Robert J. Gilliard, Ph.D.

Affiliations: 
2017-2022 Chemistry University of Virginia, Charlottesville, VA 
 2023- Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
Main-Group Synthetic Chemistry
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"Robert Gilliard"
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Publications

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Barker JE, Obi AD, Dickie DA, et al. (2023) Boron-Doped Pentacenes: Isolation of Crystalline 5,12- and 5,7-Diboratapentacene Dianions. Journal of the American Chemical Society. 145: 2028-2034
Wentz K, Molino A, Freeman L, et al. (2022) Approaching Dianionic Tetraoxadiborecine Macrocycles: 10-Membered Bora-Crown Ethers Incorporating Borafluorenate Units. Angewandte Chemie (International Ed. in English)
Obi AD, Dickie DA, Tiznado W, et al. (2022) A Multidimensional Approach to Carbodiphosphorane-Bismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate. Inorganic Chemistry. 61: 19452-19462
Warring LS, Walley JE, Dickie DA, et al. (2022) Lewis Superacidic Heavy Pnictaalkene Cations: Comparative Assessment of Carbodicarbene-Stibenium and Carbodicarbene-Bismuthenium Ions. Inorganic Chemistry
Wentz KE, Molino A, Freeman LA, et al. (2022) Systematic Electronic and Structural Studies of 9-Carbene-9-Borafluorene Monoanions and Transformations into Luminescent Boron Spirocycles. Inorganic Chemistry. 61: 17049-17058
Wentz KE, Molino A, Freeman LA, et al. (2022) Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone. Journal of the American Chemical Society
Obi AD, Frey NC, Dickie DA, et al. (2022) N-Heterocyclic Carbene-Assisted Reversible Migratory Coupling of Aminoborane at Magnesium. Angewandte Chemie (International Ed. in English). e202211496
Hollister KK, Yang W, Mondol R, et al. (2022) Isolation of Stable Borepin Radicals and Anions. Angewandte Chemie (International Ed. in English)
Hollister KK, Molino A, Breiner G, et al. (2022) Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions. Journal of the American Chemical Society. 144: 590-598
Wentz KE, Molino A, Freeman LA, et al. (2021) Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides. Inorganic Chemistry
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