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Carsten Milsmann, Ph.D. - Publications

Affiliations: 
2010-2011 Chemistry Cornell University, Ithaca, NY, United States 
 2011-2014 Chemistry Princeton University, Princeton, NJ 
 2014- Chemistry West Virginia University, Morgantown, WV, United States 
Area:
Inorganic Chemistry, Photochemistry
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59 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Valerio LR, Hakey BM, Leary DC, Stockdale E, Brennessel WW, Milsmann C, Matson EM. Synthesis and Characterization of Isostructural Th(IV) and U(IV) Pyridine Dipyrrolide Complexes. Inorganic Chemistry. PMID 38377955 DOI: 10.1021/acs.inorgchem.3c04391  0.697
2023 Leary DC, Zhang Y, Rodriguez JG, Akhmedov NG, Petersen JL, Dolinar BS, Milsmann C. Organometallic Intermediates in the Synthesis of Photoluminescent Zirconium and Hafnium Complexes with Pyridine Dipyrrolide Ligands. Organometallics. 42: 1220-1231. PMID 37324448 DOI: 10.1021/acs.organomet.3c00058  0.47
2022 Leary DC, Martinez JC, Akhmedov NG, Petersen JL, Milsmann C. Long-lived photoluminescence from an eight-coordinate zirconium(IV) complex with four 2-(2'-pyridyl)pyrrolide ligands. Chemical Communications (Cambridge, England). 58: 11917-11920. PMID 36196958 DOI: 10.1039/d2cc04912k  0.788
2022 Gowda AS, Lee TS, Rosko MC, Petersen JL, Castellano FN, Milsmann C. Long-Lived Photoluminescence of Molecular Group 14 Compounds through Thermally Activated Delayed Fluorescence. Inorganic Chemistry. PMID 35507416 DOI: 10.1021/acs.inorgchem.2c00182  0.531
2022 Hakey BM, Leary DC, Lopez LM, Valerio LR, Brennessel WW, Milsmann C, Matson EM. Synthesis and Characterization of Pyridine Dipyrrolide Uranyl Complexes. Inorganic Chemistry. 61: 6182-6192. PMID 35420825 DOI: 10.1021/acs.inorgchem.2c00348  0.822
2021 Hakey BM, Leary DC, Xiong J, Harris CF, Darmon JM, Petersen JL, Berry JF, Guo Y, Milsmann C. High Magnetic Anisotropy of a Square-Planar Iron-Carbene Complex. Inorganic Chemistry. PMID 34431660 DOI: 10.1021/acs.inorgchem.1c01860  0.813
2021 Yang M, Sheykhi S, Zhang Y, Milsmann C, Castellano FN. Low power threshold photochemical upconversion using a zirconium(iv) LMCT photosensitizer. Chemical Science. 12: 9069-9077. PMID 34276936 DOI: 10.1039/d1sc01662h  0.636
2020 Zhang Y, Leary DC, Belldina AM, Petersen JL, Milsmann C. Effects of Ligand Substitution on the Optical and Electrochemical Properties of (Pyridinedipyrrolide)zirconium Photosensitizers. Inorganic Chemistry. PMID 32975946 DOI: 10.1021/acs.inorgchem.0c02343  0.399
2020 Đ PMN, Akhmedov NG, Petersen JL, Dolinar BS, Milsmann C. Photochemical synthesis of a zirconium cyclobutadienyl complex. Chemical Communications (Cambridge, England). PMID 32286584 DOI: 10.1039/D0Cc01104E  0.456
2020 Zhang Y, Lee TS, Favale JM, Leary DC, Petersen JL, Scholes GD, Castellano FN, Milsmann C. Delayed fluorescence from a zirconium(IV) photosensitizer with ligand-to-metal charge-transfer excited states. Nature Chemistry. PMID 32203439 DOI: 10.1038/S41557-020-0430-7  0.659
2019 Hakey BM, Darmon JM, Akhmedov NG, Petersen JL, Milsmann C. Reactivity of Pyridine Dipyrrolide Iron(II) Complexes with Organic Azides: C-H Amination and Iron Tetrazene Formation. Inorganic Chemistry. PMID 31364852 DOI: 10.1021/Acs.Inorgchem.9B01560  0.838
2019 Zhang Y, Akhmedov NG, Petersen JL, Milsmann C. Photoluminescence of Seven-Coordinate Zirconium and Hafnium Complexes with 2,2'-Pyridylpyrrolide Ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30620447 DOI: 10.1002/Chem.201804671  0.511
2019 Hakey BM, Darmon JM, Zhang Y, Petersen JL, Milsmann C. Synthesis and Electronic Structure of Neutral Square-Planar High-Spin Iron(II) Complexes Supported by a Dianionic Pincer Ligand. Inorganic Chemistry. PMID 30608668 DOI: 10.1021/Acs.Inorgchem.8B02730  0.845
2018 Zhang Y, Lee TS, Petersen JL, Milsmann C. A Zirconium Photosensitizer with a Long-Lived Excited State: Mechanistic Insight into Photo-Induced Single Electron Transfer. Journal of the American Chemical Society. PMID 29671586 DOI: 10.1021/Jacs.8B00742  0.471
2018 Thakellapalli H, Farajidizaji B, Li S, Heller JC, Zhang Y, Akhmedov NG, Milsmann C, Petersen JL, Wang KK. Synthesis of a Cyclophane Bearing Two Benz[a]anthracene Units Connected at 5 and 7 Positions with Two Naphth-1,4-diyl Groups. The Journal of Organic Chemistry. PMID 29377690 DOI: 10.1021/Acs.Joc.7B03081  0.375
2018 Gowda AS, Petersen JL, Milsmann C. Redox Chemistry of Bis(pyrrolyl)pyridine Chromium and Molybdenum Complexes: An Experimental and Density Functional Theoretical Study. Inorganic Chemistry. PMID 29376653 DOI: 10.1021/Acs.Inorgchem.7B02809  0.546
2018 Zhang Y, Petersen JL, Milsmann C. Photochemical C–C Bond Formation in Luminescent Zirconium Complexes with CNN Pincer Ligands Organometallics. 37: 4488-4499. DOI: 10.1021/Acs.Organomet.8B00388  0.54
2017 Li S, Aljhdli M, Thakellapalli H, Farajidizaji B, Zhang Y, Akhmedov NG, Milsmann C, Popp BV, Wang KK. Synthesis and Structure of a Functionalized [9]Cycloparaphenylene Bearing Three Indeno[2,1-a]fluorene-11,12-dione-2,9-diyl Units. Organic Letters. PMID 28727459 DOI: 10.1021/Acs.Orglett.7B01866  0.377
2016 Zhang Y, Petersen JL, Milsmann C. A Luminescent Zirconium(IV) Complex as a Molecular Photosensitizer for Visible Light Photoredox Catalysis. Journal of the American Chemical Society. PMID 27643820 DOI: 10.1021/Jacs.6B05934  0.535
2014 Milsmann C, Semproni SP, Chirik PJ. N-N bond cleavage of 1,2-diarylhydrazines and N-H bond formation via H-atom transfer in vanadium complexes supported by a redox-active ligand. Journal of the American Chemical Society. 136: 12099-107. PMID 25066657 DOI: 10.1021/Ja5062196  0.8
2014 Semproni SP, Milsmann C, Chirik PJ. Four-coordinate cobalt pincer complexes: electronic structure studies and ligand modification by homolytic and heterolytic pathways. Journal of the American Chemical Society. 136: 9211-24. PMID 24897302 DOI: 10.1021/Ja504334A  0.827
2014 Russell SK, Hoyt JM, Bart SC, Milsmann C, Stieber SCE, Semproni SP, Debeer S, Chirik PJ. Synthesis, electronic structure and reactivity of bis(imino)pyridine iron carbene complexes: Evidence for a carbene radical Chemical Science. 5: 1168-1174. DOI: 10.1039/C3Sc52450G  0.852
2013 Yu RP, Darmon JM, Milsmann C, Margulieux GW, Stieber SC, DeBeer S, Chirik PJ. Catalytic hydrogenation activity and electronic structure determination of bis(arylimidazol-2-ylidene)pyridine cobalt alkyl and hydride complexes. Journal of the American Chemical Society. 135: 13168-84. PMID 23968297 DOI: 10.1021/Ja406608U  0.804
2013 Atienza CC, Milsmann C, Semproni SP, Turner ZR, Chirik PJ. Reversible carbon-carbon bond formation induced by oxidation and reduction at a redox-active cobalt complex. Inorganic Chemistry. 52: 5403-17. PMID 23594241 DOI: 10.1021/Ic400352R  0.81
2013 Semproni SP, Knobloch DJ, Milsmann C, Chirik PJ. Redox-induced N2 hapticity switching in zirconocene dinitrogen complexes. Angewandte Chemie (International Ed. in English). 52: 5372-6. PMID 23589359 DOI: 10.1002/Anie.201301800  0.777
2013 Tondreau AM, Stieber SC, Milsmann C, Lobkovsky E, Weyhermüller T, Semproni SP, Chirik PJ. Oxidation and reduction of bis(imino)pyridine iron dinitrogen complexes: evidence for formation of a chelate trianion. Inorganic Chemistry. 52: 635-46. PMID 23268722 DOI: 10.1021/Ic301675T  0.842
2013 Schneider CJ, Cashion JD, Chilton NF, Etrillard C, Fuentealba M, Howard JAK, Létard JF, Milsmann C, Moubaraki B, Sparkes HA, Batten SR, Murray KS. Spin crossover in a 3,5-bis(2-pyridyl)-1,2,4-triazolate-bridged dinuclear iron(II) complex [{Fe(NCBH3)(py)}2-(μ-L 1)2] - Powder versus single crystal study European Journal of Inorganic Chemistry. 850-864. DOI: 10.1002/Ejic.201201075  0.454
2012 E Stieber SC, Milsmann C, Hoyt JM, Turner ZR, Finkelstein KD, Wieghardt K, Debeer S, Chirik PJ. Bis(imino)pyridine Iron Dinitrogen Compounds Revisited: Differences in Electronic Structure Between Four- and Five-Coordinate Derivatives. Organometallics. 31: 2275-2285. PMID 22675236 DOI: 10.1021/Om201212M  0.843
2012 Milsmann C, Turner ZR, Semproni SP, Chirik PJ. Azo N=N bond cleavage with a redox-active vanadium compound involving metal-ligand cooperativity. Angewandte Chemie (International Ed. in English). 51: 5386-90. PMID 22514017 DOI: 10.1002/Anie.201201085  0.804
2012 Semproni SP, Milsmann C, Chirik PJ. Structure and reactivity of a hafnocene μ-nitrido prepared from dinitrogen cleavage. Angewandte Chemie (International Ed. in English). 51: 5213-6. PMID 22489093 DOI: 10.1002/Anie.201201361  0.761
2012 Stieber SC, Milsmann C, Hoyt JM, Turner ZR, Finkelstein KD, Wieghardt K, DeBeer S, Chirik PJ. Bis(imino)pyridine iron dinitrogen compounds revisited: differences in electronic structure between four- and five-coordinate derivatives. Inorganic Chemistry. 51: 3770-85. PMID 22394054 DOI: 10.1021/Ic202750N  0.857
2012 Tondreau AM, Atienza CCH, Darmon JM, Milsmann C, Hoyt HM, Weller KJ, Nye SA, Lewis KM, Boyer J, Delis JGP, Lobkovsky E, Chirik PJ. Synthesis, electronic structure, and alkene hydrosilylation activity of terpyridine and bis(imino)pyridine iron dialkyl complexes Organometallics. 31: 4886-4893. DOI: 10.1021/Om3004527  0.833
2012 Semproni SP, Milsmann C, Chirik PJ. Side-on dinitrogen complexes of titanocenes with disubstituted cyclopentadienyl ligands: Synthesis, structure, and spectroscopic characterization Organometallics. 31: 3672-3682. DOI: 10.1021/Om300156Z  0.789
2011 Bowman AC, Milsmann C, Bill E, Turner ZR, Lobkovsky E, DeBeer S, Wieghardt K, Chirik PJ. Synthesis and electronic structure determination of N-alkyl-substituted bis(imino)pyridine iron imides exhibiting spin crossover behavior. Journal of the American Chemical Society. 133: 17353-69. PMID 21985461 DOI: 10.1021/Ja205736M  0.849
2011 Hojilla Atienza CC, Milsmann C, Lobkovsky E, Chirik PJ. Synthesis, electronic structure, and ethylene polymerization activity of bis(imino)pyridine cobalt alkyl cations. Angewandte Chemie (International Ed. in English). 50: 8143-7. PMID 21692158 DOI: 10.1002/Anie.201102825  0.642
2011 Tondreau AM, Milsmann C, Lobkovsky E, Chirik PJ. Oxidation and reduction of bis(imino)pyridine iron dicarbonyl complexes. Inorganic Chemistry. 50: 9888-95. PMID 21667935 DOI: 10.1021/Ic200730K  0.837
2011 Russell SK, Milsmann C, Lobkovsky E, Weyhermüller T, Chirik PJ. Synthesis, electronic structure, and catalytic activity of reduced bis(aldimino)pyridine iron compounds: experimental evidence for ligand participation. Inorganic Chemistry. 50: 3159-69. PMID 21395246 DOI: 10.1021/Ic102186Q  0.747
2011 Gass IA, Gartshore CJ, Lupton DW, Moubaraki B, Nafady A, Bond AM, Boas JF, Cashion JD, Milsmann C, Wieghardt K, Murray KS. Anion dependent redox changes in iron bis-terdentate nitroxide {NNO} chelates. Inorganic Chemistry. 50: 3052-64. PMID 21384832 DOI: 10.1021/Ic102588H  0.67
2011 Hojilla Atienza CC, Milsmann C, Lobkovsky E, Chirik PJ. Inside Cover: Synthesis, Electronic Structure, and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations (Angew. Chem. Int. Ed. 35/2011) Angewandte Chemie International Edition. 50: 7956-7956. DOI: 10.1002/Anie.201104185  0.598
2011 Hojilla Atienza CC, Milsmann C, Lobkovsky E, Chirik PJ. Innentitelbild: Synthesis, Electronic Structure, and Ethylene Polymerization Activity of Bis(imino)pyridine Cobalt Alkyl Cations (Angew. Chem. 35/2011) Angewandte Chemie. 123: 8104-8104. DOI: 10.1002/Ange.201104185  0.606
2010 Tondreau AM, Milsmann C, Patrick AD, Hoyt HM, Lobkovsky E, Wieghardt K, Chirik PJ. Synthesis and electronic structure of cationic, neutral, and anionic bis(imino)pyridine iron alkyl complexes: evaluation of redox activity in single-component ethylene polymerization catalysts. Journal of the American Chemical Society. 132: 15046-59. PMID 20882992 DOI: 10.1021/Ja106575B  0.847
2010 Bowman AC, Milsmann C, Bill E, Lobkovsky E, Weyhermüller T, Wieghardt K, Chirik PJ. Reduced N-alkyl substituted bis(imino)pyridine cobalt complexes: molecular and electronic structures for compounds varying by three oxidation states. Inorganic Chemistry. 49: 6110-23. PMID 20540554 DOI: 10.1021/Ic100717W  0.844
2010 Milsmann C, Sproules S, Bill E, Weyhermüller T, George SD, Wieghardt K. Stabilization of high-valent Fe(IV)S6-cores by dithiocarbamate(1-) and 1,2-dithiolate(2-) ligands in octahedral [Fe(IV)(Et2dtc)(3-n)(mnt)(n)]((n-1)-) complexes (n=0, 1, 2, 3): a spectroscopic and density functional theory computational study. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 3628-45. PMID 20209531 DOI: 10.1002/Chem.200903381  0.692
2010 Bowman AC, Milsmann C, Atienza CC, Lobkovsky E, Wieghardt K, Chirik PJ. Synthesis and molecular and electronic structures of reduced bis(imino)pyridine cobalt dinitrogen complexes: ligand versus metal reduction. Journal of the American Chemical Society. 132: 1676-84. PMID 20085321 DOI: 10.1021/Ja908955T  0.837
2010 Yao S, Xiong Y, Milsmann C, Bill E, Pfirrmann S, Limberg C, Driess M. Reversible P(4) activation with nickel(I) and an eta(3)-coordinated tetraphosphorus ligand between two Ni(I) centers. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 436-9. PMID 19937871 DOI: 10.1002/Chem.200902820  0.387
2009 Milsmann C, Bill E, Weyhermüller T, DeBeer George S, Wieghardt K. Electronic structures of [Ru(II)(cyclam)(Et(2)dtc)](+), [Ru(cyclam)(tdt)](+), and [Ru(cyclam)(tdt)](2+): an X-ray absorption spectroscopic and computational study (tdt = toluene-3,4-dithiolate; Et(2)dtc = N,N-diethyldithiocarbamate(1-)). Inorganic Chemistry. 48: 9754-66. PMID 19769378 DOI: 10.1021/Ic9011845  0.66
2009 Milsmann C, Patra GK, Bill E, Weyhermüller T, DeBeer George S, Wieghardt K. Octahedral monodithiolene complexes of iron: characterization of S,S'-coordinated dithiolate(1-) pi radical monoanions: a spectroscopic and density functional theoretical investigation. Inorganic Chemistry. 48: 7430-45. PMID 19572498 DOI: 10.1021/Ic900936P  0.839
2009 Yao S, Xiong Y, Zhang X, Schlangen M, Schwarz H, Milsmann C, Driess M. Facile dissociation of [(LNi(II))2E2] dichalcogenides: evidence for [LNi(II)E2] superselenides and supertellurides in solution. Angewandte Chemie (International Ed. in English). 48: 4551-4. PMID 19449351 DOI: 10.1002/Anie.200901132  0.311
2009 Milsmann C, Bothe E, Bill E, Weyhermüller T, Wieghardt K. Octahedral monodithiolene complexes of cobalt(III) and chromium(III). Spectroscopic and density functional theoretical characterization of S,S'-coordinated benzene-1,2-dithiolate(1-) pi radicals. Inorganic Chemistry. 48: 6211-21. PMID 19432428 DOI: 10.1021/Ic900515J  0.556
2009 Meltzer A, Präsang C, Milsmann C, Driess M. The striking stabilization of Ni0(eta6-arene) complexes by an ylide-like silylene ligand. Angewandte Chemie (International Ed. in English). 48: 3170-3. PMID 19322860 DOI: 10.1002/Anie.200900290  0.473
2009 Wile BM, Trovitch RJ, Bart SC, Tondreau AM, Lobkovsky E, Milsmann C, Bill E, Wieghardt K, Chirik PJ. Reduction chemistry of aryl- and alkyl-substituted bis(imino)pyridine iron dihalide compounds: molecular and electronic structures of [(PDI)2Fe] derivatives. Inorganic Chemistry. 48: 4190-200. PMID 19035761 DOI: 10.1021/Ic801623M  0.84
2009 Bröring M, Funk M, Milsmann C. Investigating different strategies towards the preparation of chiral and achiral bis-picket fence corroles Journal of Porphyrins and Phthalocyanines. 13: 107-113. DOI: 10.1142/S1088424609000139  0.614
2009 Bröring M, Milsmann C, Ruck S, Köhler S. Bis-picket-fence corroles Journal of Organometallic Chemistry. 694: 1011-1015. DOI: 10.1016/J.Jorganchem.2008.04.039  0.703
2009 Meltzer A, Präsang C, Milsmann C, Driess M. Bemerkenswerte Stabilisierung von Ni0(η6-Aren)-Komplexen durch einen Ylid-artigen Silylenliganden Angewandte Chemie. 121: 3216-3219. DOI: 10.1002/Ange.200900290  0.338
2008 Spikes GH, Milsmann C, Bill E, Weyhermüller T, Wieghardt K. One- and two-electron reduced 1,2-diketone ligands in [Zn(II)(L*)2(Et2O)], [Co(II)(L*)2(Et2O)], and Na2(Et2O)4[Co(II)(LRed)2]. Inorganic Chemistry. 47: 11745-54. PMID 19006386 DOI: 10.1021/Ic801470P  0.542
2008 Yao S, Milsmann C, Bill E, Wieghardt K, Driess M. From a paramagnetic, mononuclear supersulfidonickel(II) complex to a diamagnetic dimer with a four-sulfur two-electron bond. Journal of the American Chemical Society. 130: 13536-7. PMID 18803388 DOI: 10.1021/Ja806101H  0.648
2008 Yao S, Bill E, Milsmann C, Wieghardt K, Driess M. A "side-on" superoxonickel complex [LNi(O2)] with a square-planar tetracoordinate nickel(II) center and its conversion into [LNi(mu-OH)2NiL]. Angewandte Chemie (International Ed. in English). 47: 7110-3. PMID 18671225 DOI: 10.1002/Anie.200802234  0.525
2008 Yao S, Bill E, Milsmann C, Wieghardt K, Driess M. Ein Side-on-Superoxonickel-Komplex [LNi(O2)] mit quadratisch- planarem, vierfach koordinierten Nickel(II)-Zentrum und seine Umwandlung in [LNi(μ-OH)2NiL] Angewandte Chemie. 120: 7218-7221. DOI: 10.1002/Ange.200802234  0.461
2006 Milsmann C, Levina A, Harris HH, Foran GJ, Turner P, Lay PA. Charge distribution in chromium and vanadium catecholato complexes: X-ray absorption spectroscopic and computational studies. Inorganic Chemistry. 45: 4743-54. PMID 16749839 DOI: 10.1021/Ic0603611  0.612
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