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Alexander T. Radosevich, Ph.D

Affiliations:	2011-2016	Chemistry	Pennsylvania State University, State College, PA, United States
	2016-	Chemistry	Massachusetts Institute of Technology, Cambridge, MA, United States

Area:

Synthetic methodology, catalysis

Website:

http://web.mit.edu/radosevichlab/index.html

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"Alexander Radosevich"

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Parents

Olaf G. Wiest	research assistant	2002	Notre Dame
F. Dean Toste	grad student	2007	UC Berkeley
(Application of rhenium- and vanadium -oxo complexes as catalysts in organic synthesis.)
Daniel G. Nocera	post-doc	2007-2010	MIT

Children

Samantha Damiano	grad student	2012-2014	Penn State
Kyle D. Reichl	grad student	2010-2016	Penn State
Rixin Wang	post-doc		Penn State
Allen J. Pistner	post-doc	2015-	Penn State

Collaborators

BETA: Related publications

Publications

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Hu S, Radosevich AT. (2024) Electrophilic C(sp2)-H Cyanation with Inorganic Cyanate (OCN-) by PIII/PV=O-Catalyzed Phase Transfer Activation. Angewandte Chemie (International Ed. in English). e202409854
Roth D, Radosevich AT, Greb L. (2023) Reversible Oxidative Addition of Nonactivated C-H Bonds to Structurally Constrained Phosphenium Ions. Journal of the American Chemical Society
Li G, Lavagnino MN, Ali SZ, et al. (2022) Tandem C/N-Difunctionalization of Nitroarenes: Reductive Amination and Annulation by a Ring Expansion/Contraction Sequence. Journal of the American Chemical Society
Bruch QJ, Tanushi A, Müller P, et al. (2022) Metal-Ligand Role Reversal: Hydride-Transfer Catalysis by a Functional Phosphorus Ligand with a Spectator Metal. Journal of the American Chemical Society
Drance MJ, Tanushi A, Radosevich AT. (2022) Two-Site O-H Addition to an Iridium Complex Featuring a Nonspectator Tricoordinate Phosphorus Ligand. Journal of the American Chemical Society. 144: 20243-20248
Hong SY, Radosevich AT. (2022) Chemoselective Primary Amination of Aryl Boronic Acids by P/P═O-Catalysis: Synthetic Capture of the Transient Nef Intermediate HNO. Journal of the American Chemical Society
Li G, Kanda Y, Hong SY, et al. (2022) Enabling Reductive C-N Cross-Coupling of Nitroalkanes and Boronic Acids by Steric Design of P(III)/P(V)═O Catalysts. Journal of the American Chemical Society. 144: 8242-8248
Lipshultz JM, Radosevich AT. (2021) Uniting Amide Synthesis and Activation by P/P-Catalyzed Serial Condensation: Three-Component Assembly of 2-Amidopyridines. Journal of the American Chemical Society
Li G, Miller SP, Radosevich AT. (2021) P/P═O-Catalyzed Intermolecular N-N Bond Formation: Cross-Selective Reductive Coupling of Nitroarenes and Anilines. Journal of the American Chemical Society
Li G, Te Grotenhuis C, Radosevich AT. (2021) Reductive C-N Coupling by P/P=O-Catalysis. Trends in Chemistry. 3: 72-73

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