cached image

Michael D. Hopkins - Publications

Affiliations: 
Chemistry University of Chicago, Chicago, IL 
Area:
Materials - Nanoscale - Organometallic - Supramolecular
Website:
http://chemistry.uchicago.edu/faculty/faculty/person/member/michael-d-hopkins.html

64 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Vibbert HB, Filatov AS, Hopkins MD. Synthesis, Structure, and Bonding of d3 Molybdenum-Oxo Complexes. Angewandte Chemie (International Ed. in English). PMID 32171049 DOI: 10.1002/Anie.202001379  0.341
2019 La Porte NT, Moravec DB, Schaller RD, Hopkins MD. Light-Driven Redox Activation of CO- and H-Activating Complexes in a Self-Assembled Triad. The Journal of Physical Chemistry. B. PMID 31729229 DOI: 10.1021/Acs.Jpcb.9B07830  0.766
2017 Rudshteyn B, Vibbert HB, May R, Wasserman E, Warnke I, Hopkins MD, Batista VS. Thermodynamic and Structural Factors That Influence the Redox Potentials of Tungsten–Alkylidyne Complexes Acs Catalysis. 7: 6134-6143. DOI: 10.1021/Acscatal.7B01636  0.704
2015 Kamm J, Iverson C, Lau WY, Hopkins MD. Axial Ligand Effects on the Structures of Self-Assembled Gallium-Porphyrin Monolayers on HOPG. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 26703936 DOI: 10.1021/Acs.Langmuir.5B03696  0.731
2014 La Porte NT, Moravec DB, Hopkins MD. Electron-transfer sensitization of H2 oxidation and CO2 reduction catalysts using a single chromophore. Proceedings of the National Academy of Sciences of the United States of America. 111: 9745-50. PMID 24961370 DOI: 10.1073/Pnas.1321375111  0.756
2014 O'Hanlon DC, Cohen BW, Moravec DB, Dallinger RF, Hopkins MD. Electronic, redox, and photophysical consequences of metal-for-carbon substitution in oligo-phenylene-ethynylenes. Journal of the American Chemical Society. 136: 3127-36. PMID 24479436 DOI: 10.1021/Ja411354D  0.798
2014 Sun J, Simpson CK, Hopkins MD, Hock AS, Schrock RR. Tungsten Benzylidyne Complexes Inorganic Syntheses. 36: 137-141. DOI: 10.1002/9781118744994.ch25  0.753
2013 Moravec DB, Hopkins MD. Photoinduced charge separation in zinc-porphyrin/tungsten-alkylidyne dyads: generation of reactive porphyrin and metallo radical states. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 17082-91. PMID 24307366 DOI: 10.1002/Chem.201303118  0.81
2013 Morales-Verdejo CA, Newsom MI, Cohen BW, Vibbert HB, Hopkins MD. Dihydrogen activation by a tungsten-alkylidyne complex: toward photoredox chromophores that deliver renewable reducing equivalents. Chemical Communications (Cambridge, England). 49: 10566-8. PMID 24013856 DOI: 10.1039/c3cc45606d  0.731
2013 Haines DE, O'Hanlon DC, Manna J, Jones MK, Shaner SE, Sun J, Hopkins MD. Oxidation-potential tuning of tungsten-alkylidyne complexes over a 2 V range. Inorganic Chemistry. 52: 9650-8. PMID 23905602 DOI: 10.1021/Ic401450U  0.768
2013 Moravec DB, Hopkins MD. FRET sensitization of tungsten-alkylidyne complexes by zinc porphyrins in self-assembled dyads. The Journal of Physical Chemistry. A. 117: 1744-55. PMID 23374026 DOI: 10.1021/Jp312421D  0.818
2013 Moravec DB, Lovaasen BM, Hopkins MD. Near-infrared transient-absorption spectroscopy of zinc tetraphenylporphyrin and related compounds. Observation of bands that selectively probe the S1 excited state Journal of Photochemistry and Photobiology a: Chemistry. 254: 20-24. DOI: 10.1016/J.Jphotochem.2012.12.025  0.76
2012 Lovaasen BM, Lockard JV, Cohen BW, Yang S, Zhang X, Simpson CK, Chen LX, Hopkins MD. Ground-state and excited-state structures of tungsten-benzylidyne complexes. Inorganic Chemistry. 51: 5660-70. PMID 22372556 DOI: 10.1021/Ic202622S  0.793
2011 Sun J, Shaner SE, Jones MK, O’Hanlon DC, Mugridge JS, Hopkins MD. Correction to Synthesis, Structures, Bonding, and Redox Chemistry of Ditungsten Butadiyne Complexes with W≡C–C≡W Backbones Inorganic Chemistry. 50: 10516-10516. DOI: 10.1021/Ic201710S  0.79
2010 Cohen BW, Lovaasen BM, Simpson CK, Cummings SD, Dallinger RF, Hopkins MD. 1000-fold enhancement of luminescence lifetimes via energy-transfer equilibration with the T1 state of Zn(TPP). Inorganic Chemistry. 49: 5777-9. PMID 20521796 DOI: 10.1021/Ic100316S  0.789
2010 Sun J, Shaner SE, Jones MK, O'Hanlon DC, Mugridge JS, Hopkins MD. Synthesis, structures, bonding, and redox chemistry of ditungsten butadiyne complexes with W[triple bond]C-C[triple bond]W backbones. Inorganic Chemistry. 49: 1687-98. PMID 20095626 DOI: 10.1021/Ic902088X  0.804
2006 Hu J, Sun J, Hopkins MD, Rosenbaum TF. Molecular building blocks for magnetic spin chains Journal of Physics Condensed Matter. 18: 10837-10841. DOI: 10.1088/0953-8984/18/48/010  0.418
2005 Da Re RE, Hopkins MD. Electronic spectroscopy and photophysics of metal-alkylidyne complexes Coordination Chemistry Reviews. 249: 1396-1409. DOI: 10.1016/j.ccr.2005.03.011  0.771
2004 Haines DE, Miskowski VM, Hopkins MD. Theoretical and empirical relationships between the redox potentials and 1(δ → δ*) transition energies of quadruply bonded complexes Journal of Cluster Science. 15: 489-502. DOI: 10.1007/S10876-004-5771-7  0.558
2003 Simpson CK, Da Re RE, Pollagi TP, Steele IM, Dallinger RF, Hopkins MD. Effects of cation-anion interactions on the structures and photophysical properties of anionic d0 tungsten-benzylidyne complexes Inorganica Chimica Acta. 345: 309-319. DOI: 10.1016/S0020-1693(02)01292-6  0.786
2002 Da Re RE, Hopkins MD. Electronic spectra and structures of d2 molybdenum-oxo complexes. Effects of structural distortions on orbital energies, two-electron terms, and the mixing of singlet and triplet states. Inorganic Chemistry. 41: 6973-85. PMID 12495335 DOI: 10.1021/Ic020565R  0.817
2000 Manna J, Dallinger RF, Miskowski VM, Hopkins MD. Vibrational spectroscopy and normal-mode analysis of tungsten-methylidyne complexes. Insight into the nature of the M≡C-H bonds Journal of Physical Chemistry B. 104: 10928-10939. DOI: 10.1021/Jp001680V  0.763
1999 John KD, Hopkins MD. Synthesis and reactions of metallo-diethynylbenzenes: Building blocks for redox-active poly(phenyleneethynylene)s Chemical Communications. 589-590. DOI: 10.1039/A809231A  0.628
1999 Beers WW, McCarley RE, Martin DS, Miskowski VM, Gray HB, Hopkins MD. Electronic spectra of cyclotetramolybdenum(II) diynes Coordination Chemistry Reviews. 187: 103-120. DOI: 10.1016/S0010-8545(99)00008-9  0.55
1998 John KD, Miskowski VM, Vance MA, Dallinger RF, Wang LC, Geib SJ, Hopkins MD. Molecular Structures, Vibrational Spectroscopy, and Normal-Mode Analysis of M(2)(C&tbd1;CR)(4)(PMe(3))(4) Dimetallatetraynes. Observation of Strongly Mixed Metal-Metal and Metal-Ligand Vibrational Modes. Inorganic Chemistry. 37: 6858-6873. PMID 11670823 DOI: 10.1021/Ic980866U  0.658
1997 Brison HA, Pollagi TP, Stoner TC, Geib SJ, Hopkins MD. One-dimensional alignment of organometallic donor-acceptor compounds via coordination polymerization. Synthesis and structures of [W(≡CC6H4X-4)(OBut)3]∞ (X = NMe2, SMe) Chemical Communications. 1263-1264. DOI: 10.1039/A701046J  0.402
1997 Stevenson MA, Hopkins MD. Convenient synthesis of W(≡CR)X3(dme) compounds from W(≡CR)(OBut)3 triple-bond metathesis products Organometallics. 16: 3572-3573. DOI: 10.1021/Om970394B  0.346
1997 John KD, Stoner TC, Hopkins MD. Ground-state and excited-state C≡C stretching frequencies of dimetallapolyyne redox congeners. Direct evidence for metal→alkynyl π-back-bonding Organometallics. 16: 4948-4950. DOI: 10.1021/Om970325X  0.625
1997 Heinselman KS, Miskowski VM, Geib SJ, Wang LC, Hopkins MD. Molecular Structures and FT-Raman Spectroscopy of Luminescent Niobium and Tantalum Arylimido Compounds Inorganic Chemistry. 36: 5530-5538. DOI: 10.1021/Ic970494+  0.388
1996 John KD, Geib SJ, Hopkins MD. Coupling of alkynyl ligands at a quadruply bonded molybdenum dimer Organometallics. 15: 4357-4361. DOI: 10.1021/Om960351F  0.648
1996 Pollagi TP, Manna J, Geib SJ, Hopkins MD. Molecular structure of [W(N)(O-2,6-C6H3 iPr2) 3]2: A metal-nitrido compound with a cyclic diyne structure Inorganica Chimica Acta. 243: 177-183. DOI: 10.1016/0020-1693(96)04905-5  0.758
1995 Fan E, Yang J, Geib SJ, Stoner TC, Hopkins MD, Hamilton AD. Hydrogen-bonding control of molecular aggregation: Self-complementary subunits lead to rod-shaped structures in the solid state Journal of the Chemical Society, Chemical Communications. 1251-1252. DOI: 10.1039/C39950001251  0.34
1995 Heinselman KS, Hopkins MD. Luminescence properties of d0 metal-imido compounds Journal of the American Chemical Society. 117: 12340-12341. DOI: 10.1021/Ja00154A039  0.322
1995 Manna J, John KD, Hopkins MD. The Bonding of Metal-Alkynyl Complexes Advances in Organometallic Chemistry. 38: 79-154. DOI: 10.1016/S0065-3055(08)60427-X  0.814
1994 Manna J, Kuk RJ, Dallinger RF, Hopkins MD. Nature of the Metal-Carbon Triple Bond. A Reevaluation of the M.tplbond.C Stretching Frequency and Force Constant Journal of the American Chemical Society. 116: 9793-9794. DOI: 10.1021/Ja00100A072  0.736
1994 Stoner TC, Schaefer WP, Marsh RE, Hopkins MD. Synthesis and characterization of M2(CCR)4(PMe3)4 dimetallapolyynes Journal of Cluster Science. 5: 107-124. DOI: 10.1007/Bf01165494  0.412
1993 Manna J, Geib SJ, Hopkins MD. [W(CH)(dmpe)2(nBu)], a complex with a bent methylidyne ligand Angewandte Chemie (International Edition in English). 32: 858-861. DOI: 10.1002/Anie.199308581  0.752
1993 Manna J, Geib SJ, Hopkins MD. [W(CH)(dmpe)2(nBu)], ein Komplex mit einem gewinkelten Methylidin-Liganden Angewandte Chemie. 105: 897-899. DOI: 10.1002/Ange.19931050613  0.717
1992 Manna J, Geib SJ, Hopkins MD. .pi.-Conjugated metallabutadiyne complexes: synthesis, structure, and bonding Journal of the American Chemical Society. 114: 9199-9200. DOI: 10.1021/Ja00049A068  0.764
1992 Manna J, Gilbert TM, Dallinger RF, Geib SJ, Hopkins MD. Nature of the frontier orbitals of tungsten benzylidyne complexes Journal of the American Chemical Society. 114: 5870-5872. DOI: 10.1021/Ja00040A065  0.756
1992 Stoner TC, Geib SJ, Hopkins MD. Preparation and characterization of 1,1-W2(CCMe)2Cl2(PMe3)4. Structural and spectroscopic manifestations of .delta.(MM)-.pi.(CC) conjugation Journal of the American Chemical Society. 114: 4201-4204. DOI: 10.1021/Ja00037A024  0.35
1992 Hopkins MD, Miskowski VM, Killough PM, Sattelberger AP, Woodruff WH, Gray HB. Far-infrared spectroscopy of quadruply bonded M2X4L4 complexes Inorganic Chemistry. 31: 5368-5374. DOI: 10.1021/Ic00052A010  0.407
1992 Marshall JL, Hopkins MD, Miskowski VM, Gray HB. Electronic spectra of pyrazolyl-bridged binuclear iridium(I) complexes Inorganic Chemistry. 31: 5034-5040. DOI: 10.1021/Ic00050A022  0.555
1992 Miskowski VM, Gray HB, Hopkins MD. Fluorescence excitation spectra of quadruply bonded M2X4L4 complexes Inorganic Chemistry. 31: 2085-2091. DOI: 10.1021/Ic00037A020  0.556
1990 Stoner TC, Dallinger RF, Hopkins MD. Preparation and electronic characterization of M2(CCR)4(PMe3)4: A class of conjugated transition-metal complexes Journal of the American Chemical Society. 112: 5651-5653. DOI: 10.1021/Ja00170A046  0.366
1988 Hopkins MD, Miskowski VM, Gray HB. Upper electronic excited states of quadruply bonded M2X4(PMe3)4 complexes Journal of the American Chemical Society. 110: 1787-1793. DOI: 10.1021/Ja00214A021  0.551
1988 Lichtenberger DL, Copenhaver AS, Gray HB, Marshall JL, Hopkins MD. Valence electronic structure of bis(pyrazolyl)-bridged iridium dicarbonyl dimers. Electronic effects of 3,5-dimethylpyrazolyl substitution on metal-metal interactions Inorganic Chemistry. 27: 4488-4493. DOI: 10.1021/Ic00297A030  0.486
1988 Miskowski VM, Albin M, Hopkins MD, Brinza DE, Gray HB. Franck-Condon analyses on the IBM PC/AT Computers and Chemistry. 12: 171-174. DOI: 10.1016/0097-8485(88)85014-9  0.343
1988 HOPKINS MD, MISKOWSKI VM, GRAY HB. ChemInform Abstract: Upper Electronic Excited States of Quadruply Bonded M2X4(PMe3)4 Complexes Cheminform. 19. DOI: 10.1002/chin.198828028  0.486
1988 Hopkins MD, Miskowski VM, Gray HB. Upper electronic excited states of quadruply bonded M2X4(PMe3)4 complexes Journal of the American Chemical Society. 110: 1787-1793.  0.333
1987 Bray RG, Bercaw JE, Gray HB, Hopkins MD, Paciello RA. Electronic spectroscopy of iron and ruthenium pentamethylcyclopentadienyl-trimethylphosphine complexes Organometallics. 6: 922-925. DOI: 10.1021/Om00148A004  0.449
1987 Hopkins MD, Schaefer WP, Bronikowski MJ, Woodruff WH, Miskowski VM, Dallinger RF, Gray HB. Ligand perturbation of the molecular and electronic structures of quadruply bonded dimers. The crystal structures of Mo2Br4(PMe3)4 and Mo2I4(PMe3)4, and the vibrational and electronic spectra of a series of M2X4L4 complexes Journal of the American Chemical Society. 109: 408-416. DOI: 10.1021/Ja00236A019  0.564
1987 Hopkins MD, Gray HB, Miskowski VM. δ→δ* Revisited: What the energies and intensities mean Polyhedron. 6: 705-714. DOI: 10.1016/S0277-5387(00)86878-3  0.461
1987 HOPKINS MD, SCHAEFER WP, BRONIKOWSKI MJ, WOODRUFF WH, MISKOWSKI VM, DALLINGER RF, GRAY HB. ChemInform Abstract: Ligand Perturbation of the Molecular and Electronic Structures of Quadruply Bonded Dimers. The Crystal Structures of Mo2Br4(PMe3)4 and Mo2I4(PMe3)4, and the Vibrational and Electronic Spectra of a Series of M2X4L4 Complexes. Cheminform. 18. DOI: 10.1002/chin.198722055  0.459
1987 HOPKINS MD, MISKOWSKI VM, GRAY HB. ChemInform Abstract: Luminescence from Nitrido Complexes of Osmium(VI). Evidence for a Nontotally Symmetric Excited-State Distortion Cheminform. 18. DOI: 10.1002/chin.198712048  0.456
1986 Zietlow TC, Hopkins MD, Gray HB. Electrochemistry of quadruply bonded molybdenum dimers. Evidence for metal-to-halide back-bonding Journal of the American Chemical Society. 108: 8266-8267. DOI: 10.1021/Ja00286A028  0.485
1986 Hopkins MD, Miskowski VM, Gray HB. Luminescence from nitrido complexes of osmium(VI). Evidence for a nontotally symmetric excited-state distortion Journal of the American Chemical Society. 108: 6908-6911. DOI: 10.1021/Ja00282A012  0.524
1986 Hopkins MD, Miskowski VM, Gray HB. Electronic and vibrational spectroscopy of the triply metal-metal bonded dimolybdenum tetrakis(hydrogen phosphate) [Mo2(HPO4)42- ion. Inferences as to the energetics of .delta.-bonding from spectroscopic correlations to dimolybdenum tetrasulfate [Mo2(SO4)44-/3-] ion Journal of the American Chemical Society. 108: 959-963. DOI: 10.1021/Ja00265A020  0.469
1986 HOPKINS MD, MISKOWSKI VM, GRAY HB. ChemInform Abstract: Electronic and Vibrational Spectroscopy of the Triply Metal - Metal Bonded Mo2(HPO4)42-Ion. Inferences as to the Energetics of δ-Bonding from Spectroscopic Correlations to Mo2(SO4)44-/3-. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198626009  0.487
1985 Hopkins MD, Zietlow TC, Miskowski VM, Gray HB. Magnetic and spectroscopic properties of the .delta..delta.* states of tetrachlorotetrakis(trimethylphosphine)dimolybdenum and .beta.-[tetrachlorobis[1,2-bis(dimethylphosphino)ethane]dimolybdenum]: experimental determination of the energy of a triplet .delta..delta.* state Journal of the American Chemical Society. 107: 510-512. DOI: 10.1021/Ja00288A044  0.447
1985 Zietlow TC, Hopkins MD, Gray HB. Electronic spectroscopy and photophysics of d4 clusters Journal of Solid State Chemistry. 57: 112-119. DOI: 10.1016/S0022-4596(85)80064-5  0.439
1985 HOPKINS MD, ZIETLOW TC, MISKOWSKI VM, GRAY HB. ChemInform Abstract: MAGNETIC AND SPECTROSCOPIC PROPERTIES OF THE ΔΔ* STATES OF TETRACHLOROTETRAKIS(TRIMETHYLPHOSPHINE)DIMOLYBDENUM AND β-(TETRACHLOROBIS(1,2-BIS(DIMETHYLPHOSPHINO)ETHANE)DIMOLYBDENUM): EXPERIMENTAL DETERMINATION OF THE ENERGY OF A TRIPLET Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198521068  0.444
1984 Hopkins MD, Gray HB. Nature of the emissive excited state of quadruply bonded tetrakis(trimethylphosphine)tetrahalodimolybdenum (Mo2X4(PMe3)4) complexes Journal of the American Chemical Society. 106: 2468-2469. DOI: 10.1021/Ja00320A059  0.529
1984 HOPKINS MD, GRAY HB. ChemInform Abstract: NATURE OF THE EMISSIVE EXCITED STATE OF QUADRUPLY BONDED TETRAKIS(TRIMETHYLPHOSPHINE)TETRAHALODIMOLYBDENUM (MO2X4(PME3)4) COMPLEXES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198430042  0.461
Show low-probability matches.