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Francis J. Barrios, Ph.D.

Affiliations: 
2013 Chemistry Purdue University, West Lafayette, IN, United States 
Area:
natural product synthesis
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David A. Colby grad student 2013 Purdue
 (Chemoselective modification of natural products: The use of aluminum-amides complexes as reagents for the transient in situ masking of reactive carbonyl groups.)

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Publications

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Liang S, Barrios FJ, Okoromoba OE, et al. (2017) Bromofluorination of Unsaturated Compounds using DMPU/HF as a Fluorinating Reagent. Journal of Fluorine Chemistry. 203: 136-139
Barrios FJ, Springer BC, Hazlitt RA, et al. (2015) Effect of Substituents and Stability of Transient Aluminum-Aminals in the Presence of Nucleophiles. Synthesis. 47: 175-180
Barrios FJ, Springer BC, Hazlitt RA, et al. (2015) Effect of Substituents and Stability of Transient Aluminum-Aminals in the Presence of Nucleophiles Synthesis (Germany). 47: 175-180
Barrios FJ, Springer BC, Colby DA. (2013) Control of transient aluminum-aminals for masking and unmasking reactive carbonyl groups. Organic Letters. 15: 3082-5
Gunn EJ, Williams JT, Huynh DT, et al. (2011) The natural products parthenolide and andrographolide exhibit anti-cancer stem cell activity in multiple myeloma. Leukemia & Lymphoma. 52: 1085-97
Barrios FJ, Zhang X, Colby DA. (2010) Dialkylaluminum N,O-dimethylhydroxylamine complex as a reagent to mask reactive carbonyl groups in situ from nucleophiles. Organic Letters. 12: 5588-91
Huynh DT, Iannotti MJ, Gunn EJ, et al. (2010) Abstract 4292: Parthenolide and structurally related natural products as anti-cancer stem cell agents: A new era in treatment of multiple myeloma Cancer Research. 70: 4292-4292
Han C, Barrios FJ, Riofski MV, et al. (2010) ChemInform Abstract: Semisynthetic Derivatives of Sesquiterpene Lactones by Palladium-Catalyzed Arylation of the α-Methylene-γ-lactone Substructure. Cheminform. 41
Han C, Barrios FJ, Riofski MV, et al. (2009) Semisynthetic derivatives of sesquiterpene lactones by palladium-catalyzed arylation of the alpha-methylene-gamma-lactone substructure. The Journal of Organic Chemistry. 74: 7176-9
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