☰

Robert J. Gilliard, Ph.D. - Publications

Affiliations: 
2017-2022 Chemistry University of Virginia, Charlottesville, VA 
 2023- Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
Main-Group Synthetic Chemistry
Tree Info Similar researchers PubMed Report error

42 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Barker JE, Obi AD, Dickie DA, Gilliard RJ. Boron-Doped Pentacenes: Isolation of Crystalline 5,12- and 5,7-Diboratapentacene Dianions. Journal of the American Chemical Society. 145: 2028-2034. PMID 36689632 DOI: 10.1021/jacs.2c11494  0.789
2022 Wentz K, Molino A, Freeman L, Dickie D, Wilson D, Gilliard RJ. Approaching Dianionic Tetraoxadiborecine Macrocycles: 10-Membered Bora-Crown Ethers Incorporating Borafluorenate Units. Angewandte Chemie (International Ed. in English). PMID 36437238 DOI: 10.1002/anie.202215772  0.804
2022 Obi AD, Dickie DA, Tiznado W, Frenking G, Pan S, Gilliard RJ. A Multidimensional Approach to Carbodiphosphorane-Bismuth Coordination Chemistry: Cationization, Redox-Flexibility, and Stabilization of a Crystalline Bismuth Hydridoborate. Inorganic Chemistry. 61: 19452-19462. PMID 36412917 DOI: 10.1021/acs.inorgchem.2c03337  0.832
2022 Warring LS, Walley JE, Dickie DA, Tiznado W, Pan S, Gilliard RJ. Lewis Superacidic Heavy Pnictaalkene Cations: Comparative Assessment of Carbodicarbene-Stibenium and Carbodicarbene-Bismuthenium Ions. Inorganic Chemistry. PMID 36350227 DOI: 10.1021/acs.inorgchem.2c03135  0.828
2022 Wentz KE, Molino A, Freeman LA, Dickie DA, Wilson DJD, Gilliard RJ. Systematic Electronic and Structural Studies of 9-Carbene-9-Borafluorene Monoanions and Transformations into Luminescent Boron Spirocycles. Inorganic Chemistry. 61: 17049-17058. PMID 36259945 DOI: 10.1021/acs.inorgchem.2c01945  0.793
2022 Wentz KE, Molino A, Freeman LA, Dickie DA, Wilson DJD, Gilliard RJ. Activation of Carbon Dioxide by 9-Carbene-9-borafluorene Monoanion: Carbon Monoxide Releasing Transformation of Trioxaborinanone to Luminescent Dioxaborinanone. Journal of the American Chemical Society. PMID 36037435 DOI: 10.1021/jacs.2c06845  0.758
2022 Obi AD, Frey NC, Dickie DA, Webster CE, Gilliard RJ. N-Heterocyclic Carbene-Assisted Reversible Migratory Coupling of Aminoborane at Magnesium. Angewandte Chemie (International Ed. in English). e202211496. PMID 36000510 DOI: 10.1002/anie.202211496  0.785
2022 Hollister KK, Yang W, Mondol R, Wentz KE, Molino A, Kaur A, Dickie DA, Frenking G, Pan S, Wilson DJD, Gilliard RJ. Isolation of Stable Borepin Radicals and Anions. Angewandte Chemie (International Ed. in English). PMID 35289046 DOI: 10.1002/anie.202202516  0.794
2022 Hollister KK, Molino A, Breiner G, Walley JE, Wentz KE, Conley AM, Dickie DA, Wilson DJD, Gilliard RJ. Air-Stable Thermoluminescent Carbodicarbene-Borafluorenium Ions. Journal of the American Chemical Society. 144: 590-598. PMID 35016509 DOI: 10.1021/jacs.1c11861  0.78
2021 Wentz KE, Molino A, Freeman LA, Dickie DA, Wilson DJD, Gilliard RJ. Reactions of 9-Carbene-9-Borafluorene Monoanion and Selenium: Synthesis of Boryl-Substituted Selenides and Diselenides. Inorganic Chemistry. PMID 34472333 DOI: 10.1021/acs.inorgchem.1c02124  0.799
2021 Obi AD, Machost HR, Dickie DA, Gilliard RJ. A Thermally Stable Magnesium Phosphaethynolate Grignard Complex. Inorganic Chemistry. 60: 12481-12488. PMID 34346670 DOI: 10.1021/acs.inorgchem.1c01700  0.76
2021 Freeman LA, Obi AD, Machost HR, Molino A, Nichols AW, Dickie DA, Wilson DJD, Machan CW, Gilliard RJ. Soluble, crystalline, and thermally stable alkali CO and carbonite (CO) clusters supported by cyclic(alkyl)(amino) carbenes. Chemical Science. 12: 3544-3550. PMID 34163627 DOI: 10.1039/d0sc06851a  0.783
2021 Wentz K, Molino A, Weisflog S, Kaur A, Dickie D, Wilson D, Gilliard RJ. Stabilization of the Elusive 9-Carbene-9-Borafluorene Monoanion. Angewandte Chemie (International Ed. in English). PMID 33780572 DOI: 10.1002/anie.202103628  0.823
2021 Walley JE, Warring LS, Kertész E, Wang G, Dickie DA, Benkő Z, Gilliard RJ. Indirect Access to Carbene Adducts of Bismuth- and Antimony-Substituted Phosphaketene and Their Unusual Thermal Transformation to Dipnictines and [(NHC)OCP][OCP]. Inorganic Chemistry. 60: 4733-4743. PMID 33689349 DOI: 10.1021/acs.inorgchem.0c03683  0.763
2021 Godbold P, Johnson G, Obi AD, Brown R, Hwang S, Gilliard RJ, Zhang S. Surfactant Removal for Colloidal Nanocrystal Catalysts Mediated by N-Heterocyclic Carbenes. Journal of the American Chemical Society. PMID 33570957 DOI: 10.1021/jacs.0c12278  0.783
2021 Wang G, Walley J, Dickie D, Molino A, Wilson D, Gilliard RJ. s-Block Multiple Bonds: Isolation of a Beryllium Imido Complex. Angewandte Chemie (International Ed. in English). PMID 33411396 DOI: 10.1002/anie.202016027  0.819
2020 Walley J, Warring L, Wang G, Dickie DA, Pan S, Frenking G, Gilliard RJ. Carbodicarbene Bismaalkene Cations: Unravelling the Complexities of Carbene versus Carbone in Heavy Pnictogen Chemistry. Angewandte Chemie (International Ed. in English). PMID 33290596 DOI: 10.1002/anie.202014398  0.831
2020 Krantz K, Weisflog S, Frey N, Yang W, Dickie D, Webster CE, Gilliard RJ. Planar, Stair-stepped, and Twisted: Modulating Structure and Photophysics in Pyrene- and Benzene-Fused N-Heterocyclic Boranes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32364300 DOI: 10.1002/Chem.202002118  0.56
2020 Wang G, Walley JE, Dickie DA, Pan S, Frenking G, Gilliard RJ. A Stable, Crystalline Beryllium Radical Cation. Journal of the American Chemical Society. PMID 32088963 DOI: 10.1021/Jacs.9B13777  0.806
2020 Yang W, Krantz K, Dickie D, Molino A, Wilson D, Gilliard RJ. Crystalline BP-Doped Phenanthryne via Photolysis of The Elusive Boraphosphaketene. Angewandte Chemie (International Ed. in English). PMID 31912624 DOI: 10.1002/anie.201916362  0.634
2019 Yang W, Krantz K, Freeman L, Dickie D, Molino A, Frenking G, Pan S, Wilson D, Gilliard RJ. Persistent Borafluorene Radicals. Angewandte Chemie (International Ed. in English). PMID 31816143 DOI: 10.1002/Anie.201909627  0.814
2019 Krantz KE, Weisflog SL, Yang W, Dickie DA, Frey NC, Webster CE, Gilliard RJ. Extremely twisted and bent pyrene-fused N-heterocyclic germylenes. Chemical Communications (Cambridge, England). PMID 31774075 DOI: 10.1039/C9Cc08703F  0.518
2019 Freeman LA, Walley JE, Dickie DA, Gilliard RJ. Low-nuclearity magnesium hydride complexes stabilized by N-heterocyclic carbenes. Dalton Transactions (Cambridge, England : 2003). 48: 17174-17178. PMID 31724675 DOI: 10.1039/c9dt03915e  0.747
2019 Walley JE, Obi AD, Breiner G, Wang G, Dickie DA, Molino A, Dutton JL, Wilson DJD, Gilliard RJ. Cyclic(alkyl)(amino) Carbene-Promoted Ring Expansion of a Carbodicarbene Beryllacycle. Inorganic Chemistry. PMID 31380626 DOI: 10.1021/Acs.Inorgchem.9B01643  0.804
2019 Lieske LE, Freeman LA, Wang G, Dickie DA, Gilliard RJ, Machan CW. Corrigendum: Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 9117. PMID 31355518 DOI: 10.1002/Chem.201902410  0.788
2019 Yang W, Krantz K, Lucas F, Diane D, Molino A, Kaur A, Wilson D, Gilliard RJ. Stable Borepinium and Borafluorenium Heterocycles: A Reversible Thermochromic "Switch" Based on Boron-Oxygen Interactions. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31334883 DOI: 10.1002/chem.201903348  0.604
2019 Freeman LA, Walley JE, Obi AD, Wang G, Dickie DA, Molino A, Wilson DJD, Gilliard RJ. Stepwise Reduction at Magnesium and Beryllium: Cooperative Effects of Carbenes with Redox Non-Innocent α-Diimines. Inorganic Chemistry. PMID 31124671 DOI: 10.1021/Acs.Inorgchem.9B01058  0.793
2019 Lieske LE, Freeman LA, Wang G, Dickie DA, Gilliard RJ, Machan C. Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30791170 DOI: 10.1002/Chem.201900316  0.79
2019 Wang G, Freeman LA, Dickie DA, Mokrai R, Benkő Z, Gilliard RJ. Isolation of Cyclic(Alkyl)(Amino) Carbene-Bismuthinidene Mediated by a Beryllium(0) Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 25: 4335-4339. PMID 30706565 DOI: 10.1002/Chem.201900458  0.816
2018 Wang G, Freeman LA, Dickie DA, Mokrai R, Benkő Z, Gilliard RJ. Highly Reactive Cyclic(alkyl)(amino) Carbene- and N-Heterocyclic Carbene-Bismuth(III) Complexes: Synthesis, Structure, and Computations. Inorganic Chemistry. 57: 11687-11695. PMID 30160485 DOI: 10.1021/Acs.Inorgchem.8B01813  0.809
2017 Gilliard RJ, Heift D, Benkő Z, Keiser JM, Rheingold AL, Grützmacher H, Protasiewicz JD. An isolable magnesium diphosphaethynolate complex. Dalton Transactions (Cambridge, England : 2003). PMID 29242885 DOI: 10.1039/C7Dt04539E  0.695
2017 Gilliard RJ, Suter R, Schrader E, Benkő Z, Rheingold AL, Grützmacher H, Protasiewicz JD. Synthesis of P2C2O2 and P2CO via NHC-mediated coupling of the phosphaethynolate anion. Chemical Communications (Cambridge, England). PMID 29095454 DOI: 10.1039/C7Cc07654A  0.708
2017 Kieser JM, Gilliard RJ, Rheingold AL, Grützmacher H, Protasiewicz JD. Insertion of sodium phosphaethynolate, Na[OCP], into a zirconium-benzyne complex. Chemical Communications (Cambridge, England). PMID 28430281 DOI: 10.1039/C7Cc01482A  0.688
2016 Beil A, Gilliard RJ, Grützmacher H. From the parent phosphinidene-carbene adduct NHC = PH to cationic P4-rings and P2-cycloaddition products. Dalton Transactions (Cambridge, England : 2003). 45: 2044-52. PMID 26400646 DOI: 10.1039/C5Dt03014E  0.506
2014 Chen M, Wang Y, Gilliard RJ, Wei P, Schwartz NA, Robinson GH. Synthesis and molecular structure of an abnormal carbene-gallium chloride complex. Dalton Transactions (Cambridge, England : 2003). 43: 14211-4. PMID 24934096 DOI: 10.1039/C4Dt00933A  0.685
2014 Chen M, Wang Y, Xie Y, Wei P, Gilliard RJ, Schwartz NA, Schaefer HF, Schleyer Pv, Robinson GH. Dynamic complexation of copper(I) chloride by carbene-stabilized disilicon. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9208-11. PMID 24909852 DOI: 10.1002/Chem.201403095  0.683
2013 Abraham MY, Wang Y, Xie Y, Gilliard RJ, Wei P, Vaccaro BJ, Johnson MK, Schaefer HF, Schleyer PV, Robinson GH. Oxidation of carbene-stabilized diarsenic: diarsene dications and diarsenic radical cations. Journal of the American Chemical Society. 135: 2486-8. PMID 23363453 DOI: 10.1021/Ja400219D  0.643
2012 Wang Y, Xie Y, Abraham MY, Gilliard RJ, Wei P, Campana CF, Schaefer HF, Schleyer Pv, Robinson GH. NHC-stabilized triorganozincates: syntheses, structures, and transformation to abnormal carbene-zinc complexes. Angewandte Chemie (International Ed. in English). 51: 10173-6. PMID 22962055 DOI: 10.1002/Anie.201204712  0.663
2012 Gilliard RJ, Abraham MY, Wang Y, Wei P, Xie Y, Quillian B, Schaefer HF, Schleyer PV, Robinson GH. Carbene-stabilized beryllium borohydride. Journal of the American Chemical Society. 134: 9953-5. PMID 22670857 DOI: 10.1021/Ja304514F  0.664
2010 Mangalum A, Gilliard RJ, Hanley JM, Parker AM, Smith RC. Metal ion detection by luminescent 1,3-bis(dimethylaminomethyl) phenyl receptor-modified chromophores and cruciforms. Organic & Biomolecular Chemistry. 8: 5620-7. PMID 20938511 DOI: 10.1039/C0Ob00156B  0.629
2009 Morgan BP, Gilliard RJ, Loungani RS, Smith RC. Poly(p-phenylene ethynylene) Incorporating Sterically Enshrouding m-Terphenyl Oxacyclophane Canopies. Macromolecular Rapid Communications. 30: 1399-405. PMID 21638397 DOI: 10.1002/Marc.200900160  0.6
2009 Morgan BP, Galdamez GA, Gilliard RJ, Smith RC. Canopied trans-chelating bis(N-heterocyclic carbene) ligand: synthesis, structure and catalysis. Dalton Transactions (Cambridge, England : 2003). 2020-8. PMID 19259573 DOI: 10.1039/B815739A  0.685
Show low-probability matches.