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Neal P. Mankad, Ph.D. - Publications

Affiliations: 
Chemistry University of Illinois at Chicago, Chicago, IL, United States 
Area:
inorganic chemistry, catalysis
Website:
http://chem.uic.edu/chemistry/people/faculty/neal-mankad
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77 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Mankad NP. Triazenide-supported [CuS] structural mimics of Cu that mediate NO disproportionation rather than reduction. Chemical Science. 15: 1820-1828. PMID 38303935 DOI: 10.1039/d3sc05451a  0.386
2023 Alayoglu P, Chang T, Yan C, Chen YS, Mankad NP. Uncovering a CF Effect on X-ray Absorption Energies of [Cu(CF ) ] and Related Copper Compounds by Using Resonant Diffraction Anomalous Fine Structure (DAFS) Measurements. Angewandte Chemie (International Ed. in English). e202313744. PMID 37938103 DOI: 10.1002/anie.202313744  0.375
2023 Radzhabov MR, Mankad NP. Activation of robust bonds by carbonyl complexes of Mn, Fe and Co. Chemical Communications (Cambridge, England). 59: 11932-11946. PMID 37727948 DOI: 10.1039/d3cc03078d  0.307
2023 Tung P, Mankad NP. Light-Mediated Synthesis of Aliphatic Anhydrides by Cu-Catalyzed Carbonylation of Alkyl Halides. Journal of the American Chemical Society. 145: 9423-9427. PMID 37075476 DOI: 10.1021/jacs.3c01224  0.348
2023 Basu D, Subasinghe SMS, Mankad NP. Reactivity of a Dithiocarbamate-Ligated [W≡S] Complex with Hydride Donors: Toward a Synthetic Mimic of Formate Dehydrogenase. Inorganic Chemistry. PMID 37026841 DOI: 10.1021/acs.inorgchem.3c00086  0.323
2021 Yu HC, Telser J, Mankad NP. Synthesis and characterization of heteromultinuclear Ni/M clusters (M = Fe, Ru, W) including a paramagnetic (NHC)Ni-WCp*(CO) heterobinuclear complex. Organometallics. 40: 2123-2132. PMID 36405371 DOI: 10.1021/acs.organomet.1c00263  0.352
2021 Cheng LJ, Mankad NP. Copper-Catalyzed Carbonylative Coupling of Alkyl Halides. Accounts of Chemical Research. PMID 33881839 DOI: 10.1021/acs.accounts.1c00115  0.331
2021 Rathnayaka SC, Mankad NP. Coordination chemistry of the Cu site in nitrous oxide reductase and its synthetic mimics. Coordination Chemistry Reviews. 429. PMID 33692589 DOI: 10.1016/j.ccr.2020.213718  0.352
2020 Rathnayaka SC, Islam SM, DiMucci IM, MacMillan SN, Lancaster KM, Mankad NP. Probing the electronic and mechanistic roles of the μ-sulfur atom in a synthetic Cu model system. Chemical Science. 11: 3441-3447. PMID 34745516 DOI: 10.1039/c9sc06251c  0.391
2020 Cheng LJ, Zhao S, Mankad N. One-Step Synthesis of Acylboron Compounds via Cu-Catalyzed Carbonylative Borylation of Alkyl Halides. Angewandte Chemie (International Ed. in English). PMID 33090619 DOI: 10.1002/anie.202012373  0.345
2020 Ghosh D, Sinhababu S, Santarsiero BD, Mankad NP. A W/Cu synthetic model for the Mo/Cu cofactor of aerobic CODH indicates that biochemical CO oxidation requires a frustrated Lewis acid/base pair. Journal of the American Chemical Society. PMID 32598845 DOI: 10.1021/Jacs.0C03343  0.464
2020 Cheng LJ, Mankad NP. C-C and C-X coupling reactions of unactivated alkyl electrophiles using copper catalysis. Chemical Society Reviews. PMID 32458840 DOI: 10.1039/D0Cs00316F  0.374
2020 Rathnayaka SC, Hsu CW, Johnson BJ, Iniguez SJ, Mankad NP. Impact of Electronic and Steric Changes of Ligands on the Assembly, Stability, and Redox Activity of Cu(μ-S) Model Compounds of the Cu Active Site of Nitrous Oxide Reductase (NOR). Inorganic Chemistry. PMID 32309936 DOI: 10.1021/Acs.Inorgchem.0C00564  0.459
2020 Cheng LJ, Mankad NP. Cu-Catalyzed Carbonylative Silylation of Alkyl Halides: Efficient Access to Acylsilanes. Journal of the American Chemical Society. 142: 80-84. PMID 31851513 DOI: 10.1021/Jacs.9B12043  0.429
2020 Rathnayaka SC, Islam SM, DiMucci IM, MacMillan SN, Lancaster KM, Mankad NP. Probing the electronic and mechanistic roles of the μ4-sulfur atom in a synthetic CuZ model system Chemical Science. 11: 3441-3447. DOI: 10.1039/C9Sc06251C  0.323
2020 Yu H, Islam SM, Mankad NP. Cooperative Heterobimetallic Substrate Activation Enhances Catalytic Activity and Amplifies Regioselectivity in 1,4-Hydroboration of Pyridines Acs Catalysis. 10: 3670-3675. DOI: 10.1021/Acscatal.0C00515  0.352
2020 Lakliang Y, Mankad NP. Heterometallic Cu2Fe and Zn2Fe2 Complexes Derived from [Fe(CO)4]2– and Cu/Fe Bifunctional N2O Activation Reactivity Organometallics. 39: 2043-2046. DOI: 10.1021/Acs.Organomet.0C00212  0.439
2019 Zhao S, Mankad NP. Synergistic Copper-Catalyzed Reductive Aminocarbonylation of Alkyl Iodides with Nitroarenes. Organic Letters. PMID 31802670 DOI: 10.1021/Acs.Orglett.9B04092  0.472
2019 Hsu CW, Rathnayaka SC, Islam SM, MacMillan SN, Mankad N. N2O Reductase Activity of a [Cu4S] Cluster in the 4CuI Redox State Modulated by Hydrogen Bond Donors and Proton Relays in the Secondary Coordination Sphere. Angewandte Chemie (International Ed. in English). PMID 31661177 DOI: 10.1002/Anie.201906327  0.469
2019 Cheng LJ, Mankad NP. Heterobimetallic Control of Regioselectivity in Alkyne Hydrostannylation: Divergent Syntheses of α- and (E)-β-Vinylstannanes via Cooperative Sn-H Bond Activation. Journal of the American Chemical Society. PMID 30702884 DOI: 10.1021/Jacs.9B00068  0.504
2019 Leon NJ, Yu H, Mazzacano TJ, Mankad NP. Pursuit of C–H Borylation Reactions with Non-Precious Heterobimetallic Catalysts: Hypothesis-Driven Variations on a Design Theme Synlett. 31: 125-132. DOI: 10.1055/S-0039-1691504  0.388
2019 Zhang Y, Karunananda MK, Yu H, Clark KJ, Williams W, Mankad NP, Ess DH. Dynamically Bifurcating Hydride Transfer Mechanism and Origin of Inverse Isotope Effect for Heterodinuclear AgRu-Catalyzed Alkyne Semihydrogenation Acs Catalysis. 9: 2657-2663. DOI: 10.1021/Acscatal.8B04130  0.738
2019 Leon NJ, Yu H, Mazzacano TJ, Mankad NP. Mixed phosphine/carbonyl derivatives of heterobimetallic copper–iron and copper–tungsten catalysts Polyhedron. 157: 116-123. DOI: 10.1016/J.Poly.2018.09.062  0.465
2018 Rathnayaka SC, Lindeman SV, Mankad NP. Multinuclear Cu(I) Clusters Featuring a New Triply Bridging Coordination Mode of Phosphaamidinate Ligands. Inorganic Chemistry. PMID 30003779 DOI: 10.1021/Acs.Inorgchem.8B01422  0.442
2018 Cheng LJ, Mankad N. Cu-Catalyzed Borocarbonylative Coupling of Internal Alkynes with Unactivated Alkyl Halides: Modular Synthesis of Tetrasubstituted β-Borylenones. Angewandte Chemie (International Ed. in English). PMID 29846998 DOI: 10.1002/Anie.201804883  0.375
2018 Zhao S, Mankad N. Cu-catalyzed Hydroxymethylation of Unactivated Alkyl Iodides with CO to Provide One Carbon Extended Alcohols. Angewandte Chemie (International Ed. in English). PMID 29504659 DOI: 10.1002/Anie.201801814  0.44
2018 Bagherzadeh S, Mankad NP. Oxidation of a [Cu2S] complex by N2O and CO2: insights into a role of tetranuclearity in the CuZ site of nitrous oxide reductase. Chemical Communications (Cambridge, England). PMID 29333559 DOI: 10.1039/C7Cc09067F  0.46
2018 Mankad NP. Diverse bimetallic mechanisms emerging from transition metal Lewis acid/base pairs: development of co-catalysis with metal carbenes and metal carbonyl anions. Chemical Communications (Cambridge, England). PMID 29333547 DOI: 10.1039/C7Cc09675E  0.392
2017 Pye DR, Mankad NP. Bimetallic catalysis for C-C and C-X coupling reactions. Chemical Science. 8: 1705-1718. PMID 29780450 DOI: 10.1039/C6Sc05556G  0.388
2017 Cheng LJ, Islam SM, Mankad NP. Synthesis of Allylic Alcohols via Cu-Catalyzed Hydrocarbonylative Coupling of Alkynes with Alkyl Halides. Journal of the American Chemical Society. PMID 29278494 DOI: 10.1021/Jacs.7B12582  0.393
2017 Pye DR, Cheng LJ, Mankad NP. Cu/Mn bimetallic catalysis enables carbonylative Suzuki-Miyaura coupling with unactivated alkyl electrophiles. Chemical Science. 8: 4750-4755. PMID 28966784 DOI: 10.1039/C7Sc01170A  0.477
2017 Cheng LJ, Mankad NP. Cu-Catalyzed Hydrocarbonylative C-C Coupling of Terminal Alkynes with Alkyl Iodides. Journal of the American Chemical Society. PMID 28700224 DOI: 10.1021/Jacs.7B05205  0.447
2017 Karunananda MK, Mankad NP. Cooperative Strategies for Catalytic Hydrogenation of Unsaturated Hydrocarbons Acs Catalysis. 7: 6110-6119. DOI: 10.1021/Acscatal.7B02203  0.75
2016 Mazzacano TJ, Leon NJ, Waldhart GW, Mankad NP. Fundamental organometallic chemistry under bimetallic influence: driving β-hydride elimination and diverting migratory insertion at Cu and Ni. Dalton Transactions (Cambridge, England : 2003). PMID 27991624 DOI: 10.1039/C6Dt04533B  0.406
2016 Johnson BJ, Antholine WE, Lindeman SV, Graham MJ, Mankad NP. A 1-hole Cu4S cluster with N2O reductase activity: a structural and functional model for CuZ. Journal of the American Chemical Society. PMID 27685680 DOI: 10.1021/Jacs.6B05480  0.415
2016 Mankad NP. Selectivity Effects in Bimetallic Catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26879884 DOI: 10.1002/Chem.201505002  0.346
2016 Bagherzadeh S, Mankad NP. Extremely efficient hydroboration of ketones and aldehydes by copper carbene catalysis. Chemical Communications (Cambridge, England). PMID 26871503 DOI: 10.1039/C5Cc09162D  0.447
2016 Mazzacano TJ, Mankad NP. Dehydrogenative Borylation and Silylation of Styrenes Catalyzed by Copper-Carbenes Acs Catalysis. 7: 146-149. DOI: 10.1021/Acscatal.6B02594  0.447
2016 Karunananda MK, Mankad NP. Heterobimetallic H2 Addition and Alkene/Alkane Elimination Reactions Related to the Mechanism of E-Selective Alkyne Semihydrogenation Organometallics. 36: 220-227. DOI: 10.1021/Acs.Organomet.6B00356  0.752
2015 Karunananda MK, Mankad NP. E-Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis. Journal of the American Chemical Society. PMID 26550848 DOI: 10.1021/Jacs.5B10357  0.772
2015 Parmelee SR, Mankad NP. A data-intensive re-evaluation of semibridging carbonyl ligands. Dalton Transactions (Cambridge, England : 2003). 44: 17007-14. PMID 26391421 DOI: 10.1039/C5Dt02813B  0.304
2015 Bagherzadeh S, Mankad NP. Catalyst Control of Selectivity in CO2 Reduction Using a Tunable Heterobimetallic Effect. Journal of the American Chemical Society. PMID 26293355 DOI: 10.1021/Jacs.5B05692  0.483
2015 Johnson BJ, Antholine WE, Lindeman SV, Mankad NP. A Cu4S model for the nitrous oxide reductase active sites supported only by nitrogen ligands. Chemical Communications (Cambridge, England). PMID 26111160 DOI: 10.1039/C5Cc04675K  0.461
2015 Mazzacano TJ, Mankad NP. Thermal C-H borylation using a CO-free iron boryl complex. Chemical Communications (Cambridge, England). 51: 5379-82. PMID 25515057 DOI: 10.1039/C4Cc09180A  0.346
2015 Parmelee SR, Mazzacano TJ, Zhu Y, Mankad NP, Keith JA. A heterobimetallic mechanism for c-h borylation elucidated from experimental and computational data Acs Catalysis. 5: 3689-3699. DOI: 10.1021/Acscatal.5B00275  0.436
2015 Karunananda MK, Parmelee SR, Waldhart GW, Mankad NP. Experimental and Computational Characterization of the Transition State for C-X Bimetallic Oxidative Addition at a Cu-Fe Reaction Center Organometallics. 34: 3857-3864. DOI: 10.1021/Acs.Organomet.5B00476  0.795
2014 Banerjee S, Karunananda MK, Bagherzadeh S, Jayarathne U, Parmelee SR, Waldhart GW, Mankad NP. Synthesis and characterization of heterobimetallic complexes with direct Cu-M bonds (M = Cr, Mn, Co, Mo, Ru, W) supported by N-heterocyclic carbene ligands: a toolkit for catalytic reaction discovery. Inorganic Chemistry. 53: 11307-15. PMID 25275927 DOI: 10.1021/Ic5019778  0.786
2014 Johnson BJ, Lindeman SV, Mankad NP. Assembly, structure, and reactivity of Cu₄S and Cu₃S models for the nitrous oxide reductase active site, Cu(Z)*. Inorganic Chemistry. 53: 10611-9. PMID 25211396 DOI: 10.1021/Ic501720H  0.487
2014 Karunananda MK, Vázquez FX, Alp EE, Bi W, Chattopadhyay S, Shibata T, Mankad NP. Experimental determination of redox cooperativity and electronic structures in catalytically active Cu-Fe and Zn-Fe heterobimetallic complexes. Dalton Transactions (Cambridge, England : 2003). 43: 13661-71. PMID 25100199 DOI: 10.1039/C4Dt01841A  0.789
2014 Jayarathne U, Parmelee SR, Mankad NP. Small molecule activation chemistry of Cu-Fe heterobimetallic complexes toward CS2 and N2O. Inorganic Chemistry. 53: 7730-7. PMID 24979669 DOI: 10.1021/Ic501054Z  0.487
2014 Waldhart GW, Mankad NP. trans-Tetra-carbonyl-bis-(tri-phenyl-phosphane-κP)molybdenum(0). Acta Crystallographica. Section E, Structure Reports Online. 70: m36. PMID 24764810 DOI: 10.1107/S1600536814000300  0.335
2014 Johnson MW, Bagley SW, Mankad NP, Bergman RG, Mascitti V, Toste FD. Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives. Angewandte Chemie (International Ed. in English). 53: 4404-7. PMID 24652820 DOI: 10.1002/Anie.201400037  0.508
2014 Mankad NP. Non-precious metal catalysts for C-H borylation enabled by metal-metal cooperativity Synlett. 25: 1197-1201. DOI: 10.1055/S-0033-1340823  0.375
2014 Karunananda MK, Vázquez FX, Alp EE, Bi W, Chattopadhyay S, Shibata T, Mankad NP. Experimental determination of redox cooperativity and electronic structures in catalytically active Cu-Fe and Zn-Fe heterobimetallic complexes Dalton Transactions. 43: 13661-13671. DOI: 10.1039/c4dt01841a  0.765
2014 Jayarathne U, Parmelee SR, Mankad NP. Small molecule activation chemistry of Cu-Fe heterobimetallic complexes toward CS2 and N2O Inorganic Chemistry. 53: 7730-7737. DOI: 10.1021/ic501054z  0.339
2014 Waldhart GW, Mankad NP. Photochemical Heck benzylation of styrenes catalyzed by Na[FeCp(CO)2] Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2014.12.033  0.407
2014 Johnson MW, Bagley SW, Mankad NP, Bergman RG, Mascitti V, Toste FD. ChemInform Abstract: Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives. Cheminform. 45: no-no. DOI: 10.1002/chin.201441091  0.42
2013 Mazzacano TJ, Mankad NP. Base metal catalysts for photochemical C-H borylation that utilize metal-metal cooperativity. Journal of the American Chemical Society. 135: 17258-61. PMID 24074248 DOI: 10.1021/Ja408861P  0.431
2013 Jayarathne U, Mazzacano TJ, Bagherzadeh S, Mankad NP. Heterobimetallic complexes with polar, unsupported Cu-Fe and Zn-Fe bonds stabilized by N-heterocyclic carbenes Organometallics. 32: 3986-3992. DOI: 10.1021/Om400471U  0.492
2012 Mankad NP, Toste FD. C(sp(3))-F reductive elimination from alkylgold(iii) fluoride complexes. Chemical Science (Royal Society of Chemistry : 2010). 3: 72-76. PMID 23087810 DOI: 10.1039/C1Sc00515D  0.476
2011 Tkatchouk E, Mankad NP, Benitez D, Goddard WA, Toste FD. Two metals are better than one in the gold catalyzed oxidative heteroarylation of alkenes. Journal of the American Chemical Society. 133: 14293-300. PMID 21861448 DOI: 10.1021/Ja2012627  0.596
2011 Takaoka A, Mankad NP, Peters JC. Dinitrogen complexes of sulfur-ligated iron. Journal of the American Chemical Society. 133: 8440-3. PMID 21574618 DOI: 10.1021/Ja2020907  0.568
2010 Tsay C, Mankad NP, Peters JC. Four-coordinate, trigonal pyramidal Pt(II) and Pd(II) complexes. Journal of the American Chemical Society. 132: 13975-7. PMID 20857908 DOI: 10.1021/Ja105284P  0.565
2010 Mankad NP, Toste FD. C-C coupling reactivity of an alkylgold(III) fluoride complex with arylboronic acids. Journal of the American Chemical Society. 132: 12859-61. PMID 20726525 DOI: 10.1021/Ja106257N  0.552
2010 Lee Y, Mankad NP, Peters JC. Triggering N(2) uptake via redox-induced expulsion of coordinated NH(3) and N(2) silylation at trigonal bipyramidal iron. Nature Chemistry. 2: 558-65. PMID 20571574 DOI: 10.1038/Nchem.660  0.654
2010 Mankad NP, Müller P, Peters JC. Catalytic N-N coupling of aryl azides to yield azoarenes via trigonal bipyramid iron-nitrene intermediates. Journal of the American Chemical Society. 132: 4083-5. PMID 20199026 DOI: 10.1021/Ja910224C  0.575
2009 Mankad NP, Harkins SB, Antholine WE, Peters JC. Multifrequency EPR studies of [Cu(1.5)Cu(1.5)](+) for Cu2(mu-NR2)2 and Cu2(mu-PR2)2 diamond cores. Inorganic Chemistry. 48: 7026-32. PMID 19572723 DOI: 10.1021/Ic801864Z  0.797
2009 Mankad NP, Antholine WE, Szilagyi RK, Peters JC. Three-coordinate copper(I) amido and aminyl radical complexes. Journal of the American Chemical Society. 131: 3878-80. PMID 19253942 DOI: 10.1021/Ja809834K  0.662
2009 Whited MT, Mankad NP, Lee Y, Oblad PF, Peters JC. Dinitrogen complexes supported by tris(phosphino)silyl ligands. Inorganic Chemistry. 48: 2507-17. PMID 19209938 DOI: 10.1021/Ic801855Y  0.776
2008 Harkins SB, Mankad NP, Miller AJ, Szilagyi RK, Peters JC. Probing the electronic structures of [Cu2(mu-XR2)]n+ diamond cores as a function of the bridging X atom (X = N or P) and charge (n = 0, 1, 2). Journal of the American Chemical Society. 130: 3478-85. PMID 18298114 DOI: 10.1021/Ja076537V  0.788
2008 Mankad NP, Peters JC. Diazoalkanes react with a bis(phosphino)borate copper(i) source to generate [Ph2BP(tBu)2]Cu(eta1-N2CR2), [Ph2BP(tBu)2]Cu(CPh2), and [Ph2BP(tBu)2]Cu-N(CPh2)(NCPh2). Chemical Communications (Cambridge, England). 1061-3. PMID 18292890 DOI: 10.1039/B713687K  0.626
2007 Mankad NP, Whited MT, Peters JC. Terminal FeI-N2 and FeII...H-C interactions supported by tris(phosphino)silyl ligands. Angewandte Chemie (International Ed. in English). 46: 5768-71. PMID 17600810 DOI: 10.1002/Anie.200701188  0.715
2006 Thomas CM, Mankad NP, Peters JC. Characterization of the terminal iron(IV) imides [[PhBP(t)(Bu)2(pz')]Fe(IV)NAd]+. Journal of the American Chemical Society. 128: 4956-7. PMID 16608321 DOI: 10.1021/Ja0604358  0.658
2005 Mankad NP, Rivard E, Harkins SB, Peters JC. Structural snapshots of a flexible Cu2P2 core that accommodates the oxidation states Cu(I)Cu(I), Cu1.5Cu1.5, and Cu(II)Cu(II). Journal of the American Chemical Society. 127: 16032-3. PMID 16287283 DOI: 10.1021/Ja056071L  0.778
2004 Rieth RD, Mankad NP, Calimano E, Sadighi JP. Palladium-catalyzed cross-coupling of pyrrole anions with aryl chlorides, bromides, and iodides. Organic Letters. 6: 3981-3. PMID 15496079 DOI: 10.1021/Ol048367M  0.687
2004 Mankad NP, Laitar DS, Sadighi JP. Synthesis, structure, and alkyne reactivity of a dimeric (carbene)copper(I) hydride Organometallics. 23: 3369-3371. DOI: 10.1021/Om0496380  0.718
2004 Mankad NP, Gray TG, Laitar DS, Sadighi JP. Synthesis, Structure, and CO 2 Reactivity of a Two-Coordinate (Carbene)copper(I) Methyl Complex Organometallics. 23: 1191-1193. DOI: 10.1021/Om034368R  0.706
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