Nobuharu Iwasawa - Publications

Affiliations: 
Tokyo Institute of Technology 

220 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Fujimaki Y, Iwasawa N, Takaya J. Merging the Norrish type I reaction and transition metal catalysis: photo- and Rh-promoted borylation of C-C σ-bonds of aryl ketones. Chemical Science. 14: 1960-1965. PMID 36845921 DOI: 10.1039/d2sc06801j  0.392
2022 Fukuda K, Harada T, Iwasawa N, Takaya J. Facile synthesis and utilization of bis(-phosphinophenyl)zinc as isolable PZnP-pincer ligands enabled by boron-zinc double transmetallation. Dalton Transactions (Cambridge, England : 2003). PMID 35481921 DOI: 10.1039/d2dt01222g  0.333
2021 Saito T, Caner J, Toriumi N, Iwasawa N. Rhodium-catalyzed meta-Selective C-H Carboxylation Reaction of 1,1-Diarylethylenes via Hydrorhodation-Rhodium Migration. Angewandte Chemie (International Ed. in English). PMID 34402148 DOI: 10.1002/anie.202109470  0.376
2020 Homma Y, Fukuda K, Iwasawa N, Takaya J. Ruthenium-catalyzed regio- and site-selective C-H borylation of phenol derivatives. Chemical Communications (Cambridge, England). 56: 10710-10713. PMID 32789342 DOI: 10.1039/D0Cc02889D  0.367
2020 Saito T, Jin Y, Isobe K, Suga T, Takaya J, Iwasawa N. Rh-Catalyzed Direct Carboxylation of Alkenyl C-H Bonds of Alkenylpyrazoles. Chemistry, An Asian Journal. PMID 32415807 DOI: 10.1002/Asia.202000476  0.361
2020 Ito T, Iwasawa N, Takaya J. Photo-promoted Skeletal Rearrangement of Phosphine-Borane Frustrated Lewis Pairs Involving Cleavage of Unstrained C-C σ-Bonds. Angewandte Chemie (International Ed. in English). PMID 32329933 DOI: 10.1002/Anie.202004444  0.423
2020 Takata H, Ono K, Iwasawa N. Controlled release of the guest molecule via borate formation of a fluorinated boronic ester cage. Chemical Communications (Cambridge, England). PMID 32297611 DOI: 10.1039/D0Cc01441A  0.312
2020 Takahashi K, Hirataka Y, Ito T, Iwasawa N. Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO2 Organometallics. 39: 1561-1572. DOI: 10.1021/Acs.Organomet.9B00659  0.383
2019 Ono K, Niibe M, Iwasawa N. A K-promoted Diels-Alder reaction by using a self-assembled macrocyclic boronic ester containing two crown ether moieties. Chemical Science. 10: 7627-7632. PMID 31588314 DOI: 10.1039/C9Sc01597C  0.423
2019 Yamada R, Iwasawa N, Takaya J. Rhodium-Catalyzed C-H Activation Enabled by an Indium Metalloligand. Angewandte Chemie (International Ed. in English). 58: 17251-17254. PMID 31559666 DOI: 10.1002/Anie.201910197  0.316
2019 Takaya J, Hoshino M, Ueki K, Saito N, Iwasawa N. Synthesis, structure, and reactivity of pincer-type iridium complexes having gallyl- and indyl-metalloligands utilizing 2,5-bis(6-phosphino-2-pyridyl)pyrrolide as a new scaffold for metal-metal bonds. Dalton Transactions (Cambridge, England : 2003). 48: 14606-14610. PMID 31549112 DOI: 10.1039/C9Dt03443A  0.38
2019 Takahashi K, Cho K, Iwai A, Ito T, Iwasawa N. Development of N-Phosphinomethyl-substituted NHC-Nickel(0) Complexes as Robust Catalysts for Acrylate Salt Synthesis from Ethylene and CO2. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31464036 DOI: 10.1002/Chem.201903625  0.342
2019 Murata K, Numasawa N, Shimomaki K, Takaya J, Iwasawa N. Improved Conditions for the Visible-Light Driven Hydrocarboxylation by Rh(I) and Photoredox Dual Catalysts Based on the Mechanistic Analyses. Frontiers in Chemistry. 7: 371. PMID 31231630 DOI: 10.3389/Fchem.2019.00371  0.364
2019 Shimomaki K, Nakajima T, Caner J, Toriumi N, Iwasawa N. Palladium-Catalyzed Visible-Light-Driven Carboxylation of Aryl and Alkenyl Triflates by Using Photoredox Catalysts. Organic Letters. 21: 4486-4489. PMID 31180681 DOI: 10.1021/Acs.Orglett.9B01340  0.39
2019 Saito N, Takaya J, Iwasawa N. Stabilized Gallylene in a Pincer-Type Ligand: Synthesis, Structure, and Reactivity of PGa P-Ir Complexes. Angewandte Chemie (International Ed. in English). 58: 9998-10002. PMID 31081223 DOI: 10.1002/Anie.201904968  0.359
2019 Takahashi K, Shimo S, Hupf E, Ochiai J, Braun C, Delgado W, Xu L, He G, Rivard E, Iwasawa N. Self-assembly of macrocyclic boronic esters bearing tellurophene moieties and their guest responsive phosphorescence. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31034114 DOI: 10.1002/Chem.201901319  0.338
2019 Watanabe S, Ario A, Iwasawa N. Re(I)-catalyzed hydropropargylation of enamides: a useful method for the preparation of 4-pentynylamine derivatives. The Journal of Antibiotics. 72: 490-493. PMID 30846847 DOI: 10.1038/S41429-019-0162-3  0.522
2019 Fukuda K, Iwasawa N, Takaya J. Ruthenium-Catalyzed ortho C-H Borylation of Arylphosphines. Angewandte Chemie (International Ed. in English). 58: 2850-2853. PMID 30663212 DOI: 10.1002/Anie.201813278  0.444
2019 Ito T, Takahashi K, Iwasawa N. Reactivity of a Ruthenium(0) Complex Bearing a Tetradentate Phosphine Ligand: Applications to Catalytic Acrylate Salt Synthesis from Ethylene and CO2 Organometallics. 38: 205-209. DOI: 10.1021/Acs.Organomet.8B00789  0.412
2018 Iwasawa N, Watanabe S, Ario A, Sogo H. Re(I)-Catalyzed Hydropropargylation of Silyl Enol Ethers Utilizing Dynamic Interconversion of Vinylidene-Alkenylmetal Intermediates via 1,5-Hydride Transfer. Journal of the American Chemical Society. 140: 7769-7772. PMID 29894186 DOI: 10.1021/Jacs.8B02903  0.433
2018 Ono K, Shimo S, Takahashi K, Yasuda N, Uekusa H, Iwasawa N. Dynamic Interconversion among Boroxine Cages Based on Pyridine Ligation. Angewandte Chemie (International Ed. in English). PMID 29380501 DOI: 10.1002/Anie.201713221  0.325
2018 Uchikura T, Ono K, Takahashi K, Iwasawa N. Utilization of Donor-Acceptor Interaction for the Catalytic Acceleration of the Nucleophilic Addition to Aromatic Carbonyl Compounds. Angewandte Chemie (International Ed. in English). PMID 29314440 DOI: 10.1002/Anie.201711726  0.381
2018 Takaya J, Iwasawa N. Synthesis, Structure, and Reactivity of a Mononuclear η2‐(Ge–H)palladium(0) Complex Bearing a PGeP‐Pincer‐Type Germyl Ligand: Reactivity Differences between Silicon and Germanium European Journal of Inorganic Chemistry. 2018: 5012-5018. DOI: 10.1002/Ejic.201801257  0.356
2017 Shimomaki K, Murata K, Martin R, Iwasawa N. Visible Light-Driven Carboxylation of Aryl Halides by the Combined Use of Palladium and Photoredox Catalysts. Journal of the American Chemical Society. PMID 28657743 DOI: 10.1021/Jacs.7B04838  0.388
2017 Suga T, Saitou T, Takaya J, Iwasawa N. Mechanistic study of the rhodium-catalyzed carboxylation of simple aromatic compounds with carbon dioxide. Chemical Science. 8: 1454-1462. PMID 28616144 DOI: 10.1039/C6Sc03838G  0.392
2017 Takaya J, Iwasawa N. Synthesis, Structure, and Catalysis of Palladium Complexes Bearing a Group 13 Metalloligand: Remarkable Effect of an Aluminum-Metalloligand in Hydrosilylation of CO. Journal of the American Chemical Society. 139: 6074-6077. PMID 28423896 DOI: 10.1021/Jacs.7B02553  0.345
2017 Takaya J, Miyama K, Zhu C, Iwasawa N. Metallic reductant-free synthesis of α-substituted propionic acid derivatives through hydrocarboxylation of alkenes with a formate salt. Chemical Communications (Cambridge, England). PMID 28333168 DOI: 10.1039/C7Cc01377A  0.47
2017 Murata K, Numasawa N, Shimomaki K, Takaya J, Iwasawa N. Construction of a visible light-driven hydrocarboxylation cycle of alkenes by the combined use of Rh(i) and photoredox catalysts. Chemical Communications (Cambridge, England). 53: 3098-3101. PMID 28243662 DOI: 10.1039/C7Cc00678K  0.315
2017 Ono K, Tohyama Y, Uchikura T, Kikuchi Y, Fujii K, Uekusa H, Iwasawa N. Control of the reversibility during boronic ester formation: application to the construction of ferrocene dimers and trimers. Dalton Transactions (Cambridge, England : 2003). PMID 28139793 DOI: 10.1039/C6Dt04845E  0.378
2017 Imayoshi R, Nakajima K, Takaya J, Iwasawa N, Nishibayashi Y. Front Cover: Synthesis and Reactivity of Iron– and Cobalt–Dinitrogen Complexes Bearing PSiP‐Type Pincer Ligands toward Nitrogen Fixation (Eur. J. Inorg. Chem. 32/2017) European Journal of Inorganic Chemistry. 2017: 3767-3767. DOI: 10.1002/Ejic.201700862  0.353
2017 Imayoshi R, Nakajima K, Takaya J, Iwasawa N, Nishibayashi Y. Synthesis and Reactivity of Iron– and Cobalt–Dinitrogen Complexes Bearing PSiP‐Type Pincer Ligands toward Nitrogen Fixation European Journal of Inorganic Chemistry. 2017: 3769-3778. DOI: 10.1002/Ejic.201700569  0.39
2016 Sogo H, Iwasawa N. Rhenium(I)-Catalyzed Generation of α,β-Unsaturated Carbene Complex Intermediates from Propargyl Ethers for the Preparation of Cycloheptadiene Derivatives. Angewandte Chemie (International Ed. in English). 55: 10057-60. PMID 27391557 DOI: 10.1002/Anie.201604371  0.488
2016 Shimomaki K, Kusama H, Iwasawa N. Total Synthesis of (±)-Integrifolin. Chemistry (Weinheim An Der Bergstrasse, Germany). 22: 9953-7. PMID 27147582 DOI: 10.1002/Chem.201601275  0.364
2016 Kusama H, Tazawa A, Ishida K, Iwasawa N. Total Synthesis of (±)-Englerin A Using An Intermolecular [3+2] Cycloaddition Reaction of Platinum-Containing Carbonyl Ylide. Chemistry, An Asian Journal. 11: 64-7. PMID 26377511 DOI: 10.1002/Asia.201500935  0.471
2016 Kusama H, Tazawa A, Ishida K, Iwasawa N. Total Synthesis of (±)-Englerin A Using An Intermolecular [3+2] Cycloaddition Reaction of Platinum-Containing Carbonyl Ylide Chemistry - An Asian Journal. 11: 64-67. DOI: 10.1002/asia.201500935  0.367
2015 Takaya J, Ito S, Nomoto H, Saito N, Kirai N, Iwasawa N. Fluorine-controlled C-H borylation of arenes catalyzed by a PSiN-pincer platinum complex. Chemical Communications (Cambridge, England). PMID 26436574 DOI: 10.1039/C5Cc07263H  0.457
2015 Ohyama T, Uchida M, Kusama H, Iwasawa N. Total Synthesis of Proposed Structure of Yuremamine and All Diastereomers Using [3+2]-Cycloaddition of Platinum-Containing Azomethine Ylide. Chemistry, An Asian Journal. 10: 1850-3. PMID 26103522 DOI: 10.1002/Asia.201500491  0.41
2015 Zhu C, Takaya J, Iwasawa N. Use of formate salts as a hydride and a co2 source in PGeP-palladium complex-catalyzed hydrocarboxylation of allenes. Organic Letters. 17: 1814-7. PMID 25794110 DOI: 10.1021/Acs.Orglett.5B00692  0.41
2014 Kikuchi Y, Ono K, Johmoto K, Uekusa H, Iwasawa N. Inclusion of two different guest molecules within a rationally designed macrocyclic boronic ester in organic solvent. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 15737-41. PMID 25336243 DOI: 10.1002/Chem.201405163  0.321
2014 Suga T, Mizuno H, Takaya J, Iwasawa N. Direct carboxylation of simple arenes with CO₂ through a rhodium-catalyzed C-H bond activation. Chemical Communications (Cambridge, England). 50: 14360-3. PMID 25296263 DOI: 10.1039/C4Cc06188H  0.339
2014 Takaya J, Iwasawa N. Silyl ligand mediated reversible β-hydrogen elimination and hydrometalation at palladium. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11812-9. PMID 25080222 DOI: 10.1002/Chem.201403220  0.363
2014 Kikuchi Y, Takahagi H, Ono K, Iwasawa N. Enhancement of host-guest interactions using rationally designed macrocyclic boronic esters with a naphthalene core. Chemistry, An Asian Journal. 9: 1001-5. PMID 24488933 DOI: 10.1002/Asia.201301577  0.311
2014 Takaya J, Kirai N, Iwasawa N. Mechanistic Studies on the Stereoisomerization between Two Stereoisomeric, Isolable Five-Coordinate Borylpalladium(II) Complexes Bearing a Phenylene-Bridged PSiP-Pincer Type Ligand Organometallics. 33: 1499-1502. DOI: 10.1021/Om401004C  0.305
2013 Ito S, Takata H, Ono K, Iwasawa N. Release and recovery of guest molecules during the reversible borate gel formation of guest-included macrocyclic boronic esters. Angewandte Chemie (International Ed. in English). 52: 11045-8. PMID 24038674 DOI: 10.1002/Anie.201303870  0.331
2013 Watanabe E, Kaiho A, Kusama H, Iwasawa N. Cobalt-salen complex-catalyzed oxidative generation of alkyl radicals from aldehydes for the preparation of hydroperoxides. Journal of the American Chemical Society. 135: 11744-7. PMID 23915227 DOI: 10.1021/Ja406028C  0.424
2013 Sasano K, Takaya J, Iwasawa N. Palladium(II)-catalyzed direct carboxylation of alkenyl C-H bonds with CO2. Journal of the American Chemical Society. 135: 10954-7. PMID 23865901 DOI: 10.1021/Ja405503Y  0.349
2013 Kirai N, Takaya J, Iwasawa N. Two reversible σ-bond metathesis pathways for boron-palladium bond formation: selective synthesis of isomeric five-coordinate borylpalladium complexes. Journal of the American Chemical Society. 135: 2493-6. PMID 23384145 DOI: 10.1021/Ja400294M  0.341
2013 Takaya J, Iwasawa N. Development of New Catalytic Synthetic Reactions Utilizing Palladium Complexes Bearing a PSiP-Pincer Type Ligand Journal of Synthetic Organic Chemistry Japan. 71: 417-424. DOI: 10.5059/Yukigoseikyokaishi.71.417  0.455
2013 Kirai N, Iguchi S, Ito T, Takaya J, Iwasawa N. PSiP-Pincer Type Palladium-Catalyzed Dehydrogenative Borylation of Alkenes and 1,3-Dienes Bulletin of the Chemical Society of Japan. 86: 784-799. DOI: 10.1246/Bcsj.20130004  0.53
2013 Kusama H, Sogo H, Saito K, Suga T, Iwasawa N. Construction of Cyclohepta[b]indoles via Platinum-Catalyzed Intermolecular Formal [4+3]-Cycloaddition Reaction of α,β-Unsaturated Carbene Complex Intermediates with Siloxydienes Synlett. 24: 1364-1370. DOI: 10.1055/S-0033-1338938  0.542
2012 Ooi I, Sakurai T, Takaya J, Iwasawa N. Protonation-triggered generation of acylcobalt species from alkyne-[Co2(CO)6] complexes and their reaction with alkenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14618-21. PMID 23055203 DOI: 10.1002/Chem.201202749  0.429
2012 Ito S, Ono K, Iwasawa N. Controlled self-assembly of multiple diastereomeric macrocyclic boronic esters composed of two chiral units. Journal of the American Chemical Society. 134: 13962-5. PMID 22881294 DOI: 10.1021/Ja306249F  0.357
2012 Karibe Y, Kusama H, Iwasawa N. Chromium(0)-catalyzed tandem cyclization of α,β-unsaturated thioimidates containing an enyne moiety. Angewandte Chemie (International Ed. in English). 51: 6214-8. PMID 22566201 DOI: 10.1002/Anie.201201505  0.4
2012 Takaya J, Nakamura S, Iwasawa N. Synthesis, Structure, and Catalytic Activity of Palladium Complexes Bearing a Tridentate PXP-Pincer Ligand of Heavier Group 14 Element (X = Ge, Sn) Chemistry Letters. 41: 967-969. DOI: 10.1246/Cl.2012.967  0.355
2012 Ebisawa M, Kusama H, Iwasawa N. Selective Intermolecular [2 + 2] Cycloaddition Reaction Using Platinum(II) Catalyst with Hollow-shaped Triethynylphosphine Chemistry Letters. 41: 786-788. DOI: 10.1246/Cl.2012.786  0.444
2012 Takaya J, Iwasawa N. Catalytic, Direct Synthesis of Bis(boronate) Compounds Acs Catalysis. 2: 1993-2006. DOI: 10.1021/Cs300320U  0.456
2011 Kusama H, Watanabe E, Ishida K, Iwasawa N. Efficient control for the cationic platinum(II)-catalyzed concise synthesis of two types of fused carbocycles with angular oxygen functionality. Chemistry, An Asian Journal. 6: 2273-7. PMID 21786426 DOI: 10.1002/Asia.201100460  0.349
2011 Takaya J, Kirai N, Iwasawa N. Efficient synthesis of diborylalkenes from alkenes and diboron by a new PSiP-pincer palladium-catalyzed dehydrogenative borylation. Journal of the American Chemical Society. 133: 12980-3. PMID 21780822 DOI: 10.1021/Ja205186K  0.527
2011 Takaya J, Iwasawa N. Reaction of bis(o-phosphinophenyl)silane with M(PPh3)4 (M = Ni, Pd, Pt): synthesis and structural analysis of η2-(Si-H) metal(0) and pentacoordinate silyl metal(II) hydride complexes of the Ni triad bearing a PSiP-pincer ligand. Dalton Transactions (Cambridge, England : 2003). 40: 8814-21. PMID 21725574 DOI: 10.1039/C1Dt10526D  0.308
2011 Kusama H, Karibe Y, Imai R, Onizawa Y, Yamabe H, Iwasawa N. Tungsten(0)- and rhenium(I)-catalyzed tandem cyclization of acetylenic dienol silyl ethers based on geminal carbo-functionalization of alkynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 4839-48. PMID 21425366 DOI: 10.1002/Chem.201003019  0.485
2011 Takaya J, Sasano K, Iwasawa N. Efficient one-to-one coupling of easily available 1,3-dienes with carbon dioxide. Organic Letters. 13: 1698-701. PMID 21370864 DOI: 10.1021/Ol2002094  0.479
2011 Ito K, Tamashima H, Iwasawa N, Kusama H. Photochemically promoted transition metal-free cross-coupling of acylsilanes with organoboronic esters. Journal of the American Chemical Society. 133: 3716-9. PMID 21344901 DOI: 10.1021/Ja1102597  0.42
2011 Mizuno H, Takaya J, Iwasawa N. Rhodium(I)-catalyzed direct carboxylation of arenes with CO2 via chelation-assisted C-H bond activation. Journal of the American Chemical Society. 133: 1251-3. PMID 21192682 DOI: 10.1021/Ja109097Z  0.401
2011 Saito K, Sogou H, Suga T, Kusama H, Iwasawa N. Platinum(II)-catalyzed generation and [3+2] cycloaddition reaction of α,β-unsaturated carbene complex intermediates for the preparation of polycyclic compounds. Journal of the American Chemical Society. 133: 689-91. PMID 21171651 DOI: 10.1021/Ja108586D  0.539
2011 Takaya J, Miyashita Y, Kusama H, Iwasawa N. [3+2] Cycloaddition of metal-containing azomethine ylides for highly efficient synthesis of mitosene skeleton Tetrahedron. 67: 4455-4466. DOI: 10.1016/J.Tet.2011.04.017  0.515
2010 Takahagi H, Iwasawa N. Crystallization-controlled dynamic self-assembly and an on/off switch for equilibration using boronic ester formation. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 13680-8. PMID 20945311 DOI: 10.1002/Chem.201001013  0.428
2010 Iwasawa N, Ooi I, Inaba K, Takaya J. [4+2] cycloaddition reaction of cyclic alkyne-{Co2(CO)6} complexes with dienes. Angewandte Chemie (International Ed. in English). 49: 7534-7. PMID 20818634 DOI: 10.1002/Anie.201002683  0.428
2010 Onizawa Y, Hara M, Hashimoto T, Kusama H, Iwasawa N. Synthetic studies on and mechanistic insight into [W(CO)5(L)]-catalyzed stereoselective construction of functionalized bicyclo[5.3.0]decane frameworks. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 10785-96. PMID 20680944 DOI: 10.1002/Chem.201001003  0.553
2010 Mizuno A, Kusama H, Iwasawa N. Rhodium-catalyzed synthesis of gamma-pyrones by three consecutive redox-aldol reactions of allylic alcohols with alpha,beta-unsaturated aldehydes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8248-50. PMID 20572189 DOI: 10.1002/Chem.201001068  0.386
2010 Ishida K, Kusama H, Iwasawa N. Enantioselective preparation of 8-oxabicyclo[3.2.1]octane derivatives via asymmetric [3+2]-cycloaddition of platinum-containing carbonyl ylides with vinyl ethers. Journal of the American Chemical Society. 132: 8842-3. PMID 20540576 DOI: 10.1021/Ja102391T  0.477
2010 Kusama H, Karibe Y, Onizawa Y, Iwasawa N. Gold-catalyzed tandem cyclization of dienol silyl ethers for the preparation of bicyclo[4.3.0]nonane derivatives. Angewandte Chemie (International Ed. in English). 49: 4269-72. PMID 20446327 DOI: 10.1002/Anie.201001061  0.476
2010 Saito K, Onizawa Y, Kusama H, Iwasawa N. Rhenium(I)-catalyzed cyclization of silyl enol ethers containing a propargyl carboxylate moiety: versatile access to highly substituted phenols. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 4716-20. PMID 20301146 DOI: 10.1002/Chem.200903586  0.511
2010 Iwasawa N, Ishida K, Kusama H. Platinum-Catalyzed Asymmetric [3+2] Cycloadditions of Carbonyl Ylides Synfacts. 2010: 1020-1020. DOI: 10.1055/s-0030-1257945  0.425
2010 Mizuno A, Kusama H, Iwasawa N. ChemInform Abstract: Rhodium-Catalyzed Synthesis of γ-Pyrones by Three Consecutive Redox-Aldol Reactions of Allylic Alcohols with α,β-Unsaturated Aldehydes. Cheminform. 41: no-no. DOI: 10.1002/CHIN.201052140  0.367
2010 Mizuno A, Kusama H, Iwasawa N. ChemInform Abstract: Rhodium(I)-Catalyzed [4 + 1] Cycloaddition Reactions of α,β-Unsaturated Imines with Terminal Alkynes for the Preparation of Pyrrole Derivatives. Cheminform. 41. DOI: 10.1002/CHIN.201006099  0.414
2010 Iwasawa N, Maeyama K, Kusama H. ChemInform Abstract: A Novel Reaction for Annulation onto α,β-Unsaturated Ketones: W(CO)5×L Promoted exo- and endo-Selective Cyclizations of ω-Acetylenic Silyl Enol Ethers Prepared by 1,4-Addition of Propargyl Malonate to Enones. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200216041  0.409
2010 GONG YD, TANAKA H, IWASAWA N, NARASAKA K. ChemInform Abstract: Lewis Acid-Promoted Disproportionation Reaction of Aromatic Vinyl Ethers and Acetals and Its Application to the Synthesis of Paracotoin. Cheminform. 30: no-no. DOI: 10.1002/chin.199901053  0.4
2010 MAEYAMA K, IWASAWA N. ChemInform Abstract: W(CO)5×THF-Catalyzed endo-Selective Cyclization of ω-Acetylenic Silyl Enol Ethers. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199826063  0.321
2010 NARASAKA K, IWASAWA N. ChemInform Abstract: Asymmetric Reactions Promoted by Titanium Reagents Cheminform. 25: no-no. DOI: 10.1002/chin.199421288  0.599
2010 HASELTINE JN, PAZ CABAL M, MANTLO NB, IWASAWA N, YAMASHITA DS, COLEMAN RS, DANISHEFSKY SJ, SCHULTE GK. ChemInform Abstract: Total Synthesis of Calicheamicinone: New Arrangements for Actuation of the Reductive Cycloaromatization of Aglycon Congeners. Cheminform. 22: no-no. DOI: 10.1002/chin.199135270  0.504
2009 Kusama H, Ebisawa M, Funami H, Iwasawa N. Platinum(II)-catalyzed intermolecular [3 + 2] cycloaddition of propadienyl silyl ethers and alkenyl ethers. Journal of the American Chemical Society. 131: 16352-3. PMID 19860447 DOI: 10.1021/Ja907633B  0.448
2009 Mizuno A, Kusama H, Iwasawa N. Rhodium(I)-catalyzed [4+1] cycloaddition reactions of alpha,beta-unsaturated imines with terminal alkynes for the preparation of pyrrole derivatives. Angewandte Chemie (International Ed. in English). 48: 8318-20. PMID 19784995 DOI: 10.1002/Anie.200904402  0.415
2009 Ito K, Hara Y, Mori S, Kusama H, Iwasawa N. Theoretical study of the cycloaddition reaction of a tungsten-containing carbonyl ylide. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 12408-16. PMID 19777512 DOI: 10.1002/Chem.200901033  0.498
2009 Takaya J, Sangu K, Iwasawa N. Molybdenum(0)-promoted carbonylative cyclization of o-haloaryl- and beta-haloalkenylimine derivatives by oxidative addition of a carbon(sp2)-halogen bond: preparation of two types of gamma-lactams. Angewandte Chemie (International Ed. in English). 48: 7090-3. PMID 19705391 DOI: 10.1002/Anie.200902884  0.309
2009 Takaya J, Iwasawa N. Bis(o-phosphinophenyl)silane as a Scaffold for Dynamic Behavior of H−Si and C−Si Bonds with Palladium(0) Organometallics. 28: 6636-6638. DOI: 10.1021/Om900874P  0.386
2008 Takaya J, Iwasawa N. Hydrocarboxylation of allenes with CO2 catalyzed by silyl pincer-type palladium complex. Journal of the American Chemical Society. 130: 15254-5. PMID 18942785 DOI: 10.1021/Ja806677W  0.467
2008 Takaya J, Tadami S, Ukai K, Iwasawa N. Copper(I)-catalyzed carboxylation of aryl- and alkenylboronic esters. Organic Letters. 10: 2697-700. PMID 18507391 DOI: 10.1021/Ol800829Q  0.52
2008 Takaya J, Udagawa S, Kusama H, Iwasawa N. Synthesis of N-fused tricyclic indoles by a tandem [1,2] Stevens-type rearrangement/1,2-alkyl migration of metal-containing ammonium ylides. Angewandte Chemie (International Ed. in English). 47: 4906-9. PMID 18504728 DOI: 10.1002/Anie.200705517  0.366
2008 Kusama H, Ishida K, Funami H, Iwasawa N. Platinum(II)-catalyzed reaction of gamma,delta-ynones with alkenes for the construction of 8-oxabicyclo[3.2.1]octane skeletons: generation of platinum-containing carbonyl ylides from acyclic precursors. Angewandte Chemie (International Ed. in English). 47: 4903-5. PMID 18496797 DOI: 10.1002/Anie.200705129  0.467
2008 Iwasawa N, Otsuka M, Yamashita S, Aoki M, Takaya J. Synthesis, structure, and reactivity of naphthalyne-Co2(CO)6 complexes. Journal of the American Chemical Society. 130: 6328-9. PMID 18433124 DOI: 10.1021/Ja801569Q  0.381
2008 Takahashi A, Hirose Y, Kusama H, Iwasawa N. Chelation-assisted electrocyclic reactions of 3-alkenyl-2,2'-bipyridines: an efficient method for the synthesis of 5,6-dihydro-1,10-phenanthroline and 1,10-phenanthroline derivatives. Chemical Communications (Cambridge, England). 609-11. PMID 18209805 DOI: 10.1039/B715442A  0.515
2008 Onizawa Y, Kusama H, Iwasawa N. Efficient control of pi-alkyne and vinylidene complex pathways for the W(CO)5(L)-catalyzed synthesis of two types of nitrogen-containing bicyclic compounds. Journal of the American Chemical Society. 130: 802-3. PMID 18154295 DOI: 10.1021/Ja0782605  0.457
2008 Kusama H, Ishida K, Funami H, Iwasawa N. ChemInform Abstract: Platinum(II)-Catalyzed Reaction of γ,δ-Ynones with Alkenes for the Construction of 8-Oxabicyclo[3.2.1]octane Skeletons: Generation of Platinum-Containing Carbonyl Ylides from Acyclic Precursors. Cheminform. 39. DOI: 10.1002/CHIN.200845141  0.398
2007 Aoki M, Izumi S, Kaneko M, Ukai K, Takaya J, Iwasawa N. Ni(0)-promoted hydroxycarboxylation of 1,2-dienes by reaction with CO2 and O2. Organic Letters. 9: 1251-3. PMID 17341089 DOI: 10.1021/Ol070038H  0.358
2007 Funami H, Kusama H, Iwasawa N. Preparation of substituted cyclopentadienes through platinum(II)-catalyzed cyclization of 1,2,4-trienes. Angewandte Chemie (International Ed. in English). 46: 909-11. PMID 17177221 DOI: 10.1002/Anie.200603986  0.426
2007 Grandmarre A, Kusama H, Iwasawa N. W(CO)5(L)-catalyzed Cyclization of ω-Acetylenic Silyl Enol Ethers for the Preparation of Nitrogen-containing Cyclic Compounds Chemistry Letters. 36: 66-67. DOI: 10.1246/Cl.2007.66  0.399
2007 Inaba K, Takaya J, Iwasawa N. Stereoselective Synthesis of Medium-sized Cyclic Compounds through the Intramolecular Michael-type Reaction Utilizing Alkyne-Hexacarbonyldicobalt Complex Formation Chemistry Letters. 36: 474-475. DOI: 10.1246/Cl.2007.474  0.431
2007 Kusama H, Funami H, Iwasawa N. Synthesis of Naphthalene Derivatives through Platinum(II)-Catalyzed Reaction of 2-Alkynylbenzoates with Vinyl Ethers Synthesis. 2007: 2014-2024. DOI: 10.1055/S-2007-983737  0.478
2007 Sangu K, Watanabe T, Takaya J, Iwasawa N. Intermolecular addition reaction to alkenes of acylmolybdenum complexes generated by oxidative addition of aryl or alkenyl halides with molybdenum(0) carbonyl complexes Synlett. 2007: 929-933. DOI: 10.1055/S-2007-973858  0.435
2007 Miura T, Kiyota K, Kusama H, Iwasawa N. W(CO)5(L)-catalyzed 6-endo-selective cyclization and formal Cope rearrangement of allenyl silyl enol ethers Journal of Organometallic Chemistry. 692: 562-568. DOI: 10.1016/J.Jorganchem.2006.08.037  0.501
2006 Kusama H, Onizawa Y, Iwasawa N. W(CO)5(L)-catalyzed tandem intramolecular cyclopropanation/cope rearrangement for the stereoselective construction of bicyclo[5.3.0]decane framework. Journal of the American Chemical Society. 128: 16500-1. PMID 17177389 DOI: 10.1021/Ja0671924  0.46
2006 Asakura T, Kojima T, Miura T, Iwasawa N. Useful reactions of silylated propargyltungsten or propargylmolybdenum species. Angewandte Chemie (International Ed. in English). 45: 6874-7. PMID 17001716 DOI: 10.1002/Anie.200602188  0.377
2006 Ukai K, Aoki M, Takaya J, Iwasawa N. Rhodium(I)-catalyzed carboxylation of aryl- and alkenylboronic esters with CO2. Journal of the American Chemical Society. 128: 8706-7. PMID 16819845 DOI: 10.1021/Ja061232M  0.457
2006 Kusama H, Sawada T, Okita A, Shiozawa F, Iwasawa N. Synthesis of isochromene esters utilizing 1,6-addition of nucleophiles to benzopyranylidenetungsten(0) complexes. Organic Letters. 8: 1077-9. PMID 16524272 DOI: 10.1021/Ol052951T  0.511
2006 Kusama H, Suzuki Y, Takaya J, Iwasawa N. Intermolecular 1,5-dipolar cycloaddition reaction of tungsten-containing vinylazomethine ylides leading to seven-membered heterocycles. Organic Letters. 8: 895-7. PMID 16494468 DOI: 10.1021/Ol0529795  0.522
2006 Kusama H, Miyashita Y, Takaya J, Iwasawa N. Pt(II)- or Au(III)-catalyzed [3+2] cycloaddition of metal-containing azomethine ylides: highly efficient synthesis of the mitosene skeleton. Organic Letters. 8: 289-92. PMID 16408897 DOI: 10.1021/Ol052610F  0.459
2006 Kusama H, Iwasawa N. Cycloaddition Reactions of Transition Metal-containing Benzopyrylium and Related Zwitterionic Intermediates Chemistry Letters. 35: 1082-1087. DOI: 10.1246/Cl.2006.1082  0.385
2005 Iwasawa N, Inaba K, Nakayama S, Aoki M. Complexation-initiated intramolecular [4+2] cycloaddition: construction of bridged-type cycloadducts. Angewandte Chemie (International Ed. in English). 44: 7447-50. PMID 16240305 DOI: 10.1002/Anie.200502313  0.332
2005 Miura T, Kiyota K, Kusama H, Iwasawa N. W(CO)5(L)-catalyzed formal cope rearrangement of allenyl silyl enol ethers. Organic Letters. 7: 1445-7. PMID 15816723 DOI: 10.1021/Ol0473694  0.426
2005 Yamabe H, Mizuno A, Kusama H, Iwasawa N. Rh(I)-catalyzed cyclization of 1-arylprop-2-yn-1-ol derivatives utilizing rhodium 1,4-migration. Journal of the American Chemical Society. 127: 3248-9. PMID 15755120 DOI: 10.1002/CHIN.200531078  0.434
2005 Kusama H, Funami H, Shido M, Hara Y, Takaya J, Iwasawa N. Generation and reaction of tungsten-containing carbonyl ylides: [3 + 2]-cycloaddition reaction with electron-rich alkenes. Journal of the American Chemical Society. 127: 2709-16. PMID 15725028 DOI: 10.1021/Ja044194K  0.494
2005 Kusama H, Yamabe H, Onizawa Y, Hoshino T, Iwasawa N. Rhenium(I)-catalyzed intramolecular geminal carbofunctionalization of alkynes: tandem cyclization of omega-acetylenic dienol silyl ethers. Angewandte Chemie (International Ed. in English). 44: 468-70. PMID 15624130 DOI: 10.1002/Anie.200461559  0.524
2004 Aoki M, Kaneko M, Izumi S, Ukai K, Iwasawa N. Bidentate amidine ligands for nickel(0)-mediated coupling of carbon dioxide with unsaturated hydrocarbons. Chemical Communications (Cambridge, England). 2568-9. PMID 15543283 DOI: 10.1039/B411802B  0.356
2004 Kusama H, Funami H, Takaya J, Iwasawa N. Platinum(II)-catalyzed reaction of 2-alkynylbenzoates or benzothioates with vinyl ethers: a concise method for synthesis of 1-acyl-4-alkoxy- or 1-acyl-4-alkylsulfanylnaphthalene derivatives. Organic Letters. 6: 605-8. PMID 14961634 DOI: 10.1021/Ol0364024  0.532
2004 Takaya J, Kusama H, Iwasawa N. Isolation and Reaction of (Indolin-3-ylidene)pentacarbonyltungsten Generated from Tungsten-containing Azomethine Ylide Chemistry Letters. 33: 16-17. DOI: 10.1246/Cl.2004.16  0.435
2004 Miura T, Murata H, Kiyota K, Kusama H, Iwasawa N. W(CO)5(L)-promoted cyclization of 1-iodo-1-alkynes via iodovinylidene tungsten complexes Journal of Molecular Catalysis a-Chemical. 213: 59-71. DOI: 10.1016/J.Molcata.2003.10.050  0.457
2003 Lee K, Kim H, Miura T, Kiyota K, Kusama H, Kim S, Iwasawa N, Lee PH. Indium-mediated beta-allylation, beta-propargylation, and beta-allenylation onto alpha,beta-unsaturated ketones: reactions of in-situ-generated 3-tert-butyldimethylsilyloxyalk-2-enylsulfonium salts with in-situ-generated organoindium reagents. Journal of the American Chemical Society. 125: 9682-8. PMID 12904034 DOI: 10.1021/Ja035988M  0.413
2003 Miura T, Kiyota K, Kusama H, Lee K, Kim H, Kim S, Lee PH, Iwasawa N. W(CO)5(L)-catalyzed endo-selective cyclization of allenyl silyl enol ethers: an efficient method for the cyclopentene annulation onto alpha,beta-unsaturated ketones. Organic Letters. 5: 1725-8. PMID 12735762 DOI: 10.1021/Ol034365A  0.46
2003 Fuchibe K, Iwasawa N. Generation of reactive species by one-electron reduction of Fischer-type carbene complexes of group 6 metals and their use for carbon-carbon bond formation. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 905-14. PMID 12584706 DOI: 10.1002/Chem.200390112  0.363
2002 Iwasawa N, Miura T, Kiyota K, Kusama H, Lee K, Lee PH. An efficient method for cyclopentene annulation onto alpha,beta-unsaturated ketones: W(CO)(5)(L)-catalyzed 5-endo-dig cyclization of 6-siloxy-5-en-1-ynes. Organic Letters. 4: 4463-6. PMID 12465913 DOI: 10.1002/CHIN.200316101  0.372
2002 Kusama H, Takaya J, Iwasawa N. A facile method for the synthesis of polycyclic indole derivatives: the generation and reaction of tungsten-containing azomethine ylides. Journal of the American Chemical Society. 124: 11592-3. PMID 12296713 DOI: 10.1021/Ja027589H  0.498
2002 Kusama H, Yamabe H, Iwasawa N. W(CO)5-amine catalyzed exo- and endo-selective cyclizations of omega-alkynyl silyl enol ethers: a highly useful method for the construction of polycyclic compounds. Organic Letters. 4: 2569-71. PMID 12123378 DOI: 10.1021/Ol026202C  0.482
2002 Miura T, Iwasawa N. Reactions of iodinated vinylidene complexes generated from 1-iodo-1-alkynes and W(CO)5(thf). Journal of the American Chemical Society. 124: 518-9. PMID 11804472 DOI: 10.1021/Ja0113091  0.46
2002 Iwasawa N, Kusama H, Maeyama K. W (C0) 5 (L) -Catalyzed Construction of Cyclic Carbon Frameworks Journal of Synthetic Organic Chemistry Japan. 60: 1036-1048. DOI: 10.5059/Yukigoseikyokaishi.60.1036  0.508
2002 Kusama H, Shiozawa F, Shido M, Iwasawa N. Tandem Cyclizations of Benzopyranylidenetungsten(0) Complexes with Electron-Rich Dienes for the Stereoselective Synthesis of Polycyclic Carbon Skeletons. Chemistry Letters. 31: 124-125. DOI: 10.1246/Cl.2002.124  0.455
2001 Iwasawa N, Maeyama K, Kusama H. A novel reaction for annulation onto alpha,beta-unsaturated ketones: W(CO)(5).L promoted exo- and endo-selective cyclizations of omega-acetylenic silyl enol ethers prepared by 1,4-addition of propargyl malonate to enones. Organic Letters. 3: 3871-3873. PMID 11720557 DOI: 10.1021/Ol016718G  0.527
2001 Iwasawa N, Shido M, Kusama H. Generation and reaction of metal-containing carbonyl ylides: tandem [3 + 2]-cycloaddition--carbene insertion leading to novel polycyclic compounds. Journal of the American Chemical Society. 123: 5814-5815. PMID 11403621 DOI: 10.1021/Ja010478I  0.42
2001 Iwasawa N, Saitou M, Kusama H. Reactions of silyl-substituted Fischer-type carbene complexes with silanes Journal of Organometallic Chemistry. 617: 741-743. DOI: 10.1016/S0022-328X(00)00721-X  0.44
2000 Fuchibe K, Iwasawa N. Reactions of novel reactive species generated by Samarium(II)-mediated one-electron reduction of fischer-type carbene complexes Organic Letters. 2: 3297-3299. PMID 11029194 DOI: 10.1021/Ol006367Q  0.33
2000 Iwasawa N, Sakurada F, Iwamoto M. Complexation-Initiated Intramolecular Diels−Alder Reaction Organic Letters. 2: 871-873. PMID 10814441 DOI: 10.1021/Ol005650M  0.46
2000 Iwasawa N, Shido M, Maeyama aK, Kusama H. Novel Synthesis of Pentacarbonylbenzopyranylidenetungsten(0) Complexes and Their Diels−Alder Reaction with Electron-Rich Alkenes Journal of the American Chemical Society. 122: 10226-10227. DOI: 10.1021/Ja001481P  0.46
2000 Fuchibe K, Iwasawa N. A Novel Use of the Anions of Fischer-type Carbene Complexes as Alkenyl Metallic Species Tetrahedron. 56: 4907-4915. DOI: 10.1016/S0040-4020(00)00205-2  0.394
2000 Iwasawa N, Narasaka K. Transition Metal Promoted Ring Expansion of Alkynyl- and Propadienylcyclopropanes Topics in Current Chemistry. 207: 69-88. DOI: 10.1007/3-540-48255-5_2  0.505
1999 Iwasawa N, Funahashi M, Hayakawa S, Ikeno T, Narasaka K. Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(pyridine-2-carboxylate) and Its Application to Total Synthesis of 10-Isothiocyanatoguaia-6-ene Bulletin of the Chemical Society of Japan. 72: 85-97. DOI: 10.1246/Bcsj.72.85  0.468
1999 Maeyama K, Iwasawa N. W(CO)5·THF-Catalyzed Electrocyclizations of Aromatic Enynes via Vinylidene Intermediates Journal of Organic Chemistry. 64: 1344-1346. DOI: 10.1021/Jo981361O  0.469
1999 Iwasawa N, Satoh H. A Novel Synthesis of 4,5-Didehydrotropone−Co2(CO)4•dppm Complexes Journal of the American Chemical Society. 121: 7951-7952. DOI: 10.1021/Ja990338X  0.36
1999 Iwasawa N, Funahashi M, Hayakawa S, Ikeno T, Narasaka K. Synthesis of medium-sized bicyclic compounds by intramolecular cyclization of cyclic β-keto radicals generated from cyclopropanols using manganese(III) tris(pyridine-2-carboxylate) and its application to total synthesis of 10-isothiocyanatoguaia-6-ene Bulletin of the Chemical Society of Japan. 72: 85-97.  0.573
1998 Iwasawa N. Octacarbonyldicobalt Mediated Rearrangement of 1-Alkynyl and 1-Allenylcyclopropanols Journal of Synthetic Organic Chemistry Japan. 56: 1058-1068. DOI: 10.5059/Yukigoseikyokaishi.56.1058  0.503
1998 Gong YD, Tanaka H, Iwasawa N, Narasaka K. Lewis Acid-Promoted Disproportionation Reaction of Aromatic Vinyl Ethers and Acetals and Its Application to the Synthesis of Paracotoin Bulletin of the Chemical Society of Japan. 71: 2181-2185. DOI: 10.1246/Bcsj.71.2181  0.676
1998 Iwasawa N, Ochiai T, Maeyama K. Concise Synthesis of Fully-Substituted Furan, Pyrrole, Butenolide, and 2-Butene-4-lactam Esters Journal of Organic Chemistry. 63: 3164-3165. DOI: 10.1021/Jo980214N  0.471
1998 Iwasawa N, Matsuo T, Iwamoto M, Ikeno T. Rearrangement of 1-(1-Alkynyl)cyclopropanols to 2-Cyclopentenones via Their Hexacarbonyldicobalt Complexes. A New Use of Alkyne−Co2(CO)6 Complexes in Organic Synthesis Journal of the American Chemical Society. 120: 3903-3914. DOI: 10.1021/Ja9734004  0.527
1998 Maeyama K, Iwasawa N. W(CO)5·THF-Catalyzed Endo-Selective Cyclization of ω-Acetylenic Silyl Enol Ethers Journal of the American Chemical Society. 120: 1928-1929. DOI: 10.1021/Ja973317G  0.43
1997 Iwasawa N, Matsuo T. Synthesis of Polycyclic Compounds by the Reaction of Co2(CO)6 Complexed 1-(o-(1-Alkynyl)phenyl)cyclopropanols. Chemistry Letters. 26: 341-342. DOI: 10.1246/Cl.1997.341  0.465
1997 Iwasawa N, Ochiai T, Maeyama K. Observation and Iodine Oxidation of the Protonated Anionic Propargyltungsten Species Formed in the Reaction of Fischer-Type Carbene Complexes with Alkynyllithiums Organometallics. 16: 5137-5139. DOI: 10.1021/Om970835R  0.384
1997 Iwasawa N, Maeyama K, Saitou M. Reactions Of Propargyl Metallic Species Generated By The Addition Of Alkynyllithiums To Fischer-Type Carbene Complexes Journal of the American Chemical Society. 119: 1486-1487. DOI: 10.1021/Ja962173N  0.381
1996 Sakurai H, Iwasawa N, Narasaka K. Synthesis Of A Bis(Boronate) Compound Having S-Indacene Framework And Its Property As A Host Molecule For Dimethylaminopyridine Bulletin of the Chemical Society of Japan. 69: 2585-2594. DOI: 10.1246/Bcsj.69.2585  0.325
1996 Sakurai H, Iwasawa N, Narasaka K. Synthesis of a bis(boronate) compound having s-indacene framework and its property as a host molecule for dimethylaminopyridine Bulletin of the Chemical Society of Japan. 69: 2585-2594.  0.466
1995 Iwasawa N, Owada Y, Matsuo T. Octacarbonyldicobalt Promoted Transformation of 1-(1,2-Propadienyl)cyclopropanols to 1,4-Hydroquinones Chemistry Letters. 1995: 115-116. DOI: 10.1246/Cl.1995.115  0.338
1994 Iwasawa N, Saitou M. Stereoselective Synthesis of (E) and (Z)-Vinylsilane by the Addition Reaction of Organometallic Reagent to Silyl-substituted Fischer-type Carbene Complex Chemistry Letters. 1994: 231-234. DOI: 10.1246/Cl.1994.231  0.497
1994 Iwasawa N, Funahashi M, Narasaka K. Total Synthesis Of 10-Isothiocyanatoguaia-6-Ene Chemistry Letters. 1994: 1697-1700. DOI: 10.1246/Cl.1994.1697  0.473
1993 Iwasawa N, Matsuo T. Rearrangement of 1-Alkynylcyclopropanol to 3-Substituted 2-Cyclopentenone Promoted by a Catalytic Amount of Octacarbonyldicobalt-Triphenylphosphite Chemistry Letters. 1993: 997-1000. DOI: 10.1246/Cl.1993.997  0.459
1993 Iwasawa N, Funahashi M, Hayakawa S, Narasaka K. Synthesis of Medium-Sized Bicyclic Compounds by Intramolecular Cyclization of Cyclic β-Keto Radicals Generated from Cyclopropanols Using Manganese(III) Tris(2-pyridinecarboxylate) Chemistry Letters. 22: 545-548. DOI: 10.1246/Cl.1993.545  0.59
1993 Iwasawa N, Iwamoto M. A conformationally controlled regioselective rearrangement of 2-substituted 1-alkynylcyclopropanols to 2-cyclopenten-1-ones via hexacarbonyldicobalt complex Chemistry Letters. 1993: 1257-1260. DOI: 10.1246/Cl.1993.1257  0.453
1993 Iwasawa N, Hayakawa S, Funahashi M, Isobe K, Narasaka K. Generation ofβ-Carbonyl Radicals from Cyclopropanol Derivatives by the Oxidation with Manganese(III) 2-Pyridinecarboxylate and Their Reactions with Electron-Rich and -Deficient Olefins Bulletin of the Chemical Society of Japan. 66: 819-827. DOI: 10.1246/Bcsj.66.819  0.622
1992 Iwasawa N. A Novel Rearrangement of 1-Alkynylcyclopropanol to 2-Cyclopenten-1-one via Dicobalt Hexacarbonyl Complex Chemistry Letters. 1992: 473-476. DOI: 10.1246/Cl.1992.473  0.349
1991 Drak J, Iwasawa N, Danishefsky S, Crothers DM. The carbohydrate domain of calicheamicin gamma I1 determines its sequence specificity for DNA cleavage. Proceedings of the National Academy of Sciences of the United States of America. 88: 7464-8. PMID 1881884 DOI: 10.1073/Pnas.88.17.7464  0.429
1991 Iwasawa N, Hayakawa S, Isobe K, Narasaka K. Generation of β-Keto Radicals from Cyclopropanol Derivatives by the Use of Manganese(III) 2-Pyridinecarboxylate as an Oxidant and Their Reactions with Olefins Chemistry Letters. 20: 1193-1196. DOI: 10.1246/Cl.1991.1193  0.475
1991 Narasaka K, Shimada S, Osoda K, Iwasawa N. Phenylboronic acid as a template in the Diels-Alder reaction Synthesis. 1991: 1171-1172. DOI: 10.1055/S-1991-28413  0.488
1991 Haseltine JN, Paz Cabal M, Mantlo NB, Iwasawa N, Yamashita DS, Coleman RS, Danishefsky SJ, Schulte GK. Total synthesis of calicheamicinone: new arrangements for actuation of the reductive cycloaromatization of aglycon congeners Journal of the American Chemical Society. 113: 3850-3866. DOI: 10.1021/Ja00010A030  0.681
1991 Narasaka K, Saitou M, Iwasawa N. Asymmetric synthesis of the hydronaphthalene moieties of mevinic acids Tetrahedron: Asymmetry. 2: 1305-1318. DOI: 10.1016/S0957-4166(00)80028-2  0.66
1991 Narasaka K, Shimada S, Osoda K, Iwasawa N. Phenylboronic acid as a template in the Diels-Alder reaction Synthesis. 1171-1172.  0.565
1990 Narasaka K, Sakurai H, Kato T, Iwasawa N. Synthesis of Bidentate Lewis Acids and Their Properties as Host Molecules Chemistry Letters. 19: 1271-1274. DOI: 10.1246/Cl.1990.1271  0.503
1989 Iwasawa N, Sugimori J, Kawase Y, Narasaka K. Asymmetric Intramolecular Diels–Alder Reaction Catalyzed by the Chiral Titanium Reagent Chemistry Letters. 18: 1947-1950. DOI: 10.1246/Cl.1989.1947  0.672
1989 Iwasawa N, Hayashi Y, Sakurai H, Narasaka K. Characterization of the Chiral Titanium Reagent Prepared from the Tartrate-derived Chiral Diol and Titanium Dichloride Diisopropoxide Chemistry Letters. 18: 1581-1584. DOI: 10.1246/Cl.1989.1581  0.656
1989 Narasaka K, Iwasawa N, Inoue M, Yamada T, Nakashima M, Sugimori J. Asymmetric Diels-Alder Reaction Catalyzed by a Chiral Titanium Reagent Journal of the American Chemical Society. 111: 5340-5345. DOI: 10.1021/Ja00196A045  0.411
1989 Iwasawa N, Yura T, Mukaiyama T. Catalytic use of tin(II) reagents in organic synthesis Tetrahedron. 45: 1197-1207. DOI: 10.1016/0040-4020(89)80028-6  0.574
1989 Narasaka K, Iwasawa N, Inoue M, Yamada T, Nakashima M, Sugimori J. Asymmetric Diels-Alder reaction catalyzed by a chiral titanium reagent Journal of the American Chemical Society. 111: 5340-5345.  0.629
1988 Iwasawa N, Kato T, Narasaka K. A Convenient Method for Dihydroxylation of Olefins by the Combined Use of Osmium Tetroxide and Dihydroxyphenyiborane Chemistry Letters. 17: 1721-1724. DOI: 10.1246/Cl.1988.1721  0.567
1988 Yura T, Iwasawa N, Narasaka K, Mukaiyama T. The Catalytic Asymmetric Michael Reaction of Tin(II) Enethiolates Chemistry Letters. 17: 1025-1026. DOI: 10.1246/Cl.1988.1025  0.597
1988 Yura T, Iwasawa N, Mukaiyama T. The Enantioselective Michael Reaction of Tin(II) Enolates Chemistry Letters. 17: 1021-1024. DOI: 10.1246/Cl.1988.1021  0.61
1988 Minamikawa H, Hayakawa S, Yamada T, Iwasawa N, Narasaka K. Asymmetric Hydrocyanation of Aldehydes Using Chiral Titanium Reagents Bulletin of the Chemical Society of Japan. 61: 4379-4383. DOI: 10.1246/Bcsj.61.4379  0.592
1987 Mukaiyama T, Iwasawa N. Tin(II) enolates in organic synthesis. Nippon Kagaku Kaishi. 1099-1107. DOI: 10.1246/Nikkashi.1987.1099  0.483
1987 Yura T, Iwasawa N, Mukaiyama T. New possibilities in the Michael reaction by the use of tin(II) enolates. Chemistry Letters. 16: 791-794. DOI: 10.1246/Cl.1987.791  0.593
1987 Mukaiyama T, Clark RSJ, Iwasawa N. A Convenient Preparation of α-(p-Hydroxy- or p-Aminophenyl) Carbonyl Compounds. Addition–Reduction Reaction of Tin(II) Enolate with p-Benzoquinone and Its Mono-N-tosylimino Derivative Chemistry Letters. 16: 479-482. DOI: 10.1246/Cl.1987.479  0.488
1987 Iwasawa N, Mukaiyama T. An Essentially Mild and Efficient Catalyst System for the Activation of Carbonyl Compounds and Their Derivatives. The Combined Use of Trimethylsilyl Chloride and Tin(II) Chloride Chemistry Letters. 16: 463-466. DOI: 10.1246/Cl.1987.463  0.583
1987 Narasaka K, Inoue M, Yamada T, Sugimori J, Iwasawa N. Asymmetric Diels–Alder Reaction by the Use of a Chiral Titanium Catalyst with Molecular Sieves 4A. Remarkable Solvent Effect on the Enantioselectivity Chemistry Letters. 16: 2409-2412. DOI: 10.1246/Cl.1987.2409  0.649
1987 Mukaiyama T, Iwasawa N, Yura T, Clark RSJ. The tin(II) enolate addition reactions to α, β-unsaturated ketones and quinones Tetrahedron. 43: 5003-5017. DOI: 10.1016/S0040-4020(01)87679-1  0.53
1986 Iwasawa N, Mukaiyama T. Highly Stereoselective Aldol-Type Reaction Of Chiral Tin(Ii) Enolate. Formal Total Synthesis Of (±)-Thienamycin Chemistry Letters. 15: 637-640. DOI: 10.1246/Cl.1986.637  0.577
1986 Yura T, Iwasawa N, Mukaiyama T. STEREOSELECTIVE ALDOL REACTION FOR THE PREPARATION OF β-ETHYLTHIOMETHYL ALDOLS VIA TIN(II) ENOLATE BY THE USE OF A CATALYTIC AMOUNT OF THE TIN(II) SPECIES Chemistry Letters. 15: 187-190. DOI: 10.1246/Cl.1986.187  0.576
1986 Yura T, Iwasawa N, Clark R, Mukaiyama T. Asymmetric sulfenylation of tin(II) enolates of ketones and 3-acyl-2-oxazolidones: application to the synthesis of optically active epoxides Chemistry Letters. 15: 1809-1812. DOI: 10.1246/Cl.1986.1809  0.569
1986 IWASAWA N, MUKAIYAMA T. ChemInform Abstract: Highly Stereoselective Aldol-Type Reaction of Chiral Tin(II) Enolate. Chemischer Informationsdienst. 17. DOI: 10.1002/CHIN.198646088  0.382
1986 Yura T, Iwasawa N, Mukaiyama T. Stereoselective Aldol Reaction for the Preparation of β-Ethylthiomethyl Aldols via Tin(II) Enolate by the Use of a Catalytic Amount of the Tin(II) Species. Cheminform. 17. DOI: 10.1002/Chin.198645076  0.543
1986 IWASAWA N, HUANG H, MUKAIYAMA T. ChemInform Abstract: Stannous Triflate Mediated Aldol Reaction of 3-(3-Alkoxy- and 3-Aminopropanoyl)thiazolidine-2-thiones. Chemischer Informationsdienst. 17. DOI: 10.1002/CHIN.198603196  0.383
1985 Mukaiyama T, Yura T, Iwasawa N. STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXYESTERS AND ALDEHYDES VIA DIVALENT TIN ENOLATE. A SYNTHESIS OF 2-AMINO-2-DEOXY-D-ARABINITOL Chemistry Letters. 14: 809-812. DOI: 10.1246/Cl.1985.809  0.572
1985 Kato J, Iwasawa N, Mukaiyama T. A novel method for the preparation of symmetrical and unsymmetrical ethers. Trityl perchlorate promoted reduction of carbonyl compounds with triethylsilane. Chemistry Letters. 14: 743-746. DOI: 10.1246/Cl.1985.743  0.527
1985 Mukaiyama T, Kato J, Miyoshi N, Iwasawa N. A novel and useful method for the preparation of methyl esters from dimethyl acetals Chemistry Letters. 14: 1255-1258. DOI: 10.1246/Cl.1985.1255  0.505
1985 Iwasawa N, Huang H, Mukaiyama T. STANNOUS TRIFLATE MEDIATED ALDOL REACTION OF 3-(3-ALKOXY AND 3-AMINOPROPANOYL) THIAZOLIDINE-2-THIONES STEREOSELECTIVE SYNTHESIS OF β-LACTAM DERIVATIVES Chemistry Letters. 14: 1045-1048. DOI: 10.1246/Cl.1985.1045  0.553
1985 Mukaiyama T, Kato J, Miyoshi N, Iwasawa N. A Novel and Useful Method for the Preparation of Methyl Esters from Dimethyl Acetals. Cheminform. 16. DOI: 10.1002/Chin.198552189  0.445
1985 Mukaiyama T, Yura T, Iwasawa N. Stereoselective Synthesis of cis-α,ß-Epoxyesters and Aldehydes via Divalent Tin Enolate. A Synthesis of 2-Amino-2-deoxy-D-arabinitol. Cheminform. 16. DOI: 10.1002/Chin.198549067  0.429
1985 Kato J, Iwasawa N, Mukaiyama T. A Novel Method For The Preparation Of Symmetrical And Unsymmetrical Ethers. Trityl Perchlorate Promoted Reduction Of Carbonyl Compounds With Triethylsilane Cheminform. 16. DOI: 10.1002/Chin.198548150  0.47
1985 Huang H, Iwasawa N, Mukaiyama T. A CONVENIENT METHOD FOR THE CONSTRUCTION OF β-LACTAM COMPOUNDS FROM β-AMINO ACIDS USING 2-CHLORO-1-METHYLPYRIDINIUM IODIDE AS CONDENSING REAGENT Cheminform. 16. DOI: 10.1002/Chin.198507165  0.47
1984 Mukaiyama T, Iwasawa N. Versatile relative and absolute stereocontrol in stannous triflate mediated aldol-type reactions of 3-(2-benzyloxyacetyl)thiazolidine-2-thione. Chemistry Letters. 13: 753-756. DOI: 10.1246/Cl.1984.753  0.591
1984 Huang H, Iwasawa N, Mukaiyama T. A CONVENIENT METHOD FOR THE CONSTRUCTION OF β-LACTAM COMPOUNDS FROM β-AMINO ACIDS USING 2-CHLORO-1-METHYLPYRIDINIUM IODIDE AS CONDENSING REAGENT Chemistry Letters. 13: 1465-1466. DOI: 10.1246/Cl.1984.1465  0.523
1984 Mukaiyama T, Iwasawa N, Stevens RW, Haga T. Synthetic control leading to chiral compounds Tetrahedron. 40: 1381-1390. DOI: 10.1016/S0040-4020(01)82423-6  0.54
1983 Iwasawa N, Mukaiyama T. Highly Enantioselective Aldol-Type Reaction Of 3-Acetylthiazolidine-2-Thione With Achiral Aldehydes Chemistry Letters. 12: 297-298. DOI: 10.1246/Cl.1983.297  0.629
1983 Takebayashi T, Iwasawa N, Mukaiyama T, Hata T. Stereoselective Intramolecular Diels-Alder Reactions of α,β-Unsaturated Amides Using Internal Coordination of Metal Salts Bulletin of the Chemical Society of Japan. 56: 1669-1677. DOI: 10.1246/Bcsj.56.1669  0.608
1983 Takebayashi T, Iwasawa N, Mukaiyama T. Synthetic Control by Internal Interaction. The Intramolecular Diels-Alder Reactions of Furan Derivatives and α, β-Unsaturated Amides Bulletin of the Chemical Society of Japan. 56: 1107-1112. DOI: 10.1246/Bcsj.56.1107  0.597
1983 Takebayashi T, Iwasawa N, Mukaiyama T, Hata T. STEREOSELECTIVE INTRAMOLECULAR DIELS-ALDER REACTIONS OF α,β-UNSATURATED AMIDES USING INTERNAL COORDINATION OF METAL SALTS Cheminform. 14. DOI: 10.1002/Chin.198340200  0.565
1983 Iwasawa N, Mukaiyama T. Highly Enantioselective Aldol-Type Reaction Of 3-Acetylthiazolidine-2-Thione With Achiral Aldehydes Cheminform. 14. DOI: 10.1002/Chin.198336215  0.587
1983 Takebayashi T, Iwasawa N, Mukaiyama T. SYNTHETIC CONTROL BY INTERNAL INTERACTION. THE INTRAMOLECULAR DIELS-ALDER REACTIONS OF FURAN DERIVATIVES AND α,β-UNSATURATED AMIDES Cheminform. 14. DOI: 10.1002/Chin.198333204  0.566
1983 Mukaiyama T, Iwasawa N. STANNOUS TRIFLATE MEDIATED ALDOL REACTION OF 3-ACYLTHIAZOLIDINE-2-THIONE: A CONVENIENT METHOD FOR THE STEREOSELECTIVE SYNTHESES OF β-HYDROXY ALDEHYDE AND β-HYDROXY CARBOXYLIC ACID DERIVATIVES Cheminform. 14. DOI: 10.1002/Chin.198323234  0.567
1983 Mukaiyama T, Haga T, Iwasawa N. STEREOSELECTIVE SYNTHESIS OF CIS-α,β-EPOXY KETONES VIA DIVALENT TIN ENOLATE Cheminform. 14. DOI: 10.1002/Chin.198317183  0.43
1983 Iwasawa N, Mukaiyama T. Enantioselective Cross Aldol Reaction Via Divalent Tin Enolate Cheminform. 14. DOI: 10.1002/Chin.198310189  0.563
1983 Stevens RW, Iwasawa N, Mukaiyama T. Stannous Triflate: A Facile Cross-Aldol Reaction Between Two Ketones Via Divalent Tin Enolates Cheminform. 14. DOI: 10.1002/Chin.198310188  0.565
1982 Takebayashi T, Iwasawa N, Mukaiyama T. AN EFFICIENT METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF TRICYCLIC COMPOUNDS—THE INTRAMOLECULAR DIELS–ALDER REACTION OF CYCLIC α,β-UNSATURATED CARBOXAMIDES— Chemistry Letters. 11: 579-582. DOI: 10.1246/Cl.1982.579  0.613
1982 Iwasawa N, Takebayashi T, Mukaiyama T. Synthetic Control By Internal Coordination Of Metal Salts The Intramolecular Ene Reactions Of N-(3-Methyl-2-Butenyl)-N-(2-Hydroxyphenyl)Acrylamides Chemistry Letters. 11: 513-516. DOI: 10.1246/Cl.1982.513  0.539
1982 Mukaiyama T, Stevens RW, Iwasawa N. Stannous Triflate: A New Aldol Reaction Via Divalent Tin Enolates Chemistry Letters. 11: 353-356. DOI: 10.1246/Cl.1982.353  0.572
1982 Mukaiyama T, Iwasawa N. STANNOUS TRIFLATE MEDIATED ALDOL REACTION OF 3-ACYLTHIAZOLIDINE-2-THIONE: A CONVENIENT METHOD FOR THE STEREOSELECTIVE SYNTHESES OF β-HYDROXY ALDEHYDE AND β-HYDROXY CARBOXYLIC ACID DERIVATIVES Chemistry Letters. 11: 1903-1906. DOI: 10.1246/Cl.1982.1903  0.561
1982 Stevens RW, Iwasawa N, Mukaiyama T. Stannous triflate: A facile cross-aldol reaction between two ketones via divalent tin enolates. Chemistry Letters. 11: 1459-1462. DOI: 10.1246/Cl.1982.1459  0.55
1982 Iwasawa N, Mukaiyama T. Enantioselective cross aldol reaction via divalent tin enolate. Chemistry Letters. 11: 1441-1444. DOI: 10.1246/Cl.1982.1441  0.603
1982 Iwasawa N, Takebayashi T, Mukaiyama T. Synthetic Control By Internal Coordination Of Metal Salts. The Intramolecular Ene Reactions Of N-(3-Methyl-2-Butenyl)-N-(2-Hydroxyphenyl)Acrylamides Cheminform. 13. DOI: 10.1002/Chin.198245233  0.494
1982 Takebayashi T, Iwasawa N, Mukaiyama T. AN EFFICIENT METHOD FOR THE STEREOSELECTIVE SYNTHESIS OF TRICYCLIC COMPOUNDS. THE INTRAMOLECULAR DIELS-ALDER REACTION OF CYCLIC α,β-UNSATURATED CARBOXAMIDES Cheminform. 13. DOI: 10.1002/Chin.198245202  0.593
1982 Mukaiyama T, Stevens RW, Iwasawa N. Stannous Triflate: A New Aldol Reaction Via Divalent Tin Enolates Cheminform. 13. DOI: 10.1002/Chin.198234129  0.567
1981 Mukaiyama T, Iwasawa N. A FACILE ASYMMETRIC SYNTHESIS OF β-SUBSTITUTED ALKANOIC ACID THE HIGHLY STEREOSELECTIVE MICHAEL ADDITION OF GRIGNARD REAGENTS TO α,β-UNSATURATED CARBOXYLIC AMIDES DERIVED FROM L-EPHEDRINE Chemistry Letters. 10: 913-916. DOI: 10.1246/Cl.1981.913  0.545
1981 Mukaiyama T, Iwasawa N. THE ASYMMETRIC DIELS–ALDER REACTIONS OF α,β-UNSATURATED CARBOXYLIC AMIDES DERIVED FROM (−)-PHENYLGLYCINOL AND THE ASYMMETRIC TOTAL SYNTHESIS OF (+)-FARNESIFEROL C Chemistry Letters. 10: 29-32. DOI: 10.1246/Cl.1981.29  0.584
1981 Mukaiyama T, Iwasawa N. THE ASYMMETRIC DIELS-ALDER REACTIONS OF α,β-UNSATURATED CARBOXYLIC AMIDES DERIVED FROM (-)-PHENYLGLYCINOL AND THE ASYMMETRIC TOTAL SYNTHESIS OF (+)-FARNESIFEROL C Cheminform. 12. DOI: 10.1002/Chin.198131214  0.595
1980 Mukaiyama T, Iwasawa N, Tsuji T, Narasaka K. New Synthesis Of Karahana Ether Cheminform. 11. DOI: 10.1002/Chin.198011219  0.488
1980 Mukaiyama T, Tsuji T, Iwasawa N. Synthetic Control By Internal Coordination Of Metal Salts. The Intramolecular Diels-Alder Reactions Of N-Furfuryl-N-(2-Hydroxyphenyl)Acrylamides Cheminform. 11. DOI: 10.1002/Chin.198006239  0.493
1979 Mukaiyama T, Tsuji T, Iwasawa N. Synthetic Control By Internal Coordination Of Metal Salts The Intramolecular Diels-Alder Reactions Of N-Furfuryl-N-(2-Hydroxyphenyl)Acrylamides Chemistry Letters. 8: 697-700. DOI: 10.1246/Cl.1979.697  0.558
1979 Mukaiyama T, Iwasawa N, Tsuji T, Narasaka K. NEW SYNTHESIS OF KARAHANA ETHER Chemistry Letters. 8: 1175-1176. DOI: 10.1246/Cl.1979.1175  0.645
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