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Adrian Chaplin - Publications

Affiliations: 
2007-2010  
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49/68 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Krämer T, Gyton MR, Bustos I, Sinclair MJG, Tan SY, Wedge CJ, Macgregor SA, Chaplin AB. Stability and C-H Bond Activation Reactions of Palladium(I) and Platinum(I) Metalloradicals: Carbon-to-Metal H-Atom Transfer and an Organometallic Radical Rebound Mechanism. Journal of the American Chemical Society. PMID 37318758 DOI: 10.1021/jacs.3c04167  0.408
2023 Emerson-King J, Chaplin AB. Template synthesis of an intermediate in silver salt metathesis using a calix[4]arene-based diphosphine ligand. Dalton Transactions (Cambridge, England : 2003). 52: 5044-5046. PMID 37066625 DOI: 10.1039/d3dt00567d  0.325
2023 Emerson-King J, Pan S, Gyton MR, Tonner-Zech R, Chaplin AB. Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand. Chemical Communications (Cambridge, England). PMID 36727440 DOI: 10.1039/d2cc06837k  0.303
2023 Poole EW, Bustos I, Hood TM, Smart JE, Chaplin AB. Iridium complexes of an -trifluoromethylphenyl substituted PONOP pincer ligand. Dalton Transactions (Cambridge, England : 2003). PMID 36602231 DOI: 10.1039/d2dt03608h  0.406
2022 Longcake A, Lees MR, Senn MS, Chaplin AB. Oxidative Addition of C-Cl Bonds to a Rh(PONOP) Pincer Complex. Organometallics. 41: 3557-3567. PMID 36533115 DOI: 10.1021/acs.organomet.2c00400  0.382
2021 Hood TM, Chaplin AB. Synthesis and reactivity of iridium complexes of a macrocyclic PNP pincer ligand. Dalton Transactions (Cambridge, England : 2003). PMID 33511383 DOI: 10.1039/d0dt04303f  0.483
2020 Kynman AE, Lau S, Dowd SO, Krämer T, Chaplin AB. Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex. European Journal of Inorganic Chemistry. 2020: 3899-3906. PMID 33328794 DOI: 10.1002/ejic.202000780  0.406
2020 Storey CM, Gyton MR, Andrew RE, Chaplin AB. Terminal alkyne coupling reactions through a ring: effect of ring size on rate and regioselectivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32677713 DOI: 10.1002/chem.202002962  0.343
2020 Gyton MR, Kynman AE, Leforestier B, Gallo A, Lewandowski JR, Chaplin AB. Isolation and structural characterisation of rhodium(iii) η-fluoroarene complexes: experimental verification of predicted regioselectivity. Dalton Transactions (Cambridge, England : 2003). 49: 5791-5793. PMID 32314773 DOI: 10.1039/d0dt01137a  0.309
2020 Leforestier B, Gyton MR, Chaplin AB. Synthesis and group 9 complexes of macrocyclic PCP and POCOP pincer ligands. Dalton Transactions (Cambridge, England : 2003). 49: 2087-2101. PMID 32031194 DOI: 10.1039/c9dt04835a  0.318
2020 Hood TM, Gyton MR, Chaplin AB. Synthesis and rhodium complexes of macrocyclic PNP and PONOP pincer ligands. Dalton Transactions (Cambridge, England : 2003). 49: 2077-2086. PMID 31912067 DOI: 10.1039/c9dt04474d  0.335
2019 Parker GL, Lau S, Leforestier B, Chaplin AB. Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study. European Journal of Inorganic Chemistry. 2019: 3791-3798. PMID 31598095 DOI: 10.1002/ejic.201900727  0.328
2019 Hood TM, Leforestier B, Gyton MR, Chaplin AB. Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes. Inorganic Chemistry. 58: 7593-7601. PMID 31117634 DOI: 10.1021/acs.inorgchem.9b00957  0.339
2019 Emerson-King J, Prokes I, Chaplin AB. Rhodium(III) Complexes Featuring Coordinated CF Appendages. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 6317-6319. PMID 30875135 DOI: 10.1002/chem.201901184  0.318
2019 Gyton MR, Hood TM, Chaplin AB. A convenient method for the generation of {Rh(PNP)} and {Rh(PONOP)} fragments: reversible formation of vinylidene derivatives. Dalton Transactions (Cambridge, England : 2003). 48: 2877-2880. PMID 30729961 DOI: 10.1039/c8dt05049j  0.379
2018 Gyton MR, Leforestier B, Chaplin AB. Rhodium(III) and Iridium(III) Complexes of a NHC-Based Macrocycle: Persistent Weak Agostic Interactions and Reactions with Dihydrogen. Organometallics. 37: 3963-3971. PMID 30449914 DOI: 10.1021/acs.organomet.8b00595  0.41
2018 Knighton RC, Emerson-King J, Rourke JP, Ohlin CA, Chaplin AB. Solution, Solid-State, and Computational Analysis of Agostic Interactions in a Coherent Set of Low-Coordinate Rhodium(III) and Iridium(III) Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 24: 4927-4938. PMID 29377308 DOI: 10.1002/chem.201705990  0.342
2018 Emerson-King J, Knighton RC, Gyton MR, Chaplin AB. Rotaxane synthesis exploiting the M(i)/M(iii) redox couple. Dalton Transactions (Cambridge, England : 2003). 46: 11645-11655. PMID 28835957 DOI: 10.1039/c7dt02648j  0.362
2017 Patchett R, Knighton RC, Mattock JD, Vargas A, Chaplin AB. Potassium Binding Adjacent to Cationic Transition-Metal Fragments: Unusual Heterobimetallic Adducts of a Calix[4]arene-Based Thione Ligand. Inorganic Chemistry. PMID 29094927 DOI: 10.1021/acs.inorgchem.7b02441  0.349
2017 Hauser SA, Emerson-King J, Habershon S, Chaplin AB. UV-light promoted C-H bond activation of benzene and fluorobenzenes by an iridium(i) pincer complex. Chemical Communications (Cambridge, England). 53: 3634-3636. PMID 28304407 DOI: 10.1039/C6Cc09807J  0.444
2017 Pike SD, Crimmin MR, Chaplin AB. Organometallic chemistry using partially fluorinated benzenes. Chemical Communications (Cambridge, England). 53: 3615-3633. PMID 28304406 DOI: 10.1039/c6cc09575e  0.694
2016 Patchett R, Chaplin AB. Coordination chemistry of a calix[4]arene-based NHC ligand: dinuclear complexes and comparison to I(i)Pr2Me2. Dalton Transactions (Cambridge, England : 2003). 45: 8945-55. PMID 27160544 DOI: 10.1039/c6dt01001f  0.37
2015 Hauser SA, Prokes I, Chaplin AB. Low-coordinate iridium NHC complexes derived from selective and reversible C-H bond activation of fluoroarenes. Chemical Communications (Cambridge, England). 51: 4425-8. PMID 25679455 DOI: 10.1039/c5cc00529a  0.436
2014 Wheatley JE, Ohlin CA, Chaplin AB. Solvent promoted reversible cyclometalation in a tethered NHC iridium complex. Chemical Communications (Cambridge, England). 50: 685-7. PMID 24281774 DOI: 10.1039/c3cc48015a  0.377
2013 Andrew RE, Chaplin AB. Synthesis, structure and dynamics of NHC-based palladium macrocycles. Dalton Transactions (Cambridge, England : 2003). 43: 1413-23. PMID 24201818 DOI: 10.1039/c3dt52578c  0.376
2012 Chaplin AB, Hooper JF, Weller AS, Willis MC. Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands. Journal of the American Chemical Society. 134: 4885-97. PMID 22324763 DOI: 10.1021/Ja211649A  0.636
2012 Hooper JF, Chaplin AB, González-Rodríguez C, Thompson AL, Weller AS, Willis MC. Aryl methyl sulfides as substrates for rhodium-catalyzed alkyne carbothiolation: arene functionalization with activating group recycling. Journal of the American Chemical Society. 134: 2906-9. PMID 22296656 DOI: 10.1021/Ja2108992  0.476
2011 Chaplin AB, Weller AS. A rhodium(III) complex of the linear diborazine H3B·NMe2BH2·NMe2H: an intermediate in the dehydrocoupling of H3B·NMe2H. Acta Crystallographica. Section C, Crystal Structure Communications. 67: m355-8. PMID 22051952 DOI: 10.1107/S0108270111043447  0.659
2011 Chaplin AB, Green JC, Weller AS. C-C activation in the solid state in an organometallic σ-complex. Journal of the American Chemical Society. 133: 13162-8. PMID 21736363 DOI: 10.1021/Ja2047599  0.566
2011 Sewell LJ, Chaplin AB, Weller AS. Hydroboration of an alkene by amine-boranes catalysed by a [Rh(PR3)2]+ fragment. Mechanistic insight and tandem hydroboration/dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 40: 7499-501. PMID 21713289 DOI: 10.1039/C1Dt10819K  0.567
2011 Johnson HC, Robertson AP, Chaplin AB, Sewell LJ, Thompson AL, Haddow MF, Manners I, Weller AS. Catching the first oligomerization event in the catalytic formation of polyaminoboranes: H3B·NMeHBH2·NMeH2 bound to iridium. Journal of the American Chemical Society. 133: 11076-9. PMID 21699193 DOI: 10.1021/Ja2040738  0.621
2011 Dallanegra R, Pilgrim BS, Chaplin AB, Donohoe TJ, Weller AS. Dehydrogenation of cyclic thioethers bound to a [Rh(diphosphine)]+ fragment. Dalton Transactions (Cambridge, England : 2003). 40: 6626-8. PMID 21611674 DOI: 10.1039/C1Dt10503E  0.574
2011 González-Rodríguez C, Pawley RJ, Chaplin AB, Thompson AL, Weller AS, Willis MC. Rhodium-catalyzed branched-selective alkyne hydroacylation: a ligand-controlled regioselectivity switch. Angewandte Chemie (International Ed. in English). 50: 5134-8. PMID 21506226 DOI: 10.1002/Anie.201100956  0.507
2011 Stevens CJ, Dallanegra R, Chaplin AB, Weller AS, Macgregor SA, Ward B, McKay D, Alcaraz G, Sabo-Etienne S. [Ir(PCy3)2(H)2(H2B-NMe2)]+ as a latent source of aminoborane: probing the role of metal in the dehydrocoupling of H3B⋅NMe2H and retrodimerisation of [H2BNMe2]2. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 3011-20. PMID 21322070 DOI: 10.1002/Chem.201002517  0.654
2011 Dallanegra R, Robertson AP, Chaplin AB, Manners I, Weller AS. Tuning the [L2Rh···H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes. Chemical Communications (Cambridge, England). 47: 3763-5. PMID 21293798 DOI: 10.1039/C0Cc05460G  0.544
2010 Sparkes HA, Chaplin AB, Weller AS, Howard JA. Bond catastrophes in rhodium complexes: experimental charge-density studies of [Rh(C7H8)(P(t)Bu3)Cl] and [Rh(C7H8)(PCy3)Cl]. Acta Crystallographica. Section B, Structural Science. 66: 503-14. PMID 20841918 DOI: 10.1107/S0108768110031496  0.532
2010 Sewell LJ, Chaplin AB, Abdalla JA, Weller AS. Reversible C-H activation of a P(t)Bu(i)Bu2 ligand to reveal a masked 12 electron [Rh(PR3)2]+ cation. Dalton Transactions (Cambridge, England : 2003). 39: 7437-9. PMID 20623070 DOI: 10.1039/C0Dt00449A  0.611
2010 Townsend NS, Chaplin AB, Abu Naser M, Thompson AL, Rees NH, Macgregor SA, Weller AS. Reactivity of the latent 12-electron fragment [Rh(PiBu3)2]+ with aryl bromides: aryl-Br and phosphine ligand C-H activation. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8376-89. PMID 20572181 DOI: 10.1002/Chem.201000554  0.674
2010 Hiney RM, Chaplin AB, Harmer J, Green JC, Weller AS. Using EPR to follow reversible dihydrogen addition to paramagnetic clusters of high hydride count: [Rh(6)(PCy(3))(6)H(12)](+) and [Rh(6)(PCy(3))(6)H(14)](+). Dalton Transactions (Cambridge, England : 2003). 39: 1726-33. PMID 20449414 DOI: 10.1039/B919209C  0.594
2010 Dallanegra R, Chaplin AB, Tsim J, Weller AS. Amino-borane oligomers bound to a Rh(I) metal fragment. Chemical Communications (Cambridge, England). 46: 3092-4. PMID 20424747 DOI: 10.1039/C003055D  0.636
2010 Chaplin AB, Weller AS. Amine- and dimeric amino-borane complexes of the {Rh(P(i)Pr3)2}+ fragment and their relevance to the transition-metal-mediated dehydrocoupling of amine-boranes. Inorganic Chemistry. 49: 1111-21. PMID 20052982 DOI: 10.1021/Ic9020542  0.669
2010 Chaplin AB, Weller AS. B-H activation at a rhodium(I) center: isolation of a bimetallic complex relevant to the transition-metal-catalyzed dehydrocoupling of amine-boranes. Angewandte Chemie (International Ed. in English). 49: 581-4. PMID 19937888 DOI: 10.1002/Anie.200905185  0.589
2009 Douglas TM, Chaplin AB, Weller AS, Yang X, Hall MB. Monomeric and oligomeric amine-borane sigma-complexes of rhodium. intermediates in the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 131: 15440-56. PMID 19785431 DOI: 10.1021/Ja906070R  0.66
2009 Dallanegra R, Chaplin AB, Weller AS. Bis(sigma-amine-borane) complexes: an unusual binding mode at a transition-metal center. Angewandte Chemie (International Ed. in English). 48: 6875-8. PMID 19688804 DOI: 10.1002/Anie.200903121  0.565
2009 Chaplin AB, Poblador-Bahamonde AI, Sparkes HA, Howard JA, Macgregor SA, Weller AS. Alkyl dehydrogenation in a Rh(I) complex via an isolated agostic intermediate. Chemical Communications (Cambridge, England). 244-6. PMID 19099083 DOI: 10.1039/B816739G  0.516
2008 Douglas TM, Chaplin AB, Weller AS. Amine-borane sigma-complexes of rhodium. relevance to the catalytic dehydrogenation of amine-boranes. Journal of the American Chemical Society. 130: 14432-3. PMID 18844358 DOI: 10.1021/Ja806582N  0.553
2007 Chaplin AB, Dyson PJ. Reactivity and catalytic activity of a robust ruthenium(II)-triphos complex. Inorganic Chemistry. 47: 381-90. PMID 18044884 DOI: 10.1021/IC701773A  0.372
2007 Scolaro C, Chaplin AB, Hartinger CG, Bergamo A, Cocchietto M, Keppler BK, Sava G, Dyson PJ. Tuning the hydrophobicity of ruthenium(II)-arene (RAPTA) drugs to modify uptake, biomolecular interactions and efficacy. Dalton Transactions (Cambridge, England : 2003). 5065-72. PMID 17992291 DOI: 10.1039/B705449A  0.33
2004 Chaplin AB, Harrison JA, Nielson AJ, Shen C, Waters JM. A case for linear agostic interactions: identification by DFT calculation in a complex of Ta containing a uniquely caged triphenylmethyl C-H hydrogen. Dalton Transactions (Cambridge, England : 2003). 2643-8. PMID 15514746 DOI: 10.1039/b405918b  0.375
Low-probability matches (unlikely to be authored by this person)
2016 Andrew RE, Storey CM, Chaplin AB. Well-defined coinage metal transfer agents for the synthesis of NHC-based nickel, rhodium and palladium macrocycles. Dalton Transactions (Cambridge, England : 2003). PMID 27157720 DOI: 10.1039/c6dt01263a  0.3
2020 Leforestier B, Gyton MR, Chaplin AB. Oxidative Addition of a Mechanically Entrapped C(sp)-C(sp) Bond to a Rhodium(I) Pincer Complex. Angewandte Chemie (International Ed. in English). 59: 23500-23504. PMID 32929831 DOI: 10.1002/anie.202009546  0.297
2020 Storey CM, Kalpokas A, Gyton MR, Krämer T, Chaplin AB. A shape changing tandem Rh(CNC) catalyst: preparation of bicyclo[4.2.0]octa-1,5,7-trienes from terminal aryl alkynes. Chemical Science. 11: 2051-2057. PMID 32180927 DOI: 10.1039/c9sc06153c  0.288
2018 Storey CM, Gyton MR, Andrew RE, Chaplin AB. Terminal alkyne coupling reactions through a ring: mechanistic insights and regiochemical switching. Angewandte Chemie (International Ed. in English). PMID 30004163 DOI: 10.1002/anie.201807028  0.283
2005 Chaplin AB, Harrison JA, Dyson PJ. Revisiting the electronic structure of phosphazenes. Inorganic Chemistry. 44: 8407-17. PMID 16270979 DOI: 10.1021/ic0511266  0.275
2016 Troadec T, Tan SY, Wedge CJ, Rourke JP, Unwin PR, Chaplin AB. One-Electron Oxidation of [M(P(t) Bu3 )2 ] (M=Pd, Pt): Isolation of Monomeric [Pd(P(t) Bu3 )2 ](+) and Redox-Promoted C-H Bond Cyclometalation. Angewandte Chemie (International Ed. in English). 55: 3754-7. PMID 26879233 DOI: 10.1002/Anie.201511467  0.264
2017 Emerson-King J, Hauser SA, Chaplin AB. C-F bond activation of perfluorinated arenes by a bioxazoline-derived N-heterocyclic carbene. Organic & Biomolecular Chemistry. 15: 787-789. PMID 28009924 DOI: 10.1039/c6ob02556k  0.26
2020 Hood TM, Chaplin AB. Reactions of Rh(PNP) pincer complexes with terminal alkynes: homocoupling through a ring or not at all. Dalton Transactions (Cambridge, England : 2003). 49: 16649-16652. PMID 33174892 DOI: 10.1039/d0dt03550e  0.256
2016 Andrew RE, González-Sebastián L, Chaplin AB. NHC-based pincer ligands: carbenes with a bite. Dalton Transactions (Cambridge, England : 2003). 45: 1299-305. PMID 26673868 DOI: 10.1039/c5dt04429d  0.252
2022 Parker GL, Van Lommel R, Roig N, Alonso M, Chaplin AB. Modulation of metal carbonyl stretching frequencies in the second coordination sphere through the internal Stark effect. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 36082961 DOI: 10.1002/chem.202202283  0.245
2024 Sinclair MJG, Roig N, Gyton MR, Tsoureas N, Cloke FGN, Alonso M, Chaplin AB. T-Shaped Palladium and Platinum {MNO} Nitrosyl Complexes. Inorganic Chemistry. PMID 38207212 DOI: 10.1021/acs.inorgchem.3c03434  0.239
2006 Ainscough EW, Brodie AM, Chaplin AB, O'Connor JM, Otter CA. Gold(I) and platinum(II) complexes with a new diphosphine ligand based on the cyclotriphosphazene platform. Dalton Transactions (Cambridge, England : 2003). 1264-6. PMID 16505903 DOI: 10.1039/b517309b  0.239
2007 Ainscough EW, Brodie AM, Chaplin AB, Derwahl A, Harrison JA, Otter CA. Conformational flexibility in 2,2'-Dioxybiphenyl-chloro-cyclotetraphosphazenes and its relevance to polyphosphazene analogues. Inorganic Chemistry. 46: 2575-83. PMID 17335275 DOI: 10.1021/ic062141t  0.218
2019 Gyton MR, Leforestier B, Chaplin AB. Rhodium(I) Pincer Complexes of Nitrous Oxide. Angewandte Chemie (International Ed. in English). 58: 15295-15298. PMID 31513331 DOI: 10.1002/anie.201908333  0.178
2013 Boyt SM, Chaplin AB. 2,6-Bis[1-(2,4,6-tri-methyl-phenyl-imino)-eth-yl]pyridine. Acta Crystallographica. Section E, Structure Reports Online. 70: o73. PMID 24855472 DOI: 10.1107/S1600536813033801  0.178
2015 Andrew RE, Chaplin AB. Synthesis and reactivity of NHC-based rhodium macrocycles. Inorganic Chemistry. 54: 312-22. PMID 25494305 DOI: 10.1021/ic5024828  0.177
2018 Simpson Q, Sinclair MJG, Lupton DW, Chaplin AB, Hooper JF. Oxidative Cross-Coupling of Boron and Antimony Nucleophiles via Palladium(I). Organic Letters. PMID 30192552 DOI: 10.1021/Acs.Orglett.8B01989  0.152
2024 Hood TM, Lau S, Chaplin AB. Capture of mechanically interlocked molecules by rhodium-mediated terminal alkyne dimerisation. Rsc Advances. 14: 7740-7744. PMID 38444978 DOI: 10.1039/d4ra00566j  0.12
2022 Sinclair MJG, Chaplin AB. Heterolytic carbon-iodine bond cleavage by a palladium(I) metalloradical. Dalton Transactions (Cambridge, England : 2003). 51: 11617-11619. PMID 35852934 DOI: 10.1039/d2dt02152h  0.112
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