Carl D. Hoff, PhD - Publications

Affiliations: 
Chemistry University of Miami, Coral Gables, FL 
Area:
Organometallic Chemistry
Website:
http://www.as.miami.edu/chemistry/people/CarlHoff

108 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Bayrakdar TACA, Nahra F, Davis JV, Gamage MM, Captain B, Temprado M, Marazzi M, Saab M, Hecke KV, Ormerod D, Hoff CD, Nolan SP. Dinuclear Gold(I) Complexes Bearing Alkyl-Bridged Bis(N-heterocyclic carbene) Ligands as Catalysts for Carboxylative Cyclization of Propargylamine: Synthesis, Structure, and Kinetic and Mechanistic Comparison to the Mononuclear Complex [Au(IPr)Cl] Organometallics. 39: 2907-2916. DOI: 10.1021/Acs.Organomet.0C00404  0.534
2018 Koppaka A, Cai X, Majumdar S, Etezadi S, Serafim LF, Temprado M, Captain B, Hoff CD. Reactions of Sn(Si( Bu)2Me)3 with HM(CO)3C5R5 (M = Cr or Mo, R = H or CH3) and Hg. Ionic, covalent, and μ-CO bonding patterns between transition metals and tin Inorganica Chimica Acta. 469: 550-560. DOI: 10.1016/J.Ica.2017.09.052  0.596
2017 Palluccio TD, Cai X, Majumdar S, Serafim LF, Tomson NC, Wieghardt K, Cazin CSJ, Nolan SP, Rybak-Akimova EV, Fernández-González MA, Temprado M, Captain B, Hoff CD. Ligand-directed Reactivity in Dioxygen and Water Binding to cis-[Pd(NHC)2(η2-O2)]. Journal of the American Chemical Society. PMID 29172489 DOI: 10.1021/Jacs.7B09905  0.626
2017 Cai X, Majumdar S, Serafim LF, Temprado M, Nolan SP, Cazin CS, Captain B, Hoff CD. N-heterocyclic carbene complexes of palladium in oxygen atom transfer reactions involving the making and breaking of N-O bonds Inorganica Chimica Acta. 468: 285-293. DOI: 10.1016/J.Ica.2017.05.069  0.677
2016 Cai X, Majumdar S, Fortman GC, Koppaka A, Serafim L, Captain B, Temprado M, Hoff CD. Thermodynamic, Kinetic, Structural, and Computational Studies of the Ph3Sn-H, Ph3Sn-SnPh3, and Ph3Sn-Cr(CO)3C5Me5 Bond Dissociation Enthalpies. Inorganic Chemistry. PMID 27704803 DOI: 10.1021/Acs.Inorgchem.6B01978  0.802
2015 Koppaka A, Yempally V, Zhu L, Fortman GC, Temprado M, Hoff CD, Captain B. Synthesis of [Pt(SnBu(t)3)(IBu(t))(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear Pt-Sn Complexes. Inorganic Chemistry. PMID 26673480 DOI: 10.1021/Acs.Inorgchem.5B02441  0.728
2014 Majumdar S, Stauber JM, Palluccio TD, Cai X, Velian A, Rybak-Akimova EV, Temprado M, Captain B, Cummins CC, Hoff CD. Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes. Inorganic Chemistry. 53: 11185-96. PMID 25280113 DOI: 10.1021/Ic5017005  0.61
2014 O'Reilly ME, Pahls DR, Webb JR, Boaz NC, Majumdar S, Hoff CD, Groves JT, Cundari TR, Gunnoe TB. Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand. Dalton Transactions (Cambridge, England : 2003). 43: 8273-81. PMID 24715057 DOI: 10.1039/C4Dt00234B  0.443
2014 Majumdar S, Captain B, Cazin CSJ, Nolan SP, Hoff CD. Enthalpies of ligand substitution for [Mo(η5C 5H5)(CO)2(NO)] - The role of π-bonding effects in metal-ligand bond strengths Journal of Chemical Thermodynamics. 73: 156-162. DOI: 10.1016/J.Jct.2013.12.003  0.591
2013 Tofan D, Temprado M, Majumdar S, Hoff CD, Cummins CC. Functionalization reactions characteristic of a robust bicyclic diphosphane framework. Inorganic Chemistry. 52: 8851-64. PMID 23841641 DOI: 10.1021/Ic401052A  0.397
2013 Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Chui M, Temprado M, Silvia JS, Cozzolino AF, Tofan D, Velian A, Cummins CC, Captain B, Hoff CD. Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide. Journal of the American Chemical Society. 135: 11357-72. PMID 23805977 DOI: 10.1021/Ja405395Z  0.628
2013 Karikachery AR, Lee HB, Masjedi M, Ross A, Moody MA, Cai X, Chui M, Hoff CD, Sharp PR. High quantum yield molecular bromine photoelimination from mononuclear platinum(IV) complexes. Inorganic Chemistry. 52: 4113-9. PMID 23484618 DOI: 10.1021/Ic4004998  0.549
2013 Temprado M, Majumdar S, Cai X, Captain B, Hoff CD. Synthesis, structure, and thermochemistry of adduct formation between N-heterocyclic carbenes and isocyanates or mesitylnitrile oxide Structural Chemistry. 24: 2059-2068. DOI: 10.1007/S11224-013-0305-2  0.578
2012 Cozzolino AF, Tofan D, Cummins CC, Temprado M, Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Captain B, Hoff CD. Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex. Journal of the American Chemical Society. 134: 18249-52. PMID 23082724 DOI: 10.1021/Ja309621H  0.629
2011 Cai X, Majumdar S, Fortman GC, Frutos LM, Temprado M, Clough CR, Cummins CC, Germain ME, Palluccio T, Rybak-Akimova EV, Captain B, Hoff CD. Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. Inorganic Chemistry. 50: 9620-30. PMID 21875050 DOI: 10.1021/Ic2013599  0.796
2011 Cai X, Majumdar S, Fortman GC, Cazin CS, Slawin AM, Lhermitte C, Prabhakar R, Germain ME, Palluccio T, Nolan SP, Rybak-Akimova EV, Temprado M, Captain B, Hoff CD. Oxygen binding to [Pd(L)(L')] (L= NHC, L' = NHC or PR3, NHC = N-heterocyclic carbene). synthesis and structure of a paramagnetic trans-[Pd(NHC)2(η(1)-O2)2] complex. Journal of the American Chemical Society. 133: 1290-3. PMID 21204538 DOI: 10.1021/Ja1103348  0.755
2010 Kégl T, Fortman GC, Temprado M, Hoff CD. Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms Physical Inorganic Chemistry: Reactions, Processes, and Applications. 429-494. DOI: 10.1002/9780470602577.ch10  0.715
2009 Germain ME, Temprado M, Castonguay A, Kryatova OP, Rybak-Akimova EV, Curley JJ, Mendiratta A, Tsai YC, Cummins CC, Prabhakar R, McDonough JE, Hoff CD. Coordination-mode control of bound nitrile radical complex reactivity: intercepting end-on nitrile-Mo(III) radicals at low temperature. Journal of the American Chemical Society. 131: 15412-23. PMID 19919164 DOI: 10.1021/Ja905849A  0.659
2009 Achord P, Fujita E, Muckerman JT, Scott B, Fortman GC, Temprado M, Cai X, Captain B, Isrow D, Weir JJ, McDonough JE, Hoff CD. Experimental and computational studies of binding of dinitrogen, nitriles, azides, diazoalkanes, pyridine, and pyrazines to M(PR(3))(2)(CO)(3) (M = Mo, W; R = Me, (i)Pr). Inorganic Chemistry. 48: 7891-904. PMID 19621935 DOI: 10.1021/Ic900764E  0.797
2009 Fortman GC, Captain B, Hoff CD. Thermodynamic investigations of the staudinger reaction of trialkylphosphines with 1-adamantyl azide and the isolation of an unusual s-cis phosphazide. Inorganic Chemistry. 48: 1808-10. PMID 19235943 DOI: 10.1021/Ic8024205  0.741
2009 Fortman GC, Captain B, Hoff CD. Stoichiometric and catalytic conversion of 1-adamantyl azide to 1-adamantyl isocyanate by [Cr(CO) 3Cp] 2 and reaction with Mo(CO) 3(P iPr 3) 2 to form Mo(κ 2- iPr 3P=NN=NAd)(CO) 3(P iPr 3) Organometallics. 28: 3587-3590. DOI: 10.1021/Om900004K  0.758
2008 Temprado M, McDonough JE, Mendiratta A, Tsai YC, Fortman GC, Cummins CC, Rybak-Akimova EV, Hoff CD. Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. Inorganic Chemistry. 47: 9380-9. PMID 18788794 DOI: 10.1021/Ic800945M  0.822
2008 McDonough JE, Mendiratta A, Curley JJ, Fortman GC, Fantasia S, Cummins CC, Rybak-Akimova EV, Nolan SP, Hoff CD. Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorganic Chemistry. 47: 2133-41. PMID 18260626 DOI: 10.1021/Ic701611P  0.807
2008 Fortman GC, Kégl T, Hoff CD. Kinetic, thermodynamic, and mechanistic aspects of oxidative addition reactions of RE-ER (E = S, Se, Te) and transition metal complexes Current Organic Chemistry. 12: 1279-1297. DOI: 10.2174/138527208785909574  0.737
2008 Fortman GC, Isrow D, McDonough JE, Von Ragué Schleyer P, Schaefer HF, Scott B, Kubas GJ, Kégl T, Ungváry F, Hoff CD. Kinetic and thermodynamic studies of the reactivity of (trimethylsilyl) diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo-N2CH2SiMe3 bond strength and experimental determination of the enthalpy of formation of (trimethylsilyl)diazomethane Organometallics. 27: 4873-4884. DOI: 10.1021/Om800336P  0.804
2008 Kelly RA, Clavier H, Giudice S, Scott NM, Stevens ED, Bordner J, Samardjiev I, Hoff CD, Cavallo L, Nolan SP. Determination of N-heterocyclic carbene (NHC) steric and electronic parameters using the [(NHC)Ir(CO)2Cl] system Organometallics. 27: 202-210. DOI: 10.1021/Om701001G  0.531
2007 Fortman GC, Kégl T, Li QS, Zhang X, Schaefer HF, Xie Y, King RB, Telser J, Hoff CD. Spectroscopic detection and theoretical confirmation of the role of Cr2(CO)5(C5R5)2 and .Cr(CO)2(ketene)(C5R5) as intermediates in carbonylation of N=N=CHSiMe3 to O=C=CHSiMe3 by .Cr(CO)3(C5R5) (R = H, CH3). Journal of the American Chemical Society. 129: 14388-400. PMID 17960906 DOI: 10.1021/Ja075008O  0.752
2007 Muckerman JT, Fujita E, Hoff CD, Kubas GJ. Theoretical investigation of the binding of small molecules and the intramolecular agostic interaction at tungsten centers with carbonyl and phosphine ligands. The Journal of Physical Chemistry. B. 111: 6815-21. PMID 17511495 DOI: 10.1021/Jp070153+  0.419
2007 Weir JJ, McDonough JE, Fortman G, Isrow D, Hoff CD, Scott B, Kubas GJ. Synthesis, structure, and thermochemistry of the formation of the metal-metal bonded dimers [Mo(mu-TeAr)(CO)3(PiP3)]2 (Ar = phenyl, naphthyl) by phosphine elimination from *Mo(TePh)(CO)3(PiPr3)2. Inorganic Chemistry. 46: 652-9. PMID 17257007 DOI: 10.1021/Ic061654X  0.823
2007 Hoff CD. Thermodynamics of Ligand Binding and Exchange in Organometallic Reactions Progress in Inorganic Chemistry. 40: 503-561. DOI: 10.1002/9780470166413.Ch7  0.367
2006 McDonough JE, Weir JJ, Sukcharoenphon K, Hoff CD, Kryatova OP, Rybak-Akimova EV, Scott BL, Kubas GJ, Mendiratta A, Cummins CC. Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. Journal of the American Chemical Society. 128: 10295-303. PMID 16881661 DOI: 10.1021/Ja063250+  0.803
2006 Mendiratta A, Cummins CC, Kryatova OP, Rybak-Akimova EV, McDonough JE, Hoff CD. Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction. Journal of the American Chemical Society. 128: 4881-91. PMID 16594725 DOI: 10.1021/Ja0587796  0.677
2005 Stephens FH, Johnson MJ, Cummins CC, Kryatova OP, Kryatov SV, Rybak-Akimova EV, McDonough JE, Hoff CD. Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: a thermochemical, kinetic, and quantum chemical investigation. Journal of the American Chemical Society. 127: 15191-200. PMID 16248661 DOI: 10.1021/Ja054253+  0.672
2005 McDonough JE, Weir JJ, Carlson MJ, Hoff CD, Kryatova OP, Rybak-Akimova EV, Clough CR, Cummins CC. Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. Inorganic Chemistry. 44: 3127-36. PMID 15847418 DOI: 10.1021/Ic048321P  0.722
2005 Dorta R, Stevens ED, Scott NM, Costabile C, Cavallo L, Hoff CD, Nolan SP. Steric and electronic properties of N-heterocyclic carbenes (NHC): a detailed study on their interaction with Ni(CO)4. Journal of the American Chemical Society. 127: 2485-95. PMID 15725003 DOI: 10.1021/Ja0438821  0.712
2004 Stephens FH, Figueroa JS, Cummins CC, Kryatova OP, Kryatov SV, Rybak-Akimova EV, McDonough JE, Hoff CD. Small-molecule activation by molybdaziridine hydride complexes: Mechanistic sequence of the small-molecule binding and molybdaziridine ring-opening steps Organometallics. 23: 3126-3138. DOI: 10.1021/Om040045Z  0.671
2003 Mendiratta A, Cummins CC, Kryatova OP, Rybak-Akimova EV, McDonough JE, Hoff CD. Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh (E = S, Se, and Te) elimination. Inorganic Chemistry. 42: 8621-3. PMID 14686837 DOI: 10.1021/Ic035077D  0.679
2003 Sukcharoenphon K, Moran D, Schleyer Pv, McDonough JE, Abboud KA, Hoff CD. Increased reactivity of the *Cr(CO)3(C5Me5) radical with thiones versus thiols: a theoretical and experimental investigation. Inorganic Chemistry. 42: 8494-503. PMID 14658905 DOI: 10.1021/Ic034791S  0.819
2003 Dorta R, Stevens ED, Hoff CD, Nolan SP. Stable, three-coordinate Ni(CO)(2)(NHC) (NHC = N-heterocyclic carbene) complexes enabling the determination of Ni-NHC bond energies. Journal of the American Chemical Society. 125: 10490-1. PMID 12940710 DOI: 10.1021/Ja0362151  0.723
2003 Bor G, Fachinetti G, Hoff CD, Palyi G, Zucchi C, Ungváry F, Tannenbaum R. Infrared spectra of isotopically substituted XCo(CO)4 (X=H, EtC(O), EtOC(O) and EtOC(O)CH2) molecules Inorganica Chimica Acta. 353: 168-176. DOI: 10.1016/S0020-1693(03)00309-8  0.353
2003 Lang RF, Ju TD, Bryan JC, Kubas GJ, Hoff CD. Oxidative addition of thiols, and thiol/thiolate exchange reactions of low valent molybdenum and tungsten complexes. Synthetic, structural and calorimetric study of trigonal prismatic W(CO)2(1,10-phenanthroline)(3,4-toluenedithiolate) Inorganica Chimica Acta. 348: 157-164. DOI: 10.1016/S0020-1693(02)01489-5  0.513
2002 Sukcharoenphon K, Ju TD, Abboud KA, Hoff CD. Dinuclear oxidative addition of N-H and S-H bonds at chromium. Reaction of (*)Cr(CO)(3)(C(5)Me(5)) with [o-(HA)C(6)H(4)S-Cr(CO)(3)(C(5)Me(5))] (A = S, NH) yielding [eta(2)-o-(mu-A)C(6)H(4)S-Cr(C(5)Me(5))](2) and H-Cr(CO)(3)(C(5)Me(5)). Inorganic Chemistry. 41: 6769-74. PMID 12470073 DOI: 10.1021/Ic0204934  0.806
2002 Moran D, Sukcharoenphon K, Puchta R, Schaefer HF, Schleyer PV, Hoff CD. 2-Pyridinethiol/2-pyridinethione tautomeric equilibrium. A comparative experimental and computational study. The Journal of Organic Chemistry. 67: 9061-9. PMID 12467429 DOI: 10.1021/Jo0263768  0.791
2002 Capps KB, Whitener GD, Bauer A, Abboud KA, Wasser IM, Vollhardt KP, Hoff CD. Synthesis and crystal structures of (fulvalene)W(2)(SH)(2)(CO)(6), (fulvalene)W(2)(mu-S(2))(CO)(6), and (fulvalene)W(2)(mu-S)(CO)(6): low valent tungsten carbonyl sulfide and disulfide complexes stabilized by the bridging fulvalene ligand. Inorganic Chemistry. 41: 3212-7. PMID 12055000 DOI: 10.1021/Ic025590B  0.434
2001 Cherry JP, Johnson AR, Baraldo LM, Tsai YC, Cummins CC, Kryatov SV, Rybak-Akimova EV, Capps KB, Hoff CD, Haar CM, Nolan SP. On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes. Journal of the American Chemical Society. 123: 7271-86. PMID 11472154 DOI: 10.1021/Ja0031063  0.587
2001 Sukcharoenphon K, Capps KB, Abboud KA, Hoff CD. Synthesis and structure of W(eta(2)-mp)(2)(CO)(3) (mp = monoanion of 2-mercaptopyridine) and its reactions with 2,2'-pyridine disulfide and/or NO to yield W(eta(2)-mp)(4), W(eta(2)-mp)(2)(NO)(2), and W(eta(2)-mp)(3)(NO). Inorganic Chemistry. 40: 2402-8. PMID 11327919 DOI: 10.1021/Ic000722R  0.817
2000 Huang J, Schanz HJ, Stevens ED, Nolan SP, Capps KB, Bauer A, Hoff CD. Structural and solution calorimetric studies of sulfur binding to nucleophilic carbenes. Inorganic Chemistry. 39: 1042-5. PMID 12526387 DOI: 10.1021/Ic990906+  0.744
2000 Hoff CD. Thermodynamic and kinetic studies of stable low valent transition metal radical complexes Coordination Chemistry Reviews. 206: 451-467. DOI: 10.1016/S0010-8545(00)00337-4  0.442
1999 Capps KB, Bauer A, Abboud KA, Hoff CD. Reaction of *NO Thiolate and Thiol Complexes: Elimination of PhSNO from W(phen)(CO)(2)(SPh)(2), CO from W(phen)(CO)(2)((-S)(2)Arene), and HNO from W(phen)(CO)(3)(RSH). Inorganic Chemistry. 38: 6212-6217. PMID 11671335 DOI: 10.1021/Ic990830H  0.468
1999 Capps KB, Bauer A, Sukcharoenphon K, Hoff CD. Kinetic and Thermodynamic Studies of Reaction of *Cr(CO)(3)C(5)Me(5), HCr(CO)(3)C(5)Me(5), and PhSCr(CO)(3)C(5)Me(5) with *NO. Reductive Elimination of Thermodynamically Unstable Molecules HNO and RSNO Driven by Formation of the Strong Cr-NO Bond. Inorganic Chemistry. 38: 6206-6211. PMID 11671334 DOI: 10.1021/Ic990829I  0.814
1999 Capps KB, Bauer A, Ju TD, Hoff CD. Mechanistic Study of the Reaction of (*)Cr(CO)(3)C(5)Me(5) with H(2)S Yielding HCr(CO)(3)C(5)Me(5), HSCr(CO)(3)C(5)Me(5), and C(5)Me(5)(CO)(2)Cr=S=Cr(CO)(2)C(5)Me(5). Kinetic Evidence for Formation of the Substituted Radical Complex (*)Cr(CO)(2)(H(2)S)C(5)Me(5). Inorganic Chemistry. 38: 6130-6135. PMID 11671323 DOI: 10.1021/Ic990571W  0.41
1999 Bauer A, Capps KB, Wixmerten B, Abboud KA, Hoff CD. The Enthalpy of Insertion of Sulfur into the Metal-Hydrogen Bond. Synthetic, Structural, and Calorimetric Study of the Complexes HS-M(CO)(3)C(5)R(5) [M = Cr, Mo, W; R = H, Me]. Inorganic Chemistry. 38: 2136-2142. PMID 11670997 DOI: 10.1021/Ic981221X  0.444
1999 Vollhardt KPC, Cammack JK, Matzger AJ, Bauer A, Capps KB, Hoff CD. Thermodynamic and Kinetic Study of Oxidative Addition/Reductive Elimination of H2and D2to FulvaleneCr2(CO)6:  Evidence for Relatively Strong Metal−Metal Bonds in Fulvalenedimetals Inorganic Chemistry. 38: 2624-2631. DOI: 10.1021/Ic981360E  0.414
1999 Capps KB, Bauer A, Kiss G, Hoff CD. The rate and mechanism of oxidative addition of H2 to the ·Cr(CO)3C5Me5 radical - Generation of a model for reaction of H2 with the ·Co(CO)4 radical Journal of Organometallic Chemistry. 586: 23-30. DOI: 10.1016/S0022-328X(99)00194-1  0.463
1999 Capps KB, Bauer A, Sukcharoenphon K, Hoff CD. Kinetic and thermodynamic studies of reaction of •Cr(CO)3C5Me5, HCr(CO)3C5Me5, and PhSCr(CO)3C5Me5 with •NO. Reductive elimination of thermodynamically unstable molecules HNO and RSNO driven by formation of the strong CR-NO bond Inorganic Chemistry. 38: 6206-6211.  0.806
1999 Capps KB, Bauer A, Ju TD, Hoff CD. Mechanistic study of the reaction oḟCr(CO)3C5Me5 with H2S yielding HCr(CO)3C5Me5, HSCr(CO)3C5Me5, and C5Me5(CO)2Cr=S=Cr(CO)2C 5Me5. Inorganic Chemistry. 38: 6130-6135.  0.331
1999 Capps KB, Bauer A, Abboud KA, Hoff CD. Reaction of •NO thiolate and thiol complexes: Elimination of PhSNO from W(phen)(CO)2(SPh)2, CO from W(phen)(CO)2((-S)2Arene), and HNO from W(phen)(CO)3(RSH) Inorganic Chemistry. 38: 6212-6217.  0.33
1998 Capps KB, Wixmerten B, Bauer A, Hoff CD. Thermochemistry of Sulfur Atom Transfer. Enthalpies of Reaction of Phosphines with Sulfur, Selenium, and Tellurium, and of Desulfurization of Triphenylarsenic Sulfide, Triphenylantimony Sulfide, and Benzyl Trisulfide Inorganic Chemistry. 37: 2861-2864. DOI: 10.1021/Ic9715862  0.306
1998 Ju TD, Capps KB, Roper GC, Lang RF, Hoff CD. First- and second-order mechanisms for oxidative addition for bound methyl disulfide in the complex W(CO)3(phen) (MeSSMe) Inorganica Chimica Acta. 270: 488-498. DOI: 10.1016/S0020-1693(97)06104-5  0.437
1997 Bender BR, Kubas GJ, Jones LH, Swanson BI, Eckert J, Capps KB, Hoff CD. Why does D2 bind better than H2? A theoretical and experimental study of the equilibrium isotope effect on H2 binding in a M(η2-H2) complex. Normal coordinate analysis of W(CO)3(PCy3)2(η2-H2) Journal of the American Chemical Society. 119: 9179-9190. DOI: 10.1021/Ja971009C  0.381
1997 Ju TD, Capps KB, Lang RF, Roper GC, Hoff CD. Reaction of Phenyl and Methyl Disulfide with ·Cr(CO)3C5Me5 and HCr(CO)3C5Me5. Metal Radical and Metal Hydride Reactivity at the Sulfur-Sulfur Bond. Different Mechanisms for Oxidative Addition of Alkyl and Aryl Disulfides Inorganic Chemistry. 36: 614-621. DOI: 10.1021/Ic960294I  0.442
1997 Lang RF, Ju TD, Kiss G, Hoff CD, Bryan JC, Kubas GJ. Reactions of the complexes M(Pr3)2(CO)3(M = Cr, Mo, W; R = iPr, Cy) with thiols, hydrogen sulfide, disulfides, hydrogen iodide and iodine. The role of heteroatoms in determining the metal-hydrogen bond strength at a sterically crowded metal center Inorganica Chimica Acta. 259: 317-327. DOI: 10.1016/S0020-1693(97)05510-2  0.513
1996 Ju TD, Lang RF, Roper GC, Hoff CD. Oxidative addition of butanethiol and thiophenol to the 'Cr(CO)3C5Me5 radical. Kinetic and thermodynamic study of a third-order reaction and its catalysis Journal of the American Chemical Society. 118: 5328-5329. DOI: 10.1021/Ja960082K  0.408
1995 Mukerjee SL, Gonzalez AA, Nolan SP, Ju TD, Lang RF, Hoff CD. Heats of reaction of HMo(CO)3(C5R5) (R = H, CH3) with diphenyldisulfide and of formation of the clusters [PhSMo(CO)x(C5H5)]2, x = 1,2. Thermodynamic study of molybdenum-sulfur bond strengths Inorganica Chimica Acta. 240: 175-182. DOI: 10.1016/0020-1693(95)04533-3  0.6
1994 Zhang S, Shen JK, Basolo F, Ju TD, Lang RF, Kiss G, Hoff CD. Ground-State versus transition-state effects in arene displacement reactions of the complexes (η6-arene)Cr(CO)3 : linear dependence of transition-state energies and resonance energies of the arene ligands Organometallics. 13: 3692-3702. DOI: 10.1021/Om00021A049  0.327
1994 Lang RF, Ju TD, Hoff CD, Bryan JC, Kubas GJ. Synthesis and Structure of W(CO)(phen)(SPh)2(.eta.2-SO2): A Tungsten(II) Sulfur Dioxide Complex That Spontaneously Extrudes Sulfur To Form the Tungsten(VI) Dioxo Complex W(phen)(SPh)2(O)2 Journal of the American Chemical Society. 116: 9747-9748. DOI: 10.1021/Ja00100A049  0.373
1994 Lang RF, Ju TD, Kiss G, Hoff CD, Bryan JC, Kubas GJ. Oxidative Addition of Thiols, Disulfides, Iodine, and Hydrogen Iodide to W(CO)3(PiPr3)2. Preparation of Stable 17-Electron Tungsten Thiolate Radicals from Complexes with Weak W-H Bonds Journal of the American Chemical Society. 116: 7917-7918. DOI: 10.1021/Ja00096A067  0.393
1994 Lang RF, Ju TD, Kiss G, Hoff CD, Bryan JC, Kubas GJ. Oxidative addition of disulfides to the complex W(CO)3(phen)(EtCN). Synthesis, structure, and reactivity of W(CO)2(phen)(SR)2 (R = Ph, Me, CH2Ph, tBu; phen = 1,10-phenanthroline) coordinatively unsaturated complexes of tungsten(II) that reversibly bind CO and other ligands Inorganic Chemistry. 33: 3899-3907. DOI: 10.1021/Ic00096A013  0.379
1994 Kiss G, Nolan SP, Hoff CD. Direct solution calorimetric measurements of enthalpies of proton and electron transfer reactions for transition metal complexes. Thermochemical study of metal-hydride and metal-metal bond energies Inorganica Chimica Acta. 227: 285-292. DOI: 10.1016/0020-1693(94)04218-7  0.575
1992 Harrison R, Arif AM, Wulfsberg G, Lang R, Ju T, Kiss G, Hoff CD, Richmond TG. Crystallographic and spectroscopic assessment of chelate-stabilized aryl halide complexes at a seven-coordinate d4 molybdenum centre Journal of the Chemical Society, Chemical Communications. 1374-1376. DOI: 10.1039/C39920001374  0.389
1992 Kubas GJ, Burns CJ, Khalsa GRK, Van Der Sluys LS, Kiss G, Hoff CD. Dihydrogen: A better ligand than water? IR and X-ray evidence for aquo coordination in W(CO)3(PR3)2(H2O), thermodynamics of H2O versus η2-H2 binding, and H2O/D2 isotopic exchange. Implications on the biological activation of hydrogen Organometallics. 11: 3390-3404. DOI: 10.1021/Om00046A044  0.334
1992 Carl Watkins W, Jaeger T, Kidd CE, Fortier S, Baird MC, Kiss G, Roper GC, Hoff CD. An investigation of the homolytic dissociation of [η5-C5Me5Cr(CO)3]2 and related complexes. The role of ligand substitution on the solution thermochemistry of metal-metal bond cleavage Journal of the American Chemical Society. 114: 907-914. DOI: 10.1021/Ja00029A018  0.382
1992 Mukerjee SL, Lang RF, Ju T, Kiss G, Hoff CD. Heats of the reactions of tricarbonyl(naphthalene)chromium, tricarbonyl(cycloheptatriene)chromium, tricarbonyl(cycloheptatriene)tungsten, and tricarbonyltris(ethylcyanide)tungsten with pyridine, phosphines, phosphites, and other ligands. Comparative thermochemical study of L3M(CO)3 complexes (M = Cr, Mo, W) Inorganic Chemistry. 31: 4885-4889. DOI: 10.1021/Ic00049A030  0.476
1991 Kubas GJ, Kiss G, Hoff CD. Solution calorimetric, equilibrium, and synthetic studies of oxidative addition/reductive elimination of C5R5H (R = H, Me, indenyl) to/from the complexes M(CO)3(RCN)3/(η5-C5R 5)M(CO)3H (M = Cr, Mo, W) Organometallics. 10: 2870-2876. DOI: 10.1021/Om00054A062  0.376
1991 Zhang K, Gonzalez AA, Mukerjee SL, Chou SJ, Hoff CD, Kubat-Martin KA, Barnhart D, Kubas GJ. Solution calorimetric and stopped-flow kinetic study of ligand substitution for the complexes M(CO)3(PCy3)2(L) (M = Cr Mo, W). Comparison of first-, second-, and third-row transition-metal-ligand bonds at a sterically crowded metal center Journal of the American Chemical Society. 113: 9170-9176. DOI: 10.1021/Ja00024A023  0.401
1990 Millar JM, Kastrup RV, Melchior MT, Horváth IT, Hoff CD, Crabtree RH. Kinetics by high-pressure nuclear magnetic resonance: Reversible hydrogen binding in (η2-H2)Cr(CO)3[P(C6H 11)3]2 Journal of the American Chemical Society. 112: 9643-9645. DOI: 10.1021/Ja00182A036  0.356
1990 Kiss G, Zhang K, Mukerjee SL, Hoff CD, Roper GC. Heat of reaction of the Cr(CO)3(C5Me5) radical with hydrogen and related reactions. Relative and absolute bond strengths in the complexes H-Cr(CO)2(L)(C5R5) Journal of the American Chemical Society. 112: 5657-5658. DOI: 10.1021/Ja00170A050  0.475
1990 Kiss G, Zhang K, Mukerjee SL, Hoff CD, Roper GC. Heat of reaction of the Cr(CO)3(C5Me5) radical with H2 and related reactions. Relative and absolute bond strengths in the complexes H-Cr(CO)2(L)(C5R5) Journal of the American Chemical Society. 112: 5657-5658.  0.377
1989 Zhang K, Gonzalez AA, Hoff CD. Stopped-flow kinetic study of the reaction of (P(C6H11)3)2W(CO)3(L) (L = H2, D2, and N2) with pyridine. Kinetic resolution of reaction of dihydride versus molecular hydrogen complexes Journal of the American Chemical Society. 111: 3627-3632. DOI: 10.1021/Ja00192A021  0.473
1989 Gonzalez AA, Hoff CD. Entropy of binding molecular hydrogen and nitrogen in the complexes (P(C6H11)3)2M(CO)3 (M = Cr, Mo, W) Inorganic Chemistry. 28: 4295-4297. DOI: 10.1021/Ic00322A023  0.407
1989 Gonzalez AA, Zhang K, Hoff CD. Rate of reaction of (P(C6H11)3)2W(CO)3 with py, P(OMe)3, PPh2Me, and 2,6-Me2py. Stopped-flow kinetic study of concerted reactions at a sterically crowded metal center Inorganic Chemistry. 28: 4285-4290. DOI: 10.1021/Ic00322A021  0.43
1988 Gonzalez AA, Zhang K, Nolan SP, Vega RLdl, Mukerjee SL, Hoff CD, Kubas GJ. Thermodynamic and kinetic studies of the complexes W(CO)3(PCy3)2(L) (L=H2, N2, NCCH3, pyridine, P(OMe)3, CO) Organometallics. 7: 2429-2435. DOI: 10.1021/Om00102A001  0.533
1988 Gonzalez AA, Mukerjee SL, Chou SJ, Kai Z, Hoff CD. Synthesis of (PCy3)2Cr(CO)3 and its reactions with hydrogen, nitrogen, and other ligands [5] Journal of the Chemical Society. 110: 4419-4421. DOI: 10.1021/Ja00221A055  0.437
1988 Mukerjee SL, Nolan SP, Hoff CD, Vega RLdl. Heat of reaction of (norbornadiene)molybdenum tetracarbonyl with monodentate and bidentate ligands : solution thermochemical study of ligand substitution in the complexes cis-L2Mo(CO)4 Inorganic Chemistry. 27: 81-85. DOI: 10.1021/Ic00274A018  0.513
1988 Nolan SP, La Vega RLD, Mukerjee SL, Gonzalez AA, Zhang K, Hoff CD. The heat of reaction of EtMo(CO)3C5H5 and HMo(CO)3C5H5 and related reactions. Thermochemical study of reductive elimination in alkyl molybdenum complexes Polyhedron. 7: 1491-1498. DOI: 10.1016/S0277-5387(00)81777-5  0.517
1988 Stoutland PO, Bergman RG, Nolan SP, Hoff CD. The thermodynamic driving force for CH activation at iridium Polyhedron. 7: 1429-1440. DOI: 10.1016/S0277-5387(00)81772-6  0.55
1988 Nolan SP, Hoff CD. Pentamethylcyclopentadienylmolybdenumtricarbonyl hydride, pentamethylcyclopentadienylmolybdenumtricarbonyl dimer, cycloheptatriene molybdenumtricarbonyl, tris(pyridine)-molybdenumtricarbonyl and related L3Mo(CO)3 complexes Organometallic Syntheses. 58-66. DOI: 10.1016/B978-0-444-42956-8.50026-8  0.509
1987 Kegley SE, Schaverien CJ, Freudenberger JH, Bergman RG, Nolan SP, Hoff CD. Rhodium alkoxide complexes. Formation of an unusually strong intermolecular hydrogen bond in (PMe3)3Rh-Otol(HOtol) Journal of the American Chemical Society. 109: 6563-6565. DOI: 10.1021/Ja00255A080  0.524
1987 Nolan SP, Hoff CD, Stoutland PO, Newman LJ, Buchanan JM, Bergman RG, Yang GK, Peters KS. Heats of reaction of Cp(PMe3)Ir(R)(H) (R = C6H5, C6H11, H) with HCl, CCl4, CBr4, and MeI. A solution thermochemical study of the C-H insertion reaction Journal of the American Chemical Society. 109: 3143-3145. DOI: 10.1021/Ja00244A046  0.598
1986 Nolan SP, Lopez de la Vega R, Hoff CD. Thermochemical study of the Lewis acid promoted carbonyl insertion reaction. Journal of the American Chemical Society. 108: 7852-3. PMID 22283308 DOI: 10.1021/Ja00284A070  0.513
1986 Nolan SP, Vega RLdl, Hoff CD. Heats of reaction of (toluene)Mo(CO)3 with substituted arenes, sodium cyclopentadiene, nitriles, isocyanides, and other ligands : solution thermodynamic study of ligand exchange in the complexes fac-L3Mo(CO)3 Organometallics. 5: 2529-2537. DOI: 10.1021/Om00143A022  0.571
1986 Nolan SP, Lopez de la Vega R, Hoff CD. Heats of reaction of [Mo(CO)2Cp*]2 (Cp* = C5H5, C5Me5, C9H7) with carbon monoxide, acetylene, and phenylacetylene. Thermochemical investigation of the molybdenum-molybdenum triple bond Inorganic Chemistry. 25: 4446-4448. DOI: 10.1021/Ic00244A033  0.516
1986 Nolan SP, Lopez de la Vega R, Mukerjee SL, Hoff CD. Heats of reaction of RMo(CO)3C5H5 (R = H, Me, Et) with phosphines and phosphites: thermodynamic study of the carbonyl-insertion reaction Inorganic Chemistry. 25: 1160-1165. DOI: 10.1021/Ic00228A020  0.582
1986 Nolan SP, De La Vega RL, Hoff CD. Heats of reaction of HMo(CO)3C5H5 with CCl4 and CBr4 and of NaMo(CO)3C5H5 with I2 and CH3. Solution thermochemical study of the MoX bond for X = H, Cl, Br, I and CH3 Journal of Organometallic Chemistry. 315: 187-199. DOI: 10.1016/0022-328X(86)80437-5  0.554
1986 Nolan SP, Vega RLDL, Mukerjee SL, Hoff CD. Heats of Reaction of RMo(CO)3C5H5(R: H, CH3, C2H5) with Phosphines and Phosphites: Thermodynamic Study of the CO-Insertion Reaction. Cheminform. 17. DOI: 10.1002/Chin.198633074  0.521
1985 Kovács I, Hoff CD, Ungváry F, Markó L. Kinetic investigation of the mixed-metal bimolecular reductive eliminations in the reactions of EtOC(O)CH2M(CO)n or EtOC(O)M(CO)n (M = Co, n = 4; M = Mn, n = 5) with HCo(CO)4 or HMn(CO)5 Organometallics. 4: 1347-1350. DOI: 10.1021/Om00127A007  0.372
1985 Hoff CD, Ungvary F, King RB, Marko L. KINETICS OF THE REACTIONS OF (ETHOXYCARBONYL)METHYLCOBALT TETRACARBONYL WITH **1**3CO, Ph//3P, HCo(CO)//4, AND H//2. A COMPARISON OF THE REACTIVITIES OF RCo(CO)//4 (R equals CH//2COOEt, COOEt, AND H) COMPLEXES. Journal of the American Chemical Society. 107: 666-671. DOI: 10.1021/Ja00289A019  0.426
1985 Nolan SP, Hoff CD. The heats of reaction of phosphines and phosphites with toluene-molybdenum tricarbonyl. Importance of both steric and electronic factors in determining the MoPR3 bond strength Journal of Organometallic Chemistry. 290: 365-373. DOI: 10.1016/0022-328X(85)87299-5  0.605
1985 Nolan SP, Hoff CD, Landrum JT. Synthesis and thermochemistry of HMo(CO)3C5Me5; Comparison of cyclopentadienyl and pentamethylcyclopentadienyl ligands Journal of Organometallic Chemistry. 282: 357-362. DOI: 10.1016/0022-328X(85)87194-1  0.587
1985 Landrum JT, Hoff CD. The heats of hydrogenation of the metal-metal bonded complexes [M(CO)3C5H5]2 (M = Cr, Mo, W) Journal of Organometallic Chemistry. 282: 215-224. DOI: 10.1016/0022-328X(85)87171-0  0.418
1985 Hoff CD. Thermochemistry of molybdenum tricarbonyl complexes of arenes and cyclic polyolefins Journal of Organometallic Chemistry. 282: 201-214. DOI: 10.1016/0022-328X(85)87170-9  0.473
1985 Hoff C, Ungvary F, King RB, Marko L. Kinetics of the reactions of (ethoxycarbonyl)methylcobalt tetracarbonyl with carbon-13 monoxide, triphenylphosphine, hydridocobalt tetracarbonyl, and hydrogen. A comparison of the reactivities of (ethoxycarbonyl)methyl-, ethoxycarbonyl-, and hydridocobalt tetracarbonyl complexes Journal of the American Chemical Society. 107: 666-671. DOI: 10.1002/Chin.198524320  0.386
1983 Hoff CD. The heats of iodination of chromium tricarbonyl complexes of arenes and cycloheptatriene Journal of Organometallic Chemistry. 246: c53-c56. DOI: 10.1016/0022-328X(83)80208-3  0.327
1981 Connolly JW, Hoff C. Organic Compounds of Divalent Tin and Lead Advances in Organometallic Chemistry. 19: 123-153. DOI: 10.1016/S0065-3055(08)60365-2  0.415
1981 Dory TS, Zuckerman JJ, Hoff CD, Connolly JW. Reinvestigation of the claim that bis-(η5-cyclopentadienyl) tin(II) and (η5-cyclopentadienyl)tricarbonyltungsten hydride form bis-[(η5-cyclopentadienyl)tricarbonyltungsten]tin(II) Journal of the Chemical Society, Chemical Communications. 521-522.  0.5
1978 Chan TM, Connolly JW, Hoff CD, Millich F. Photochemical reaction between cyclohexyl isocyanide and π-cyclopentadienyldicarbonyltrimethylsilyliron(II) Journal of Organometallic Chemistry. 152: 287-293. DOI: 10.1016/S0022-328X(00)90647-8  0.542
1978 Connolly JW, Hoff CD. The reaction of trichlorosilyltetracarbonyliron hydride (HFe(CO)4SiCl3) with conjugated dienes Journal of Organometallic Chemistry. 160: 467-475. DOI: 10.1016/S0022-328X(00)89103-2  0.558
1978 Hoff CD, Connolly JW. Synthesis and reactions of the transition metal substituted tin hydride HSn[Mo(CO)3C5H5]3 Journal of Organometallic Chemistry. 148: 127-135. DOI: 10.1016/S0022-328X(00)84056-5  0.552
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