Dimitri N. Coucouvanis - Publications

Affiliations: 
Chemistry University of Michigan, Ann Arbor, Ann Arbor, MI 
Area:
Design, Synthesis, Structures and Reactivities of Metal Clusters and Supramolecules
Website:
https://lsa.umich.edu/chem/people/emeritus/dcouc.html

91 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Demadis KD, Malinak SM, Coucouvanis D. Catalytic Reduction of Hydrazine to Ammonia with MoFe(3)S(4)-Polycarboxylate Clusters. Possible Relevance Regarding the Function of the Molybdenum-Coordinated Homocitrate in Nitrogenase. Inorganic Chemistry. 35: 4038-4046. PMID 11666602 DOI: 10.1021/ic960098b  0.371
2013 Paital AR, Zhan J, Kim R(, Kampf J, Collins P, Coucouvanis D. Synthesis and structures of perthio- and polymeric metal complexes with the tetrathio- and dithioterephthalate ligands Polyhedron. 64: 328-338. DOI: 10.1016/J.Poly.2013.06.003  0.427
2013 Gerlach DL, Coucouvanis D, Kampf J, Lehnert N. Isolation and characterization of single and sulfide-bridged double [4Fe-4S] cubane clusters with 4-pyridinethiolato ligands European Journal of Inorganic Chemistry. 5253-5264. DOI: 10.1002/Ejic.201300802  0.799
2013 Gerlach DL, Coucouvanis D, Lehnert N. Connecting [4Fe-4S] clusters and hemes - Towards modeling the active site of sulfite reductase European Journal of Inorganic Chemistry. 3883-3890. DOI: 10.1002/Ejic.201300308  0.783
2009 Coucouvanis D, Paital AR, Zhang Q, Lehnert N, Ahlrichs R, Fink K, Fenske D, Powell AK, Lan Y. Synthesis, electronic structure, and structural characterization of the new, "non-innocent" 4,5-dithio-catecholate ligand, its metal complexes, and their oxidized 4,5-dithio-o-quinone derivatives. Inorganic Chemistry. 48: 8830-44. PMID 19691301 DOI: 10.1021/Ic901002Y  0.635
2008 Koutmos M, Georgakaki IP, Tsiolis P, Coucouvanis D. Synthesis and characterization of MoFe3S4 and Mo 2Fe2S4 single cubanes Zeitschrift Fur Anorganische Und Allgemeine Chemie. 634: 255-261. DOI: 10.1002/Zaac.200700419  0.701
2007 Kalyvas H, Coucouvanis D. Synthesis and reactivity of a new octanuclear iron-sulfur nitrosyl cluster. Inorganic Chemistry. 45: 8462-4. PMID 17029349 DOI: 10.1021/ic060417r  0.325
2007 Kalyvas H, Coucouvanis D. Synthesis and characterization of new heterometallic iron sulfur nitrosyl clusters Polyhedron. 26: 4765-4778. DOI: 10.1016/J.Poly.2007.06.015  0.536
2006 Xiao Y, Koutmos M, Case DA, Coucouvanis D, Wang H, Cramer SP. Dynamics of an [Fe4S4(SPh)4]2- cluster explored via IR, Raman, and nuclear resonance vibrational spectroscopy (NRVS)-analysis using 36S substitution, DFT calculations, and empirical force fields. Dalton Transactions (Cambridge, England : 2003). 2192-201. PMID 16673033 DOI: 10.1039/B513331A  0.715
2006 Koutmos M, Georgakaki IP, Coucouvanis D. Borohydride, azide, and chloride anions as terminal ligands on Fe/Mo/S clusters. Synthesis, structure and characterization of [(Cl4-cat)(PPr3) MoFe3S4(X)2]2(Bu4N)4 and [(Cl4-cat)(PPr3)MoFe3S4 (PPr3)(X)]2(Bu4N)2 (X = N3-, BH4-, Cl-) double-fused cubanes. NMR reactivity studies of [(Cl4-cat)(PPr3) MoFe3S4(BH4)2]2(Bu4N)4. Inorganic Chemistry. 45: 3648-56. PMID 16634597 DOI: 10.1021/Ic052156B  0.757
2006 Koutmos M, Coucouvanis D. Metal clusters as ligands. Substitution of fe ions in Fe/Mo/S clusters by thiophilic CuI ions. Inorganic Chemistry. 45: 1421-3. PMID 16471948 DOI: 10.1021/Ic051860P  0.76
2005 Smith MC, Xiao Y, Wang H, George SJ, Coucouvanis D, Koutmos M, Sturhahn W, Alp EE, Zhao J, Cramer SP. Normal-mode analysis of FeCl4- and Fe2S2Cl42- via vibrational mössbauer, resonance Raman, and FT-IR spectroscopies. Inorganic Chemistry. 44: 5562-70. PMID 16060605 DOI: 10.1021/Ic0482584  0.673
2005 Han J, Coucouvanis D. Synthesis and structure of the organometallic MFe2(mu3-S)2 clusters (M = Mo or Fe). Dalton Transactions (Cambridge, England : 2003). 1234-40. PMID 15782259 DOI: 10.1039/B419051C  0.672
2005 Koutmos M, Kalyvas H, Sanakis Y, Simopoulos A, Coucouvanis D. Systematic synthesis of heterometallic Ni/Fe/S and Cu/Fe/S clusters with a pentlandite-like M8S6 core. Journal of the American Chemical Society. 127: 3706-7. PMID 15771499 DOI: 10.1021/Ja042938O  0.73
2005 Koutmos M, Coucouvanis D. Metal clusters as ligands: substitution of Fe ions in Fe/Mo/S clusters by thiophilic Cu(I) ions to give clusters with [Cu4Mo2Fe2S8]4+ and [Cu5Mo3Fe4S11]6+ cores. Angewandte Chemie (International Ed. in English). 44: 1971-4. PMID 15724256 DOI: 10.1002/Anie.200462596  0.746
2004 Koutmos M, Coucouvanis D. Borohydride anions as terminal ligands on a Fe/Mo/S cluster. Synthesis, structure, and characterization of the [(Cl4-cat)(PPr3)MoFe3S4(BH4)2]2(Bu4N)4 double-fused cubane. Inorganic Chemistry. 43: 6508-10. PMID 15476337 DOI: 10.1021/Ic049275W  0.775
2004 Koutmos M, Coucouvanis D. Superclusters: a host-guest complex with a cyclic array of three bridged MoFe3S4 clusters. Angewandte Chemie (International Ed. in English). 43: 5023-5. PMID 15384123 DOI: 10.1002/Anie.200460154  0.702
2004 Nava P, Han J, Ahlrichs R, Coucouvanis D. An evaluation by density functional theory of M-M interactions in organometallic clusters with the [Fe(3)MoS(3)](2+) cores. Inorganic Chemistry. 43: 3225-9. PMID 15132630 DOI: 10.1021/Ic0499392  0.599
2004 Huniar U, Ahlrichs R, Coucouvanis D. Density functional theory calculations and exploration of a possible mechanism of N2 reduction by nitrogenase. Journal of the American Chemical Society. 126: 2588-601. PMID 14982469 DOI: 10.1021/Ja030541Z  0.307
2003 Coucouvanis D, Rosa D, Pike J. Recognition and transport of amphiphilic molecules by a new class of inorganic ditopic receptors. The synthesis of M-t Bu4-salphen-3n-cr-n complexes and their use (M = Mn,Fe, n = 6) in the transport of tryptophan and serotonin across bulk liquid membranes Comptes Rendus Chimie. 6: 317-327. DOI: 10.1016/S1631-0748(03)00041-9  0.761
2003 Coucouvanis D, Han J, Ahlrichs R, Nava P, Huniar U. Density functional theory calculations on the nitrogenase cofactor and synthetic analogs Journal of Inorganic Biochemistry. 96: 19. DOI: 10.1016/S0162-0134(03)80435-X  0.439
2002 Han J, Coucouvanis D. Synthesis and structure of singly bridged and doubly bridged [MoFe(3)S(4)] double cubanes with bidentate phosphine ligands. Inorganic Chemistry. 41: 2738-46. PMID 12005498 DOI: 10.1021/Ic010913+  0.628
2002 Coucouvanis D, Han J, Moon N. Synthesis and characterization of sulfur-voided cubanes. Structural analogues for the MoFe(3)S(3) subunit in the nitrogenase cofactor. Journal of the American Chemical Society. 124: 216-24. PMID 11782173 DOI: 10.1021/Ja0110832  0.669
2002 Han J, Huang M, Coucouvanis D. New heteronuclear Mo/Fe/S clusters. The syntheses and structures of (Cl4-cat)Mo(PEt3)Fe3S4(SPEt3)2Cl and (Cl4-cat)2MoFe2S2(PEt3)2(CO)4 clusters Polyhedron. 21: 2523-2530. DOI: 10.1016/S0277-5387(02)01208-1  0.662
2002 Swenson D, Baenziger NC, Coucouvanis D. Tetrahedral Mercaptide Complexes. Crystal And Molecular Structures Of ((C6H5)4P)2M(Sc6H5)4 Complexes (M = Cadmium(Ii), Zinc(Ii), Nickel(Ii), Cobalt(Ii), And Manganese(Ii)) Cheminform. 9. DOI: 10.1002/Chin.197827056  0.318
2001 Han J, Koutmos M, Ahmad SA, Coucouvanis D. Rational synthesis of high nuclearity Mo/Fe/S clusters: the reductive coupling approach in the convenient synthesis of (Cl(4)-cat)(2)Mo(2)Fe(6)S(8)(PR(3))(6) [R = Et, (n)Pr, (n)Bu] and the new [(Cl(4)-cat)(2)Mo(2)Fe(2)S(3)O(PEt(3))(3)Cl]-1/2(Fe(PEt(3))(2)(MeCN)(4)) and (Cl(4)-cat)(2)Mo(2)Fe(3)S(5)(PEt(3))(5) clusters. Inorganic Chemistry. 40: 5985-99. PMID 11681915 DOI: 10.1021/Ic0104914  0.779
2001 Stavrev KK, Urahata S, Herz T, Han J, Coucouvanis D. Theoretical study on the electronic structure and properties of synthetic MoFe3S3 compounds International Journal of Quantum Chemistry. 85: 469-474. DOI: 10.1002/Qua.1538  0.613
2001 Pike JD, Rosa DT, Coucouvanis D. Lipophilic Metal−Salicylideneimine−Crown Ether Hybrids — Ditopic Carriers in the Facilitated Transport of Amphiphilic Molecules Across Bulk Liquid Membranes European Journal of Inorganic Chemistry. 2001: 761-777. DOI: 10.1002/1099-0682(200103)2001:3<761::Aid-Ejic761>3.0.Co;2-Z  0.723
1998 Reynolds III RA, Dunham WR, Coucouvanis D. Kinetic Lability, Structural Diversity, and Oxidation Reactions of New Oligomeric, Anionic Carboxylate-Pyridine Complexes. Inorganic Chemistry. 37: 1232-1241. PMID 11670328 DOI: 10.1021/Ic971537P  0.479
1998 Rosa DT, Young VG, Coucouvanis D. Crown-Ether-Functionalized Mn(III) Salicylaldimine Complexes as Ditopic Carriers. Efficient Transport of Tryptophan and Serotonin across a CHCl3 Barrier Inorganic Chemistry. 37: 5042-5043. DOI: 10.1021/Ic9808910  0.343
1998 Coucouvanis D. Syntheses, Structures, and Reactions of Binary and Tertiary Thiomolybdate Complexes Containing the (O)Mo(Sx) AND (S)Mo(Sx) Functional Groups (x = 1, 2, 4) Advances in Inorganic Chemistry. 45: 1-73. DOI: 10.1016/S0898-8838(08)60024-0  0.399
1998 Kröckel M, Trautwein AX, Winkler H, Coucouvanis D, Kostikas A, Papaefthymiou V. A synthetic iron-containing prismane complex: peculiar electron-delocalization and spin-coupling properties deduced from Mössbauer and magnetization studies Inorganica Chimica Acta. 283: 111-117. DOI: 10.1016/S0020-1693(98)00308-9  0.322
1997 Mandimutsira BS, Chen S-, Reynolds RA, Coucouvanis D. The synthesis and structural characterization of the [Nb(Se)3StBu]2−, [Nb(O)(Se2)SeH]2−, [(Nb(O)(Se2)2)2Se4]4− and {[Nb(Se)3]2O}4− anions. New elementary selenoniobates Polyhedron. 16: 3911-3920. DOI: 10.1016/S0277-5387(97)00218-0  0.368
1996 Reynolds RA, Yu WO, Dunham WR, Coucouvanis D. Synthesis and Characterization of a New Class of μ3-OH-Bridged Trimers That Contain Octahedrally Coordinated Divalent Metal Ions Bridged by Three Acetate Ligands and a Unique Catecholate Ligand. Solid State Molecular Structures of the [(py)5MII3(OAc)3(μ3-OH)((cat)] Complexes (M = Mn(II), Fe(II), Co(II), Ni(II)) Inorganic Chemistry. 35: 2721-2722. DOI: 10.1021/Ic960097J  0.451
1996 Coucouvanis D, Demadis KD, Malinak SM, Mosier PE, Tyson MA, Laughlin LJ. Catalytic and stoichiometric multielectron reduction of hydrazine to ammonia and acetylene to ethylene with clusters that contain the MFe3S4 cores (MMo, V). Relevance to the function of nitrogenase Journal of Molecular Catalysis a-Chemical. 107: 123-135. DOI: 10.1016/1381-1169(95)00168-9  0.434
1996 Jonasdottir S, Kim C, Kampf J, Coucouvanis D. Macrocyclic catecholate complexes as ligands. Synthesis, structural characterization and properties of the [MH2ETC] and {[Ni(ETC)]Cu}– complexes (M = Co, Ni; H4ETC = the macrocyclic catechol, 2,3-ethylene-5,6:13,14-di(5′-methylbzo)-9,10-(4′,5′-diolbzo)-[14]-1,4,8,11-[N4]-7, 12-diene) Inorganica Chimica Acta. 243: 255-270. DOI: 10.1016/0020-1693(95)04916-9  0.38
1996 Coucouvanis D. Functional analogs for the reduction of certain nitrogenase substrates. Are multiple sites within the Fe/Mo/S active center involved in the 6e – reduction of N 2 ? Journal of Biological Inorganic Chemistry. 1: 594-600. DOI: 10.1007/S007750050098  0.526
1995 Coucouvanis D, Reynolds RA, Dunham WR. Synthesis and Characterization of a New Class of Asymmetric Aqua-Acetate Bridged Dimers. Solid State Molecular Structures of the [M2(.mu.-H2O)(.mu.-OAc)2(OAc)3(Py)2]- Anions (M = Mn(II), Fe(II), Co(II)). A Structural Model for the Fe2 Site in Methane Monooxygenase Journal of the American Chemical Society. 117: 7570-7571. DOI: 10.1021/Ja00133A041  0.43
1995 Mandimutsira BS, Chen S-, Demadis KD, Coucouvanis D. Synthesis and Structural Characterization of the [Nb(O)(S2)2SH]2-, [Nb(S)3SH]2-, and {[Nb(S)3]2O}4- anions. New elementary Thio- and Oxothioniobates Inorganic Chemistry. 34: 2267-2268. DOI: 10.1021/Ic00113A003  0.315
1995 Coucouvanis D, Demadis KD, Laughlin LJ, Malinak SM, Mosier PE. The use of MFe3S4 clusters (M = Mo, V) and derivatives in the reduction of nitrogenase substrates Journal of Inorganic Biochemistry. 59: 726. DOI: 10.1016/0162-0134(95)97813-6  0.402
1994 Coucouvanis D, Hadjikyriacou A, Lester R, Kanatzidis MG. Zirconium-Sulfur Chemistry. Synthesis and Structural Characterization of the Zr3S3(tBuS)2(BH4)4(THF)2, Zr6S6(tBuS)4(BH4)8(THF)2, Zr3(S)(tBuS)10, and (Mg(THF)6)[Zr2(SPh)7.2(CH2Ph)1.8]2.cntdot.3THF Clusters. Activation and Cleavage of the C-S bond in Zirconium-Coordinated Alkanethiolate Ligands Inorganic Chemistry. 33: 3645-3655. DOI: 10.1021/Ic00095A006  0.476
1994 Demadis KD, Chen S, Coucouvanis D. The synthesis, and properties of Fe/Mo/S clusters with MoFe3S4 cubane subunits, Mo bound bidentate oxalate ligands and terminal or bridging cyanide ligands. Structural characterization of (Et4N)3[(C2O4)(CN)MoFe3S4Cl3] and (Et4N)5{[C2O4)MoFe3S4Cl2]2(μ-CN)(μ-S)} Polyhedron. 13: 3147-3151. DOI: 10.1016/S0277-5387(00)83684-0  0.461
1991 Papaefthymiou V, Kostikas A, Simopoulos A, Al-Ahmad S, Coucouvanis D. Magnetic properties of [(CO)3MoFe3S4(SR)3]3− (R=Bz,Et,Ph), a synthetic cubane-type cluster simulating three-iron centers in proteins. Journal of Inorganic Biochemistry. 43: 279. DOI: 10.1016/0162-0134(91)84269-F  0.357
1990 Koo SM, Bergero R, Salifoglou A, Coucouvanis D. First examples of six-coordinate niobium and tantalum homoleptic complexes with monodentate arenethiolate ligands. Synthesis and structural characterization of [Ph4P]2[Nb(SPh)6], Na(THF)3Nb(SPh-pMe)6. [(15-crown-5)Na][Ta(SPh)6], and Nb2(.mu.2-SPh)4(SPh)4(SPh)2Cl2(C2H5CN)2 Inorganic Chemistry. 29: 4844-4846. DOI: 10.1021/Ic00349A002  0.375
1990 Al-Ahmad SA, Salifoglou A, Kanatzidis MG, Dunham WR, Coucouvanis D. Octanuclear Heterometallic Clusters with Rhombic Dodecahedral Cores. The Synthesis, Structural Characterization, and Properties of the {Fe 6 S 6 (p-RPhO) 6 [M(CO) 3 ] 2 } n− Clusters (M = Mo, n = 3, R = Me, OMe, NMe 2 ; M = W, n = 3, R = Me; M = Mo, n = 4, R = Me, OMe, COMe). Precursors for Synthetic Analogues for the Fe/Mo/S Site in Nitrogenase Inorganic Chemistry. 29: 927-938. DOI: 10.1021/Ic00330A007  0.457
1989 Coucouvanis D, Challen PR, Koo SM, Davis WM, Butler W, Dunham WR. Stepwise synthesis and structural characterization of the molybdenum-iron-sulfur {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)2}6- and {[MoFe3S4Cl2(Cl4cat)]2(.mu.2-S)(.mu.2-OH}5- doubly bridged double cubanes obtained by the coupling of [MoFe3S4] clusters Inorganic Chemistry. 28: 4181-4183. DOI: 10.1021/Ic00322A001  0.471
1989 Coucouvanis D, Swenson D, Baenziger NC, Pedelty R, Caffery ML, Kanodia S. Protonation of the 1,1-dithiolene ligands in the [Cu8(L)6]4- cubanes (L = [S2C:C(COOR)2]2-) and synthesis of the [Cu8(L)6-n(H-L)n]-(4-n) clusters. Synthesis and structural characterization of the [Cu10(H-L)6(L)2] decanuclear cluster Inorganic Chemistry. 28: 2829-2836. DOI: 10.1021/Ic00313A028  0.344
1989 Coucouvanis D, Toupadakis A, Koo S, Hadjikyriacou A. An inorganic functional group approach to the systematic synthesis and reactivity studies of binuclear Mo/S and Mo/S/O complexes Polyhedron. 8: 1705-1716. DOI: 10.1016/S0277-5387(00)80621-X  0.393
1989 Coucouvanis D, Challen PR, Koo S, Ahmad SA, Dunham WR. Sulfido bridged Fe/S and Fe/Mo/S clusters. A new proposed model for the Fe/Mo/S center in nitrogenase Journal of Inorganic Biochemistry. 36: 205. DOI: 10.1016/0162-0134(89)84171-6  0.493
1988 Coucouvanis D, Salifoglou A, Kanatzidis MG, Dunham WR, Simopoulos A, Kostikas A. Synthesis, Structural Characterization, and Electronic Properties of the [Fe6S6X6(M(CO)3)2]n-Anions (M = Mo, W; n = 3, 4; X = Cl, Br, I). Heteronuclear Clusters of Possible Structural Relevance to the Fe/Mo/S Center in Nitrogenase Inorganic Chemistry. 27: 4066-4077. DOI: 10.1021/Ic00295A034  0.587
1988 Salifoglou A, Simopoulos A, Kostikas A, Dunham RW, Kanatzidis MG, Coucouvanis D. Dimeric complexes containing the disulfidodiron(2+) cores coordinated by non-sulfur terminal ligands. Synthesis, structural characterization, and spectroscopic properties of [Et4N]2[Fe2S2(o,o'-C12H8O2)2], [Et4N]2[Fe2S2(C4H4N)4], and [Et4N]2[Fe2S2(O-o-C6H4CH(n-C4H9)NHC6H4-o-S)2] and the structure of [Ph4P]2[Fe2S2(OC6H4-p-CH3)4] Inorganic Chemistry. 27: 3394-3406. DOI: 10.1021/Ic00292A026  0.464
1988 Coucouvanis D, Toupadakis A, Hadjikyriacou A. Synthesis of thiomolybdenyl complexes with [Mo2(S)2(O)2]2+ cores and substitutionally labile ligands. Crystal and molecular structure of the tris(dimethylformamide)dioxotetrasulfidodimolybdenum complex Inorganic Chemistry. 27: 3272-3273. DOI: 10.1021/Ic00292A005  0.348
1988 Coucouvanis D, Al-Ahmad S, Salifoglou A, Dunham WR, Sands RH. A New Cubane Cluster with the[MoFe3S4]0 Core and Possible Relevance to the Fe3-Centers in Ferredoxins. The Synthesis, Structure and Properties of the[Fe3S4(SEt)3Mo(CO)3]3⊖ Anion Angewandte Chemie International Edition in English. 27: 1353-1355. DOI: 10.1002/Anie.198813531  0.53
1988 Coucouvanis D, Al-Ahmad S, Salifoglou A, Dunham WR, Sands RH. Ein Cubancluster mit dem [MoFe3S4]0-Gerüst und seine mögliche Relevanz im Hinblick auf die Fe3-Zentren in Ferredoxinen: das [Fe3S4(SEt)3Mo(CO)3]3⊖-Ion Angewandte Chemie. 100: 1404-1406. DOI: 10.1002/Ange.19881001022  0.351
1987 Coucouvanis D, Kanatzidis MG, Salifoglou A, Dunham WR, Simopoulos A, Sams JR, Papaefthymiou V, Kostikas A, Strouse CE. Spectroscopic and structural evidence of temperature dependent charge localization and structural differentiation of the iron sites within the [Fe6S6X6]2- clusters (X = chloro, bromo) Journal of the American Chemical Society. 109: 6863-6865. DOI: 10.1021/Ja00256A057  0.406
1987 Coucouvanis D, Salifoglou A, Kanatzidis MG, Simopoulos A, Kostikas A. Synthesis, structural characterization and electronic structures of the [Fe6S6(X)6(Mo(CO)3)2]3- clusters (X = Cl, Br) Journal of the American Chemical Society. 109: 3807-3808. DOI: 10.1021/Ja00246A063  0.527
1986 Salifoglou A, Kanatzidis MG, Coucouvanis D. The synthesis and structural characterization of [Et4N]3[Fe6S6(p-MeC6H4O)6{W(CO)3}2]. A hetero-polynuclear aggregate that contains the [W2Fe6S6]3+ core Journal of the Chemical Society, Chemical Communications. 559-561. DOI: 10.1039/C39860000559  0.409
1986 Kanatzidis MG, Coucouvanis D. New [Fe6S6Cl6(Mo(CO)3)2]n- (n = 3, 4) clusters. Derivatives of either [Fe6S6Cl6]3- or [Fe4S4Cl4]2- with possible relevance to the iron-molybdenum-sulfide center in nitrogenase Journal of the American Chemical Society. 108: 337-338. DOI: 10.1021/Ja00262A048  0.42
1986 Kanatzidis MG, Salifoglou A, Coucouvanis D. Chemistry of [Fe6S6]3+ prismatic cages. Synthesis, structural characterization, and electronic structures of the [Et4N]3[Fe6S6L6] clusters (L=p-CH3C6H4O−, Br−) Inorganic Chemistry. 25: 2460-2468. DOI: 10.1021/Ic00234A036  0.526
1986 Coucouvanis D, Hadjikyriacou A, Draganjac M, Kanatzidis MG, Ileperuma O. Unique reactivity characteristics of Mo-coordinated S2−2 and S2−4 ligands Polyhedron. 5: 349-356. DOI: 10.1016/S0277-5387(00)84932-3  0.382
1986 Papaefthymiou V, Simopoulos A, Kostikas A, Coucouvanis D. Determination of fine and hyperfine structure in Fe-Mo(W) dinuclear clusters Hyperfine Interactions. 30: 337-353. DOI: 10.1007/Bf02394329  0.399
1986 Kanatzidis MG, Salifoglou A, Coucouvanis D. Chemistry of (Fe6S6)3+Prismatic Cages. Synthesis, Structural Characterization, and Electronic Structures of the (Et4N)3(Fe6S6L6) Clusters (L: p-CH3C6H4O-, Br-). Cheminform. 17. DOI: 10.1002/Chin.198647312  0.53
1986 Coucouvanis D, Lester RK, Kanatzidis MG, Kessissoglou DP. First Examples of Polynuclear, Sulfur-Containing, Zirconium Compounds. Cheminform. 17. DOI: 10.1002/Chin.198616275  0.371
1985 Coucouvanis D, Hadjikyriacou A, Kanatzidis MG. The synthesis and structural characterization of Zr3(S)(ButS)10. A Zr–S cluster that contains thiolate ligands in three different modes of co-ordination Journal of the Chemical Society, Chemical Communications. 1224-1225. DOI: 10.1039/C39850001224  0.5
1985 Coucouvanis D, Lester RK, Kanatzidis MG, Kessisoglou D. First examples of polynuclear, sulfur-containing, zirconium compounds. Synthesis and structural characterization of the trinuclear Zr3S3(S-tert-Bu)2(BH4)4(THF)2 and the hexanuclear Zr6S6(S-tert-Bu)4(BH4)8(THF)2 clusters Journal of the American Chemical Society. 107: 8279-8280. DOI: 10.1021/Ja00312A087  0.478
1985 Coucouvanis D, Kanatzidis MG. Synthesis and characterization of a new Fe/Mo/S cluster containing the [Fe6Mo2S6]3+ core. A precursor to a possible structural analogue for the Fe/Mo site of nitrogenase Journal of the American Chemical Society. 107: 5005-5006. DOI: 10.1021/Ja00303A036  0.537
1985 Kanatzidis MG, Coucouvanis D, Simopoulos A, Kostikas A, Papaefthymiou V. Synthesis, Structural Characterization, and Electronic Properties of the Ph4P+ Salts of the Mixed Terminal Ligand Cubanes Fe4S4(Et2Dtc)n(X)4-n 2-(X = Cl-, PhS-) (n = 1, 2). Two Different Modes of Ligation on the [Fe4S4]2+ Core Journal of the American Chemical Society. 107: 4925-4935. DOI: 10.1021/Ja00303A018  0.448
1985 Kanatzidis MG, Salifoglou A, Coucouvanis D. A new Fe/S cluster with the (Fe6S6)3+ prismatic core and p-methylphenolate terminal ligands: the synthesis, structure, and properties of (Et4N)3Fe6S6(OC6H4-p-CH3)6 Journal of the American Chemical Society. 107: 3358-3360. DOI: 10.1021/Ja00297A058  0.439
1985 Kanatzidis MG, Baenziger NC, Coucouvanis D. Crystal and molecular structures of the copper(II) and copper(III) dithiooxalate complexes (18-crown-6)2K2Cu(S2C2O2)2 and ([C6H5)3P]2N)Cu(S2C2O2)2 Inorganic Chemistry. 24: 2680-2683. DOI: 10.1021/Ic00211A019  0.42
1985 Coucouvanis D, Patil PR, Kanatzidis MG, Detering B, Baenziger NC. Synthesis and reactions of binary metal sulfides. Structural characterization of the [(S4)2Zn]2-, [(S4)2Ni]2-, [(S5)Mn(S6)]2-, and [(CS4)2Ni]2- anions Inorganic Chemistry. 24: 24-31. DOI: 10.1021/Ic00195A007  0.48
1985 Kanatzidis MG, Baenziger NC, Coucouvanis D. Crystal And Molecular Structures Of The Copper(Ii) And Copper(Iii) Dithiooxalate Complexes (18-Crown-6)2K2Cu(S2C2O2)2 And ((C6H5)3P)2N)Cu(S2C2O2)2 Cheminform. 16. DOI: 10.1002/Chin.198549047  0.435
1985 Kanatzidis MG, Salifoglou A, Coucouvanis D. A New Iron/Sulfur Cluster With The (Fe6S6)3+ Prismatic Core And P-Methylphenolate Terminal Ligands. The Synthesis, Structure, And Properties Of (Et4N)3Fe6S6(Oc6H4-P-Ch3)6 Cheminform. 16. DOI: 10.1002/Chin.198538290  0.531
1985 Kanatzidis MG, Hagen WR, Dunham WR, Lester RK, Coucouvanis D. Metastable Iron/Sulfur Clusters. The Synthesis, Electronic Structure, And Transformations Of The (Fe6S6(L)6)3- Clusters (L = Cl-, Br, I-, Rs-, Ro-) And The Structure Of ((C2H5)4N)3(Fe6S6Cl6) Cheminform. 16. DOI: 10.1002/Chin.198527308  0.55
1985 Coucouvanis D, Patil PR, Kanatzidis MG, Detering B, Baenziger NC. Synthesis And Reactions Of Binary Metal Sulfides. Structural Characterization Of The ((S4)2Zn)2-, ((S4)2Ni)2-, ((S5)Mn(S6))2-, And ((Cs4)2Ni)2- Anions Cheminform. 16. DOI: 10.1002/Chin.198525317  0.48
1984 Kanatzidis MG, Dunham WR, Hagen WR, Coucouvanis D. A new iron–sulphide cluster containing the ‘prismane’[Fe6(µ-S)6]3+ core. Synthesis, structure, and properties of [Et4N]3[Fe6S6Cl6] Journal of the Chemical Society, Chemical Communications. 356-358. DOI: 10.1039/C39840000356  0.528
1984 Coucouvanis D, Kanatzidis MG, Dunham WR, Hagen WR. Oxidative transformation of the iron-sulfur [Fe4S4X4]2- "cubanes" to the [Fe6S6X6]2- "prismane" clusters (X = chlorine, bromine). The crystal and molecular structure of [(C6H5)4P]2Fe6S6Cl6 Journal of the American Chemical Society. 106: 7998-7999. DOI: 10.1021/Ja00337A073  0.505
1984 Coucouvanis D, Salifoglou A, Kanatzidis MG, Simopoulos A, Papaefthymiou V. Dimeric complexes containing the disulfidodiiron(2+) cores coordinated by non-sulfur containing terminal ligands. The crystal and molecular structures of the tetraethylammonium salts of the [Fe2S2(o,o'-C12H8O2)2]2- and [Fe2S2(C4H4N)4]2- anions Journal of the American Chemical Society. 106: 6081-6082. DOI: 10.1021/Ja00332A056  0.327
1984 Kanatzidis MG, Baenziger NC, Coucouvanis D, Simopoulos A, Kostikas A. Synthesis, structural characterization, and electronic structures of the mixed terminal ligand iron-sulfur cubanes [Fe4S4Cl2(XPh)2]2- (X = S, O) and [Fe4S4(SPh)2(OC6H4Me-p)2]2-. The first examples of [Fe4S4]2+ cores with a noncompressed D2d idealized geometry Journal of the American Chemical Society. 106: 4500-4511. DOI: 10.1021/Ja00328A033  0.534
1984 Kanatzidis MG, Coucouvanis D. Addition of activated acetylenes to coordinated polysulfide ligands. 2. Synthesis of the Fe2[S2C2(COOCH3)2]42- dithiolene complex by the addition of CH3OOCC.tplbond.CCOOCH3 to the (Fe2S12)2- anion. The crystal and molecular structure of (Ph4P)2Fe2[S2C2(COOCH3)2]4 Inorganic Chemistry. 23: 403-409. DOI: 10.1021/Ic00172A005  0.506
1983 Teo BK, Antonio MR, Coucouvanis D, Simhon ED, Stremple PP. EXAFS model for the iron-molybdenum cofactor of nitrogenase: molybdenum, tungsten, and iron EXAFS of the [Cl2FeS2MS2FeCl2]2- (M = molybdenum or tungsten) dianions. A comparison with the Mo EXAFS of nitrogenase Journal of the American Chemical Society. 105: 5767-5770. DOI: 10.1021/Ja00356A011  0.308
1983 Kanatzidis MG, Baenziger NC, Coucouvanis D. Crystal structure determination of bis(tetraphenylphosphonium) heptasulfide, (Ph4P)2S7 Inorganic Chemistry. 22: 290-292. DOI: 10.1021/Ic00144A019  0.429
1983 Teo BK, Antonio MR, Coucouvanis D, Simhon ED, Stremple PP. Exafs Model For The Iron‐Molybdenum Cofactor Of Nitrogenase: Molybdenum, Tungsten, And Iron Exafs Of The (Cl2Fes2Ms2Fecl2)2‐ (M = Molybdenum Or Tungsten) Dianions. A Comparison With The Mo Exafs Of Nitrogenase Cheminform. 14. DOI: 10.1002/Chin.198349039  0.314
1983 Kanatzidis MG, Baenziger NC, Coucouvanis D. Crystal Structure Determination Of Bis(Tetraphenylphosphonium) Heptasulfide, (Ph4P)2S7 Cheminform. 14. DOI: 10.1002/Chin.198317071  0.429
1982 Balasubramaniam A, Coucouvanis D. Fe-Mo complexes of cysteinyl peptides Inorganica Chimica Acta. 66. DOI: 10.1016/S0020-1693(00)85777-1  0.361
1981 Stremple P, Baenziger NC, Coucouvanis D. Coordination unsaturation in the iron tetrahiometalate complexes. Synthesis and structural characterization of the [Fe(WS4)2(HCON(CH3)2)2]2- complex anion Journal of the American Chemical Society. 103: 4601-4603. DOI: 10.1021/Ja00405A061  0.423
1981 Coucouvanis D, Swenson D, Baenziger NC, Murphy C, Holah DG, Sfarnas N, Simopoulos A, Kostikas A. Tetrahedral complexes containing the Fe(II)S4 core. The syntheses, ground-state electronic structures and crystal and molecular structures of the bis(tetraphenylphosphonium) tetrakis (thiophenolato)ferrate (II) and bis (tetrapheny lphosphonium) bis(dithiosquarato)ferrate (II) complexes. An analog for the active site in reducd rubredoxins (Rdred) Journal of the American Chemical Society. 103: 3350-3362. DOI: 10.1021/Ja00402A020  0.417
1981 Stremple P, Baenziger NC, Coucouvanis D. Coordination Unsaturation In The Iron Tetrahiometalate Complexes. Synthesis And Structural Characterization Of The (Fe(Ws4)2(Hcon(Ch3)2)2)2‐ Complex Anion Cheminform. 12. DOI: 10.1002/Chin.198143280  0.423
1981 Coucouvanis D, Swenson D, Baenziger NC, Murphy C, Holah DG, Sfarnas N, Simopoulos A, Kostikas A. Tetrahedral Complexes Containing The Fe(Ii)S4 Core. The Syntheses, Ground-State Electronic Structures And Crystal And Molecular Structures Of The Bis(Tetraphenylphosphonium) Tetrakis (Thiophenolato)Ferrate (Ii) And Bis (Tetrapheny Lphosphonium) Bis(Dithiosquarato)Ferrate (Ii) Complexes. An Analog For The Active Site In Reducd Rubredoxins (Rdred) Cheminform. 12. DOI: 10.1002/Chin.198138300  0.373
1980 Coucouvanis D, Baenziger NC, Simhon ED, Stremple P, Swenson D, Simopoulos A, Kostikas A, Petrouleas V, Papaefthymiou V. Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten). First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site Journal of the American Chemical Society. 102: 1732-1734. DOI: 10.1021/Ja00525A050  0.355
1980 Coucouvanis D, Baenziger NC, Simhon ED, Stremple P, Swenson D, Simopoulos A, Kostikas A, Petrouleas V, Papaefthymiou V. Synthesis and structural characterization of the (Ph4P)2[Cl2FeS2MS2FeCl2] complexes (M = molybdenum, tungsten). First example of a doubly bridging thiomolybdate (MoS4) unit and its possible relevance as a structural feature in the nitrogenase active site Cheminform. 11. DOI: 10.1002/Chin.198023293  0.355
1978 Swenson D, Baenziger NC, Coucouvanis D. Tetrahedral mercaptide complexes. Crystal and molecular structures of [(C6H5)4P]2M(SC6H5)4 complexes (M = cadmium(II), zinc(II), nickel(II), cobalt(II), and manganese(II)) Journal of the American Chemical Society. 100: 1932-1934. DOI: 10.1021/Ja00474A053  0.318
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