| Year |
Citation |
Score |
| 2023 |
Zhao C, Besset T, Legault CY, Jubault P. Experimental and Computational Studies for the Synthesis of Functionalized Cyclopropanes from 2-Substituted Allylic Derivatives with Ethyl Diazoacetate. Chemistry (Weinheim An Der Bergstrasse, Germany). e202303070. PMID 37985211 DOI: 10.1002/chem.202303070 |
0.413 |
|
| 2023 |
Schneider Y, Jadhav AP, Legault CY. Synthesis of Indoles Using the Electrophilic Potential of Diazirines. The Journal of Organic Chemistry. 88: 14809-14819. PMID 37779242 DOI: 10.1021/acs.joc.3c01673 |
0.314 |
|
| 2023 |
Nguyen TM, Legault CY, Blanchard N, Bizet V, Cahard D. Tracking SF5I in the Iodopentafluorosulfanylation of Alkynes. Chemistry (Weinheim An Der Bergstrasse, Germany). e202302914. PMID 37698052 DOI: 10.1002/chem.202302914 |
0.314 |
|
| 2023 |
Lussier T, Legault CY. Iodine(III)-Mediated Enantioselective Oxidative Contraction of Dihydropyranones. Organic Letters. 25: 2825-2829. PMID 37058468 DOI: 10.1021/acs.orglett.3c00759 |
0.777 |
|
| 2021 |
Pace DP, Robidas R, Tran UPN, Legault CY, Nguyen TV. Iodine-Catalyzed Synthesis of Substituted Furans and Pyrans: Reaction Scope and Mechanistic Insights. The Journal of Organic Chemistry. PMID 34048250 DOI: 10.1021/acs.joc.1c00608 |
0.405 |
|
| 2020 |
Wasfy N, Rasheed F, Robidas R, Hunter I, Shi J, Doan B, Legault CY, Fishlock D, Orellana A. Pyridylic anions are soft nucleophiles in the palladium-catalyzed C(sp)-H allylation of 4-alkylpyridines. Chemical Science. 12: 1503-1512. PMID 34163914 DOI: 10.1039/d0sc03304a |
0.388 |
|
| 2020 |
Wolf J, Huber F, Erochok N, Heinen F, Guerin V, Legault C, Kirsch S, Huber SM. Activation of a metal-halogen bond by halogen bonding. Angewandte Chemie (International Ed. in English). PMID 32472957 DOI: 10.1002/Anie.202005214 |
0.738 |
|
| 2020 |
Wolf J, Huber F, Erochok N, Heinen F, Guérin V, Legault CY, Kirsch SF, Huber SM. Aktivierung einer Metall‐Halogen‐Bindung durch Halogenbrücken Angewandte Chemie. 132: 16638-16643. DOI: 10.1002/Ange.202005214 |
0.685 |
|
| 2019 |
Zhao Z, Ma KCY, Legault CY, Murphy GK. Denitrogenative Hydrotrifluoromethylation of Benzaldehyde Hydrazones: Synthesis of (2,2,2-Trifluoroethyl)arenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31276254 DOI: 10.1002/Chem.201902818 |
0.403 |
|
| 2019 |
Dagenais R, Lussier T, Legault CY. Iodine(III)-Mediated Contraction of 3,4-Dihydropyranones: Access to Polysubstituted γ-Butyrolactones. Organic Letters. PMID 31247750 DOI: 10.1021/Acs.Orglett.9B01893 |
0.711 |
|
| 2019 |
Guérin V, Ménard A, Guernon H, Moutounet O, Legault CY. From Chelating to Bridging Ligands: N-Sulfonyliminoimidazolium Ylides as Precursors to Anionic N-Heterocyclic Carbene Ligands Organometallics. 38: 409-416. DOI: 10.1021/Acs.Organomet.8B00764 |
0.735 |
|
| 2018 |
Nikolaev A, Legault CY, Zhang M, Orellana A. The Acid-Free Cyclopropanol-Minisci Reaction Reveals the Catalytic Role of Silver-Pyridine Complexes. Organic Letters. PMID 29350043 DOI: 10.1021/Acs.Orglett.7B03938 |
0.441 |
|
| 2017 |
Robidas R, Guérin V, Provençal L, Echeverria M, Legault CY. Investigation of Iodonium Trifluoroborate Zwitterions as Bifunctional Arene Reagents. Organic Letters. PMID 29144752 DOI: 10.1021/Acs.Orglett.7B03307 |
0.748 |
|
| 2017 |
Labattut A, Tremblay PL, Moutounet O, Legault CY. Experimental and Theoretical Quantification of the Lewis Acidity of Iodine(III) Species. The Journal of Organic Chemistry. PMID 28770606 DOI: 10.1021/Acs.Joc.7B01616 |
0.301 |
|
| 2017 |
Cocaud C, Nicolas C, Poisson T, Pannecoucke X, Legault CY, Martin OR. Tunable Approach for the Stereoselective Synthesis of 1-C-Diethylphosphono(difluoromethyl) Iminosugars as Glycosyl Phosphate Mimics. The Journal of Organic Chemistry. PMID 28221798 DOI: 10.1021/Acs.Joc.6B03071 |
0.311 |
|
| 2017 |
Basdevant B, Guilbault A, Beaulieu S, Lauriers AJ, Legault CY. Iodine(III)-mediated synthesis of chiral α-substituted ketones: recent advances and mechanistic insights Pure and Applied Chemistry. 89: 781-789. DOI: 10.1515/Pac-2016-1212 |
0.414 |
|
| 2017 |
Dagenais R, Lauriers AJ, Legault CY. Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Investigation of the Effect of Iodine(III) Reagents Synthesis. 49: 2928-2932. DOI: 10.1055/S-0036-1588439 |
0.78 |
|
| 2016 |
Lauriers AJ, Legault CY. Enol and Ynol Surrogates: Promising Substrates for Hypervalent Iodine Chemistry Asian Journal of Organic Chemistry. 5: 1078-1099. DOI: 10.1002/Ajoc.201600246 |
0.418 |
|
| 2015 |
Jobin-Des Lauriers A, Legault CY. Metathetical Redox Reaction of (Diacetoxyiodo)arenes and Iodoarenes. Molecules (Basel, Switzerland). 20: 22635-44. PMID 26694343 DOI: 10.3390/Molecules201219874 |
0.465 |
|
| 2015 |
Jobin-Des Lauriers A, Legault CY. Iodine(III)-Mediated Oxidative Hydrolysis of Haloalkenes: Access to α-Halo Ketones by a Release-and-Catch Mechanism. Organic Letters. PMID 26679382 DOI: 10.1021/Acs.Orglett.5B03345 |
0.42 |
|
| 2015 |
Basdevant B, Legault CY. Enantioselective Iodine(III)-Mediated Synthesis of α-Tosyloxy Ketones: Breaking the Selectivity Barrier. Organic Letters. 17: 4918-21. PMID 26378799 DOI: 10.1021/Acs.Orglett.5B02501 |
0.494 |
|
| 2015 |
Beaulieu S, Legault CY. Mechanistic Insights on the Iodine(III)-Mediated α-Oxidation of Ketones. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 11206-11. PMID 26118902 DOI: 10.1002/Chem.201501177 |
0.435 |
|
| 2015 |
Basdevant B, Legault CY. Study of the Reactivity of [Hydroxy(tosyloxy)iodo]benzene Toward Enol Esters to Access α-Tosyloxy Ketones. The Journal of Organic Chemistry. 80: 6897-902. PMID 26098233 DOI: 10.1021/Acs.Joc.5B00948 |
0.449 |
|
| 2015 |
Langdon SM, Legault CY, Gravel M. Origin of chemoselectivity in N-heterocyclic carbene catalyzed cross-benzoin reactions: DFT and experimental insights. The Journal of Organic Chemistry. 80: 3597-610. PMID 25734574 DOI: 10.1021/Acs.Joc.5B00301 |
0.456 |
|
| 2015 |
Petiot P, Dansereau J, Hébert M, Khene I, Ahmad T, Samaali S, Leroy M, Pinsonneault F, Legault CY, Gagnon A. Copper-catalyzed O-arylation of N-protected 1,2-aminoalcohols using functionalized trivalent organobismuth reagents. Organic & Biomolecular Chemistry. 13: 1322-7. PMID 25501446 DOI: 10.1039/C4Ob02497D |
0.618 |
|
| 2015 |
Petiot P, Dansereau J, Hébert M, Khene I, Ahmad T, Samaali S, Leroy M, Pinsonneault F, Legault CY, Gagnon A. Copper-catalyzed O-arylation of N-protected 1,2-aminoalcohols using functionalized trivalent organobismuth reagents Organic and Biomolecular Chemistry. 13: 1322-1327. DOI: 10.1039/c4ob02497d |
0.533 |
|
| 2015 |
Langdon SM, Legault CY, Gravel M. Origin of chemoselectivity in N-heterocyclic carbene catalyzed cross-benzoin reactions: DFT and experimental insights Journal of Organic Chemistry. 80: 3597-3610. DOI: 10.1021/acs.joc.5b00301 |
0.325 |
|
| 2015 |
Champagne PA, Drouin M, Legault CY, Audubert C, Paquin JF. Revised mechanistic explanation for the alcohol-promoted amination of benzylic fluorides under highly concentrated conditions: Computational and experimental evidence on a model substrate Journal of Fluorine Chemistry. 171: 113-119. DOI: 10.1016/J.Jfluchem.2014.08.018 |
0.336 |
|
| 2014 |
Schneider Y, Prévost J, Gobin M, Legault CY. Diazirines as potent electrophilic nitrogen sources: application to the synthesis of pyrazoles. Organic Letters. 16: 596-9. PMID 24378081 DOI: 10.1021/Ol403495E |
0.363 |
|
| 2013 |
Champagne PA, Pomarole J, Thérien MÈ, Benhassine Y, Beaulieu S, Legault CY, Paquin JF. Enabling nucleophilic substitution reactions of activated alkyl fluorides through hydrogen bonding. Organic Letters. 15: 2210-3. PMID 23614350 DOI: 10.1021/Ol400765A |
0.382 |
|
| 2013 |
Guernon H, Legault CY. N -acyliminoimidazolium ylides as precursors to anionic N -heterocyclic carbene ligands: Control of topology and reactivity Organometallics. 32: 1988-1994. DOI: 10.1021/Om400078F |
0.381 |
|
| 2013 |
Thérien ME, Guilbault AA, Legault CY. New chiral iodooxazoline catalysts for the I(III)-mediated α-tosyloxylation of ketones: Refining the stereoinduction model Tetrahedron Asymmetry. 24: 1193-1197. DOI: 10.1016/J.Tetasy.2013.08.002 |
0.416 |
|
| 2012 |
Guilbault AA, Basdevant B, Wanie V, Legault CY. Catalytic enantioselective α-tosyloxylation of ketones using iodoaryloxazoline catalysts: insights on the stereoinduction process. The Journal of Organic Chemistry. 77: 11283-95. PMID 23234479 DOI: 10.1021/Jo302393U |
0.397 |
|
| 2012 |
Legault CY, Prévost J. 1-Fluoro-3,3-dimethyl-1,3-dihydro-1λ(3)-benzo[d][1,2]iodoxole. Acta Crystallographica. Section E, Structure Reports Online. 68: o1238. PMID 22606171 DOI: 10.1107/S1600536812012822 |
0.312 |
|
| 2012 |
Beaumier F, Dupuis M, Spino C, Legault CY. Formal intramolecular (4 + 1)-cycloaddition of dialkoxycarbenes: control of the stereoselectivity and a mechanistic portrait. Journal of the American Chemical Society. 134: 5938-53. PMID 22404454 DOI: 10.1021/Ja211927B |
0.455 |
|
| 2012 |
Guilbault AA, Legault CY. Drastic enhancement of activity in iodane-based α-tosyloxylation of ketones: Iodine(III) does the hypervalent twist Acs Catalysis. 2: 219-222. DOI: 10.1021/Cs200612S |
0.372 |
|
| 2011 |
Cheong PH, Legault CY, Um JM, Çelebi-Ölçüm N, Houk KN. Quantum mechanical investigations of organocatalysis: mechanisms, reactivities, and selectivities. Chemical Reviews. 111: 5042-137. PMID 21707120 DOI: 10.1021/Cr100212H |
0.762 |
|
| 2009 |
Garcia Y, Schoenebeck F, Legault CY, Merlic CA, Houk KN. Theoretical bond dissociation energies of halo-heterocycles: trends and relationships to regioselectivity in palladium-catalyzed cross-coupling reactions. Journal of the American Chemical Society. 131: 6632-9. PMID 19368385 DOI: 10.1021/Ja9004927 |
0.505 |
|
| 2008 |
Yu ZX, Cheong PH, Liu P, Legault CY, Wender PA, Houk KN. Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes. Journal of the American Chemical Society. 130: 2378-9. PMID 18251468 DOI: 10.1021/Ja076444D |
0.748 |
|
| 2008 |
Legault CY, Charette AB, Cozzi PG. Iridium catalyzed enantioselective hydrogenation of N-iminopyridinium ylides: Mechanistic insights Heterocycles. 76: 1271-1283. DOI: 10.3987/Com-08-S(N)93 |
0.562 |
|
| 2007 |
Legault CY, Garcia Y, Merlic CA, Houk KN. Origin of regioselectivity in palladium-catalyzed cross-coupling reactions of polyhalogenated heterocycles. Journal of the American Chemical Society. 129: 12664-5. PMID 17914827 DOI: 10.1021/Ja075785O |
0.515 |
|
| 2005 |
Legault CY, Kendall C, Charette AB. Structure and reactivity of a new anionic N-heterocyclic carbene silver(I) complex. Chemical Communications (Cambridge, England). 3826-8. PMID 16041430 DOI: 10.1039/B506232B |
0.569 |
|
| 2005 |
Legault CY, Charette AB. Catalytic asymmetric hydrogenation of N-iminopyridinium ylides: expedient approach to enantioenriched substituted piperidine derivatives. Journal of the American Chemical Society. 127: 8966-7. PMID 15969570 DOI: 10.1021/Ja0525298 |
0.597 |
|
| 2005 |
Charette AB, Boezio AA, Côté A, Moreau E, Pytkowicz J, Desrosiers JN, Legault C. Asymmetric catalytic addition of diorganozinc reagents to imines: Scope and application Pure and Applied Chemistry. 77: 1259-1267. DOI: 10.1351/Pac200577071259 |
0.717 |
|
| 2004 |
Charette AB, Legault C, Bélanger-Gariépy F. 3,3-Pentamethylenediaziridine Acta Crystallographica Section E: Structure Reports Online. 60: o1921-o1922. DOI: 10.1107/S1600536804023888 |
0.514 |
|
| 2003 |
Legault C, Charette AB. Highly efficient synthesis of O-(2,4-dinitrophenyl)hydroxylamine. Application to the synthesis of substituted N-benzoyliminopyridinium ylides. The Journal of Organic Chemistry. 68: 7119-22. PMID 12946163 DOI: 10.1021/Jo034456L |
0.553 |
|
| 2003 |
Legault C, Charette AB. Complexation promoted additions to N-benzoyliminopyridinium ylides. A novel and highly regioselective approach to polysubstituted piperidines. Journal of the American Chemical Society. 125: 6360-1. PMID 12785763 DOI: 10.1021/Ja0348647 |
0.584 |
|
| Show low-probability matches. |