| Year |
Citation |
Score |
| 2019 |
Apeloig Y, Kratish Y, Pinchuk D, Kaushansky A, Molev V, Tumanskii B, Bravo-Zhivotovskii D. The Reactions of Carbon Monoxide with Silyl and Silenyl Lithium. Synthesis and Isolation of the First Stable Bis-Silyl Ketyl Radical and 1-Silaallenolate Lithium. Angewandte Chemie (International Ed. in English). PMID 31591792 DOI: 10.1002/Anie.201910336 |
0.399 |
|
| 2019 |
Zborovsky L, Kostenko A, Bravo-Zhivotovskii D, Apeloig Y. Mechanism of the Thermal Z⇌E Isomerization of a Stable Silene. Experiment and Theory. Angewandte Chemie (International Ed. in English). PMID 31342616 DOI: 10.1002/Anie.201907864 |
0.338 |
|
| 2019 |
Wang Y, Karni M, Yao S, Kaushansky A, Apeloig Y, Driess M. Synthesis of an Isolable Bis(silylene)-Stabilized Silylone and Its Reactivity Toward Small Gaseous Molecules. Journal of the American Chemical Society. PMID 31337219 DOI: 10.1021/Jacs.9B06603 |
0.403 |
|
| 2019 |
Pinchuk D, Kratish Y, Mathew J, Zborovsky L, Bravo-Zhivotovskii D, Tumanskii B, Apeloig Y. Generation and Electron Paramagnetic Spectroscopy of the First Silenyl Radicals (R2C=Si•-R). Experiment and Theory. Angewandte Chemie (International Ed. in English). PMID 30912602 DOI: 10.1002/Anie.201901772 |
0.324 |
|
| 2018 |
Wang Y, Karni M, Yao S, Apeloig Y, Driess M. An Isolable Bis(silylene)-Stabilized Germylone and Its Reactivity. Journal of the American Chemical Society. PMID 30500210 DOI: 10.1021/Jacs.8B11605 |
0.393 |
|
| 2018 |
Minkovich B, Ruderfer I, Kaushansky A, Bravo-Zhivotovskii D, Apeloig Y. α-Sila-Dipeptides: Synthesis and Characterization. Angewandte Chemie (International Ed. in English). PMID 30117620 DOI: 10.1002/Anie.201807027 |
0.301 |
|
| 2018 |
Kratish Y, Kostenko A, Kaushansky A, Tumanskii B, Bravo-Zhivotovskii D, Apeloig Y. Generation and Characterization of the First Persistent Platinum(I) Centered Radical. Angewandte Chemie (International Ed. in English). PMID 29763519 DOI: 10.1002/Anie.201805107 |
0.334 |
|
| 2017 |
Mashin E, Kratish Y, Kaushansky A, Bravo-Zhivotovskii D, Apeloig Y. Synthesis by Si-H bond lithiation of novel half-pincer and pincer silyllithium compounds and their molecular structures Structural Chemistry. 28: 537-544. DOI: 10.1007/S11224-017-0910-6 |
0.311 |
|
| 2016 |
Xiong Y, Yao S, Karni M, Kostenko A, Burchert A, Apeloig Y, Driess M. Heavier congeners of CO and CO as ligands: from zero-valent germanium ('germylone') to isolable monomeric GeX and GeX complexes (X = S, Se, Te). Chemical Science. 7: 5462-5469. PMID 30034685 DOI: 10.1039/C6Sc01839D |
0.376 |
|
| 2016 |
Zhou YP, Karni M, Yao S, Apeloig Y, Driess M. A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity. Angewandte Chemie (International Ed. in English). PMID 27804223 DOI: 10.1002/Anie.201609520 |
0.383 |
|
| 2016 |
Pinchuk D, Mathew J, Kaushansky A, Bravo-Zhivotovskii D, Apeloig Y. Isolation and Characterization, Including by X-ray Crystallography, of Contact and Solvent-Separated Ion Pairs of Silenyl Lithium Species. Angewandte Chemie (International Ed. in English). 55: 10258-10262. PMID 27466152 DOI: 10.1002/Anie.201603640 |
0.391 |
|
| 2015 |
Linden MM, Reisenauer HP, Gerbig D, Karni M, Schäfer A, Müller T, Apeloig Y, Schreiner PR. Preparation of a Silanone through Oxygen Atom Transfer to a Stable Cyclic Silylene. Angewandte Chemie (International Ed. in English). PMID 26315924 DOI: 10.1002/Anie.201501844 |
0.499 |
|
| 2015 |
Kostenko A, Tumanskii B, Karni M, Inoue S, Ichinohe M, Sekiguchi A, Apeloig Y. Observation of a Thermally Accessible Triplet State Resulting from Rotation around a Main-Group π Bond. Angewandte Chemie (International Ed. in English). PMID 26297814 DOI: 10.1002/Anie.201506291 |
0.341 |
|
| 2015 |
Kratish Y, Molev G, Kostenko A, Sheberla D, Tumanskii B, Botoshansky M, Shimada S, Bravo-Zhivotovskii D, Apeloig Y. Activation of Homolytic SiZn and SiHg Bond Cleavage, Mediated by a Pt(0) Complex, via Novel PtZn and PtHg Compounds. Angewandte Chemie (International Ed. in English). 54: 11817-21. PMID 26288342 DOI: 10.1002/Anie.201505805 |
0.742 |
|
| 2015 |
Klatt T, Werner V, Maximova MG, Didier D, Apeloig Y, Knochel P. Preparation and Regioselective Magnesiation or Lithiation of Bis(trimethylsilyl)methyl-Substituted Heteroaryls for the Generation of Highly Functionalized Heterocycles. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 7830-4. PMID 25864885 DOI: 10.1002/Chem.201500627 |
0.333 |
|
| 2014 |
Smirnov P, Katan E, Mathew J, Kostenko A, Karni M, Nijs A, Bolm C, Apeloig Y, Marek I. Formation of three new bonds and two stereocenters in acyclic systems by zinc-mediated enantioselective alkynylation of acylsilanes, Brook rearrangement, and ene-allene carbocyclization reactions. The Journal of Organic Chemistry. 79: 12122-35. PMID 25271364 DOI: 10.1021/Jo501977R |
0.351 |
|
| 2014 |
Werner V, Klatt T, Fujii M, Markiewicz J, Apeloig Y, Knochel P. Preparation and regioselective metalation of bis(trimethylsilyl)methyl-substituted aryl derivatives. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 8338-42. PMID 24890675 DOI: 10.1002/Chem.201402531 |
0.315 |
|
| 2013 |
Smirnov P, Mathew J, Nijs A, Katan E, Karni M, Bolm C, Apeloig Y, Marek I. One-pot zinc-promoted asymmetric alkynylation/brook-type rearrangement/ene-allene cyclization: highly selective formation of three new bonds and two stereocenters in acyclic systems. Angewandte Chemie (International Ed. in English). 52: 13717-21. PMID 24155160 DOI: 10.1002/Anie.201306749 |
0.335 |
|
| 2013 |
Kosa M, Karni M, Apeloig Y. Were reactions of triplet silylenes observed? Journal of the American Chemical Society. 135: 9032-40. PMID 23687959 DOI: 10.1021/Ja403068R |
0.396 |
|
| 2013 |
Dietl N, Troiani A, Schlangen M, Ursini O, Angelini G, Apeloig Y, de Petris G, Schwarz H. Mechanistic aspects of gas-phase hydrogen-atom transfer from methane to [CO](·+) and [SiO](·+) : why do they differ? Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 6662-9. PMID 23536523 DOI: 10.1002/Chem.201204157 |
0.325 |
|
| 2012 |
Zborovsky L, Dobrovetsky R, Botoshansky M, Bravo-Zhivotovskii D, Apeloig Y. Synthesis of silenyllithiums Li(R'3Si)Si═C(SiR3)(1-Ad) via transient silyne-silylidene intermediates. Journal of the American Chemical Society. 134: 18229-32. PMID 23088441 DOI: 10.1021/Ja308777V |
0.313 |
|
| 2012 |
Dobrovetsky R, Kratish Y, Tumanskii B, Botoshansky M, Bravo-Zhivotovskii D, Apeloig Y. Radical activation of Si-H bonds by organozinc and silylzinc reagents: synthesis of geminal dizinciosilanes and zinciolithiosilanes. Angewandte Chemie (International Ed. in English). 51: 4671-5. PMID 22473880 DOI: 10.1002/Anie.201200126 |
0.402 |
|
| 2012 |
Karni M, Apeloig Y. Conjugation, Resonance, and Stability in N-Heterocyclic Silylenes and in Phosphorus Ylide Substituted Silylenes Organometallics. 31: 2403-2415. DOI: 10.1021/Om300031X |
0.372 |
|
| 2012 |
Kostenko A, Müller B, Kaufmann F, Apeloig Y, Siehl H. The 1-Phenyl-1-(trimethylsilyl)ethyl Cation: An NMR Spectroscopic and Computational Study of the α-Silyl Effect in Benzyl Cations European Journal of Organic Chemistry. 2012: 1730-1736. DOI: 10.1002/Ejoc.201101741 |
0.369 |
|
| 2011 |
Apeloig Y. Chemistry. The diamond within a silicon analog of cyclobutadiene. Science (New York, N.Y.). 331: 1277-8. PMID 21393535 DOI: 10.1126/Science.1202157 |
0.38 |
|
| 2010 |
Dobrovetsky R, Bravo-Zhivotovskii D, Tumanskii B, Botoshansky M, Apeloig Y. Synthesis, isolation, and characterization of 1,1-diGrignard and 1,1-dizincio silanes. Angewandte Chemie (International Ed. in English). 49: 7086-8. PMID 20737525 DOI: 10.1002/Anie.201002876 |
0.359 |
|
| 2010 |
Dobrovetsky R, Zborovsky L, Sheberla D, Botoshansky M, Bravo-Zhivotovskii D, Apeloig Y. Isolation of silenolates (R3Si)2Si=C(OLi)Ad with a doubly bonded silicon atom. Angewandte Chemie (International Ed. in English). 49: 4084-7. PMID 20437438 DOI: 10.1002/Anie.201001024 |
0.768 |
|
| 2010 |
Epping JD, Yao S, Karni M, Apeloig Y, Driess M. Si=X multiple bonding with four-coordinate silicon? Insights into the nature of the Si=O and Si=S double bonds in stable silanoic esters and related thioesters: a combined NMR spectroscopic and computational study. Journal of the American Chemical Society. 132: 5443-55. PMID 20349991 DOI: 10.1021/Ja1004812 |
0.355 |
|
| 2010 |
Sheberla D, Tumanskii B, Tomasik AC, Mitra A, Hill NJ, West R, Apeloig Y. Different electronic structure of phosphonyl radical adducts of N-heterocyclic carbenes, silylenes and germylenes: EPR spectroscopic study and DFT calculations Chemical Science. 1: 234-241. DOI: 10.1039/C0Sc00143K |
0.767 |
|
| 2010 |
Sheberla D, Tumanskii B, Bravo-Zhivotovskii D, Molev G, Molev V, Lee VY, Takanashi K, Sekiguchi A, Apeloig Y. Electronic Structure of Bis(silyl)carbon-, Bis(silyl)silicon-, and Bis(silyl)germanium-Centered Radicals (R3Si)2XE•(E = C, Si, Ge; X = H, Re(CO)5, F): EPR and DFT Studies† Organometallics. 29: 5596-5606. DOI: 10.1021/Om100812B |
0.76 |
|
| 2010 |
SKLENAK S, APELOIG Y, RAPPOPORT Z. ChemInform Abstract: Calculated pKEnol Values for Enols of Carboxylic Acid Derivatives HC=C(OH)X (X: OH, NH2, NMe2, OMe, OCHO, F, Cl, Br). Cheminform. 30: no-no. DOI: 10.1002/CHIN.199909032 |
0.45 |
|
| 2010 |
BRAVO-ZHIVOTOVSKII D, BRAUDE V, STANGER A, KAPON M, APELOIG Y. ChemInform Abstract: Novel Route to C=Si Double Bonds via a Peterson-Type Reaction. Cheminform. 23: no-no. DOI: 10.1002/CHIN.199243199 |
0.621 |
|
| 2009 |
Molev G, Tumanskii B, Sheberla D, Botoshansky M, Bravo-Zhivotovskii D, Apeloig Y. Isolable photoreactive polysilyl radicals. Journal of the American Chemical Society. 131: 11698-700. PMID 19722593 DOI: 10.1021/Ja905097B |
0.763 |
|
| 2009 |
Bravo-Zhivotovskii D, Melamed S, Molev V, Sigal N, Tumanskii B, Botoshansky M, Molev G, Apeloig Y. Radical polymerization of the silene (Me3Si)2Si=CR2 by hydrogen transfer from a trimethylsilyl group. Angewandte Chemie (International Ed. in English). 48: 1834-7. PMID 19185047 DOI: 10.1002/Anie.200805840 |
0.323 |
|
| 2009 |
Karni M, Apeloig Y, Kapp J, Schleyer PvR. Theoretical Aspects of Compounds Containing Si, Ge, Sn and Pb Patai's Chemistry of Functional Groups. 1-163. DOI: 10.1002/9780470682531.Pat0235 |
0.34 |
|
| 2008 |
Xi HW, Karni M, Apeloig Y. Silabutadienes. Internal rotations and pi-conjugation. A density functional theory study. The Journal of Physical Chemistry. A. 112: 13066-79. PMID 18850695 DOI: 10.1021/Jp803837H |
0.371 |
|
| 2008 |
Bravo-Zhivotovskii D, Dobrovetsky R, Nemirovsky D, Molev V, Bendikov M, Molev G, Botoshansky M, Apeloig Y. The synthesis and isolation of a metal-substituted bis-silene. Angewandte Chemie (International Ed. in English). 47: 4343-5. PMID 18446914 DOI: 10.1002/Anie.200800973 |
0.583 |
|
| 2007 |
Tumanskii B, Sheberla D, Molev G, Apeloig Y. Dual character of arduengo carbene-radical adducts: addition versus coordination product. Angewandte Chemie (International Ed. in English). 46: 7408-11. PMID 17722140 DOI: 10.1002/Anie.200702297 |
0.75 |
|
| 2007 |
Kosa M, Karni aM, Apeloig Y. Theoretical Study of Ladder Polysilanes Organometallics. 26: 2806-2814. DOI: 10.1021/Om0610344 |
0.323 |
|
| 2006 |
Kosa M, Karni M, Apeloig Y. Trisilaallene and the Relative Stability of Si3H4 Isomers. Journal of Chemical Theory and Computation. 2: 956-64. PMID 26633055 DOI: 10.1021/Ct050154A |
0.372 |
|
| 2006 |
Kravchenko V, Kinjo R, Sekiguchi A, Ichinohe M, West R, Balazs YS, Schmidt A, Karni M, Apeloig Y. Solid-state (29)Si NMR study of RSiSiR: a tool for analyzing the nature of the Si-Si bond. Journal of the American Chemical Society. 128: 14472-3. PMID 17090026 DOI: 10.1021/Ja065817S |
0.346 |
|
| 2006 |
Dilman AD, Levin VV, Karni M, Apeloig Y. Activation of pentafluorophenylsilanes by weak Lewis bases in reaction with iminium cations. The Journal of Organic Chemistry. 71: 7214-23. PMID 16958514 DOI: 10.1021/Jo0606812 |
0.382 |
|
| 2006 |
Lee VY, Fukawa T, Nakamoto M, Sekiguchi A, Tumanskii BL, Karni M, Apeloig Y. (tBu2MeSi)2Sn=Sn(SiMetBu2)2: a distannene with a >Sn=Sn< double bond that is stable both in the solid state and in solution. Journal of the American Chemical Society. 128: 11643-51. PMID 16939290 DOI: 10.1021/Ja063322X |
0.378 |
|
| 2006 |
Leigh WJ, Owens TR, Bendikov M, Zade SS, Apeloig Y. A combined experimental and theoretical study of the kinetics and mechanism of the addition of alcohols to electronically stabilized silenes: a new mechanism for the addition of alcohols to the Si=C bond. Journal of the American Chemical Society. 128: 10772-83. PMID 16910672 DOI: 10.1021/Ja0613557 |
0.756 |
|
| 2006 |
Molev G, Bravo-Zhivotovskii D, Karni M, Tumanskii B, Botoshansky M, Apeloig Y. Synthesis, molecular structure, and reactivity of the isolable silylenoid with a tricoordinate silicon. Journal of the American Chemical Society. 128: 2784-5. PMID 16506741 DOI: 10.1021/Ja0575880 |
0.35 |
|
| 2005 |
Tumanskii B, Pine P, Apeloig Y, Hill NJ, West R. Radical reactions of a stable N-heterocyclic germylene: EPR study and DFT calculation. Journal of the American Chemical Society. 127: 8248-9. PMID 15941234 DOI: 10.1021/Ja051169L |
0.391 |
|
| 2005 |
and MK, Apeloig Y, and NT, Nagase S. Ab Initio and DFT Study of the 29Si NMR Chemical Shifts in RSi⋮SiR Organometallics. 24: 6319-6330. DOI: 10.1021/Om058033G |
0.368 |
|
| 2005 |
Bravo-Zhivotovskii D, Ruderfer I, Yuzefovich M, Kosa M, Botoshansky M, Tumanskii B, Apeloig Y. Mercury-Substituted Silyl Radical Intermediates in Formation and Fragmentation of Geminal Dimercury Silyl Compounds† Organometallics. 24: 2698-2704. DOI: 10.1021/Om050118U |
0.353 |
|
| 2004 |
Bendikov M, Kravchenko V, Apeloig Y, Becker JY. The first electrochemical study of a silene. An unusually low oxidation potential, comparable to those of strong organic π-electron donors Organometallics. 23: 921-923. DOI: 10.1021/Om0341909 |
0.619 |
|
| 2004 |
Danovich D, Ogliaro F, Karni M, Apeloig Y, Cooper DL, Shaik S. Silynes (RC≡SiR′) and Disilynes (RSi≡SiR′): Why Are Less Bonds Worth Energetically More? Angewandte Chemie. 116: 143-143. DOI: 10.1002/1521-3757(20011105)113:21<4146::Aid-Ange4146>3.0.Co;2-N |
0.338 |
|
| 2003 |
Ari JB, Karni M, Apeloig Y, Mandelbaum A. The role of hydride migration in the mechanism of alcohol elimination from protonated ethers upon chemical ionization International Journal of Mass Spectrometry. 228: 297-306. DOI: 10.1016/S1387-3806(03)00200-8 |
0.362 |
|
| 2003 |
Bravo-Zhivotovskii D, Korogodsky G, Apeloig Y. Synthesis of the first long-lived bis-silene Journal of Organometallic Chemistry. 686: 58-65. DOI: 10.1016/S0022-328X(03)00549-7 |
0.358 |
|
| 2003 |
Azinović D, Bravo-Zhivotovskii D, Bendikov M, Apeloig Y, Tumanskii B, Vepřek S. Spectroscopic studies of the role of silyl radicals in photolysis of polysilanes Chemical Physics Letters. 374: 257-263. DOI: 10.1016/S0009-2614(03)00717-6 |
0.636 |
|
| 2003 |
Kozhushkov S, Späth T, Kosa M, Apeloig Y, Yufit D, de Meijere A. Relative Stabilities of Spirocyclopropanated Cyclopropyl Cations European Journal of Organic Chemistry. 2003: 4234-4242. DOI: 10.1002/Ejoc.200300440 |
0.334 |
|
| 2002 |
Kozhushkov S, Späth T, Fiebig T, Galland B, Ruasse MF, Xavier P, Apeloig Y, de Meijere A. Reactivities of methylenetriangulanes and spirocyclopropanated bicyclopropylidenes toward bromine. Relative stabilities of spirocyclopropanated versus methyl-substituted bromonium ions. The Journal of Organic Chemistry. 67: 4100-14. PMID 12054944 DOI: 10.1021/Jo0162686 |
0.363 |
|
| 2002 |
Müller T, Apeloig Y. Possible strategies toward the elusive tetraaminodisilene. Journal of the American Chemical Society. 124: 3457-60. PMID 11916431 DOI: 10.1021/Ja011956S |
0.378 |
|
| 2002 |
Karni M, Apeloig Y. The quest for a stable silyne, RSi≡CR . The effect of bulky substituents (1) Silicon Chemistry. 1: 59-65. DOI: 10.1023/A:1016091614005 |
0.358 |
|
| 2002 |
Sigal N, Apeloig Y. Theoretical study of heavier group 14 analogues of allene Organometallics. 21: 5486-5493. DOI: 10.1021/Om020304P |
0.32 |
|
| 2002 |
Bendikov M, Quadt SR, Rabin O, Apeloig Y. Addition of nucleophiles to silenes. A theoretical study of the effect of substituents on their kinetic stability Organometallics. 21: 3930-3939. DOI: 10.1021/Om0202571 |
0.638 |
|
| 2002 |
Cypryk M, Apeloig Y. Mechanism of the acid-catalyzed Si-O bond cleavage in siloxanes and siloxanols. A theoretical study Organometallics. 21: 2165-2175. DOI: 10.1021/Om011055S |
0.367 |
|
| 2002 |
Bendikov M, Solouki B, Auner N, Apeloig Y. Ionization potentials of silenes (R′2Si=CR2). Experiment and theory Organometallics. 21: 1349-1354. DOI: 10.1021/Om0108292 |
0.639 |
|
| 2002 |
Korogodsky G, Bendikov M, Bravo-Zhivotovskii D, Apeloig Y. Determination of the solution acidity of tris(trimethylsilyl) silane Organometallics. 21: 3157-3161. DOI: 10.1021/Om010821S |
0.584 |
|
| 2002 |
Bravo-Zhivotovskii D, Melamed S, Kapon M, Apeloig Y. Thermal Transformation of a 1,2-Disilacyclobutane to a Trisilacyclobutane† Organometallics. 21: 2049-2054. DOI: 10.1021/Om0107690 |
0.344 |
|
| 2002 |
Bendikov M, Apeloig Y, Bukalov S, Garbuzova I, Leites L. The Raman, ultraviolet, and infrared spectra and the JSi=C NMR coupling constant of the stable silence (t-BuMe2Si)(Me3Si)Si=2-Ad. Manifestations of the Si=C double bond Journal of Physical Chemistry A. 106: 4880-4885. DOI: 10.1021/Jp014158X |
0.624 |
|
| 2002 |
Bravo-Zhivotovskii D, Yuzefovich M, Sigal N, Korogodsky G, Klinkhammer K, Tumanskii B, Shames A, Apeloig Y. The Synthesis of the First Compound with Li‐Si‐Hg Bonding: [{Li(iPr3Si)2Si}2Hg]—a Source for the [Li(iPr3Si)2Si]. Radical Angewandte Chemie. 41: 649-651. DOI: 10.1002/1521-3773(20020215)41:4<649::Aid-Anie649>3.0.Co;2-6 |
0.363 |
|
| 2001 |
Apeloig Y, Yuzefovich M, Bendikov M, Bravo-Zhivotovskii D, Bläser D, Boese R. Branched Star-Type Polysilyllithium Compounds: The Effects of β-Silyl Substitution and of Complexation on Their Molecular Structure. Angewandte Chemie (International Ed. in English). 40: 3016-20. PMID 12203634 DOI: 10.1002/1521-3773(20010817)40:16<3016::Aid-Anie3016>3.0.Co;2-A |
0.626 |
|
| 2001 |
Buffy JJ, West R, Bendikov M, Apeloig Y. Chemical shielding tensors for a silicon-carbon double bond. Journal of the American Chemical Society. 123: 978-9. PMID 11456634 DOI: 10.1021/Ja003389Z |
0.614 |
|
| 2001 |
Takahashi M, Tsutsui S, Sakamoto K, Kira M, Müller T, Apeloig Y. Dimers of diaminosilylenes: doubly bonded or bridged? The dimers of (i-Pr(2)N)(2)Si:. Journal of the American Chemical Society. 123: 347-8. PMID 11456528 DOI: 10.1021/Ja003463D |
0.328 |
|
| 2001 |
Halton B, Kay AJ, McNichols AT, Stang PJ, Apeloig Y, Boese R, Maulitz AH, Haumann T. Studies in the cycloproparene series: Cycloaddition reactions of diarylmethylidenecycloproparenes Arkivoc. 2001: 8-31. DOI: 10.3998/Ark.5550190.0002.702 |
0.471 |
|
| 2001 |
Maas G, Alt M, Mayer D, Bergsträsser U, Sklenak S, Xavier P, Apeloig Y. Catalytic and photochemical cyclopropanation of alkenes with methyl diazo(trialkylsilyl)acetates: Steric effects and thermodynamic stabilities of cyclopropanes Organometallics. 20: 4607-4615. DOI: 10.1021/Om010491B |
0.664 |
|
| 2001 |
Müller T, Bendikov M, Auner N, Apeloig Y. The trichlorovinylsilane/tert-butyllithium reagent - A source for transient silenes? Organometallics. 20: 598-600. DOI: 10.1021/Om000833Y |
0.615 |
|
| 2001 |
Sigal N, Apeloig Y. Are disilacyclopropylidenes and their carbenoids good precursors for the unknown 1,3-disilaallenes? Journal of Organometallic Chemistry. 636: 148-156. DOI: 10.1016/S0022-328X(01)00996-2 |
0.357 |
|
| 2001 |
Takahashi M, Kira M, Sakamoto K, Müller T, Apeloig Y. Theoretical prediction of vertical transition energies of diaminosilylenes and aminosubstituted disilenes Journal of Computational Chemistry. 22: 1536-1541. DOI: 10.1002/Jcc.1106 |
0.349 |
|
| 2001 |
Apeloig Y, Yuzefovich M, Bendikov M, Bravo-Zhivotovskii D, Bläser D, Boese R. Verzweigte, sternförmige Polysilyllithiumverbindungen: der Einfluss vonβ-Silylsubstitution und Komplexierung auf die Molekülstruktur Angewandte Chemie. 113: 3106-3109. DOI: 10.1002/1521-3757(20010817)113:16<3106::Aid-Ange3106>3.0.Co;2-4 |
0.562 |
|
| 2001 |
de Meijere A, Faber D, Heinecke U, Walsh R, Müller T, Apeloig Y. On the Question of Cyclopropylidene Intermediates in Cyclopropene-to-Allene Rearrangements − Tetrakis(trimethylsilyl)cyclopropene, 3-Alkenyl-1,2,3-tris(trimethylsilyl)cyclopropenes, and Related Model Compounds European Journal of Organic Chemistry. 2001: 663-680. DOI: 10.1002/1099-0690(200102)2001:4<663::Aid-Ejoc663>3.0.Co;2-E |
0.379 |
|
| 2000 |
Vlaar MJ, Ehlers AW, de Kanter FJ, Schakel M, Spek AL, Lutz M, Sigal N, Apeloig Y, Lammertsma K. A Novel CSiP Ring from the Reaction of a Complexed Phosphinidene and a Silene This work was supported by the Council for Chemical Sciences of the Netherlands Organization for Scientific Research (NWO/CW). Angewandte Chemie (International Ed. in English). 39: 4127-4130. PMID 11093228 DOI: 10.1002/1521-3773(20001117)39:22<4127::Aid-Anie4127>3.0.Co;2-B |
0.498 |
|
| 2000 |
Apeloig Y, Sklenak S. On the possible formation of Si=O, Si=S, and Si=Se double bonds via the reaction of silylenes with oxirane, thiirane, and selenirane, respectively. An ab initio theoretical study Canadian Journal of Chemistry. 78: 1496-1510. DOI: 10.1139/V00-107 |
0.705 |
|
| 2000 |
Sklenak S, Apeloig Y, Rappoport Z. Equilibria of simple thioenol/thiocarbonyl pairs. Comparison with the oxygen analogs and with the parent selenium and tellurium systems. A theoretical study Journal of the Chemical Society-Perkin Transactions 1. 2269-2279. DOI: 10.1039/B004289G |
0.712 |
|
| 2000 |
Apeloig Y, Bravo-Zhivotovskii D, Yuzefovich M, Bendikov M, Shames AI. Polysilyl radicals: EPR study of the formation and decomposition of star polysilanes Applied Magnetic Resonance. 18: 425-434. DOI: 10.1007/Bf03162156 |
0.669 |
|
| 2000 |
Vlaar M, Ehlers A, de Kanter F, Schakel M, Spek A, Lutz M, Sigal N, Apeloig Y, Lammertsma K. Ein neuartiger CSiP-Ring durch Reaktion eines komplexierten Phosphinidens und eines Silens Angewandte Chemie. 112: 4296-4299. DOI: 10.1002/1521-3757(20001117)112:22<4296::Aid-Ange4296>3.0.Co;2-5 |
0.493 |
|
| 2000 |
Apeloig Y, Korogodsky G, Bravo-Zhivotovskii D, Bläser D, Boese R. The Syntheses and Molecular Structure of a Branched Oligosilyl Anion with a Record of Nine Silicon Atoms and of the First Branched Oligosilyl Dianion European Journal of Inorganic Chemistry. 2000: 1091-1095. DOI: 10.1002/(Sici)1099-0682(200005)2000:5<1091::Aid-Ejic1091>3.0.Co;2-1 |
0.364 |
|
| 1999 |
Karni M, Apeloig Y, Schröder D, Zummack W, Rabezzana R, Schwarz H. HCSiF and HCSiCl: The First Detection of Molecules with Formal C≡Si Triple Bonds. Angewandte Chemie (International Ed. in English). 38: 331-335. PMID 29711652 DOI: 10.1002/(Sici)1521-3773(19990201)38:3<331::Aid-Anie331>3.0.Co;2-8 |
0.375 |
|
| 1999 |
Bravo-Zhivotovskii D, Yuzefovich M, Bendikov M, Klinkhammer K, Apeloig Y. The Synthesis and Molecular Structure of the First Two-Coordinate, Dinuclear σ-Bonded Mercury(I) RHgHgR Compound. Angewandte Chemie (International Ed. in English). 38: 1100-2. PMID 25138508 DOI: 10.1002/(Sici)1521-3773(19990419)38:8<1100::Aid-Anie1100>3.0.Co;2-N |
0.641 |
|
| 1999 |
Apeloig Y, Bravo-Zhivotovskii D, Bendikov M, Danovich D, Botoshansky M, Vakul'skaya T, Voronkov M, Samoilova R, Zdravkova M, Igonin V, Shklover V, Struchkov Y. Synthesis and x-ray molecular structure of the first stable organic radical lacking resonance stabilization [8] Journal of the American Chemical Society. 121: 8118-8119. DOI: 10.1021/Ja991109D |
0.638 |
|
| 1999 |
Bravo-Zhivotovskii D, Yuzefovich M, Bendikov M, Klinkhammer K, Apeloig Y. Synthese und Molekülstruktur der ersten zweifach koordinierten zweikernigen Quecksilber(I)-Verbindung des Typs RHgHgR Angewandte Chemie. 111: 1169-1171. DOI: 10.1002/(Sici)1521-3757(19990419)111:8<1169::Aid-Ange1169>3.0.Co;2-9 |
0.583 |
|
| 1999 |
Karni M, Apeloig Y, Schröder D, Zummack W, Rabezzana R, Schwarz H. Nachweis von HCSiF und HCSiCl als die ersten Moleküle mit formalen C≡Si-Bindungen Angewandte Chemie. 111: 343-347. DOI: 10.1002/(Sici)1521-3757(19990201)111:3<343::Aid-Ange343>3.0.Co;2-Y |
0.31 |
|
| 1998 |
Apeloig Y, Nakash M. Arrhenius Parameters for the Addition of Phenols to the Silicon−Silicon Double Bond of Tetramesityldisilene† Organometallics. 17: 2307-2312. DOI: 10.1021/Om980016M |
0.77 |
|
| 1998 |
Apeloig Y, Nakash M. Solvent-Dependent Stereoselectivity in the Addition ofp-CH3OC6H4OH to (E)-1,2-Di-tert-butyl-1,2-dimesityldisilene. Evidence for Rotation around the Si−Si Bond in the Zwitterionic Intermediate Organometallics. 17: 1260-1265. DOI: 10.1021/Om970700L |
0.782 |
|
| 1998 |
Sklenák S, Apeloig Y, Rappoport Z. Calculated pKEnolValues for Enols of Carboxylic Acid Derivatives HCC(OH)X (X = OH, NH2, NMe2, OMe, OCHO, F, Cl, Br) Journal of the American Chemical Society. 120: 10359-10364. DOI: 10.1021/Ja980354E |
0.728 |
|
| 1998 |
Apeloig Y, Boese R, Halton B, Maulitz AH. Molecular Structures of Fulvalenes Derived from Methylidenecycloproparenes: X-ray Structure Determinations and ab Initio Calculations Journal of the American Chemical Society. 120: 10147-10153. DOI: 10.1021/Ja973020I |
0.334 |
|
| 1998 |
Apeloig Y, Bravo-Zhivotovskii D, Zharov I, Panov V, Leigh WJ, Sluggett GW. Thermal and photochemical [2+2] cycloreversion of a 1,2- disilacyclobutane and a 1,2-digermacyclobutane Journal of the American Chemical Society. 120: 1398-1404. DOI: 10.1021/Ja9729600 |
0.617 |
|
| 1998 |
Zoller U, Shakkour E, Pastersky I, Sklenak Š, Apeloig Y. Polycyclic Arene Episulfides. Attempted Synthesis, Molecular Orbital Calculations and Comparison with Arene Oxides Tetrahedron. 54: 14283-14300. DOI: 10.1016/S0040-4020(98)00884-9 |
0.669 |
|
| 1997 |
Shvily R, Müller T, Apeloig Y, Mandelbaum A. Direct evidence for anchimeric assistance in alcohol elimination fromgas-phase MH+ ions of 1,4-dialkoxycyclohexanes under chemicalionisation. Experiment and theory Journal of the Chemical Society-Perkin Transactions 1. 1221-1234. DOI: 10.1039/A605638E |
0.315 |
|
| 1997 |
Cypryk M, Apeloig Y. Ab initio study of silyloxonium ions Organometallics. 16: 5938-5949. DOI: 10.1021/Om9701128 |
0.325 |
|
| 1997 |
Apeloig Y, Yuzefovich M, Bendikov M, Bravo-Zhivotovskii D, Klinkhammer K. A New Method for the Synthesis of Branched Polysilane Anions Organometallics. 16: 1265-1269. DOI: 10.1021/Om960733L |
0.633 |
|
| 1997 |
West R, Cavalieri JD, Buffy JJ, Fry C, Zilm KW, Duchamp JC, Kira M, Iwamoto T, Müller T, Apeloig Y. A solid-state 1NMR and theoretical study of the chemical bonding in disilenes Journal of the American Chemical Society. 119: 4972-4976. DOI: 10.1021/Ja963921B |
0.301 |
|
| 1996 |
Apeloig Y, Danovich D. Ionization energies of linear and cyclic polysilanes. Application of the green's function method coupled with semiempirical molecular orbital calculations Organometallics. 15: 350-360. DOI: 10.1021/Om950583Z |
0.311 |
|
| 1996 |
De Meijere A, Faber D, Noltemeyer M, Boese R, Haumann T, Müller T, Bendikov M, Matzner E, Apeloig Y. Tris(trimethylsilyl)cyclopropenylmm cation: The first X-ray structure analysis of an α-silyl-substituted carbocation Journal of Organic Chemistry. 61: 8564-8568. DOI: 10.1021/Jo960478E |
0.663 |
|
| 1996 |
Apeloig Y, Bendikov M, Yuzefovich M, Nakash M, Bravo-Zhivotovskii D, Bläser D, Boese R. Novel stable silenes via a sila-Peterson-type reaction. Molecular structure and reactivity Journal of the American Chemical Society. 118: 12228-12229. DOI: 10.1021/Ja962844H |
0.771 |
|
| 1996 |
Apeloig Y, Nakash M. The Mechanism of Addition of Phenols to Tetramesityldisilene. Evidence for Both Nucleophilic and Electrophilic Rate-Determining Steps Journal of the American Chemical Society. 118: 9798-9799. DOI: 10.1021/Ja961746T |
0.779 |
|
| 1996 |
West R, Sohn H, Powell DR, Müller T, Apeloig Y. The Dianion of Tetraphenylgermole is Aromatic Angewandte Chemie International Edition in English. 35: 1002-1004. DOI: 10.1002/Anie.199610021 |
0.321 |
|
| 1995 |
Bravo-Zhivotovskii D, Zharov I, Kapon M, Apeloig Y. A novel synthesis of a germene and of a 1,2-digermacyclobutane via a Peterson-type reaction Journal of the Chemical Society, Chemical Communications. 1625-1626. DOI: 10.1039/C39950001625 |
0.349 |
|
| 1995 |
Apeloig Y, Albrecht K. Ab Initio Study on the Unimolecular Decomposition Mechanisms and Spectroscopic Properties of CH3OF Journal of the American Chemical Society. 117: 9564-9569. DOI: 10.1021/Ja00142A027 |
0.348 |
|
| 1995 |
Apeloig Y, Albrecht K. Triple Bonds to Silicon. Relative Stabilities and Energy Barriers Separating Silanitriles and Silaisonitriles. An ab Initio Study Journal of the American Chemical Society. 117: 7263-7264. DOI: 10.1021/Ja00132A034 |
0.333 |
|
| 1995 |
Apeloig Y, Matzner E. Evidence for the Dominant Role of Secondary Orbital Interactions in Determining the Stereochemistry of the Diels-Alder Reaction: The Case of Cyclopropene Journal of the American Chemical Society. 117: 5375-5376. DOI: 10.1021/Ja00124A027 |
0.369 |
|
| 1995 |
Müller T, Apeloig Y, Hemme I, Klingebiel U, Noltemeyer M. Tetrafluorocyclodisilazanes: synthesis, crystal structure, and molecular orbital ab initio calculations Journal of Organometallic Chemistry. 494: 133-142. DOI: 10.1016/0022-328X(95)05402-B |
0.411 |
|
| 1995 |
Apeloig Y, Zharov I, Bravo-Zhivotovskii D, Ovchinnikov Y, Struchkov Y. Synthesis and the electronic spectra of the first ß-ketoacylsilanes and their lithium enolates: new insights into hyperconjugation in acylsilanes and their enolates Journal of Organometallic Chemistry. 499: 73-82. DOI: 10.1016/0022-328X(95)00313-F |
0.656 |
|
| 1994 |
Frey J, Schottland E, Rappoport Z, Bravo-Zhivotovskii D, Nakash M, Botoshansky M, Kaftory M, Apeloig Y. The effective ‘size’ of the tris(trimethylsilyl)silyl group in several molecular environments Journal of the Chemical Society-Perkin Transactions 1. 2555-2562. DOI: 10.1039/P29940002555 |
0.793 |
|
| 1994 |
Apeloig Y, Nakash M. Reversal of Stereoselectivity in the Reduction of gem-Dichlorides by Tributyltin Hydride and Tris(trimethylsilyl)silane. Synthetic and Mechanistic Implications Journal of the American Chemical Society. 116: 10781-10782. DOI: 10.1021/Ja00102A052 |
0.766 |
|
| 1994 |
Apeloig Y, Karni M, West R, Welsh K. Electronic Spectra of Ethynyl- and Vinylsilylenes: Experiment and Theory Journal of the American Chemical Society. 116: 9719-9729. DOI: 10.1021/Ja00100A042 |
0.345 |
|
| 1994 |
Apeloig Y, Biton R, Zuilhof H, Lodder G. Destabilized vinyl cations. An MO study of the influence of electron-withdrawing substituents Tetrahedron Letters. 35: 265-268. DOI: 10.1016/S0040-4039(00)76527-0 |
0.331 |
|
| 1993 |
Danovich D, Apeloig Y, Shaik S. A reliable and inexpensive method for calculating ionization potentials and electron affinities of radicals and molecules Journal of the Chemical Society-Perkin Transactions 1. 321-330. DOI: 10.1039/P29930000321 |
0.312 |
|
| 1993 |
Halton B, Kay AJ, McNichols AT, Stang PJ, Apeloig Y, Maulitz AH, Boese R, Haumann T. Diarylmethylenecyclopropabenzenes in cycloaddition Tetrahedron Letters. 34: 6151-6154. DOI: 10.1016/S0040-4039(00)61754-9 |
0.47 |
|
| 1993 |
Bravo-Zhivotovskii D, Apeloig Y, Ovchinnikov Y, Igonin V, Struchkov YT. A novel route to the trisilacyclobutane moiety. A possible silene-disilene reaction Journal of Organometallic Chemistry. 446: 123-129. DOI: 10.1016/0022-328X(93)80043-B |
0.35 |
|
| 1993 |
Apeloig Y, Merin-Aharoni O, Danovich D, Ioffe A, Shaik S. Does Hydride Ion Transfer from Silanes to Carbenium Ions Proceed Via a Rate-Determining Formation of a Silicenium Ion or Via a Rate-Determining Electron Transfer? An Ab Initio Quantum Mechanical Study and a Curve-Crossing Analysis Israel Journal of Chemistry. 33: 387-402. DOI: 10.1002/Ijch.199300046 |
0.351 |
|
| 1992 |
Bravo-Zhivotovskii D, Braude V, Stanger A, Kapon M, Apeloig Y. Novel route to carbon-silicon double bonds via a Peterson-type reaction Organometallics. 11: 2326-2328. DOI: 10.1021/Om00043A003 |
0.634 |
|
| 1991 |
Danovich D, Apeloig Y. Ionization energies of triazines and tetrazines. Application of Green's function method coupled with semiempirical molecular orbital calculations Journal of the Chemical Society, Perkin Transactions 2. 1865-1873. DOI: 10.1039/P29910001865 |
0.302 |
|
| 1991 |
Stang PJ, Crittell CM, Arif AM, Karni M, Apeloig Y. Single-crystal molecular structure determinations and theoretical calculations on alkynyl sulfonate and carboxylate esters Journal of the American Chemical Society. 113: 7461-7470. DOI: 10.1021/Ja00020A002 |
0.512 |
|
| 1991 |
Siehl HU, Kaufmann F, Apeloig Y, Braude V, Danovich D, Berndt A, Stamatis N. The First Persistentβ-Silyl-Substituted Vinyl Cation Angewandte Chemie International Edition in English. 30: 1479-1482. DOI: 10.1002/Anie.199114791 |
0.356 |
|
| 1990 |
Drewello T, Burgers PC, Zummack W, Apeloig Y, Schwarz H. Experimental evidence for novel hydrogen/methyl exchange processes preceding the unimolecular dissociation of silicon-containing cations in the gas phase Organometallics. 9: 1161-1165. DOI: 10.1021/Om00118A041 |
0.369 |
|
| 1990 |
Apeloig Y, Arad D, Rappoport Z. Alkyl- and silyl-substituent effects on keto-enol equilibria and the structures of simple aliphatic enols. A theoretical ab initio study Journal of the American Chemical Society. 112: 9131-9140. DOI: 10.1021/Ja00181A015 |
0.503 |
|
| 1990 |
Karni M, Apeloig Y. Substituent effects on the geometries and energies of the silicon-silicon double bond Journal of the American Chemical Society. 112: 8589-8590. DOI: 10.1021/Ja00179A057 |
0.323 |
|
| 1990 |
Stang PJ, Kitamura T, Karni M, Apeloig Y, Arif AM. A single crystal molecular structure determination and theoretical calculations on alkynyl carboxylate esters Journal of the American Chemical Society. 112: 374-381. DOI: 10.1021/Ja00157A057 |
0.433 |
|
| 1990 |
RAPPOPORT Z, AVRAMOVITCH B, KARNI M, APELOIG Y. ChemInform Abstract: Nucleophilic Attacks on Carbon-Carbon Double Bonds. Part 37. Thiocyanate Ion Promoted E ⇌ Z Isomerization of α-Bromo-β,β-Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS-. Cheminform. 21. DOI: 10.1002/chin.199007084 |
0.436 |
|
| 1989 |
Uggerud E, Arad D, Apeloig Y, Schwarz H. Extraordinary large stabilization of the phenyl cation by hyperconjugation with strained bonds. Experimental confirmation of a theoretical prediction Journal of the Chemical Society, Chemical Communications. 1015-1016. DOI: 10.1039/C39890001015 |
0.356 |
|
| 1989 |
Rappoport Z, Avramovitch B, Karni M, Apeloig Y. Thiocyanate Ion Promoted
E ⇌ Z
Isomerization of a‐Bromo‐β,β‐Diactivated Electrophilic Olefins: An Apparent High Nucleofugality of NCS
− Israel Journal of Chemistry. 29: 267-279. DOI: 10.1002/Ijch.198900036 |
0.546 |
|
| 1988 |
Apeloig Y, Karni M. The stabilities of α-oxy and α-thio carbenium ions: the importance of the ground-state energies of the neutral precursors Journal of the Chemical Society-Perkin Transactions 1. 625-636. DOI: 10.1039/P29880000625 |
0.349 |
|
| 1988 |
Apeloig Y, Stanger A. The anomeric effect at silicon Journal of Organometallic Chemistry. 346: 305-313. DOI: 10.1016/0022-328X(88)80130-X |
0.616 |
|
| 1987 |
Apeloig Y, Karni M, Stanger A, Schwarz H, Drewello T, Czekay G. Rearrangement vs. dissociation of gaseous silicon-containing cations: a combined experimental–theoretical approach Journal of the Chemical Society, Chemical Communications. 989-991. DOI: 10.1039/C39870000989 |
0.61 |
|
| 1987 |
Nadler EB, Rappoport Z, Arad D, Apeloig Y. The first .alpha.-silicon-substituted simple enol. The stabilizing effect of the silyl substituent Journal of the American Chemical Society. 109: 7873-7875. DOI: 10.1021/Ja00259A041 |
0.495 |
|
| 1987 |
Apeloig Y, Stanger A. The first demonstration of solvolytic generation of a simple silicenium ion (R3Si+). Access via 1,2-methyl migration Journal of the American Chemical Society. 109: 272-273. DOI: 10.1021/Ja00235A041 |
0.589 |
|
| 1987 |
Apeloig Y, Arad D, Kapon M, Wallerstein M. The stereochemistry of diels-alder reactions of cyclopropenes Tetrahedron Letters. 28: 5917-5920. DOI: 10.1016/S0040-4039(01)81090-X |
0.331 |
|
| 1987 |
APELOIG Y, STANGER A. ChemInform Abstract: First Demonstration of Solvolytic Generation of a Simple Silicenium Ion (R3Si+). Access via 1,2-Methyl Migration. Cheminform. 18. DOI: 10.1002/chin.198721207 |
0.557 |
|
| 1986 |
Luke BT, Pople JA, Krogh-Jespersen MB, Apeloig Y, Karni M, Chandrasekhar J, Schleyer PvR. A theoretical survey of unsaturated or multiply bonded and divalent silicon compounds. Comparison with carbon analogs Journal of the American Chemical Society. 108: 270-284. DOI: 10.1021/Ja00262A014 |
0.602 |
|
| 1986 |
Luke BT, Pople JA, Krogh-Jespersen MB, Apeloig Y, Chandrasekhar J, Schleyer PvR. A theoretical survey of singly bonded silicon compounds. Comparison of the structures and bond energies of silyl and methyl derivatives Journal of the American Chemical Society. 108: 260-269. DOI: 10.1021/Ja00262A013 |
0.605 |
|
| 1986 |
Apeloig Y, Karni M, Stang PJ, Christensen SB. The selectivity of isopropylidenecarbene Tetrahedron Letters. 27: 6115-6118. DOI: 10.1016/S0040-4039(00)85412-X |
0.455 |
|
| 1986 |
LUKE BT, POPLE JA, KROGH-JESPERSEN M, APELOIG Y, KARNI M, CHANDRASEKHAR J, VON RAGUE SCHLEYER P. ChemInform Abstract: Theoretical Survey of Unsaturated or Multiply Bonded and Divalent Silicon Compounds. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198618004 |
0.563 |
|
| 1986 |
Luke BT, Pople JA, Krogh-Jespersen M-, Apeloig Y, Chandrasekhar J, Schleyer PVR. Theoretical Survey of Singly Bonded Silicon Compounds. Comparison of the Structures and Bond Energies of Silyl and Methyl Derivatives Cheminform. 17. DOI: 10.1002/Chin.198618003 |
0.57 |
|
| 1985 |
Kaftory M, Apeloig Y, Rappoport Z. The effect of steric crowding on the structures of solvolytically reactive arylvinyl systems Journal of the Chemical Society-Perkin Transactions 1. 16: 29-37. DOI: 10.1039/P29850000029 |
0.502 |
|
| 1985 |
Apeloig Y, Karni M. The effect of substituents on the first transition in the visible spectra of silanediyls (silylenes) Journal of the Chemical Society, Chemical Communications. 1048-1049. DOI: 10.1039/C39850001048 |
0.307 |
|
| 1985 |
Apeloig Y, Stanger A. Are carbenium ions stabilized or destabilized by .alpha.-silyl substitution? The solvolysis of 2-(trimethylsilyl)-2-adamantyl p-nitrobenzoate Journal of the American Chemical Society. 107: 2806-2807. DOI: 10.1021/Ja00295A043 |
0.609 |
|
| 1985 |
Stanger A, Apeloig Y, Ginsburg D. Propellanes. Part LXXXI. Why are tetrakis[organoboranediylbis(oxy)]cyclobutanes formed without a trace of the isomeric tetrakis-dioxabora[3.3.2]propellanes? Helvetica Chimica Acta. 68: 1179-1185. DOI: 10.1002/Hlca.19850680513 |
0.616 |
|
| 1985 |
STANGER A, APELOIG Y, GINSBURG D. ChemInform Abstract: PROPELLANES. PART LXXXI. WHY ARE TETRAKIS(ORGANOBORANEDIYLBIS(OXY))CYCLOBUTANES FORMED WITHOUT A TRACE OF THE ISOMERIC TETRAKISDIOXABORA(3.3.2)PROPELLANES? Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198547050 |
0.606 |
|
| 1985 |
APELOIG Y, STANGER A. ChemInform Abstract: ARE CARBENIUM IONS STABILIZED OR DESTABILIZED BY α-SILYL SUBSTITUTION? THE SOLVOLYSIS OF 2-(TRIMETHYLSILYL)-2-ADAMANTYL P-NITROBENZOATE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198536085 |
0.569 |
|
| 1985 |
KAFTORY M, APELOIG Y, RAPPOPORT Z. ChemInform Abstract: THE EFFECT OF STERIC CROWDING ON THE STRUCTURES OF SOLVOLYTICALLY REACTIVE ARYLVINYL SYSTEMS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198516080 |
0.391 |
|
| 1985 |
APELOIG Y, KARNI M. ChemInform Abstract: SUBSTITUENT EFFECTS ON THE CARBON-SILICON DOUBLE BOND. MONOSUBSTITUTED SILENES Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198509058 |
0.336 |
|
| 1984 |
Apeloig Y, Karni M. On the experimental–theoretical discrepancy regarding the silicon–carbon double bond length Journal of the Chemical Society, Chemical Communications. 768-768. DOI: 10.1039/C39840000768 |
0.312 |
|
| 1984 |
Apeloig Y, Karni M. Substituent Effects on the Carbon-Silicon Double Bond. Monosubstituted Silenes Journal of the American Chemical Society. 106: 6676-6682. DOI: 10.1021/Ja00334A036 |
0.36 |
|
| 1984 |
Apeloig Y, Karni M, Ciommer B, Depke G, Frenking G, Meyn S, Schmidt J, Schwarz H. Mechanism of keto Å enol tautomerism of ionized vinyl alcohol versus acetaldehyde and their dissociation to C2H3O+ and H·. An ab initio molecular orbital study International Journal of Mass Spectrometry and Ion Processes. 59: 21-37. DOI: 10.1016/0168-1176(84)87067-6 |
0.353 |
|
| 1983 |
Apeloig Y, Karni M, Ciommer B, Depke G, Frenking G, Meyn S, Schmidt J, Schwarz H. [CH3COH]˙+, the central intermediate in the isomerization–dissociation reactions of ionized vinyl alcohol Journal of the Chemical Society, Chemical Communications. 1497-1499. DOI: 10.1039/C39830001497 |
0.335 |
|
| 1983 |
Apeloig Y, Stanger A. Additions and Corrections - α-Silicon-Substituted Vinyl Cations. A Theoretical ab Initio Investigation. The Journal of Organic Chemistry. 48: 5413-5413. DOI: 10.1021/Jo00174A600 |
0.641 |
|
| 1983 |
Apeloig Y, Karni M, Stang PJ, Fox DP. Transition-state geometries and stereoselectivity of alkylidenecarbene addition to olefins. An experimental and theoretical investigation Journal of the American Chemical Society. 105: 4781-4792. DOI: 10.1021/Ja00352A042 |
0.433 |
|
| 1983 |
Apeloig Y, Karni M, Rappoport Z. Nucleophilic attacks on carbon-carbon double bonds. Part 29. Role of hyperconjugation in determining the stereochemistry of nucleophilic epoxidation and cyclopropanation of electrophilic olefins Journal of the American Chemical Society. 105: 2784-2793. DOI: 10.1021/Ja00347A044 |
0.503 |
|
| 1983 |
Apeloig Y, Ciommer B, Frenking G, Karni M, Mandelbaum A, Schwarz H, Weisz A. Mechanism of carbon dioxide elimination from ionized methyl haloacetates in the gas phase. Formation of CH3XCH2+.cntdot. and CH3XCHX+.cntdot. (X = Cl, Br) halonium radical ions Journal of the American Chemical Society. 105: 2186-2193. DOI: 10.1021/Ja00346A015 |
0.315 |
|
| 1983 |
Schleyer PvR, Apeloig Y, Arad D, Luke BT, Pople JA. The structure and energy of SiH+5. comparisons with CH+5 and BH5 Chemical Physics Letters. 95: 477-482. DOI: 10.1016/0009-2614(83)80336-4 |
0.301 |
|
| 1983 |
Apeloig Y, Karni M, Stang PJ, Fox DP. Transition-State Geometries And Stereoselectivity Of Alkylidenecarbene Addition To Olefins. An Experimental And Theoretical Investigation Cheminform. 14. DOI: 10.1002/Chin.198344112 |
0.433 |
|
| 1983 |
APELOIG Y, KARNI M, RAPPOPORT Z. ChemInform Abstract: NUCLEOPHILIC ATTACKS ON CARBON-CARBON DOUBLE BONDS. PART 29. ROLE OF HYPERCONJUGATION IN DETERMINING THE STEREOCHEMISTRY OF NUCLEOPHILIC EPOXIDATION AND CYCLOPROPANATION OF ELECTROPHILIC OLEFINS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198332103 |
0.444 |
|
| 1983 |
STANG PJ, LADIKA M, APELOIG Y, STANGER A, SCHIAVELLI MD, HUGHEY MR. ChemInform Abstract: BIMOLECULAR SUBSTITUTION AT CARBON IN NEOPENTYL-LIKE SILYLCARBINYL SULFONATES Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198309250 |
0.65 |
|
| 1982 |
Apeloig Y, Stanger A. .alpha.-Silicon-substituted vinyl cations. A theoretical ab initio investigation The Journal of Organic Chemistry. 47: 1462-1468. DOI: 10.1021/Jo00347A017 |
0.618 |
|
| 1982 |
Stang PJ, Ladika M, Apeloig Y, Stanger A, Schiavelli MD, Hughey MR. Bimolecular substitution at carbon in neopentyl-like silylcarbinyl sulfonates Journal of the American Chemical Society. 104: 6852-6854. DOI: 10.1021/Ja00388A096 |
0.644 |
|
| 1982 |
APELOIG Y, STANGER A. ChemInform Abstract: α-SILICON-SUBSTITUTED VINYL CATIONS. A THEORETICAL AB INITIO INVESTIGATION Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198235126 |
0.643 |
|
| 1981 |
Apeloig Y. Negative fluorine hyperconjugation. A theoretical re-examination Journal of the Chemical Society, Chemical Communications. 396-398. DOI: 10.1039/C39810000396 |
0.302 |
|
| 1981 |
Apeloig Y, Franke W, Rappoport Z, Schwarz H, Stahl D. Dissociative ionization of aryl-substituted vinyl bromides in the gas phase: experimental and computational evidence for the formation of stable .alpha.-arylvinyl cations both by direct means and by spontaneous exothermic isomerization of unstable isomeric ions Journal of the American Chemical Society. 103: 2770-2780. DOI: 10.1021/Ja00400A047 |
0.502 |
|
| 1981 |
Ashkenazi P, Kaftory M, Arad D, Apeloig Y, Ginsburg D. Propellanes. LXII. Theendo- andexo-adducts of 11-cyano-1,6-methano[10] annulene with 4-methyl-1,2,4-triazoline-3,5-dione Helvetica Chimica Acta. 64: 579-581. DOI: 10.1002/Hlca.19810640222 |
0.314 |
|
| 1981 |
APELOIG Y, FRANKE W, RAPPOPORT Z, SCHWARZ H, STAHL D. ChemInform Abstract: DISSOCIATIVE IONIZATION OF ARYL-SUBSTITUTED VINYL BROMIDES IN THE GAS PHASE: EXPERIMENTAL AND COMPUTATIONAL EVIDENCE FOR THE FORMATION OF STABLE α-ARYLVINYL CATIONS BOTH BY DIRECT MEANS AND BY SPONTANEOUS EXOTHERMIC ISOMERIZATION OF U Chemischer Informationsdienst. 12. DOI: 10.1002/Chin.198134069 |
0.539 |
|
| 1980 |
Apeloig Y, Collins JB, Cremer D, Bally T, Haselbach E, Pople JA, Chandrasekhar J, Schleyer PVR. Theoretical study of the isomeric cyclopropylidenemethyl and 1-cyclobutenyl cations, unusually stable vinyl cations The Journal of Organic Chemistry. 45: 3496-3501. DOI: 10.1021/Jo01305A025 |
0.576 |
|
| 1980 |
Rappoport Z, Apeloig Y, Greenblatt J. Vinylic cations from solvolysis. 29. Solvolysis of 9-(.alpha.-bromoarylidene)anthrones as a probe to the reactivity-selectivity relationship in solvolysis reactions Journal of the American Chemical Society. 102: 3837-3848. DOI: 10.1021/Ja00531A028 |
0.488 |
|
| 1980 |
Apeloig Y, Schrieber R, Stang PJ. Exocyclic Alkylidene Carbenes - An ab initio Theoretical Study. Tetrahedron Letters. 21: 411-414. DOI: 10.1016/S0040-4039(01)85487-3 |
0.492 |
|
| 1980 |
Apeloig Y, Clark T, Kos AJ, Jemmis ED, Schleyer PVR. Geometries and Energies of Dilithioethylene Isomers and of Vinyl Lithium. AnAb InitioStudy Israel Journal of Chemistry. 20: 43-50. DOI: 10.1002/Chin.198040063 |
0.573 |
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| 1980 |
RAPPOPORT Z, GREENBLATT J, APELOIG Y. ChemInform Abstract: 1,10-, 1,4-, AND 1,2-ELIMINATIONS AND 1,5- AND 1,7-REARRANGEMENTS IN THE REACTIONS OF SUBSTITUTED 9-ANISYLIDENE-9,10-DIHYDROANTHRACENES AND ANTHRONES IN ACETIC ACID Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198007218 |
0.45 |
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| 1979 |
Rappoport Z, Greenblatt J, Apeloig Y. 1,10-, 1,4-, and 1,2-Eliminations and 1,5- and 1,7-rearrangements in the reactions of substituted 9-anisylidene-9,10-dihydroanthracenes and anthrones in acetic acid The Journal of Organic Chemistry. 44: 3687-3694. DOI: 10.1021/Jo01335A015 |
0.506 |
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| 1979 |
Apeloig Y, Rappoport Z. The importance of hyperconjugation in nucleophilic vinylic substitution Journal of the American Chemical Society. 101: 5095-5098. DOI: 10.1021/Ja00511A065 |
0.529 |
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| 1979 |
APELOIG Y, RAPPOPORT Z. ChemInform Abstract: THE IMPORTANCE OF HYPERCONJUGATION IN NUCLEOPHILIC VINYLIC SUBSTITUTION Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197947088 |
0.469 |
|
| 1978 |
Apeloig Y, Schreiber R. A theoretical investigation of substituted alkylidene carbenes Tetrahedron Letters. 19: 4555-4558. DOI: 10.1016/S0040-4039(01)95276-1 |
0.329 |
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| 1978 |
APELOIG Y, SCHLEYER PVR, POPLE JA. ChemInform Abstract: MOLECULAR ORBITAL THEORY OF THE ELECTRONIC STRUCTURE OF MOLECULES. 36. A THEORETICAL STUDY OF SEVERAL α-SUBSTITUTED VINYL CATIONS Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197801076 |
0.379 |
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| 1977 |
Apeloig Y, Schleyer PVR, Pople JA. MO Theory of the Electronic Structure of Molecules. Part 35. β-Substituent Effects. on the Stabilities of Ethyl and Vinyl Cations. Comparison with Isoelectronic Methyl Boranes. The Relative Importance of Hyperconjugative and Inductive Cheminform. 8. DOI: 10.1002/Chin.197750054 |
0.309 |
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| 1976 |
Collins JB, Dill JD, Jemmis ED, Apeloig Y, Schleyer PvR, Seeger R, Pople JA. Stabilization of planar tetracoordinate carbon Journal of the American Chemical Society. 98: 5419-5427. DOI: 10.1021/Ja00434A001 |
0.481 |
|
| 1975 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XXI. Solvent effects on the external ion return and the internal return in several vinylic solvolyses Journal of the American Chemical Society. 97: 836-842. DOI: 10.1021/Ja00837A024 |
0.48 |
|
| 1975 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XX. Ion pairs and free ions in the solvolysis and isomerization of 1,2-dianisyl-2-phenylvinyl halides and mesylates. Use of cis-trans isomerization as a mechanistic tool Journal of the American Chemical Society. 97: 821-835. DOI: 10.1021/Ja00837A023 |
0.48 |
|
| 1975 |
RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 21, SOLVENT EFFECTS ON THE EXTERNAL ION RETURN AND THE INTERNAL RETURN IN SEVERAL VINYLIC SOLVOLYSES Chemischer Informationsdienst. 6: no-no. DOI: 10.1002/Chin.197518116 |
0.514 |
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| 1975 |
Rappoport Z, Apeloig Y. Vinylic Cations From Solvolysis Part 20, Ion Pairs And Free Ions In The Solvolysis And Isomerization Of 1,2-Dianisyl-2-Phenylvinyl Halides And Mesylates, Use Of Cis-Trans Isomerization As A Mechanistic Tool Cheminform. 6. DOI: 10.1002/Chin.197518115 |
0.48 |
|
| 1974 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. XXII. High stereoselectivity in the synthesis of and ion pair return in the solvolysis of (E)-.alpha.-bromo-.beta.-deuterio-p-methoxystyrene Journal of the American Chemical Society. 96: 6428-6436. DOI: 10.1021/Ja00827A029 |
0.479 |
|
| 1974 |
Rappoport Z, Kaspi J, Apeloig Y. Vinylic cations from solvolysis. XIX. Low tosylate-bromide reactivity ratios in vinylic solvolyses. Do kOTs/kBr ratios measure the polarity of the solvolytic transition state Journal of the American Chemical Society. 96: 2612-2614. DOI: 10.1021/Ja00815A049 |
0.464 |
|
| 1974 |
RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 22, HIGH STEREOSELECTIVITY IN THE SYNTHESIS OF AND ION PAIR RETURN IN THE SOLVOLYSIS OF (E)-ALPHA-BROMO-BETA-DEUTERIO-P-METHOXYSTYRENE Chemischer Informationsdienst. 5: no-no. DOI: 10.1002/Chin.197450131 |
0.484 |
|
| 1974 |
RAPPOPORT Z, KASPI J, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS PART 19, LOW TOSYLATE-BROMIDE REACTIVITY RATIOS IN VINYLIC SOLVOLYSES, DO K(OTS)/K(BR) RATIOS MEASURE THE POLARITY OF THE SOLVOLYTIC TRANSITION STATE Chemischer Informationsdienst. 5. DOI: 10.1002/Chin.197426157 |
0.46 |
|
| 1973 |
Rappoport Z, Pross A, Apeloig Y. Vinylic cations from solvolysis. XVI. High kcis/ktrans reactivity ratio in the solvolysis of α-bromo-β-tert-butyl-p-methoxystyrenes Tetrahedron Letters. 14: 2015-2018. DOI: 10.1016/S0040-4039(01)86795-2 |
0.476 |
|
| 1973 |
RAPPOPORT Z, PROSS A, APELOIG Y. ChemInform Abstract: VINYLIC CATIONS FROM SOLVOLYSIS, HIGH K(CIS)/K(TRANS)-REACTIVITY RATIO IN THE SOLVOLYSIS OF ALPHA-BROMO-BETA-TERT.-BUTYL-P-METHOXY-STYRENES Chemischer Informationsdienst. 4: no-no. DOI: 10.1002/Chin.197337114 |
0.466 |
|
| 1970 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. VI. Cis-trans isomerization as a tool for studying vinyl cation formation Tetrahedron Letters. 11: 1845-1848. DOI: 10.1016/S0040-4039(01)98098-0 |
0.498 |
|
| 1970 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. IV. Absence of β-aryl participation in the solvolysis of triarylvinyl halides Tetrahedron Letters. 11: 1817-1820. DOI: 10.1016/S0040-4039(01)98091-8 |
0.471 |
|
| 1970 |
RAPPOPORT Z, APELOIG Y. ChemInform Abstract: VINYLKATIONEN DURCH SOLVOLYSE 2. MITT. STEREOCHEMIE DER SN1-RK. VON 1,2-DIANISYL-2-PHENYL-VINYLHALIDEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197009092 |
0.508 |
|
| 1969 |
Rappoport Z, Apeloig Y. Vinylic cations from solvolysis. II. Stereochemistry of the SN1 reaction of 1,2-dianisyl-2-phenylvinyl halides Journal of the American Chemical Society. 91: 6734-6742. DOI: 10.1021/Ja01052A033 |
0.505 |
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