural Characterization of Tl[Bp(Trip)] and Tl[Tp(Trip)]. Inorganic Chemistry. 36: 3787-3790. PMID 11670076 DOI: 10.1021/Ic970259R  0.425
2019 Kimblin C, Parkin G. Comparison of Zinc and Cadmium Coordination Environments in Synthetic Analogues of Carbonic Anhydrase: Synthesis and Structure of {[Pim(Pr)()i(,Bu)()t]Cd(OH(2))(OClO(3))}(ClO(4)). Inorganic Chemistry. 35: 6912-6913. PMID 11666864 DOI: 10.1021/Ic961007D  0.356
2019 Dowling C, Murphy VJ, Parkin G. Bis(pyrazolylethyl) Ether Ligation to Zinc and Cobalt: Meridional vs Facial Coordination and the Suitability of Such Ligands in Providing a NNO Donor Set for Modeling Bioinorganic Aspects of Zinc Chemistry. Inorganic Chemistry. 35: 2415-2420. PMID 11666450 DOI: 10.1021/Ic9512744  0.386
2019 Parkin G. Representation of Three-Center–Two-Electron Bonds in Covalent Molecules with Bridging Hydrogen Atoms Journal of Chemical Education. 96: 2467-2475. DOI: 10.1021/Acs.Jchemed.9B00750  0.355
2019 Rauch M, Roberts RC, Parkin G. Reactivity of [TismPriBenz]MgMe towards secondary amines and terminal alkynes: Catalytic dehydrocoupling with hydrosilanes to afford Si–N and Si–C bonds Inorganica Chimica Acta. 494: 271-279. DOI: 10.1016/J.Ica.2019.03.015  0.412
2018 Rauch M, Parkin G. Insertion of CS into the Mg-H bond: synthesis and structural characterization of the magnesium dithioformate complex, [Tism]Mg(κ-SCH). Dalton Transactions (Cambridge, England : 2003). PMID 29947628 DOI: 10.1039/C8Dt01947A  0.405
2018 Al-Harbi A, Hammond MJ, Parkin G. Organometallic Zirconium Compounds in an Oxygen-Rich Coordination Environment: Synthesis and Structural Characterization of Tris(oxoimidazolyl)hydroboratozirconium Compounds. Inorganic Chemistry. PMID 29314851 DOI: 10.1021/Acs.Inorgchem.7B02832  0.451
2018 Neary MC, Quinlivan PJ, Parkin G. Zerovalent Nickel Compounds Supported by 1,2-Bis(diphenylphosphino)benzene: Synthesis, Structures, and Catalytic Properties. Inorganic Chemistry. 57: 374-391. PMID 29244503 DOI: 10.1021/Acs.Inorgchem.7B02636  0.357
2018 Ruccolo S, Rauch M, Parkin G. Synthesis and Structural Characterization of Tris(isopropylbenzimidazol-2-ylthio)methyl Zinc Complexes, [TitmPriBenz]ZnX: Modulation of Transannular Zn–C Interactions Organometallics. 37: 1708-1718. DOI: 10.1021/Acs.Organomet.8B00158  0.805
2018 Parkin G. Special issue on pincer ligands Polyhedron. 143: 1. DOI: 10.1016/J.Poly.2018.02.019  0.331
2017 Ruccolo S, Rauch M, Parkin G. Tris[(1-isopropylbenzimidazol-2-yl)dimethylsilyl]methyl metal complexes, [Tism]M: a new class of metallacarbatranes, isomerization to a tris(N-heterocyclic carbene) derivative, and evidence for an inverted ligand field. Chemical Science. 8: 4465-4474. PMID 30155219 DOI: 10.1039/C7Sc00499K  0.777
2017 Rauch M, Parkin G. Zinc and Magnesium Catalysts for the Hydrosilylation of Carbon Dioxide. Journal of the American Chemical Society. 139: 18162-18165. PMID 29226678 DOI: 10.1021/Jacs.7B10776  0.367
2017 Al-Harbi A, Kriegel B, Gulati S, Hammond MJ, Parkin G. Bis- and Tris(2-oxobenzimidazolyl)hydroborato Complexes of Sodium and Thallium: New Classes of Bidentate and Tridentate Oxygen Donor Ligands. Inorganic Chemistry. 56: 15271-15284. PMID 29210574 DOI: 10.1021/Acs.Inorgchem.7B02638  0.431
2017 Rauch M, Ruccolo S, Parkin G. Synthesis, Structure, and Reactivity of a Terminal Magnesium Hydride Compound with a Carbatrane Motif, [Tism(Pr(i)Benz)]MgH: A Multifunctional Catalyst for Hydrosilylation and Hydroboration. Journal of the American Chemical Society. PMID 28901762 DOI: 10.1021/Jacs.7B06719  0.795
2017 Quinlivan PJ, Parkin G. Flexibility of the Carbodiphosphorane, (Ph3P)2C: Structural Characterization of a Linear Form. Inorganic Chemistry. 56: 5493-5497. PMID 28430421 DOI: 10.1021/Acs.Inorgchem.7B00381  0.324
2017 Kreider-Mueller A, Quinlivan PJ, Owen JS, Parkin G. Tris(2-mercaptoimidazolyl)hydroborato Cadmium Thiolate Complexes, [Tm(Bu(t))]CdSAr: Thiolate Exchange at Cadmium in a Sulfur-Rich Coordination Environment. Inorganic Chemistry. PMID 28368611 DOI: 10.1021/Acs.Inorgchem.7B00296  0.613
2017 Neary MC, Parkin G. Reactivity of Cyclopentadienyl Molybdenum Compounds towards Formic Acid: Structural Characterization of CpMo(PMe3)(CO)2H, CpMo(PMe3)2(CO)H, [CpMo(μ-O)(μ-O2CH)]2, and [Cp*Mo(μ-O)(μ-O2CH)]2. Inorganic Chemistry. 56: 1511-1523. PMID 28103030 DOI: 10.1021/Acs.Inorgchem.6B02606  0.473
2017 Parkin G. Special issue on tridentate and tetradentate tripodal ligands Polyhedron. 125: 1. DOI: 10.1016/J.Poly.2017.02.021  0.336
2017 Sambade D, Parkin G. Synthesis and structural characterization of tris(pyrazolyl)hydroaluminate and tris(pyrazolyl)hydrogallate lithium compounds Polyhedron. 125: 219-229. DOI: 10.1016/J.Poly.2016.10.043  0.371
2016 Rauch M, Ruccolo S, Mester JP, Rong Y, Parkin G. Synthesis, structure and reactivity of a terminal magnesium fluoride compound, [Tp]MgF: hydrogen bonding, halogen bonding and C-F bond formation. Chemical Science. 7: 142-149. PMID 29861975 DOI: 10.1039/C5Sc03504J  0.796
2016 Chakrabarti N, Ruccolo S, Parkin G. Cadmium Compounds with an [N3C] Atrane Motif: Evidence for the Generation of a Cadmium Hydride Species. Inorganic Chemistry. 55: 12105-12109. PMID 27934411 DOI: 10.1021/Acs.Inorgchem.6B02196  0.774
2016 Green ML, Parkin G. The classification and representation of main group element compounds that feature three-center four-electron interactions. Dalton Transactions (Cambridge, England : 2003). PMID 27845802 DOI: 10.1039/C6Dt03570A  0.54
2016 Rong Y, Sambade D, Parkin G. Molecular structures of tris(1-tert-butyl-2-mercaptoimidazolyl)hydroborate complexes of titanium, zirconium and hafnium. Acta Crystallographica. Section C, Structural Chemistry. 72: 806-812. PMID 27811416 DOI: 10.1107/S2053229616008925  0.47
2016 Ruccolo S, Sattler W, Rong Y, Parkin G. Modulation of Zn-C Bond Lengths Induced by Ligand Architecture in Zinc Carbatrane Compounds. Journal of the American Chemical Society. PMID 27779860 DOI: 10.1021/Jacs.6B09250  0.812
2016 Neary MC, Parkin G. Nickel-catalyzed release of H2 from formic acid and a new method for the synthesis of zerovalent Ni(PMe3)4. Dalton Transactions (Cambridge, England : 2003). PMID 27247982 DOI: 10.1039/C6Dt01499B  0.333
2016 Kreider-Mueller A, Quinlivan PJ, Rauch M, Owen JS, Parkin G. Synthesis, structure and reactivity of [Tm(Bu(t))]ZnH, a monomeric terminal zinc hydride compound in a sulfur-rich coordination environment: access to a heterobimetallic compound. Chemical Communications (Cambridge, England). PMID 26731427 DOI: 10.1039/C5Cc08915H  0.617
2016 Yurkerwich K, Quinlivan PJ, Rong Y, Parkin G. Phenylselenolate Mercury Alkyl Compounds, PhSeHgMe and PhSeHgEt: Molecular Structures, Protolytic Hg-C Bond Cleavage and Phenylselenolate Exchange. Polyhedron. 103: 307-314. PMID 26644634 DOI: 10.1016/J.Poly.2015.06.007  0.814
2016 Neary MC, Parkin G. Structural characterization of the nickel(II) formate complex, Ni(py)4(O2CH)2·2py, and re-evaluation of the nitrate counterpart, Ni(py)4(ONO2)2·2py: Evidence for non-linear nitrate coordination Polyhedron. 116: 189-196. DOI: 10.1016/J.Poly.2016.04.033  0.44
2016 Rauch M, Rong Y, Sattler W, Parkin G. Synthesis of a terminal zinc hydride compound, [TpBut,Me]ZnH, from a hydroxide derivative, [TpBut,Me]ZnOH: Interconversions with the fluoride complex, [TpBut,Me]ZnF Polyhedron. 103: 135-140. DOI: 10.1016/J.Poly.2015.10.010  0.623
2015 Neary MC, Parkin G. Dehydrogenation, disproportionation and transfer hydrogenation reactions of formic acid catalyzed by molybdenum hydride compounds. Chemical Science. 6: 1859-1865. PMID 29308136 DOI: 10.1039/C4Sc03128H  0.409
2015 Kreider-Mueller A, Quinlivan PJ, Rong Y, Owen JS, Parkin G. Exchange of Alkyl and Tris(2-mercapto-1-t-butylimidazolyl)hydroborato Ligands Between Zinc, Cadmium and Mercury. Journal of Organometallic Chemistry. 792: 177-183. PMID 26273109 DOI: 10.1016/J.Jorganchem.2015.04.014  0.591
2015 Kreider-Mueller A, Quinlivan PJ, Owen JS, Parkin G. Synthesis and structures of cadmium carboxylate and thiocarboxylate compounds with a sulfur-rich coordination environment: carboxylate exchange kinetics involving tris(2-mercapto-1-t-butylimidazolyl)hydroborato cadmium complexes, [Tm(Bu(t))]Cd(O2CR). Inorganic Chemistry. 54: 3835-50. PMID 25826184 DOI: 10.1021/Acs.Inorgchem.5B00017  0.614
2015 Palmer JH, Parkin G. Protolytic cleavage of Hg-C bonds induced by 1-methyl-1,3-dihydro-2H-benzimidazole-2-selone: synthesis and structural characterization of mercury complexes. Journal of the American Chemical Society. 137: 4503-16. PMID 25822075 DOI: 10.1021/Jacs.5B00840  0.439
2015 Palmer JH, Parkin G. Influence of Benzannulation on Metal Coordination Geometries: Synthesis and Structural Characterization of Tris(2-mercapto-1-methylbenzimidazolyl)hydroborato Cadmium Bromide, {[Tm(MeBenz)]Cd(μ-Br)}2. Journal of Molecular Structure. 1081: 530-535. PMID 25601793 DOI: 10.1016/J.Molstruc.2014.10.023  0.371
2015 Zuzek AA, Parkin G. Oxidative addition of SiH4 and GeH4 to Ir(PPh3)2(CO)Cl: structural and spectroscopic evidence for the formation of products derived from cis oxidative addition. Dalton Transactions (Cambridge, England : 2003). 44: 2801-8. PMID 25510558 DOI: 10.1039/C4Dt03363A  0.396
2015 Sattler W, Ruccolo S, Rostami Chaijan M, Nasr Allah T, Parkin G. Hydrosilylation of Aldehydes and Ketones Catalyzed by a Terminal Zinc Hydride Complex, [κ3-Tptm]ZnH Organometallics. 34: 4717-4731. DOI: 10.1021/Acs.Organomet.5B00506  0.807
2015 Sattler A, Parkin G. Synthesis, structural characterization, and cyclometalation chemistry of tantalum terphenyl compounds Organometallics. 34: 1828-1843. DOI: 10.1021/Acs.Organomet.5B00158  0.646
2015 Kreider-Mueller A, Quinlivan PJ, Rong Y, Owen JS, Parkin G. Exchange of alkyl and tris(2-mercapto-1-t-butylimidazolyl)hydroborato ligands between zinc, cadmium and mercury Journal of Organometallic Chemistry. DOI: 10.1016/j.jorganchem.2015.04.014  0.542
2014 Zuzek AA, Neary MC, Parkin G. σ-Silane, disilanyl, and [W(μ-H)Si(μ-H)W] bridging silylene complexes via the reactions of W(PMe3)4(η2-CH2PMe2)H with phenylsilanes. Journal of the American Chemical Society. 136: 17934-7. PMID 25516157 DOI: 10.1021/Ja510703S  0.419
2014 Palmer JH, Parkin G. Synthesis and Structural Characterization of 1-Arylimidazole-2-thiones and N,N'-Aryldiethoxyethylthioureas with Electronically Diverse Substituents: A Manifold of Hydrogen Bonding Networks. New Journal of Chemistry = Nouveau Journal De Chimie. 38: 4071-4082. PMID 25214759 DOI: 10.1039/C4Nj00521J  0.411
2014 Palmer JH, Parkin G. Synthesis and structural characterization of tris(2-mercapto-1-methylbenzimidazolyl)hydroborato cadmium halide complexes, {[Tm(MeBenz)]Cd(μ-Cl)}2 and [Tm(MeBenz)]CdI: a rare example of cadmium in a trigonal bipyramidal sulfur-rich coordination environment. Dalton Transactions (Cambridge, England : 2003). 43: 13874-82. PMID 25105778 DOI: 10.1039/C4Dt01820F  0.382
2014 Kreider-Mueller A, Rong Y, Owen JS, Parkin G. Molecular structures of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato and tris(2-mercapto-1-adamantylimidazolyl)hydroborato sodium complexes: analysis of [Tm(R)] ligand coordination modes and conformations. Dalton Transactions (Cambridge, England : 2003). 43: 10852-65. PMID 24898480 DOI: 10.1039/C4Dt01271B  0.634
2014 Zuzek AA, Parkin G. Si-H and Si-C bond cleavage reactions of silane and phenylsilanes with Mo(PMe3)6: silyl, hypervalent silyl, silane, and disilane complexes. Journal of the American Chemical Society. 136: 8177-80. PMID 24874576 DOI: 10.1021/Ja503368J  0.413
2014 Rong Y, Palmer JH, Parkin G. Benzannulated tris(2-mercapto-1-imidazolyl)hydroborato ligands: tetradentate κ4-S3H binding and access to monomeric monovalent thallium in an [S3] coordination environment. Dalton Transactions (Cambridge, England : 2003). 43: 1397-407. PMID 24201311 DOI: 10.1039/C3Dt52418C  0.454
2014 Sattler W, Parkin G. Reduction of bicarbonate and carbonate to formate in molecular zinc complexes Catalysis Science and Technology. 4: 1578-1584. DOI: 10.1039/C3Cy01065A  0.63
2014 Green MLH, Parkin G. Application of the covalent bond classification method for the teaching of inorganic chemistry Journal of Chemical Education. 91: 807-816. DOI: 10.1021/Ed400504F  0.368
2014 Sattler A, Parkin G. Trinuclear, tetranuclear and octanuclear chalcogenido clusters of molybdenum and tungsten supported by trimethylphosphine ligands Dedicated with respect and gratitude to John E. Bercaw, EQG, on the occasion of his 70th birthday. Happy birthday, John! Polyhedron. 84: 74-86. DOI: 10.1016/J.Poly.2014.06.019  0.645
2014 Sattler A, Zuzek AA, Parkin G. Molecular structure of W(PMe3)3H6 in the solid state and in solution Inorganica Chimica Acta. 422: 102-108. DOI: 10.1016/J.Ica.2014.07.013  0.657
2014 Shin JH, Churchill DG, Parkin G, Roggan S, Jankowski C, Limberg C, Tonks I, Bercaw J. Bis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum Inorganic Syntheses. 36: 58-62. DOI: 10.1002/9781118744994.ch12  0.805
2013 Sattler W, Ruccolo S, Parkin G. Synthesis, structure, and reactivity of a terminal organozinc fluoride compound: hydrogen bonding, halogen bonding, and donor-acceptor interactions. Journal of the American Chemical Society. 135: 18714-7. PMID 24320225 DOI: 10.1021/Ja408733F  0.818
2013 Sattler W, Palmer JH, Bridges CC, Joshee L, Zalups RK, Parkin G. Structural characterization of 1,3-propanedithiols that feature carboxylic acids: Homologues of mercury chelating agents. Polyhedron. 64. PMID 24187425 DOI: 10.1016/J.Poly.2013.05.012  0.641
2013 Yurkerwich K, Rong Y, Parkin G. Gallium hydride and monovalent indium compounds that feature tris(pyrazolyl)hydroborate ligands. Acta Crystallographica. Section C, Crystal Structure Communications. 69: 963-7. PMID 24005500 DOI: 10.1107/S0108270113016648  0.828
2013 Al-Harbi A, Rong Y, Parkin G. Synthesis and structural characterization of bis(2-oxoimidazolyl)hydroborato complexes: a new class of bidentate oxygen-donor ligands. Inorganic Chemistry. 52: 10226-8. PMID 23987579 DOI: 10.1021/Ic401658N  0.434
2013 Al-Harbi A, Rong Y, Parkin G. Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: a new class of metallacarbatranes and a monovalent thallium alkyl compound. Dalton Transactions (Cambridge, England : 2003). 42: 14053-7. PMID 23986264 DOI: 10.1039/C3Dt52163J  0.411
2013 Al-Harbi A, Rong Y, Parkin G. Synthesis and structural characterization of bis and tris(2-mercapto-1-methylbenzimidazolyl)hydroborato complexes: benzannulation promotes κ³-coordination. Dalton Transactions (Cambridge, England : 2003). 42: 11117-27. PMID 23801309 DOI: 10.1039/C3Dt51092A  0.447
2013 Rong Y, Al-Harbi A, Kriegel B, Parkin G. Structural characterization of 2-imidazolones: comparison with their heavier chalcogen counterparts. Inorganic Chemistry. 52: 7172-82. PMID 23738650 DOI: 10.1021/Ic400788G  0.41
2013 Palmer JH, Parkin G. 2-Seleno-1-alkylbenzimidazoles and their Diselenides: Synthesis and Structural Characterization of a 2-Seleno-1-methylbenzimidazole Complex of Mercury. Polyhedron. 52: 658-668. PMID 23543946 DOI: 10.1016/J.Poly.2012.07.090  0.443
2013 Rong Y, Parkin G. The synthesis and structures of tris(2-pyridylseleno)methyl zinc compounds with 2-, 3-, and 4-coordination modes Australian Journal of Chemistry. 66: 1306-1310. DOI: 10.1071/Ch13263  0.451
2013 Chakrabarti N, Sattler W, Parkin G. Structural characterization of tris(pyrazolyl)hydroborato and tris(2-pyridylthio)methyl lithium compounds: Lithium in uncommon trigonal pyramidal and trigonal monopyramidal coordination environments Polyhedron. 58: 235-246. DOI: 10.1016/J.Poly.2013.02.008  0.657
2012 Green JC, Green ML, Parkin G. The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds. Chemical Communications (Cambridge, England). 48: 11481-503. PMID 23047247 DOI: 10.1039/C2Cc35304K  0.583
2012 Sattler W, Parkin G. Zinc catalysts for on-demand hydrogen generation and carbon dioxide functionalization. Journal of the American Chemical Society. 134: 17462-5. PMID 23046174 DOI: 10.1021/Ja308500S  0.611
2012 Sattler A, Parkin G. A new class of transition metal pincer ligand: tantalum complexes that feature a [CCC] X3-donor array derived from a terphenyl ligand. Journal of the American Chemical Society. 134: 2355-66. PMID 22260227 DOI: 10.1021/Ja210404X  0.682
2012 Sattler W, Parkin G. Structural characterization of zinc bicarbonate compounds relevant to the mechanism of action of carbonic anhydrase Chemical Science. 3: 2015-2019. DOI: 10.1039/C2Sc20167D  0.647
2012 Rong Y, Al-Harbi A, Parkin G. Highly Variable Zr–CH2–Ph Bond Angles in Tetrabenzylzirconium: Analysis of Benzyl Ligand Coordination Modes Organometallics. 31: 8208-8217. DOI: 10.1021/Om300820B  0.385
2012 Sattler W, Parkin G. Low temperature NMR spectroscopic investigation of a zinc bicarbonate compound: Thermodynamics of bicarbonate formation by insertion of CO 2 into the zinc hydroxide bond of [Tp Bu t,Me]ZnOH Polyhedron. 32: 41-48. DOI: 10.1016/J.Poly.2011.08.015  0.662
2011 Sattler A, Parkin G. Formation of a cationic alkylidene complex via formal hydride abstraction: synthesis and structural characterization of [W(PMe3)4(η2-CHPMe2)H]X (X = Br, I). Chemical Communications (Cambridge, England). 47: 12828-30. PMID 22048609 DOI: 10.1039/C1Cc15457E  0.668
2011 Yurkerwich K, Yurkerwich M, Parkin G. Synthesis and structural characterization of tris(2-mercapto-1-adamantylimidazolyl)hydroborato complexes: a sterically demanding tripodal [S3] donor ligand. Inorganic Chemistry. 50: 12284-95. PMID 21951277 DOI: 10.1021/Ic201504D  0.78
2011 Sattler A, Ruccolo S, Parkin G. Structural characterization of TaMe3Cl2 and Ta(PMe3)2Me3Cl2, a pair of five and seven-coordinate d0 tantalum methyl compounds. Dalton Transactions (Cambridge, England : 2003). 40: 7777-82. PMID 21720617 DOI: 10.1039/C1Dt10806A  0.82
2011 Sattler W, Parkin G. Synthesis, structure, and reactivity of a mononuclear organozinc hydride complex: facile insertion of CO2 into a Zn-H Bond and CO2-promoted displacement of siloxide ligands. Journal of the American Chemical Society. 133: 9708-11. PMID 21644528 DOI: 10.1021/Ja2035706  0.714
2011 Sattler A, Parkin G. Carbon-sulfur bond cleavage and hydrodesulfurization of thiophenes by tungsten. Journal of the American Chemical Society. 133: 3748-51. PMID 21348517 DOI: 10.1021/Ja111034G  0.645
2011 Al-Harbi A, Sattler W, Sattler A, Parkin G. Synthesis and structural characterization of tris(2-oxo-1-tert-butylimidazolyl) and tris(2-oxo-1-methylbenzimidazolyl)hydroborato complexes: a new class of tripodal oxygen donor ligand. Chemical Communications (Cambridge, England). 47: 3123-5. PMID 21264429 DOI: 10.1039/C0Cc03943H  0.761
2011 Sattler A, Janak KE, Parkin G. Modeling aspects of hydrodesulfurization by molybdenum hydride compounds: Desulfurization of thiophene and benzothiophene and C-S bond cleavage of dibenzothiophene Inorganica Chimica Acta. 369: 197-202. DOI: 10.1016/J.Ica.2010.11.020  0.68
2010 Zeika O, Li Y, Jockusch S, Parkin G, Sattler A, Sattler W, Turro NJ. Synthesis of polynitroxides based on nucleophilic aromatic substitution. Organic Letters. 12: 3696-9. PMID 20666471 DOI: 10.1021/Ol101529U  0.709
2010 Yurkerwich K, Coleman F, Parkin G. Bis(2-mercapto-1-R-imidazolyl)hydroborato complexes of aluminium, gallium, indium and thallium: compounds possessing gallium-gallium bonds and a trivalent thallium alkyl. Dalton Transactions (Cambridge, England : 2003). 39: 6939-42. PMID 20596580 DOI: 10.1039/C0Dt00461H  0.806
2010 Sattler A, Parkin G. Cleaving carbon-carbon bonds by inserting tungsten into unstrained aromatic rings. Nature. 463: 523-6. PMID 20110998 DOI: 10.1038/Nature08730  0.629
2010 Melnick JG, Yurkerwich K, Parkin G. On the chalcogenophilicity of mercury: evidence for a strong Hg-Se bond in [Tm(Bu(t))]HgSePh and its relevance to the toxicity of mercury. Journal of the American Chemical Society. 132: 647-55. PMID 20020759 DOI: 10.1021/Ja907523X  0.811
2010 Yurkerwich K, Buccella D, Melnick JG, Parkin G. Tris(2-mercapto-1-tert-butylimidazolyl)hydroborato gallium derivatives: Synthesis of di- and trigallium compounds in a sulfur-rich coordination environment Chemical Science. 1: 210-214. DOI: 10.1039/C0Sc00145G  0.773
2010 Pang K, Rong Y, Parkin G. Molecular structures of three coordinate zinc and cadmium complexes that feature β-diketiminato and anilido-imine ligands Polyhedron. 29: 1881-1890. DOI: 10.1016/J.Poly.2010.02.020  0.763
2010 Yurkerwich K, Parkin G. Gallium and indium compounds supported by a [PNP] pincer ligand Inorganica Chimica Acta. 364: 157-161. DOI: 10.1016/J.Ica.2010.07.064  0.837
2010 Yurkerwich K, Parkin G. Catenated Gallium Compounds Supported by a Tris(pyrazolyl)hydroborato Ligand Journal of Cluster Science. 21: 225-234. DOI: 10.1007/S10876-010-0314-X  0.792
2010 RABINOVICH D, PARKIN G. ChemInform Abstract: Synthesis and Structure of W(PMe3)4(Te)2: The First Transition-Metal Complex with a Terminal Tellurido Ligand. Cheminform. 23: no-no. DOI: 10.1002/CHIN.199212236  0.629
2010 RABINOVICH D, ZELMAN R, PARKIN G. ChemInform Abstract: Competitive sp3 and sp2 C-H Bond Activation of Phenols by W(PMe3)6 and W(PMe3)4(η2-CH2PMe2)H: Formation of Four- and Five-Membered Oxametallacycles. Cheminform. 22: no-no. DOI: 10.1002/CHIN.199113228  0.612
2009 Melnick JG, Yurkerwich K, Parkin G. Synthesis, structure, and reactivity of two-coordinate mercury alkyl compounds with sulfur ligands: relevance to mercury detoxification. Inorganic Chemistry. 48: 6763-72. PMID 20507113 DOI: 10.1021/Ic900721G  0.82
2009 Pang K, Figueroa JS, Tonks IA, Sattler W, Parkin G. 2-Mercapto-1-t-butylimidazolyl as a Bridging Ligand: Synthesis and Structural Characterization of Nickel and Palladium Paddlewheel Complexes. Inorganica Chimica Acta. 362: 4609-4615. PMID 20161357 DOI: 10.1016/J.Ica.2009.05.025  0.798
2009 Sattler W, Parkin G. Synthesis of transition metal isocyanide compounds from carbonyl complexes via reaction with Li[Me3SiNR]. Chemical Communications (Cambridge, England). 7566-8. PMID 20024281 DOI: 10.1039/B917156H  0.615
2009 Sattler W, Yurkerwich K, Parkin G. Molecular structures of protonated and mercurated derivatives of thimerosal. Dalton Transactions (Cambridge, England : 2003). 4327-33. PMID 19662310 DOI: 10.1039/B823467A  0.807
2009 Sattler A, Zhu G, Parkin G. Multiple modes for coordination of phenazine to molybdenum: ring fusion promotes access to eta4-coordination, oxidative addition of dihydrogen and hydrogenation of aromatic nitrogen compounds. Journal of the American Chemical Society. 131: 7828-38. PMID 19438232 DOI: 10.1021/Ja901896X  0.701
2009 Buccella D, Parkin G. p-tert-Butyltetrathiatetramercaptocalix[4]arene as a sulfur-rich platform for molybdenum, tungsten and nickel. Chemical Communications (Cambridge, England). 289-91. PMID 19209305 DOI: 10.1039/B816066J  0.721
2009 Parkin G. Temperature-dependent transitions between normal and inverse isotope effects pertaining to the interaction of H-H and C-H bonds with transition metal centers. Accounts of Chemical Research. 42: 315-25. PMID 19133745 DOI: 10.1021/Ar800156H  0.38
2008 Buccella D, Janak KE, Parkin G. Reactivity of Mo(PMe3)6 towards benzothiophene and selenophenes: new pathways relevant to hydrodesulfurization. Journal of the American Chemical Society. 130: 16187-9. PMID 18998651 DOI: 10.1021/Ja8070545  0.72
2008 Zachmanoglou CE, Lee H, Jang SH, Pang K, Parkin G. Silicon-Carbon bond cleavage reactions of Ansa tungstenocene compounds: the [Me2Si] bridge as a site for metallocene functionalization. Proceedings of the National Academy of Sciences of the United States of America. 105: 11060-5. PMID 18635687 DOI: 10.1073/Pnas.0803089105  0.706
2008 Yurkerwich K, Buccella D, Melnick JG, Parkin G. Monovalent indium in a sulfur-rich coordination environment: synthesis, structure and reactivity of tris(2-mercapto-1-tert-butylimidazolyl)hydroborato indium, [TmBut]In. Chemical Communications (Cambridge, England). 3305-7. PMID 18622452 DOI: 10.1039/B803037E  0.795
2008 Buccella D, Parkin G. Mononuclear and dinuclear molybdenum and tungsten complexes of p-tert-butyltetrathiacalix[4]arene and p-tert-butyltetrasulfonylcalix[4]arene: facile cleavage of the calixarene ligand framework by nickel. Journal of the American Chemical Society. 130: 8617-9. PMID 18557612 DOI: 10.1021/Ja803215X  0.715
2008 Melnick JG, Yurkerwich K, Buccella D, Sattler W, Parkin G. Molecular structures of thimerosal (Merthiolate) and other arylthiolate mercury alkyl compounds. Inorganic Chemistry. 47: 6421-6. PMID 18533648 DOI: 10.1021/Ic8005426  0.79
2008 Lipton AS, Morlok MM, Parkin G, Ellis PD. 67Zn solid-state NMR spectroscopy of ([Tp But,Me]Zn(OH2))[HOB(C6F5)3]. the importance of the anion [HOB(C6F5)3]-. Inorganic Chemistry. 47: 5184-9. PMID 18470984 DOI: 10.1021/Ic800009B  0.327
2008 Pang K, Tanski JM, Parkin G. Reactivity of the Ni-->B dative sigma-bond in the nickel boratrane compounds [kappa4-B(mimBut)3]NiX (X=Cl, OAc, NCS, N3): synthesis of a series of B-functionalized tris(2-mercapto-1-tert-butylimidazolyl)borato complexes, [YTmBut)]NiZ. Chemical Communications (Cambridge, England). 1008-10. PMID 18283365 DOI: 10.1039/B714466K  0.77
2008 Zhu G, Pang K, Parkin G. New modes for coordination of aromatic heterocyclic nitrogen compounds to molybdenum: catalytic hydrogenation of quinoline, isoquinoline, and quinoxaline by Mo(PMe3)4H4. Journal of the American Chemical Society. 130: 1564-5. PMID 18183981 DOI: 10.1021/Ja078102D  0.775
2008 Zhu G, Pang K, Parkin G. Coordination chemistry of molybdenum relevant to hydrodenitrogenation: Reactivity of Mo(PMe3)6 towards 6-membered heterocyclic aromatic nitrogen compounds involving C–H bond cleavage and η6-coordination Inorganica Chimica Acta. 361: 3221-3229. DOI: 10.1016/J.Ica.2007.10.048  0.774
2007 Parkin G. Applications of Tripodal [S(3)] and [Se(3)] L(2)X Donor Ligands to Zinc, Cadmium and Mercury Chemistry: Organometallic and Bioinorganic Perspectives. New Journal of Chemistry = Nouveau Journal De Chimie. 31: 1996-2014. PMID 19484137 DOI: 10.1039/B712012E  0.358
2007 Figueroa JS, Yurkerwich K, Melnick J, Buccella D, Parkin G. Applications of bis(1-R-imidazol-2-yl)disulfides and diselenides as ligands for main-group and transition metals: kappa2-(N,N) coordination, S-S bond cleavage, and S-S/E-E (E = S, Se) bond metathesis reactions. Inorganic Chemistry. 46: 9234-44. PMID 17900186 DOI: 10.1021/Ic701228Y  0.815
2007 Melnick JG, Parkin G. Cleaving mercury-alkyl bonds: a functional model for mercury detoxification by MerB. Science (New York, N.Y.). 317: 225-7. PMID 17626880 DOI: 10.1126/Science.1144314  0.43
2007 Brookhart M, Green ML, Parkin G. Agostic interactions in transition metal compounds. Proceedings of the National Academy of Sciences of the United States of America. 104: 6908-14. PMID 17442749 DOI: 10.1073/Pnas.0610747104  0.681
2007 Landry VK, Buccella D, Pang K, Parkin G. Bis- and tris(2-seleno-1-methylimidazolyl)hydroborato complexes, {[BseMe]ZnX}2(X=Cl, I), [BseMe]2Zn and [TseMe]Re(CO)3: structural evidence that the [BseMe] ligand is not merely a "heavier" version of the sulfur counterpart, [BmMe]. Dalton Transactions (Cambridge, England : 2003). 866-70. PMID 17297514 DOI: 10.1039/B616630J  0.816
2007 Landry VK, Pang K, Quan SM, Parkin G. Tetrahedral nickel nitrosyl complexes with tripodal [N3] and [Se3] donor ancillary ligands: structural and computational evidence that a linear nitrosyl is a trivalent ligand. Dalton Transactions (Cambridge, England : 2003). 820-4. PMID 17297507 DOI: 10.1039/B616674A  0.739
2007 Buccella D, Tanski JM, Parkin G. Factors influencing coordination versus oxidative addition of C-H bonds to molybdenum and tungsten: Structural and spectroscopic evidence that the calixarene framework promotes C-H bond activation Organometallics. 26: 3275-3278. DOI: 10.1021/Om700279C  0.791
2007 Hascall. Tony HT, Pang K, Parkin G. exo and endo Isomerism of Subvalent Tin and Germanium Complexes Derived from 1,3-Diethers of p-tert-Butylcalix[4]arene. Cheminform. 38. DOI: 10.1016/J.Tet.2007.06.127  0.727
2007 Hascall T, Pang K, Parkin G. exo and endo Isomerism of subvalent tin and germanium complexes derived from 1,3-diethers of p-tert-butylcalix[4]arene Tetrahedron. 63: 10826-10833. DOI: 10.1016/J.TET.2007.06.127  0.671
2007 Landry VK, Parkin G. Synthesis and structural characterization of [BseMe]Ni(PPh3)(NO), a nickel complex with a bent nitrosyl ligand Polyhedron. 26: 4751-4757. DOI: 10.1016/J.Poly.2007.06.005  0.439
2007 Kelly BV, Weintrob EC, Buccella D, Tanski JM, Parkin G. Synthesis and structural characterization of tris(phenolate)amine complexes of antimony derived from [κ4 -N (CH2 ArBu2t O)3] Sb Inorganic Chemistry Communications. 10: 699-704. DOI: 10.1016/J.Inoche.2007.02.027  0.783
2007 Parkin G. Applications of deuterium isotope effects for probing aspects of reactions involving oxidative addition and reductive elimination of H–H and C–H bonds Journal of Labelled Compounds and Radiopharmaceuticals. 50: 1088-1114. DOI: 10.1002/Jlcr.1435  0.307
2006 Buccella D, Parkin G. p-tert-Butylcalix[4]arene complexes of molybdenum and tungsten: reactivity of the calixarene methylene C-H bond and the facile migration of the metal around the phenolic rim of the calixarene. Journal of the American Chemical Society. 128: 16358-64. PMID 17165791 DOI: 10.1021/Ja066457B  0.721
2006 Pang K, Quan SM, Parkin G. Palladium complexes with Pd-->B dative bonds: analysis of the bonding in the palladaboratrane compound [kappa4-B(mimBut)3]Pd(PMe3). Chemical Communications (Cambridge, England). 5015-7. PMID 17146512 DOI: 10.1039/B611654J  0.673
2006 Minoura M, Landry VK, Melnick JG, Pang K, Marchiò L, Parkin G. Synthesis and structural characterization of tris(2-seleno-1-mesitylimidazolyl) hydroborato complexes: a new type of strongly electron donating tripodal selenium ligand. Chemical Communications (Cambridge, England). 3990-2. PMID 17003875 DOI: 10.1039/B608078B  0.727
2006 Landry VK, Minoura M, Pang K, Buccella D, Kelly BV, Parkin G. Synthesis and structural characterization of 1-mesityl-1,3-dihydro-imidazole-2-selone and bis(1-mesitylimidazol-2-yl)diselenide: experimental evidence that the selone is more stable than the selenol tautomer. Journal of the American Chemical Society. 128: 12490-7. PMID 16984200 DOI: 10.1021/Ja063168E  0.814
2006 Figueroa JS, Melnick JG, Parkin G. Reactivity of the metal-->BX3 dative sigma-bond: 1,2-addition reactions of the Fe-->BX3 moiety of the ferraboratrane complex [kappa4-B(mimBu t)3]Fe(CO)2. Inorganic Chemistry. 45: 7056-8. PMID 16933903 DOI: 10.1021/Ic061353N  0.65
2006 Melnick JG, Parkin G. Methyl and arylchalcogenolate complexes of cadmium in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroborato cadmium complexes [Tm(Bu(t))]CdMe, and [Tm(Bu(t))]CdEAr (E = O, S, Se, Te) and analysis of the bonding in chalcogenolate compounds. Dalton Transactions (Cambridge, England : 2003). 4207-10. PMID 16932812 DOI: 10.1039/B607916D  0.477
2006 Zhu G, Janak KE, Parkin G. A normal equilibrium isotope effect for oxidative addition of H2 to (eta6-anthracene)Mo(PMe3)3. Chemical Communications (Cambridge, England). 2501-3. PMID 16758029 DOI: 10.1039/B604159K  0.524
2006 Zhu G, Janak KE, Figueroa JS, Parkin G. Oxidative addition of dihydrogen to (eta6-arene)Mo(PMe3)3 complexes: origin of the naphthalene and anthracene effects. Journal of the American Chemical Society. 128: 5452-61. PMID 16620117 DOI: 10.1021/Ja058107F  0.736
2006 Landry VK, Melnick JG, Buccella D, Pang K, Ulichny JC, Parkin G. Synthesis and structural characterization of [kappa3-B,S,S-B(mimR)3]Ir(CO)(PPh3)H (R = Bu(t), Ph) and [kappa4-B(mim(Bu(t))3]M(PPh3)Cl (M = Rh, Ir): analysis of the bonding in metal borane compounds. Inorganic Chemistry. 45: 2588-97. PMID 16529480 DOI: 10.1021/Ic051975T  0.82
2006 Melnick JG, Zhu G, Buccella D, Parkin G. Thiolate exchange in [TmR]ZnSR' complexes and relevance to the mechanisms of thiolate alkylation reactions involving zinc enzymes and proteins. Journal of Inorganic Biochemistry. 100: 1147-54. PMID 16516971 DOI: 10.1016/J.Jinorgbio.2005.12.023  0.753
2006 Kelly BV, Tanski JM, Janak KE, Parkin G. C-H versus O-H bond cleavage reactions of Bis(2-hydroxyphenyl)phenylamine, PhN(o-C6H4OH)2: Synthesis and structural characterization of mononuclear and dinuclear tungsten aryloxide complexes which exhibit bidentate, tridentate, and tetradentate coordination modes Organometallics. 25: 5839-5842. DOI: 10.1021/Om060732L  0.652
2006 Parkin G. A Simple Description of the Bonding in Transition-Metal Borane Complexes Organometallics. 25: 4744-4747. DOI: 10.1021/Om060580U  0.375
2006 Buccella D, Shultz A, Melnick JG, Konopka F, Parkin G. Cp[Tm Me]ZrCl 2, a tris(2-mercapto-1-methylimidazolyl) hydroborato complex of zirconium and a new type of precatalyst for olefin polymerization Organometallics. 25: 5496-5499. DOI: 10.1021/Om060571L  0.725
2006 Churchill DG, Bridgewater BM, Zhu G, Pang K, Parkin G. Carbon–hydrogen versus carbon–chalcogen bond cleavage of furan, thiophene and selenophene by ansa molybdenocene complexes Polyhedron. 25: 499-512. DOI: 10.1016/J.Poly.2005.08.016  0.707
2006 Shin JH, Churchill DG, Bridgewater BM, Pang K, Parkin G. Hydride, halide, methyl, carbonyl, and chalcogenido derivatives of permethylmolybdenocene Inorganica Chimica Acta. 359: 2942-2955. DOI: 10.1016/J.Ica.2005.12.037  0.708
2005 Zhu G, Parkin G. Synthesis and structural characterization of M(PMe3)3(O2CR)2(OH2)H2 (M = Mo, W): aqua-hydride complexes of molybdenum and tungsten. Inorganic Chemistry. 44: 9637-9. PMID 16363830 DOI: 10.1021/Ic051617Q  0.561
2005 Morlok MM, Janak KE, Zhu G, Quarless DA, Parkin G. Intramolecular N-H...S hydrogen bonding in the zinc thiolate complex [Tm(Ph)]ZnSCH2C(O)NHPh: a mechanistic investigation of thiolate alkylation as probed by kinetics studies and by kinetic isotope effects. Journal of the American Chemical Society. 127: 14039-50. PMID 16201826 DOI: 10.1021/Ja0536670  0.54
2005 Tanski JM, Kelly BV, Parkin G. Multidentate aryloxide and oxo-aryloxide complexes of antimony: synthesis and structural characterization of [eta4-N(o-C6H4O)3]Sb(OSMe2), {{[eta3-N(o-C6H4OH)- (o-C6H4O)2]Sb}2(mu2-O)}2 and {[eta3-PhN(o-C6H4O)2]Sb}4(mu3-O)2. Dalton Transactions (Cambridge, England : 2003). 2442-7. PMID 15995755 DOI: 10.1039/B505308K  0.586
2005 Zachmanoglou CE, Melnick JG, Bridgewater BM, Churchill DG, Parkin G. ChiralAnsaZirconocene Compounds with [Me2Si] and [Me4Si2] Bridges and withtert-Butyl Ring Substituents:  Synthesis and Structural Characterization of theRacemoComplexesrac-[Me2Si(C5H2-2,4-But2)2]ZrCl2andrac-[Me4Si2(C5H2-2,4-But2)2]ZrCl2 Organometallics. 24: 603-611. DOI: 10.1021/Om049273J  0.447
2005 Lee H, Bonanno JB, Bridgewater BM, Churchill DG, Parkin G. Ansa-titanocene pyrrolyl complexes: The synthesis and structural characterization of [Me2Si(C5Me4)2]Ti(NC4H4)X (X=H, Me, Cl and NC4H4) and [Me2Si(C5Me4)(C5Me3CH2)]Ti(NC4H4) Polyhedron. 24: 1356-1365. DOI: 10.1016/J.Poly.2005.04.005  0.408
2005 Kelly BV, Tanski JM, Anzovino MB, Parkin G. Synthesis and structural analysis of Bis(2-hydroxyphenyl) phenylamine, PhN(o-C6H4OH)2: Comparison with Tris(2-hydroxyphenyl)amine N(o-C6H4OH)3 Journal of Chemical Crystallography. 35: 969-981. DOI: 10.1007/S10870-005-5360-0  0.575
2004 Melnick JG, Docrat A, Parkin G. Methyl, hydrochalcogenido, and phenylchalcogenolate complexes of zinc in a sulfur rich coordination environment: syntheses and structural characterization of the tris(2-mercapto-1-tert-butylimidazolyl)hydroboratozinc complexes [TmBut]ZnMe, [TmBut]ZnEH (E = S, Se) and [TmBut]ZnEPh (E = O, S, Se, Te). Chemical Communications (Cambridge, England). 2870-1. PMID 15599448 DOI: 10.1039/B412218F  0.42
2004 Morlok MM, Docrat A, Janak KE, Tanski JM, Parkin G. The molecular structure of the tris(2-mercapto-1-tolylimidazolyl)hydroborato zinc(2-mercapto-1-tolylimidazole) complex, [[Tm(p-Tol)]Zn(mim(p-Tol))][ClO4]: intermolecular N-H...OClO3versus intramolecular N-H...S hydrogen bonding interactions of the mercaptoimidazole ligand. Dalton Transactions (Cambridge, England : 2003). 3448-52. PMID 15510261 DOI: 10.1039/B412147C  0.667
2004 Janak KE, Shin JH, Parkin G. Molybdenocene trihydride complexes: influence of a [Me2Si] ansa bridge on classical versus nonclassical nature, stability with respect to elimination of dihydrogen, and acidity. Journal of the American Chemical Society. 126: 13054-70. PMID 15469304 DOI: 10.1021/Ja047554C  0.401
2004 Parkin G. Chemistry. Zinc-zinc bonds: a new frontier. Science (New York, N.Y.). 305: 1117-8. PMID 15326345 DOI: 10.1126/Science.1102500  0.333
2004 Baik MH, Friesner RA, Parkin G. Theoretical investigation of the metal-metal interaction in dimolybdenum complexes with bridging hydride and methyl ligands Polyhedron. 23: 2879-2900. DOI: 10.1016/J.Poly.2004.08.004  0.409
2004 Docrat A, Morlok MM, Bridgewater BM, Churchill DG, Parkin G. N–H⋯O hydrogen bonding interactions in tetrahedral [ZnS4] complexes of relevance to zinc enzymes: the synthesis, structures and reactivity of tris(2-mercapto-1-arylimidazolyl)hydroborato zinc(2-mercapto-1-arylimidazole) complexes, {[TmAr]Zn(mimAr)}[ClO4] (Ar=Ph, p-Tol) Polyhedron. 23: 481-488. DOI: 10.1016/J.Poly.2003.11.035  0.444
2003 Bergquist C, Fillebeen T, Morlok MM, Parkin G. Protonation and reactivity towards carbon dioxide of the mononuclear tetrahedral zinc and cobalt hydroxide complexes, [Tp(Bu)t(,Me)]ZnOH and [Tp(Bu)t(,Me)]CoOH: comparison of the reactivity of the metal hydroxide function in synthetic analogues of carbonic anhydrase. Journal of the American Chemical Society. 125: 6189-99. PMID 12785851 DOI: 10.1021/Ja034711J  0.819
2003 Janak KE, Parkin G. Temperature-dependent transitions between normal and inverse equilibrium isotope effects for coordination and oxidative addition of C-H and H-H bonds to a transition metal center. Journal of the American Chemical Society. 125: 6889-91. PMID 12783540 DOI: 10.1021/Ja034559L  0.355
2003 Tanski JM, Parkin G. Tantalum amido and imido complexes supported by tris[(2-indolyl)methyl]amine, a tetradentate trianionic ligand with reduced pi-donor character. Inorganic Chemistry. 42: 264-6. PMID 12693204 DOI: 10.1021/Ic026182A  0.624
2003 Lipton AS, Bergquist C, Parkin G, Ellis PD. Solid-State 67Zn NMR spectroscopic studies and ab initio molecular orbital calculations on a synthetic analogue of carbonic anhydrase. Journal of the American Chemical Society. 125: 3768-72. PMID 12656608 DOI: 10.1021/Ja021328Q  0.796
2003 Janak KE, Churchill DG, Parkin G. Computational evidence that the inverse kinetic isotope effect for reductive elimination of methane from a tungstenocene methyl-hydride complex is associated with the inverse equilibrium isotope effect for formation of a sigma-complex intermediate. Chemical Communications (Cambridge, England). 22-3. PMID 12610946 DOI: 10.1039/B209684F  0.373
2003 Churchill DG, Janak KE, Wittenberg JS, Parkin G. Normal and inverse primary kinetic deuterium isotope effects for C-H bond reductive elimination and oxidative addition reactions of molybdenocene and tungstenocene complexes: evidence for benzene sigma-complex intermediates. Journal of the American Chemical Society. 125: 1403-20. PMID 12553844 DOI: 10.1021/Ja027670K  0.396
2003 Janak KE, Parkin G. Deuterium and tritium equilibrium isotope effects for coordination and oxidative addition of dihydrogen to [W(CO)5] and for the interconversion of W(CO)52-H2) and W(CO)5H2 Organometallics. 22: 4378-4380. DOI: 10.1021/Om0303810  0.332
2003 Tanski JM, Parkin G. Tantalum amido and imido complexes supported by tris[(2-indolyl)methyl]amine, a tetradentate trianionic ligand with reduced π-donor character Inorganic Chemistry. 42: 264-266. DOI: 10.1021/ic026182a  0.596
2003 Zhu G, Tanski JM, Parkin G. Synthesis and structure of [pzBu2t]Mo(PMe3)4H, a d4 molybdenum complex that exhibits η2-coordination of the 3,5-di-t-butylpyrazolyl ligand Polyhedron. 22: 199-203. DOI: 10.1016/S0277-5387(02)01265-2  0.738
2002 Hascall T, Baik MH, Bridgewater BM, Shin JH, Churchill DG, Friesner RA, Parkin G. A non-classical hydrogen bond in the molybdenum arene complex [eta 6-C6H5C6H3(Ph)OH]Mo(PMe3)3: evidence that hydrogen bonding facilitates oxidative addition of the O-H bond. Chemical Communications (Cambridge, England). 2644-5. PMID 12510278 DOI: 10.1039/B208678F  0.388
2002 Zhu G, Tanski JM, Churchill DG, Janak KE, Parkin G. The reactivity of Mo(PMe3)(6) towards heterocyclic nitrogen compounds: transformations relevant to hydrodenitrogenation. Journal of the American Chemical Society. 124: 13658-9. PMID 12431079 DOI: 10.1021/Ja028512W  0.738
2002 Zachmanoglou CE, Docrat A, Bridgewater BM, Parkin G, Brandow CG, Bercaw JE, Jardine CN, Lyall M, Green JC, Keister JB. The electronic influence of ring substituents and ansa bridges in zirconocene complexes as probed by infrared spectroscopic, electrochemical, and computational studies. Journal of the American Chemical Society. 124: 9525-46. PMID 12167048 DOI: 10.1021/Ja020236Y  0.801
2002 Biros SM, Bridgewater BM, Villeges-Estrada A, Tanski JM, Parkin G. Antimony ethylene glycolate and catecholate compounds: structural characterization of polyesterification catalysts. Inorganic Chemistry. 41: 4051-7. PMID 12132933 DOI: 10.1021/Ic020204B  0.617
2002 Shin JH, Parkin G. Kinetic and thermodynamic preferences for the diastereoselective oxidative addition of H(2) to trans-Ir(PR(3))(2)(CO)Cl: monodentate chiral phosphines may impart exceptional degrees of diastereoselectivity. Journal of the American Chemical Society. 124: 7652-3. PMID 12083907 DOI: 10.1021/Ja026059I  0.43
2002 Janak KE, Tanski JM, Churchill DG, Parkin G. Thiophene and butadiene-thiolate complexes of molybdenum: observations relevant to the mechanism of hydrodesulfurization. Journal of the American Chemical Society. 124: 4182-3. PMID 11960426 DOI: 10.1021/Ja012771O  0.659
2002 Bergquist C, Koutcher L, Vaught AL, Parkin G. Reactivity of the B-H Bond in tris(pyrazolyl)hydroborato zinc complexes: unexpected example of zinc hydride formation in a protic solvent and its relevance towards hydrogen transfer to NAD(+) mimics by tris(pyrazolyl)hydroborato zinc complexes in alcoholic media. Inorganic Chemistry. 41: 625-7. PMID 11849057 DOI: 10.1021/Ic011136G  0.829
2002 Zhu G, Tanski JM, Parkin G. Synthesis and structural characterization of 2,5-diphenylpyrrolyl complexes of zinc, [pyr2,5-Ph2]2Zn(THF) and {[pyr 2,5-Ph2]Zn(THF)2 (μ3-O)Zn[pyr 2,5-Ph2]}2: A zinc oxo complex with planar μ 3-oxo bridges Journal of Chemical Crystallography. 32: 469-475. DOI: 10.1023/A:1021144809986  0.679
2002 Tanski JM, Parkin G. The synthesis and molecular structures of 2,5-diarylpyrroles, [pyr Ar2]H (Ar = Ph, 2,4-xyl) Journal of Chemical Crystallography. 32: 185-190. DOI: 10.1023/A:1020239919672  0.633
2002 Tanski JM, Parkin G. Synthesis and structures of zirconium-pyrrolyl complexes: Computational analysis of the factors that influence the coordination modes of pyrrolyl ligands Organometallics. 21: 587-589. DOI: 10.1021/Om011006F  0.642
2002 Zhu G, Tanski JM, Churchill DG, Janak KE, Parkin G. The reactivity of Mo(PMe3)6 towards heterocyclic nitrogen compounds: Transformations relevant to hydrodenitrogenation Journal of the American Chemical Society. 124: 13658-13659. DOI: 10.1021/ja028512w  0.611
2002 Hascall T, Murphy VJ, Janak KE, Parkin G. The syntheses and structures of coordinatively unsaturated aryloxy-hydride complexes of molybdenum, Mo(PMe3)4(OAr)H: Reversible C-H bond activation and comparison with their tungsten analogues Journal of Organometallic Chemistry. 652: 37-49. DOI: 10.1016/S0022-328X(02)01306-2  0.452
2002 Shin JH, Churchill DG, Parkin G. Carbonyl abstraction reactions of Cp*Mo(PMe3)3H with CO2, (CH2O)n, HCO2H, and MeOH: the synthesis of Cp*Mo(PMe3)2(CO)H and the catalytic decarboxylation of formic acid Journal of Organometallic Chemistry. 642: 9-15. DOI: 10.1016/S0022-328X(01)01218-9  0.43
2001 Shin JH, Bridgewater BM, Churchill DG, Parkin G. Synthesis and structural characterization of PHP[(C(5)Me(4))(2)], a monodentate chiral phosphine derived from intramolecular C-C coupling of tetramethylcyclopentadienyl groups: an evaluation of steric and electronic properties. Inorganic Chemistry. 40: 5626-35. PMID 11599963 DOI: 10.1021/Ic010443J  0.365
2001 Shin JH, Bridgewater BM, Churchill DG, Baik MH, Friesner RA, Parkin G. An experimental and computational analysis of the formation of the terminal nitrido complex (eta3-Cp*)2Mo(N)(N3) by elimination of N2 from Cp*2Mo(N3)2: the barrier to elimination is strongly influenced by the exo versus endo configuration of the azide ligand. Journal of the American Chemical Society. 123: 10111-2. PMID 11592896 DOI: 10.1021/Ja011416V  0.332
2001 Kimblin C, Bridgewater BM, Churchill DG, Hascall T, Parkin G. Bis(mercaptoimidazolyl)(pyrazolyl)hydroborato complexes of zinc, cadmium, and cobalt: structural evidence for the enhanced tendency of zinc in biological systems to adopt tetrahedral M[S4] coordination. Inorganic Chemistry. 39: 4240-3. PMID 11196918 DOI: 10.1021/Ic000093L  0.426
2001 Shin JH, Savage W, Murphy VJ, Bonanno JB, Churchill DG, Parkin G. The syntheses, structures and reactivity of bis(tert-butylcyclopentadienyl)molybdenum derivatives: nitrogen alkylation of an η2-acetonitrile ligand and influence of the chalcogen on the barrier to inversion of chalcogenoether adducts Journal of the Chemical Society-Dalton Transactions. 1732-1753. DOI: 10.1039/B100372K  0.481
2001 Trnka TM, Bonanno JB, Bridgewater BM, Parkin G. Bis(permethylindenyl) complexes of thorium: Synthesis, structure, and reactivity Organometallics. 20: 3255-3264. DOI: 10.1021/Om010233E  0.432
2001 Bridgewater BM, Parkin G. A zinc hydroxide complex of relevance to 5-aminolevulinate dehydratase: The synthesis, structure and reactivity of the tris(2-mercapto-1-phenylimidazolyl)hydroborato complex [TmPh]ZnOH Inorganic Chemistry Communications. 4: 126-129. DOI: 10.1016/S1387-7003(00)00218-5  0.418
2001 Kimblin C, Churchill DG, Bridgewater BM, Girard JN, Quarless DA, Parkin G. Tris(mercaptoimidazolyl)hydroborato complexes of cobalt and iron, [TmPh]2M (M=Fe, Co): structural comparisons with their tris(pyrazolyl)hydroborato counterparts Polyhedron. 20: 1891-1896. DOI: 10.1016/S0277-5387(01)00780-X  0.387
2001 Dowling CM, Parkin G. Syntheses and crystal structures of [BpBut,Me]ZnX, [BpBut,Pri]ZnX (X=Me, I) and {[BpBut,Me]Cd(μ-I)}2: mononuclear versus dinuclear bis(pyrazolyl)hydroborato zinc and cadmium complexes Polyhedron. 20: 285-289. DOI: 10.1016/S0277-5387(00)00619-7  0.396
2000 Kimblin C, Murphy VJ, Hascall T, Bridgewater BM, Bonanno JB, Parkin G. Structural studies of the [tris(imidazolyl)phosphine]metal nitrate complexes [[PimPrl,But]M(NO3)]+ (M = Co, Cu, Zn, Cd, Hg): comparison of nitrate-binding modes in synthetic analogues of carbonic anhydrase. Inorganic Chemistry. 39: 967-74. PMID 12526376 DOI: 10.1021/Ic990682V  0.375
2000 Bridgewater BM, Fillebeen T, Friesner RA, Parkin G. A zinc thiolate species which mimics aspects of the chemistry of the Ada repair protein and matrix metalloproteinases: the synthesis, structure and reactivity of the tris(2-mercapto-1-phenylimidazolyl)hydroborato complex [TmPh]ZnSPh Journal of the Chemical Society-Dalton Transactions. 4494-4496. DOI: 10.1039/B007886G  0.333
2000 Lee H, Bridgewater BM, Parkin G. Influence of a [Me2Si] ansa bridge on the barrier to rotation about the Zr–phenyl bond and on the generation and reactivity of benzyne intermediates: comparison of the structures and reactivity of [Me2Si(C5Me4)2]Zr(Ph)X and Cp*2Zr(Ph)X (X = H, Cl, Ph) Journal of the Chemical Society-Dalton Transactions. 4490-4493. DOI: 10.1039/B005117I  0.411
2000 Kimblin C, Bridgewater BM, Churchill DG, Parkin G. Synthesis and molecular structures of a pair of tris(imidazolyl)phosphine cobalt–perchlorate complexes, {[PimPri2]Co(OClO3)}[ClO4] and {[PimPri2]Co(OH2)(HOMe)(OClO3)}[ClO4] Journal of the Chemical Society-Dalton Transactions. 2191-2194. DOI: 10.1039/B002894K  0.416
2000 Kimblin C, Bridgewater BM, Hascall T, Parkin G. The synthesis and structural characterization of bis(mercaptoimidazolyl)(pyrazolyl)hydroborato and tris(mercaptoimidazolyl)hydroborato complexes of thallium(I) and thallium(III) Journal of the Chemical Society-Dalton Transactions. 1267-1274. DOI: 10.1039/A909542J  0.436
2000 Kimblin C, Bridgewater BM, Hascall T, Parkin G. The synthesis and structural characterization of bis(mercaptoimidazolyl)hydroborato complexes of lithium, thallium and zinc Journal of the Chemical Society-Dalton Transactions. 891-897. DOI: 10.1039/A908411H  0.413
2000 Shin JH, Bridgewater BM, Parkin G. CationicAnsa-Zirconocene and Hafnocene Derivatives of a Monoanionic Phosphonium-Bridged Bis(permethylcyclopentadienyl) Ligand:  Synthesis and Structural Characterization of {[Me2P(C5Me4)2]MCl2}+(M = Zr, Hf) and {[Me2P(C5Me4)2]ZrMe2}+ Organometallics. 19: 5155-5159. DOI: 10.1021/Om000536T  0.432
2000 Churchill DG, Bridgewater BM, Parkin G. Modeling Aspects of Hydrodesulfurization at Molybdenum:  Carbon−Sulfur Bond Cleavage of Thiophenes byAnsaMolybdenocene Complexes Journal of the American Chemical Society. 122: 178-179. DOI: 10.1021/Ja9936316  0.324
2000 Bergquist C, Storrie H, Koutcher L, Bridgewater BM, Friesner RA, Parkin G. Factors influencing the thermodynamics of zinc alkoxide formation by alcoholysis of the terminal hydroxide complex, [TpBut,Me]ZnOH: An experimental and theoretical study relevant to the mechanism of action of liver alcohol dehydrogenase Journal of the American Chemical Society. 122: 12651-12658. DOI: 10.1021/Ja002286D  0.787
2000 Bergquist C, Bridgewater BM, Harlan CJ, Norton JR, Friesner RA, Parkin G. Aqua, alcohol, and acetonitrile adducts of tris(perfluorophenyl)borane: Evaluation of Bronsted acidity and ligand lability with experimental and computational methods Journal of the American Chemical Society. 122: 10581-10590. DOI: 10.1021/Ja001915G  0.784
2000 Bridgewater BM, Parkin G. Lead Poisoning and the Inactivation of 5-Aminolevulinate Dehydratase as Modeled by the Tris(2-mercapto-1-phenylimidazolyl)hydroborato Lead Complex, {[TmPh]Pb}[ClO4] Journal of the American Chemical Society. 122: 7140-7141. DOI: 10.1021/Ja001530Y  0.322
2000 Bridgewater BM, Parkin G. The synthesis and molecular structure of [TmPh]2Pb: a complex with an ‘inverted’ η4-coordination mode for the tris(2-mercapto-1-phenylimidazolyl)hydroborato ligand Inorganic Chemistry Communications. 3: 534-536. DOI: 10.1016/S1387-7003(00)00136-2  0.424
2000 Hascall T, Bridgewater BM, Parkin G. Reactivity of Mo(PMe3)5H2 towards catecholborane: synthesis and structure of Mo(PMe3)4(η2-H2BCat)H Polyhedron. 19: 1063-1066. DOI: 10.1016/S0277-5387(00)00350-8  0.424
2000 Kisko JL, Fillebeen T, Hascall T, Parkin G. The synthesis and structural characterization of phenyl tris(3-t-butylpyrazolyl)borato alkyl complexes of magnesium and zinc, [PhTpBut]MgR (R=Me, Et) and [PhTpBut]ZnMe Journal of Organometallic Chemistry. 596: 22-26. DOI: 10.1016/S0022-328X(99)00534-3  0.394
1999 Bergquist C, Parkin G. Modeling the Catalytic Cycle of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a Four-Coordinate Zinc Ethoxide Complex and Determination of Relative Zn-OR versus Zn-OH Bond Energies. Inorganic Chemistry. 38: 422-423. PMID 11673942 DOI: 10.1021/Ic981267Q  0.798
1999 Kimblin C, Bridgewater BM, Churchill DG, Parkin G. Mononuclear tris(2-mercapto-1-arylimidazolyl)hydroborato complexes of zinc, [TmAr]ZnX: structural evidence that a sulfur rich coordination environment promotes the formation of a tetrahedral alcohol complex in a synthetic analogue of LADH Chemical Communications. 2301-2302. DOI: 10.1039/A906561J  0.342
1999 Ghosh P, Churchill DG, Rubinshtein M, Parkin G. Synthesis and molecular structure of bis(pyrazolyl)(3,5-di-tert- butylpyrazolyl)hydroborato thallium: A hetero-tris(pyrazolyl)-hydroborato ligand derived from two different pyrazoles New Journal of Chemistry. 23: 961-963. DOI: 10.1039/A906292K  0.647
1999 Kuchta MC, Hahn JM, Parkin G. Divalent tin and lead complexes of a bulky salen ligand: the syntheses and structures of [SalenBut,Me]Sn and [SalenBut,Me]Pb Journal of the Chemical Society-Dalton Transactions. 3559-3563. DOI: 10.1039/A905490A  0.481
1999 Kuchta MC, Rheingold AL, Parkin G. Structural characterization of an ordered crystalline modification of [In(SePh)3](∞) New Journal of Chemistry. 23: 957-959. DOI: 10.1039/A905250J  0.405
1999 Kisko JL, Hascall T, Kimblin C, Parkin G. Phenyl tris(3-tert-butylpyrazolyl)borato complexes of lithium and thallium, [PhTpBut]M (M = Li, Tl): a novel structure for a monomeric tris(pyrazolyl)boratothallium complex and a study of its stereochemical nonrigidity by 1H and 205Tl NMR spectroscopy Journal of the Chemical Society-Dalton Transactions. 1929-1936. DOI: 10.1039/A901875A  0.417
1999 Shin JH, Parkin G. The ansa-effect in permethyltantalocene chemistry: a [Me2Si] ansa bridge promotes olefin-insertion and reductive-elimination reactions for [Me2Si(C5Me4)2]Ta(η2-C2H4)H and [Me2Si(C5Me4)2]TaH3 Chemical Communications. 887-888. DOI: 10.1039/A900895K  0.405
1999 Lee H, Bonanno JB, Hascall T, Cordaro J, Hahn JM, Parkin G. [Me2Si] Ansa bridged complexes of permethyltitanocene: synthesis and structural characterization of fulvene derivatives with trialkylidenemethane character† Journal of the Chemical Society-Dalton Transactions. 1365-1368. DOI: 10.1039/A900173E  0.422
1999 Churchill D, Shin JH, Hascall T, Hahn JM, Bridgewater BM, Parkin G. TheAnsaEffect in Permethylmolybdenocene Chemistry:  A [Me2Si]AnsaBridge Promotes Intermolecular C−H and C−C Bond Activation Organometallics. 18: 2403-2406. DOI: 10.1021/Om990195N  0.354
1999 Shin JH, Hascall T, Parkin G. Phosphorus-Bridgedansa-Metallocene Complexes of Titanium, Zirconium, and Hafnium:  The Syntheses and Structures of [PhP(C5Me4)2]MX2and [Ph(E)P(C5Me4)2]MX2(E = O, S, Se) Derivatives Organometallics. 18: 6-9. DOI: 10.1021/Om9807396  0.426
1999 Hascall T, Rabinovich D, Murphy VJ, Beachy MD, Friesner RA, Parkin G. Mechanistic and theoretical analysis of the oxidative addition of H2 to six-coordinate molybdenum and tungsten complexes M(PMe3)4X2 (M = Mo, W; X = F, Cl, Br, I): An inverse equilibrium isotope effect and an unprecedented halide dependence Journal of the American Chemical Society. 121: 11402-11417. DOI: 10.1021/Ja9920009  0.664
1999 Bergquist C, Parkin G. Protonation of the Hydroxide Ligand in a Synthetic Analogue of Carbonic Anhydrase, [TpBut,Me]ZnOH:  Inhibition of Reactivity Towards CO2 Journal of the American Chemical Society. 121: 6322-6323. DOI: 10.1021/Ja991134J  0.781
1999 Ghosh P, Rheingold AL, Parkin G. Synthesis and Molecular Structure of Bis(pyrazolyl)hydroborato Thallium {[Bp]Tl}2:  A [BpRR‘]Tl Complex with an Unbridged Close TlI···TlIContact Inorganic Chemistry. 38: 5464-5467. DOI: 10.1021/Ic990647O  0.617
1999 Ho Shin J, Parkin G. Synthesis and structure of [μ-PhP(C5Me4)2][Nb(μ-NBut)Cl]2, a novel dinuclear niobium complex supported by an ansa ligand Inorganic Chemistry Communications. 2: 428-430. DOI: 10.1016/S1387-7003(99)00114-8  0.447
1999 Dowling CM, Parkin G. Syntheses of [BpBut,Me]AlMe2 and [BpBut,Me]GaMe2: structural comparison of a pair of bis(pyrazolyl)hydroborato aluminum and gallium methyl complexes Polyhedron. 18: 3567-3571. DOI: 10.1016/S0277-5387(99)00305-8  0.388
1999 Ghosh P, Wood M, Bonanno JB, Hascall T, Parkin G. Bis(pyrazolylethyl)thioether ligation to zinc and cadmium: structural characterization of [S(CH2CH2pzMe2)2]ZnCl2, [S(CH2CH2pzMe2)2]CdI2 and [S(CH2CH2pzMe2)2]Cd(NO3)2 Polyhedron. 18: 1107-1113. DOI: 10.1016/S0277-5387(98)00396-9  0.595
1998 Ghosh P, Hascall T, Dowling C, Parkin G. Asymmetric bis(pyrazolyl)hydroborato ligands via direct synthesis: structural characterization of thallium and zinc complexes† Journal of the Chemical Society-Dalton Transactions. 3355-3358. DOI: 10.1039/A806298F  0.631
1998 Ghosh P, Parkin G. Mimicking the binding of glutamate to zinc in thermolysin and carboxypeptidase: the synthesis of [η3-(HCO2)BpBut,Pri]ZnCl by insertion of CO2 into a B–H bond of the bis(pyrazolyl)hydroborato zinc complex [BpBut,Pri]ZnCl Journal of the Chemical Society-Dalton Transactions. 2281-2284. DOI: 10.1039/A804025G  0.64
1998 Ghosh P, Bonanno JB, Parkin G. Synthesis and structure of [BpBut,Pri]2Co: a bis(pyrazolyl)hydroborato cobalt(II) complex with trans [Co · · · H–B] interactions Journal of the Chemical Society-Dalton Transactions. 2779-2782. DOI: 10.1039/A803862G  0.61
1998 Kuchta MC, Parkin G. Synthesis and structural characterization of [TpBut2]GaS: a terminal gallium sulfido complex in a system for which the indium counterpart is a tetrasulfido derivative, [TpBut2]In(η2-S4) Journal of the Chemical Society-Dalton Transactions. 2279-2280. DOI: 10.1039/A803566K  0.361
1998 Shin JH, Parkin G. Phosphorus–carbon bond activation of PMe3 at a dimolybdenum center: synthesis and structure of [Cp*Mo(µ-O2CMe)]2(µ-PMe2)(µ-Me) Chemical Communications. 1273-1274. DOI: 10.1039/A801835I  0.392
1998 Kuchta MC, Parkin G. Incorrect atom connectivity in X-ray structure solutions associated with a "‘partial polar ambiguity’': a non-macrocyclic structure for the macrocyclic lead complex, [η4-Me8taa]Pb New Journal of Chemistry. 22: 523-530. DOI: 10.1039/A709201F  0.356
1998 Kuchta MC, Hascall T, Parkin G. The synthesis and structure of {[η4-Me8taa]Sn(µ-O)}2: a bridging oxo complex in a system that yields terminal sulfido and selenido counterparts Chemical Communications. 751-752. DOI: 10.1039/A709065J  0.427
1998 Ghosh P, Parkin G. Modeling the active sites of bacteriophage T7 lysozyme, bovine 5-aminolevulinate dehydratase, and peptide deformylase: synthesis and structural characterization of a bis(pyrazolyl)(thioalkoxy)hydroborato zinc complex, [(Ph2CHS)BpBut,Pri]ZnI Chemical Communications. 413-414. DOI: 10.1039/A707444A  0.612
1998 Hascall T, Parkin G, Rheingold AL, Guzei I. Subvalent germanium and tin complexes supported by a dianionic calixarene ligand: structural characterization of exo and endo isomers of [Butcalix(TMS)2]Ge Chemical Communications. 101-102. DOI: 10.1039/A705937J  0.462
1998 Shin JH, Parkin G. Fluoro Complexes of Permethyltantalocene, Cp*2TaF3and [Cp*2TaF2][BF4]:  Facile Formation of a Tetrafluoroborate Complex via Corrosion of Borosilicate Glass Organometallics. 17: 5689-5696. DOI: 10.1021/Om980549V  0.403
1998 Kisko JL, Hascall T, Parkin G. The Synthesis, Structure, and Reactivity of Phenyl Tris(3-tert-butylpyrazolyl)borato Iron Methyl, [PhTpBut]FeMe:  Isolation of a Four-Coordinate Monovalent Iron Carbonyl Complex, [PhTpBut]FeCO Journal of the American Chemical Society. 120: 10561-10562. DOI: 10.1021/Ja982323P  0.304
1998 Ghosh P, Desrosiers PJ, Parkin G. Chemical Shift Anisotropy as a Mechanism for Modulating ApparentJTl-HandJTl-CCoupling Constants in Tris(pyrazolyl)hydroborato Thallium Complexes Journal of the American Chemical Society. 120: 10416-10422. DOI: 10.1021/Ja981636H  0.587
1998 Lee H, Hascall T, Desrosiers PJ, Parkin G. Synthesis and Structural Characterization of {[Me2Si(C5Me4)2]Zr(η2-C2H4)H}2Mg:  Anansa-Zirconocene Ethylene−Hydride Complex Journal of the American Chemical Society. 120: 5830-5831. DOI: 10.1021/Ja980813B  0.414
1998 Lee H, Desrosiers PJ, Guzei I, Rheingold AL, Parkin G. TheAnsa-Effect in Zirconocene Chemistry:  The Syntheses and Interconversions of the Hydride Complexes {[Me2Si(C5Me4)2]Zr(H)(μ-H)}2, [Me2Si(C5Me4)2]ZrH2(PMe3), and [Me2Si(C5Me4)2]Zr(Ph)H Journal of the American Chemical Society. 120: 3255-3256. DOI: 10.1021/Ja9742242  0.391
1998 Murphy VJ, Rabinovich D, Hascall T, Klooster WT, Koetzle TF, Parkin G. False minima in X-ray structure solutions associated with a 'partial polar ambiguity': Single crystal X-ray and neuron diffraction studies on the eight-coordinate tungsten hydride complexes, W(PMe3)4H2X2 (X = F, Cl, Br, I) and W(PMe3)4H2F(FHF) Journal of the American Chemical Society. 120: 4372-4387. DOI: 10.1021/Ja974086G  0.675
1998 Kuchta MC, Parkin G. Terminal chalcogenido complexes of Group 13 and 14 elements Coordination Chemistry Reviews. 176: 323-372. DOI: 10.1016/S0010-8545(98)00123-4  0.355
1997 Kimblin C, Hascall T, Parkin G. Modeling the Catalytic Site of Liver Alcohol Dehydrogenase: Synthesis and Structural Characterization of a [Bis(thioimidazolyl)(pyrazolyl)hydroborato]zinc Complex, [HB(tim(Me))(2)pz]ZnI. Inorganic Chemistry. 36: 5680-5681. PMID 11670182 DOI: 10.1021/Ic9710871  0.389
1997 Han R, Ghosh P, Desrosiers PJ, Trofimenko S, Parkin G. Synthesis and structural characterization of tris[3-trifluoromethyl-5-(2-thienyl)pyrazolyl]hydroborato thallium, Tl[TpCF3,Tn]: a monovalent thallium complex with a highly solvent dependent JTl–F coupling constant, ranging from 0 to 850 Hz Journal of the Chemical Society-Dalton Transactions. 3713-3718. DOI: 10.1039/A703496B  0.624
1997 Kisko JL, Hascall T, Parkin G. Multiple Bonding of Titanium and Vanadium to the Heavier Chalcogens:  Syntheses and Structures of the Terminal Selenido and Tellurido Complexes [η4-Me8taa]ME (M = Ti, V; E = Se, Te) Journal of the American Chemical Society. 119: 7609-7610. DOI: 10.1021/Ja971043R  0.385
1997 Kuchta MC, Parkin G. Terminal Chalcogenido Complexes of Gallium Supported by Tris(3,5-di-tert-butylpyrazolyl)hydroborato Ligation:  [TpBut2]GaE (E = Se, Te) Inorganic Chemistry. 36: 2492-2493. DOI: 10.1021/Ic970208U  0.36
1997 Dowling C, Ghosh P, Parkin G. Structural characterization of bis(pyrazolyl)hydroborato thallium complexes: monomeric “two-coordinate” thallium derivatives supplemented by [Tl…H-B] interactions Polyhedron. 16: 3469-3473. DOI: 10.1016/S0277-5387(97)00120-4  0.613
1997 Trnka TM, Parkin G. A survey of terminal chalcogenido complexes of the transition metals : Trends in their distribution and the variation of their M=E bond lengths Polyhedron. 16: 1031-1045. DOI: 10.1016/S0277-5387(96)00411-1  0.339
1997 Ghosh P, Parkin G. Synthesis and structure of a monomeric magnesium phenylselenolate complex [Tpp-Tol]MgSePh supported by tris (3-p-tolylpyrazolyl)hydroborato ligation Polyhedron. 16: 1255-1257. DOI: 10.1016/S0277-5387(96)00409-3  0.598
1997 Howard WA, Trnka TM, Waters M, Parkin G. Terminal chalcogenido complexes of zirconium: Syntheses and reactivity of Cp2*Zr(E)(NC5H5) (E = O, S, Se, Te) Journal of Organometallic Chemistry. 528: 95-121. DOI: 10.1016/S0022-328X(96)06584-9  0.667
1996 Ghosh P, Parkin G. Synthesis and Structure of a Magnesium Hydroxide Complex Supported by Tris(pyrazolyl)hydroborato Ligation, {[Tp(Ar,Me)]Mg(&mgr;-OH)}(2) (Ar = p-Bu(t)C(6)H(4)). Inorganic Chemistry. 35: 1429-1430. PMID 11666354 DOI: 10.1021/Ic9515970  0.658
1996 Kuchta MC, Dias HV, Bott SG, Parkin G. Synthesis and Structure of [Tp(Bu)()t()2]In, a Highly Twisted [Tris(3,5-di-tert-butylpyrazolyl)hydroborato]indium(I) Complex: Comparison with the Re-Evaluated Ordered Structure of [Tp(Bu)()t]In. Inorganic Chemistry. 35: 943-948. PMID 11666268 DOI: 10.1021/Ic9509948  0.381
1996 Kimblin C, Allen WE, Parkin G. The Synthesis and Structure ofTris[2-(1,4-diisopropylimidazolyl)]phosphine Zinc Nitrate, [PimPri2]Zn(NO3)2: Structural Consequences oft-ButylversusIsopropyl Substitution inTris(imidazolyl) phosphine Zinc Complexes Main Group Chemistry. 1: 297-300. DOI: 10.1080/13583149612331338577  0.426
1996 Kuchta MC, Parkin G. Oxidative-Addition Reactions of a Monomeric Indium(I) Complex Supported byTris(3,5-di-t-butylpyrazolyl)-hydroborato Ligation, [TpBut2]In: The Syntheses and Structures of [TpBut2]InI2and [TpBut2]In(η2-S4) Main Group Chemistry. 1: 291-295. DOI: 10.1080/13583149612331338567  0.379
1996 Kuchta MC, Parkin G. Comparison of the reactivity of germanium and tin terminal chalcogenido complexes: the syntheses of chalcogenolate and dichalcogenidostannacyclopentane derivatives Chemical Communications. 1669-1670. DOI: 10.1039/Cc9960001669  0.344
1996 Ghosh P, Parkin G. Terminal hydrochalcogenido and bridging selenido derivatives of magnesium supported by tris(3-p-tolylpyrazolyl)hydroborate ligation: the syntheses and structures of [Tpp-Tol]MgEH (E = S, Se) and {[Tpp-Tol]Mg}2Se Chemical Communications. 1239-1240. DOI: 10.1039/Cc9960001239  0.638
1996 Kimblin C, Murphy VJ, Parkin G. Tris(imidazolyl)phosphine cobalt complexes: structural comparisons with isoelectronic tris(pyrazolyl)hydroborato analogues Chemical Communications. 235-236. DOI: 10.1039/Cc9960000235  0.412
1996 Hascall T, Murphy VJ, Parkin G. Reversible C−H Bond Activation in Coordinatively Unsaturated Molybdenum Aryloxy Complexes, Mo(PMe3)4(OAr)H:  Comparison with Their Tungsten Analogs Organometallics. 15: 3910-3912. DOI: 10.1021/Om960553B  0.453
1996 Kuchta MC, Bonanno JB, Parkin G. A monovalent gallium complex supported by tris(3,5-di-tert-butylpyrazoylyl)hydroborato ligation: The synthesis and structures of [Tp(Bu(t)2)]Ga and its GaI3 adduct, [Tp(Bu(t)2)]Ga→GaI3 Journal of the American Chemical Society. 118: 10914-10915. DOI: 10.1021/Ja962698F  0.365
1996 Murphy VJ, Hascall T, Chen JY, Parkin G. Hydrogen Bonding to Transition Metal Fluoride Ligands:  The Synthesis and Structure of the Bifluoride Complex Mo(PMe3)4H2F(FHF) Journal of the American Chemical Society. 118: 7428-7429. DOI: 10.1021/Ja961350H  0.362
1996 Kuchta MC, Parkin G. Oxidative-addition to a four-coordinate tin(II) complex supported by octamethyldibenzotetraaza[14]annulene dianion ligation, [η4-Me8taa]Sn: The syntheses and structures of [η4-Me8taa]sni2 and {[η4-Me8taa]SnI(THF)}{l3} Polyhedron. 15: 4599-4602. DOI: 10.1016/0277-5387(96)00204-5  0.448
1996 Dowling C, Parkin G. Elaboration of the bis(pyrazolyl)hydroborato ligand [BpBut,Pri] into the NNO donor ligand, [(MeO)BpBut,Pri]: Structural characterization of a complex in which the [(MeO)BpBut,Pri] ligand models the binding of zinc to the peptide backbone in thermolysin Polyhedron. 15: 2463-2465. DOI: 10.1016/0277-5387(96)00014-9  0.426
1995 Dowling, CM, Leslie D, Chisholm MH, Parkin G. The Synthesis and Structural Characterization of the Sterically Demanding Tris (3,5-di-t-butylpyrazolyl) hydroborato Ligand, [TpBut2]: A Highly Twisted, Propeller-Like, Ligand System Main Group Chemistry. 1: 29-52. DOI: 10.1080/13583149512331338245  0.38
1995 Kimblin C, Allen WE, Parkin G. The synthesis and structure of {[PimPri,But]ZnOH}(ClO 4): A tris(imidazolyl)phosphine zinc hydroxide complex and a proposed structural model for carbonic anhydrase Journal of the Chemical Society, Chemical Communications. 1813-1815. DOI: 10.1039/C39950001813  0.381
1995 Murphy VJ, Rabinovich D, Halkyard S, Parkin G. Oxidative cleavage of the Te-Te bond in η2-ditellurido complexes: Syntheses and structures of M(PMe3)4(η 2-Te2)H2 (M=Mo, W) Journal of the Chemical Society, Chemical Communications. 1099-1100. DOI: 10.1039/C39950001099  0.661
1995 Howard WA, Trnka TM, Parkin G. Synthesis And Structure Of (Eta 5-C5Me5)2Zr(Se)Co, A Nonclassical D0 Zirconium Carbonyl Complex Organometallics. 14: 4037-4039. DOI: 10.1021/Om00009A003  0.311
1995 Shin JH, Parkin G. Selenium Complexes of Permethyltantalocene: Interesting Contrasts with Their Tellurium Analogs Organometallics. 14: 1104-1106. DOI: 10.1021/Om00003A010  0.318
1995 Looney A, Han R, Gorrell IB, Cornebise M, Yoon K, Parkin G, Rheingold AL. Monomeric Alkyl and Hydride Derivatives of Zinc Supported by Poly(pyrazoly)hydroborato Ligation: Synthetic, Structural, and Reactivity Studies Organometallics. 14: 274-288. DOI: 10.1021/Om00001A041  0.335
1995 Kuchta MC, Parkin G. Multiple Bonding to Indium: The Synthesis and Structure of [TpBut2]InSe, a Terminal Selenido Complex Supported by Tris(3,5-di-tert-butylpyrazolyl)hydroborato Ligation Journal of the American Chemical Society. 117: 12651-12652. DOI: 10.1021/Ja00155A036  0.408
1995 Murphy VJ, Rabinovich D, Parkin G. False Minima and the Perils of a Polar Axis in X-ray Structure Solutions: Molecular Structures of W(PMe3)4H2X2 (X = F, Cl, Br) and W(PMe3)4H2F2(H2O) Journal of the American Chemical Society. 117: 9762-9763. DOI: 10.1021/Ja00143A022  0.621
1995 Rabinovich D, Parkin G. Terminal Sulfido, Selenido, and Tellurido Complexes of Tungsten Inorganic Chemistry. 34: 6341-6361. DOI: 10.1021/Ic00129A021  0.657
1995 Howard WA, Trnka TM, Parkin G. Syntheses Of The Phenylchalcogenolate Complexes (Eta 5-C5Me5)2Zr(Eph)2 (E = O, S, Se, Te) And (Eta 5-C5H5)2Zr(Oph)2 : Structural Comparisons Within A Series Of Complexes Containing Zirconium-Chalcogen Single Bonds Inorganic Chemistry. 34: 5900-5909. DOI: 10.1021/Ic00127A031  0.432
1995 Howard WA, Parkin G, Rheingold AL. Non-classical carbonyl complexes of zirconium: The syntheses, characterization, and reactivities of (η5-C5Me5)2Zr(η2-E2)(CO) (E  S, Se, Te) Polyhedron. 14: 25-44. DOI: 10.1016/0277-5387(94)00320-E  0.394
1995 Yoon K, Parkin G. Tris(3-t-butyl-5-methylpyrazolyl)hydroborato derivatives of copper and thallium: The structural influence of a 5-methyl substituent Polyhedron. 14: 811-821. DOI: 10.1016/0277-5387(94)00300-4  0.356
1995 Han R, Parkin G, Trofimenko S. The tris[3-(9-anthryl)pyrazol-1-yl]hydroborato ligand, [TpAnt]: Compositional disorder between a vacancy and a chain of three atoms Polyhedron. 14: 387-391. DOI: 10.1016/0277-5387(94)00256-E  0.395
1995 Howard WA, Trnka TM, Parkin G. Syntheses of the phenylchalcogenolate complexes (η5-C5Me5)2Zr(EPh)2 (E = O, S, Se, Te) and (η5-C5H5)2Zr(OPh)2: Structural comparisons within a series of complexes containing zirconium-chalcogen single bonds Inorganic Chemistry. 34: 5900-5909.  0.326
1994 Kuchta MC, Parkin G. Multiple bonding between germanium and the chalcogens: The syntheses and structures of the terminal chalogenido complexes (η4-Me 8taa)GeE (E=S, Se, Te) Journal of the Chemical Society, Chemical Communications. 1351-1352. DOI: 10.1039/C39940001351  0.389
1994 Shin JH, Parkin G. Telluroformaldehyde, Tellurido, and Ditellurido Derivatives of Permethyltantalocene Organometallics. 13: 2147-2149. DOI: 10.1021/Om00018A004  0.322
1994 Kuchta MC, Parkin G. Terminal Sulfido and Selenido Complexes of Tin: Syntheses and Structures of [.eta.4-Me8taa]SnE (E = S, Se) Journal of the American Chemical Society. 116: 8372-8373. DOI: 10.1021/Ja00097A057  0.354
1994 Howard WA, Parkin G. Terminal oxo, sulfido, selenido, and tellurido complexes of zirconium, (.eta.5-C5Me4R)2Zr(E)(NC5H5): comparison of terminal Zr-E single and Zr:E double-bond lengths Journal of the American Chemical Society. 116: 606-615. DOI: 10.1021/Ja00081A022  0.309
1994 Han R, Parkin G. [Tris(3-tert-butylpyrazolyl)hydroborato]beryllium hydride: synthesis, structure, and reactivity of a terminal beryllium hydride complex. [Erratum to document cited in CA116:142684] Inorganic Chemistry. 33: 3848-3848. DOI: 10.1021/Ic00095A035  0.333
1994 Rabinovich D, Parkin G. Syntheses, Structures, and Reactivities of Terminal Selenido Complexes of Tungsten Inorganic Chemistry. 33: 2313-2314. DOI: 10.1021/Ic00089A001  0.624
1994 Looney A, Saleh A, Zhang Y, Parkin G. Tris(pyrazolyl)hydroborato Complexes of Cadmium: A Bidentate Nitrate Derivative and Its Relevance to Carbonic Anhydrase Activity Inorganic Chemistry. 33: 1158-1164. DOI: 10.1021/Ic00084A031  0.422
1994 Shin JH, Parkin G. The syntheses, structures and reactivity of some mononuclear and dinuclear pentamethylcyclopentadienyl molybdenum complexes Polyhedron. 13: 1489-1493. DOI: 10.1016/S0277-5387(00)81719-2  0.471
1994 A. Howard W, Parkin G. Multiple bonds between hafnium and the chalcogens: syntheses and structures of the terminal chalcogenido complexes (η15-C5Me4R)2Hf(E)(NC5 H5) (E  O, S, Se, Te) Journal of Organometallic Chemistry. 472: c1-c4. DOI: 10.1016/0022-328X(94)80226-2  0.393
1993 Howard WA, Parkin G. Interconversion of hydrosulfido and sulfido ligands in permethylzirconocene complexes Organometallics. 12: 2363-2366. DOI: 10.1021/Om00030A053  0.39
1993 Rabinovich D, Parkin G. Isocyanide-induced coupling of terminal tellurido ligands: the synthesis and structure of W(PMe3)(CN-tert-Bu)4(.eta.2-Te2) Journal of the American Chemical Society. 115: 9822-9823. DOI: 10.1021/Ja00074A068  0.648
1993 Howard WA, Waters M, Parkin G. Terminal zirconium oxo complexes: Synthesis, structure, and reactivity of (η5-C5Me4R)2Zr(O)(NC 5H4R′) Journal of the American Chemical Society. 115: 4917-4918. DOI: 10.1021/Ja00064A074  0.652
1993 Looney A, Han R, McNeill K, Parkin G. Tris(pyrazolyl)hydroboratozinc hydroxide complexes as functional models for carbonic anhydrase: on the nature of the bicarbonate intermediate Journal of the American Chemical Society. 115: 4690-4697. DOI: 10.1021/Ja00064A033  0.442
1993 Rabinovich D, Parkin G. Mechanistic study of the oxidative addition of dihydrogen to tetrakis(trimethylphosphine)diiodotungsten: observation of an inverse equilibrium isotope effect Journal of the American Chemical Society. 115: 353-354. DOI: 10.1021/Ja00054A055  0.626
1993 Han R, Parkin G. Synthesis, structure, and reactivity of {.eta.3-HB(3-tert-Bupz)3}BeCH3, a terminal beryllium alkyl complex supported by tris(3-tert-butylpyrazolyl)hydroborato ligation Inorganic Chemistry. 32: 4968-4970. DOI: 10.1021/Ic00074A050  0.396
1993 Parkin G. Bond-stretch isomerism in transition metal complexes: a reevaluation of crystallographic data Chemical Reviews. 93: 887-911. DOI: 10.1021/Cr00019A003  0.346
1993 Howard WA, Parkin G. Hydrogen bonding of H2O to the hydroxo ligands of Cp*2Zr(OH)2: implications for proton and oxygen exchange processes. The crystal and molecular structure of the hydrate Cp*2Zr(OH)2 · (H2O) Polyhedron. 12: 1253-1256. DOI: 10.1016/S0277-5387(00)88220-0  0.399
1993 Libertini E, Yoon K, Parkin G. The synthesis of [HB]3,5-(Butph)2pz]3]− (Butph = p-C6H4But), a new tris(pyrazolyl)hydroborato ligand: the crystal and molecular structure of Tl{η3-HB[3,5-(Butph)2pz]3} Polyhedron. 12: 2539-2542. DOI: 10.1016/S0277-5387(00)83081-8  0.41
1993 Antonelli DM, Schaefer WP, Parkin G, Bercaw JE. Synthesis and characterization of (η5-C5Me5) 2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene Journal of Organometallic Chemistry. 462: 213-220. DOI: 10.1016/0022-328X(93)83360-8  0.605
1992 Yoon K, Parkin G, Hughes DL, Leigh GJ. Origin of the two significantly different W–Cl bond lengths for chemically equivalent bonds in mer-[WCl3(PMe2Ph)3] Journal of the Chemical Society-Dalton Transactions. 769-773. DOI: 10.1039/Dt9920000769  0.306
1992 Nelson JE, Parkin G, Bercaw JE. Synthesis and characterization of thioaldehyde hydride derivatives of permethyltantalocene. Investigations of their equilibration with thiolates and the stereochemistry of alkyl migrations from sulfur to tantalum Organometallics. 11: 2181-2189. DOI: 10.1021/Om00042A036  0.605
1992 Rabinovich D, Zelman R, Parkin G. Synthetic, structural, and mechanistic studies of the carbon-hydrogen bond activation of phenols by tungsten complexes W(PMe3)6 and W(PMe3)4(.eta.2-CH2PMe2)H Journal of the American Chemical Society. 114: 4611-4621. DOI: 10.1021/Ja00038A025  0.714
1992 Yoon K, Parkin G, Rheingold AL. Bond-stretch isomerism in the chlorooxomolybdenum complexes cis-mer-MoOCl2(PR3)3: a reinvestigation Journal of the American Chemical Society. 114: 2210-2218. DOI: 10.1021/Ja00032A041  0.399
1992 Han R, Parkin G. [Tris(pyrazolyl)hydroborato]magnesium alkyl derivatives: reactivity studies Journal of the American Chemical Society. 114: 748-757. DOI: 10.1021/Ja00028A051  0.323
1992 Yoon K, Parkin G. Resolved and unresolved crystallographic disorder between cyano-.eta.3-[hydrotris(3-tert-butylpyrazolyl)borato]zinc and the halo analogs. Inorganic Chemistry. 31: 1656-1662. DOI: 10.1021/Ic00035A026  0.356
1992 Looney AG, Cornebise M, Miller D, Parkin G. Synthesis and reactivity of zinc and aluminum alkyl derivatives stabilized by oxygen tripod ligands Inorganic Chemistry. 31: 989-992. DOI: 10.1021/Ic00032A013  0.339
1992 Han R, Parkin G. [Tris(3-tert-butylpyrazolyl)hydroborato]beryllium hydride: synthesis, structure, and reactivity of a terminal beryllium hydride complex Inorganic Chemistry. 31: 983-988. DOI: 10.1021/Ic00032A012  0.435
1992 Parkin G, Van Asselt A, Leahy DJ, Whinnery L, Hua NG, Quan RW, Henling LM, Schaefer WP, Santarsiero BD, Bercaw JE. Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (.eta.5-C5Me5)2Ta(:O)H and (.eta.5-C5Me5)2Ta(:NC6H5)H: doubly or triply bonded tantalum oxo and imido ligands? Inorganic Chemistry. 31: 82-85. DOI: 10.1021/Ic00027A016  0.588
1992 Parkin G. Do bond-stretch isomers really exist? Accounts of Chemical Research. 25: 455-460. DOI: 10.1021/Ar00022A004  0.316
1991 Han R, Gorrell IB, Looney AG, Parkin G. Tris(3-tert-butylpyrazolyl)hydroborato zinc hydride: synthesis, structure and reactivity of a monomeric zinc hydride derivative Journal of the Chemical Society, Chemical Communications. 717-719. DOI: 10.1039/C39910000717  0.385
1991 Han R, Parkin G. [Tris(pyrazolyl)hydroborato]magnesium alkyl derivatives: synthetic and structural studies Organometallics. 10: 1010-1020. DOI: 10.1021/Om00050A036  0.385
1991 Gibson VC, Parkin G, Bercaw JE. Synthesis and reactivity of permethyltantalocene derivatives processing .eta.3-allyl, .eta.2-butadiene, .eta.2-methylallene, and .eta.1-alkenylidene ligands. Model studies for the role of surface vinylidenes in the Fischer-Tropsch hydrocarbon-chain-lengthening process Organometallics. 10: 220-231. DOI: 10.1021/Om00047A053  0.65
1991 Han R, Parkin G. Unidentate versus bidentate coordination of nitrate ligands: relevance to carbonic anhydrase activity Journal of the American Chemical Society. 113: 9707-9708. DOI: 10.1021/Ja00025A065  0.332
1991 Rabinovich D, Parkin G. Synthesis and structure of W(PMe3)4(Te)2: the first transition-metal complex with a terminal tellurido ligand Journal of the American Chemical Society. 113: 9421-9422. DOI: 10.1021/Ja00024A088  0.66
1991 Rabinovich D, Parkin G. The syntheses, structures, and reactivity of monomeric tungsten(IV) and tungsten(VI) bis(sulfido) complexes: facile elimination of hydrogen from hydrogen sulfide Journal of the American Chemical Society. 113: 5904-5905. DOI: 10.1021/Ja00015A078  0.667
1991 Yoon K, Parkin G, Rheingold AL. A reinvestigation of the molecular structures of cis-mer-MoOCl2(PR3)3: do bond-stretch isomers really exist? Journal of the American Chemical Society. 113: 1437-1438. DOI: 10.1021/Ja00004A068  0.309
1991 Alsfasser R, Trofimenko S, Looney A, Parkin G, Vahrenkamp H. A mononuclear zinc hydroxide complex stabilized by a highly substituted tris(pyrazolyl)hydroborato ligand: analogies with the enzyme carbonic anhydrase Inorganic Chemistry. 30: 4098-4100. DOI: 10.1021/Ic00021A026  0.363
1991 Looney A, Parkin G, Rheingold AL. Anion coordination by protonated tris(pyrazolyl)hydroborato derivatives: crystal structure of the host-guest complex [{.eta.3-HB(3-tert-Bu-pzH)3}Cl] [AlCl4] Inorganic Chemistry. 30: 3099-3101. DOI: 10.1021/Ic00015A031  0.395
1990 Gorrell IB, Looney A, Parkin G. Tris(pyrazolyl)hydroboratozinc alkyl derivatives: direct comparison of the reactivity of Zn-C and Mg-C bonds Journal of the Chemical Society, Chemical Communications. 220-222. DOI: 10.1039/C39900000220  0.358
1990 Rabinovich D, Zelman R, Parkin G. Competitive sp3 and sp2 carbon-hydrogen bond activation of phenols by W(PMe3)6 and W(PMe3)4(.eta.2-CH2PMe2)H: formation of four- and five-membered oxametallacycles Journal of the American Chemical Society. 112: 9632-9633. DOI: 10.1021/Ja00182A029  0.626
1990 Rabinovich D, Parkin G. Hexakis(trimethylphosphine)tungsten(0): synthesis, structure, and reactivity Journal of the American Chemical Society. 112: 5381-5383. DOI: 10.1021/Ja00169A073  0.611
1990 Gorrell IB, Looney A, Parkin G, Rheingold AL. [Bis(3-tert-butylpyrazolyl)hydroborato]zinc alkyl derivatives: competitive reactivity of zinc-carbon and boron-hydrogen bonds Journal of the American Chemical Society. 112: 4068-4069. DOI: 10.1021/Ja00166A070  0.342
1990 Han R, Parkin G. Insertion of oxygen into the magnesium-carbon bonds of the alkyl derivatives {.eta.3-HB(3-tert-Bupz)3}MgR [R = CH3, CH2CH3, CH(CH3)2, C(CH3)3]. Formation of alkylperoxo derivatives and oxygen atom transfer Journal of the American Chemical Society. 112: 3662-3663. DOI: 10.1021/Ja00165A063  0.376
1990 Han R, Parkin G. Reaction of O2 with {η3-HB(3-Butpz)3}MgCH2Si(CH3)3: Facile SiC bond cleavage and formation of {η3-HB( Polyhedron. 9: 2655-2657. DOI: 10.1016/S0277-5387(00)86844-8  0.369
1990 Han R, Bachrach M, Parkin G. Competitive alkyl and halide metathesis in the reactions of grignard reagents with Tl{η3-HB(3-Butpz)3} Polyhedron. 9: 1775-1778. DOI: 10.1016/S0277-5387(00)83987-X  0.379
1990 Looney A, Parkin G. Poly(pyrazolyl)hydroborato and poly(pyrazolyl)methane aluminium alkyl derivatives Polyhedron. 9: 265-276. DOI: 10.1016/S0277-5387(00)80579-3  0.399
1990 Han R, Parkin G. Ligand redistribution reactions of tris(3,5-dimethylpyrazolyl)hydroboratomagnesium alkyl derivatives: crystal structure of {η3-HB(3,5-Me2pz)3}2Mg Journal of Organometallic Chemistry. 393. DOI: 10.1016/0022-328X(90)85177-Z  0.376
1990 RABINOVICH D, PARKIN G. ChemInform Abstract: Hexakis(trimethylphosphine)tungsten(0): Synthesis, Structure, and Reactivity. Cheminform. 21. DOI: 10.1002/CHIN.199041262  0.575
1989 Parkin G, Bercaw JE. Direct protonation of the W–H bonds of bis(pentamethylcyclopentadienyl)tungsten dihydride Journal of the Chemical Society, Chemical Communications. 255-257. DOI: 10.1039/C39890000255  0.536
1989 Parkin G, Bercaw JE. Elimination processes for alkyl, hydride, and hydroxy derivatives of permethyltungstenocene Organometallics. 8: 1172-1179. DOI: 10.1021/Om00107A008  0.487
1989 Han R, Looney A, Parkin G. Tris(pyrazolyl)hydroboratomagnesium and aluminum alkyl derivatives: alkyl exchange with methyl iodide and enolate formation with acetone Journal of the American Chemical Society. 111: 7276-7278. DOI: 10.1021/Ja00200A066  0.32
1989 Parkin G, Bercaw JE. (.eta.5-C5Me5)2W:O: an exceptionally reactive organometallic oxo derivative. Reduction with dihydrogen and reaction with dioxygen resulting in insertion of oxygen into a tungsten-carbon bond Journal of the American Chemical Society. 111: 391-393. DOI: 10.1021/Ja00183A072  0.531
1988 Parkin G, Marsh RE, Schaefer WP, Bercaw JE. Structure of (pentamethylcyclopentadienyl)((pentamethylcyclopentadienyl)oxy)dioxotungsten(VI) , (η5-C5Me5)W(O)2(OC 5Me5). Structural evidence for the strong trans influence of the oxo ligand Inorganic Chemistry. 27: 3262-3264. DOI: 10.1021/Ic00291A052  0.54
1988 Parkin G, Bercaw JE. Halide, hydride, alkyl, oxo and related derivatives of bis(pentamethylcyclopentadienyl)tungsten(IV) Polyhedron. 7: 2053-2082. DOI: 10.1016/S0277-5387(00)80724-X  0.546
1987 Green MLH, Parkin G. Synthesis of (η-cyclopentadienyl)(trimethylphosphine)tungsten derivatives and related chemistry Journal of the Chemical Society-Dalton Transactions. 1611-1618. DOI: 10.1039/Dt9870001611  0.375
1987 Parkin G, Bunel E, Burger BJ, Trimmer MS, Van Asselt A, Bercaw JE. Alpha- and beta-migratory insertion and elimination processes for alkyl complexes of permethyl-scandocene and permethyltantalocene Journal of Molecular Catalysis. 41: 21-39. DOI: 10.1016/0304-5102(87)80017-2  0.77
1986 Green MLH, Parkin G, Chen M, Prout K. The chemistry of [W(PMe3)4(η2-CH2PMe2)H]: synthesis of hydroxy-hydrido, fluoro-hydrido, and silyl-hydrido derivatives and the dimerisation of ethylene and propene giving η4-diene derivatives. Crystal structure of [W(PMe3)4H2(OH2)F]F Journal of the Chemical Society-Dalton Transactions. 2227-2236. DOI: 10.1039/Dt9860002227  0.398
1986 Green MLH, Parkin G. Ethylene insertion into the W–C bond of the η2-formaldehyde ligand system of W(PMe3)4(η2-CH2O)H2 giving the oxometallacyclopentane derivative W(OCH2CH2CH2)(PMe3)2(C2H4)2 and related studies Journal of the Chemical Society, Chemical Communications. 90-91. DOI: 10.1039/C39860000090  0.413
1986 Green ML, Parkin G, O'Hare D, Wong L, Derome AE. The reaction of [W(PMe3)4(η2-CH2PMe2)H] with carbon dioxide and dihydrogen: characterisation of [{W(PMe3)3(η1-PMe2CH2)}2(C3H2O6)] using two-dimensional nuclear magnetic resonance spectroscopy Journal of Organometallic Chemistry. 317: 61-68. DOI: 10.1016/S0022-328X(00)99345-8  0.762
1985 Green MLH, Parkin G. The synthesis of electron-rich η-cyclopentadienyl trimethylphosphine complexes of tungsten Journal of the Chemical Society, Chemical Communications. 1383-1384. DOI: 10.1039/C39850001383  0.401
1985 Green MLH, Parkin G. η-Arene and η-cyclohexadiene tungsten chemistry: new synthetic routes to tertiary phosphine–hydride derivatives Journal of the Chemical Society, Chemical Communications. 771-773. DOI: 10.1039/C39850000771  0.389
1985 Green MLH, O'Hare D, Parkin G. Formation of η-benzene or η-cyclohexa-1,3-diene compounds of chromium, tungsten, and rhenium from cyclohexane and the metal atoms Journal of the Chemical Society, Chemical Communications. 356-357. DOI: 10.1039/C39850000356  0.544
1985 Kilner M, Parkin G, Talbot AG. Synthetic use of lithium nitride, an unusual reducing agent. Formation of Ti4 and Ti6 complexes Journal of the Chemical Society, Chemical Communications. 34-35. DOI: 10.1039/C39850000034  0.306
1984 Green MLH, Parkin G, Moynihan KJ, Prout K. Formation of an η2-formaldehyde compound from methanol and its hydrogenation giving methanol Journal of the Chemical Society, Chemical Communications. 1540-1540. DOI: 10.1039/C39840001540  0.4
1984 Green MLH, Parkin G. Formation of η-cyclopentadienylpentahydrido(trimethylphosphine)tungsten from cyclopentane, trimethylphosphine, and tungsten atoms Journal of the Chemical Society, Chemical Communications. 1467-1468. DOI: 10.1039/C39840001467  0.354
1984 Green MLH, Parkin G, Mingqin C, Prout K. Trimethylphosphine–tungsten chemistry: hydrido, silyl, fluoro, hydroxy, and aquo derivatives: crystal structure of [W(PMe3)4H2(OH2)F]F Journal of the Chemical Society, Chemical Communications. 1400-1402. DOI: 10.1039/C39840001400  0.349
1983 GREEN MLH, PARKIN G, BASHKIN J, FAIL J, PROUT K. ChemInform Abstract: SYNTHETIC PATHWAYS IN BINUCLEAR MOLYBDENUM CHEMISTRY: μ-ACETATO-, CHLORO-, AND TERTIARY PHOSPHINE DERIVATIVES: X-RAY STRUCTURE DETERMINATION OF TRANS-((MOCL(PBU3)(μ-O2CME))2 Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198312278  0.656
1982 Green MLH, Parkin G, Bashkin J, Fail J, Prout K. Synthetic pathways in binuclear molybdenum chemistry: μ-acetato-, chloro-, and tertiary phosphine derivatives; X-ray structure determination of trans-[{MoCl(PBun3)(μ-O2CMe)}2] Journal of the Chemical Society, Dalton Transactions. 2519-2525. DOI: 10.1039/Dt9820002519  0.685
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