Raman K. Afshar, Ph.D.

Affiliations: 
University of California, Santa Cruz, Santa Cruz, CA, United States 
Area:
Inorganic Chemistry, Protein Active Site Modeling, Design and Syntheses of NO- and CO-donors, Green Chemistry
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"Raman Afshar"
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Pradip K. Mascharak grad student 2005 UC Santa Cruz
 (Iron nitrosyls derived from polypyridine ligands with carboxamide group(s): Syntheses, structures, photolability of nitric oxide, and S-nitrosylation of thiols and papain.)
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Publications

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Afshar RK, Eroy-Reveles AA, Olmstead MM, et al. (2006) Stoichiometric and catalytic secondary O-atom transfer by Fe(III)-NO 2 complexes derived from a planar tetradentate non-heme ligand: Reminiscence of heme chemistry Inorganic Chemistry. 45: 10347-10354
Afshar RK, Patra AK, Bill E, et al. (2006) Synthesis, structure, and properties of an Fe(II) carbonyl [(PaPy 3)Fe(CO)](ClO4): Insight into the reactivity of Fe(II)-CO and Fe(II)-NO moieties in non-heme iron chelates of N-donor ligands Inorganic Chemistry. 45: 3774-3781
Afshar RK, Granados KE, Olmstead MM, et al. (2006) Unusual iron-mediated C-N bond formation and synthesis of the Fe(III) complex of a polypyridine ligand with one carboxamide group Inorganic Chemistry Communications. 9: 1286-1288
Afshar RK, Bhalla R, Rowland JM, et al. (2006) Syntheses, structures, and properties of Co(III) complexes derived from polypyridine ligands containing one carboxamido nitrogen donor Inorganica Chimica Acta. 359: 4105-4113
Afshar RK, Patra AK, Mascharak PK. (2005) Light-induced inhibition of papain by a {Mn-NO}6 nitrosyl: Identification of papain-SNO adduct by mass spectrometry Journal of Inorganic Biochemistry. 99: 1458-1464
Afshar RK, Patra AK, Olmstead MM, et al. (2004) Syntheses, structures, and reactivities of (Fe-NO)6 nitrosyls derived from polypyridine-carboxamide ligands: photoactive NO-donors and reagents for S-nitrosylation of alkyl thiols. Inorganic Chemistry. 43: 5736-43
Patra AK, Afshar RK, Rowland JM, et al. (2003) Thermally induced stoichiometric and catalytic O-atom transfer by a non-heme iron(III)-nitro complex: first example of reversible [Fe-NO]7<-->FeIII-NO2 transformation in the presence of dioxygen. Angewandte Chemie (International Ed. in English). 42: 4517-21
Patra AK, Afshar R, Olmstead MM, et al. (2002) The first non-heme iron(III) complex with a ligated carboxamido group that exhibits photolability of a bound NO ligand. Angewandte Chemie (International Ed. in English). 41: 2512-5
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