Scott P. Semproni, Ph.D. - Publications

Affiliations: 
2014 Chemistry Princeton University, Princeton, NJ 
Area:
application of organometallic molecules to chemical synthesis

34 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Chirik PJ, Park Y, Semproni SP, Zhong H. Synthesis, Electronic Structure, and Reactivity of a Planar Four-Coordinate, Cobalt-Imido Complex. Angewandte Chemie (International Ed. in English). PMID 33876539 DOI: 10.1002/anie.202104320  0.8
2019 Rummelt SM, Zhong H, Léonard NG, Semproni SP, Chirik PJ. Oxidative Addition of Dihydrogen, Boron Compounds, and Aryl Halides to a Cobalt(I) Cation Supported by a Strong-Field Pincer Ligand. Organometallics. 38: 1081-1090. PMID 30962670 DOI: 10.1021/Acs.Organomet.8B00870  0.808
2017 Yu RP, Darmon JM, Semproni SP, Turner ZR, Chirik PJ. Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals Organometallics. 36: 4341-4343. DOI: 10.1021/Acs.Organomet.7B00398  0.821
2016 Obligacion JV, Semproni SP, Pappas I, Chirik PJ. Cobalt Catalyzed C(spy)-H Borylation: Mechanistic Insights Inspire Catalyst Design. Journal of the American Chemical Society. PMID 27476954 DOI: 10.1021/Jacs.6B06144  0.565
2014 Darmon JM, Yu RP, Semproni SP, Turner ZR, Stieber SC, DeBeer S, Chirik PJ. Electronic Structure Determination of Pyridine N-Heterocyclic Carbene Iron Dinitrogen Complexes and Neutral Ligand Derivatives. Organometallics. 33: 5423-5433. PMID 25328270 DOI: 10.1021/Om500727T  0.788
2014 Scheuermann ML, Semproni SP, Pappas I, Chirik PJ. Carbon dioxide hydrosilylation promoted by cobalt pincer complexes. Inorganic Chemistry. 53: 9463-5. PMID 25171221 DOI: 10.1021/Ic501901N  0.75
2014 Milsmann C, Semproni SP, Chirik PJ. N-N bond cleavage of 1,2-diarylhydrazines and N-H bond formation via H-atom transfer in vanadium complexes supported by a redox-active ligand. Journal of the American Chemical Society. 136: 12099-107. PMID 25066657 DOI: 10.1021/Ja5062196  0.801
2014 Semproni SP, Milsmann C, Chirik PJ. Four-coordinate cobalt pincer complexes: electronic structure studies and ligand modification by homolytic and heterolytic pathways. Journal of the American Chemical Society. 136: 9211-24. PMID 24897302 DOI: 10.1021/Ja504334A  0.8
2014 Margulieux GW, Semproni SP, Chirik PJ. Photochemically induced reductive elimination as a route to a zirconocene complex with a strongly activated N₂ ligand. Angewandte Chemie (International Ed. in English). 53: 9189-92. PMID 24652660 DOI: 10.1002/Anie.201402401  0.689
2014 Obligacion JV, Semproni SP, Chirik PJ. Cobalt-catalyzed C-H borylation. Journal of the American Chemical Society. 136: 4133-6. PMID 24588541 DOI: 10.1021/Ja500712Z  0.568
2014 Semproni SP, Hojilla Atienza CC, Chirik PJ. Oxidative addition and C-H activation chemistry with a PNP pincer-ligated cobalt complex Chemical Science. 5: 1956-1960. DOI: 10.1039/C4Sc00255E  0.676
2014 Russell SK, Hoyt JM, Bart SC, Milsmann C, Stieber SCE, Semproni SP, Debeer S, Chirik PJ. Synthesis, electronic structure and reactivity of bis(imino)pyridine iron carbene complexes: Evidence for a carbene radical Chemical Science. 5: 1168-1174. DOI: 10.1039/C3Sc52450G  0.802
2014 Semproni SP, Chirik PJ. N-H and N-C bond formation with an N2-derived dihafnium μ-nitrido complex Organometallics. 33: 3727-3737. DOI: 10.1021/Om500393N  0.698
2014 Obligacion JV, Semproni SP, Chirik PJ. ChemInform Abstract: Cobalt-Catalyzed C-H Borylation. Cheminform. 45: no-no. DOI: 10.1002/chin.201443184  0.497
2013 Semproni SP, Chirik PJ. Activation of dinitrogen-derived hafnium nitrides for nucleophilic N-C bond formation with a terminal isocyanate. Angewandte Chemie (International Ed. in English). 52: 12965-9. PMID 24123920 DOI: 10.1002/Anie.201307097  0.685
2013 Semproni SP, Chirik PJ. Synthesis of a base-free hafnium nitride from N2 cleavage: a versatile platform for dinitrogen functionalization. Journal of the American Chemical Society. 135: 11373-83. PMID 23829435 DOI: 10.1021/Ja405477M  0.704
2013 Atienza CC, Milsmann C, Semproni SP, Turner ZR, Chirik PJ. Reversible carbon-carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex. Inorganic Chemistry. 52: 5403-17. PMID 23594241 DOI: 10.1021/Ic400352R  0.796
2013 Semproni SP, Knobloch DJ, Milsmann C, Chirik PJ. Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes. Angewandte Chemie (International Ed. in English). 52: 5372-6. PMID 23589359 DOI: 10.1002/Anie.201301800  0.769
2013 Hoyt JM, Sylvester KT, Semproni SP, Chirik PJ. Synthesis and electronic structure of bis(imino)pyridine iron metallacyclic intermediates in iron-catalyzed cyclization reactions. Journal of the American Chemical Society. 135: 4862-77. PMID 23448301 DOI: 10.1021/Ja400895J  0.681
2013 Tondreau AM, Stieber SC, Milsmann C, Lobkovsky E, Weyhermüller T, Semproni SP, Chirik PJ. Oxidation and reduction of bis(imino)pyridine iron dinitrogen complexes: evidence for formation of a chelate trianion. Inorganic Chemistry. 52: 635-46. PMID 23268722 DOI: 10.1021/Ic301675T  0.789
2013 Semproni SP, Chirik PJ. Dinitrogen borylation with group 4 metallocene complexes European Journal of Inorganic Chemistry. 3907-3915. DOI: 10.1002/Ejic.201300046  0.658
2012 Darmon JM, Stieber SC, Sylvester KT, Fernández I, Lobkovsky E, Semproni SP, Bill E, Wieghardt K, DeBeer S, Chirik PJ. Oxidative addition of carbon-carbon bonds with a redox-active bis(imino)pyridine iron complex. Journal of the American Chemical Society. 134: 17125-37. PMID 23043331 DOI: 10.1021/Ja306526D  0.804
2012 Milsmann C, Turner ZR, Semproni SP, Chirik PJ. Azo N=N bond cleavage with a redox-active vanadium compound involving metal-ligand cooperativity. Angewandte Chemie (International Ed. in English). 51: 5386-90. PMID 22514017 DOI: 10.1002/Anie.201201085  0.809
2012 Semproni SP, Milsmann C, Chirik PJ. Structure and reactivity of a hafnocene μ-nitrido prepared from dinitrogen cleavage. Angewandte Chemie (International Ed. in English). 51: 5213-6. PMID 22489093 DOI: 10.1002/Anie.201201361  0.718
2012 Monfette S, Turner ZR, Semproni SP, Chirik PJ. Enantiopure C1-symmetric bis(imino)pyridine cobalt complexes for asymmetric alkene hydrogenation. Journal of the American Chemical Society. 134: 4561-4. PMID 22390262 DOI: 10.1021/Ja300503K  0.753
2012 Knobloch DJ, Semproni SP, Lobkovsky E, Chirik PJ. Studies into the mechanism of CO-induced N2 cleavage promoted by an ansa-hafnocene complex and C-C bond formation from an observed intermediate. Journal of the American Chemical Society. 134: 3377-86. PMID 22324370 DOI: 10.1021/Ja208562D  0.804
2012 Semproni SP, Margulieux GW, Chirik PJ. Di- and tetrametallic hafnocene oxamidides prepared from CO-induced N 2 bond cleavage and thermal rearrangement to hafnocene cyanide derivatives Organometallics. 31: 6278-6287. DOI: 10.1021/Om3005542  0.665
2012 Semproni SP, Milsmann C, Chirik PJ. Side-on dinitrogen complexes of titanocenes with disubstituted cyclopentadienyl ligands: Synthesis, structure, and spectroscopic characterization Organometallics. 31: 3672-3682. DOI: 10.1021/Om300156Z  0.768
2011 Semproni SP, Lobkovsky E, Chirik PJ. Dinitrogen silylation and cleavage with a hafnocene complex. Journal of the American Chemical Society. 133: 10406-9. PMID 21682285 DOI: 10.1021/Ja2042595  0.699
2010 Semproni SP, Stephen McNeil W, Baillie RA, Patrick BO, Campana CF, Legzdins P. Ground-state electronic asymmetry in Cp*W(NO)(η1- isonitrile)2 complexes Organometallics. 29: 867-875. DOI: 10.1021/Om901018N  0.504
2010 Graham PM, Buschhaus MSA, Baillie RA, Semproni SP, Legzdins P. Hydroperoxide-initiated intramolecular insertions of NO into metal-carbon bonds Organometallics. 29: 5068-5072. DOI: 10.1021/Om1002842  0.434
2009 Semproni SP, Legzdins P. Unprecedented reactivity initiated by insertion of 2,6-xylylisonitrile into the w-alkyl linkages of Cp*W(NO)(n-alkyl)(η3-CH 2CHCHMe) complexes Organometallics. 28: 6139-6141. DOI: 10.1021/Om900739K  0.497
2009 Semproni SP, Graham PM, Buschhaus MSA, Patrick BO, Legzdins P. Toward alkane functionalization effected with CpW(NO)(alkyl) (η3-allyl) Complexes Organometallics. 28: 4480-4490. DOI: 10.1021/Om900307P  0.519
2008 Tsang JY, Buschhaus MS, Graham PM, Semiao CJ, Semproni SP, Kim SJ, Legzdins P. Facile and selective aliphatic C-H bond activation at ambient temperatures initiated by Cp*W(NO)(CH2CMe3)(eta(3)-CH2CHCHMe). Journal of the American Chemical Society. 130: 3652-63. PMID 18284241 DOI: 10.1021/Ja710606V  0.542
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