Thomas B. Rauchfuss - Publications

Affiliations: 
Chemistry University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
synthetic inorganic, bioinorganic, and organometallic chemistry
Website:
http://www.chemistry.illinois.edu/faculty/Thomas_Rauchfuss.html

285 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Yu X, Rao G, Britt RD, Rauchfuss TB. Final Stages in the Biosynthesis of the [FeFe]-Hydrogenase Active Site. Angewandte Chemie (International Ed. in English). e202404044. PMID 38551577 DOI: 10.1002/anie.202404044  0.35
2023 Zhang F, Woods TJ, Rauchfuss TB. Hybrids of [FeFe]- and [NiFe]-Hase Active Site Models. Organometallics. 42: 1607-1614. PMID 37928214 DOI: 10.1021/acs.organomet.3c00173  0.422
2023 Villarreal DG, Rao G, Tao L, Liu L, Rauchfuss TB, Britt RD. Characterizing the Biosynthesis of the [Fe(II)(CN)(CO)(cysteinate)] Organometallic Product of the Radical-SAM Enzyme HydG by EPR and Mössbauer Spectroscopy. The Journal of Physical Chemistry. B. PMID 37861415 DOI: 10.1021/acs.jpcb.3c05495  0.366
2022 Zhang Y, Woods T, Rauchfuss TB. Synthesis and Dynamics of Ferrous Polychalcogenides [Fe(E)(CN)(CO)] (E = S, Se, or Te). Inorganic Chemistry. PMID 35561009 DOI: 10.1021/acs.inorgchem.2c00684  0.31
2022 Zhang Y, Tao L, Woods TJ, Britt RD, Rauchfuss TB. Organometallic Fe(μ-SH)(CO)(CN) Cluster Allows the Biosynthesis of the [FeFe]-Hydrogenase with Only the HydF Maturase. Journal of the American Chemical Society. PMID 35041427 DOI: 10.1021/jacs.1c12506  0.315
2021 Basu D, Gray DL, Woods TJ, Rauchfuss TB, Arrigoni F, Zampella G. Challenges in the Synthesis of Active Site Mimics for [NiFe]-Hydrogenases. Organometallics. 40: 3306-3312. PMID 37933322 DOI: 10.1021/acs.organomet.1c00412  0.351
2021 Zhang F, Woods TJ, Zhu L, Rauchfuss TB. Inhibition of [FeFe]-hydrogenase by formaldehyde: proposed mechanism and reactivity of FeFe alkyl complexes. Chemical Science. 12: 15673-15681. PMID 35003598 DOI: 10.1039/d1sc05803g  0.387
2021 Britt RD, Rauchfuss TB. Biosynthesis of the [FeFe] hydrogenase H-cluster a synthetic [Fe(II)(CN)(CO)(cysteinate)] complex. Dalton Transactions (Cambridge, England : 2003). 50: 12386-12391. PMID 34545884 DOI: 10.1039/d1dt02258j  0.37
2021 Rauchfuss TB, Woods T, Zhang F, Richers CP. Surprising Condensation Reactions of the Azadithiolate Cofactor. Angewandte Chemie (International Ed. in English). PMID 34324230 DOI: 10.1002/anie.202108135  0.363
2021 Rohac R, Martin L, Liu L, Basu D, Tao L, Britt RD, Rauchfuss TB, Nicolet Y. Crystal Structure of the [FeFe]-Hydrogenase Maturase HydE Bound to Complex-B. Journal of the American Chemical Society. PMID 34048236 DOI: 10.1021/jacs.1c03367  0.395
2021 Pelmenschikov V, Birrell JA, Gee LB, Richers CP, Reijerse EJ, Wang H, Arragain S, Mishra N, Yoda Y, Matsuura H, Li L, Tamasaku K, Rauchfuss TB, Lubitz W, Cramer SP. Vibrational Perturbation of the [FeFe] Hydrogenase H-Cluster Revealed by CH-ADT Labeling. Journal of the American Chemical Society. PMID 34043346 DOI: 10.1021/jacs.1c02323  0.354
2021 Zhang F, Woods TJ, Rauchfuss TB, Arrigoni F, Zampella G. CO substitution by PPh in FeS(CO) proceeds a novel FeS intermediate. Chemical Communications (Cambridge, England). PMID 33890601 DOI: 10.1039/d1cc00956g  0.342
2021 Arrigoni F, Zampella G, Zhang F, Kagalwala HN, Li QL, Woods TJ, Rauchfuss TB. Computational and Experimental Investigations of the Fe(μ-S)/Fe(μ-S) Equilibrium. Inorganic Chemistry. PMID 33650855 DOI: 10.1021/acs.inorgchem.0c03709  0.36
2020 Liu L, Woods TJ, Rauchfuss TB. Reactions of [FeC(CO)(S)]: Cluster Growth, Redox, Sulfiding. European Journal of Inorganic Chemistry. 2020: 3460-3465. PMID 33883972 DOI: 10.1002/Ejic.202000736  0.44
2020 Tao L, Pattenaude SA, Joshi S, Begley TP, Rauchfuss TB, Britt RD. The radical SAM enzyme HydE generates adenosylated Fe(I) intermediates en route to the [FeFe]-hydrogenase catalytic H-cluster. Journal of the American Chemical Society. PMID 32434327 DOI: 10.1021/Jacs.0C03802  0.835
2019 Birrell JA, Pelmenschikov V, Mishra N, Wang H, Yoda Y, Tamasaku K, Rauchfuss TB, Cramer SP, Lubitz W, DeBeer S. Spectroscopic and Computational Evidence that [FeFe] Hydrogenases Operate Exclusively with CO-bridged Intermediates. Journal of the American Chemical Society. PMID 31820961 DOI: 10.1021/Jacs.9B09745  0.315
2019 Reijerse E, Pelmenschikov V, Birrell JA, Richers CP, Kaupp M, Rauchfuss TB, Cramer SP, Lubitz W. Asymmetry in the Ligand Coordination Sphere of the [FeFe] Hydrogenase Active Site Is Reflected in the Magnetic Spin Interactions of the Aza-Propanedithiolate Ligand. The Journal of Physical Chemistry Letters. PMID 31580680 DOI: 10.1021/Acs.Jpclett.9B02354  0.452
2019 Rao G, Pattenaude SA, Alwan K, Blackburn NJ, Britt RD, Rauchfuss TB. The binuclear cluster of [FeFe] hydrogenase is formed with sulfur donated by cysteine of an [Fe(Cys)(CO)(CN)] organometallic precursor. Proceedings of the National Academy of Sciences of the United States of America. PMID 31570604 DOI: 10.1073/Pnas.1913324116  0.83
2019 Liu L, Rauchfuss TB, Woods TJ. Iron Carbide-Sulfide Carbonyl Clusters. Inorganic Chemistry. PMID 31184487 DOI: 10.1021/Acs.Inorgchem.9B01231  0.359
2019 Kagalwala HN, Lalaoui N, Li QL, Liu L, Woods T, Rauchfuss TB. Redox and "Antioxidant" Properties of Fe(μ-SH)(CO)(PPh). Inorganic Chemistry. PMID 30724559 DOI: 10.1021/Acs.Inorgchem.8B03344  0.52
2019 Basu D, Bailey TS, Lalaoui N, Richers CP, Woods TJ, Rauchfuss TB, Arrigoni F, Zampella G. Synthetic Designs and Structural Investigations of Biomimetic Ni-Fe Thiolates. Inorganic Chemistry. PMID 30707014 DOI: 10.1021/Acs.Inorgchem.8B02991  0.495
2018 Basu D, Woods TJ, Rauchfuss TB. Ni(ii) complexes of the phosphine-oxime PhPCH-2-CH[double bond, length as m-dash]NOH. Dalton Transactions (Cambridge, England : 2003). PMID 29762614 DOI: 10.1039/C8Dt01551A  0.334
2018 Li Q, Lalaoui N, Woods TJ, Rauchfuss TB, Arrigoni F, Zampella G. Electron-Rich, Diiron Bis(monothiolato) Carbonyls: C-S Bond Homolysis in a Mixed Valence Diiron Dithiolate. Inorganic Chemistry. PMID 29620876 DOI: 10.1021/Acs.Inorgchem.8B00094  0.483
2018 Sommer C, Richers CP, Lubitz W, Rauchfuss TB, Reijerse EJ. A [RuRu] Analogue of an [FeFe]-Hydrogenase Traps the Key Hydride Intermediate of the Catalytic Cycle. Angewandte Chemie (International Ed. in English). PMID 29577535 DOI: 10.1002/Anie.201801914  0.464
2018 Carlson MR, Gray DL, Richers CP, Wang W, Zhao PH, Rauchfuss TB, Pelmenschikov V, Pham CC, Gee LB, Wang H, Cramer SP. Sterically Stabilized Terminal Hydride of a Diiron Dithiolate. Inorganic Chemistry. PMID 29384371 DOI: 10.1021/Acs.Inorgchem.7B02903  0.438
2018 Basu D, Gilbert-Wilson R, Gray DL, Rauchfuss TB, Dash AK. Fe and Co Complexes of Rigidly Planar Phosphino-Quinoline-Pyridine Ligands for Catalytic Hydrosilylation and Dehydrogenative Silylation Organometallics. 37: 2760-2768. DOI: 10.1021/Acs.Organomet.8B00416  0.449
2017 Pelmenschikov V, Birrell JA, Pham CC, Mishra N, Wang H, Sommer C, Reijerse E, Richers CP, Tamasaku K, Yoda Y, Rauchfuss TB, Lubitz W, Cramer SP. Reaction Coordinate Leading to H2 Production in [FeFe]-Hydrogenase Identified by NRVS and DFT. Journal of the American Chemical Society. PMID 29054130 DOI: 10.1021/Jacs.7B09751  0.46
2017 Schilter D, Gray DL, Fuller AL, Rauchfuss TB. Synthetic Models for Nickel-Iron Hydrogenase Featuring Redox-Active Ligands. Australian Journal of Chemistry. 70: 505-515. PMID 28819328 DOI: 10.1071/Ch16614  0.782
2017 Carlson MR, Gilbert-Wilson R, Gray DR, Mitra J, Rauchfuss TB, Richers CP. Diiron Dithiolate Hydrides Complemented with Proton-Responsive Phosphine-Amine Ligands. European Journal of Inorganic Chemistry. 2017: 3169-3173. PMID 28808414 DOI: 10.1002/Ejic.201700474  0.505
2017 Yu X, Tung CH, Wang W, Huynh MT, Gray DL, Hammes-Schiffer S, Rauchfuss TB. Interplay between Terminal and Bridging Diiron Hydrides in Neutral and Oxidized States. Organometallics. 36: 2245-2253. PMID 28781408 DOI: 10.1021/Acs.Organomet.7B00297  0.412
2017 Lalaoui N, Woods T, Rauchfuss TB, Zampella G. Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct. Organometallics. 36: 2054-2057. PMID 28781407 DOI: 10.1021/Acs.Organomet.7B00236  0.51
2017 Reijerse EJ, Pham CC, Pelmenschikov V, Gilbert-Wilson R, Adamska-Venkatesh A, Siebel JF, Gee LB, Yoda Y, Tamasaku K, Lubitz W, Rauchfuss TB, Cramer SP. Direct Observation of an Iron-bound Terminal Hydride in [FeFe]-Hydrogenase by Nuclear Resonance Vibrational Spectroscopy. Journal of the American Chemical Society. PMID 28291336 DOI: 10.1021/Jacs.7B00686  0.455
2017 Richers CP, Bertke JA, Rauchfuss TB. Syntheses of transition metal methoxysiloxides. Dalton Transactions (Cambridge, England : 2003). PMID 28138664 DOI: 10.1039/C6Dt04205H  0.386
2016 Zhao P, Gray DL, Rauchfuss TB. Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe2(S3CPh2)(CO)6] and Related Complexes. European Journal of Inorganic Chemistry. 2016: 2681-2683. PMID 27818613 DOI: 10.1002/Ejic.201600366  0.476
2016 Schilter D, Camara JM, Huynh MT, Hammes-Schiffer S, Rauchfuss TB. Hydrogenase Enzymes and Their Synthetic Models: The Role of Metal Hydrides. Chemical Reviews. PMID 27353631 DOI: 10.1021/Acs.Chemrev.6B00180  0.802
2016 Ulloa OA, Huynh MT, Richers CP, Bertke JA, Nilges MJ, Hammes-Schiffer S, Rauchfuss TB. Mechanism of H2 Production by Models for the [NiFe]-Hydrogenases: Role of Reduced Hydrides. Journal of the American Chemical Society. PMID 27328053 DOI: 10.1021/Jacs.6B04579  0.471
2016 Li Y, Rauchfuss TB. Synthesis of Diiron(I) Dithiolato Carbonyl Complexes. Chemical Reviews. PMID 27258046 DOI: 10.1021/Acs.Chemrev.5B00669  0.501
2016 Zhou X, Barton BE, Chambers GM, Rauchfuss TB, Arrigoni F, Zampella G. Preparation and Protonation of Fe2(pdt)(CNR)6, Electron-Rich Analogues of Fe2(pdt)(CO)6. Inorganic Chemistry. PMID 26999632 DOI: 10.1021/Acs.Inorgchem.5B02789  0.759
2016 Chu WY, Gilbert-Wilson R, Rauchfuss TB, Van Gastel M, Neese F. Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis Organometallics. 35: 2900-2914. DOI: 10.1021/Acs.Organomet.6B00457  0.617
2016 Chu WY, Richers CP, Kahle ER, Rauchfuss TB, Arrigoni F, Zampella G. Imine-Centered Reactions in Imino-Phosphine Complexes of Iron Carbonyls Organometallics. 35: 2782-2792. DOI: 10.1021/Acs.Organomet.6B00318  0.686
2016 Chambers GM, Rauchfuss TB, Arrigoni F, Zampella G. Effect of Pyramidalization of the M2(SR)2 Center: The Case of (C5H5)2Ni2(SR)2 Organometallics. 35: 836-846. DOI: 10.1021/Acs.Organomet.6B00068  0.357
2015 Zhao P, Bertke JA, Rauchfuss TB. Crystal structure of [μ2-3,3-dimethyl-4-(propan-2-yl-idene)thietane-2,2-dithiol-ato-κ(4) S:S':S:S']bis[tricarbonyl-iron(I)](Fe-Fe). Acta Crystallographica. Section E, Crystallographic Communications. 71: 1296-1299. PMID 26594495 DOI: 10.1107/S2056989015018496  0.488
2015 Richers CP, Bertke JA, Rauchfuss TB. Crystal structure of bis-(acetyl-acetonato-κ(2) O,O')(tetra-hydro-furan-κO)(tri-fluoro-methane-sulfonato-κO)iron(III). Acta Crystallographica. Section E, Crystallographic Communications. 71: 1165-1168. PMID 26594397 DOI: 10.1107/S2056989015016849  0.471
2015 Chambers GM, Huynh MT, Li Y, Hammes-Schiffer S, Rauchfuss TB, Reijerse E, Lubitz W. Models of the Ni-L and Ni-SIa States of the [NiFe]-Hydrogenase Active Site. Inorganic Chemistry. PMID 26421729 DOI: 10.1021/Acs.Inorgchem.5B01662  0.438
2015 Richers CP, Bertke JA, Rauchfuss TB. Crystal structure of di-μ-hydroxido-κ(4) O:O-bis[bis(acetyl-acetonato-κ(2) O,O')cobalt(III)]. Acta Crystallographica. Section E, Crystallographic Communications. 71: 983-5. PMID 26396771 DOI: 10.1107/S2056989015013663  0.345
2015 Richers CP, Bertke JA, Gray DL, Rauchfuss TB. Crystal structure of tetrakis-(acetyl-acetonato)di-chloridodi-μ3-methano-lato-tetra-μ2-methano-lato-tetra-iron(III). Acta Crystallographica. Section E, Crystallographic Communications. 71: 976-9. PMID 26396769 DOI: 10.1107/S2056989015013535  0.444
2015 Ogata H, Krämer T, Wang H, Schilter D, Pelmenschikov V, van Gastel M, Neese F, Rauchfuss TB, Gee LB, Scott AD, Yoda Y, Tanaka Y, Lubitz W, Cramer SP. Hydride bridge in [NiFe]-hydrogenase observed by nuclear resonance vibrational spectroscopy. Nature Communications. 6: 7890. PMID 26259066 DOI: 10.1038/Ncomms8890  0.768
2015 Gilbert-Wilson R, Siebel JF, Adamska-Venkatesh A, Pham CC, Reijerse E, Wang H, Cramer SP, Lubitz W, Rauchfuss TB. Spectroscopic Investigations of [FeFe] Hydrogenase Maturated with [(57)Fe2(adt)(CN)2(CO)4](2.). Journal of the American Chemical Society. 137: 8998-9005. PMID 26091969 DOI: 10.1021/Jacs.5B03270  0.469
2015 Rauchfuss TB. Diiron Azadithiolates as Models for the [FeFe]-Hydrogenase Active Site and Paradigm for the Role of the Second Coordination Sphere. Accounts of Chemical Research. PMID 26079848 DOI: 10.1021/Acs.Accounts.5B00177  0.509
2015 Angamuthu R, Chen CS, Cochrane TR, Gray DL, Schilter D, Ulloa OA, Rauchfuss TB. N-Substituted Derivatives of the Azadithiolate Cofactor from the [FeFe] Hydrogenases: Stability and Complexation. Inorganic Chemistry. 54: 5717-24. PMID 26000618 DOI: 10.1021/Acs.Inorgchem.5B00290  0.823
2015 Gilbert-Wilson R, Chu WY, Rauchfuss TB. Phosphine-iminopyridines as platforms for catalytic hydrofunctionalization of alkenes. Inorganic Chemistry. 54: 5596-603. PMID 25978588 DOI: 10.1021/Acs.Inorgchem.5B00692  0.643
2015 Chu WY, Zhou X, Rauchfuss TB. Cooperative metal-ligand reactivity and catalysis in low-spin ferrous alkoxides Organometallics. 34: 1619-1625. DOI: 10.1021/Om501152H  0.658
2014 Lin T, Ulloa OA, Rauchfuss TB, Gray DL. Diiron Azamonothiolates via Scission of Dithiadiazacyclooctanes by Iron Carbonyls. European Journal of Inorganic Chemistry. 2015: 4109-4114. PMID 26167130 DOI: 10.1002/Ejic.201402413  0.443
2014 Lansing JC, Camara JM, Gray DE, Rauchfuss TB. Hydrogen Production Catalyzed by Bidirectional, Biomimetic Models of the [FeFe]-Hydrogenase Active Site. Organometallics. 33: 5897-5906. PMID 25364093 DOI: 10.1021/Om5004013  0.791
2014 Schilter D, Pelmenschikov V, Wang H, Meier F, Gee LB, Yoda Y, Kaupp M, Rauchfuss TB, Cramer SP. Synthesis and vibrational spectroscopy of (57)Fe-labeled models of [NiFe] hydrogenase: first direct observation of a nickel-iron interaction. Chemical Communications (Cambridge, England). 50: 13469-72. PMID 25237680 DOI: 10.1039/C4Cc04572F  0.755
2014 Huynh MT, Wang W, Rauchfuss TB, Hammes-Schiffer S. Computational investigation of [FeFe]-hydrogenase models: characterization of singly and doubly protonated intermediates and mechanistic insights. Inorganic Chemistry. 53: 10301-11. PMID 25207842 DOI: 10.1021/Ic5013523  0.423
2014 Huynh MT, Schilter D, Hammes-Schiffer S, Rauchfuss TB. Protonation of nickel-iron hydrogenase models proceeds after isomerization at nickel. Journal of the American Chemical Society. 136: 12385-95. PMID 25094041 DOI: 10.1021/Ja505783Z  0.756
2014 Tse EC, Schilter D, Gray DL, Rauchfuss TB, Gewirth AA. Multicopper models for the laccase active site: effect of nuclearity on electrocatalytic oxygen reduction. Inorganic Chemistry. 53: 8505-16. PMID 25072935 DOI: 10.1021/Ic501080C  0.783
2014 Manor BC, Ringenberg MR, Rauchfuss TB. Borane-protected cyanides as surrogates of H-bonded cyanides in [FeFe]-hydrogenase active site models. Inorganic Chemistry. 53: 7241-7. PMID 24992155 DOI: 10.1021/Ic500470Z  0.755
2014 Carroll ME, Chen J, Gray DE, Lansing JC, Rauchfuss TB, Schilter D, Volkers PI, Wilson SR. Ferrous Carbonyl Dithiolates as Precursors to FeFe, FeCo, and FeMn Carbonyl Dithiolates. Organometallics. 33: 858-867. PMID 24803716 DOI: 10.1021/Om400752A  0.831
2014 Chambers GM, Mitra J, Rauchfuss TB, Stein M. Ni(I)/Ru(II) model for the Ni-L state of the [NiFe]hydrogenases: synthesis, spectroscopy, and reactivity. Inorganic Chemistry. 53: 4243-9. PMID 24684697 DOI: 10.1021/Ic500389P  0.414
2014 Wang W, Rauchfuss TB, Zhu L, Zampella G. New reactions of terminal hydrides on a diiron dithiolate. Journal of the American Chemical Society. 136: 5773-82. PMID 24661238 DOI: 10.1021/Ja501366J  0.469
2014 Breitzer JG, Holloway GA, Rauchfuss TB, Salata MR, Kee CL, Yan YK. Electrochemical Synthesis of Tetraethylammonium Tetrathiooxalate Inorganic Syntheses. 36: 201-203. DOI: 10.1002/9781118744994.ch36  0.761
2013 Schilter D, Rauchfuss TB. And the winner is...azadithiolate: an amine proton relay in the [FeFe] hydrogenases. Angewandte Chemie (International Ed. in English). 52: 13518-20. PMID 24307392 DOI: 10.1002/Anie.201307132  0.689
2013 Manor BC, Rauchfuss TB. Hydrogen activation by biomimetic [NiFe]-hydrogenase model containing protected cyanide cofactors. Journal of the American Chemical Society. 135: 11895-900. PMID 23899049 DOI: 10.1021/Ja404580R  0.399
2013 Wang W, Nilges MJ, Rauchfuss TB, Stein M. Isolation of a mixed valence diiron hydride: evidence for a spectator hydride in hydrogen evolution catalysis. Journal of the American Chemical Society. 135: 3633-9. PMID 23383865 DOI: 10.1021/Ja312458F  0.477
2013 Thorseth MA, Letko CS, Tse EC, Rauchfuss TB, Gewirth AA. Ligand effects on the overpotential for dioxygen reduction by tris(2-pyridylmethyl)amine derivatives. Inorganic Chemistry. 52: 628-34. PMID 23244437 DOI: 10.1021/Ic301656X  0.781
2013 Kamali S, Wang H, Mitra D, Ogata H, Lubitz W, Manor BC, Rauchfuss TB, Byrne D, Bonnefoy V, Jenney FE, Adams MW, Yoda Y, Alp E, Zhao J, Cramer SP. Observation of the Fe-CN and Fe-CO vibrations in the active site of [NiFe] hydrogenase by nuclear resonance vibrational spectroscopy. Angewandte Chemie (International Ed. in English). 52: 724-8. PMID 23136119 DOI: 10.1002/Anie.201204616  0.412
2013 Chambers GM, Angamuthu R, Gray DL, Rauchfuss TB. Organo ruthenium-nickel dithiolates with redox-responsive nickel sites Organometallics. 32: 6324-6329. DOI: 10.1021/Om4006824  0.769
2013 Zaffaroni R, Rauchfuss TB, Fuller A, De Gioia L, Zampella G. Contrasting protonation behavior of diphosphido vs dithiolato diiron(I) carbonyl complexes Organometallics. 32: 232-238. DOI: 10.1021/Om300997S  0.512
2012 Carroll ME, Barton BE, Rauchfuss TB, Carroll PJ. Synthetic models for the active site of the [FeFe]-hydrogenase: catalytic proton reduction and the structure of the doubly protonated intermediate. Journal of the American Chemical Society. 134: 18843-52. PMID 23126330 DOI: 10.1021/Ja309216V  0.778
2012 Zaffaroni R, Rauchfuss TB, Gray DL, De Gioia L, Zampella G. Terminal vs bridging hydrides of diiron dithiolates: protonation of Fe2(dithiolate)(CO)2(PMe3)4. Journal of the American Chemical Society. 134: 19260-9. PMID 23095145 DOI: 10.1021/Ja3094394  0.432
2012 Schilter D, Rauchfuss TB. Nickel-iron dithiolates related to the deactivated [NiFe]-hydrogenases. Dalton Transactions (Cambridge, England : 2003). 41: 13324-9. PMID 22992700 DOI: 10.1039/C2Dt31895D  0.763
2012 Olsen MT, Rauchfuss TB, Zaffaroni R. Reaction of Aryl Diazonium Salts and Diiron(I) Dithiolato Carbonyls: Evidence for Radical Intermediates. Organometallics. 31: 3447-3450. PMID 22962513 DOI: 10.1021/Om300107S  0.741
2012 Schilter D, Rauchfuss TB, Stein M. Connecting [NiFe]- and [FeFe]-hydrogenases: mixed-valence nickel-iron dithiolates with rotated structures. Inorganic Chemistry. 51: 8931-41. PMID 22838645 DOI: 10.1021/Ic300910R  0.776
2012 Silakov A, Olsen MT, Sproules S, Reijerse EJ, Rauchfuss TB, Lubitz W. EPR/ENDOR, Mössbauer, and quantum-chemical investigations of diiron complexes mimicking the active oxidized state of [FeFe]hydrogenase. Inorganic Chemistry. 51: 8617-28. PMID 22800196 DOI: 10.1021/Ic3013766  0.738
2012 Letko CS, Rauchfuss TB, Zhou X, Gray DL. Influence of second coordination sphere hydroxyl groups on the reactivity of copper(I) complexes. Inorganic Chemistry. 51: 4511-20. PMID 22452599 DOI: 10.1021/Ic202207E  0.796
2012 Wang W, Rauchfuss TB, Bertini L, Zampella G. Unsensitized photochemical hydrogen production catalyzed by diiron hydrides. Journal of the American Chemical Society. 134: 4525-8. PMID 22364563 DOI: 10.1021/Ja211778J  0.398
2012 Schilter D, Nilges MJ, Chakrabarti M, Lindahl PA, Rauchfuss TB, Stein M. Mixed-valence nickel-iron dithiolate models of the [NiFe]-hydrogenase active site. Inorganic Chemistry. 51: 2338-48. PMID 22304696 DOI: 10.1021/Ic202329Y  0.783
2012 Camara JM, Rauchfuss TB. Combining acid-base, redox and substrate binding functionalities to give a complete model for the [FeFe]-hydrogenase. Nature Chemistry. 4: 26-30. PMID 22169868 DOI: 10.1038/Nchem.1180  0.818
2012 Lei H, Royer AM, Rauchfuss TB, Gray D. C 2-symmetric iron(II) diphosphine-dialkoxide dicarbonyl and related complexes Organometallics. 31: 6408-6414. DOI: 10.1021/Om300631A  0.831
2012 Ringenberg MR, Rauchfuss TB. Protonation-enhanced Lewis acidity of iridium complexes containing noninnocent amidophenolates European Journal of Inorganic Chemistry. 490-495. DOI: 10.1002/Ejic.201101011  0.719
2011 Angamuthu R, Carroll ME, Ramesh M, Rauchfuss TB. A New Route to Azadithiolato Complexes. European Journal of Inorganic Chemistry. 2011: 1029-1032. PMID 23125531 DOI: 10.1002/Ejic.201001208  0.83
2011 Carroll ME, Barton BE, Gray DL, Mack AE, Rauchfuss TB. Active-site models for the nickel-iron hydrogenases: effects of ligands on reactivity and catalytic properties. Inorganic Chemistry. 50: 9554-63. PMID 21866886 DOI: 10.1021/Ic2012759  0.821
2011 Olsen MT, Gray DL, Rauchfuss TB, De Gioia L, Zampella G. Stereochemistry of electrophilic attack at 34e⁻ dimetallic complexes: the case of diiron dithiolato carbonyls + MeS⁺. Chemical Communications (Cambridge, England). 47: 6554-6. PMID 21776614 DOI: 10.1039/C1Cc10858A  0.732
2011 Thorseth MA, Letko CS, Rauchfuss TB, Gewirth AA. Dioxygen and hydrogen peroxide reduction with hemocyanin model complexes. Inorganic Chemistry. 50: 6158-62. PMID 21627090 DOI: 10.1021/Ic200386D  0.789
2011 Letko CS, Heiden ZM, Rauchfuss TB, Wilson SR. Coordination chemistry of the soft chiral Lewis acid [Cp*Ir(TsDPEN)]+. Inorganic Chemistry. 50: 5558-66. PMID 21574553 DOI: 10.1021/Ic200160Q  0.82
2011 Camara JM, Rauchfuss TB. Mild redox complementation enables H2 activation by [FeFe]-hydrogenase models. Journal of the American Chemical Society. 133: 8098-101. PMID 21548619 DOI: 10.1021/Ja201731Q  0.823
2011 Ringenberg MR, Gray DL, Rauchfuss TB. Oxidative addition of a diphosphine anhydride to iron(0) and nickel(0): A simple approach to installing four ligands Organometallics. 30: 2885-2888. DOI: 10.1021/Om200073K  0.741
2010 Olsen MT, Rauchfuss TB, Wilson SR. Role of the azadithiolate cofactor in models for [FeFe]-hydrogenase: novel structures and catalytic implications. Journal of the American Chemical Society. 132: 17733-40. PMID 21114298 DOI: 10.1021/Ja103998V  0.759
2010 Royer AM, Salomone-Stagni M, Rauchfuss TB, Meyer-Klaucke W. Iron acyl thiolato carbonyls: structural models for the active site of the [Fe]-hydrogenase (Hmd). Journal of the American Chemical Society. 132: 16997-7003. PMID 21062066 DOI: 10.1021/Ja1072228  0.827
2010 Barton BE, Rauchfuss TB. Hydride-containing models for the active site of the nickel-iron hydrogenases. Journal of the American Chemical Society. 132: 14877-85. PMID 20925337 DOI: 10.1021/Ja105312P  0.707
2010 Barton BE, Olsen MT, Rauchfuss TB. Artificial hydrogenases. Current Opinion in Biotechnology. 21: 292-7. PMID 20356731 DOI: 10.1016/j.copbio.2010.03.003  0.79
2010 Salomone-Stagni M, Stellato F, Whaley CM, Vogt S, Morante S, Shima S, Rauchfuss TB, Meyer-Klaucke W. The iron-site structure of [Fe]-hydrogenase and model systems: an X-ray absorption near edge spectroscopy study. Dalton Transactions (Cambridge, England : 2003). 39: 3057-64. PMID 20221540 DOI: 10.1039/B922557A  0.799
2010 Barton BE, Zampella G, Justice AK, De Gioia L, Rauchfuss TB, Wilson SR. Isomerization of the hydride complexes [HFe2(SR)2(PR3)(x)(CO)(6-x)]+ (x = 2, 3, 4) relevant to the active site models for the [FeFe]-hydrogenases. Dalton Transactions (Cambridge, England : 2003). 39: 3011-9. PMID 20221534 DOI: 10.1039/B910147K  0.793
2010 Ringenberg MR, Nilges MJ, Rauchfuss TB, Wilson SR. Oxidation of dihydrogen by iridium complexes of redox-active ligands Organometallics. 29: 1956-1965. DOI: 10.1021/Om9010593  0.691
2010 Royer AM, Rauchfuss TB, Gray DL. Organoiridium pyridonates and their role in the dehydrogenation of alcohols Organometallics. 29: 6763-6768. DOI: 10.1021/Om100901B  0.802
2010 Bischof SM, Periana RA, Ringenberg MR, Rauchfuss TB. Iridium Complexes: Oxygen and Carbon Bound Acetylacetonato Iridium(III) Complexes Inorganic Syntheses. 35: 173-178. DOI: 10.1002/9780470651568.ch9  0.63
2010 Ohki Y, Ohta S, Tatsumi K, Davis LM, Girolami GS, Royer AM, Rauchfuss TB. Bio-Inspired Iron and Nickel Complexes: Monomeric Iron(II) Complexes Having Two Sterically Hindered Arylthiolates Inorganic Syntheses. 35: 137-143. DOI: 10.1002/9780470651568.ch7  0.78
2010 Kim SB, Lotz S, Sun S, Chung YK, Pike RD, Sweigart DA, Carroll ME, Morvan D, Rauchfuss TB. Organometallic Reagents: Manganese Tricarbonyl Transfer (MTT) Agents Inorganic Syntheses. 35: 114-120. DOI: 10.1002/9780470651568.ch6  0.508
2010 Schaub T, Radius U, Brucks A, Choules MP, Olsen MT, Rauchfuss TB. Carbene Ligands and Complexes: 1,3-Dialkyl-Imidazole-2-Ylidenes Inorganic Syntheses. 35: 78-83. DOI: 10.1002/9780470651568.ch4  0.663
2010 Kajita Y, Tachi Y, Hitomi Y, Nakagawa T, Kishima Y, Kodera M, Letko CS, Rauchfuss TB. Coordination Compounds: Tris(2-Picolinyl)Methane and its Copper(I) Complex Inorganic Syntheses. 35: 74-77. DOI: 10.1002/9780470651568.ch3  0.783
2010 Schaub T, Radius U, Brucks A, Choules MP, Olsen MT, Rauchfuss TB. 1,3-dialkyl-imidazole-2-ylidenes Inorganic Syntheses. 35: 78-91.  0.679
2010 Chen CH, Liaw WF, Whaley CM, Rauchfuss TB. Iron-cyanocarbonyl complexes [PPN][Fe(CO) 4(CN)] and [PPN][FeBr(CO) 3(CN) 2] Inorganic Syntheses. 35: 129-147.  0.783
2009 Olsen MT, Barton BE, Rauchfuss TB. Hydrogen activation by biomimetic diiron dithiolates. Inorganic Chemistry. 48: 7507-9. PMID 19603776 DOI: 10.1021/Ic900850U  0.816
2009 Barton BE, Whaley CM, Rauchfuss TB, Gray DL. Nickel-iron dithiolato hydrides relevant to the [NiFe]-hydrogenase active site. Journal of the American Chemical Society. 131: 6942-3. PMID 19413314 DOI: 10.1021/Ja902570U  0.841
2009 Whaley CM, Rauchfuss TB, Wilson SR. Coordination chemistry of [HFe(CN)(2)(CO)(3)](-) and its derivatives: toward a model for the iron subsite of the [NiFe]-hydrogenases. Inorganic Chemistry. 48: 4462-9. PMID 19374433 DOI: 10.1021/Ic900200S  0.807
2009 Heiden ZM, Rauchfuss TB. Proton-assisted activation of dihydrogen: mechanistic aspects of proton-catalyzed addition of H2 to Ru and Ir amido complexes. Journal of the American Chemical Society. 131: 3593-600. PMID 19236021 DOI: 10.1021/Ja807277S  0.716
2009 Boyer JL, Cundari TR, DeYonker NJ, Rauchfuss TB, Wilson SR. Redox activation of alkene ligands in platinum complexes with non-innocent ligands. Inorganic Chemistry. 48: 638-45. PMID 19138145 DOI: 10.1021/Ic8017248  0.542
2009 Royer AM, Rauchfuss TB, Gray DL. Oxidative addition of thioesters to iron(0): active-site models for Hmd, nature's third hydrogenase Organometallics. 28: 3618-3620. DOI: 10.1021/Om9004059  0.804
2009 Letko CS, Heiden ZM, Rauchfuss TB. Activation and deactivation of Cp*Ir(TsDPEN) hydrogenation catalysts in water European Journal of Inorganic Chemistry. 4927-4930. DOI: 10.1002/Ejic.200900780  0.794
2008 Barton BE, Olsen MT, Rauchfuss TB. Aza- and oxadithiolates are probable proton relays in functional models for the [FeFe]-hydrogenases. Journal of the American Chemical Society. 130: 16834-5. PMID 19053433 DOI: 10.1021/Ja8057666  0.808
2008 Olsen MT, Justice AK, Gloaguen F, Rauchfuss TB, Wilson SR. New nitrosyl derivatives of diiron dithiolates related to the active site of the [FeFe]-hydrogenases. Inorganic Chemistry. 47: 11816-24. PMID 19007207 DOI: 10.1021/Ic801542W  0.82
2008 Heiden ZM, Zampella G, De Gioia L, Rauchfuss TB. [FeFe]-hydrogenase models and hydrogen: oxidative addition of dihydrogen and silanes. Angewandte Chemie (International Ed. in English). 47: 9756-9. PMID 19003843 DOI: 10.1002/Anie.200804400  0.671
2008 Olsen MT, Bruschi M, De Gioia L, Rauchfuss TB, Wilson SR. Nitrosyl derivatives of diiron(I) dithiolates mimic the structure and Lewis acidity of the [FeFe]-hydrogenase active site. Journal of the American Chemical Society. 130: 12021-30. PMID 18700771 DOI: 10.1021/Ja802268P  0.76
2008 Justice AK, De Gioia L, Nilges MJ, Rauchfuss TB, Wilson SR, Zampella G. Redox and structural properties of mixed-valence models for the active site of the [FeFe]-hydrogenase: progress and challenges. Inorganic Chemistry. 47: 7405-14. PMID 18620387 DOI: 10.1021/Ic8007552  0.683
2008 Volkers PI, Boyke CA, Chen J, Rauchfuss TB, Whaley CM, Wilson SR, Yao H. Precursors to [FeFe]-hydrogenase models: syntheses of Fe2(SR)2(CO)6 from CO-free iron sources. Inorganic Chemistry. 47: 7002-8. PMID 18610969 DOI: 10.1021/Ic800601K  0.82
2008 Stanley JL, Heiden ZM, Rauchfuss TB, Wilson SR, De Gioia L, Zampella G. Desymmetrized Diiron Azadithiolato Carbonyls: A Step Toward Modeling the Iron-Only Hydrogenases. Organometallics. 27: 119-125. PMID 18552987 DOI: 10.1021/Om7009599  0.763
2008 Guo Y, Wang H, Xiao Y, Vogt S, Thauer RK, Shima S, Volkers PI, Rauchfuss TB, Pelmenschikov V, Case DA, Alp EE, Sturhahn W, Yoda Y, Cramer SP. Characterization of the Fe site in iron-sulfur cluster-free hydrogenase (Hmd) and of a model compound via nuclear resonance vibrational spectroscopy (NRVS). Inorganic Chemistry. 47: 3969-77. PMID 18407624 DOI: 10.1021/Ic701251J  0.822
2008 Justice AK, Nilges MJ, Rauchfuss TB, Wilson SR, De Gioia L, Zampella G. Diiron dithiolato carbonyls related to the H(ox)CO state of [FeFe]-hydrogenase. Journal of the American Chemical Society. 130: 5293-301. PMID 18341276 DOI: 10.1021/Ja7113008  0.684
2008 Barton BE, Rauchfuss TB. Terminal hydride in [FeFe]-hydrogenase model has lower potential for H2 production than the isomeric bridging hydride. Inorganic Chemistry. 47: 2261-3. PMID 18333613 DOI: 10.1021/Ic800030Y  0.722
2008 Ringenberg MR, Kokatam SL, Heiden ZM, Rauchfuss TB. Redox-switched oxidation of dihydrogen using a non-innocent ligand. Journal of the American Chemical Society. 130: 788-9. PMID 18163627 DOI: 10.1021/Ja076801K  0.81
2008 Royer AM, Rauchfuss TB, Wilson SR. Coordination chemistry of a model for the GP cofactor in the Hmd hydrogenase: hydrogen-bonding and hydrogen-transfer catalysis. Inorganic Chemistry. 47: 395-7. PMID 18081276 DOI: 10.1021/Ic7018692  0.789
2008 Heiden ZM, Gorecki BJ, Rauchfuss TB. Lewis base adducts derived from transfer hydrogenation catalysts: Scope and selectivity Organometallics. 27: 1542-1549. DOI: 10.1021/Om700996M  0.693
2008 George SJ, Fu J, Guo Y, Drury OB, Friedrich S, Rauchfuss T, Volkers PI, Peters JC, Scott V, Brown SD, Thomas CM, Cramer SP. X-ray photochemistry in iron complexes from Fe(0) to Fe(IV) - Can a bug become a feature? Inorganica Chimica Acta. 361: 1157-1165. DOI: 10.1016/J.Ica.2007.10.039  0.818
2008 Boyer JL, Rauchfuss TB, Wilson SR. Nanoscale ensembles using building blocks inspired by the [FeFe]-hydrogenase active site Comptes Rendus Chimie. 11: 922-925. DOI: 10.1016/J.Crci.2008.01.017  0.627
2007 Stanley JL, Rauchfuss TB, Wilson SR. Studies on the Condensation Pathway to and Properties of Diiron Azadithiolate Carbonyls. Organometallics. 26: 1907-1911. PMID 18592045 DOI: 10.1021/Om0611150  0.486
2007 Mealli C, Rauchfuss TB. Models for the hydrogenases put the focus where it should be--hydrogen. Angewandte Chemie (International Ed. in English). 46: 8942-4. PMID 17963205 DOI: 10.1002/Anie.200703413  0.477
2007 Heiden ZM, Rauchfuss TB. Homogeneous catalytic reduction of dioxygen using transfer hydrogenation catalysts. Journal of the American Chemical Society. 129: 14303-10. PMID 17958423 DOI: 10.1021/Ja073774P  0.716
2007 Justice AK, Zampella G, De Gioia L, Rauchfuss TB. Lewis vs. Brønsted-basicities of diiron dithiolates: spectroscopic detection of the "rotated structure" and remarkable effects of ethane- vs. propanedithiolate. Chemical Communications (Cambridge, England). 2019-21. PMID 17713064 DOI: 10.1039/B700754J  0.672
2007 Justice AK, Rauchfuss TB, Wilson SR. Unsaturated, mixed-valence diiron dithiolate model for the H(ox) state of the [FeFe] hydrogenase. Angewandte Chemie (International Ed. in English). 46: 6152-4. PMID 17615612 DOI: 10.1002/Anie.200702224  0.695
2007 Volkers PI, Rauchfuss TB. Extending the motif of the [FeFe]-hydrogenase active site models: protonation of Fe2(NR)2(CO)6-xLx species. Journal of Inorganic Biochemistry. 101: 1748-51. PMID 17606299 DOI: 10.1016/J.Jinorgbio.2007.05.005  0.841
2007 Rauchfuss TB. Chemistry. A promising mimic of hydrogenase activity. Science (New York, N.Y.). 316: 553-4. PMID 17463276 DOI: 10.1126/Science.1140733  0.324
2007 Boyer JL, Kuhlman ML, Rauchfuss TB. Evolution of organo-cyanometallate cages: supramolecular architectures and new Cs+-specific receptors. Accounts of Chemical Research. 40: 233-42. PMID 17284016 DOI: 10.1021/Ar050215J  0.778
2007 Justice AK, Zampella G, De Gioia L, Rauchfuss TB, van der Vlugt JI, Wilson SR. Chelate control of diiron(I) dithiolates relevant to the [Fe-Fe]- hydrogenase active site. Inorganic Chemistry. 46: 1655-64. PMID 17279743 DOI: 10.1021/Ic0618706  0.778
2007 Boyer JL, Ramesh M, Yao H, Rauchfuss TB, Wilson SR. Redox-switched complexation/decomplexation of K(+) and Cs(+) by molecular cyanometalate boxes. Journal of the American Chemical Society. 129: 1931-6. PMID 17260985 DOI: 10.1021/Ja0646545  0.568
2007 Boyer JL, Wilson SR, Rauchfuss TB. Bis(acetonitrile-κN)(η5-pentamethylcyclopentadienyl) -(pyrimidine-κN)rhodium(III) bis(hexafluoridophosphate) Acta Crystallographica Section E: Structure Reports Online. 63: m2574. DOI: 10.1107/S1600536807044716  0.6
2007 Heiden ZM, Rauchfuss TB. Proton-Induced Lewis Acidity of Unsaturated Iridium Amides [J. Am. Chem. Soc.2006,128, 13048−13049]. Journal of the American Chemical Society. 129: 3027-3027. DOI: 10.1021/Ja0699844  0.661
2007 Boyer JL, Yao H, Kuhlman ML, Rauchfuss TB, Wilson S. Cyanometalate cages with exchangeable terminal ligands European Journal of Inorganic Chemistry. 2721-2728. DOI: 10.1002/Ejic.200700001  0.836
2007 Rauchfuss TB. The Coordination Chemistry of Thiophenes Progress in Inorganic Chemistry. 39: 259-329. DOI: 10.1002/9780470166406.Ch5  0.339
2007 Brandt PF, Lesch DA, Stafford PR, Rauchfuss TB, Kolis JW, Roof LC. Fe2(S2)(CO)6 and Fe3Te2(CO)9,10 Inorganic Syntheses. 31: 112-116. DOI: 10.1002/9780470132623.Ch17  0.413
2006 Heiden ZM, Rauchfuss TB. Proton-induced lewis acidity of unsaturated iridium amides. Journal of the American Chemical Society. 128: 13048-9. PMID 17017773 DOI: 10.1021/Ja0653831  0.722
2006 Justice AK, Linck RC, Rauchfuss TB. Diruthenium dithiolato cyanides: basic reactivity studies and a post hoc examination of nature's choice of Fe versus Ru for hydrogenogenesis. Inorganic Chemistry. 45: 2406-12. PMID 16529459 DOI: 10.1021/Ic051989Z  0.833
2006 Smith SJ, Whaley CM, Rauchfuss TB, Wilson SR. MS2(Me2PC2H4PMe2)2 (M = Mo, W): acid-base properties, proton transfer, and reversible protonolysis of sulfido ligands. Inorganic Chemistry. 45: 679-87. PMID 16411703 DOI: 10.1021/Ic051443C  0.773
2006 Volkers PI, Rauchfuss TB, Wilson SR. Coordination chemistry of 3-mercapto-2-(mercaptomethyl)propanoic acid (dihydroasparagusic acid) with iron and nickel European Journal of Inorganic Chemistry. 4793-4799. DOI: 10.1002/Ejic.200600636  0.841
2006 Linck RC, Rauchfuss TB. Synthetic Models for Bioorganometallic Reaction Centers Bioorganometallics: Biomolecules, Labeling, Medicine. 403-435. DOI: 10.1002/3527607692.ch12  0.771
2005 van der Vlugt JI, Rauchfuss TB, Whaley CM, Wilson SR. Characterization of a diferrous terminal hydride mechanistically relevant to the Fe-only hydrogenases. Journal of the American Chemical Society. 127: 16012-3. PMID 16287273 DOI: 10.1021/Ja055475A  0.837
2005 van der Vlugt JI, Rauchfuss TB, Wilson SR. Electron-rich diferrous-phosphane-thiolates relevant to Fe-only hydrogenase: is cyanide "nature's trimethylphosphane"? Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 90-8. PMID 16220561 DOI: 10.1002/Chem.200500752  0.7
2005 Yao H, Kuhlman ML, Rauchfuss TB, Wilson SR. Organo-tricyanoborates as tectons: illustrative coordination polymers based on copper(I) derivatives. Inorganic Chemistry. 44: 6256-64. PMID 16124804 DOI: 10.1021/Ic0506153  0.772
2005 Boyke CA, van der Vlugt JI, Rauchfuss TB, Wilson SR, Zampella G, De Gioia L. Diferrous cyanides as models for the Fe-only hydrogenases. Journal of the American Chemical Society. 127: 11010-8. PMID 16076208 DOI: 10.1021/Ja051584D  0.831
2005 Whaley CM, Rauchfuss TB, Wilson SR. Bis[(1,4,7,10,13,16-hexaoxacyclooctadecane)-potassium] carbonyltricyanorhodate(I) acetonitrile solvate Acta Crystallographica Section E: Structure Reports Online. 61: m1918-m1919. DOI: 10.1107/S1600536805027297  0.756
2005 Yao H, Rauchfuss TB, Wilson SR. [Me 8Pt 4ReS 4] - and related PtMe 2-containing clusters derived from tetrathiorhenate Journal of Organometallic Chemistry. 690: 193-196. DOI: 10.1016/J.Jorganchem.2004.09.010  0.346
2004 Kuhlman ML, Rauchfuss TB. Competing H-H, S-S, and M-M bond formation in the "shape-shifting" cluster [Ru4S3(arene)4]2+. Angewandte Chemie (International Ed. in English). 43: 6742-5. PMID 15593142 DOI: 10.1002/Anie.200461264  0.776
2004 Boyke CA, Rauchfuss TB, Wilson SR, Rohmer MM, Bénard M. [Fe2(SR)2(mu-CO)(CNMe)6]2+ and analogues: a new class of diiron dithiolates as structural models for the H(ox)Air state of the fe-only hydrogenase. Journal of the American Chemical Society. 126: 15151-60. PMID 15548012 DOI: 10.1021/Ja049050K  0.835
2004 Justice AK, Linck RC, Rauchfuss TB, Wilson SR. Dihydrogen activation by a diruthenium analogue of the Fe-only hydrogenase active site. Journal of the American Chemical Society. 126: 13214-5. PMID 15479062 DOI: 10.1021/Ja0455594  0.819
2004 Kuhlman ML, Yao H, Rauchfuss TB. Synthesis and characterization of the hexagonal prismatic cage [THF[subset or is implied by][PhB(CN)(3)](6)[Cp*Rh](6)](6+). Chemical Communications (Cambridge, England). 1370-1. PMID 15179469 DOI: 10.1039/B401505C  0.789
2004 Kuhlman ML, Rauchfuss TB. Hybrid cluster-cages formed via cyanometalate condensation: Cs subset Co(4)Ru(6)S(2)(CN)(12), Co(4)Ru(9)S(6)(CN)(9), and Rh(4)Ru(9)S(6)(CN)(9) frameworks. Inorganic Chemistry. 43: 430-5. PMID 14731004 DOI: 10.1021/Ic034745S  0.789
2004 Rauchfuss TB. Research on soluble metal sulfides: from polysulfido complexes to functional models for the hydrogenases. Inorganic Chemistry. 43: 14-26. PMID 14704049 DOI: 10.1021/Ic0343760  0.458
2004 Kuhlman ML, Rauchfuss TB. A condensation of [Ru 3S 2(cymene) 3] 2+ with sulfide to give the dendridic cluster [Ru 9S 8(cymene) 6] 2+ Organometallics. 23: 5085-5087. DOI: 10.1021/Om0496941  0.776
2004 Schwarz DE, Frenkel AI, Nuzzo RG, Rauchfuss TB, Vairavamurthy A. Electrosynthesis of ReS4. XAS Analysis of ReS2, Re2S7, and ReS4 Chemistry of Materials. 16: 151-158. DOI: 10.1021/Cm034467V  0.497
2004 Wunder M, Rauchfuss TB, Fenske D. Syntheses and crystal structures of new selenido-bridged ruthenium clusters | Synthesen und kristallstrukturen neuer selenidoverbrückter ruthenium-clusterverbindungen Zeitschrift Fur Anorganische Und Allgemeine Chemie. 630: 1578-1580. DOI: 10.1002/Zaac.200400204  0.316
2004 Contakes SM, Klausmeyer KK, Rauchfuss TB. Tricyanometalate building blocks and organometallic cyanide cages Inorganic Syntheses. 34: 166-171.  0.694
2004 Kuhlman ML, Yao H, Rauchfuss TB. Synthesis and characterization of the hexagonal prismatic cage {THF⊂[PhB(CN)3]6[Cp*Rh]6} 6+ Chemical Communications. 10: 1370-1371.  0.769
2003 Kayal A, Rauchfuss TB. Protonation studies of the new iron carbonyl cyanide trans-[Fe(CO)3(CN)2]2-: implications with respect to hydrogenases. Inorganic Chemistry. 42: 5046-8. PMID 12924874 DOI: 10.1021/Ic034455B  0.476
2003 Kuhlman ML, Rauchfuss TB. Structural chemistry of "defect" cyanometalate boxes: (Cs subset [CpCo(CN)3]4[Cp*Ru]3) and (M subset [Cp*Rh(CN)3]4[Cp*Ru]3) (M = NH4, Cs). Journal of the American Chemical Society. 125: 10084-92. PMID 12914472 DOI: 10.1021/Ja035253H  0.795
2003 Linck RC, Spahn CW, Rauchfuss TB, Wilson SR. Structural analogues of the bimetallic reaction center in acetyl CoA synthase: a Ni--Ni model with bound CO. Journal of the American Chemical Society. 125: 8700-1. PMID 12862445 DOI: 10.1021/Ja035606C  0.79
2003 Schwarz DE, Rauchfuss TB, Wilson SR. Aggregation of PMe3-stabilized molybdenum sulfides and the catalytic dehydrogenation of H2S. Inorganic Chemistry. 42: 2410-7. PMID 12665378 DOI: 10.1021/Ic026215M  0.618
2003 Reynolds MA, Rauchfuss TB, Wilson SR. Ruthenium derivatives of NiS2N2 complexes as analogues of bioorganometallic reaction centers Organometallics. 22: 1619-1625. DOI: 10.1021/Om020724E  0.634
2002 Gloaguen F, Lawrence JD, Rauchfuss TB, Bénard M, Rohmer MM. Bimetallic carbonyl thiolates as functional models for Fe-only hydrogenases. Inorganic Chemistry. 41: 6573-82. PMID 12470052 DOI: 10.1021/Ic025838X  0.762
2002 Lawrence JD, Rauchfuss TB, Wilson SR. New class of diiron dithiolates related to the Fe-only hydrogenase active site: synthesis and characterization of [Fe2(SR)(2)(CNMe)7]2+. Inorganic Chemistry. 41: 6193-5. PMID 12444758 DOI: 10.1021/Ic025919T  0.77
2002 Holloway GA, Pavot C, Scaringe SA, Lu Y, Rauchfuss TB. An organometallic route to oligonucleotides containing phosphoroselenoate. Chembiochem : a European Journal of Chemical Biology. 3: 1061-5. PMID 12404630 DOI: 10.1002/1439-7633(20021104)3:11<1061::Aid-Cbic1061>3.0.Co;2-9  0.61
2002 Contakes SM, Kuhlman ML, Ramesh M, Wilson SR, Rauchfuss TB. Systematic assembly of the double molecular boxes: [Cs subset [CpCo(CN)(3)](4)[Cp*Ru](3)] as a tridentate ligand. Proceedings of the National Academy of Sciences of the United States of America. 99: 4889-93. PMID 11959940 DOI: 10.1073/Pnas.062647799  0.822
2002 Contakes SM, Hsu SC, Rauchfuss TB, Wilson SR. Preparative and structural studies on the carbonyl cyanides of iron, manganese, and ruthenium: fundamentals relevant to the hydrogenases. Inorganic Chemistry. 41: 1670-8. PMID 11896739 DOI: 10.1021/Ic011030L  0.806
2002 Li H, Rauchfuss TB. Iron carbonyl sulfides, formaldehyde, and amines condense to give the proposed azadithiolate cofactor of the Fe-only hydrogenases. Journal of the American Chemical Society. 124: 726-7. PMID 11817928 DOI: 10.1021/Ja016964N  0.469
2001 Schwarz DE, Dopke JA, Rauchfuss TB, Wilson SR. [ReH(SH) (PMe ) ]: A Catalyst for Fundamental Transformations Involving H and H S. Angewandte Chemie (International Ed. in English). 40: 2351-2353. PMID 29711838 DOI: 10.1002/1521-3773(20010618)40:12<2351::Aid-Anie2351>3.0.Co;2-L  0.583
2001 Gloaguen F, Lawrence JD, Schmidt M, Wilson SR, Rauchfuss TB. Synthetic and structural studies on [Fe2(SR)2(CN)x(CO)6-x](x-) as active site models for Fe-only hydrogenases. Journal of the American Chemical Society. 123: 12518-27. PMID 11741415 DOI: 10.1021/Ja016071V  0.764
2001 Gloaguen F, Lawrence JD, Rauchfuss TB. Biomimetic hydrogen evolution catalyzed by an iron carbonyl thiolate. Journal of the American Chemical Society. 123: 9476-7. PMID 11562244 DOI: 10.1021/Ja016516F  0.704
2001 Linck RC, Pafford RJ, Rauchfuss TB. Heterolytic and homolytic activation of dihydrogen at an unusual iridium (II) sulfide. Journal of the American Chemical Society. 123: 8856-7. PMID 11535095 DOI: 10.1021/Ja010603Q  0.766
2001 Rauchfuss TB, Contakes SM, Hsu SC, Reynolds MA, Wilson SR. The influence of cyanide on the carbonylation of iron(II): synthesis of Fe-Sr-Cn-Co centers related to the hydrogenase active sites. Journal of the American Chemical Society. 123: 6933-4. PMID 11448203 DOI: 10.1021/Ja015948N  0.816
2001 Schwarz DE, Dopke JA, Rauchfuss TB, Wilson SR. [ReH] Angewandte Chemie (International Ed. in English). 40: 2351-2353. PMID 11433519 DOI: 10.1002/1521-3773(20010618)40:12<2351::AID-ANIE2351>3.0.CO;2-L  0.451
2001 Lawrence JD, Li H, Rauchfuss TB, Bénard M, Rohmer MM. Diiron Azadithiolates as Models for the Iron-Only Hydrogenase Active Site: Synthesis, Structure, and Stereoelectronics This research was supported by the NIH and the Centre Universitaire et Régional de Ressources Informatiques of ULP and CNRS. Angewandte Chemie (International Ed. in English). 40: 1768-1771. PMID 11353506 DOI: 10.1002/1521-3773(20010504)40:9<1768::Aid-Anie17680>3.0.Co;2-E  0.698
2001 Eckermann AL, Fenske D, Rauchfuss TB. Syntheses of Ru-S clusters with kinetically labile ligands via the photolysis of [(cymene)3RuS2](PF6)2. Inorganic Chemistry. 40: 1459-65. PMID 11261951 DOI: 10.1021/Ic0010609  0.368
2001 Breitzer JG, Smirnov AI, Szczepura LF, Wilson SR, Rauchfuss TB. Redox properties of C6S8(n-) and C3S5(n-) (n = 0, 1, 2): stable radicals and unusual structural properties for C-S-S-C bonds. Inorganic Chemistry. 40: 1421-9. PMID 11261946 DOI: 10.1021/Ic000999R  0.785
2001 Lawrence JD, Li H, Rauchfuss TB. Beyond Fe-only hydrogenases: N-functionalized 2-aza-1,3-dithiolates Fe2[(SCH2)2NR](CO)x (x = 5, 6) Chemical Communications. 1482-1483. DOI: 10.1039/B104195A  0.748
2001 Contakes SM, Rauchfuss TB. Alkali metal-templated assembly of the tetrahedral cyanometallate cages [m⊂Mo4(μ-CN)6(CO)12]5-(M = Li, Na) Chemical Communications. 553-554. DOI: 10.1039/B010192N  0.744
2000 Contakes SM, Klausmeyer KK, Rauchfuss TB. Coordination solids derived from Cp*M(CN)3- (M = Rh, Ir). Inorganic Chemistry. 39: 2069-75. PMID 12526514 DOI: 10.1021/Ic991037R  0.769
2000 Dopke JA, Wilson SR, Rauchfuss TB. Influence of H2S and thiols on the binding of alkenes and alkynes to ReS4-: the spectator sulfido effect. Inorganic Chemistry. 39: 5014-21. PMID 11233197 DOI: 10.1021/Ic0001661  0.383
2000 Moreland AC, Rauchfuss TB. Binding of pi-acceptor ligands to (triamine)iron(II) complexes. Inorganic Chemistry. 39: 3029-36. PMID 11196897 DOI: 10.1021/Ic9912629  0.83
2000 Contakes SM, Rauchfuss TB. {K subset Angewandte Chemie (International Ed. in English). 39: 1984-1986. PMID 10941004 DOI: 10.1002/1521-3773(20000602)39:11<1984::Aid-Anie1984>3.0.Co;2-M  0.701
2000 Schwarz DE, Rauchfuss TB. The addition of isocyanides to ReS4−: [3 + 1] cycloaddition to SMS Chemical Communications. 1123-1124. DOI: 10.1039/B000932F  0.547
2000 Holloway GA, Klausmeyer KK, Wilson SR, Rauchfuss TB. Aufbau Approach to Multimetallic Ensembles Based on Tetrathiooxalate: [Cp* 4 Rh 4 (C 2 S 4 ) 2 ] 2+ , [Cp* 3 Rh 2 Ru(C 2 S 4 )] + , and [Cp* 6 Rh 6 (C 2 S 4 ) 2 ] 4+ Organometallics. 19: 5370-5375. DOI: 10.1021/Om000521V  0.67
2000 Fraņois S, Rohmer MM, Bénard M, Moreland AC, Rauchfuss TB. The N-H···S hydrogen bond in (TACN)2Fe2S6 (TACN = triazacyclononane) and in model systems involving the persulfido moiety: An ab initio and DFT study Journal of the American Chemical Society. 122: 12743-12750. DOI: 10.1021/Ja0011717  0.802
2000 Breitzer JG, Rauchfuss TB. Studies on α-C3S5 2- (dmit2-) and its dinuclear Ni(II) complex: Spectroscopic and structural characterization Polyhedron. 19: 1283-1291. DOI: 10.1016/S0277-5387(00)00381-8  0.806
2000 Holloway GA, Klausmeyer KK, Wilson SR, Rauchfuss TB. Aufbau approach to multimetallic ensembles based on tetrathiooxalate: [Cp*4Rh4(C2S4) 2]2+, [Cp*3Rh2Ru(C2S4)]+, and [Cp*6Rh6(C2S4) 2]4+ Organometallics. 19: 5370-5375.  0.593
2000 Schwarz DE, Rauchfuss TB. The addition of isocyanides to ReS4-: [3 + 1] cycloaddition to S=M=S Chemical Communications. 1123-1124.  0.482
1999 Contakes SM, Schmidt M, Rauchfuss TB. Synthesis of organometallic solids by protonation of Cp*M(CN)3n- (M = Rh, Ir, Ru) Chemical Communications. 1183-1184. DOI: 10.1039/A902115I  0.763
1999 Breitzer JG, Dlott DD, Iwaki LK, Kirkpatrick SM, Rauchfuss TB. Third-Order Nonlinear Optical Properties of Sulfur-Rich Compounds Journal of Physical Chemistry A. 103: 6930-6937. DOI: 10.1021/Jp990137F  0.76
1999 Schmidt M, Contakes SM, Rauchfuss TB. First generation analogues of the binuclear site in the Fe-only hydrogenases: Fe2(μ-SR)2(CO)4(CN)2/2-[8] Journal of the American Chemical Society. 121: 9736-9737. DOI: 10.1021/Ja9924187  0.79
1999 Goodman JT, Rauchfuss TB. Binding of alkenes to ReS4 - Journal of the American Chemical Society. 121: 5017-5022. DOI: 10.1021/Ja9843775  0.331
1999 Klausmeyer KK, Wilson SR, Rauchfuss TB. Alkali metal-templated assembly of cyanometalate 'boxes' (NEt4)3{M[Cp*Rh(Cn)3]4[Mo(CO)3]4} (M = K, Cs). Selective binding of Cs+ Journal of the American Chemical Society. 121: 2705-2711. DOI: 10.1021/Ja982347W  0.349
1999 Holloway GA, Rauchfuss TB. Direct observation of ligand-centered redox in Cp*2Rh2(μ-C2S4)Cl x (x = 2, 0) a Inorganic Chemistry. 38: 3018-3019. DOI: 10.1021/Ic990150E  0.642
1999 Pafford RJ, Chou JH, Rauchfuss TB. Dehydrogenative route to metallo dithiolenes: The reaction of zinc polysulfides and alkenes Inorganic Chemistry. 38: 3779-3786. DOI: 10.1021/Ic990090C  0.797
1999 Contakes SM, Schmidt M, Rauchfuss TB. Correction: Synthesis of organometallic solids by protonation of Cp(*)M(CN)3(n-)(M = Rh, Ir, Ru) (Chemical Communications (1999) (1183)) Chemical Communications. 1769.  0.723
1998 Klausmeyer KK, Rauchfuss TB, Wilson SR. Stepwise Assembly of [(C H ) (C Me ) Co Rh (CN) ] , an "Organometallic Box" . Angewandte Chemie (International Ed. in English). 37: 1694-1696. PMID 29711502 DOI: 10.1002/(Sici)1521-3773(19980703)37:12<1694::Aid-Anie1694>3.0.Co;2-0  0.333
1998 Contakes SM, Klausmeyer KK, Milberg RM, Wilson SR, Rauchfuss TB. The seven-component assembly of the bowl-shaped cages Cp*7Rh7(CN)12 2+ and Cp*Rh3Ir4(CN)12 2+ Organometallics. 17: X-3635. DOI: 10.1021/Om9803772  0.762
1998 Brandt PF, Compton DL, Rauchfuss TB. ansa-ferrocenes with both trisulfide and hydrocarbon straps Organometallics. 17: 2702-2706. DOI: 10.1021/Om9800041  0.78
1998 Moreland AC, Rauchfuss TB. Synthesis, structure, and reactivity of a remarkable iron sulfide: (TACN)2Fe2S6 [8] Journal of the American Chemical Society. 120: 9376-9377. DOI: 10.1021/Ja981388P  0.787
1998 Chou JH, Rauchfuss TB, Szczepura LF. Studies on the electroactive heterocycles C6S8(0/2-) and C6S6O2(0/2-) and related metal complexes Journal of the American Chemical Society. 120: 1805-1811. DOI: 10.1021/Ja973186J  0.382
1998 Pafford RJ, Rauchfuss TB. Effect of Ancillary Ligands on the Reactivity and Structure of Zinc Polysulfido Complexes Inorganic Chemistry. 37: 1974-1980. DOI: 10.1021/Ic971564F  0.809
1998 Breitzer JG, Chou JH, Rauchfuss TB. A New Synthesis of Tetrathiooxalate and Its Conversion to C3S5 2- and C4S6 2- Inorganic Chemistry. 37: 2080-2082. DOI: 10.1021/Ic971327C  0.766
1997 Venturelli A, Rauchfuss TB, Verma AK. Sulfido-Persulfido Equilibria in Sulfur-Rich Metal Clusters: The Case of (C(5)Me(5))(3)RhRu(2)S(4)(2+). Inorganic Chemistry. 36: 1360-1365. PMID 11669713 DOI: 10.1021/Ic9609564  0.344
1997 Dailey KK, Rauchfuss TB. π-Complexes of metalloporphyrins as model intermediates in hydrodementallation (HDM) catalysis Polyhedron. 16: 3129-3138. DOI: 10.1016/S0277-5387(96)00549-9  0.411
1997 Brandt PF, Lesch DA, Stafford PR, Rauchfuss TB, Kolis JW, Roof LC. Fe2(S2)(CO)6 and Fe3Te 2(CO)9, 10 Inorganic Syntheses. 31: 112-116.  0.789
1996 Westmeyer MD, Rauchfuss TB, Verma AK. Iron Sulfido Derivatives of the Fullerenes C(60) and C(70). Inorganic Chemistry. 35: 7140-7147. PMID 11666898 DOI: 10.1021/Ic960728+  0.378
1996 Dailey KK, Rauchfuss TB, Yap GPA, Rheingold AL. Metalloporphyrins as Ligands: Synthesis and Characterization of [(η6‐cymene)‐Ru{η5‐Ni(OEP)}]2+ Angewandte Chemie. 35: 1833-1835. DOI: 10.1002/Anie.199618331  0.324
1995 Feng Q, Rauchfuss TB, Wilson SR. Aminolysis of dicationic ruthenium thiophene complexes Organometallics. 14: 2923-2930. DOI: 10.1021/Om00006A042  0.307
1995 Feng Q, Krautscheid H, Rauchfuss TB, Skaugset AE, Venturelli A. Thermal Fragmentation of Acyl Thiolato Complexes to Reactive Metal Sulfido Intermediates. Structure of Ru(.eta.6-SC3Me3COMe)(PPh3)2 Organometallics. 14: 297-304. DOI: 10.1021/Om00001A043  0.314
1995 Verma AK, Rauchfuss TB, Wilson SR. Donor solvent mediated reactions of elemental zinc and sulfur, sans explosion Inorganic Chemistry. 34: 3072-3078. DOI: 10.1021/Ic00115A038  0.322
1995 Compton DL, Brandt PF, Rauchfuss TB, Rosenbaum DF, Zukoski CF. Organometallic polymers based on S-S and Se-Se linked n-butylferrocenes Chemistry of Materials. 7: 2342-2349. DOI: 10.1021/Cm00060A025  0.334
1994 Houser EJ, Krautscheid H, Rauchfuss TB, Wilson SR. Synthesis and S-centred reactivity of (C5Me5)3Ru3S4+ Journal of the Chemical Society, Chemical Communications. 1283-1284. DOI: 10.1039/C39940001283  0.347
1994 Venturelli A, Rauchfuss TB. Mobile Metal-Metal Bonds: Studies on Mixed Valence Ir3 and Ir4 Clusters Journal of the American Chemical Society. 116: 4824-4831. DOI: 10.1021/Ja00090A030  0.327
1994 Luo S, Rauchfuss TB, Rheingold AL. Thermal decomposition of (C6Me6)Ru(η4-C4Me4S) and related reactivity and structural studies Journal of Organometallic Chemistry. 472: 295-302. DOI: 10.1016/0022-328X(94)80215-7  0.384
1993 Houser EJ, Dev S, Ogilvy AE, Rauchfuss TB, Wilson SR. Sulfido and related derivatives of pentamethylcyclopentadienylruthenium(III)-(IV) complex Organometallics. 12: 4678-4681. DOI: 10.1021/Om00035A065  0.325
1993 Krautscheid H, Feng Q, Rauchfuss TB. Base hydrolysis of ruthenium(II) thiophene complexes and reactions of the coordinated ligands Organometallics. 12: 3273-3281. DOI: 10.1021/Om00032A057  0.322
1993 Paul PP, Rauchfuss TB, Wilson SR. General synthesis of metalloid polysulfide complexes from the elements: structures of Sb2S152- and InS8(N-MeIm)- Journal of the American Chemical Society. 115: 3316-3317. DOI: 10.1021/Ja00061A035  0.307
1993 Houser EJ, Rauchfuss TB, Wilson SR. Synthetic and structural studies on (RC5H4)4Ru4E40/2+ (E = sulfur, selenium, tellurium): mobile metal-metal bonds within a mixed-valence ruthenium (IV)/ruthenium(III) cluster Inorganic Chemistry. 32: 4069-4076. DOI: 10.1021/Ic00071A017  0.358
1992 Luo S, Rauchfuss TB, Wilson SR. Arene vs thiophene reduction in the system (C6R6)Ru(C4R4S)2+ and the protonation of η4-thiophene ligands Journal of the American Chemical Society. 114: 8515-8520. DOI: 10.1021/Ja00048A024  0.342
1992 Davies CE, Green JC, Kaltsoyannis N, MacDonald MA, Qin J, Rauchfuss TB, Redfern CM, Stringer GH, Woolhouse MG. Electronic structure of metal chalcogen cubane clusters: photoelectron spectroscopic, electrochemical, and theoretical studies of [(.eta.-C5H4Me)TiS]4, [(.eta.-C5H4Me)VS]4, [(.eta.-C5H5)CrO]4, [(.eta.-C5H4Me)CrO]4, [(.eta.-C5H4Me)CrS]4, [(.eta.-C5H4Me)CrSe]4, [(.eta.-C5H4-iso-Pr)MoS]4, and [(.eta.-C5H4-iso-Pr)MoSe]4 Inorganic Chemistry. 31: 3779-3791. DOI: 10.1021/Ic00044A021  0.307
1992 Amarasekera J, Houser EJ, Rauchfuss TB, Stern CL. Synthetic studies on the cyclopentadienylruthenium-triphenylphosphine-diselenium system: redox interconversions of Ru2(Se2)2 cores Inorganic Chemistry. 31: 1614-1620. DOI: 10.1021/Ic00035A018  0.414
1992 Rauchfuss TB, Dev S, Wilson SR. N-methylimidazole-promoted reactions of iron and nickel carbonyls with chalcogens: interconversions of iron polysulfide complexes and the structure of [FeSe8(CO)2]2- Inorganic Chemistry. 31: 153-154. DOI: 10.1021/Ic00028A001  0.372
1991 Massa MA, Rauchfuss TB, Wilson SR. A unidentate thiometalate complex: (MeCp)(dppe)Ru-S-ReS3 [bis(diphenylphosphinoethane][methyl cyclopentadienyl-.mu.-sulfidotrisulfidorheniumruthenium] Inorganic Chemistry. 30: 4667-4669. DOI: 10.1021/Ic00024A040  0.326
1991 Dev S, Ramli E, Rauchfuss TB, Wilson SR. Synthesis and structure of [M(N-methylimidazole)6]S8 (M = Mn, Fe, Ni, Mg). Polysulfide salts prepared by the reaction N-methylimidazole + metal powder + sulfur Inorganic Chemistry. 30: 2514-2519. DOI: 10.1021/Ic00011A011  0.385
1991 Morse DB, Rauchfuss TB, Wilson SR. Studies On Organometallic Oxidants : Structure, Redox Properties, And Magnetism Of (C5H5)Vbr3 And (C5H5)Vi3 Inorganic Chemistry. 30: 775-778. DOI: 10.1021/Ic00004A030  0.413
1990 Skaugset AE, Rauchfuss TB, Wilson SR. Base Hydrolysis of Coordinated Thiophene: A Route from Thiophenes to Furans and the Preparation of [(C5Me5)RhS]4 Organometallics. 9: 2875-2876. DOI: 10.1021/Om00161A012  0.377
1990 Dev S, Ramli E, Rauchfuss TB, Stern CL. Direct Approaches to Zinc Polychalcogenide Chemistry:ZnS6(N-MeIm)2 and ZnSe4(N-MeIm)2 Journal of the American Chemical Society. 112: 6385-6386. DOI: 10.1021/Ja00173A030  0.302
1990 Howard KE, Lockemeyer JR, Massa MA, Rauchfuss TB, Wilson SR, Yang X. Thiometalate Complexes Containing Arene, Thiophene, and Cyclobutadiene Coligands. Are Thiometalate Clusters Good Models for Desulfurization Catalysts? Inorganic Chemistry. 29: 4385-4390. DOI: 10.1021/Ic00347A012  0.356
1989 Amarasekera J, Rauchfuss TB, Wilson SR. Synthesis of cuboidal (C5H4Me)4Ru4E4 by condensation of (C5H4Me)Ru(PPh3)2EH (E = S, Se) Journal of the Chemical Society, Chemical Communications. 14-16. DOI: 10.1039/C39890000014  0.313
1989 Ogilvy AE, Skaugset AE, Rauchfuss TB. Electron-Transfer Activation of Coordinated Thiophene: Preparation and Desulfurization of (η5-C5Me5)Rh(η4-C4Me4S) Organometallics. 8: 2739-2741. DOI: 10.1021/Om00113A037  0.393
1989 Amarasekera J, Rauchfuss TB. Interconversion of persulfido, sulfur hydride, and hydride ligands coordinated to CpRu(PPh3)2+ Inorganic Chemistry. 28: 3875-3883. DOI: 10.1021/Ic00319A024  0.412
1988 Ogilvy AE, Draganjac M, Rauchfuss TB, Wilson SR. Activation and desulfurization of thiophene and benzothiophene by iron carbonyls [Erratum to document cited in CA108(23):204794V] Organometallics. 7: 2084-2084. DOI: 10.1021/Om00099A040  0.777
1987 Amarasekera J, Rauchfuss TB, Wilson SR. Synthesis, structure, and properties of [CpRu(PR3)2]2(μ-S2)2+. Effects of strong π-donation in a disulfur complex Inorganic Chemistry. 26: 3328-3332. DOI: 10.1021/Ic00267A023  0.34
1987 Giolando DM, Rauchfuss TB, Clark GM. (CH3C5H4)2TiS2SiMe2: A reactive complex containing an Si-S ligand Inorganic Chemistry. 26: 3080-3082. DOI: 10.1021/Ic00266A002  0.337
1987 Amarasekera J, Rauchfuss TB, Rheingold AL. Nonclassical polysulfide complexes: cage and ring compounds [(MeCp)Ru(PPh3)]2Sx (x = 6, 4) Inorganic Chemistry. 26: 2017-2018. DOI: 10.1021/Ic00260A001  0.306
1987 Giolando DM, Rauchfuss TB, Rheingold AL. Ditellurene, selenatellurene and thiatellurene complexes. Structure of Pt(1,2-Te2C6H4)(PPh3)2 Inorganic Chemistry. 26: 1636-1638. DOI: 10.1021/Ic00257A035  0.301
1986 Rauchfuss TB, Rodgers DPS, Wilson SR. Synthesis of a new type of metal dithiolene complex via an induced reaction of acetylenes with a ruthenium sulfide Journal of the American Chemical Society. 108: 3114-3115. DOI: 10.1021/Ja00271A056  0.306
1986 Wrobleski DA, Cromer DT, Ortiz JV, Rauchfuss TB, Ryan RR, Sattelberger AP. Preparation and characterization of the first organoactinide polysulfide (.eta.5-C5Me5)2ThS5. A unique example of the twist-boat conformation of the MS5 ring Journal of the American Chemical Society. 108: 174-175. DOI: 10.1021/Ja00261A028  0.308
1986 Weatherill TD, Rauchfuss TB, Scott RA. Structural evidence concerning the frontier orbitals in [Fe2E2(CO)6]2- (E = S, Se): redox-active dichalcogen ligands Inorganic Chemistry. 25: 1466-1472. DOI: 10.1021/Ic00229A033  0.315
1986 Bolinger CM, Weatherill TD, Rauchfuss TB, Rheingold AL, Day CS, Wilson SR. (CH3C5H4)2V2S4 as an Organometallic Ligand: Preparation of Iron, Cobalt, Nickel, and Iridium Derivatives and Structures of a V4Ni Cluster and Three V2Fe Clusters Inorganic Chemistry. 25: 634-643. DOI: 10.1021/Ic00225A011  0.405
1986 Rauchfuss TB, Rodgers DPS, Wilson SR. Synthesis of a New Type of Metal Dithiolene Complex via an Induced Reaction of Acetylenes with a Ruthenium Sulfide. Cheminform. 17. DOI: 10.1002/Chin.198640290  0.306
1986 Weatherill TD, Rauchfuss TB, Scott RA. Structural Evidence Concerning the Frontier Orbitals in [Fe,E2(CO)6]2- (E = S, Se): Redox-Active Dichalcogen Ligands. Cheminform. 17. DOI: 10.1002/Chin.198635053  0.387
1986 Bolinger CM, Weatherill TD, Rauchfuss TB, Rheingold AL, Day CS, Wilson SR. (CH3C5H4)2V2S4as an Organometallic Ligand: Preparation of Iron, Cobalt, Nickel, and Iridium Derivatives and Structures of a V4Ni Cluster and Three V2Fe Clusters. Cheminform. 17. DOI: 10.1002/Chin.198628273  0.326
1986 Draganjac M, Rauchfuss TB. Transition Metal Polysulfides: Coordination Compounds with Purely Inorganic Chelate Ligands Cheminform. 17. DOI: 10.1002/Chin.198604353  0.782
1985 Draganjac M, Ruffing CJ, Rauchfuss TB. A model for thiophene chemisorption: a stabilized, .eta.1S-thiophene complex and its relationship to .eta.5-coordination Organometallics. 4: 1909-1911. DOI: 10.1021/Om00129A045  0.791
1985 Ruffing CJ, Rauchfuss TB. Synthetic and reactivity studies on (C5H5)2Ti(.mu.-SH)2Mo(CO)4 and related compounds Organometallics. 4: 524-528. DOI: 10.1021/Om00122A016  0.389
1985 Bogan LE, Rauchfuss TB, Rheingold AL. Synthesis and structures of the tellurium-bridged molybdenum iron carbonyl cluster (C5H5)2Mo2FexTe2(CO)7 (x = 1, 2). Cluster assembly mechanisms and the role of the tellurium Journal of the American Chemical Society. 107: 3843-3850. DOI: 10.1002/Chin.198542305  0.31
1985 Bolinger CM, Rauchfuss TB, Wilson SR. 4-PHENYL-1,2,4-TRIAZOLINE-3,5-DIONE: A PROSTHESIS FOR THE .mu±eta.1-S2 SULFUR LIGAND IN ORGANOVANADIUM SULFIDE CHEMISTRY Cheminform. 16. DOI: 10.1002/Chin.198515292  0.355
1985 Hoots JE, Lesch DA, Rauchfuss TB. Peracid Oxidation Of Inorganic Chalcogen Ligands In Transition-Metal Complexes Cheminform. 16. DOI: 10.1002/Chin.198503327  0.309
1985 Wrobleski DA, Day CS, Goodman BA, Rauchfuss TB. Synthesis and Characterization of Heterobimetallic Complexes Derived from (o-(Diphenylphosphino)benzoyl)pinacolone (HacacP). The Structure of PtCl2{Cu(acacP)2}. Cheminform. 16. DOI: 10.1002/Chin.198501317  0.3
1985 Draganjac M, Rauchfuss TB. Transition Metal Polysulfides: Coordination Compounds with Purely Inorganic Chelate Ligands Angewandte Chemie. 24: 742-757. DOI: 10.1002/Anie.198507421  0.791
1985 Draganjac M, Rauchfuss TB. Übergangsmetallpolysulfide, Koordinationsverbindungen mit rein anorganischen Chelatliganden Angewandte Chemie. 97: 745-760. DOI: 10.1002/Ange.19850970906  0.756
1984 Zank GA, Rauchfuss TB. Thiophosphoryl Complexes of Bis(cyclopentadienyl)titanium. 1. Syntheses, Interconversions, and Structures Organometallics. 3: 1191-1199. DOI: 10.1021/Om00086A009  0.339
1984 Bolinger CM, Rauchfuss TB, Wilson SR. 4-Phenyl-1,2,4-triazoline-3,5-dione: A prosthesis for the μ-η1-S2 ligand in organovanadium sulfide chemistry Journal of the American Chemical Society. 106: 7800-7807. DOI: 10.1021/Ja00337A025  0.371
1984 Wrobleski DA, Day CS, Goodman BA, Rauchfuss TB. Synthesis and Characterization of Heterobimetallic Complexes Derived from (o(Diphenylphosphino)benzoyl)pinacolone (HacacP). The Structure of PtCl2{Cu(acacP)2} Journal of the American Chemical Society. 106: 5464-5472. DOI: 10.1021/Ja00331A014  0.3
1984 Hoots JE, Lesch DA, Rauchfuss TB. Peracid oxidation of inorganic chalcogen ligands in transition-metal complexes Inorganic Chemistry. 23: 3130-3136. DOI: 10.1021/Ic00188A022  0.316
1984 Bucknor SM, Draganjac M, Rauchfuss TB, Ruffing CJ, Fultz WC, Rheingold AL. Synthesis and structure of a stable complex featuring an S-bound dibenzothiophene ligand: RuCl2(4-R2PDBT)2 (DBT = dibenzothiophene) Journal of the American Chemical Society. 106: 5379-5381. DOI: 10.1002/Chin.198451306  0.798
1984 Hoots JE, Rauchfuss TB. SYNTHESIS AND REACTIVITY OF (IR(η2-E2R) (PH2PCH2CH2PPH2)2)2+ (E = S, SE; R = H, CH3) Cheminform. 15. DOI: 10.1002/Chin.198401318  0.319
1983 Hoots JE, Rauchfuss TB, Wilson SR. The first transition metal thiosulphinate and sulphenate esters: [Ir(η2-S2OMe)(dppe)2]2+ and [Ir(η1-SOMe)(MeNC)(dppe)2]2+[dppe = 1,2-bis(diphenylphosphino)ethane] Journal of the Chemical Society, Chemical Communications. 1226-1228. DOI: 10.1039/C39830001226  0.336
1983 Hoots JE, Rauchfuss TB. Synthesis and Reactivity of [Ir(η2-E2R)(Ph2PCH2CH2PPh2)2]2+ (E = S, Se; R = H, CH3) Inorganic Chemistry. 22: 2806-2812. DOI: 10.1021/Ic00162A009  0.319
1983 Bogan LE, Lesch DA, Rauchfuss TB. Synthesis of heterometallic cluster compounds from Fe3(μ3-Te)2(CO)9 and comparisons with analogous sulfide clusters Journal of Organometallic Chemistry. 250: 429-438. DOI: 10.1016/0022-328X(83)85067-0  0.45
1983 Rauchfuss TB. Functionalized Tertiary Phosphines and Related Ligands in Organometallic Coordination Chemistry and Catalysis Cheminform. 15: 239-256. DOI: 10.1007/978-1-4613-3623-5_7  0.343
1983 Bolinger CM, Rauchfuss TB, Rheingold AL. Synthesis and structures of the vanadium sulfide cluster compounds (iso-PrC5H4)2V2S4 and (C5H5)2V2S2[S2C2(CF3)2]: the influence of .pi.-bonding on the geometry of the .mu.-disulfido ligand Journal of the American Chemical Society. 105: 6321-6323. DOI: 10.1002/Chin.198402247  0.333
1982 Lesch DA, Rauchfuss TB. Reactivity of Fe3(.mu.3-Te)2(CO)9 toward Lewis bases. 1 Organometallics. 1: 499-506. DOI: 10.1021/Om00063A017  0.425
1982 Wrobleski DA, Rauchfuss TB. Synthetic approaches to coordinatively unsaturated heterobimetallic complexes Journal of the American Chemical Society. 104: 2314-2316. DOI: 10.1021/Ja00372A037  0.313
1982 Day VW, Lesch DA, Rauchfuss TB. Fe2(.mu.2-E2)(CO)6 (E = sulfur, selenium, and tellurium) as reagents for the preparation of mixed-metal chalcogenide clusters Journal of the American Chemical Society. 104: 1290-1295. DOI: 10.1021/Ja00369A024  0.348
1982 Bolinger CM, Rauchfuss TB. Template syntheses of 1,2-alkene dichalcogenide chelates via the addition of activated acetylenes to biscyclopentadienyltitanium pentachalcogenides Inorganic Chemistry. 21: 3947-3954. DOI: 10.1021/Ic00141A018  0.308
1982 Rauchfuss TB, Weatherill TD. Roussin's Red Salt revisited: reactivity of Fe2(.mu.-E)2(NO)42- (E = S, Se, Te) and related compounds Inorganic Chemistry. 21: 827-830. DOI: 10.1021/Ic00132A071  0.347
1982 Day VW, Lesch DA, Rauchfuss TB. FE2(μ2-E2)(CO)6 (E = SULFUR, SELENIUM, AND TELLURIUM) AS REAGENTS FOR THE PREPARATION OF MIXED-METAL CHALCOGENIDE CLUSTERS Cheminform. 13. DOI: 10.1002/Chin.198226289  0.353
1981 Lesch DA, Rauchfuss TB. Isolation and characterization of Fe2(.mu.-Te2)(CO)6 and its conversion to Fe3(.mu.3-Te)2(CO)x (x = 9, 10) Inorganic Chemistry. 20: 3583-3585. DOI: 10.1021/Ic50225A001  0.388
1980 Lesch DA, Rauchfuss TB. Directed synthesis of mixed metal chalcogenide clusters: oxidative additions of Fe2 μ2-E2)(CO)6 (E = S, Se, Te) Journal of Organometallic Chemistry. 199. DOI: 10.1016/S0022-328X(00)84533-7  0.408
1980 Jeffrey JC, Rauchfuss TB. Metal Complexes Of Hemilabile Ligands. Reactivity And Structure Of Dichlorobis(O-(Diphenylphosphino)Anisole)Ruthenium(Ii) Cheminform. 11. DOI: 10.1002/Chin.198002311  0.34
1979 Jeffrey JC, Rauchfuss TB. Metal complexes of hemilabile ligands. Reactivity and structure of dichlorobis(o-(diphenylphosphino)anisole)ruthenium(II) Inorganic Chemistry. 18: 2658-2666. DOI: 10.1021/Ic50200A004  0.34
1977 Best SA, Brant P, Feltham RD, Rauchfuss TB, Roundhill DM, Walton RA. X-ray photoelectron spectra of inorganic molecules. 18. Observations on sulfur 2p binding energies in transition metal complexes of sulfur-containing ligands Inorganic Chemistry. 16: 1976-1979. DOI: 10.1021/Ic50174A030  0.308
1976 Rauchfuss TB, Shu JS, Roundhill DM. Synthesis and chemistry of new nickel, palladium, and platinum complexes of 1,2-ethanedithiol, 1,3-propanedithiol, 1,4-butanedithiol, 1,4,8-trithianonane, and 1,4,8,11-tetrathiaundecane Inorganic Chemistry. 15: 2096-2101. DOI: 10.1021/Ic50163A017  0.335
1975 Rauchfuss TB, Roundhill DM. Synthesis and reactions of new complexes of nickel, palladium, and platinum with 1,2-ethanedithiol, 2-(methylthio)ethanethiol, and 2-(methylthio)ethane disulfide Journal of the American Chemical Society. 97: 3386-3392. DOI: 10.1021/Ja00845A018  0.334
1975 Mercer GD, Shu JS, Rauchfuss TB, Roundhill DM. Hexadecarbonylhexahodium. Homogeneous catalyst for the oxidation of carbon monoxide to carbon dioxide and for the oxidative cleavage of carbon-carbon bonds in ketones to carboxylic acids Journal of the American Chemical Society. 97: 1967-1968. DOI: 10.1021/Ja00840A068  0.505
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