Apparao Draksharapu, Ph.D. - Publications

Affiliations: 
2018- Chemistry Indian Institute of Technology Kanpur, Kanpur, Uttar Pradesh, India 
Area:
Bio-Inorganic Chemistry
Website:
https://draksharapu.weebly.com/

52 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Kumar R, Maji A, Biswas B, Draksharapu A. Amphoteric reactivity of a putative Cu(II)-CPBA intermediate. Dalton Transactions (Cambridge, England : 2003). PMID 38426906 DOI: 10.1039/d3dt03747a  0.354
2023 Gupta S, Arora P, Kumar R, Awasthi A, Chandra B, Eerlapally R, Xiong J, Guo Y, Que LJ, Draksharapu A. Formation of a Reactive [Mn(III)-O-Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes. Angewandte Chemie (International Ed. in English). e202316378. PMID 37997195 DOI: 10.1002/anie.202316378  0.658
2023 Awasthi A, Mallojjala SC, Kumar R, Eerlapally R, Hirschi JS, Draksharapu A. Altering the Localization of an Unpaired Spin in a Formal Ni(V) Species. Chemistry (Weinheim An Der Bergstrasse, Germany). e202302824. PMID 37903027 DOI: 10.1002/chem.202302824  0.402
2023 Kumar R, Ahsan F, Awasthi A, Swart M, Draksharapu A. Generation of Ru(III)-hypochlorite with resemblance to the heme-dependent haloperoxidase enzyme. Dalton Transactions (Cambridge, England : 2003). PMID 37609762 DOI: 10.1039/d3dt02028b  0.386
2023 Arora P, Gupta S, Vechalapu SK, Kumar R, Awasthi A, Senthil S, Khanna S, Allimuthu D, Draksharapu A. Mn(II) Polypyridyl Complexes: Precursors to High Valent Mn(V)=O Species and Inhibitors of Cancer Cell Proliferation. Chemistry (Weinheim An Der Bergstrasse, Germany). e202301506. PMID 37415318 DOI: 10.1002/chem.202301506  0.359
2023 Eerlapally R, Gupta S, Awasthi A, Kumar R, Draksharapu A. Spectroscopic characterization and the reactivity of a high valent (L)Cu(III) species supported by a proline-based pseudopeptide. Dalton Transactions (Cambridge, England : 2003). PMID 37294205 DOI: 10.1039/d3dt00697b  0.698
2023 Kumar R, Keshri R, Prodhan K, Shaikh K, Draksharapu A. A tetranuclear Mn-diamond core complex as a functional mimic of both catechol oxidase and phenoxazinone synthase enzymes. Dalton Transactions (Cambridge, England : 2003). PMID 37226832 DOI: 10.1039/d3dt00761h  0.583
2022 Awasthi A, Leach IF, Engbers S, Kumar R, Eerlapally R, Gupta S, Klein JEMN, Draksharapu A. Formation and Reactivity of a Fleeting Ni(III) Bisphenoxyl Diradical Species. Angewandte Chemie (International Ed. in English). PMID 35978531 DOI: 10.1002/anie.202211345  0.725
2022 Kumar R, Awasthi A, Gupta S, Eerlapally R, Draksharapu A. Spectroscopic characterization of a Ru(III)-OCl intermediate: a structural mimic of haloperoxidase enzymes. Dalton Transactions (Cambridge, England : 2003). PMID 35968730 DOI: 10.1039/d2dt01947g  0.712
2022 Aldous L, Comba P, DeBeer S, Dey A, Draksharapu A, Duboc C, Itoh S, Karlin K, Kundu S, López Domene R, Maréchal JD, Mazumdar S, Mukherjee R, Parker D, Pordea A, et al. Small molecule activation and synthetic analogues: general discussion. Faraday Discussions. PMID 35531924 DOI: 10.1039/d2fd90012b  0.465
2022 Anilkumar A, Ash P, Chakravarty AR, Comba P, DeBeer S, Dey A, Draksharapu A, Goswami D, Itoh S, Karlin K, Lakshmi KV, Mazumdar S, Pantazis D, Parker D, Que L, et al. Electron transfer, spectroscopy and theory: general discussion. Faraday Discussions. PMID 35510729 DOI: 10.1039/d2fd90013k  0.483
2021 Que L, Sheng Y, Abelson CS, Prakash J, Draksharapu A, Young VG. Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex. Angewandte Chemie (International Ed. in English). PMID 34292639 DOI: 10.1002/anie.202108309  0.726
2020 Que L, Draksharapu A, Xu S. CeIV- and HClO4-Promoted Assembly of an Fe2IV(µ-O)2 Diamond Core from its Monomeric FeIV=O Precursor at Room Temperature. Angewandte Chemie (International Ed. in English). PMID 32902902 DOI: 10.1002/Anie.202010027  0.692
2020 Banerjee S, Draksharapu A, Crossland P, Fan R, Guo Y, Swart M, Que L. Sc3+-promoted O-O bond cleavage of a (μ-1,2-peroxo)diiron(III) species formed from an iron(II) precursor and O2 to generate a complex with an FeIV2(μ-O)2 core. Journal of the American Chemical Society. PMID 32017545 DOI: 10.1021/Jacs.9B12081  0.688
2019 Xu S, Draksharapu A, Rasheed W, Que L. Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate to Form a Potent FeV=O Oxidant with Heme Compound I-Like Reactivity. Journal of the American Chemical Society. PMID 31513741 DOI: 10.1021/Jacs.9B08442  0.809
2019 Dantignana V, Serrano-Plana J, Draksharapu A, Magallón C, Banerjee S, Fan R, Gamba I, Guo Y, Que L, Costas M, Company A. Spectroscopic and reactivity comparisons between nonheme oxoiron(IV) and oxoiron(V) species bearing the same ancillary ligand. Journal of the American Chemical Society. PMID 31469954 DOI: 10.1021/Jacs.9B05758  0.683
2019 Banerjee S, Rasheed W, Fan R, Draksharapu A, Oloo W, Guo Y, Que L. NMR Reveals That a Highly Reactive Nonheme Fe(IV)=O Complex Retains its 6- Coordinate Geometry and S = 1 State in Solution. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31059593 DOI: 10.1002/Chem.201902048  0.813
2018 Prakash J, Sheng Y, Draksharapu A, Klein JEMN, Cramer CJ, Que L. Facile Conversion of syn-[Fe (O)(TMC)] into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism. Angewandte Chemie (International Ed. in English). PMID 30556289 DOI: 10.1002/Anie.201811454  0.733
2018 Chen J, Draksharapu A, Angelone D, Unjaroen D, Padamati SK, Hage R, Swart M, Duboc C, Browne WR. HO Oxidation by Fe-OOH Intermediates and Its Effect on Catalytic Efficiency. Acs Catalysis. 8: 9665-9674. PMID 30319886 DOI: 10.1021/Acscatal.8B02326  0.685
2018 Rasheed W, Draksharapu A, Banerjee S, Young VG, Fan R, Guo Y, Ozerov M, Nehrkorn J, Krzystek J, Telser J, Que L. Crystallographic evidence for a sterically induced ferryl tilt in a non-heme oxoiron(IV) complex that makes it a better oxidant. Angewandte Chemie (International Ed. in English). PMID 29882390 DOI: 10.1002/Anie.201804836  0.822
2018 Kal S, Draksharapu A, Que L. Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene. Journal of the American Chemical Society. PMID 29618199 DOI: 10.1021/Jacs.8B01435  0.666
2018 Fan R, Serrano-Plana J, Oloo WN, Draksharapu A, Delgado-Pinar E, Company A, Martin-Diaconescu V, Borrell M, Lloret-Fillol J, García-España E, Guo Y, Bominaar EL, Que L, Costas M, Münck E. Spectroscopic and DFT Characterization of a Highly Reactive Nonheme Fe-oxo Intermediate. Journal of the American Chemical Society. PMID 29463085 DOI: 10.1021/Jacs.7B11400  0.75
2018 Browne WR, Chen J, Draksharapu A, Gruden M, Stepanovic S. A non-heme iron photocatalyst for light driven aerobic oxidation of methanol. Angewandte Chemie (International Ed. in English). PMID 29334586 DOI: 10.1002/Anie.201712678  0.644
2017 Zhou A, Crossland PM, Draksharapu A, Jasniewski AJ, Kleespies ST, Que L. Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 29218640 DOI: 10.1007/S00775-017-1517-5  0.687
2017 Que L, Klein JEMN, Draksharapu A, Shokri A, Cramer CJ. On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29205555 DOI: 10.1002/Chem.201704977  0.68
2017 Serrano-Plana J, Acuña-Parés F, Dantignana V, Oloo WN, Castillo E, Draksharapu A, Whiteoak CJ, Martin-Diaconescu V, Basallote MG, Luis JM, Que L, Costas M, Company A. Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29193378 DOI: 10.1002/Chem.201704851  0.682
2017 Chen J, Draksharapu A, Harvey E, Rasheed W, Que L, Browne WR. Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes. Chemical Communications (Cambridge, England). PMID 29099136 DOI: 10.1039/C7Cc07452B  0.816
2017 Draksharapu A, Rasheed W, Klein JEMN, Que L. Facile and reversible formation of Fe(III)-O-Ce(IV) adducts from nonheme oxoiron(IV) complexes and Ce(III). Angewandte Chemie (International Ed. in English). PMID 28598024 DOI: 10.1002/Anie.201704322  0.813
2017 Padamati SK, Angelone D, Draksharapu A, Primi G, Martin DJ, Tromp M, Swart M, Browne WR. Transient Formation and Reactivity of a High Valent Nickel(IV) Oxido Complex. Journal of the American Chemical Society. PMID 28581745 DOI: 10.1021/Jacs.7B04158  0.706
2017 Pattanayak S, Jasniewski AJ, Rana A, Draksharapu A, Singh KK, Weitz A, Hendrich M, Que L, Dey A, Sen Gupta S. Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with Fe(V)═O and Fe(IV)═O Units. Inorganic Chemistry. PMID 28481521 DOI: 10.1021/Acs.Inorgchem.7B00448  0.676
2016 Zhou A, Prakash J, Rohde GT, Klein JE, Kleespies ST, Draksharapu A, Fan R, Guo Y, Cramer CJ, Que L. The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [Fe(IV)(Oanti/syn)(TMC)](2+) Isomers. Inorganic Chemistry. PMID 28001379 DOI: 10.1021/Acs.Inorgchem.6B02417  0.732
2016 Corona T, Draksharapu A, Padamati SK, Gamba I, Martin-Diaconescu V, Acuña-Parés F, Browne WR, Company A. Rapid hydrogen and oxygen atom transfer by a high-valent nickel-oxygen species. Journal of the American Chemical Society. PMID 27598293 DOI: 10.1021/Jacs.6B07544  0.711
2016 Padamati SK, Draksharapu A, Unjaroen D, Browne WR. Conflicting Role of Water in the Activation of H2O2 and the Formation and Reactivity of Non-Heme Fe(III)-OOH and Fe(III)-O-Fe(III) Complexes at Room Temperature. Inorganic Chemistry. PMID 27074109 DOI: 10.1021/Acs.Inorgchem.5B02976  0.685
2015 Drienovská I, Rioz-Martínez A, Draksharapu A, Roelfes G. Novel artificial metalloenzymes by in vivo incorporation of metal-binding unnatural amino acids. Chemical Science. 6: 770-776. PMID 28936318 DOI: 10.1039/C4Sc01525H  0.395
2015 Draksharapu A, Angelone D, Quesne MG, Padamati SK, Gómez L, Hage R, Costas M, Browne WR, de Visser SP. Identification and Spectroscopic Characterization of Nonheme Iron(III) Hypochlorite Intermediates. Angewandte Chemie (Weinheim An Der Bergstrasse, Germany). 127: 4431-4435. PMID 27478260 DOI: 10.1002/ange.201411995  0.642
2015 Draksharapu A, Codolà Z, Gómez L, Lloret-Fillol J, Browne WR, Costas M. Spectroscopic Analyses on Reaction Intermediates Formed during Chlorination of Alkanes with NaOCl Catalyzed by a Nickel Complex. Inorganic Chemistry. PMID 26540133 DOI: 10.1021/Acs.Inorgchem.5B01463  0.697
2015 Corona T, Pfaff FF, Acuña-Parés F, Draksharapu A, Whiteoak CJ, Martin-Diaconescu V, Lloret-Fillol J, Browne WR, Ray K, Company A. Reactivity of a Nickel(II) Bis(amidate) Complex with meta-Chloroperbenzoic Acid: Formation of a Potent Oxidizing Species. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26311073 DOI: 10.1002/Chem.201501841  0.802
2015 Draksharapu A, Angelone D, Quesne MG, Padamati SK, Gómez L, Hage R, Costas M, Browne WR, de Visser SP. Identification and spectroscopic characterization of nonheme iron(III) hypochlorite intermediates. Angewandte Chemie (International Ed. in English). 54: 4357-61. PMID 25663379 DOI: 10.1002/Anie.201411995  0.675
2015 Draksharapu A, Boersma AJ, Browne WR, Roelfes G. Characterisation of the interactions between substrate, copper(II) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis. Dalton Transactions (Cambridge, England : 2003). 44: 3656-63. PMID 25491950 DOI: 10.1039/C4Dt02734E  0.637
2015 Draksharapu A, Boersma AJ, Leising M, Meetsma A, Browne WR, Roelfes G. Binding of copper(II) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis. Dalton Transactions (Cambridge, England : 2003). 44: 3647-55. PMID 25476597 DOI: 10.1039/C4Dt02733G  0.651
2015 Draksharapu A, Boersma AJ, Browne WR, Roelfes G. Characterisation of the interactions between substrate, copper(ii) complex and DNA and their role in rate acceleration in DNA-based asymmetric catalysis Dalton Transactions. 44: 3656-3663. DOI: 10.1039/c4dt02734e  0.539
2015 Draksharapu A, Boersma AJ, Leising M, Meetsma A, Browne WR, Roelfes G. Binding of copper(ii) polypyridyl complexes to DNA and consequences for DNA-based asymmetric catalysis Dalton Transactions. 44: 3647-3655. DOI: 10.1039/c4dt02733g  0.538
2014 Pap JS, Draksharapu A, Giorgi M, Browne WR, Kaizer J, Speier G. Stabilisation of μ-peroxido-bridged Fe(III) intermediates with non-symmetric bidentate N-donor ligands Chemical Communications. 50: 1326-1329. PMID 24343416 DOI: 10.1039/C3Cc48196D  0.716
2014 Angelone D, Draksharapu A, Browne WR, Choudhuri MMR, Crutchley RJ, Xu X, Doyle MP. Dinuclear compounds without a metal-metal bond. Dirhodium(III,III) carboxamidates Inorganica Chimica Acta. 424: 235-240. DOI: 10.1016/J.Ica.2014.09.006  0.663
2013 Abdolahzadeh S, Boyle NM, Draksharapu A, Dennis AC, Hage R, De Boer JW, Browne WR. Off-line reaction monitoring of the oxidation of alkenes in water using drop coating deposition Raman (DCDR) spectroscopy Analyst. 138: 3163-3171. PMID 23589804 DOI: 10.1039/C3An00330B  0.575
2013 Brennan C, Draksharapu A, Browne WR, McGarvey JJ, Vos JG, Pryce MT. Unexpected reversible pyrazine based methylation in a Ru(II) complex bearing a pyrazin-2'-yl-1,2,4-triazolato ligand and its effect on acid/base and photophysical properties. Dalton Transactions (Cambridge, England : 2003). 42: 2546-55. PMID 23212175 DOI: 10.1039/C2Dt31589K  0.69
2013 McGarvey JJ, Draksharapu A, Browne WR. Spectroscopy, photophysics and structural dynamics in metal-Centred species, some recent investigations: From spin-Crossover complexes and oxygen activation to photocatalysis Spectroscopic Properties of Inorganic and Organometallic Compounds. 44: 68-94. DOI: 10.1039/9781849737791-00068  0.589
2013 Halpin Y, Logtenberg H, Cleary L, Schenk S, Schulz M, Draksharapu A, Browne WR, Vos JG. An electrochemical and raman spectroscopy study of the surface behaviour of mononuclear ruthenium and osmium polypyridyl complexes based on pyridyl- and thiophene-based linkers European Journal of Inorganic Chemistry. 4291-4299. DOI: 10.1002/Ejic.201300366  0.781
2012 Draksharapu A, Li Q, Roelfes G, Browne WR. Photo-induced oxidation of [Fe(II)(N4Py)CH3CN] and related complexes. Dalton Transactions (Cambridge, England : 2003). 41: 13180-90. PMID 23011515 DOI: 10.1039/C2Dt30392B  0.688
2012 Draksharapu A, Li Q, Logtenberg H, van den Berg TA, Meetsma A, Killeen JS, Feringa BL, Hage R, Roelfes G, Browne WR. Ligand exchange and spin state equilibria of Fe(II)(N4Py) and related complexes in aqueous media. Inorganic Chemistry. 51: 900-13. PMID 22220629 DOI: 10.1021/Ic201879B  0.812
2012 Draksharapu A, Li Q, Roelfes G, Browne WR. Photo-induced oxidation of [Fe II(N4Py)CH 3CN] and related complexes Dalton Transactions. 41: 13180-13190. DOI: 10.1039/c2dt30392b  0.606
2011 Schulz M, Hirschmann J, Draksharapu A, Singh Bindra G, Soman S, Paul A, Groarke R, Pryce MT, Rau S, Browne WR, Vos JG. Reinvestigating 2,5-di(pyridin-2-yl)pyrazine ruthenium complexes: selective deuteration and Raman spectroscopy as tools to probe ground and excited-state electronic structure in homo- and heterobimetallic complexes. Dalton Transactions (Cambridge, England : 2003). 40: 10545-52. PMID 21850330 DOI: 10.1039/C1Dt10960J  0.698
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