| Year |
Citation |
Score |
| 2024 |
Doyle LM, Bienenmann RLM, Gericke R, Xu S, Farquhar ER, Que L, McDonald AR. Preparation and characterization of MnMn complexes with relevance to class Ib ribonucleotide reductases. Journal of Inorganic Biochemistry. 257: 112583. PMID 38733704 DOI: 10.1016/j.jinorgbio.2024.112583 |
0.807 |
|
| 2024 |
Chandra B, Ahsan F, Sheng Y, Swart M, Que L. A tale of two topological isomers: Uptuning [Fe(O)(Mecyclam)] for olefin epoxidation. Proceedings of the National Academy of Sciences of the United States of America. 121: e2319799121. PMID 38478690 DOI: 10.1073/pnas.2319799121 |
0.656 |
|
| 2024 |
Rasheed W, Pal N, Aboelenen AM, Banerjee S, Oloo WN, Klein JEMN, Fan R, Xiong J, Guo Y, Que L. NMR and Mössbauer Studies Reveal a Temperature-Dependent Switch from = 1 to 2 in a Nonheme Oxoiron(IV) Complex with Faster C-H Bond Cleavage Rates. Journal of the American Chemical Society. PMID 38299607 DOI: 10.1021/jacs.3c10694 |
0.843 |
|
| 2024 |
Doyle L, Magherusan A, Xu S, Murphy K, Farquhar ER, Molton F, Duboc C, Que L, McDonald AR. Class Ib Ribonucleotide Reductases: Activation of a Peroxido-MnMn to Generate a Reactive Oxo-MnMn Oxidant. Inorganic Chemistry. 63: 2194-2203. PMID 38231137 DOI: 10.1021/acs.inorgchem.3c04163 |
0.824 |
|
| 2023 |
Li Y, Abelson C, Que L, Wang D. 10-fold faster C-H bond hydroxylation by a Co(µ-O) complex [via a Co(µ-O)(µ-OH) intermediate] versus its FeFe analog. Proceedings of the National Academy of Sciences of the United States of America. 120: e2307950120. PMID 38085777 DOI: 10.1073/pnas.2307950120 |
0.449 |
|
| 2023 |
Gupta S, Arora P, Kumar R, Awasthi A, Chandra B, Eerlapally R, Xiong J, Guo Y, Que LJ, Draksharapu A. Formation of a Reactive [Mn(III)-O-Ce(IV)] Species and its Facile Equilibrium with Related Mn(IV)(OX) (X = Sc or H) Complexes. Angewandte Chemie (International Ed. in English). e202316378. PMID 37997195 DOI: 10.1002/anie.202316378 |
0.759 |
|
| 2022 |
Aldous L, Comba P, DeBeer S, Dey A, Draksharapu A, Duboc C, Itoh S, Karlin K, Kundu S, López Domene R, Maréchal JD, Mazumdar S, Mukherjee R, Parker D, Pordea A, ... Que L, et al. Small molecule activation and synthetic analogues: general discussion. Faraday Discussions. PMID 35531924 DOI: 10.1039/d2fd90012b |
0.727 |
|
| 2022 |
Anilkumar A, Ash P, Chakravarty AR, Comba P, DeBeer S, Dey A, Draksharapu A, Goswami D, Itoh S, Karlin K, Lakshmi KV, Mazumdar S, Pantazis D, Parker D, Que L, et al. Electron transfer, spectroscopy and theory: general discussion. Faraday Discussions. PMID 35510729 DOI: 10.1039/d2fd90013k |
0.59 |
|
| 2022 |
Rohde GT, Xue G, Que L. Explorations of the nonheme high-valent iron-oxo landscape: crystal structure of a synthetic complex with an [FeIV2(μ-O)] diamond core relevant to the chemistry of sMMOH. Faraday Discussions. PMID 35171169 DOI: 10.1039/d1fd00066g |
0.471 |
|
| 2022 |
Oloo WN, Szávuly M, Kaizer J, Que L. Nonheme Diiron Oxygenase Mimic That Generates a Diferric-Peroxo Intermediate Capable of Catalytic Olefin Epoxidation and Alkane Hydroxylation Including Cyclohexane. Inorganic Chemistry. 61: 37-41. PMID 34894683 DOI: 10.1021/acs.inorgchem.1c03468 |
0.484 |
|
| 2021 |
Que L, Sheng Y, Abelson CS, Prakash J, Draksharapu A, Young VG. Unmasking Steps in Intramolecular Aromatic Hydroxylation by a Synthetic Nonheme Oxoiron(IV) Complex. Angewandte Chemie (International Ed. in English). PMID 34292639 DOI: 10.1002/anie.202108309 |
0.807 |
|
| 2021 |
Crossland PM, Guo Y, Que L. Spontaneous Formation of an Fe/Mn Diamond Core: Models for the Fe/Mn Sites in Class 1c Ribonucleotide Reductases. Inorganic Chemistry. PMID 34110143 DOI: 10.1021/acs.inorgchem.1c00684 |
0.455 |
|
| 2021 |
Tripodi GL, Dekker MMJ, Roithová J, Que L. Tuning the H-Atom Transfer Reactivity of Iron(IV)-Oxo Complexes as Probed by Infrared Photodissociation Spectroscopy. Angewandte Chemie (International Ed. in English). 60: 7126-7131. PMID 33393186 DOI: 10.1002/anie.202016695 |
0.524 |
|
| 2020 |
Que L, Draksharapu A, Xu S. CeIV- and HClO4-Promoted Assembly of an Fe2IV(µ-O)2 Diamond Core from its Monomeric FeIV=O Precursor at Room Temperature. Angewandte Chemie (International Ed. in English). PMID 32902902 DOI: 10.1002/Anie.202010027 |
0.791 |
|
| 2020 |
Banerjee S, Draksharapu A, Crossland P, Fan R, Guo Y, Swart M, Que L. Sc3+-promoted O-O bond cleavage of a (μ-1,2-peroxo)diiron(III) species formed from an iron(II) precursor and O2 to generate a complex with an FeIV2(μ-O)2 core. Journal of the American Chemical Society. PMID 32017545 DOI: 10.1021/Jacs.9B12081 |
0.815 |
|
| 2020 |
Que L. High-Valent Nonheme Iron Oxidants in Biology: Lessons from Synthetic Fe=O Complexes. Bulletin of Japan Society of Coordination Chemistry. 62: 30-37. PMID 25678937 |
0.538 |
|
| 2019 |
Sabenya G, Gamba I, Gómez L, Clémancey M, Frisch JR, Klinker EJ, Blondin G, Torelli S, Que L, Martin-Diaconescu V, Latour JM, Lloret-Fillol J, Costas M. Octahedral iron(iv)-tosylimido complexes exhibiting single electron-oxidation reactivity. Chemical Science. 10: 9513-9529. PMID 32055323 DOI: 10.1039/C9Sc02526J |
0.862 |
|
| 2019 |
Xu S, Draksharapu A, Rasheed W, Que L. Acid pKa Dependence in O-O Bond Heterolysis of a Nonheme FeIII-OOH Intermediate to Form a Potent FeV=O Oxidant with Heme Compound I-Like Reactivity. Journal of the American Chemical Society. PMID 31513741 DOI: 10.1021/Jacs.9B08442 |
0.852 |
|
| 2019 |
Dantignana V, Serrano-Plana J, Draksharapu A, Magallón C, Banerjee S, Fan R, Gamba I, Guo Y, Que L, Costas M, Company A. Spectroscopic and reactivity comparisons between nonheme oxoiron(IV) and oxoiron(V) species bearing the same ancillary ligand. Journal of the American Chemical Society. PMID 31469954 DOI: 10.1021/Jacs.9B05758 |
0.717 |
|
| 2019 |
Kal S, Xu S, Que L. Bio-inspired Nonheme Iron Oxidation Catalysis. Growing Evidence for the Involvement of Oxoiron(V) Oxidants in Cleaving Strong C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 31373120 DOI: 10.1002/anie.201906551 |
0.381 |
|
| 2019 |
Rasheed W, Fan R, Abelson CS, Peterson PO, Ching WM, Guo Y, Que L. Structural implications of the paramagnetically shifted NMR signals from pyridine H atoms on synthetic nonheme Fe=O complexes. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 31172289 DOI: 10.1007/S00775-019-01672-3 |
0.824 |
|
| 2019 |
Banerjee S, Rasheed W, Fan R, Draksharapu A, Oloo W, Guo Y, Que L. NMR Reveals That a Highly Reactive Nonheme Fe(IV)=O Complex Retains its 6- Coordinate Geometry and S = 1 State in Solution. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31059593 DOI: 10.1002/Chem.201902048 |
0.846 |
|
| 2019 |
Kal S, Que L. Activation of a Non-Heme Fe -OOH by a Second Fe to Hydroxylate Strong C-H Bonds: Possible Implications for Soluble Methane Monooxygenase. Angewandte Chemie (International Ed. in English). 58: 8484-8488. PMID 30997707 DOI: 10.1002/anie.201903465 |
0.48 |
|
| 2019 |
Magherusan AM, Kal S, Nelis DN, Doyle LM, Farquhar ER, Que L, McDonald AR. A MnIIMnIII-peroxide complex capable of aldehyde deformylation. Angewandte Chemie (International Ed. in English). PMID 30830996 DOI: 10.1002/Anie.201900717 |
0.812 |
|
| 2019 |
Kim J, Dong Y, Larka E, Que L. Electrospray Ionization Mass Spectral Characterization of Transient Iron Species of Bioinorganic Relevance. Inorganic Chemistry. 35: 2369-2372. PMID 11666437 DOI: 10.1021/ic951091h |
0.44 |
|
| 2018 |
Prakash J, Sheng Y, Draksharapu A, Klein JEMN, Cramer CJ, Que L. Facile Conversion of syn-[Fe (O)(TMC)] into the anti Isomer via Meunier's Oxo-Hydroxo Tautomerism Mechanism. Angewandte Chemie (International Ed. in English). PMID 30556289 DOI: 10.1002/Anie.201811454 |
0.826 |
|
| 2018 |
Cutsail Iii GE, Banerjee R, Zhou A, Que L, Lipscomb JD, DeBeer S. High-Resolution EXAFS Provides Evidence for a Longer Fe•••Fe Distance in the Q Intermediate of Methane Monooxygenase. Journal of the American Chemical Society. PMID 30398343 DOI: 10.1021/Jacs.8B10313 |
0.592 |
|
| 2018 |
Andris E, Navrátil R, Jašík J, Puri M, Costas M, Que L, Roithová J. Trapping Iron(III)-Oxo Species at the Boundary of the "Oxo Wall": Insights into the Nature of the Fe(III)-O Bond. Journal of the American Chemical Society. PMID 30336001 DOI: 10.1021/Jacs.8B08950 |
0.46 |
|
| 2018 |
Xu S, Veach JJ, Oloo WN, Peters KC, Wang J, Perry RH, Que L. Detection of a transient Fe(O)(OH) species involved in olefin oxidation by a bio-inspired non-haem iron catalyst. Chemical Communications (Cambridge, England). PMID 30028454 DOI: 10.1039/C8Cc03990A |
0.471 |
|
| 2018 |
Rasheed W, Draksharapu A, Banerjee S, Young VG, Fan R, Guo Y, Ozerov M, Nehrkorn J, Krzystek J, Telser J, Que L. Crystallographic evidence for a sterically induced ferryl tilt in a non-heme oxoiron(IV) complex that makes it a better oxidant. Angewandte Chemie (International Ed. in English). PMID 29882390 DOI: 10.1002/Anie.201804836 |
0.881 |
|
| 2018 |
Kal S, Draksharapu A, Que L. Sc (or HClO) Activation of a Nonheme Fe-OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene. Journal of the American Chemical Society. PMID 29618199 DOI: 10.1021/Jacs.8B01435 |
0.765 |
|
| 2018 |
Komor AJ, Jasniewski AJ, Que L, Lipscomb JD. Diiron monooxygenases in natural product biosynthesis. Natural Product Reports. PMID 29552683 DOI: 10.1039/C7Np00061H |
0.564 |
|
| 2018 |
Fan R, Serrano-Plana J, Oloo WN, Draksharapu A, Delgado-Pinar E, Company A, Martin-Diaconescu V, Borrell M, Lloret-Fillol J, García-España E, Guo Y, Bominaar EL, Que L, Costas M, Münck E. Spectroscopic and DFT Characterization of a Highly Reactive Nonheme Fe-oxo Intermediate. Journal of the American Chemical Society. PMID 29463085 DOI: 10.1021/Jacs.7B11400 |
0.835 |
|
| 2018 |
Jasniewski AJ, Que L. Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes. Chemical Reviews. 118: 2554-2592. PMID 29400961 DOI: 10.1021/acs.chemrev.7b00457 |
0.365 |
|
| 2017 |
Khenkin AM, Vedichi M, Shimon LJW, Cranswick MA, Klein JEMN, Que L, Neumann R. Hydrogen-Atom Transfer Oxidation with H2O2 Catalyzed by [FeII(1,2-bis(2,2'-bipyridyl-6-yl)ethane(H2O)2]2+: Likely Involvement of a (μ-Hydroxo)(μ-1,2-peroxo)diiron(III) Intermediate. Israel Journal of Chemistry. 57: 990-998. PMID 29335656 DOI: 10.1002/Ijch.201700059 |
0.366 |
|
| 2017 |
Zhou A, Crossland PM, Draksharapu A, Jasniewski AJ, Kleespies ST, Que L. Oxoiron(IV) complexes as synthons for the assembly of heterobimetallic centers such as the Fe/Mn active site of Class Ic ribonucleotide reductases. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 29218640 DOI: 10.1007/S00775-017-1517-5 |
0.788 |
|
| 2017 |
Que L, Klein JEMN, Draksharapu A, Shokri A, Cramer CJ. On the Lewis Acidity of the Oxoiron(IV) Unit in a Tetramethylcyclam Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29205555 DOI: 10.1002/Chem.201704977 |
0.728 |
|
| 2017 |
Serrano-Plana J, Acuña-Parés F, Dantignana V, Oloo WN, Castillo E, Draksharapu A, Whiteoak CJ, Martin-Diaconescu V, Basallote MG, Luis JM, Que L, Costas M, Company A. Acid-triggered O-O bond heterolysis of a nonheme FeIII(OOH) species for the stereospecific hydroxylation of strong C-H bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29193378 DOI: 10.1002/Chem.201704851 |
0.72 |
|
| 2017 |
Klein JEMN, Mandal D, Ching WM, Mallick D, Que L, Shaik S. Privileged Role of Thiolate as the Axial Ligand in Hydrogen Atom Transfer Reactions by Oxoiron(IV) Complexes in Shaping the Potential Energy Surface and Inducing Significant H-Atom Tunneling. Journal of the American Chemical Society. PMID 29179544 DOI: 10.1021/Jacs.7B11300 |
0.529 |
|
| 2017 |
Magherusan A, Zhou A, Farquhar E, Garcia Melchor M, Twamley B, Que L, McDonald AR. Mimicking class Ib Mn2 ribonucleotide reductase: a MnII2 complex and its reaction with superoxide. Angewandte Chemie (International Ed. in English). PMID 29165865 DOI: 10.1002/Anie.201709806 |
0.824 |
|
| 2017 |
Castillo RG, Banerjee R, Allpress CJ, Rohde GT, Bill E, Que L, Lipscomb JD, DeBeer S. High-Energy Resolution Fluorescence Detected X-ray Absorption of the Q intermediate of Soluble Methane Monooxygenase. Journal of the American Chemical Society. PMID 29136468 DOI: 10.1021/Jacs.7B09560 |
0.592 |
|
| 2017 |
Oloo WN, Banerjee R, Lipscomb JD, Que L. Equilibrating (L)Fe(III)-OOAc and (L)Fe(V)(O) Species in Hydrocarbon Oxidations by Bio-Inspired Nonheme Iron Catalysts using H2O2 and AcOH. Journal of the American Chemical Society. PMID 29136467 DOI: 10.1021/Jacs.7B06246 |
0.665 |
|
| 2017 |
Chen J, Draksharapu A, Harvey E, Rasheed W, Que L, Browne WR. Direct photochemical activation of non-heme Fe(iv)[double bond, length as m-dash]O complexes. Chemical Communications (Cambridge, England). PMID 29099136 DOI: 10.1039/C7Cc07452B |
0.864 |
|
| 2017 |
Ching WM, Zhou A, Klein JEMN, Fan R, Knizia G, Cramer CJ, Guo Y, Que L. Correction to Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand. Inorganic Chemistry. PMID 29028324 DOI: 10.1021/Acs.Inorgchem.7B02374 |
0.302 |
|
| 2017 |
Ching WM, Zhou A, Klein JEMN, Fan R, Knizia G, Cramer CJ, Guo Y, Que L. Characterization of the Fleeting Hydroxoiron(III) Complex of the Pentadentate TMC-py Ligand. Inorganic Chemistry. PMID 28858496 DOI: 10.1021/Acs.Inorgchem.7B01459 |
0.521 |
|
| 2017 |
Komor AJ, Rivard BS, Fan R, Guo Y, Que L, Lipscomb JD. CmlI N-Oxygenase Catalyzes the Final Three Steps in Chloramphenicol Biosynthesis without Dissociation of Intermediates. Biochemistry. PMID 28823151 DOI: 10.1021/Acs.Biochem.7B00695 |
0.599 |
|
| 2017 |
Jasniewski AJ, Komor AJ, Lipscomb JD, Que L. An Unprecedented (μ-1,1-Peroxo)diferric Structure for the Ambiphilic Orange Peroxo Intermediate of the Nonheme N-Oxygenase CmlI. Journal of the American Chemical Society. PMID 28673082 DOI: 10.1021/Jacs.7B05389 |
0.682 |
|
| 2017 |
Draksharapu A, Rasheed W, Klein JEMN, Que L. Facile and reversible formation of Fe(III)-O-Ce(IV) adducts from nonheme oxoiron(IV) complexes and Ce(III). Angewandte Chemie (International Ed. in English). PMID 28598024 DOI: 10.1002/Anie.201704322 |
0.862 |
|
| 2017 |
Verma P, Varga Z, Klein JEMN, Cramer CJ, Que L, Truhlar DG. Assessment of electronic structure methods for the determination of the ground spin states of Fe(ii), Fe(iii) and Fe(iv) complexes. Physical Chemistry Chemical Physics : Pccp. PMID 28484765 DOI: 10.1039/C7Cp01263B |
0.347 |
|
| 2017 |
Pattanayak S, Jasniewski AJ, Rana A, Draksharapu A, Singh KK, Weitz A, Hendrich M, Que L, Dey A, Sen Gupta S. Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with Fe(V)═O and Fe(IV)═O Units. Inorganic Chemistry. PMID 28481521 DOI: 10.1021/Acs.Inorgchem.7B00448 |
0.782 |
|
| 2017 |
Bigelow JO, England J, Klein JE, Farquhar ER, Frisch JR, Martinho M, Mandal D, Münck E, Shaik S, Que L. Oxoiron(IV) Tetramethylcyclam Complexes with Axial Carboxylate Ligands: Effect of Tethering the Carboxylate on Reactivity. Inorganic Chemistry. PMID 28257190 DOI: 10.1021/Acs.Inorgchem.6B02659 |
0.847 |
|
| 2017 |
Kal S, Que L. Dioxygen activation by nonheme iron enzymes with the 2-His-1-carboxylate facial triad that generate high-valent oxoiron oxidants. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 28074299 DOI: 10.1007/s00775-016-1431-2 |
0.438 |
|
| 2016 |
Zhou A, Prakash J, Rohde GT, Klein JE, Kleespies ST, Draksharapu A, Fan R, Guo Y, Cramer CJ, Que L. The Two Faces of Tetramethylcyclam in Iron Chemistry: Distinct Fe-O-M Complexes Derived from [Fe(IV)(Oanti/syn)(TMC)](2+) Isomers. Inorganic Chemistry. PMID 28001379 DOI: 10.1021/Acs.Inorgchem.6B02417 |
0.821 |
|
| 2016 |
Sutherlin KD, Liu LV, Lee YM, Kwak Y, Yoda Y, Saito M, Kurokuzu M, Kobayashi Y, Seto M, Que L, Nam W, Solomon EI. Nuclear resonance vibrational spectroscopic definition of peroxy intermediates in non-heme iron sites. Journal of the American Chemical Society. PMID 27726349 DOI: 10.1021/Jacs.6B07227 |
0.402 |
|
| 2016 |
Jasniewski AJ, Knoot CJ, Lipscomb JD, Que L. A Carboxylate Shift Regulates Dioxygen Activation by the Diiron Nonheme β-Hydroxylase CmlA upon Binding of a Substrate-Loaded Nonribosomal Peptide Synthetase. Biochemistry. PMID 27668828 DOI: 10.1021/Acs.Biochem.6B00834 |
0.607 |
|
| 2016 |
Jasniewski AJ, Engstrom LM, Vu VV, Park MH, Que L. X-ray absorption spectroscopic characterization of the diferric-peroxo intermediate of human deoxyhypusine hydroxylase in the presence of its substrate eIF5a. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27380180 DOI: 10.1007/S00775-016-1373-8 |
0.647 |
|
| 2016 |
Puri M, Company A, Sabenya G, Costas M, Que L. Oxygen Atom Exchange between H2O and Non-Heme Oxoiron(IV) Complexes: Ligand Dependence and Mechanism. Inorganic Chemistry. 55: 5818-27. PMID 27275633 DOI: 10.1021/acs.inorgchem.6b00023 |
0.535 |
|
| 2016 |
Prakash J, Que L. Formation of the syn isomer of [Fe(IV)(Oanti)(TMC)(NCMe)](2+) in the reaction of Lewis acids with the side-on bound peroxo ligand in [Fe(III)(η(2)-O2)(TMC)](.) Chemical Communications (Cambridge, England). PMID 27273175 DOI: 10.1039/C6Cc01660J |
0.673 |
|
| 2016 |
Komor AJ, Rivard BS, Fan R, Guo Y, Que L, Lipscomb JD. Mechanism for Six-Electron Aryl-N-oxygenation by the Non-Heme Diiron Enzyme CmlI. Journal of the American Chemical Society. PMID 27203126 DOI: 10.1021/Jacs.6B03341 |
0.595 |
|
| 2016 |
Stout HD, Kleespies ST, Chiang CW, Lee WZ, Que L, Münck E, Bominaar EL. Spectroscopic and Theoretical Study of Spin-Dependent Electron Transfer in an Iron(III) Superoxo Complex. Inorganic Chemistry. PMID 27159412 DOI: 10.1021/Acs.Inorgchem.6B00134 |
0.842 |
|
| 2016 |
Puri M, Biswas AN, Fan R, Guo Y, Que L. Modeling Non-Heme Iron Halogenases: High-Spin Oxoiron(IV)-Halide Complexes That Halogenate C-H Bonds. Journal of the American Chemical Society. PMID 26875530 DOI: 10.1021/Jacs.5B11511 |
0.792 |
|
| 2015 |
Prakash J, Rohde GT, Meier KK, Münck E, Que L. Upside Down! Crystallographic and Spectroscopic Characterization of an [Fe(IV)(Osyn)(TMC)](2+) Complex. Inorganic Chemistry. 54: 11055-7. PMID 26615667 DOI: 10.1021/Acs.Inorgchem.5B02011 |
0.857 |
|
| 2015 |
Serrano-Plana J, Oloo WN, Acosta-Rueda L, Meier KK, Verdejo B, Garcia-España E, Basallote MG, Münck E, Que L, Company A, Costas M. Trapping a Highly Reactive Non-heme Iron Intermediate That Oxygenates Strong C-H Bonds with Stereoretention. Journal of the American Chemical Society. PMID 26599834 DOI: 10.1021/Jacs.5B09904 |
0.863 |
|
| 2015 |
Ye S, Xue G, Krivokapic I, Petrenko T, Bill E, Que L, Neese F. Magnetic circular dichroism and computational study of mononuclear and dinuclear iron(IV) complexes. Chemical Science (Royal Society of Chemistry : 2010). 6: 2909-2921. PMID 26417426 DOI: 10.1039/C4Sc03268C |
0.528 |
|
| 2015 |
Oloo WN, Que L. Bioinspired Nonheme Iron Catalysts for C-H and C═C Bond Oxidation: Insights into the Nature of the Metal-Based Oxidants. Accounts of Chemical Research. 48: 2612-21. PMID 26280131 DOI: 10.1021/Acs.Accounts.5B00053 |
0.563 |
|
| 2015 |
Zhou A, Kleespies ST, Van Heuvelen KM, Que L. Characterization of a heterobimetallic nonheme Fe(iii)-O-Cr(iii) species formed by O2 activation. Chemical Communications (Cambridge, England). 51: 14326-9. PMID 26265081 DOI: 10.1039/c5cc05931c |
0.465 |
|
| 2015 |
England J, Prakash J, Cranswick MA, Mandal D, Guo Y, Münck E, Shaik S, Que L. Oxoiron(IV) Complex of the Ethylene-Bridged Dialkylcyclam Ligand Me2EBC. Inorganic Chemistry. 54: 7828-39. PMID 26244657 DOI: 10.1021/Acs.Inorgchem.5B00861 |
0.814 |
|
| 2015 |
Puri M, Que L. Toward the synthesis of more reactive S = 2 non-heme oxoiron(IV) complexes. Accounts of Chemical Research. 48: 2443-52. PMID 26176555 DOI: 10.1021/acs.accounts.5b00244 |
0.364 |
|
| 2015 |
Schreiber RE, Cohen H, Leitus G, Wolf SG, Zhou A, Que L, Neumann R. Reactivity and O2 Formation by Mn(IV)- and Mn(V)-Hydroxo Species Stabilized within a Polyfluoroxometalate Framework. Journal of the American Chemical Society. PMID 26070034 DOI: 10.1021/Jacs.5B03456 |
0.426 |
|
| 2015 |
Shokri A, Que L. Conversion of Aldehyde to Alkane by a Peroxoiron(III) Complex: A Functional Model for the Cyanobacterial Aldehyde-Deformylating Oxygenase. Journal of the American Chemical Society. 137: 7686-91. PMID 26030345 DOI: 10.1021/Jacs.5B01053 |
0.495 |
|
| 2015 |
Kleespies ST, Oloo WN, Mukherjee A, Que L. C-H Bond Cleavage by Bioinspired Nonheme Oxoiron(IV) Complexes, Including Hydroxylation of n-Butane. Inorganic Chemistry. 54: 5053-64. PMID 25751610 DOI: 10.1021/Ic502786Y |
0.515 |
|
| 2015 |
Prakash J, Rohde GT, Meier KK, Jasniewski AJ, Van Heuvelen KM, Münck E, Que L. Spectroscopic identification of an Fe(III) center, not Fe(IV), in the crystalline Sc-O-Fe adduct derived from [Fe(IV)(O)(TMC)]²⁺. Journal of the American Chemical Society. 137: 3478-81. PMID 25743366 DOI: 10.1021/Jacs.5B00535 |
0.879 |
|
| 2015 |
Biswas AN, Puri M, Meier KK, Oloo WN, Rohde GT, Bominaar EL, Münck E, Que L. Modeling TauD-J: a high-spin nonheme oxoiron(IV) complex with high reactivity toward C-H bonds. Journal of the American Chemical Society. 137: 2428-31. PMID 25674662 DOI: 10.1021/Ja511757J |
0.853 |
|
| 2015 |
Codolà Z, Gómez L, Kleespies ST, Que L, Costas M, Lloret-Fillol J. Erratum: Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation. Nature Communications. 6: 6405. PMID 25672879 DOI: 10.1038/ncomms7405 |
0.328 |
|
| 2015 |
Codolà Z, Gómez L, Kleespies ST, Que L, Costas M, Lloret-Fillol J. Evidence for an oxygen evolving iron-oxo-cerium intermediate in iron-catalysed water oxidation. Nature Communications. 6: 5865. PMID 25609387 DOI: 10.1038/ncomms6865 |
0.566 |
|
| 2015 |
Makris TM, Vu VV, Meier KK, Komor AJ, Rivard BS, Münck E, Que L, Lipscomb JD. An unusual peroxo intermediate of the arylamine oxygenase of the chloramphenicol biosynthetic pathway. Journal of the American Chemical Society. 137: 1608-17. PMID 25564306 DOI: 10.1021/Ja511649N |
0.85 |
|
| 2014 |
Iyer SR, Javadi MM, Feng Y, Hyun MY, Oloo WN, Kim C, Que L. A chameleon catalyst for nonheme iron-promoted olefin oxidation. Chemical Communications (Cambridge, England). 50: 13777-80. PMID 25251577 DOI: 10.1039/C4Cc06164K |
0.407 |
|
| 2014 |
Chiang CW, Kleespies ST, Stout HD, Meier KK, Li PY, Bominaar EL, Que L, Münck E, Lee WZ. Characterization of a paramagnetic mononuclear nonheme iron-superoxo complex. Journal of the American Chemical Society. 136: 10846-9. PMID 25036460 DOI: 10.1021/Ja504410S |
0.885 |
|
| 2014 |
England J, Bigelow JO, Van Heuvelen KM, Farquhar ER, Martinho M, Meier KK, Frisch JR, Münck E, Que L. An Ultra-Stable Oxoiron(IV) Complex and Its Blue Conjugate Base. Chemical Science (Royal Society of Chemistry : 2010). 5: 1204-1215. PMID 24660055 DOI: 10.1039/C3Sc52755G |
0.869 |
|
| 2014 |
Fielding AJ, Lipscomb JD, Que L. A two-electron-shell game: intermediates of the extradiol-cleaving catechol dioxygenases. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 19: 491-504. PMID 24615282 DOI: 10.1007/S00775-014-1122-9 |
0.809 |
|
| 2014 |
Company A, Sabenya G, González-Béjar M, Gómez L, Clémancey M, Blondin G, Jasniewski AJ, Puri M, Browne WR, Latour JM, Que L, Costas M, Pérez-Prieto J, Lloret-Fillol J. Triggering the generation of an iron(IV)-oxo compound and its reactivity toward sulfides by Ru(II) photocatalysis. Journal of the American Chemical Society. 136: 4624-33. PMID 24568126 DOI: 10.1021/Ja412059C |
0.633 |
|
| 2014 |
Oloo WN, Meier KK, Wang Y, Shaik S, Münck E, Que L. Identification of a low-spin acylperoxoiron(III) intermediate in bio-inspired non-heme iron-catalysed oxidations. Nature Communications. 5: 3046. PMID 24429896 DOI: 10.1038/Ncomms4046 |
0.833 |
|
| 2014 |
Stoian SA, Xue G, Bominaar EL, Que L, Münck E. Spectroscopic and theoretical investigation of a complex with an [Oâ•Fe(IV)-O-Fe(IV)â•O] core related to methane monooxygenase intermediate Q. Journal of the American Chemical Society. 136: 1545-58. PMID 24380398 DOI: 10.1021/Ja411376U |
0.783 |
|
| 2014 |
Makhlynets OV, Oloo WN, Moroz YS, Belaya IG, Palluccio TD, Filatov AS, Müller P, Cranswick MA, Que L, Rybak-Akimova EV. H2O2 activation with biomimetic non-haem iron complexes and AcOH: connecting the g = 2.7 EPR signal with a visible chromophore. Chemical Communications (Cambridge, England). 50: 645-8. PMID 24292104 DOI: 10.1039/C3Cc47632D |
0.408 |
|
| 2014 |
Wang D, Que L. Oxidation of water by a nonhaem diiron(IV) complex via proton-coupled electron transfer. Chemical Communications (Cambridge, England). 49: 10682-4. PMID 24108275 DOI: 10.1039/c3cc46391e |
0.369 |
|
| 2013 |
Pap JS, Cranswick MA, Balogh-Hergovich E, Baráth G, Giorgi M, Rohde GT, Kaizer J, Speier G, Que L. An Iron(II)(1,3-bis(2'-pyridylimino)isoindoline) Complex as a Catalyst for Substrate Oxidation with H2O2. Evidence for a Transient Peroxodiiron(III) Species. European Journal of Inorganic Chemistry. 2013: 3858-3866. PMID 24587695 DOI: 10.1002/Ejic.201300162 |
0.468 |
|
| 2013 |
Hayden JA, Farquhar ER, Que L, Lipscomb JD, Hendrich MP. NO binding to Mn-substituted homoprotocatechuate 2,3-dioxygenase: relationship to O₂ reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 18: 717-28. PMID 23824380 DOI: 10.1007/S00775-013-1016-2 |
0.82 |
|
| 2013 |
Li F, Van Heuvelen KM, Meier KK, Münck E, Que L. Sc3+-triggered oxoiron(IV) formation from O2 and its non-heme iron(II) precursor via a Sc3+-peroxo-Fe3+ intermediate. Journal of the American Chemical Society. 135: 10198-201. PMID 23802702 DOI: 10.1021/Ja402645Y |
0.872 |
|
| 2013 |
Oloo WN, Fielding AJ, Que L. Rate-determining water-assisted O-O bond cleavage of an Fe(III)-OOH intermediate in a bio-inspired nonheme iron-catalyzed oxidation. Journal of the American Chemical Society. 135: 6438-41. PMID 23594282 DOI: 10.1021/Ja402759C |
0.865 |
|
| 2013 |
Park K, Bell CB, Liu LV, Wang D, Xue G, Kwak Y, Wong SD, Light KM, Zhao J, Alp EE, Yoda Y, Saito M, Kobayashi Y, Ohta T, Seto M, ... Que L, et al. Nuclear resonance vibrational spectroscopic and computational study of high-valent diiron complexes relevant to enzyme intermediates. Proceedings of the National Academy of Sciences of the United States of America. 110: 6275-80. PMID 23576760 DOI: 10.1073/Pnas.1304238110 |
0.418 |
|
| 2013 |
Prat I, Company A, Postils V, Ribas X, Que L, Luis JM, Costas M. The mechanism of stereospecific C-H oxidation by Fe(Pytacn) complexes: bioinspired non-heme iron catalysts containing cis-labile exchangeable sites. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 6724-38. PMID 23536410 DOI: 10.1002/Chem.201300110 |
0.51 |
|
| 2013 |
Xue G, Geng C, Ye S, Fiedler AT, Neese F, Que L. Hydrogen-bonding effects on the reactivity of [X-Fe(III)-O-Fe(IV)â•O] (X = OH, F) complexes toward C-H bond cleavage. Inorganic Chemistry. 52: 3976-84. PMID 23496330 DOI: 10.1021/Ic3027896 |
0.503 |
|
| 2013 |
Frisch JR, McDonnell R, Rybak-Akimova EV, Que L. Factors affecting the carboxylate shift upon formation of nonheme diiron-O2 adducts. Inorganic Chemistry. 52: 2627-36. PMID 23432330 DOI: 10.1021/Ic302543N |
0.823 |
|
| 2013 |
Wang D, Ray K, Collins MJ, Farquhar ER, Frisch JR, Gómez L, Jackson TA, Kerscher M, Waleska A, Comba P, Costas M, Que L. Nonheme Oxoiron(IV) Complexes of Pentadentate N5 Ligands: Spectroscopy, Electrochemistry, and Oxidative Reactivity. Chemical Science (Royal Society of Chemistry : 2010). 4: 282-291. PMID 23227304 DOI: 10.1039/C2Sc21318D |
0.883 |
|
| 2012 |
McDonald AR, Guo Y, Vu VV, Bominaar EL, Münck E, Que L. A Mononuclear Carboxylate-Rich Oxoiron(IV) Complex: a Structural and Functional Mimic of TauD Intermediate 'J' Chemical Science (Royal Society of Chemistry : 2010). 3: 1680-1693. PMID 23267430 DOI: 10.1039/C2Sc01044E |
0.868 |
|
| 2012 |
Shanmugam M, Xue G, Que L, Hoffman BM. 1H-ENDOR evidence for a hydrogen-bonding interaction that modulates the reactivity of a nonheme Fe(IV)â•O unit. Inorganic Chemistry. 51: 10080-2. PMID 22984805 DOI: 10.1021/Ic3015783 |
0.432 |
|
| 2012 |
Cranswick MA, Meier KK, Shan X, Stubna A, Kaizer J, Mehn MP, Münck E, Que L. Protonation of a peroxodiiron(III) complex and conversion to a diiron(III/IV) intermediate: implications for proton-assisted O-O bond cleavage in nonheme diiron enzymes. Inorganic Chemistry. 51: 10417-26. PMID 22971084 DOI: 10.1021/Ic301642W |
0.863 |
|
| 2012 |
Srnec M, Wong SD, England J, Que L, Solomon EI. π-Frontier molecular orbitals in S = 2 ferryl species and elucidation of their contributions to reactivity Proceedings of the National Academy of Sciences of the United States of America. 109: 14326-14331. PMID 22908238 DOI: 10.1073/Pnas.1212693109 |
0.478 |
|
| 2012 |
McDonald AR, Van Heuvelen KM, Guo Y, Li F, Bominaar EL, Münck E, Que L. Characterization of a thiolato iron(III) Peroxy dianion complex. Angewandte Chemie (International Ed. in English). 51: 9132-6. PMID 22888066 DOI: 10.1002/Anie.201203602 |
0.808 |
|
| 2012 |
Mas-Ballesté R, McDonald AR, Reed D, Usharani D, Schyman P, Milko P, Shaik S, Que L. Intramolecular gas-phase reactions of synthetic nonheme oxoiron(IV) ions: Proximity and spin-state reactivity rules Chemistry - a European Journal. 18: 11747-11760. PMID 22837063 DOI: 10.1002/Chem.201200105 |
0.789 |
|
| 2012 |
Van Heuvelen KM, Fiedler AT, Shan X, De Hont RF, Meier KK, Bominaar EL, Münck E, Que L. One-electron oxidation of an oxoiron(IV) complex to form an [O═FeV═NR]+ center. Proceedings of the National Academy of Sciences of the United States of America. 109: 11933-8. PMID 22786933 DOI: 10.1073/Pnas.1206457109 |
0.881 |
|
| 2012 |
Huo L, Fielding AJ, Chen Y, Li T, Iwaki H, Hosler JP, Chen L, Hasegawa Y, Que L, Liu A. Evidence for a dual role of an active site histidine in α-amino-β-carboxymuconate-ε-semialdehyde decarboxylase. Biochemistry. 51: 5811-21. PMID 22746257 DOI: 10.1021/Bi300635B |
0.815 |
|
| 2012 |
Li F, Chakrabarti M, Dong Y, Kauffmann K, Bominaar EL, Münck E, Que L. Structural, EPR, and Mössbauer characterization of (μ-alkoxo)(μ-carboxylato)diiron(II,III) model complexes for the active sites of mixed-valent diiron enzymes. Inorganic Chemistry. 51: 2917-29. PMID 22360600 DOI: 10.1021/Ic2021726 |
0.778 |
|
| 2012 |
Do LH, Xue G, Que L, Lippard SJ. Evaluating the identity and diiron core transformations of a (μ-oxo)diiron(III) complex supported by electron-rich tris(pyridyl-2-methyl)amine ligands. Inorganic Chemistry. 51: 2393-402. PMID 22264120 DOI: 10.1021/Ic202379B |
0.463 |
|
| 2012 |
Fielding AJ, Lipscomb JD, Que L. Characterization of an O2 adduct of an active cobalt-substituted extradiol-cleaving catechol dioxygenase. Journal of the American Chemical Society. 134: 796-9. PMID 22175783 DOI: 10.1021/Ja2095365 |
0.845 |
|
| 2011 |
Paria S, Que L, Paine TK. Oxidative decarboxylation of benzilic acid by a biomimetic iron(II) complex: evidence for an iron(IV)-oxo-hydroxo oxidant from O2. Angewandte Chemie (International Ed. in English). 50: 11129-32. PMID 21956868 DOI: 10.1002/Anie.201103971 |
0.855 |
|
| 2011 |
Chandrasekaran P, Stieber SC, Collins TJ, Que L, Neese F, DeBeer S. Prediction of high-valent iron K-edge absorption spectra by time-dependent density functional theory. Dalton Transactions (Cambridge, England : 2003). 40: 11070-9. PMID 21956429 DOI: 10.1039/C1Dt11331C |
0.473 |
|
| 2011 |
McDonald AR, Que L. Iron-oxo complexes: elusive iron(V) species identified. Nature Chemistry. 3: 761-2. PMID 21941247 DOI: 10.1038/Nchem.1153 |
0.723 |
|
| 2011 |
Xue G, Pokutsa A, Que L. Substrate-triggered activation of a synthetic [Fe2(μ-O)2] diamond core for C-H bond cleavage. Journal of the American Chemical Society. 133: 16657-67. PMID 21899336 DOI: 10.1021/ja207131g |
0.542 |
|
| 2011 |
England J, Guo Y, Van Heuvelen KM, Cranswick MA, Rohde GT, Bominaar EL, Münck E, Que L. A more reactive trigonal-bipyramidal high-spin oxoiron(IV) complex with a cis-labile site. Journal of the American Chemical Society. 133: 11880-3. PMID 21739994 DOI: 10.1021/Ja2040909 |
0.693 |
|
| 2011 |
Hirao H, Li F, Que L, Morokuma K. Theoretical study of the mechanism of oxoiron(IV) formation from H2O2 and a nonheme iron(II) complex: O-O cleavage involving proton-coupled electron transfer. Inorganic Chemistry. 50: 6637-48. PMID 21678930 DOI: 10.1021/ic200522r |
0.495 |
|
| 2011 |
Li F, Meier KK, Cranswick MA, Chakrabarti M, Van Heuvelen KM, Münck E, Que L. Characterization of a high-spin non-heme Fe(III)-OOH intermediate and its quantitative conversion to an Fe(IV)═O complex. Journal of the American Chemical Society. 133: 7256-9. PMID 21517091 DOI: 10.1021/Ja111742Z |
0.879 |
|
| 2011 |
Vu VV, Makris TM, Lipscomb JD, Que L. Active-site structure of a β-hydroxylase in antibiotic biosynthesis. Journal of the American Chemical Society. 133: 6938-41. PMID 21506543 DOI: 10.1021/Ja201822V |
0.739 |
|
| 2011 |
England J, Farquhar ER, Guo Y, Cranswick MA, Ray K, Münck E, Que L. Characterization of a tricationic trigonal bipyramidal iron(IV) cyanide complex, with a very high reduction potential, and its iron(II) and iron(III) congeners. Inorganic Chemistry. 50: 2885-96. PMID 21381646 DOI: 10.1021/Ic102094D |
0.876 |
|
| 2011 |
Wong SD, Bell CB, Liu LV, Kwak Y, England J, Alp EE, Zhao J, Que L, Solomon EI. Nuclear resonance vibrational spectroscopy on the FeIV=O S=2 non-heme site in TMG3tren: Experimentally calibrated insights into reactivity Angewandte Chemie - International Edition. 50: 3215-3218. PMID 21370371 DOI: 10.1002/Anie.201007692 |
0.403 |
|
| 2011 |
Farquhar ER, Emerson JP, Koehntop KD, Reynolds MF, Trmčić M, Que L. In vivo self-hydroxylation of an iron-substituted manganese-dependent extradiol cleaving catechol dioxygenase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 16: 589-97. PMID 21279661 DOI: 10.1007/S00775-011-0760-4 |
0.848 |
|
| 2011 |
Company A, Prat I, Frisch JR, Mas-Ballesté R, Güell M, Juhász G, Ribas X, Münck E, Luis JM, Que L, Costas M. Modeling the cis-oxo-labile binding site motif of non-heme iron oxygenases: water exchange and oxidation reactivity of a non-heme iron(IV)-oxo compound bearing a tripodal tetradentate ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 1622-34. PMID 21268165 DOI: 10.1002/Chem.201002297 |
0.832 |
|
| 2011 |
Fielding AJ, Kovaleva EG, Farquhar ER, Lipscomb JD, Que L. A hyperactive cobalt-substituted extradiol-cleaving catechol dioxygenase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 16: 341-55. PMID 21153851 DOI: 10.1007/S00775-010-0732-0 |
0.852 |
|
| 2011 |
Das P, Que L. Iron catalyzed competitive olefin oxidation and ipso-hydroxylation of benzoic acids: further evidence for an Fe(V)═O oxidant. Inorganic Chemistry. 49: 9479-85. PMID 20866083 DOI: 10.1021/ic101144s |
0.51 |
|
| 2010 |
Oldenburg PD, Feng Y, Pryjomska-Ray I, Ness D, Que L. Olefin cis-dihydroxylation with bio-inspired iron catalysts. evidence for an Fe(II)/Fe(IV) catalytic cycle. Journal of the American Chemical Society. 132: 17713-23. PMID 21105649 DOI: 10.1021/Ja1021014 |
0.87 |
|
| 2010 |
McDonald AR, Bukowski MR, Farquhar ER, Jackson TA, Koehntop KD, Seo MS, De Hont RF, Stubna A, Halfen JA, Münck E, Nam W, Que L. Sulfur versus iron oxidation in an iron-thiolate model complex. Journal of the American Chemical Society. 132: 17118-29. PMID 21070030 DOI: 10.1021/Ja1045428 |
0.867 |
|
| 2010 |
De Hont RF, Xue G, Hendrich MP, Que L, Bominaar EL, Münck E. Mössbauer, electron paramagnetic resonance, and density functional theory studies of synthetic S = 1/2 Fe(III)-O-Fe(IV)â•O complexes. Superexchange-mediated spin transition at the Fe(IV)â•O site. Inorganic Chemistry. 49: 8310-22. PMID 20795646 DOI: 10.1021/Ic100870V |
0.861 |
|
| 2010 |
England J, Guo Y, Farquhar ER, Young VG, Münck E, Que L. The crystal structure of a high-spin oxoiron(IV) complex and characterization of its self-decay pathway. Journal of the American Chemical Society. 132: 8635-44. PMID 20568768 DOI: 10.1021/Ja100366C |
0.794 |
|
| 2010 |
Wang D, Zhang M, Bühlmann P, Que L. Redox potential and C-H bond cleaving properties of a nonheme Fe(IV)=O complex in aqueous solution. Journal of the American Chemical Society. 132: 7638-44. PMID 20476758 DOI: 10.1021/Ja909923W |
0.517 |
|
| 2010 |
Xue G, De Hont R, Münck E, Que L. Million-fold activation of the [Fe(2)(micro-O)(2)] diamond core for C-H bond cleavage. Nature Chemistry. 2: 400-5. PMID 20414242 DOI: 10.1038/Nchem.586 |
0.879 |
|
| 2010 |
Mukherjee A, Cranswick MA, Chakrabarti M, Paine TK, Fujisawa K, Münck E, Que L. Oxygen activation at mononuclear nonheme iron centers: a superoxo perspective. Inorganic Chemistry. 49: 3618-28. PMID 20380464 DOI: 10.1021/Ic901891N |
0.814 |
|
| 2010 |
Janardanan D, Wang Y, Schyman P, Que L, Shaik S. The fundamental role of exchange-enhanced reactivity in C-H activation by S = 2 oxo iron(IV) complexes Angewandte Chemie - International Edition. 49: 3342-3345. PMID 20358569 DOI: 10.1002/Anie.201000004 |
0.49 |
|
| 2010 |
Torres Martin De Rosales R, Faiella M, Farquhar E, Que L, Andreozzi C, Pavone V, Maglio O, Nastri F, Lombardi A. Spectroscopic and metal-binding properties of DF3: An artificial protein able to accommodate different metal ions Journal of Biological Inorganic Chemistry. 15: 717-728. PMID 20225070 DOI: 10.1007/S00775-010-0639-9 |
0.703 |
|
| 2010 |
Paine TK, Paria S, Que L. Oxidative decarboxylation of alpha-hydroxy acids by a functional model of the nonheme iron oxygenase, CloR. Chemical Communications (Cambridge, England). 46: 1830-2. PMID 20198223 DOI: 10.1039/B925389K |
0.838 |
|
| 2010 |
Garcia-Bosch I, Company A, Frisch JR, Torrent-Sucarrat M, Cardellach M, Gamba I, Güell M, Casella L, Que L, Ribas X, Luis JM, Costas M. O2 activation and selective phenolate ortho hydroxylation by an unsymmetric dicopper mu-eta1:eta1-peroxido complex. Angewandte Chemie (International Ed. in English). 49: 2406-9. PMID 20191646 DOI: 10.1002/Anie.200906749 |
0.765 |
|
| 2010 |
Li F, England J, Que L. Near-stoichiometric conversion of H(2)O(2) to Fe(IV)=O at a nonheme iron(II) center. Insights into the O-O bond cleavage step. Journal of the American Chemical Society. 132: 2134-5. PMID 20121136 DOI: 10.1021/ja9101908 |
0.498 |
|
| 2009 |
Wang D, Farquhar ER, Stubna A, Münck E, Que L. A diiron(IV) complex that cleaves strong C-H and O-H bonds. Nature Chemistry. 1: 145-50. PMID 19885382 DOI: 10.1038/Nchem.162 |
0.862 |
|
| 2009 |
Makhlynets OV, Das P, Taktak S, Flook M, Mas-Ballesté R, Rybak-Akimova EV, Que L. Iron-promoted ortho-And/or ipso-hydroxylation of benzoic acids with H 2O2 Chemistry - a European Journal. 15: 13171-13180. PMID 19876966 DOI: 10.1002/Chem.200901296 |
0.546 |
|
| 2009 |
Fiedler AT, Que L. Reactivities of Fe(IV) complexes with oxo, hydroxo, and alkylperoxo ligands: an experimental and computational study. Inorganic Chemistry. 48: 11038-47. PMID 19863068 DOI: 10.1021/Ic901391Y |
0.527 |
|
| 2009 |
Costas M, Que L. Ligand topology tuning of iron-catalyzed hydrocarbon oxidations. Angewandte Chemie (International Ed. in English). 41: 2179-81. PMID 19746637 |
0.36 |
|
| 2009 |
Vu VV, Emerson JP, Martinho M, Kim YS, Münck E, Park MH, Que L. Human deoxyhypusine hydroxylase, an enzyme involved in regulating cell growth, activates O2 with a nonheme diiron center. Proceedings of the National Academy of Sciences of the United States of America. 106: 14814-9. PMID 19706422 DOI: 10.1073/Pnas.0904553106 |
0.815 |
|
| 2009 |
Johansson AJ, Noack H, Siegbahn PE, Xue G, Que L. Observed enhancement of the reactivity of a biomimetic diiron complex by the addition of water - mechanistic insights from theoretical modeling. Dalton Transactions (Cambridge, England : 2003). 6741-50. PMID 19690685 DOI: 10.1039/b907263b |
0.463 |
|
| 2009 |
Frisch JR, Vu VV, Martinho M, Münck E, Que L. Characterization of two distinct adducts in the reaction of a nonheme diiron(II) complex with O2. Inorganic Chemistry. 48: 8325-36. PMID 19610611 DOI: 10.1021/Ic900961K |
0.832 |
|
| 2009 |
England J, Martinho M, Farquhar ER, Frisch JR, Bominaar EL, Münck E, Que L. A synthetic high-spin oxoiron(IV) complex: generation, spectroscopic characterization, and reactivity. Angewandte Chemie (International Ed. in English). 48: 3622-6. PMID 19373820 DOI: 10.1002/Anie.200900863 |
0.857 |
|
| 2009 |
Martinho M, Xue G, Fiedler AT, Que L, Bominaar EL, Münck E. Mössbauer and DFT study of the ferromagnetically coupled diiron(IV) precursor to a complex with an Fe(IV)(2)O(2) diamond core. Journal of the American Chemical Society. 131: 5823-30. PMID 19338307 DOI: 10.1021/Ja8098917 |
0.518 |
|
| 2009 |
Company A, Feng Y, Güell M, Ribas X, Luis JM, Que L, Costas M. Olefin-dependent discrimination between two nonheme HO-FeV=O tautomeric species in catalytic H2O2 epoxidations. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 3359-62. PMID 19229926 DOI: 10.1002/Chem.200802597 |
0.436 |
|
| 2009 |
Mukherjee A, Martinho M, Bominaar EL, Münck E, Que L. Shape-selective interception by hydrocarbons of the O2-derived oxidant of a biomimetic nonheme iron complex. Angewandte Chemie (International Ed. in English). 48: 1780-3. PMID 19180613 DOI: 10.1002/Anie.200805342 |
0.675 |
|
| 2009 |
Klinker EJ, Shaik S, Hirao H, Que L. A two-state reactivity model explains unusual kinetic isotope effect patterns in C-H bond cleavage by nonheme oxoiron(IV) complexes. Angewandte Chemie (International Ed. in English). 48: 1291-5. PMID 19130517 DOI: 10.1002/Anie.200804029 |
0.79 |
|
| 2009 |
Feng Y, Ke CY, Xue G, Que L. Bio-inspired arene cis-dihydroxylation by a non-haem iron catalyst modeling the action of naphthalene dioxygenase. Chemical Communications (Cambridge, England). 50-2. PMID 19081995 DOI: 10.1039/b817222f |
0.407 |
|
| 2008 |
Bell CB, Wong SD, Xiao Y, Klinker EJ, Tenderholt AL, Smith MC, Rohde JU, Que L, Cramer SP, Solomon EI. A combined NRVS and DFT study of Fe(IV)=O model complexes: a diagnostic method for the elucidation of non-heme iron enzyme intermediates. Angewandte Chemie (International Ed. in English). 47: 9071-4. PMID 18925598 DOI: 10.1002/Anie.200803740 |
0.877 |
|
| 2008 |
Gunderson WA, Zatsman AI, Emerson JP, Farquhar ER, Que L, Lipscomb JD, Hendrich MP. Electron paramagnetic resonance detection of intermediates in the enzymatic cycle of an extradiol dioxygenase. Journal of the American Chemical Society. 130: 14465-7. PMID 18839948 DOI: 10.1021/Ja8052255 |
0.827 |
|
| 2008 |
Fiedler AT, Shan X, Mehn MP, Kaizer J, Torelli S, Frisch JR, Kodera M, Que L. Spectroscopic and computational studies of (mu-oxo)(mu-1,2-peroxo)diiron(III) complexes of relevance to nonheme diiron oxygenase intermediates. The Journal of Physical Chemistry. A. 112: 13037-44. PMID 18811130 DOI: 10.1021/Jp8038225 |
0.876 |
|
| 2008 |
Ray K, England J, Fiedler AT, Martinho M, Münck E, Que L. An inverted and more oxidizing isomer of [Fe(IV)(O)(tmc)(NCCH3)]2+. Angewandte Chemie (International Ed. in English). 47: 8068-71. PMID 18798182 DOI: 10.1002/Anie.200802219 |
0.811 |
|
| 2008 |
Jackson TA, Rohde JU, Seo MS, Sastri CV, DeHont R, Stubna A, Ohta T, Kitagawa T, Münck E, Nam W, Que L. Axial ligand effects on the geometric and electronic structures of nonheme oxoiron(IV) complexes. Journal of the American Chemical Society. 130: 12394-407. PMID 18712873 DOI: 10.1021/Ja8022576 |
0.877 |
|
| 2008 |
Thibon A, England J, Martinho M, Young VG, Frisch JR, Guillot R, Girerd JJ, Münck E, Que L, Banse F. Proton- and reductant-assisted dioxygen activation by a nonheme iron(II) complex to form an oxoiron(IV) intermediate. Angewandte Chemie (International Ed. in English). 47: 7064-7. PMID 18677790 DOI: 10.1002/Anie.200801832 |
0.87 |
|
| 2008 |
Emerson JP, Kovaleva EG, Farquhar ER, Lipscomb JD, Que L. Swapping metals in Fe- and Mn-dependent dioxygenases: evidence for oxygen activation without a change in metal redox state. Proceedings of the National Academy of Sciences of the United States of America. 105: 7347-52. PMID 18492808 DOI: 10.1073/Pnas.0711179105 |
0.842 |
|
| 2008 |
Shan X, Que L. Unexpected kinetic complexity in the formation of a nonheme oxoiron(IV) complex. Chemical Communications (Cambridge, England). 2209-11. PMID 18463742 DOI: 10.1039/b716036d |
0.377 |
|
| 2008 |
Ray K, Lee SM, Que L. Iron-oxidation-state-dependent O-O bond cleavage of meta-chloroperbenzoic acid to form an iron(IV)-oxo complex. Inorganica Chimica Acta. 361: 1066-1069. PMID 18443654 DOI: 10.1016/j.ica.2007.07.039 |
0.768 |
|
| 2008 |
Krzystek J, England J, Ray K, Ozarowski A, Smirnov D, Que L, Telser J. Determination by high-frequency and -field EPR of zero-field splitting in iron(IV) oxo complexes: implications for intermediates in nonheme iron enzymes. Inorganic Chemistry. 47: 3483-5. PMID 18386920 DOI: 10.1021/Ic800411C |
0.721 |
|
| 2008 |
Chanda A, Shan X, Chakrabarti M, Ellis WC, Popescu DL, Tiago de Oliveira F, Wang D, Que L, Collins TJ, Münck E, Bominaar EL. (TAML)FeIV O complex in aqueous solution: synthesis and spectroscopic and computational characterization. Inorganic Chemistry. 47: 3669-78. PMID 18380453 DOI: 10.1021/Ic7022902 |
0.871 |
|
| 2008 |
Mas-Balleste R, Fujita M, Que L. High-valent iron-mediated cis-hydroxyacetoxylation of olefins. Dalton Transactions (Cambridge, England : 2003). 1828-30. PMID 18369488 DOI: 10.1039/b802587h |
0.418 |
|
| 2008 |
Suzuki K, Oldenburg PD, Que L. Iron-catalyzed asymmetric olefin cis-dihydroxylation with 97% enantiomeric excess. Angewandte Chemie (International Ed. in English). 47: 1887-9. PMID 18236485 DOI: 10.1002/Anie.200705061 |
0.811 |
|
| 2008 |
Zhou Y, Shan X, Mas-Ballesté R, Bukowski MR, Stubna A, Chakrabarti M, Slominski L, Halfen JA, Münck E, Que L. Contrasting cis and trans effects on the reactivity of nonheme oxoiron(IV) complexes. Angewandte Chemie (International Ed. in English). 47: 1896-9. PMID 18228548 DOI: 10.1002/Anie.200704228 |
0.788 |
|
| 2008 |
Friese SJ, Kucera BE, Young VG, Que L, Tolman WB. Iron(II) complexes of sterically bulky alpha-ketocarboxylates. structural models for alpha-ketoacid-dependent nonheme iron halogenases. Inorganic Chemistry. 47: 1324-31. PMID 18217706 DOI: 10.1021/Ic701823Y |
0.496 |
|
| 2008 |
Hirao H, Que L, Nam W, Shaik S. A two-state reactivity rationale for counterintuitive axial ligand effects on the C-H activation reactivity of nonheme FeIV=O oxidants. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 1740-56. PMID 18186094 DOI: 10.1002/Chem.200701739 |
0.499 |
|
| 2007 |
Smith AL, Day CS, Que L, Zhou Y, Bierbach U. Unexpected Assembly of a Novel Triply Bridged Diiron(II) Core by a Bidentate Schiff Base Ligand. Inorganica Chimica Acta. 360: 2824-2828. PMID 19626127 DOI: 10.1016/j.ica.2007.01.001 |
0.711 |
|
| 2007 |
Xue G, Wang D, De Hont R, Fiedler AT, Shan X, Münck E, Que L. A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q. Proceedings of the National Academy of Sciences of the United States of America. 104: 20713-8. PMID 18093922 DOI: 10.1073/Pnas.0708516105 |
0.858 |
|
| 2007 |
Company A, Gómez L, Güell M, Ribas X, Luis JM, Que L, Costas M. Alkane hydroxylation by a nonheme iron catalyst that challenges the heme paradigm for oxygenase action. Journal of the American Chemical Society. 129: 15766-7. PMID 18052284 DOI: 10.1021/Ja077761N |
0.314 |
|
| 2007 |
Decker A, Rohde JU, Klinker EJ, Wong SD, Que L, Solomon EI. Spectroscopic and quantum chemical studies on low-spin FeIV=O complexes: Fe-O bonding and its contributions to reactivity. Journal of the American Chemical Society. 129: 15983-96. PMID 18052249 DOI: 10.1021/Ja074900S |
0.868 |
|
| 2007 |
Mas-Ballesté R, Que L. Iron-catalyzed olefin epoxidation in the presence of acetic acid: insights into the nature of the metal-based oxidant. Journal of the American Chemical Society. 129: 15964-72. PMID 18052063 DOI: 10.1021/ja075115i |
0.487 |
|
| 2007 |
Sastri CV, Lee J, Oh K, Lee YJ, Lee J, Jackson TA, Ray K, Hirao H, Shin W, Halfen JA, Kim J, Que L, Shaik S, Nam W. Axial ligand tuning of a nonheme iron(IV)-oxo unit for hydrogen atom abstraction. Proceedings of the National Academy of Sciences of the United States of America. 104: 19181-6. PMID 18048327 DOI: 10.1073/Pnas.0709471104 |
0.819 |
|
| 2007 |
Emerson JP, Farquhar ER, Que L. Structural "snapshots" along reaction pathways of non-heme iron enzymes. Angewandte Chemie (International Ed. in English). 46: 8553-6. PMID 17924385 DOI: 10.1002/Anie.200703057 |
0.76 |
|
| 2007 |
Shan X, Rohde JU, Koehntop KD, Zhou Y, Bukowski MR, Costas M, Fujisawa K, Que L. X-ray absorption spectroscopic studies of high-spin nonheme (alkylperoxo)iron(III) intermediates. Inorganic Chemistry. 46: 8410-7. PMID 17764172 DOI: 10.1021/Ic700649W |
0.849 |
|
| 2007 |
Klotz KL, Slominski LM, Hull AV, Gottsacker VM, Mas-Ballesté R, Que L, Halfen JA. Non-heme iron(II) complexes are efficient olefin aziridination catalysts. Chemical Communications (Cambridge, England). 2063-5. PMID 17713079 DOI: 10.1039/b700493a |
0.413 |
|
| 2007 |
Que L. The road to non-heme oxoferryls and beyond. Accounts of Chemical Research. 40: 493-500. PMID 17595051 DOI: 10.1021/ar700024g |
0.426 |
|
| 2007 |
Rohde JU, Betley TA, Jackson TA, Saouma CT, Peters JC, Que L. XAS characterization of a nitridoiron(IV) complex with a very short Fe-N bond. Inorganic Chemistry. 46: 5720-6. PMID 17569533 DOI: 10.1021/Ic700818Q |
0.749 |
|
| 2007 |
Company A, Gómez L, Mas-Ballesté R, Korendovych IV, Ribas X, Poater A, Parella T, Fontrodona X, Benet-Buchholz J, Solà M, Que L, Rybak-Akimova EV, Costas M. Fast O2 binding at dicopper complexes containing Schiff-base dinucleating ligands Inorganic Chemistry. 46: 4997-5012. PMID 17500512 DOI: 10.1021/Ic0701108 |
0.381 |
|
| 2007 |
Paine TK, England J, Que L. Iron-catalyzed C2-C3 bond cleavage of phenylpyruvate with O2: insight into aliphatic C-C bond-cleaving dioxygenases. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 6073-81. PMID 17469086 DOI: 10.1002/Chem.200601844 |
0.729 |
|
| 2007 |
Jensen MP, Payeras AM, Fiedler AT, Costas M, Kaizer J, Stubna A, Münck E, Que L. Kinetic analysis of the conversion of nonheme (alkylperoxo)iron(III) species to iron(IV) complexes. Inorganic Chemistry. 46: 2398-408. PMID 17326618 DOI: 10.1021/Ic0607787 |
0.845 |
|
| 2007 |
Tiago de Oliveira F, Chanda A, Banerjee D, Shan X, Mondal S, Que L, Bominaar EL, Münck E, Collins TJ. Chemical and spectroscopic evidence for an FeV-oxo complex. Science (New York, N.Y.). 315: 835-8. PMID 17185561 DOI: 10.1126/Science.1133417 |
0.863 |
|
| 2007 |
Mas-Ballesté R, Costas M, van den Berg T, Que L. Ligand topology effects on olefin oxidations by bio-inspired [FeII(N2Py2)] catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 7489-500. PMID 16871511 DOI: 10.1002/chem.200600453 |
0.318 |
|
| 2006 |
Oldenburg PD, Ke CY, Tipton AA, Shteinman AA, Que L. A structural and functional model for dioxygenases with a 2-His-1-carboxylate triad. Angewandte Chemie (International Ed. in English). 45: 7975-8. PMID 17096444 DOI: 10.1002/Anie.200603486 |
0.763 |
|
| 2006 |
Klinker EJ, Jackson TA, Jensen MP, Stubna A, Juhász G, Bominaar EL, Münck E, Que L. A tosylimido analogue of a nonheme oxoiron(IV) complex. Angewandte Chemie (International Ed. in English). 45: 7394-7. PMID 17039556 DOI: 10.1002/Anie.200602799 |
0.804 |
|
| 2006 |
Collins MJ, Ray K, Que L. electrochemical generation of a nonheme oxoiron(IV) complex. Inorganic Chemistry. 45: 8009-11. PMID 16999397 DOI: 10.1021/ic061263i |
0.734 |
|
| 2006 |
Klein DP, Young VG, Tolman WB, Que L. Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands. Inorganic Chemistry. 45: 8006-8. PMID 16999396 DOI: 10.1021/Ic0610740 |
0.476 |
|
| 2006 |
Friese SJ, Kucera BE, Que L, Tolman WB. Self-assembly of the 2-His-1-carboxylate facial triad in mononuclear iron(II) and zinc(II) models of metalloenzyme active sites. Inorganic Chemistry. 45: 8003-5. PMID 16999395 DOI: 10.1021/Ic061564S |
0.401 |
|
| 2006 |
Mehn MP, Brown SD, Jenkins DM, Peters JC, Que L. Vibrational spectroscopy and analysis of pseudo-tetrahedral complexes with metal imido bonds. Inorganic Chemistry. 45: 7417-27. PMID 16933946 DOI: 10.1021/Ic060670R |
0.781 |
|
| 2006 |
Bautz J, Comba P, Que L. Spin-crossover in an iron(III)-bispidine-alkylperoxide system. Inorganic Chemistry. 45: 7077-82. PMID 16933906 DOI: 10.1021/Ic0602401 |
0.395 |
|
| 2006 |
Rohde JU, Stubna A, Bominaar EL, Münck E, Nam W, Que L. Nonheme oxoiron(IV) complexes of tris(2-pyridylmethyl)amine with cis-monoanionic ligands. Inorganic Chemistry. 45: 6435-45. PMID 16878956 DOI: 10.1021/Ic060740U |
0.874 |
|
| 2006 |
Bautz J, Bukowski MR, Kerscher M, Stubna A, Comba P, Lienke A, Münck E, Que L. Formation of an aqueous oxoiron(IV) complex at pH 2-6 from a nonheme iron(II) complex and H2O2. Angewandte Chemie (International Ed. in English). 45: 5681-4. PMID 16858708 DOI: 10.1002/Anie.200601134 |
0.838 |
|
| 2006 |
Jensen MP, Que EL, Shan X, Rybak-Akimova E, Que L. Spectroscopic and kinetic studies of the reaction of [Cu I(6-PhTPA)]+ with O2 Dalton Transactions. 3523-3527. PMID 16855753 DOI: 10.1039/B603285K |
0.7 |
|
| 2006 |
Company A, Lamata D, Poater A, Solà M, Rybak-Akimova EV, Que L, Fontrodona X, Parella T, Llobet A, Costas M. O2 chemistry of dicopper complexes with alkyltriamine ligands. Comparing synergistic effects on O2 binding. Inorganic Chemistry. 45: 5239-41. PMID 16813375 DOI: 10.1021/Ic0602446 |
0.377 |
|
| 2006 |
Hirao H, Kumar D, Que L, Shaik S. Two-state reactivity in alkane hydroxylation by non-heme iron-oxo complexes. Journal of the American Chemical Society. 128: 8590-606. PMID 16802826 DOI: 10.1021/Ja061609O |
0.482 |
|
| 2006 |
Bukowski MR, Comba P, Lienke A, Limberg C, Lopez de Laorden C, Mas-Ballesté R, Merz M, Que L. Catalytic epoxidation and 1,2-dihydroxylation of olefins with bispidine-iron(II)/H2O2 systems. Angewandte Chemie (International Ed. in English). 45: 3446-9. PMID 16637091 DOI: 10.1002/Anie.200504357 |
0.734 |
|
| 2006 |
Paine TK, Costas M, Kaizer J, Que L. Oxoiron(IV) complexes of the tris(2-pyridylmethyl)amine ligand family: effect of pyridine alpha-substituents. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 11: 272-6. PMID 16532334 DOI: 10.1007/S00775-006-0089-6 |
0.657 |
|
| 2006 |
Shan X, Que L. High-valent nonheme iron-oxo species in biomimetic oxidations. Journal of Inorganic Biochemistry. 100: 421-33. PMID 16530841 DOI: 10.1016/j.jinorgbio.2006.01.014 |
0.529 |
|
| 2006 |
Mehn MP, Brown SD, Paine TK, Brennessel WW, Cramer CJ, Peters JC, Que L. High-spin and low-spin iron(II) complexes with facially-coordinated borohydride ligands. Dalton Transactions (Cambridge, England : 2003). 1347-51. PMID 16505914 DOI: 10.1039/B509580H |
0.851 |
|
| 2006 |
Koehntop KD, Marimanikkuppam S, Ryle MJ, Hausinger RP, Que L. Self-hydroxylation of taurine/alpha-ketoglutarate dioxygenase: evidence for more than one oxygen activation mechanism. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 11: 63-72. PMID 16320009 DOI: 10.1007/S00775-005-0059-4 |
0.877 |
|
| 2005 |
Oh NY, Seo MS, Lim MH, Consugar MB, Park MJ, Rohde JU, Han J, Kim KM, Kim J, Que L, Nam W. Self-hydroxylation of perbenzoic acids at a nonheme iron(II) center. Chemical Communications (Cambridge, England). 5644-6. PMID 16292376 DOI: 10.1039/B511302D |
0.639 |
|
| 2005 |
Oldenburg PD, Shteinman AA, Que L. Iron-catalyzed olefin cis-dihydroxylation using a bio-inspired N,N,O-ligand. Journal of the American Chemical Society. 127: 15672-3. PMID 16277487 DOI: 10.1021/Ja054947I |
0.859 |
|
| 2005 |
Bukowski MR, Koehntop KD, Stubna A, Bominaar EL, Halfen JA, Münck E, Nam W, Que L. A thiolate-ligated nonheme oxoiron(IV) complex relevant to cytochrome P450. Science (New York, N.Y.). 310: 1000-2. PMID 16254150 DOI: 10.1126/Science.1119092 |
0.837 |
|
| 2005 |
Taktak S, Flook M, Foxman BM, Que L, Rybak-Akimova EV. Ortho-hydroxylation of benzoic acids with hydrogen peroxide at a non-heme iron center. Chemical Communications (Cambridge, England). 5301-3. PMID 16244735 DOI: 10.1039/B508004E |
0.406 |
|
| 2005 |
Emerson JP, Wagner ML, Reynolds MF, Que L, Sadowsky MJ, Wackett LP. The role of histidine 200 in MndD, the Mn(II)-dependent 3,4-dihydroxyphenylacetate 2,3-dioxygenase from Arthrobacter globiformis CM-2, a site-directed mutagenesis study. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 10: 751-60. PMID 16217642 DOI: 10.1007/S00775-005-0017-1 |
0.724 |
|
| 2005 |
Pestovsky O, Stoian S, Bominaar EL, Shan X, Münck E, Que L, Bakac A. Aqueous FeIV==O: spectroscopic identification and oxo-group exchange. Angewandte Chemie (International Ed. in English). 44: 6871-4. PMID 16206322 DOI: 10.1002/Anie.200502686 |
0.751 |
|
| 2005 |
Farquhar ER, Koehntop KD, Emerson JP, Que L. Post-translational self-hydroxylation: a probe for oxygen activation mechanisms in non-heme iron enzymes. Biochemical and Biophysical Research Communications. 338: 230-9. PMID 16165090 DOI: 10.1016/J.Bbrc.2005.08.191 |
0.835 |
|
| 2005 |
Sastri CV, Park MJ, Ohta T, Jackson TA, Stubna A, Seo MS, Lee J, Kim J, Kitagawa T, Münck E, Que L, Nam W. Axial ligand substituted nonheme FeIV=O complexes: observation of near-UV LMCT bands and Fe=O Raman vibrations. Journal of the American Chemical Society. 127: 12494-5. PMID 16144389 DOI: 10.1021/Ja0540573 |
0.862 |
|
| 2005 |
Jensen MP, Costas M, Ho RY, Kaizer J, Mairata i Payeras A, Münck E, Que L, Rohde JU, Stubna A. High-valent nonheme iron. Two distinct iron(IV) species derived from a common iron(II) precursor. Journal of the American Chemical Society. 127: 10512-25. PMID 16045338 DOI: 10.1021/Ja0438765 |
0.878 |
|
| 2005 |
Kumar D, Hirao H, Que L, Shaik S. Theoretical investigation of C--H hydroxylation by (N4Py)Fe(IV)=O(2+): an oxidant more powerful than P450? Journal of the American Chemical Society. 127: 8026-7. PMID 15926822 DOI: 10.1021/Ja0512428 |
0.567 |
|
| 2005 |
Klinker EJ, Kaizer J, Brennessel WW, Woodrum NL, Cramer CJ, Que L. Structures of nonheme oxoiron(IV) complexes from X-ray crystallography, NMR spectroscopy, and DFT calculations. Angewandte Chemie (International Ed. in English). 44: 3690-4. PMID 15915527 DOI: 10.1002/Anie.200500485 |
0.791 |
|
| 2005 |
Tierney DL, Rocklin AM, Lipscomb JD, Que L, Hoffman BM. ENDOR studies of the ligation and structure of the non-heme iron site in ACC oxidase. Journal of the American Chemical Society. 127: 7005-13. PMID 15884944 DOI: 10.1021/Ja0500862 |
0.873 |
|
| 2005 |
Quiñonero D, Morokuma K, Musaev DG, Mas-Ballesté R, Que L. Metal-peroxo versus metal-oxo oxidants in non-heme iron-catalyzed olefin oxidations: computational and experimental studies on the effect of water. Journal of the American Chemical Society. 127: 6548-9. PMID 15869272 DOI: 10.1021/Ja051062Y |
0.425 |
|
| 2005 |
Bassan A, Blomberg MR, Siegbahn PE, Que L. Two faces of a biomimetic non-heme HO-Fe(v)=O oxidant: olefin epoxidation versus cis-dihydroxylation. Angewandte Chemie (International Ed. in English). 44: 2939-41. PMID 15812868 DOI: 10.1002/anie.200463072 |
0.421 |
|
| 2005 |
Shan X, Que L. Intermediates in the oxygenation of a nonheme diiron(II) complex, including the first evidence for a bound superoxo species. Proceedings of the National Academy of Sciences of the United States of America. 102: 5340-5. PMID 15802473 DOI: 10.1073/pnas.0409640102 |
0.482 |
|
| 2005 |
Rohde JU, Que L. Axial coordination of carboxylate activates the non-heme FeIV=O unit. Angewandte Chemie (International Ed. in English). 44: 2255-8. PMID 15739239 DOI: 10.1002/anie.200462631 |
0.612 |
|
| 2005 |
Koehntop KD, Emerson JP, Que L. The 2-His-1-carboxylate facial triad: a versatile platform for dioxygen activation by mononuclear non-heme iron(II) enzymes. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 10: 87-93. PMID 15739104 DOI: 10.1007/S00775-005-0624-X |
0.833 |
|
| 2005 |
Paine TK, Zheng H, Que L. Iron Coordination Chemistry of Phenylpyruvate: An Unexpected kappa3-bridging mode that leads to oxidative cleavage of the C2-C3 bond. Inorganic Chemistry. 44: 474-6. PMID 15679371 DOI: 10.1021/Ic048427K |
0.722 |
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| 2005 |
Kryatov SV, Taktak S, Korendovych IV, Rybak-Akimova EV, Kaizer J, Torelli S, Shan X, Mandal S, MacMurdo VL, Mairata i Payeras A, Que L. Dioxygen binding to complexes with Fe(II)2(mu-OH)2 cores: steric control of activation barriers and O2-adduct formation. Inorganic Chemistry. 44: 85-99. PMID 15627364 DOI: 10.1021/Ic0485312 |
0.867 |
|
| 2005 |
Bukowski MR, Halfen HL, van den Berg TA, Halfen JA, Que L. Spin-state rationale for the peroxo-stabilizing role of the thiolate ligand in superoxide reductase. Angewandte Chemie (International Ed. in English). 44: 584-7. PMID 15602754 DOI: 10.1002/Anie.200461527 |
0.652 |
|
| 2005 |
Bassan A, Blomberg MRA, Siegbahn PEM, Que L. A density functional study on a biomimetic non-heme iron catalyst: Insights into alkane hydroxylation by a formally HO-Fev=O oxidant Chemistry - a European Journal. 11: 692-705. PMID 15580652 DOI: 10.1002/chem.200400383 |
0.517 |
|
| 2004 |
Rohde JU, Torelli S, Shan X, Lim MH, Klinker EJ, Kaizer J, Chen K, Nam W, Que L. Structural insights into nonheme alkylperoxoiron(III) and oxoiron(IV) intermediates by X-ray absorption spectroscopy. Journal of the American Chemical Society. 126: 16750-61. PMID 15612713 DOI: 10.1021/Ja047667W |
0.88 |
|
| 2004 |
Koehntop KD, Rohde JU, Costas M, Que L. XAS characterization of end-on and side-on peroxoiron(III) complexes of the neutral pentadentate N-donor ligand N-methyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine. Dalton Transactions (Cambridge, England : 2003). 3191-8. PMID 15483700 DOI: 10.1039/B409727K |
0.87 |
|
| 2004 |
Mairata i Payeras A, Ho RY, Fujita M, Que L. The reaction of [FeII(tpa)] with H2O2 in acetonitrile and acetone--distinct intermediates and yet similar catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 4944-53. PMID 15372680 DOI: 10.1002/chem.200400480 |
0.508 |
|
| 2004 |
Liu P, Mehn MP, Yan F, Zhao Z, Que L, Liu HW. Oxygenase activity in the self-hydroxylation of (s)-2-hydroxypropylphosphonic acid epoxidase involved in fosfomycin biosynthesis. Journal of the American Chemical Society. 126: 10306-12. PMID 15315444 DOI: 10.1021/Ja0475050 |
0.819 |
|
| 2004 |
Que L. The oxo/peroxo debate: a nonheme iron perspective. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 684-90. PMID 15300470 DOI: 10.1007/s00775-004-0574-8 |
0.383 |
|
| 2004 |
Stubna A, Jo DH, Costas M, Brenessel WW, Andres H, Bominaar EL, Münck E, Que L. A structural and Mössbauer study of complexes with Fe(2)(micro-O(H))(2) cores: stepwise oxidation from Fe(II)(micro-OH)(2)Fe(II) through Fe(II)(micro-OH)(2)Fe(III) to Fe(III)(micro-O)(micro-OH)Fe(III). Inorganic Chemistry. 43: 3067-79. PMID 15132612 DOI: 10.1021/Ic030296K |
0.856 |
|
| 2004 |
Seo MS, In JH, Kim SO, Oh NY, Hong J, Kim J, Que L, Nam W. Direct evidence for oxygen-atom exchange between nonheme oxoiron(IV) complexes and isotopically labeled water. Angewandte Chemie (International Ed. in English). 43: 2417-20. PMID 15114578 DOI: 10.1002/Anie.200353497 |
0.396 |
|
| 2004 |
Decker A, Rohde JU, Que L, Solomon EI. Spectroscopic and quantum chemical characterization of the electronic structure and bonding in a non-heme FeIV[double bond]O complex. Journal of the American Chemical Society. 126: 5378-9. PMID 15113207 DOI: 10.1021/Ja0498033 |
0.683 |
|
| 2004 |
Vetting MW, Wackett LP, Que L, Lipscomb JD, Ohlendorf DH. Crystallographic comparison of manganese- and iron-dependent homoprotocatechuate 2,3-dioxygenases. Journal of Bacteriology. 186: 1945-58. PMID 15028678 DOI: 10.1128/Jb.186.7.1945-1958.2004 |
0.579 |
|
| 2004 |
Kryatov SV, Chavez FA, Reynolds AM, Rybak-Akimova EV, Que L, Tolman WB. Mechanistic studies on the formation and reactivity of dioxygen adducts of diiron complexes supported by sterically hindered carboxylates. Inorganic Chemistry. 43: 2141-50. PMID 15018538 DOI: 10.1021/Ic049976T |
0.438 |
|
| 2004 |
Bukowski MR, Comba P, Limberg C, Merz M, Que L, Wistuba T. Bispidine ligand effects on iron/hydrogen peroxide chemistry. Angewandte Chemie (International Ed. in English). 43: 1283-7. PMID 14991800 DOI: 10.1002/Anie.200352523 |
0.721 |
|
| 2004 |
Costas M, Mehn MP, Jensen MP, Que L. Dioxygen activation at mononuclear nonheme iron active sites: enzymes, models, and intermediates. Chemical Reviews. 104: 939-86. PMID 14871146 DOI: 10.1021/Cr020628N |
0.769 |
|
| 2004 |
Ghosh A, Tangen E, Gonzalez E, Que L. Models of high-valent intermediates of non-heme diiron alkane monooxygenases: electronic structure of a bis(micro-oxo)diron(IV) complex with locally low-spin metal centers. Angewandte Chemie (International Ed. in English). 43: 834-8. PMID 14767952 DOI: 10.1002/Anie.200351768 |
0.805 |
|
| 2004 |
Kaizer J, Klinker EJ, Oh NY, Rohde JU, Song WJ, Stubna A, Kim J, Münck E, Nam W, Que L. Nonheme FeIVO complexes that can oxidize the C-H bonds of cyclohexane at room temperature. Journal of the American Chemical Society. 126: 472-3. PMID 14719937 DOI: 10.1021/Ja037288N |
0.821 |
|
| 2004 |
Rocklin AM, Kato K, Liu HW, Que L, Lipscomb JD. Mechanistic studies of 1-aminocyclopropane-1-carboxylic acid oxidase: single turnover reaction. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 171-82. PMID 14714198 DOI: 10.1007/S00775-003-0510-3 |
0.873 |
|
| 2004 |
Bukowski MR, Zhu S, Koehntop KD, Brennessel WW, Que L. Characterization of an Fe III-OOH species and its decomposition product in a bleomycin model system. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 39-48. PMID 14564557 DOI: 10.1007/S00775-003-0494-Z |
0.878 |
|
| 2004 |
Kaizer J, Costas M, Que L. A dramatic push effect on the homolysis of FeIII(OOR) intermediates to form non-heme FeIV=O complexes. Angewandte Chemie (International Ed. in English). 42: 3671-3. PMID 12916044 DOI: 10.1002/anie.200351694 |
0.397 |
|
| 2003 |
Nam W, Choi SK, Lim MH, Rohde JU, Kim I, Kim J, Kim C, Que L. Reversible formation of iodosylbenzene-iron porphyrin intermediates in the reaction of oxoiron(IV) porphyrin pi-cation radicals and iodobenzene. Angewandte Chemie (International Ed. in English). 42: 109-11. PMID 19757605 DOI: 10.1002/Anie.200390036 |
0.601 |
|
| 2003 |
Rohde JU, Bukowski MR, Que L. Functional models for mononuclear nonheme iron enzymes. Current Opinion in Chemical Biology. 7: 674-82. PMID 14644175 DOI: 10.1016/J.Cbpa.2003.10.008 |
0.786 |
|
| 2003 |
Costas M, Cady CW, Kryatov SV, Ray M, Ryan MJ, Rybak-Akimova EV, Que L. Role of carboxylate bridges in modulating nonheme diiron(II)/O(2) reactivity. Inorganic Chemistry. 42: 7519-30. PMID 14606847 DOI: 10.1021/Ic034359A |
0.758 |
|
| 2003 |
Skulan AJ, Hanson MA, Hsu HF, Dong Y, Que L, Solomon EI. EPR spectroscopy of [Fe2O2(5-Et3-TPA)2]3+: electronic origin of the unique spin-Hamiltonian parameters of the Fe2(III,IV)O2 diamond core. Inorganic Chemistry. 42: 6489-96. PMID 14514326 DOI: 10.1021/Ic034170Z |
0.469 |
|
| 2003 |
Jensen MP, Mehn MP, Que L. Intramolecular aromatic amination through iron-mediated nitrene transfer. Angewandte Chemie (International Ed. in English). 42: 4357-60. PMID 14502710 DOI: 10.1002/Anie.200351605 |
0.772 |
|
| 2003 |
Fujita M, Costas M, Que L. Iron-catalyzed olefin cis-dihydroxylation by H2O2: electrophilic versus nucleophilic mechanisms. Journal of the American Chemical Society. 125: 9912-3. PMID 12914440 DOI: 10.1021/ja029863d |
0.435 |
|
| 2003 |
Mehn MP, Fujisawa K, Hegg EL, Que L. Oxygen activation by nonheme iron(II) complexes: alpha-keto carboxylate versus carboxylate. Journal of the American Chemical Society. 125: 7828-42. PMID 12823001 DOI: 10.1021/Ja028867F |
0.815 |
|
| 2003 |
Skulan AJ, Hanson MA, Hsu HF, Que L, Solomon EI. Spectroscopic study of [Fe2O2(5-Et3-TPA)2]3+: nature of the Fe2O2 diamond core and its possible relevance to high-valent binuclear non-heme enzyme intermediates. Journal of the American Chemical Society. 125: 7344-56. PMID 12797809 DOI: 10.1021/Ja021137N |
0.504 |
|
| 2003 |
Roelfes G, Vrajmasu V, Chen K, Ho RY, Rohde JU, Zondervan C, La Crois RM, Schudde EP, Lutz M, Spek AL, Hage R, Feringa BL, Münck E, Que L. End-on and side-on peroxo derivatives of non-heme iron complexes with pentadentate ligands: models for putative intermediates in biological iron/dioxygen chemistry. Inorganic Chemistry. 42: 2639-53. PMID 12691572 DOI: 10.1021/Ic034065P |
0.84 |
|
| 2003 |
Lim MH, Rohde JU, Stubna A, Bukowski MR, Costas M, Ho RY, Munck E, Nam W, Que L. An FeIV=O complex of a tetradentate tripodal nonheme ligand. Proceedings of the National Academy of Sciences of the United States of America. 100: 3665-70. PMID 12644707 DOI: 10.1073/Pnas.0636830100 |
0.883 |
|
| 2003 |
Ryle MJ, Koehntop KD, Liu A, Que L, Hausinger RP. Interconversion of two oxidized forms of taurine/alpha-ketoglutarate dioxygenase, a non-heme iron hydroxylase: evidence for bicarbonate binding. Proceedings of the National Academy of Sciences of the United States of America. 100: 3790-5. PMID 12642663 DOI: 10.1073/Pnas.0636740100 |
0.86 |
|
| 2003 |
Ryle MJ, Liu A, Muthukumaran RB, Ho RY, Koehntop KD, McCracken J, Que L, Hausinger RP. O2- and alpha-ketoglutarate-dependent tyrosyl radical formation in TauD, an alpha-keto acid-dependent non-heme iron dioxygenase. Biochemistry. 42: 1854-62. PMID 12590572 DOI: 10.1021/Bi026832M |
0.86 |
|
| 2003 |
Jensen MP, Lange SJ, Mehn MP, Que EL, Que L. Biomimetic aryl hydroxylation derived from alkyl hydroperoxide at a nonheme iron center. Evidence for an FeIV=O oxidant Journal of the American Chemical Society. 125: 2113-2128. PMID 12590539 DOI: 10.1021/Ja028478L |
0.86 |
|
| 2003 |
Reynolds MF, Costas M, Ito M, Jo DH, Tipton AA, Whiting AK, Que L. 4-nitrocatechol as a probe of a Mn(II)-dependent extradiol-cleaving catechol dioxygenase (MndD): comparison with relevant Fe(II) and Mn(II) model complexes. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 8: 263-72. PMID 12589562 DOI: 10.1007/s00775-002-0411-x |
0.652 |
|
| 2003 |
Rohde JU, In JH, Lim MH, Brennessel WW, Bukowski MR, Stubna A, Münck E, Nam W, Que L. Crystallographic and spectroscopic characterization of a nonheme Fe(IV)-O complex. Science (New York, N.Y.). 299: 1037-9. PMID 12586936 DOI: 10.1126/Science.299.5609.1037 |
0.872 |
|
| 2002 |
Chavez FA, Ho RY, Pink M, Young VG, Kryatov SV, Rybak-Akimova EV, Andres H, Münck E, Que L, Tolman WB. Unusual peroxo intermediates in the reaction of dioxygen with carboxylate-bridged diiron(II,II) paddlewheel complexes. Angewandte Chemie (International Ed. in English). 41: 149-52. PMID 12491468 DOI: 10.1002/1521-3773(20020104)41:1<149::Aid-Anie149>3.0.Co;2-# |
0.554 |
|
| 2002 |
Que L, Tolman WB. Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis. Angewandte Chemie (International Ed. in English). 41: 1114-37. PMID 12491240 DOI: 10.1002/1521-3773(20020402)41:7<1114::Aid-Anie1114>3.0.Co;2-6 |
0.481 |
|
| 2002 |
Bassan A, Blomberg MRA, Siegbahn PEM, Que L. A density functional study of O-O bond cleavage for a biomimetic non-heme iron complex demonstrating an FeV-intermediate Journal of the American Chemical Society. 124: 11056-11063. PMID 12224953 DOI: 10.1021/ja026488g |
0.529 |
|
| 2002 |
Lehnert N, Neese F, Ho RY, Que L, Solomon EI. Electronic structure and reactivity of low-spin Fe(III)-hydroperoxo complexes: comparison to activated bleomycin. Journal of the American Chemical Society. 124: 10810-22. PMID 12207537 DOI: 10.1021/Ja012621D |
0.556 |
|
| 2002 |
Zhou J, Rocklin AM, Lipscomb JD, Que L, Solomon EI. Spectroscopic studies of 1-aminocyclopropane-1-carboxylic acid oxidase: molecular mechanism and CO(2) activation in the biosynthesis of ethylene. Journal of the American Chemical Society. 124: 4602-9. PMID 11971707 DOI: 10.1021/Ja017250F |
0.858 |
|
| 2002 |
Chen K, Costas M, Kim J, Tipton AK, Que L. Olefin cis-dihydroxylation versus epoxidation by non-heme iron catalysts: two faces of an Fe(III)-OOH coin. Journal of the American Chemical Society. 124: 3026-35. PMID 11902894 DOI: 10.1021/ja0120025 |
0.516 |
|
| 2002 |
Mekmouche Y, Hummel H, Ho RYN, Que L, Schünemann V, Thomas F, Trautwein AX, Lebrun C, Gorgy K, Leprêtre JC, Collomb MN, Deronzier A, Fontecave M, Ménage S. Sulfide oxidation by hydrogen peroxide catalyzed by iron complexes: two metal centers are better than one. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: [d]1196-1204. PMID 11891908 DOI: 10.1002/1521-3765(20020301)8:5<1196::Aid-Chem1196>3.0.Co;2-Z |
0.428 |
|
| 2002 |
Smoukov SK, Quaroni L, Wang X, Doan PE, Hoffman BM, Que L. Electro-nuclear double resonance spectroscopic evidence for a hydroxo-bridge nucleophile involved in catalysis by a dinuclear hydrolase. Journal of the American Chemical Society. 124: 2595-603. PMID 11890810 DOI: 10.1021/Ja003169L |
0.438 |
|
| 2000 |
Jo DH, Que L. Tuning the Regiospecificity of Cleavage in Fe Catecholate Complexes: Tridentate Facial versus Meridional Ligands. Angewandte Chemie (International Ed. in English). 39: 4284-4287. PMID 29711917 DOI: 10.1002/1521-3773(20001201)39:23<4284::AID-ANIE4284>3.0.CO;2-I |
0.43 |
|
| 1999 |
Roelfes G, Lubben M, Chen K, Ho RY, Meetsma A, Genseberger S, Hermant RM, Hage R, Mandal SK, Young VG, Zang Y, Kooijman H, Spek AL, Que L, Feringa BL. Iron Chemistry of a Pentadentate Ligand That Generates a Metastable Fe(III)-OOH Intermediate. Inorganic Chemistry. 38: 1929-1936. PMID 11670967 DOI: 10.1021/ic980983p |
0.658 |
|
| 1999 |
Duboc-Toia C, Ménage S, Ho RY, Que L, Lambeaux C, Fontecave M. Enantioselective Sulfoxidation as a Probe for a Metal-Based Mechanism in H(2)O(2)-Dependent Oxidations Catalyzed by a Diiron Complex. Inorganic Chemistry. 38: 1261-1268. PMID 11670911 DOI: 10.1021/Ic980958J |
0.489 |
|
| 1975 |
Que L, Holm RH, Mortenson LE. Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin proteins. Journal of the American Chemical Society. 97: 463-4. PMID 1133364 DOI: 10.1021/Ja00835A064 |
0.477 |
|
| 1974 |
Que L, Bobrik MA, Ibers JA, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4). Journal of the American Chemical Society. 96: 4168-78. PMID 4854592 DOI: 10.1021/Ja00820A018 |
0.588 |
|
| 1974 |
DePamphilis BV, Averill BA, Herskovitz T, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-. Journal of the American Chemical Society. 96: 4159-67. PMID 4854591 DOI: 10.1021/Ja00820A017 |
0.707 |
|
| 1974 |
Bobrik MA, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2-. Journal of the American Chemical Society. 96: 285-7. PMID 4810571 DOI: 10.1021/Ja00808A064 |
0.606 |
|
| 1974 |
Que L, Anglin JR, Bobrik MA, Davison A, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IX. Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes obtained by ligand substitution reactions. Journal of the American Chemical Society. 96: 6042-8. PMID 4416035 DOI: 10.1021/Ja00826A014 |
0.627 |
|
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