Pedro J. Perez - Publications

Affiliations: 
CIQSO Universidad de Huelva 
Area:
Organometallic Chemistry, Homogeneous Catalysis

202 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Meeus EJ, Álvarez M, Koelman E, Pérez PJ, Reek JNH, de Bruin B. Copper-Catalyzed Sulfimidation in Aqueous Media: a Fast, Chemoselective and Biomolecule-Compatible Reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). e202303939. PMID 38116945 DOI: 10.1002/chem.202303939  0.387
2022 Borrego E, Caballero A, Pérez PJ. Micellar Catalysis as a Tool for C-H Bond Functionalization toward C-C Bond Formation. Organometallics. 41: 3084-3098. PMID 37810590 DOI: 10.1021/acs.organomet.2c00309  0.663
2022 Rodríguez MR, M Rodríguez A, López-Resano S, Pericàs MA, Díaz-Requejo MM, Maseras F, Pérez PJ. Non-innocent Role of the Halide Ligand in the Copper-Catalyzed Olefin Aziridination Reaction. Acs Catalysis. 13: 706-713. PMID 37808365 DOI: 10.1021/acscatal.2c05069  0.811
2022 Álvarez M, Molina F, Pérez PJ. Carbene-Controlled Regioselective Functionalization of Linear Alkanes under Silver Catalysis. Journal of the American Chemical Society. PMID 36512728 DOI: 10.1021/jacs.2c11707  0.391
2022 Díaz-Jiménez À, Monreal-Corona R, Poater A, Álvarez M, Borrego E, Pérez PJ, Caballero A, Roglans A, Pla-Quintana A. Intramolecular Interception of the Remote Position of Vinylcarbene Silver Complex Intermediates by C(sp3)-H Bond Insertion. Angewandte Chemie (International Ed. in English). PMID 36345831 DOI: 10.1002/anie.202215163  0.661
2022 Borrego E, Tiessler-Sala L, Lázaro JJ, Caballero A, Pérez PJ, Lledós A. Direct Benzene Hydroxylation with Dioxygen Induced by Copper Complexes: Uncovering the Active Species by DFT Calculations. Organometallics. 41: 1892-1904. PMID 35936655 DOI: 10.1021/acs.organomet.2c00202  0.662
2022 Pizarro JD, Schmidtke IL, Nova A, Fructos MR, Pérez PJ. Selective Functionalization of Arene C(sp)-H Bonds by Gold Catalysis: The Role of Carbene Substituents. Acs Catalysis. 12: 6851-6856. PMID 35756859 DOI: 10.1021/acscatal.2c01713  0.749
2022 Rodríguez AM, Pérez-Ruíz J, Molina F, Poveda A, Pérez-Soto R, Maseras F, Díaz-Requejo MM, Pérez PJ. Introducing the Catalytic Amination of Silanes via Nitrene Insertion. Journal of the American Chemical Society. PMID 35648453 DOI: 10.1021/jacs.2c03739  0.76
2022 Muñoz-Molina JM, Bafaluy D, Funes-Ardoiz I, de Aguirre A, Maseras F, Belderrain TR, Pérez PJ, Muñiz K. Mechanistic Studies on the Synthesis of Pyrrolidines and Piperidines via Copper-Catalyzed Intramolecular C-H Amination. Organometallics. 41: 1099-1105. PMID 35572769 DOI: 10.1021/acs.organomet.2c00095  0.848
2022 Martínez-Laguna J, Mollar-Cuni A, Ventura-Espinosa D, Martín S, Caballero A, Mata JA, Pérez PJ. Gold nanoparticle-catalysed functionalization of carbon-hydrogen bonds by carbene transfer reactions. Dalton Transactions (Cambridge, England : 2003). PMID 35285846 DOI: 10.1039/d1dt04351j  0.642
2021 Fuentes MA, Gava R, Saper NI, Romero E, Caballero A, Hartwig JF, Pérez PJ. Copper-Catalyzed Dehydrogenative Amidation of Light Alkanes. Angewandte Chemie (International Ed. in English). PMID 33979475 DOI: 10.1002/anie.202104737  0.676
2021 Álvarez M, Besora M, Molina F, Maseras F, Belderrain TR, Pérez PJ. Two Copper-Carbenes from One Diazo Compound. Journal of the American Chemical Society. PMID 33733762 DOI: 10.1021/jacs.1c01483  0.366
2021 Menendez Rodriguez G, Díaz-Requejo MM, Pérez PJ. Metal-Catalyzed Postpolymerization Strategies for Polar Group Incorporation into Polyolefins Containing C–C, C═C, and Aromatic Rings Macromolecules. 54: 4971-4985. DOI: 10.1021/ACS.MACROMOL.1C00374  0.731
2021 Martínez‐Laguna J, Caballero A, Pérez PJ. Graphene‐Supported, Well‐Defined Metal‐Based Catalysts for C−H Bond Functionalization and Related Reactions Advanced Synthesis & Catalysis. 363: 1740-1755. DOI: 10.1002/ADSC.202001325  0.679
2020 Muñoz-Molina JM, Belderrain TR, Pérez PJ. Copper-catalysed radical reactions of alkenes, alkynes and cyclopropanes with N-F reagents. Organic & Biomolecular Chemistry. PMID 33089850 DOI: 10.1039/d0ob01743d  0.819
2020 Álvarez M, Molina F, Fructos MR, Urbano J, Álvarez E, Sodupe M, Lledós A, Pérez PJ. Aerobic intramolecular carbon-hydrogen bond oxidation promoted by Cu(I) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 33057511 DOI: 10.1039/D0Dt03198D  0.785
2020 Rodríguez MR, Besora M, Molina F, Maseras F, Diaz-Requejo MM, Pérez PJ. Intermolecular Allene Functionalization by Silver-Nitrene Catalysis. Journal of the American Chemical Society. PMID 32590895 DOI: 10.1021/Jacs.0C04395  0.815
2020 Pérez PJ, Fructos MR, Pizarro JD, Molina F. ADAP Ligands as surrogates of NHCs in copper catalysis (ADAP = alkoxydiaminophosphine). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32329536 DOI: 10.1002/Chem.202001517  0.798
2020 Muñoz-Molina JM, Belderrain TR, Pérez PJ. Recent Advances in Copper-Catalyzed Radical C–H Bond Activation Using N–F Reagents Synthesis. DOI: 10.1055/S-0040-1707234  0.398
2020 Díaz-Requejo MM, Pérez PJ, Rodríguez MR. Development of Molecular Complexity through Nitrene-Transfer Reactions Catalyzed by Copper and Silver Scorpionate Complexes Synlett. 32: 763-774. DOI: 10.1055/s-0040-1706534  0.822
2020 Pizarro JD, Molina F, Fructos MR, Pérez PJ. Gold Complexes with ADAP Ligands: Effect of Bulkiness in Catalytic Carbene Transfer Reactions (ADAP = Alkoxydiaminophosphine) Organometallics. 39: 2553-2559. DOI: 10.1021/Acs.Organomet.0C00343  0.773
2020 Rodríguez AM, Rodríguez MR, Díaz‐Requejo MM, Pérez PJ. Pyrrole Functionalization by Copper‐catalyzed Nitrene Transfer Reactions Israel Journal of Chemistry. 60: 485-489. DOI: 10.1002/Ijch.201900181  0.381
2020 Díaz‐Requejo MM, Pérez PJ. The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag) European Journal of Inorganic Chemistry. 2020: 869-869. DOI: 10.1002/Ejic.202000222  0.453
2020 Díaz‐Requejo MM, Pérez PJ. Front Cover: The TpxM Core in Csp3–H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag) (Eur. J. Inorg. Chem. /2020) European Journal of Inorganic Chemistry. 2020: 868-868. DOI: 10.1002/Ejic.202000221  0.452
2020 Díaz-Requejo MM, Pérez PJ. The TpxM Core in Csp 3-H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, Ag): The TpxM Core in Csp3-H Bond Functionalization Reactions: Comparing Carbene, Nitrene, and Oxo Insertion Processes (Tpx = Scorpionate Ligand; M = Cu, A European Journal of Inorganic Chemistry. 2020: 879-885. DOI: 10.1002/Ejic.201901168  0.801
2020 Rodríguez AM, Molina F, Díaz‐Requejo MM, Pérez PJ. Front Cover Picture: Copper‐Catalyzed Selective Pyrrole Functionalization by Carbene Transfer Reaction (Adv. Synth. Catal. 10/2020) Advanced Synthesis & Catalysis. 362: 1905-1905. DOI: 10.1002/Adsc.202000393  0.397
2020 Rodríguez AM, Molina F, Díaz‐Requejo MM, Pérez PJ. Copper‐catalyzed selective pyrrole functionalization by carbene transfer reaction Advanced Synthesis & Catalysis. 362: 1998-2004. DOI: 10.1002/Adsc.201901629  0.398
2019 Álvarez M, Galindo A, Pérez PJ, Carmona E. Molybdenum and tungsten complexes with carbon dioxide and ethylene ligands. Chemical Science. 10: 8541-8546. PMID 32110290 DOI: 10.1039/C9Sc03225H  0.605
2019 Pérez PJ, Besora M, Olmos A, Gava R, Noverges B, Asensio G, Caballero A, Maseras F. A quantitative model for alkane nucleophilicity based on C-H bond structural/topological descriptors. Angewandte Chemie (International Ed. in English). PMID 31826300 DOI: 10.1002/Anie.201914386  0.633
2019 Gava R, Ballestín P, Prieto A, Caballero A, Pérez PJ. Methane functionalization in water with micellar catalysis. Chemical Communications (Cambridge, England). PMID 31475262 DOI: 10.1039/C9Cc05449A  0.645
2019 Muñoz-Molina JM, Belderrain TR, Pérez PJ. Group 11 tris(pyrazolyl)methane complexes: structural features and catalytic applications. Dalton Transactions (Cambridge, England : 2003). PMID 31157344 DOI: 10.1039/C9Dt01661A  0.84
2019 Muñoz-Molina JM, Pérez PJ. Ruthenium-Catalyzed Heck-Type Alkenylation of Alkyl Bromides. The Journal of Organic Chemistry. PMID 31132262 DOI: 10.1021/Acs.Joc.9B00898  0.84
2019 Pérez PJ, Maseras F, Muñiz K, Belderrain T, Bafaluy D, Muñoz-Molina JM, Funes-Ardoiz I, Herold S, de Aguirre AJ, Zhang H. Copper-Catalyzed N-F Bond Activation for Uniform Intramolecular C-H Amination to Pyrrolidines and Piperidines. Angewandte Chemie (International Ed. in English). PMID 30997949 DOI: 10.1002/Anie.201902716  0.823
2019 Ballestin P, Ventura-Espinosa D, Martín S, Caballero A, Mata JA, Pérez PJ. Improving Catalyst Activity in Hydrocarbon Functionalization by Remote Pyrene-Graphene Stacking. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30950103 DOI: 10.1002/Chem.201900964  0.674
2019 Rull SG, Olmos A, Pérez PJ. Gold-catalyzed ethylene cyclopropanation. Beilstein Journal of Organic Chemistry. 15: 67-71. PMID 30680040 DOI: 10.3762/Bjoc.15.7  0.498
2019 Sarmiento JT, Olmos A, Belderrain TR, Caballero A, Varea T, Pérez PJ, Asensio G. Favoring Alkane Primary Carbon–Hydrogen Bond Functionalization in Supercritical Carbon Dioxide as Reaction Medium Acs Sustainable Chemistry & Engineering. 7: 7346-7352. DOI: 10.1021/Acssuschemeng.9B00523  0.686
2019 Delgado-Rebollo M, García-Morales C, Maya C, Prieto A, Echavarren AM, Pérez PJ. Coinage metal complexes bearing fluorinated N-Heterocyclic carbene ligands Journal of Organometallic Chemistry. 898: 120856. DOI: 10.1016/J.Jorganchem.2019.07.007  0.456
2019 Muñoz-Molina JM, Belderrain TR, Pérez PJ. Trispyrazolylborate coinage metals complexes: Structural features and catalytic transformations Coordination Chemistry Reviews. 390: 171-189. DOI: 10.1016/J.Ccr.2019.03.013  0.401
2018 Carreras J, Caballero A, Pérez PJ. Alkenyl Boronates: Synthesis and Applications. Chemistry, An Asian Journal. PMID 30548535 DOI: 10.1002/Asia.201801559  0.637
2018 Albéniz AC, Molina de la Torre JÁ, Pérez-Ortega I, Beltrán A, Rodríguez M, Díaz-Requejo M, Pérez P. Trispyrazolylborate Ligands Supported on Vinylic Addition Polynorbornenes and their Copper Derivatives as Recyclable Catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30194871 DOI: 10.1002/Chem.201803852  0.819
2018 Carreras J, Popowski Y, Caballero A, Amir E, Pérez PJ. Catalytic Functionalization of C-H Bonds of Azulene by Carbene/Nitrene Incorporation. The Journal of Organic Chemistry. PMID 30032616 DOI: 10.1021/Acs.Joc.8B01731  0.704
2018 Pérez PJ, Olmos A, Gava R, Noverges B, Belleza D, Jacob K, Besora M, Sameera WMC, Etienne M, Maseras F, Asensio G, Caballero A. Measuring the relative reactivity of the carbon-hydrogen bonds of alkanes as nucleophiles. Angewandte Chemie (International Ed. in English). PMID 30015368 DOI: 10.1002/Anie.201807448  0.667
2018 Miguel-Ávila J, Tomás-Gamasa M, Olmos A, Pérez PJ, Mascareñas JL. Discrete Cu(i) complexes for azide-alkyne annulations of small molecules inside mammalian cells. Chemical Science. 9: 1947-1952. PMID 29675241 DOI: 10.1039/C7Sc04643J  0.461
2018 Olmos A, Pereira A, Belderrain TR, Pérez PJ. Multigram Synthesis of Thallium Trispyrazolylborate Compounds Synthesis. 50: 3333-3336. DOI: 10.1055/S-0037-1610106  0.324
2018 Postils V, Rodríguez M, Sabenya G, Conde A, Díaz-Requejo MM, Pérez PJ, Costas M, Solà M, Luis JM. Mechanism of the Selective Fe-Catalyzed Arene Carbon–Hydrogen Bond Functionalization Acs Catalysis. 8: 4313-4322. DOI: 10.1021/Acscatal.7B03935  0.795
2018 Álvarez M, Urbano J, Fructos MR, Álvarez E, Pérez PJ. Copper(I)‐Arene Complexes with a Sterically Hindered Tris(pyrazolyl)borate Ligand European Journal of Inorganic Chemistry. 2018: 2026-2030. DOI: 10.1002/Ejic.201800176  0.758
2018 Olmos A, Gava R, Noverges B, Bellezza D, Jacob K, Besora M, Sameera WMC, Etienne M, Maseras F, Asensio G, Caballero A, Pérez PJ. Cover Picture: Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles (Angew. Chem. Int. Ed. 42/2018) Angewandte Chemie International Edition. 57: 13693-13693. DOI: 10.1002/Anie.201810391  0.625
2018 Olmos A, Gava R, Noverges B, Bellezza D, Jacob K, Besora M, Sameera WMC, Etienne M, Maseras F, Asensio G, Caballero A, Pérez PJ. Titelbild: Measuring the Relative Reactivity of the Carbon–Hydrogen Bonds of Alkanes as Nucleophiles (Angew. Chem. 42/2018) Angewandte Chemie. 130: 13885-13885. DOI: 10.1002/Ange.201810391  0.627
2017 Vilella L, Conde A, Balcells D, Díaz-Requejo MM, Lledós A, Pérez PJ. A competing, dual mechanism for catalytic direct benzene hydroxylation from combined experimental-DFT studies. Chemical Science. 8: 8373-8383. PMID 29619184 DOI: 10.1039/C7Sc02898A  0.806
2017 Pérez PJ, Carreras J, Caballero A. Enantio- and Diastereoselective Cyclopropanation of 1-Alkenylboronates: Synthesis of 1-boryl-2,3-disubstituted Cyclopropanes. Angewandte Chemie (International Ed. in English). PMID 29226562 DOI: 10.1002/Anie.201710415  0.707
2017 Pérez PJ, Diaz-Requejo MM, Rodríguez MR, Beltrán Á, Alvarez E, Mudarra A, Maseras F. Catalytic Nitrene Transfer To Alkynes: A Novel and Versatile Route for the Synthesis of Sulfinamides and iso-Thiazoles. Angewandte Chemie (International Ed. in English). PMID 28707748 DOI: 10.1002/Anie.201705664  0.807
2017 Pérez PJ, Caballero A. Dimensioning the term carbenoid. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28640943 DOI: 10.1002/Chem.201702392  0.637
2017 Pérez PJ, Rull SG, Álvarez E, Fructos MR, Belderrain TR. The elusive palladium-diazo adduct captured: synthesis, isolation and structural characterization of [(ArNHC-PPh2)Pd(2-N2C(Ph)CO2Et)]. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28407417 DOI: 10.1002/Chem.201701362  0.717
2017 Valencia M, Pereira A, Müller-Bunz H, Belderrain TR, Perez PJ, Albrecht M. Triazolylidene iridum complexes with a pending pyridyl group for cooperative metal-ligand induced catalytic dehydrogenation of amines. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28383127 DOI: 10.1002/Chem.201700676  0.5
2017 Maestre L, Dorel R, Pablo O, Escofet I, Sameera WM, Álvarez E, Maseras F, Diaz-Requejo MM, Echavarren AM, Pérez PJ. Functional-Group-Tolerant, Silver-Catalyzed N-N Bond Formation by Nitrene Transfer to Amines. Journal of the American Chemical Society. PMID 28099010 DOI: 10.1021/Jacs.6B08219  0.791
2017 Álvarez M, Gava R, Rodríguez MR, Rull SG, Pérez PJ. Water as the Reaction Medium for Intermolecular C–H Alkane Functionalization in Micellar Catalysis Acs Catalysis. 7: 3707-3711. DOI: 10.1021/Acscatal.6B03669  0.422
2017 Caballero A, Pérez PJ. Alkane Carbon-Hydrogen Bond Functionalization as a Tool Toward a Steric Parameter for Hydrotris(pyrazolyl)borate (Tpx) Ligands Israel Journal of Chemistry. 57: 1047-1052. DOI: 10.1002/Ijch.201700110  0.683
2017 Caballero A, Pérez PJ. Frontispiece: Dimensioning the Term Carbenoid Chemistry: a European Journal. 23. DOI: 10.1002/Chem.201785861  0.533
2017 Caballero A, Pérez PJ. Cover Feature: Dimensioning the Term Carbenoid (Chem. Eur. J. 58/2017) Chemistry: a European Journal. 23: 14385-14385. DOI: 10.1002/Chem.201703134  0.539
2016 Pretorius R, Fructos MR, Müller-Bunz H, Gossage RA, Pérez PJ, Albrecht M. Synthesis and catalytic applications of 1,2,3-triazolylidene gold(i) complexes in silver-free oxazoline syntheses and C-H bond activation. Dalton Transactions (Cambridge, England : 2003). PMID 27363515 DOI: 10.1039/C6Dt02181F  0.782
2016 Fructos MR, Díaz-Requejo MM, Pérez PJ. Gold and diazo reagents: a fruitful tool for developing molecular complexity. Chemical Communications (Cambridge, England). PMID 27138365 DOI: 10.1039/C6Cc01958G  0.796
2016 Conde A, Sabenya G, Rodríguez M, Postils V, Luis JM, Díaz-Requejo MM, Costas M, Pérez PJ. Iron and Manganese Catalysts for the Selective Functionalization of Arene C(sp(2) )-H Bonds by Carbene Insertion. Angewandte Chemie (International Ed. in English). 55: 6530-4. PMID 27088627 DOI: 10.1002/Anie.201601750  0.806
2016 Álvarez M, Álvarez E, Fructos MR, Urbano J, Pérez PJ. Copper-induced ammonia N-H functionalization. Dalton Transactions (Cambridge, England : 2003). 45: 14628-33. PMID 26884083 DOI: 10.1039/C5Dt04972E  0.745
2016 Olmos A, Asensio G, Pérez PJ. Homogeneous Metal-Based Catalysis in Supercritical Carbon Dioxide as Reaction Medium Acs Catalysis. 6: 4265-4280. DOI: 10.1021/Acscatal.6B00848  0.395
2016 Fructos MR, Besora M, Braga AAC, Díaz-Requejo MM, Maseras F, Pérez PJ. Mechanistic Studies on Gold-Catalyzed Direct Arene C–H Bond Functionalization by Carbene Insertion: The Coinage-Metal Effect Organometallics. 36: 172-179. DOI: 10.1021/Acs.Organomet.6B00604  0.845
2015 Maestre L, Ozkal E, Ayats C, Beltrán Á, Díaz-Requejo MM, Pérez PJ, Pericàs MA. A fully recyclable heterogenized Cu catalyst for the general carbene transfer reaction in batch and flow. Chemical Science. 6: 1510-1515. PMID 29560239 DOI: 10.1039/C4Sc03277B  0.82
2015 Fructos MR, Urbano J, Díaz-Requejo MM, Pérez PJ. Evidencing an inner-sphere mechanism for NHC-Au(I)-catalyzed carbene-transfer reactions from ethyl diazoacetate. Beilstein Journal of Organic Chemistry. 11: 2254-60. PMID 26664649 DOI: 10.3762/Bjoc.11.245  0.822
2015 Caballero A, Díaz-Requejo MM, Fructos MR, Olmos A, Urbano J, Pérez PJ. Catalytic functionalization of low reactive C(sp(3))-H and C(sp(2))-H bonds of alkanes and arenes by carbene transfer from diazo compounds. Dalton Transactions (Cambridge, England : 2003). PMID 26568268 DOI: 10.1039/C5Dt03450G  0.803
2015 Haldón E, Nicasio MC, Pérez PJ. Copper-catalysed azide-alkyne cycloadditions (CuAAC): an update. Organic & Biomolecular Chemistry. 13: 9528-50. PMID 26284434 DOI: 10.1039/C5Ob01457C  0.48
2015 Pereira A, Champouret Y, Martín C, Álvarez E, Etienne M, Belderraín TR, Pérez PJ. Copper-Carbene Intermediates in the Copper-Catalyzed Functionalization of OH Bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 9769-75. PMID 26014686 DOI: 10.1002/Chem.201500776  0.474
2015 Gava R, Olmos A, Noverges B, Varea T, Álvarez E, Belderrain TR, Caballero A, Asensio G, Pérez PJ. Discovering copper for methane C-H bond functionalization Acs Catalysis. 5: 3726-3730. DOI: 10.1021/Acscatal.5B00718  0.751
2015 Espina M, Rivilla I, Conde A, Díaz-Requejo MM, Pérez PJ, Álvarez E, Fernández R, Lassaletta JM. Chiral, Sterically Demanding N-Heterocyclic Carbenes Fused into a Heterobiaryl Skeleton: Design, Synthesis, and Structural Analysis Organometallics. 34: 1328-1338. DOI: 10.1021/Acs.Organomet.5B00046  0.784
2015 Besora M, Braga AAC, Sameera WMC, Urbano J, Fructos MR, Pérez PJ, Maseras F. A computational view on the reactions of hydrocarbons with coinage metal complexes Journal of Organometallic Chemistry. 784: 2-12. DOI: 10.1016/J.Jorganchem.2014.10.009  0.775
2015 Gava R, Olmos A, Noverges B, Varea T, Funes-Ardoiz I, Belderrain TR, Caballero A, Maseras F, Asensio G, Pérez PJ. Functionalization of CnH2n+2 Alkanes: Supercritical Carbon Dioxide Enhances the Reactivity towards Primary Carbon-Hydrogen Bonds Chemcatchem. 7: 3254-3260. DOI: 10.1002/Cctc.201500610  0.611
2015 Beltrán Á, Álvarez E, Díaz-Requejo MM, Pérez PJ. Direct Synthesis of Hemiaminal Ethers via a Three‐Component Reaction of Aldehydes, Amines and Alcohols Advanced Synthesis & Catalysis. 357: 2821-2826. DOI: 10.1002/Adsc.201500588  0.763
2014 Fuentes MÁ, Olmos A, Muñoz BK, Jacob K, González-Núñez ME, Mello R, Asensio G, Caballero A, Etienne M, Pérez PJ. Catalytic functionalization of methane and light alkanes in supercritical carbon dioxide. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11013-8. PMID 25065490 DOI: 10.1002/Chem.201403217  0.707
2014 Haldón E, Álvarez E, Nicasio MC, Pérez PJ. 1,2,3-Triazoles from carbonyl azides and alkynes: filling the gap. Chemical Communications (Cambridge, England). 50: 8978-81. PMID 24980244 DOI: 10.1039/C4Cc03614J  0.414
2014 Arenas I, Fuentes MÁ, Alvarez E, Díaz Y, Caballero A, Castillón S, Pérez PJ. Syntheses of a novel fluorinated trisphosphinoborate ligand and its copper and silver complexes. Catalytic activity toward nitrene transfer reactions. Inorganic Chemistry. 53: 3991-9. PMID 24702601 DOI: 10.1021/Ic4028223  0.733
2014 Haldón E, Delgado-Rebollo M, Prieto A, Alvarez E, Maya C, Nicasio MC, Pérez PJ. Synthesis, structural characterization, reactivity, and catalytic properties of copper(I) complexes with a series of tetradentate tripodal tris(pyrazolylmethyl)amine ligands. Inorganic Chemistry. 53: 4192-201. PMID 24697594 DOI: 10.1021/Ic500311Y  0.443
2014 Llaveria J, Beltrán Á, Sameera WM, Locati A, Díaz-Requejo MM, Matheu MI, Castillón S, Maseras F, Pérez PJ. Chemo-, regio-, and stereoselective silver-catalyzed aziridination of dienes: scope, mechanistic studies, and ring-opening reactions. Journal of the American Chemical Society. 136: 5342-50. PMID 24621209 DOI: 10.1021/Ja412547R  0.816
2014 Haldón E, Besora M, Cano I, Cambeiro XC, Pericàs MA, Maseras F, Nicasio MC, Pérez PJ. Reaction of alkynes and azides: not triazoles through copper-acetylides but oxazoles through copper-nitrene intermediates. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3463-74. PMID 24616053 DOI: 10.1002/Chem.201303737  0.492
2014 Corro M, Besora M, Maya C, Álvarez E, Urbano J, Fructos MR, Maseras F, Pérez PJ. Catalytic copper-mediated ring opening and functionalization of benzoxazoles Acs Catalysis. 4: 4215-4222. DOI: 10.1021/Cs5012519  0.785
2014 Caballero A, Pérez PJ. Catalyst design in the alkane C-H bond functionalization of alkanes by carbene insertion with TpxM complexes (Tpx=hydrotrispyrazolylborate ligand; M=Cu, Ag) Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.02.029  0.751
2014 Gava R, Fuentes MA, Besora M, Belderrain TR, Jacob K, Maseras F, Etienne M, Caballero A, Pérez PJ. Silver-catalyzed functionalization of esters by carbene transfer: The role of ylide zwitterionic intermediates Chemcatchem. 6: 2206-2210. DOI: 10.1002/Cctc.201402241  0.693
2014 Delgado‐Rebollo M, Prieto A, Pérez PJ. Catalytic Functionalization of Indoles by Copper‐Mediated Carbene Transfer Chemcatchem. 6: 2047-2052. DOI: 10.1002/Cctc.201400097  0.372
2013 Delgado-Abad T, Martínez-Ferrer J, Caballero A, Olmos A, Mello R, González-Núñez ME, Pérez PJ, Asensio G. Supercritical carbon dioxide: a promoter of carbon-halogen bond heterolysis. Angewandte Chemie (International Ed. in English). 52: 13298-301. PMID 24130104 DOI: 10.1002/Anie.201303819  0.614
2013 Caballero A, Pérez PJ. Methane as raw material in synthetic chemistry: the final frontier. Chemical Society Reviews. 42: 8809-20. PMID 23954933 DOI: 10.1039/C3Cs60120J  0.625
2013 Conde A, Vilella L, Balcells D, Díaz-Requejo MM, Lledós A, Pérez PJ. Introducing copper as catalyst for oxidative alkane dehydrogenation. Journal of the American Chemical Society. 135: 3887-96. PMID 23409843 DOI: 10.1021/Ja310866K  0.816
2013 Rivilla I, Sameera WM, Alvarez E, Díaz-Requejo MM, Maseras F, Pérez PJ. Catalytic cross-coupling of diazo compounds with coinage metal-based catalysts: an experimental and theoretical study. Dalton Transactions (Cambridge, England : 2003). 42: 4132-8. PMID 23328754 DOI: 10.1039/C2Dt32439C  0.804
2013 Maestre L, Sameera WM, Díaz-Requejo MM, Maseras F, Pérez PJ. A general mechanism for the copper- and silver-catalyzed olefin aziridination reactions: concomitant involvement of the singlet and triplet pathways. Journal of the American Chemical Society. 135: 1338-48. PMID 23276287 DOI: 10.1021/Ja307229E  0.803
2013 Fuentes MÁ, Muñoz BK, Jacob K, Vendier L, Caballero A, Etienne M, Pérez PJ. Functionalization of non-activated C-H bonds of alkanes: an effective and recyclable catalytic system based on fluorinated silver catalysts and solvents. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 1327-34. PMID 23197347 DOI: 10.1002/Chem.201203566  0.716
2013 Iglesias MJ, Nicasio MC, Caballero A, Pérez PJ. Silver-catalyzed silicon-hydrogen bond functionalization by carbene insertion. Dalton Transactions (Cambridge, England : 2003). 42: 1191-5. PMID 23114570 DOI: 10.1039/C2Dt31460F  0.686
2013 Beltrán Á, Lescot C, Díaz-Requejo MM, Pérez PJ, Dauban P. Catalytic C–H amination of alkanes with sulfonimidamides: silver(I)-scorpionates vs. dirhodium(II) carboxylates Tetrahedron. 69: 4488-4492. DOI: 10.1016/J.Tet.2013.02.005  0.828
2013 Pereira A, Martín C, Maya C, Belderrain TR, Pérez PJ. An effective dual copper-and sulfide-catalytic system for the epoxidation of aldehydes with phenyldiazomethane Advanced Synthesis and Catalysis. 355: 2942-2951. DOI: 10.1002/Adsc.201300606  0.485
2012 Diaba F, Martínez-Laporta A, Bonjoch J, Pereira A, Muñoz-Molina JM, Pérez PJ, Belderrain TR. Cu(I)-catalyzed atom transfer radical cyclization of trichloroacetamides tethered to electron-deficient, -neutral, and -rich alkenes: synthesis of polyfunctionalized 2-azabicyclo[3.3.1]nonanes. Chemical Communications (Cambridge, England). 48: 8799-801. PMID 22836236 DOI: 10.1039/C2Cc34133F  0.829
2012 Haldón E, Álvarez E, Nicasio MC, Pérez PJ. Copper(I) complexes with trispyrazolylmethane ligands: synthesis, characterization, and catalytic activity in cross-coupling reactions. Inorganic Chemistry. 51: 8298-306. PMID 22831915 DOI: 10.1021/Ic300843A  0.503
2012 Kadina AP, Khlebnikov AF, Novikov MS, Pérez PJ, Yufit DS. Intramolecular cycloaddition of azomethine ylides, from imines of O-acylsalicylic aldehyde and ethyl diazoacetate, to ester carbonyl--experimental and DFT computational study. Organic & Biomolecular Chemistry. 10: 5582-91. PMID 22722405 DOI: 10.1039/C2Ob25676B  0.412
2012 Martín C, Sierra M, Alvarez E, Belderrain TR, Pérez PJ. Hydrotris(3-mesitylpyrazolyl)borato-copper(I) alkyne complexes: synthesis, structural characterization and rationalization of their activities as alkyne cyclopropenation catalysts. Dalton Transactions (Cambridge, England : 2003). 41: 5319-25. PMID 22382395 DOI: 10.1039/C2Dt11951J  0.535
2012 Van Koten G, Perez P, Liebeskind L. Introduction to the ennobling a base metal: Presenting copper in organometallic chemistry issue Organometallics. 31: 7631-7633. DOI: 10.1021/Om3010405  0.338
2012 Maestre L, Fructos MR, Dı́az-Requejo MM, Pérez PJ. Copper-Catalyzed Nitrene Transfer as a Tool for the Synthesis of N-Substituted 1,2-Dihydro- and 1,2,3,4-Tetrahydropyridines Organometallics. 31: 7839-7843. DOI: 10.1021/Om3008234  0.843
2012 Fuentes MÁ, Álvarez E, Caballero A, Pérez PJ. [(PhBP3)Cu(PPh3)] as a Surrogate of TpxCuL in Homogeneous Catalysis (PhBP3 = PhB(CH2PPh2)3; Tpx = Hydrotrispyrazolylborate) Organometallics. 31: 959-965. DOI: 10.1021/Om201016B  0.691
2012 Beltrán Á, Gómez-Emeterio BP, Marco C, Ellis G, Parellada MD, Díaz-Requejo MM, Corona-Galván S, Pérez PJ. Mild Catalytic Functionalization of Styrene–Butadiene Rubbers Macromolecules. 45: 9267-9274. DOI: 10.1021/Ma302120A  0.78
2012 Tubaro C, Biffis A, Gava R, Scattolin E, Volpe A, Basato M, Díaz-Requejo MM, Perez PJ. Polynuclear Copper(I) Complexes with Chelating Bis- and Tris-N-Heterocyclic Carbene Ligands: Catalytic Activity in Nitrene and Carbene Transfer Reactions European Journal of Organic Chemistry. 2012: 1367-1372. DOI: 10.1002/Ejoc.201101480  0.845
2012 Delgado-Rebollo M, Beltrán A, Prieto A, Mar Díaz-Requejo M, Echavarren AM, Pérez PJ. Catalytic hydrocarbon functionalization with gold complexes containing n-heterocyclic carbene ligands with pendant donor groups European Journal of Inorganic Chemistry. 1380-1386. DOI: 10.1002/Ejic.201101158  0.496
2011 Conde A, Díaz-Requejo MM, Pérez PJ. Direct, copper-catalyzed oxidation of aromatic C-H bonds with hydrogen peroxide under acid-free conditions. Chemical Communications (Cambridge, England). 47: 8154-6. PMID 21681295 DOI: 10.1039/C1Cc12804C  0.8
2011 Pérez PJ, Díaz-Requejo MM, Rivilla I. Gold-catalyzed naphthalene functionalization. Beilstein Journal of Organic Chemistry. 7: 653-7. PMID 21647320 DOI: 10.3762/Bjoc.7.77  0.812
2011 Caballero A, Despagnet-Ayoub E, Díaz-Requejo MM, Díaz-Rodríguez A, González-Núñez ME, Mello R, Muñoz BK, Ojo WS, Asensio G, Etienne M, Pérez PJ. Silver-catalyzed C-C bond formation between methane and ethyl diazoacetate in supercritical CO₂. Science (New York, N.Y.). 332: 835-8. PMID 21566191 DOI: 10.1126/Science.1204131  0.818
2011 Muñoz-Molina JM, Sameera WM, Álvarez E, Maseras F, Belderrain TR, Pérez PJ. Mechanistic and computational studies of the atom transfer radical addition of CCl4 to styrene catalyzed by copper homoscorpionate complexes. Inorganic Chemistry. 50: 2458-67. PMID 21319785 DOI: 10.1021/Ic102279W  0.826
2011 Cano I, Álvarez E, Nicasio MC, Pérez PJ. Regioselective formation of 2,5-disubstituted oxazoles via copper(I)-catalyzed cycloaddition of acyl azides and 1-alkynes. Journal of the American Chemical Society. 133: 191-3. PMID 21171608 DOI: 10.1021/Ja109732S  0.519
2011 Rivilla I, Gómez-Emeterio BP, Fructos MR, Díaz-Requejo MM, Pérez PJ. Exclusive Aromatic vs Aliphatic C-H Bond Functionalization by Carbene Insertion with Gold-based Catalysts Organometallics. 30: 2855-2860. DOI: 10.1021/Om200206M  0.847
2011 Fuentes MA, Rodríguez-Castillo M, Monge M, Olmos ME, López-De-Luzuriaga JM, Caballero A, Pérez PJ. Intermetallic coinage metal-catalyzed functionalization of alkanes with ethyl diazoacetate: Gold as a ligand Inorganica Chimica Acta. 369: 146-149. DOI: 10.1016/J.Ica.2011.01.012  0.69
2011 Muñoz‐Molina JM, Belderrain TR, Pérez PJ. Atom Transfer Radical Reactions as a Tool for Olefin Functionalization – On the Way to Practical Applications European Journal of Inorganic Chemistry. 2011: 3155-3164. DOI: 10.1002/Ejic.201100379  0.436
2011 Braga AAC, Caballero A, Urbano J, Diaz-Requejo MM, Pérez PJ, Maseras F. Mechanism of Side Reactions in Alkane C-H Bond Functionalization by Diazo Compounds Catalyzed by Ag and Cu Homoscorpionate Complexes-A DFT Study Chemcatchem. 3: 1646-1652. DOI: 10.1002/Cctc.201100082  0.835
2010 Llaveria J, Beltrán A, Díaz-Requejo MM, Matheu MI, Castillón S, Pérez PJ. Efficient silver-catalyzed regio- and stereospecific aziridination of dienes. Angewandte Chemie (International Ed. in English). 49: 7092-5. PMID 20718060 DOI: 10.1002/Anie.201003167  0.766
2010 Fructos MR, Alvarez E, Díaz-Requejo MM, Pérez PJ. Selective synthesis of N-substituted 1,2-dihydropyridines from furans by copper-induced concurrent tandem catalysis. Journal of the American Chemical Society. 132: 4600-7. PMID 20230037 DOI: 10.1021/Ja1006614  0.841
2010 Cano I, Nicasio MC, Pérez PJ. Copper(I) complexes as catalysts for the synthesis of N-sulfonyl-1,2,3-triazoles from N-sulfonylazides and alkynes. Organic & Biomolecular Chemistry. 8: 536-8. PMID 20090968 DOI: 10.1039/B912835B  0.476
2010 Muñoz-Molina JM, Belderraín TR, Pérez PJ. An efficient, selective, and reducing agent-free copper catalyst for the atom-transfer radical addition of halo compounds to activated olefins. Inorganic Chemistry. 49: 642-5. PMID 20000619 DOI: 10.1021/Ic901942P  0.841
2010 Díaz-Requejo M, Matheu M, Castillón S, Pérez P, Llaveria J, Beltrán Á. Regio- and Stereospecific Aziridinzation of Unsymmetric Conjugated Dienes Synfacts. 2010: 1393-1393. DOI: 10.1055/S-0030-1258864  0.749
2010 Martín C, Muñoz-Molina JM, Locati A, Alvarez E, Maseras F, Belderrain TR, Pérez PJ. Copper(I)-olefin complexes: The effect of the trispyrazolylborate ancillary ligand in structure and reactivity Organometallics. 29: 3481-3489. DOI: 10.1021/Om1002705  0.429
2010 Muñoz-Molina JM, Belderraín TR, Pérez PJ. Efficient Atom-Transfer Radical Polymerization of Methacrylates Catalyzed by Neutral Copper Complexes Macromolecules. 43: 3221-3227. DOI: 10.1021/Ma9026299  0.403
2010 Urbano J, Korthals B, Díaz-Requejo MdM, Pérez PJ, Mecking S. Catalytic cyclopropanation of polybutadienes Journal of Polymer Science Part A. 48: 4439-4444. DOI: 10.1002/Pola.24231  0.544
2010 Diaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. ChemInform Abstract: Intermolecular Copper-Catalyzed Carbon-Hydrogen Bond Activation via Carbene Insertion. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200228084  0.769
2010 Diaz-Requejo MM, Mairena MA, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. ChemInform Abstract: A Family of Highly Active Copper(I)-Homoscorpionate Catalysts for the Alkyne Cyclopropenation Reaction. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200202095  0.791
2009 Fructos MR, Díaz-Requejo MM, Pérez PJ. Highly active gold-based catalyst for the reaction of benzaldehyde with ethyl diazoacetate. Chemical Communications (Cambridge, England). 5153-5. PMID 20448977 DOI: 10.1039/B908233F  0.832
2009 Martín C, Belderraín TR, Pérez PJ. Rediscovering copper-based catalysts for intramolecular carbon-hydrogen bond functionalization by carbene insertion. Organic & Biomolecular Chemistry. 7: 4777-81. PMID 19865715 DOI: 10.1039/B911589G  0.528
2009 Cano I, Nicasio MC, Pérez PJ. Nitrene transfer reactions catalysed by copper(I) complexes in ionic liquid using chloramine-T. Dalton Transactions (Cambridge, England : 2003). 730-4. PMID 19378567 DOI: 10.1039/B813469C  0.483
2009 Urbano J, Braga AAC, Maseras F, Alvarez E, Díaz-Requejo MM, Pérez PJ. The mechanism of the catalytic functionalization of haloalkanes by carbene insertion: An experimental and theoretical study Organometallics. 28: 5968-5981. DOI: 10.1021/Om9006888  0.809
2009 Haldón E, Álvarez E, Nicasio MC, Pérez PJ. Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions Organometallics. 28: 3815-3821. DOI: 10.1021/Om900119R  0.517
2009 Lillo V, Prieto A, Bonet A, Díaz-Requejo MM, Ramírez J, Pérez PJ, Fernández E. Asymmetric β-Boration of α,β-Unsaturated Esters with Chiral (NHC)Cu Catalysts Organometallics. 28: 659-662. DOI: 10.1021/Om800946K  0.771
2009 Prieto A, Fructos MR, Mar Díaz-Requejo M, Pérez PJ, Pérez-Galán P, Delpont N, Echavarren AM. Gold-catalyzed olefin cyclopropanation Tetrahedron. 65: 1790-1793. DOI: 10.1016/J.Tet.2008.10.114  0.794
2009 Caballero A, Sabater M, Morilla ME, Nicasio MC, Belderraín TR, Díaz-Requejo MM, Pérez PJ. Hydrotrispyrazolylborate-copper complexes as catalysts for the styrene cyclopropanation reaction with ethyl diazoacetate under homogeneous and heterogeneous conditions Inorganica Chimica Acta. 362: 4599-4602. DOI: 10.1016/J.Ica.2009.05.027  0.845
2009 Caballero A, Prieto A, Díaz‐Requejo MM, Pérez PJ. Metal‐Catalyzed Olefin Cyclopropanation with Ethyl Diazoacetate: Control of the Diastereoselectivity European Journal of Inorganic Chemistry. 2009: 1137-1144. DOI: 10.1002/Ejic.200800944  0.701
2008 Díaz-Requejo MM, Pérez PJ. Coinage metal catalyzed C-H bond functionalization of hydrocarbons. Chemical Reviews. 108: 3379-94. PMID 18698739 DOI: 10.1021/Cr078364Y  0.77
2008 Urbano J, Hormigo AJ, de Frémont P, Nolan SP, Díaz-Requejo MM, Pérez PJ. Gold-promoted styrene polymerization. Chemical Communications (Cambridge, England). 759-61. PMID 18478715 DOI: 10.1039/B716145J  0.792
2008 Despagnet-Ayoub E, Jacob K, Vendier L, Etienne M, Álvarez E, Caballero A, Díaz-Requejo MM, Pérez PJ. A New Perfluorinated F21-Tp Scorpionate Ligand: Enhanced Alkane Functionalization by Carbene Insertion with (F21-Tp)M Catalysts (M = Cu, Ag) Organometallics. 27: 4779-4787. DOI: 10.1021/Om800531A  0.832
2008 Gómez-Emeterio BP, Urbano J, Díaz-Requejo MM, Pérez PJ. Easy Alkane Catalytic Functionalization Organometallics. 27: 4126-4130. DOI: 10.1021/Om800218D  0.821
2008 Muñoz‐Molina JM, Belderraín TR, Pérez PJ. Copper-Catalyzed Synthesis of 1,2-Disubstituted Cyclopentanes from 1,6-Dienes by Ring-Closing Kharasch Addition of Carbon Tetrachloride Advanced Synthesis & Catalysis. 350: 2365-2372. DOI: 10.1002/Adsc.200800364  0.509
2007 Morilla ME, Rodríguez P, Belderrain TR, Graiff C, Tiripicchio A, Nicasio MC, Pérez PJ. Synthesis, characterization, and reactivity of ruthenium diene/diamine complexes including catalytic hydrogenation of ketones. Inorganic Chemistry. 46: 9405-14. PMID 17900107 DOI: 10.1021/Ic701363G  0.467
2007 Mairena MA, Urbano J, Carbajo J, Maraver JJ, Alvarez E, Díaz-Requejo MM, Pérez PJ. Effects of the substituents in the TpxCu activation of dioxygen: an experimental study. Inorganic Chemistry. 46: 7428-35. PMID 17676732 DOI: 10.1021/Ic7007073  0.777
2007 Muñoz-Molina JM, Caballero A, Díaz-Requejo MM, Trofimenko S, Belderraín TR, Pérez PJ. Copper-homoscorpionate complexes as active catalysts for atom transfer radical addition to olefins. Inorganic Chemistry. 46: 7725-30. PMID 17503810 DOI: 10.1021/Ic0702872  0.83
2007 Yap GP, Jove F, Urbano J, Alvarez E, Trofimenko S, Díaz-Requejo MM, Pérez PJ. Unusual polybrominated polypyrazolylborates and their copper(I) complexes: synthesis, characterization, and catalytic activity. Inorganic Chemistry. 46: 780-7. PMID 17257020 DOI: 10.1021/Ic061714Z  0.799
2007 Lillo V, Fructos MR, Ramírez J, Braga AA, Maseras F, Díaz-Requejo MM, Pérez PJ, Fernández E. A valuable, inexpensive Cui/n-heterocyclic carbene catalyst for the selective diboration of styrene. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 2614-21. PMID 17183598 DOI: 10.1002/Chem.200601146  0.845
2007 Rodríguez P, Álvarez E, Nicasio MC, Pérez PJ. Catalytic Carbon−Hydrogen Bond Functionalization in an Ionic Liquid Medium Organometallics. 26: 6661-6668. DOI: 10.1021/Om700822A  0.482
2007 Caballero A, Díaz-Requejo MM, Trofimenko S, Belderraín TR, Pérez PJ. The Effect of Catalyst Loading in Copper-Catalyzed Cyclohexane Functionalization by Carbene Insertion European Journal of Inorganic Chemistry. 2007: 2848-2852. DOI: 10.1002/Ejic.200600811  0.836
2006 Díaz-Requejo MM, Belderrain TR, Nicasio MC, Pérez PJ. The carbene insertion methodology for the catalytic functionalization of unreactive hydrocarbons: no classical C-H activation, but efficient C-H functionalization. Dalton Transactions (Cambridge, England : 2003). 5559-66. PMID 17225892 DOI: 10.1039/B610183F  0.785
2006 Fructos MR, Trofimenko S, Díaz-Requejo MM, Pérez PJ. Facile amine formation by intermolecular catalytic amidation of carbon-hydrogen bonds. Journal of the American Chemical Society. 128: 11784-91. PMID 16953617 DOI: 10.1021/Ja0627850  0.841
2006 de Frémont P, Stevens ED, Fructos MR, Mar Díaz-Requejo M, Pérez PJ, Nolan SP. Synthesis, isolation and characterization of cationic gold(I) N-heterocyclic carbene (NHC) complexes. Chemical Communications (Cambridge, England). 2045-7. PMID 16767270 DOI: 10.1039/B601547F  0.771
2006 Urbano J, Izarra R, Gómez-Ariza JL, Trofimenko S, Díaz-Requejo MM, Pérez PJ. A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium. Chemical Communications (Cambridge, England). 1000-2. PMID 16491189 DOI: 10.1039/B517337J  0.818
2006 Rodríguez P, Caballero A, Díaz-Requejo MM, Nicasio MC, Pérez PJ. Very efficient, reusable copper catalyst for carbene transfer reactions under biphasic conditions using ionic liquids. Organic Letters. 8: 557-60. PMID 16468710 DOI: 10.1021/Ol052564J  0.839
2006 Braga AAC, Maseras F, Urbano J, Caballero A, Díaz-Requejo MM, Pérez PJ. Mechanism of alkane C-H bond activation by copper and silver homoscorpionate complexes Organometallics. 25: 5292-5300. DOI: 10.1021/Om060445H  0.824
2006 Fructos MR, Frémont Pd, Nolan SP, and MMD,, Pérez PJ. Alkane carbon-hydrogen bond functionalization with (NHC)MCl precatalysts (M = Cu, Au ; NHC=N-heterocyclic carbene) Organometallics. 25: 2237-2241. DOI: 10.1021/Om0507474  0.804
2005 Fructos MR, Belderrain TR, de Frémont P, Scott NM, Nolan SP, Díaz-Requejo MM, Pérez PJ. A gold catalyst for carbene-transfer reactions from ethyl diazoacetate. Angewandte Chemie (International Ed. in English). 44: 5284-8. PMID 16038003 DOI: 10.1002/Anie.200501056  0.827
2005 Caballero A, Díaz-Requejo MM, Trofimenko S, Belderrain TR, Pérez PJ. Copper-catalyzed addition of ethyl diazoacetate to furans: an alternative to dirhodium(II) tetraacetate. The Journal of Organic Chemistry. 70: 6101-4. PMID 16018710 DOI: 10.1021/Jo050551D  0.829
2005 Contreras L, Paneque M, Sellin M, Carmona E, Pérez PJ, Gutiérrez-Puebla E, Monge MÁ, Ruiz C. Novel carbon dioxide and carbonyl carbonate complexes of molybdenum. The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]·H2O New Journal of Chemistry. 29: 109-115. DOI: 10.1039/B409385B  0.55
2005 Urbano J, Belderraín TR, Nicasio MC, Trofimenko S, and MMD,, Pérez PJ. Functionalization of primary carbon-hydrogen bonds of alkanes by carbene insertion with a silver-based catalyst Organometallics. 24: 1528-1532. DOI: 10.1021/Om050024K  0.438
2005 Díaz-Requejo MM, Wehrmann P, Leatherman MD, Trofimenko S, Mecking S, Brookhart M, Pérez PJ. Controlled, copper-catalyzed functionalization of polyolefins Macromolecules. 38: 4966-4969. DOI: 10.1021/Ma050626F  0.778
2005 Díaz-Requejo MM, Pérez PJ. Copper, silver and gold-based catalysts for carbene addition or insertion reactions Journal of Organometallic Chemistry. 690: 5441-5450. DOI: 10.1016/J.Jorganchem.2005.07.092  0.817
2004 Fructos MR, Belderrain TR, Nicasio MC, Nolan SP, Kaur H, Díaz-Requejo MM, Pérez PJ. Complete control of the chemoselectivity in catalytic carbene transfer reactions from ethyl diazoacetate: an N-heterocyclic carbene-Cu system that suppresses diazo coupling. Journal of the American Chemical Society. 126: 10846-7. PMID 15339161 DOI: 10.1021/Ja047284Y  0.837
2004 Rodriguez P, Diaz-Requejo MM, Belderrain TR, Trofimenko S, Nicasio MC, Perez PJ. Alkane dehydrogenation by sequential, double C-H bond activation by TpBr3Ir(C2H4)2 (Tpbr3 = hydrotris(3,4,5-tribromo)pyrazolylborate) Organometallics. 23: 2162-2167. DOI: 10.1021/Om034242U  0.765
2004 Mairena MA, Diaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. Copper-Homoscorpionate Complexes as Very Active Catalysts for the Olefin Aziridination Reaction Organometallics. 23: 253-256. DOI: 10.1021/Om034158E  0.822
2004 Morilla ME, Diaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. Reaction of ethyl diazoacetate with alkyl-aromatic substrates: Influence of the TpxCu catalyst in the addition versus insertion chemoselectivity (Tpx = homoscorpionate) Organometallics. 23: 293-295. DOI: 10.1021/Om034156U  0.819
2003 Díaz-Requejo MM, Belderraín TR, Nicasio MC, Trofimenko S, Pérez PJ. Cyclohexane and benzene amination by catalytic nitrene insertion into C-H bonds with the copper-homoscorpionate catalyst TpBr3CuNCMe. Journal of the American Chemical Society. 125: 12078-9. PMID 14518978 DOI: 10.1021/Ja037072L  0.806
2003 Caballero A, Díaz-Requejo MM, Belderraín TR, Nicasio MC, Trofimenko S, Pérez PJ. Highly regioselective functionalization of aliphatic carbon-hydrogen bonds with a perbromohomoscorpionate copper(I) catalyst. Journal of the American Chemical Society. 125: 1446-7. PMID 12568582 DOI: 10.1021/Ja0291484  0.858
2003 Caballero A, Diaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. Functionalization of Carbon−Hydrogen Bonds of Hydrocarbons and Ethers via Carbene Insertion with Copper(I)−Homoscorpionate Catalysts Organometallics. 22: 4145-4150. DOI: 10.1021/Om034002E  0.844
2003 Morilla ME, Molina MJ, Diaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Perez PJ. Copper-catalyzed carbene insertion into O-H bonds: High selective conversion of alcohols into ethers Organometallics. 22: 2914-2918. DOI: 10.1021/Om030243A  0.783
2002 Alías FM, Daff PJ, Paneque M, Poveda ML, Carmona E, Pérez PJ, Salazar V, Alvarado Y, Atencio R, Sánchez-Delgado R. C-C bond-forming reactions of Ir(III)-alkenyls and nitriles or aldehydes: generation of reactive hydride- and alkyl-alkylidene compounds and observation of a reversible 1, 2-H shift in stable hydride-Ir(III) alkylidene complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 5132-46. PMID 12613031 DOI: 10.1002/1521-3765(20021115)8:22<5132::Aid-Chem5132>3.0.Co;2-O  0.637
2002 Morilla ME, Díaz-Requejo MM, Belderrain TR, Nicasio MC, Trofimenko S, Pérez PJ. Catalytic insertion of diazo compounds into N-H bonds: the copper alternative. Chemical Communications (Cambridge, England). 2998-9. PMID 12536785 DOI: 10.1039/B207389G  0.796
2002 Morilla ME, Morfes G, Nicasio MC, Belderrain TR, Mar Díaz-Requejo M, Graiff C, Tiripicchio A, Sánchez-Delgado R, Pérez PJ. Intramolecular dealkylation of chelating diamines with Ru(II) complexes. Chemical Communications (Cambridge, England). 1848-9. PMID 12271639 DOI: 10.1039/B205078A  0.398
2002 Díaz-Requejo MM, Caballero A, Belderraín TR, Nicasio MC, Trofimenko S, Pérez PJ. Copper(I)-homoscorpionate catalysts for the preferential, kinetically controlled cis cyclopropanation of alpha-olefins with ethyl diazoacetate. Journal of the American Chemical Society. 124: 978-83. PMID 11829605 DOI: 10.1021/Ja011895Y  0.836
2002 Díaz-Requejo MM, Belderraín TR, Nicasio MC, Trofimenko S, Pérez PJ. Intermolecular copper-catalyzed carbon [bond] hydrogen bond activation via carbene insertion. Journal of the American Chemical Society. 124: 896-7. PMID 11829584 DOI: 10.1021/Ja016798J  0.819
2001 Díaz-Requejo MM, Mairena MA, Belderrain TR, Nicasio MC, Trofimenko S, Pérez PJ. A family of highly active copper(I)-homoscorpionate catalysts for the alkyne cyclopropenation reaction. Chemical Communications (Cambridge, England). 1804-5. PMID 12240323 DOI: 10.1039/B105020F  0.815
2001 Perez PJ, Calabrese JC, Bunel EE. Synthesis, characterization, and reactivity of [((iPr)2P(CH2)3P( iPr)2)(PCy3)PdH][OR] Organometallics. 20: 337-345. DOI: 10.1021/Om0008833  0.34
2001 Díaz-Requejo †MM, Belderraín TR, Trofimenko aS, Pérez PJ. Unprecedented Highly cis-Diastereoselective Olefin Cyclopropanation Using Copper Homoscorpionate Catalysts Journal of the American Chemical Society. 123: 3167-3168. DOI: 10.1021/Ja0155736  0.787
2001 Dı́az-Requejo MM, Pérez PJ. The use of polypyrazolylborate copper(I) complexes as catalysts in the conversion of olefins into cyclopropanes, aziridines and epoxides and alkynes into cyclopropenes Journal of Organometallic Chemistry. 617: 110-118. DOI: 10.1016/S0022-328X(00)00669-0  0.828
2000 Díaz-Requejo MM, Belderraín TR, Pérez PJ. Polypyrazolylborate copper(I) complexes as catalysts of the homogeneous and heterogeneous styrene epoxidation reaction Chemical Communications. 1853-1854. DOI: 10.1039/B004806M  0.812
2000 Díaz-Requejo MM, Belderrain TR, Nicasio aMC, Pérez PJ. From Homogeneous to Heterogeneous Catalysis: Novel Anchoring of Polypyrazolylborate Copper(I) Complexes on Silica Gel through Classical and Nonclassical Hydrogen Bonds. Use as Catalysts of the Olefin Cyclopropanation Reaction Organometallics. 19: 285-289. DOI: 10.1021/Om990780O  0.824
2000 Díaz-Requejo MM, Nicasio MC, Belderrain TR, Pérez PJ, Puerta MC, Valerga P. Novel (Methyl)‐ and (Acetyl)palladium Complexes Containing Bis(pyrazolyl)borate Ligands – Dynamic Equilibrium between η2 and η1 Forms for the Complex Bp*(Me)(PCy3)Pd [Bp* = dihydridobis(3,5‐dimethylpyrazolyl)borate] European Journal of Inorganic Chemistry. 2000: 1359-1364. DOI: 10.1002/(Sici)1099-0682(200006)2000:6<1359::Aid-Ejic1359>3.0.Co;2-D  0.762
1999 Paneque M, Pérez PJ, Pizzano A, Poveda ML, Taboada S, Trujillo M, Carmona E. C−H Activation Reactions on Rh(I)−Ethylene Complexes of the Hydrotris(3,5-dimethylpyrazolyl)borate Ligand, TpMe2 Organometallics. 18: 4304-4310. DOI: 10.1021/Om990376P  0.597
1999 Díaz-Requejo †MM, Belderrain TR, Nicasio MC, Prieto aF, Pérez PJ. Kinetics of the BpCu-Catalyzed Carbene Transfer Reaction (Bp = Dihydridobis(1-pyrazolyl)borate). Is a 14-Electron Species the Real Catalyst for the General Copper-Mediated Olefin Cyclopropanation? Organometallics. 18: 2601-2609. DOI: 10.1021/Om990270U  0.812
1998 Gutiérrez-Puebla E, Monge Á, Nicasio MC, Pérez PJ, Poveda ML, Rey L, Ruíz C, Carmona E. Vinylic C-H Bond Activation and Hydrogenation Reactions of Tp'Ir(C(2)H(4))(L) Complexes. Inorganic Chemistry. 37: 4538-4546. PMID 11670599 DOI: 10.1021/IC9800785  0.562
1998 Díaz-Requejo MM, Nicasio aMC, Pérez PJ. BpCu-Catalyzed Cyclopropanation of Olefins: A Simple System That Operates under Homogeneous and Heterogeneous Conditions (Bp = Dihydridobis(pyrazolyl)borate)† Organometallics. 17: 3051-3057. DOI: 10.1021/Om980061U  0.732
1998 Baena MJ, Reyes ML, Rey L, Carmona E, Nicasio MC, Pérez PJ, Gutiérrez E, Monge A. Synthesis and characterisation of rhodium(I) complexes containing the dihydrobis(pyrazolyl)borate ligands [H2B(pz′)2]. The X-ray structures of Bp*Rh(C2H4)2 and BpRh(PPh3)2 (Bp = H2B(pz)2; Bp* = H2B(3,5-Me2-pz)2 Inorganica Chimica Acta. 273: 244-254. DOI: 10.1016/S0020-1693(97)06146-X  0.573
1998 Gutiérrez-Puebla E, Monge Á, Nicasio MC, Pérez PJ, Poveda ML, Carmona E. C−H Bond Activation of Benzene and Cyclic Ethers by TpIrIII Species Chemistry: a European Journal. 4: 2225-2236. DOI: 10.1002/(Sici)1521-3765(19981102)4:11<2225::Aid-Chem2225>3.0.Co;2-I  0.612
1997 Díaz-Requejo MM, Pérez PJ, Brookhart M, Templeton JL. Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para-Substituted Styrenes† Organometallics. 16: 4399-4402. DOI: 10.1021/Om970382Q  0.812
1997 Alvarado Y, Boutry O, Gutiérrez E, Monge A, Nicasio MC, Poveda ML, Pérez PJ, Ruíz C, Bianchini C, Carmona E. Formation of Hydrido–η3-Allyl Complexes of IrIII by Sequential Olefinic CH Bond Activation and CC Coupling of Alkenyl and Olefin Ligands Chemistry: a European Journal. 3: 860-873. DOI: 10.1002/Chem.19970030606  0.646
1997 Díaz-Requejo MM, Pérez PJ, Brookhart M, Templeton JL. Substituent effects on the reaction rates of copper-catalyzed cyclopropanation and aziridination of para-substituted styrenes Organometallics. 16: 4399-4402.  0.785
1996 Alvarado Y, Daff PJ, Pérez PJ, Poveda ML, Sánchez-Delgado †aR, Carmona E. Iridapyrrole Complexes via Formal 3 + 2 Cycloaddition of Iridium Alkenyls to Acetonitrile Organometallics. 15: 2192-2194. DOI: 10.1021/Om950957O  0.619
1995 Galindo A, Gutiérrez E, Monge A, Paneque M, Pastor A, Pérez PJ, Rogers RD, Carmona E. Dinitrogen, butadiene and related complexes of molybdenum. Crystal structures of [Mo(N2)(PMe3)5] and [Mo(η3-CH3CHCHCH2)(η4-C4H6)(PEt3)2][BF4] Journal of the Chemical Society-Dalton Transactions. 3801-3808. DOI: 10.1039/Dt9950003801  0.562
1995 Pérez PJ, Poveda ML, Carmona E. Does the Facile Inter- and Intramolecular CH Bond Activation by Tp*–Rh Complexes Proceed via RhI or RhIII Intermediates?† Angewandte Chemie. 34: 231-233. DOI: 10.1002/Anie.199502311  0.591
1995 Pérez PJ, Poveda ML, Carmona E. Einfache inter- und intramolekulare CH-Aktivierung mit Tp*-Rh-Komplexen: RhI- oder RhIII-Zwischenstufen?† Angewandte Chemie. 107: 242-244. DOI: 10.1002/Ange.19951070226  0.498
1994 Powell KR, Perez PJ, Luan L, Feng SG, White PS, Brookhart M, Templeton JL. Synthesis and Reactivity of Low-Valent Amido, Imido, Azavinylidene, and Nitrido Complexes of Tungsten Organometallics. 13: 1851-1864. DOI: 10.1021/Om00017A048  0.677
1994 Perez PJ, White PS, Brookhart M, Templeton JL. Nitrene Transfer to Trimethylphosphine from Cationic Tungsten Tosylnitrene Complexes [Tp'(CO)2W(NTs)][X] Inorganic Chemistry. 33: 6050-6056. DOI: 10.1021/Ic00104A013  0.615
1993 Galindo A, Pastor A, Perez PJ, Carmona E. Bis(ethylene) complexes of molybdenum and tungsten and their reactivity toward carbon dioxide. New examples of acrylate formation by coupling of ethylene and carbon dioxide Organometallics. 12: 4443-4451. DOI: 10.1021/Om00035A031  0.542
1993 Pérez PJ, Brookhart M, Templeton JL. A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines Organometallics. 12: 261-262. DOI: 10.1021/Om00026A007  0.759
1993 Pérez PJ, Brookhart M, Templeton JL. A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines Organometallics. 12: 261-262.  0.345
1992 Pérez PJ, Poveda ML, Carmona E. Ethylene dimerization: an alternative route involving vinyl hydride intermediates Journal of the Chemical Society, Chemical Communications. 8-9. DOI: 10.1039/C39920000008  0.564
1992 Perez PJ, Luan L, White PS, Brookhart M, Templeton JL. Simple low-valent amido, imido and nitrido complexes of tungsten Journal of the American Chemical Society. 114: 7928-7929. DOI: 10.1021/Ja00046A059  0.375
1992 Boutry O, Gutierrez E, Monge A, Nicasio MC, Perez PJ, Carmona E. Double carbon-hydrogen activation at the .alpha.-carbon of cyclic ethers by Tp*Ir(C2H4)2 Journal of the American Chemical Society. 114: 7288-7290. DOI: 10.1021/Ja00044A046  0.531
1991 Carmona E, Hughes AK, Munoz MA, O'Hare DM, Perez PJ, Poveda ML. Rotational isomerism and fluxional behavior of bis(carbon dioxide) adducts of molybdenum Journal of the American Chemical Society. 113: 9210-9218. DOI: 10.1021/Ja00024A030  0.507
1991 Alvarez R, Atwood JL, Carmona E, Perez PJ, Poveda ML, Rogers RD. Formation of carbonyl-carbonate complexes of molybdenum by reductive disproportionation of carbon dioxide. X-ray structure of Mo4(.mu.4-CO3)(CO)2(O)2(.mu.2-O)2(.mu.2-OH)4(PMe3)6 Inorganic Chemistry. 30: 1493-1499. DOI: 10.1021/Ic00007A014  0.587
1990 Carmona E, Munoz MA, Perez PJ, Poveda ML. Rotational isomerism in bis(carbon dioxide) complexes of molybdenum generated by conrotatory motion of the CO2 ligands Organometallics. 9: 1337-1339. DOI: 10.1021/Om00118A077  0.546
1989 Carmona E, Gutierrez-Puebla E, Monge A, Perez PJ, Sanchez LJ. Synthesis and properties of nitrosyl complexes of molybdenum and tungsten containing halide and trimethylphosphine ligands. Crystal and molecular structures of MoCl3(NO)(PMe3)3 and MoCl(NO)(S2CPMe3-S,S',C)(PMe3)2 Inorganic Chemistry. 28: 2120-2127. DOI: 10.1021/Ic00310A021  0.56
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