Edward McC. Arnett - Publications

Affiliations: 
Chemistry Duke University, Durham, NC 
Area:
reactive intermediates
Website:
http://www.chem.duke.edu/faculty/edward-m-arnett

68 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
1997 Arnett EM, Flowers RA, Ludwig RT, Meekhof AE, Walek SA. Triarylmethanes and 9-arylxanthenes as prototypes amphihydric compounds for relating the stabilities of cations, anions and radicals by C-H bond cleavage and electron transfer Journal of Physical Organic Chemistry. 10: 499-513. DOI: 10.1002/(Sici)1099-1395(199707)10:7<499::Aid-Poc896>3.0.Co;2-2  0.547
1996 Stoelting DT, Ludwig RT, Arnett EM. 2-Aryl-1,3-dithianes and -dithiolanes: A nearly ideal series for relating the energies for bond breaking to electron transfer Heteroatom Chemistry. 7: 481-502. DOI: 10.1002/(Sici)1098-1071(199611)7:6<481::Aid-Hc11>3.0.Co;2-M  0.347
1995 Arnett EM, Flowers RA, Ludwig RT, Meekhof A, Walek S. Thermodynamics for C-H bond-breaking of some amphihydric compounds by transfer of protons, hydride ions, H-atoms and electrons Pure and Applied Chemistry. 67: 729-734. DOI: 10.1351/Pac199567050729  0.527
1994 Arnett EM, Flowers RA, Meekhof AE, Pourjavadi A, Walek SA. Stabilities of some 2-(para-substituted-phenyl)-4,4,5,5-tetramethyl-1,3-dioxolanes relative to their conjugate dioxolenium ions, radicals and carbanions as determined by thermodynamics for hydride and electron transfer in solution Journal of Physical Organic Chemistry. 7: 663-671. DOI: 10.1002/Poc.610071204  0.563
1994 Seebach D, Bossler HG, Flowers R, Arnett EM. Calorimetric Measurements of the Complexation of Cyclosporin A, Ascomycin, Fujimycin, and Rapamycin with Lithium Chloride and with an Immunophilin Helvetica Chimica Acta. 77: 291-305. DOI: 10.1002/Hlca.19940770129  0.511
1993 Arnett EM, Flowers RA. Bond cleavage energies for molecules and their associated radical ions Chemical Society Reviews. 22: 9-15. DOI: 10.1039/Cs9932200009  0.539
1993 Arnett EM, Flowers RA, Meekhof AE, Miller L. Energetics of formation for conjugate xanthyl carbenium ions, carbanions, and radicals by hydride, proton, and electron transfer in solution and their reactions to give symmetrical bixanthyls Journal of the American Chemical Society. 115: 12603-12604. DOI: 10.1021/Ja00079A057  0.355
1992 Arnett EM, Dowd P, Flowers RA, Ham SK, Naganathan S. Thermochemical confirmation of the mechanism of action of vitamin K Journal of the American Chemical Society. 114: 9209-9210. DOI: 10.1021/Ja00049A075  0.45
1992 Arnett EM, Venimadhavan S, Amarnath K. Homolytic and heterolytic cleavage energies for carbon-nitrogen bonds Journal of the American Chemical Society. 114: 5598-5602. DOI: 10.1021/Ja00040A018  0.321
1991 Arnett EM, Venimadhavan S. Heats of reaction of resonance-stabilized carbenium ions with nitrogen bases Journal of Organic Chemistry. 56: 2742-2745. DOI: 10.1021/Jo00008A031  0.326
1990 Arnett EM, Amarnath K, Harvey NG, Cheng JP. Chemical bond-making, bond-breaking, and electron transfer in solution. Science (New York, N.Y.). 247: 423-30. PMID 17788608 DOI: 10.1126/Science.247.4941.423  0.359
1990 Arnett EM, Amarnath K, Venimadhavan S. Heats of reaction for nucleophilic and electrophilic displacement reactions in solution Journal of Organic Chemistry. 55: 3593-3596. DOI: 10.1021/Jo00298A040  0.314
1990 Arnett EM, Amarnath K, Harvey NG, Venimadhavan S. Heterolysis and homolysis energies for some carbon-oxygen bonds Journal of the American Chemical Society. 112: 7346-7353. DOI: 10.1021/Ja00176A039  0.351
1988 Harvey N, Rose P, Porter NA, Huff JB, Arnett EM. Monolayer properties of eight diastereomeric two-chain surfactants at the air/water interface: a resultant of intramolecular and intermolecular forces Journal of the American Chemical Society. 110: 4395-4399. DOI: 10.1021/Ja00221A046  0.441
1987 Arnett EM, Harrelson JA. A spectacular example of the importance of rotational barriers: The ionization of Meldrum's acid Journal of the American Chemical Society. 109: 809-812. DOI: 10.1021/Ja00237A028  0.321
1986 Arnett EM, Haaksma RA, Chawla B, Healy MH. Thermochemical comparisons of homogeneous and heterogeneous acids and bases. 1. Sulfonic acid solutions and resins as prototype Brönsted acids Journal of the American Chemical Society. 108: 4888-4896. DOI: 10.1021/Ja00276A030  0.332
1986 Porter NA, Arnett EM, Brittain WJ, Johnson EA, Krebs PJ. Stereoselectivity in the photolysis of diastereomeric diazene surfactants in aggregated media Journal of the American Chemical Society. 108: 1014-1018. DOI: 10.1021/Ja00265A028  0.438
1986 Arnett EM, Molter K. Thermodynamics and kinetics of carbon-carbon bond formation and heterolysis through reactions of carbocations with carbanions in solution Journal of Physical Chemistry. 90: 383-389. DOI: 10.1002/Chin.198624116  0.312
1985 Arnett EM, Maroldo SG, Schriver GW, Schilling SL, Troughton EB. Ion pairing and reactivity of enolate anions. 6. Kinetics and thermodynamics for reaction of alkali acetylacetonates with alkyl halides in dimethyl sulfoxide Journal of the American Chemical Society. 107: 2091-2099. DOI: 10.1002/Chin.198533154  0.348
1984 Arnett EM, Maroldo SG, Schilling SL, Harrelson JA. Ion pairing and reactivity of enolate anions. 5. Thermodynamics of ionization of β-di- and tricarbonyl compounds in dimethyl sulfoxide solution and ion pairing of their alkali salts Journal of the American Chemical Society. 106: 6759-6767. DOI: 10.1002/Chin.198509126  0.339
1983 Arnett EM, Troughton EB. CarbonCarbon bond formation by coordination of carbocations with carbanions. Tetrahedron Letters. 24: 3299-3302. DOI: 10.1016/S0040-4039(00)86253-X  0.318
1982 Arnett EM, Venkatasubramaniam KG, McIver RT, Fukuda EK, Bordwell FG, Press RD. Stabilization of the monoanion of 1,8-diaminonaphthalene by intramolecular hydrogen bonding. A novel case of amide ion homoconjugation in a superbase solution Journal of the American Chemical Society. 104: 325-326. DOI: 10.1021/Ja00365A075  0.33
1981 Arnett E, Chawla B. Additions and Corrections - Complete Thermodynamic Analysis of the Hydration of Thirteen Pyridines and Pyridium Ions. The Special Case Of 2,6-Di-tert-butylpyridine Journal of the American Chemical Society. 103: 7036-7036. DOI: 10.1021/Ja00413A602  0.307
1981 Arnett EM, Zingg SP. Chiral discrimination in the energetics of ion aggregation Journal of the American Chemical Society. 103: 1221-1222. DOI: 10.1021/Ja00395A042  0.308
1980 Arnett EM, Pienta NJ. Stabilities of carbonium ions in solution. 12. Heats of formation of alkyl chlorides as an entreé to heats of solvation of aliphatic carbonium ions Journal of the American Chemical Society. 102: 3329-3334. DOI: 10.1021/Ja00530A004  0.338
1980 Arnett EM, Pienta N, Petro C. Stabilities of carbonium ions in solution. 10. A thermochemical comparison of the relative stabilities of long-lived 2-norbornyl and butyl cations in sulfuryl chloride fluoride/antimony pentafluoride Journal of the American Chemical Society. 102: 398-400. DOI: 10.1021/Ja00521A078  0.324
1980 Arnett EM, Pienta N, Petro C. Stabilities Of Carbonium Ions In Solution. 10. A Thermochemical Comparison Of F The Relative Stabilities Of Long-Lived 2-Norbornyl And Butyl Cations In Sulfuryl Chloride Fluoride/Antimony Pentafluoride Cheminform. 11. DOI: 10.1002/Chin.198016102  0.304
1979 Arnett EM, Chawla B. Complete thermodynamic analysis of the hydration of thirteen pyridines and pyridinium ions. The special case of 2,6-Di-tert-butylpyridine Journal of the American Chemical Society. 101: 7141-7146. DOI: 10.1021/Ja00518A001  0.308
1979 Arnett EM, Petro C, Schleyer PVR. Carbonium ions in solution. 9. The relationship between carbocations in superacid and solvolysis transition states Journal of the American Chemical Society. 101: 522-526. DOI: 10.1021/Ja00497A003  0.305
1978 Arnett EM, Petro C. Stabilities of carbonium ions in solution. 8. Heats of ionization of some simple alkyl halides in superacidic media Journal of the American Chemical Society. 100: 5408-5416. DOI: 10.1021/Ja00485A026  0.339
1978 Arnett EM, Petro C. Stabilities of carbonium ions in solution. VI. A low temperature calorimetric approach to enthalpies of formation of carbocations in solution Preprints. 23: 128-140. DOI: 10.1021/Ja00485A025  0.358
1978 Arnett EM, Petro C. Stabilities of carbonium ions in solution. 6. Heats of formation of simple alkyl carbonium ions in sulfuryl chloride fluoride and their relevance to the nonclassical ion question Journal of the American Chemical Society. 100: 2563-2564. DOI: 10.1021/Ja00476A058  0.341
1978 Taft RW, Wolf JF, Beauchamp JL, Scorrano G, Arnett EM. Solvent effects of water and fluorosulfuric acid on proton transfer equilibria and the energies of solvation of gaseous onium ions Journal of the American Chemical Society. 100: 1240-1249. DOI: 10.1021/Ja00472A035  0.357
1978 Arnett EM, Chawla B. Thermometric titrations of substituted pyridines with trifluoroacetic acid in carbon tetrachloride. Hydrogen bonded ion pair systems Journal of the American Chemical Society. 100: 217-221. DOI: 10.1021/Ja00469A038  0.338
1978 DePalma VM, Arnett EM. Reactivity and ion pairing of alkali β-ketoenolates Journal of the American Chemical Society. 100: 3514-3525. DOI: 10.1002/Chin.197835096  0.366
1978 Arnett EM, Petro C. Stabilities Of Carbonium Ions In Solution. 6. Heats Of Formation Of Simple Alkyl Carbonium Ions In Sulfuryl Chloride Fluoride And Their Relevance To The Nonclassical Ion Question Cheminform. 9. DOI: 10.1002/Chin.197832138  0.341
1977 Arnett EM, Chawla B, Bell L, Taagepera M, Hehre WJ, Taft RW. Solvation and hydrogen bonding of pyridinium ions Journal of the American Chemical Society. 99: 5729-5738. DOI: 10.1021/Ja00459A034  0.304
1975 Arnett EM, Johnston DE, Small LE, Oancea D. Enthalpies of formation and solvation of some organic anions Faraday Symposia of the Chemical Society. 10: 20-28. DOI: 10.1039/Fs9751000020  0.352
1975 Arnett EM, Johnston DE, Small LE. Solvation of gaseous carbanions in dimethylsulfoxide Journal of the American Chemical Society. 97: 5598-5600. DOI: 10.1021/Ja00852A056  0.327
1975 Arnett EM, Abboud JLM. Baker-Nathan effect on solvation energies of benzenonium and other organic ions Journal of the American Chemical Society. 97: 3865-3867. DOI: 10.1021/Ja00846A078  0.311
1975 Arnett EM, Wolf JF. Solvation energies of aliphatic ammonium ions in water and fluorosulfuric acid Journal of the American Chemical Society. 97: 3262-3264. DOI: 10.1021/Ja00844A080  0.323
1975 Arnett EM, Johnston DE, Small LE. Solvation Of Gaseous Carbanions In Dimethyl Sulfoxide Cheminform. 6. DOI: 10.1002/Chin.197549103  0.332
1975 Arnett EM, Abboud JM. The Baker-Nathan Effect On Solvation Energies Of Benzenonium And Other Organic Ions Cheminform. 6. DOI: 10.1002/Chin.197536098  0.311
1974 Arnett EM, Small LE, McIver RT, Miller JS. Experimental solvation energies of aliphatic alkoxide ions and hydroxide ions Journal of the American Chemical Society. 96: 5638-5640. DOI: 10.1021/Ja00824A090  0.311
1973 Arnett EM, Wolf JF. Solvent effects in organic chemistry. XVI. An enormous alkyl substituent effect in solution Journal of the American Chemical Society. 95: 978-980. DOI: 10.1021/Ja00784A088  0.311
1973 ARNETT EM, MORIARITY TC, SMALL LE, RUDOLPH JP, QUIRK RP. ChemInform Abstract: SCHWACHE SAEUREN IN STARKEN BASEN 1. MITT. THERMOCHEMISCHE METHODE FUER DEN VERGLEICH VON ACIDITAETEN Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197319103  0.471
1972 Arnett EM, Burke JJ, Carter JV, Douty CF. Solvent effects in organic chemistry. XV. Thermodynamics of solution for nonelectrolytes in aqueous acid and salt solutions Journal of the American Chemical Society. 94: 7837-7852. DOI: 10.1021/Ja00777A029  0.317
1972 Arnett EM, Ko HC, Chao CC. Solvent effects in organic chemistry. XIV. Complexing of sodium ion by various common solvents as ligands in acetone solutions [34] Journal of the American Chemical Society. 94: 4776-4777. DOI: 10.1021/Ja00768A081  0.334
1971 Arnett EM, Moriarity TC. Heats of complexing of alkali metal ions with a crown ether in aprotic solvents [5] Journal of the American Chemical Society. 93: 4908-4910. DOI: 10.1021/Ja00748A044  0.307
1970 Arnett EM, Carter JV, Quirk RP. Weak bases in strong acids. V. Substituent effects in the formation of some protonated ketones and the corresponding carbonium ions Journal of the American Chemical Society. 92: 1770-1772. DOI: 10.1021/Ja00709A065  0.56
1970 ARNETT EM, QUIRK RP, LARSEN JW. ChemInform Abstract: SCHWACHE BASEN IN STARKEN SAEUREN 4. MITT. AUF DISSOZIATIONSWAERMEN PROTONIERTER CARBONYLVERBINDUNGEN IN FLUOROSCHWEFELSAEURE BERUHENDE BASIZITAETSSKALA Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197040135  0.489
1970 ARNETT EM, CARTER JV, QUIRK RP. ChemInform Abstract: SUBSTITUENTENEFFEKTE BEI DER BLDG. VON PROTONIERTEN KETONEN UND DER ENTSPRECHENDEN CARBONIUMIONEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197024061  0.5
1970 ARNETT EM, QUIRK RP, BURKE JJ. ChemInform Abstract: SCHWACHE BASEN IN STARKEN SAEUREN 3. MITT. DISSOZIATIONSWAERME VON AMINEN IN FLUORSCHWEFELSAEURE UND SCHWEFELSAEURE, NEUE ALLGEMEINE BASIZITAETSBESTIMMUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197022060  0.493
1969 Arnett EM, Larsen JW. Stabilities of carbonium ions in solution. IV. A large Baker-Nathan effect for alkylbenzenonium ions Journal of the American Chemical Society. 91: 1438-1442. DOI: 10.1021/Ja01034A029  0.328
1968 Arnett EM, Larsen JW. Stabilities of carbonium ions in solution. II. Benzenonium ions in antimony pentafluoride-fluorosulfonic acid at -60.degree. Journal of the American Chemical Society. 90: 792-793. DOI: 10.1021/Ja01005A043  0.342
1968 Arnett EM, Larsen JW. Stabilities of carbonium ions in solution. I. Calorimetric heats of formation in fluorosulfonic acid antimony pentafluoride mixtures at -60.degree. Journal of the American Chemical Society. 90: 791-792. DOI: 10.1021/Ja01005A042  0.358
1966 Arnett EM, McKelvey DR. Enthalpies of Transfer from Water to Dimethyl Sulfoxide for Some Ions and Molecules1,2 Journal of the American Chemical Society. 88: 2598-2599. DOI: 10.1021/Ja00963A047  0.308
1966 Arnett EM, Burke JJ. Weak Bases in Strong Acids. I. On the Hydration of Anilinium Ions in Aqueous Sulfuric Acid1 Journal of the American Chemical Society. 88: 2340-2341. DOI: 10.1021/Ja00962A060  0.339
1965 Arnett EM, Bentrude WG, Duggleby PM. Salt-Like Behavior of the t-Butyl Chloride Solvolysis Transition State1,2 Journal of the American Chemical Society. 87: 2048-2050. DOI: 10.1021/Ja01087A035  0.49
1965 Arnett EM, Bentrude WG, Burke JJ, Duggleby PM. Solvent effects in organic chemistry. V. Molecules, ions, and transition states in aqueous ethanol Journal of the American Chemical Society. 87: 1541-1553. DOI: 10.1021/Ja01085A024  0.528
1965 Arnett EM, Klingensmith GB. Aromatic displacements. III. The cleavage of benzhydrols. The mechanism in 50% aqueous acetic acid Journal of the American Chemical Society. 87: 1038-1045. DOI: 10.1021/Ja01083A018  0.305
1965 Arnett EM, Bentrude WG, Duggleby PM. Salt-like behavior of the t-butyl chloride solvolysis transition state [3] Journal of the American Chemical Society. 87: 2048-2050.  0.434
1964 Arnett EM, Bushick RD. Solvent effects in organic chemistry. III. Solvation of stable carbonium and ammonium ions in water. The temperature coefficient of the HR acidity scale Journal of the American Chemical Society. 86: 1564-1571. DOI: 10.1021/Ja01062A024  0.331
1962 Arnett EM, Wu CY. Base strengths of some saturated cyclic ethers in aqueous sulfuric acid Journal of the American Chemical Society. 84: 1684-1688. DOI: 10.1021/Ja00868A038  0.304
1962 Arnett EM, Wu CY. Base strengths of some aliphatic ethers in aqueous sulfuric acid Journal of the American Chemical Society. 84: 1680-1684. DOI: 10.1021/Ja00868A037  0.303
1960 Arnett EM, Wu CY. Stereoelectronic effects on organic bases. III. The basicities of some saturated ethers in aqueous sulfuric acid [1] Journal of the American Chemical Society. 82: 4999-5000. DOI: 10.1021/Ja01503A060  0.313
1951 Arnett EM, Miller JG, Day AR. Effect of Structure on Reactivity.1IV. Aminolysis of Esters with Secondary Amines Journal of the American Chemical Society. 73: 5393-5395. DOI: 10.1021/Ja01155A113  0.615
1950 Arnett EM, Miller JG, Day AR. Effect of Structure on Reactivity.1III. Aminolysis of Esters with Primary Amines2 Journal of the American Chemical Society. 72: 5635-5638. DOI: 10.1021/Ja01168A075  0.609
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