Wolfgang Kaim - Publications

Affiliations: 
Institute of Inorganic Chemistry Stuttgart University 

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Year Citation  Score
2022 Jordan R, Niazi M, Schäfer S, Kaim W, Klein A. Rhenium Tricarbonyl Complexes of Azodicarboxylate Ligands. Molecules (Basel, Switzerland). 27. PMID 36500250 DOI: 10.3390/molecules27238159  0.714
2022 Dhara S, Ansari MA, Schwederski B, Filippou V, Kaim W, Lahiri GK. Diosmium compounds containing bis(imidazole)--quinone bridging ligands. Dalton Transactions (Cambridge, England : 2003). PMID 35175272 DOI: 10.1039/d2dt00184e  0.432
2021 Chatterjee M, Mondal S, Hazari AS, Záliš S, Kaim W, Lahiri GK. Variable electronic structure and spin distribution in bis(2,2'-bipyridine)-metal complexes (M = Ru or Os) of 4,5-dioxido- and 4,5-diimido-pyrene. Dalton Transactions (Cambridge, England : 2003). PMID 33683255 DOI: 10.1039/d1dt00282a  0.817
2021 Kumari M, Bera SK, Blickle S, Kaim W, Lahiri GK. The Indigo Isomer Epindolidione as Redox-Active Bridging Ligand for Diruthenium Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 33459444 DOI: 10.1002/chem.202004747  0.428
2020 Kaim W, Ehret F, Filippou V, Blickle S, Bubrin M, Zalis S. Structural and Oxidation State Alternatives in Platinum and Palladium Complexes of a Redox-Active Amidinato Ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32959415 DOI: 10.1002/Chem.202003636  0.371
2020 Bera SK, Mondal S, Hazari AS, Priego JL, Jiménez-Aparicio R, Kaim W, Lahiri GK. Three Bis-BODIPY Analogous Diruthenium Redox Series: Characterization and Electronic Structure Analysis. Chemistry, An Asian Journal. PMID 32374908 DOI: 10.1002/Asia.202000326  0.85
2020 Ansari MA, Mondal S, Kaim W, Lahiri GK. Fused N-Heterocyclic-Bridged Isomeric Diruthenium Complexes [(acac)Ru(μ-DIPQD)Ru(acac)], = +2, + 1, 0, -1, -2. Inorganic Chemistry. PMID 32150396 DOI: 10.1021/Acs.Inorgchem.9B03543  0.524
2020 Kaim W, Das A, Fiedler J, Záliš S, Sarkar B. NO and NO2 as non-innocent ligands: A comparison Coordination Chemistry Reviews. 404: 213114. DOI: 10.1016/J.Ccr.2019.213114  0.635
2020 Bauer S, Záliš S, Fiedler J, Ringenberg MR, Kaim W. Oxidation State Assignments in the Organoplatinum One-Electron Redox Series [(N^ N)PtMes2 ]n , n = +,0, -,2- European Journal of Inorganic Chemistry. 2020: 2435-2443. DOI: 10.1002/Ejic.202000257  0.333
2020 Kaim W. Sites of Electron Transfer Reactivity in Organometallic Compounds European Journal of Inorganic Chemistry. 2020: 875-878. DOI: 10.1002/Ejic.202000107  0.312
2019 Sarkar SK, Siddiqui MM, Kundu S, Ghosh M, Kretsch J, Stollberg P, Herbst-Irmer R, Stalke D, Stückl AC, Schwederski B, Kaim W, Ghorai S, Jemmis ED, Roesky HW. Isolation of base stabilized fluoroborylene and its radical cation. Dalton Transactions (Cambridge, England : 2003). PMID 31139807 DOI: 10.1039/C9Dt01899A  0.434
2019 Kaim W. Chelate rings of different sizes with non-innocent ligands. Dalton Transactions (Cambridge, England : 2003). PMID 31112174 DOI: 10.1039/C9Dt01411J  0.449
2019 Sinhababu S, Kundu S, Siddiqui MM, Paesch AN, Herbst-Irmer R, Schwederski B, Saha P, Zhao L, Frenking G, Kaim W, Stalke D, Roesky HW. Synthesis of cAAC stabilized biradical of "MeSi" and "MeSiCl" monoradical from MeSiCl - an important feedstock material. Chemical Communications (Cambridge, England). PMID 30924826 DOI: 10.1039/C9Cc01448A  0.365
2019 Siddiqui MM, Sarkar SK, Sinhababu S, Ruth PN, Herbst-Irmer R, Stalke D, Ghosh M, Fu M, Zhao L, Casanova D, Frenking G, Schwederski B, Kaim W, Roesky HW. Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkylamino Carbenes. Journal of the American Chemical Society. PMID 30633503 DOI: 10.1021/Jacs.8B13434  0.369
2019 Glöckle M, Kaim W, Katz NE, García Posse M, Cutin EH, Fiedler J. The Fe(III)/Fe(II) vs Fe(2)(2.5) Formulation in Mixed-Valent Species [(NC)(4)Fe(BL)Fe(CN)(4)](3)(-), BL = 2,2'-Bipyrimidine and 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine. Distance and Size Do Not Always Matter. Inorganic Chemistry. 38: 3270-3274. PMID 11671059 DOI: 10.1021/Ic990249L  0.354
2019 Berger S, Klein A, Kaim W, Fiedler J. Variable Reduction Sequences for Axial (L) and Chelate Ligands (NwedgeN) in Rhenium(I) Complexes [(NwedgeN)Re(CO)(3)(L)](n)(). Inorganic Chemistry. 37: 5664-5671. PMID 11670716 DOI: 10.1021/Ic980268F  0.738
2019 Waldhör E, Kaim W, Lawson M, Jordanov J. Paramagnetism of Tetranuclear Complexes between TCNX Ligands (TCNE, TCNQ, TCNB) and Four Pentaammineruthenium or Dicarbonyl(pentamethylcyclopentadienyl)manganese Fragments. Inorganic Chemistry. 36: 3248-3252. PMID 11669988 DOI: 10.1021/Ic960998S  0.467
2019 Waldhör E, Kaim W, Olabe JA, Slep LD, Fiedler J. The mpz(+)/mpz(*) Pair as Organic Analogue of the NO(+)/NO(*) Ligand Redox System (mpz = N-Methylpyrazinium). A Combined Electrochemical and Spectroscopic Study (UV/Vis/NIR, IR, EPR) of Complexes [(mpz)M(CN)(5)](2)(-)(/3)(-) (M = Fe, Ru, Os). Inorganic Chemistry. 36: 2969-2974. PMID 11669945 DOI: 10.1021/Ic961426A  0.448
2019 Stange AF, Klinkhammer KW, Kaim W. A Tetragonal Bisphenoidal Tetracopper(I) Arrangement Supported by a Potentially Tridentate Ligand Containing Thiolate, Secondary Amine, and 2-Pyridine Functions: Hydrogen-Bonded Instead of Cu(I)-Coordinated Pyridine Rings in an S(4)-Symmetric Compound. Inorganic Chemistry. 35: 4087-4089. PMID 11666613 DOI: 10.1021/Ic951629J  0.36
2019 Greulich S, Kaim W, Stange AF, Stoll H, Fiedler J, Zális S. CpIr(dab) (dab = 1,4-Bis(2,6-dimethylphenyl)-1,4-diazabutadiene): A Coordinatively Unsaturated Six-pi-Electron Metallaheteroaromatic Compound? Inorganic Chemistry. 35: 3998-4002. PMID 11666595 DOI: 10.1021/Ic9514814  0.413
2019 Ernst S, Vogler C, Klein A, Kaim W, Zalis S. pi Molecular Orbital Crossing a(2)(chi)/b(1)(psi) in 1,10-Phenanthroline Derivatives. Ab Initio Calculations and EPR/ENDOR Studies of the 4,7-Diaza-1,10-phenanthroline Radical Anion and Its M(CO)(4) Complexes (M = Cr, Mo, W). Inorganic Chemistry. 35: 1295-1300. PMID 11666322 DOI: 10.1021/Ic950892H  0.681
2019 Li W, Kundu S, Köhler C, Li J, Dutta S, Yang Z, Stalke D, Herbst-Irmer R, Stückl AC, Schwederski B, Koley D, Kaim W, Roesky HW. Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents Organometallics. 38: 1939-1945. DOI: 10.1021/Acs.Organomet.9B00041  0.429
2019 Kaim W, Lahiri GK. The coordination potential of indigo, anthraquinone and related redox-active dyes Coordination Chemistry Reviews. 393: 1-8. DOI: 10.1016/J.Ccr.2019.05.002  0.483
2019 Kaim W. Materials with electronic transitions in the near-infrared Journal of Chemical Sciences. 131: 1-6. DOI: 10.1007/S12039-019-1664-Z  0.371
2019 Mondal S, Filippou V, Bubrin M, Schwederski B, Fiedler J, Kaim W. Metalloradical Compounds with 1,2-Dipivaloylhydrazido Ligands: Electron Transfer and Alkylation/Protonation Effects European Journal of Inorganic Chemistry. 2019: 2639-2647. DOI: 10.1002/Ejic.201900391  0.404
2018 Hazari AS, Ghosh P, Beyer K, Schwederski B, Kaim W, Lahiri GK. Effect of positional isomerism on the spectroelectrochemical response of 3,6-bis(2-pyridyl)-diketopyrrolopyrrolate bridged bis(carbonylhydridoruthenium) compounds. Dalton Transactions (Cambridge, England : 2003). PMID 30246843 DOI: 10.1039/C8Dt02806K  0.841
2018 Chatterjee M, Mondal S, Ghosh P, Kaim W, Lahiri GK. Mononuclear and Dinuclear Ruthenium Complexes of cis- and trans-Thioindigo: Geometrical and Electronic Structure Analyses. Inorganic Chemistry. PMID 30198711 DOI: 10.1021/Acs.Inorgchem.8B01829  0.502
2018 Mondal S, Schwederski B, Frey W, Fiedler J, Záliš S, Kaim W. At the Borderline between Metal-Metal Mixed Valency and a Radical Bridge Situation: Four Charge States of a Diruthenium Complex with a Redox-Active Bis( mer-tridentate) Ligand. Inorganic Chemistry. PMID 29528630 DOI: 10.1021/Acs.Inorgchem.8B00173  0.505
2018 Kaim W, Beyer K, Filippou V, Záliš S. Charge and spin coupling in copper compounds with hemilabile noninnocent ligands – Ambivalence in three dimensions Coordination Chemistry Reviews. 355: 173-179. DOI: 10.1016/J.Ccr.2017.08.006  0.471
2018 Bubrin M, Kvapilová H, Fiedler J, Ehret F, Záliš S, Kaim W. Hybrid α-Diimine/Bis(chalcogenoether) Ligands for Copper(I) and Copper(II) Complexes Zeitschrift FüR Anorganische Und Allgemeine Chemie. 644: 661-670. DOI: 10.1002/Zaac.201800073  0.394
2017 Ansari MA, Mandal A, Beyer K, Paretzki A, Schwederski B, Kaim W, Lahiri GK. Non-innocence and mixed valency in tri- and tetranuclear ruthenium complexes of a heteroquinone bridging ligand. Dalton Transactions (Cambridge, England : 2003). PMID 29094746 DOI: 10.1039/C7Dt03509H  0.532
2017 Kamatchi TS, Mondal S, Scherer T, Bubrin M, Natarajan K, Kaim W. Near IR Absorbing Organometallic Diruthenium Complex Intermediates: Evidence for Bridging Anthrasemiquinone Formation and against Mixed Valency. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28960495 DOI: 10.1002/Chem.201703888  0.482
2017 Kundu S, Sinhababu S, Dutta S, Mondal T, Koley D, Dittrich B, Schwederski B, Kaim W, Stückl AC, Roesky HW. Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals. Chemical Communications (Cambridge, England). PMID 28875182 DOI: 10.1039/C7Cc06358J  0.391
2017 Kundu S, Samuel PP, Sinhababu S, Luebben AV, Dittrich B, Andrada DM, Frenking G, Stückl AC, Schwederski B, Paretzki A, Kaim W, Roesky HW. Organosilicon Radicals with Si-H and Si-Me Bonds from Commodity Precursors. Journal of the American Chemical Society. PMID 28745880 DOI: 10.1021/Jacs.7B06610  0.353
2017 Ringenberg MR, Wittkamp F, Apfel UP, Kaim W. Redox Induced Configurational Isomerization of Bisphosphine-Tricarbonyliron(I) Complexes and the Difference a Ferrocene Makes. Inorganic Chemistry. PMID 28598145 DOI: 10.1021/Acs.Inorgchem.7B00957  0.341
2017 Chatterjee M, Mondal P, Beyer K, Paretzki A, Kaim W, Lahiri GK. A structurally characterised redox pair involving an indigo radical: indigo based redox activity in complexes with one or two [Ru(bpy)2] fragments. Dalton Transactions (Cambridge, England : 2003). PMID 28374021 DOI: 10.1039/C7Dt00055C  0.538
2017 Singha Hazari A, Mandal A, Beyer K, Paretzki A, Kaim W, Lahiri GK. Metal-Metal Bridging Using the DPPP Dye System: Electronic Configurations within Multiple Redox Series. Inorganic Chemistry. PMID 28207252 DOI: 10.1021/Acs.Inorgchem.6B03112  0.52
2017 Plebst S, Bubrin M, Schweinfurth D, Záliš S, Kaim W. Metal carbonyl complexes of potentially ambidentate 2,1,3-benzothiadiazole and 2,1,3-benzoselenadiazole acceptors Zeitschrift FüR Naturforschung B. 72: 839-846. DOI: 10.1515/Znb-2017-0100  0.453
2017 Arslan Biçer F, Yildirim S, Kaim W, Bubrin M. New saccharinate complexes with 3,3′-azobispyridine ligand: synthesis, characterization, and spectroscopic properties Journal of Coordination Chemistry. 70: 2853-2869. DOI: 10.1080/00958972.2017.1360489  0.45
2017 Löw I, Bubrin M, Paretzki A, Fiedler J, Záliš S, Kaim W. The BIAN ligand 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene: An electron sponge or a “normal” α-diimine ligand? Inorganica Chimica Acta. 455: 540-548. DOI: 10.1016/J.Ica.2016.05.054  0.499
2017 Kaim W, Paretzki A. Interacting metal and ligand based open shell systems: Challenges for experiment and theory Coordination Chemistry Reviews. 344: 345-354. DOI: 10.1016/J.Ccr.2016.12.008  0.434
2017 Krafft MJ, Lissner F, Fiedler J, Kaim W. Cobalt Carbonyl Hydrides with 1,1′-Diphosphinylferrocene Ligands - Structural and Electrochemical Diversity Zeitschrift FüR Anorganische Und Allgemeine Chemie. 643: 1971-1977. DOI: 10.1002/Zaac.201700312  0.408
2017 Bubrin M, Paretzki A, Hübner R, Beyer K, Schwederski B, Neugebauer P, Záliš S, Kaim W. Probing the Intramolecular Metal-Selenoether Interaction in a Bis(iminosemiquinone)copper(II) Compound Zeitschrift FüR Anorganische Und Allgemeine Chemie. 643: 1621-1627. DOI: 10.1002/Zaac.201700282  0.435
2016 Li B, Kundu S, Stückl AC, Zhu H, Keil H, Herbst-Irmer R, Stalke D, Schwederski B, Kaim W, Andrada DM, Frenking G, Roesky HW. A Stable Neutral Radical in the Coordination Sphere of Aluminum. Angewandte Chemie (International Ed. in English). PMID 27976487 DOI: 10.1002/Anie.201609101  0.378
2016 Ringenberg M, Schwilk M, Wittkamp F, Apfel UP, Kaim W. Organometallic Fe-Fe Interactions: Beyond Common Metal-Metal Bonds and Inverse Mixed-Valent Charge Transfer. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27943431 DOI: 10.1002/Chem.201605527  0.451
2016 Ansari MA, Mandal A, Paretzki A, Beyer K, Kaim W, Lahiri GK. Isomeric Diruthenium Complexes of a Heterocyclic and Quinonoid Bridging Ligand: Valence and Spin Alternatives for the Metal/Ligand/Metal Arrangement. Inorganic Chemistry. 55: 12357-12365. PMID 27934410 DOI: 10.1021/Acs.Inorgchem.6B02245  0.483
2016 Hazari AS, Paretzki A, Fiedler J, Zalis S, Kaim W, Lahiri GK. Different manifestations of enhanced π-acceptor ligation at every redox level of [Os(9-OP)L2](n), n = 2+, +, 0, - (9-OP(-) = 9-oxidophenalenone and L = bpy or pap). Dalton Transactions (Cambridge, England : 2003). PMID 27801461 DOI: 10.1039/C6Dt03764J  0.844
2016 Ansari MA, Mandal A, Paretzki A, Beyer K, Fiedler J, Kaim W, Lahiri GK. 1,5-Diamido-9,10-anthraquinone, a Centrosymmetric Redox-Active Bridge with Two Coupled β-Ketiminato Chelate Functions: Symmetric and Asymmetric Diruthenium Complexes. Inorganic Chemistry. PMID 27171539 DOI: 10.1021/Acs.Inorgchem.6B00726  0.531
2016 Mondal P, Chatterjee M, Paretzki A, Beyer K, Kaim W, Lahiri GK. Noninnocence of Indigo: Dehydroindigo Anions as Bridging Electron-Donor Ligands in Diruthenium Complexes. Inorganic Chemistry. PMID 26931407 DOI: 10.1021/Acs.Inorgchem.6B00038  0.546
2016 Mandal A, Hoque MA, Grupp A, Paretzki A, Kaim W, Lahiri GK. Analysis of Redox Series of Unsymmetrical 1,4-Diamido-9,10-anthraquinone-Bridged Diruthenium Compounds. Inorganic Chemistry. PMID 26887785 DOI: 10.1021/Acs.Inorgchem.5B02541  0.442
2016 Melin V, Henríquez A, Radojkovic C, Schwederski B, Kaim W, Freer J, Contreras D. Reduction reactivity of catecholamines and their ability to promote a Fenton reaction Inorganica Chimica Acta. 453: 1-7. DOI: 10.1016/J.Ica.2016.07.044  0.31
2016 Kaim W. Electron Transfer Reactivity of Organometallic Compounds Involving Radical-Forming Noninnocent Ligands Proceedings of the National Academy of Sciences, India Section a: Physical Sciences. 86: 445-457. DOI: 10.1007/S40010-016-0304-Y  0.31
2015 Samuel PP, Neufeld R, Chandra Mondal K, Roesky HW, Herbst-Irmer R, Stalke D, Demeshko S, Meyer F, Rojisha VC, De S, Parameswaran P, Stückl AC, Kaim W, Christian JH, Bindra JK, et al. Cr(i)Cl as well as Cr(+) are stabilised between two cyclic alkyl amino carbenes. Chemical Science. 6: 3148-3153. PMID 28706686 DOI: 10.1039/C5Sc00646E  0.397
2015 Paluru DK, Dey S, Wadawale AP, Bhuvanesh N, Grupp A, Kaim W, Jain VK. Coordination Polymers of Palladium Bridged by Carboxylate and Dimethylaminoalkylselenolate Ligands. Chemistry, An Asian Journal. PMID 26668012 DOI: 10.1002/Asia.201501087  0.372
2015 Mandal A, Grupp A, Schwederski B, Kaim W, Lahiri GK. Noninnocently Behaving Bridging Anions of the Widely Distributed Antioxidant Ellagic Acid in Diruthenium Complexes. Inorganic Chemistry. 54: 10049-57. PMID 26441246 DOI: 10.1021/Acs.Inorgchem.5B01868  0.463
2015 Ehret F, Bubrin M, Záliš S, Priego JL, Jiménez-Aparicio R, Kaim W. Metal-Induced Thiophene Ring Opening and C-C Bond Formation To Produce Unique Hexa-1,3,5-trienediyl-Coupled Non-Innocent Ligand Chelates. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 15163-6. PMID 26385512 DOI: 10.1002/Chem.201502748  0.405
2015 Mandal A, Schwederski B, Fiedler J, Kaim W, Lahiri GK. Evidence for Bidirectional Noninnocent Behavior of a Formazanate Ligand in Ruthenium Complexes. Inorganic Chemistry. 54: 8126-35. PMID 26244848 DOI: 10.1021/Acs.Inorgchem.5B01408  0.433
2015 Mandal A, Grupp A, Schwederski B, Kaim W, Lahiri GK. Varying Electronic Structures of Diosmium Complexes from Noninnocently Behaving Anthraquinone-Derived Bis-chelate Ligands. Inorganic Chemistry. 54: 7936-44. PMID 26230751 DOI: 10.1021/Acs.Inorgchem.5B01017  0.494
2015 Ehret F, Bubrin M, Záliš S, Kaim W. Metal-Chelating N,N'-Bis(4-dimethylaminophenyl)acetamidinyl Radical: A New Chromophore for the Near-Infrared Region. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 12275-8. PMID 26179080 DOI: 10.1002/Chem.201501875  0.489
2015 Roy S, Dittrich B, Mondal T, Koley D, Stückl AC, Schwederski B, Kaim W, John M, Vasa SK, Linser R, Roesky HW. Carbene supported dimer of heavier ketenimine analogue with p and si atoms. Journal of the American Chemical Society. 137: 6180-3. PMID 25919008 DOI: 10.1021/Jacs.5B03407  0.37
2015 Roy S, Stückl AC, Demeshko S, Dittrich B, Meyer J, Maity B, Koley D, Schwederski B, Kaim W, Roesky HW. Stable radicals from commonly used precursors trichlorosilane and diphenylchlorophosphine. Journal of the American Chemical Society. 137: 4670-3. PMID 25815606 DOI: 10.1021/Jacs.5B02403  0.4
2015 Das A, Ghosh P, Plebst S, Schwederski B, Mobin SM, Kaim W, Lahiri GK. Ancillary ligand control of electronic structure in o-benzoquinonediimine-ruthenium complex redox series: structures, electron paramagnetic resonance (EPR), and ultraviolet-visible-near-infrared (UV-vis-NIR) spectroelectrochemistry. Inorganic Chemistry. 54: 3376-86. PMID 25790375 DOI: 10.1021/Ic503070J  0.47
2015 Choudhuri MM, Behzad M, Al-Noaimi M, Yap GP, Kaim W, Sarkar B, Crutchley RJ. Variable noninnocence of substituted azobis(phenylcyanamido)diruthenium complexes. Inorganic Chemistry. 54: 1508-17. PMID 25611997 DOI: 10.1021/Ic502487X  0.658
2015 Paretzki A, Hübner R, Ye S, Bubrin M, Kämper S, Kaim W. Electronic, charge and magnetic interactions in three-centre systems Journal of Materials Chemistry C. 3: 4801-4809. DOI: 10.1039/C5Tc00658A  0.365
2015 Grupp A, Fiedler J, Kaim W. UV-Vis-NIR spectroelectrochemical study of tetrathiorhenate-bridged diruthenium complexes Dedicated to Prof. Claude Lapinte Polyhedron. 86: 71-75. DOI: 10.1016/J.Poly.2014.05.016  0.462
2015 Jana R, Blickle S, Lissner F, Hartenbach I, Bubrin M, Schwederski B, Kaim W. Organometal coordination by purines: Semi-chelate bonding of modified guanine and isocaffeine with bis(diorganylphosphino)ferrocene-copper Journal of Organometallic Chemistry. 782: 62-68. DOI: 10.1016/J.Jorganchem.2014.10.043  0.419
2015 Kaim W. Complete and Partial Electron Transfer Involving Coordinated NOx Advances in Inorganic Chemistry. 67: 295-313. DOI: 10.1016/Bs.Adioch.2014.10.007  0.418
2015 Bach M, Roy S, Sarkar B, Bubrin M, Niemeyer M, Fiedler J, Duboc C, Kaim W. Heterotetranuclear complexes of reduced and non-reduced bridging 1,2,4,5-tetrazine ligands with 1,1′-bis(diphenylphosphanyl)-ferrocenecopper(I) Zeitschrift Fur Anorganische Und Allgemeine Chemie. 641: 327-331. DOI: 10.1002/Zaac.201400564  0.623
2015 Jana R, Lissner F, Kaim W. Coordinative saturation of the pterin heterocycle by ferrocenylcopper(I) complex fragments Zeitschrift Fur Anorganische Und Allgemeine Chemie. 641: 261-265. DOI: 10.1002/Zaac.201400529  0.385
2014 Mondal P, Plebst S, Ray R, Mobin SM, Kaim W, Lahiri GK. Uncommon cis configuration of a metal-metal bridging noninnocent Nindigo ligand. Inorganic Chemistry. 53: 9348-56. PMID 25137231 DOI: 10.1021/Ic501460D  0.53
2014 Mondal KC, Roy S, De S, Parameswaran P, Dittrich B, Ehret F, Kaim W, Roesky HW. Stabilization of a two-coordinate mononuclear cobalt(0) compound. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11646-9. PMID 25047010 DOI: 10.1002/Chem.201403525  0.425
2014 Mondal P, Agarwala H, Jana RD, Plebst S, Grupp A, Ehret F, Mobin SM, Kaim W, Lahiri GK. Sensitivity of a strained C-C single bond to charge transfer: redox activity in mononuclear and dinuclear ruthenium complexes of bis(arylimino)acenaphthene (BIAN) ligands. Inorganic Chemistry. 53: 7389-403. PMID 24983788 DOI: 10.1021/Ic500730M  0.496
2014 Mandal A, Agarwala H, Ray R, Plebst S, Mobin SM, Priego JL, Jiménez-Aparicio R, Kaim W, Lahiri GK. Sensitivity of the valence structure in diruthenium complexes as a function of terminal and bridging ligands. Inorganic Chemistry. 53: 6082-93. PMID 24896222 DOI: 10.1021/Ic500452H  0.469
2014 Weinberger DS, Amin Sk N, Mondal KC, Melaimi M, Bertrand G, Stückl AC, Roesky HW, Dittrich B, Demeshko S, Schwederski B, Kaim W, Jerabek P, Frenking G. Isolation of neutral mononuclear copper complexes stabilized by two cyclic (alkyl)(amino)carbenes. Journal of the American Chemical Society. 136: 6235-8. PMID 24731250 DOI: 10.1021/Ja502521B  0.422
2014 Paretzki A, Bubrin M, Fiedler J, Záliš S, Kaim W. Correlated coordination and redox activity of a hemilabile noninnocent ligand in nickel complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 5414-22. PMID 24665084 DOI: 10.1002/Chem.201304316  0.473
2014 Mondal KC, Samuel PP, Roesky HW, Niepötter B, Herbst-Irmer R, Stalke D, Ehret F, Kaim W, Maity B, Koley D. Synthesis and characterization of a triphenyl-substituted radical and an unprecedented formation of a carbene-functionalized quinodimethane. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9240-5. PMID 24664879 DOI: 10.1002/Chem.201400393  0.416
2014 Li Y, Mondal KC, Samuel PP, Zhu H, Orben CM, Panneerselvam S, Dittrich B, Schwederski B, Kaim W, Mondal T, Koley D, Roesky HW. C4 cumulene and the corresponding air-stable radical cation and dication. Angewandte Chemie (International Ed. in English). 53: 4168-72. PMID 24623450 DOI: 10.1002/Anie.201310975  0.369
2014 Agarwala H, Scherer TM, Mobin SM, Kaim W, Lahiri GK. Bidirectional non-innocence of the β-diketonato ligand 9-oxidophenalenone (L-) in [Ru([9]aneS3)(L)(dmso)]n, [9]aneS3 = 1,4,7-trithiacyclononane. Dalton Transactions (Cambridge, England : 2003). 43: 3939-48. PMID 24448427 DOI: 10.1039/C3Dt53069H  0.433
2014 Mondal KC, Samuel PP, Roesky HW, Carl E, Herbst-Irmer R, Stalke D, Schwederski B, Kaim W, Ungur L, Chibotaru LF, Hermann M, Frenking G. Stabilization of a cobalt-cobalt bond by two cyclic alkyl amino carbenes. Journal of the American Chemical Society. 136: 1770-3. PMID 24437683 DOI: 10.1021/Ja4123285  0.427
2014 Mandal A, Kundu T, Ehret F, Bubrin M, Mobin SM, Kaim W, Lahiri GK. Varying electronic structural forms of ruthenium complexes of non-innocent 9,10-phenanthrenequinonoid ligands. Dalton Transactions (Cambridge, England : 2003). 43: 2473-87. PMID 24306621 DOI: 10.1039/C3Dt53104J  0.469
2014 Bubrin M, Schweinfurth D, Ehret F, Záliš S, Kvapilová H, Fiedler J, Zeng Q, Hartl F, Kaim W. Structure and spectroelectrochemical response of arene-ruthenium and arene-osmium complexes with potentially hemilabile noninnocent ligands Organometallics. 33: 4973-4985. DOI: 10.1021/Om5002815  0.524
2014 Jana R, Sarkar B, Strobel S, Mobin SM, Kaim W, Fiedler J. Electrochemical evidence for hemilabile coordination of 1,3-dimethyllumazine to [1,1′-Bis(diorganophosphino)ferrocene]copper(I) Organometallics. 33: 4784-4791A. DOI: 10.1021/Om500039A  0.647
2014 Grupp A, Bubrin M, Ehret F, Kvapilová H, Záliš S, Kaim W. Oxidation and reduction response of α-diimine complexes with tricarbonylrhenium halides and pseudohalides Journal of Organometallic Chemistry. 751: 678-685. DOI: 10.1016/J.Jorganchem.2013.08.030  0.408
2014 Ehret F, Bubrin M, Záliš S, Kaim W. Non-innocent Redox Behavior of Amidinato Ligands: Spectroscopic Evidence for Amidinyl Complexes Zeitschrift FüR Anorganische Und Allgemeine Chemie. 640: 2781-2787. DOI: 10.1002/Zaac.201400306  0.494
2014 Grupp A, Bubrin M, Ehret F, Zeng Q, Hartl F, Kvapilová H, Záliš S, Kaim W. RuII(α-diimine) or RuIII(α-diimine ·-)? structural, spectroscopic, and theoretical evidence for the stabilization of a prominent metal-to-ligand charge-transfer excited-state configuration in the ground state European Journal of Inorganic Chemistry. 110-119. DOI: 10.1002/Ejic.201301206  0.443
2013 Choudhuri MM, Kaim W, Sarkar B, Crutchley RJ. Non-innocence of 1,4-dicyanamidobenzene bridging ligands in dinuclear ruthenium complexes. Inorganic Chemistry. 52: 11060-6. PMID 24050206 DOI: 10.1021/Ic401316G  0.631
2013 Mondal KC, Roesky HW, Stückl AC, Ehret F, Kaim W, Dittrich B, Maity B, Koley D. Formation of trichlorosilyl-substituted carbon-centered stable radicals through the use of π-accepting carbenes. Angewandte Chemie (International Ed. in English). 52: 11804-7. PMID 24038666 DOI: 10.1002/Anie.201300668  0.365
2013 Jana R, Mobin SM, Schwederski B, Fiedler J, Kaim W. Variable coordination of redox-active TCNB in discrete and polymeric ferrocenylcopper(I) complexes: structures and spectroelectrochemical behaviour. Dalton Transactions (Cambridge, England : 2003). 42: 16142-50. PMID 24022668 DOI: 10.1039/C3Dt51360B  0.461
2013 Mondal P, Ehret F, Bubrin M, Das A, Mobin SM, Kaim W, Lahiri GK. A diruthenium complex of a "Nindigo" ligand. Inorganic Chemistry. 52: 8467-75. PMID 23859694 DOI: 10.1021/Ic400390B  0.505
2013 Krafft MJ, Bubrin M, Paretzki A, Lissner F, Fiedler J, Záliš S, Kaim W. Identifying intermediates of sequential electron and hydrogen loss from a dicarbonylcobalt hydride complex. Angewandte Chemie (International Ed. in English). 52: 6781-4. PMID 23666924 DOI: 10.1002/Anie.201301706  0.358
2013 Das D, Agarwala H, Chowdhury AD, Patra T, Mobin SM, Sarkar B, Kaim W, Lahiri GK. Four-center oxidation state combinations and near-infrared absorption in [Ru(pap)(Q)2]n (Q = 3,5-di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine, pap = 2-phenylazopyridine). Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 7384-94. PMID 23576220 DOI: 10.1002/Chem.201204620  0.614
2013 Ehret F, Bubrin M, Záliš S, Kaim W. Discovering more non-innocence: triazenido versus triazenyl radical ligand function, and a comment on [NO2]n as a "suspect" ligand. Angewandte Chemie (International Ed. in English). 52: 4673-5. PMID 23519944 DOI: 10.1002/Anie.201209260  0.428
2013 Dreher A, Meyer S, Näther C, Westphal A, Broda H, Sarkar B, Kaim W, Kurz P, Tuczek F. Reduction and protonation of Mo(IV) imido complexes with depe coligands: generation and reactivity of a S = 1/2 Mo(III) alkylnitrene intermediate. Inorganic Chemistry. 52: 2335-52. PMID 23398558 DOI: 10.1021/Ic301828E  0.639
2013 Agarwala H, Ehret F, Chowdhury AD, Maji S, Mobin SM, Kaim W, Lahiri GK. Electronic structure and catalytic aspects of [Ru(tpm)(bqdi)(Cl/H2O)]n, tpm = tris(1-pyrazolyl)methane and bqdi = o-benzoquinonediimine. Dalton Transactions (Cambridge, England : 2003). 42: 3721-34. PMID 23302760 DOI: 10.1039/C2Dt32402D  0.503
2013 Jana R, Lissner F, Schwederski B, Fiedler J, Kaim W. A ligand-bridged heterotetranuclear (Fe2Cu2) Redox System with Fc/Fc+ and radical ion intermediates Organometallics. 32: 5879-5886. DOI: 10.1021/Om400466U  0.437
2013 Choudhuri MMR, Kaim W, Sarkar B, Crutchley RJ. Non-innocence of 1,4-dicyanamidobenzene bridging ligands in dinuclear ruthenium complexes. Inorganic Chemistry. 52: 11060-11066. DOI: 10.1021/ic401316g  0.317
2013 Jana R, Schwederski B, Fiedler J, Kaim W. Reprint of "facilitated reduction and oxidation of {[Ru(NH 3)5]4(μ4-TCNX)}8+ by changing from TCNX = TCNQ to TCNQF4" Polyhedron. 52: 1499-1503. DOI: 10.1016/J.Poly.2013.02.004  0.478
2013 Kaim W, Sarkar B. Mixed valency of a 5d element: The osmium example Coordination Chemistry Reviews. 257: 1650-1659. DOI: 10.1016/J.Ccr.2012.08.026  0.597
2013 Wang D, Unold J, Bubrin M, Elser I, Frey W, Kaim W, Xu G, Buchmeiser MR. Ruthenium-triazene complexes as latent catalysts for UV-induced ROMP European Journal of Inorganic Chemistry. 5462-5468. DOI: 10.1002/Ejic.201301048  0.417
2012 Kundu T, Schweinfurth D, Sarkar B, Mondal TK, Fiedler J, Mobin SM, Puranik VG, Kaim W, Lahiri GK. Strong metal-metal coupling in mixed-valent intermediates [Cl(L)Ru(μ-tppz)Ru(L)Cl]+, L = β-diketonato ligands, tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. Dalton Transactions (Cambridge, England : 2003). 41: 13429-40. PMID 23007666 DOI: 10.1039/C2Dt31763J  0.651
2012 Das A, Scherer TM, Mondal P, Mobin SM, Kaim W, Lahiri GK. Experimental and DFT evidence for the fractional non-innocence of a β-diketonate ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 14434-43. PMID 23001725 DOI: 10.1002/Chem.201201785  0.394
2012 Roy S, Sarkar B, Imrich HG, Fiedler J, Záliš S, Jimenez-Aparicio R, Urbanos FA, Mobin SM, Lahiri GK, Kaim W. Charged, but found "not guilty": innocence of the suspect bridging ligands [RO(O)CNNC(O)OR]2- = L2- in [(acac)2Ru(μ-L)Ru(acac)2]n, n = +,0,-,2-. Inorganic Chemistry. 51: 9273-81. PMID 22908961 DOI: 10.1021/Ic300809W  0.66
2012 Das D, Scherer TM, Das A, Mondal TK, Mobin SM, Fiedler J, Priego JL, Jiménez-Aparicio R, Kaim W, Lahiri GK. The intricate paramagnetic state of [Os(Q)2(bpy)]+, Q = 4,6-di-tert-butyl-o-iminobenzoquinone. Dalton Transactions (Cambridge, England : 2003). 41: 11675-83. PMID 22874881 DOI: 10.1039/C2Dt30903C  0.423
2012 Das A, Scherer TM, Mobin SM, Kaim W, Lahiri GK. Application of a structure/oxidation-state correlation to complexes of bridging azo ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 11007-18. PMID 22837139 DOI: 10.1002/Chem.201201049  0.542
2012 Das AK, Hübner R, Sarkar B, Fiedler J, Záliš S, Lahiri GK, Kaim W. UV-vis-NIR and EPR characterisation of the redox series [MQ(3)](2+,+,0,-,2-), M = Ru or Os, and Q = o-quinone derivative. Dalton Transactions (Cambridge, England : 2003). 41: 8913-21. PMID 22710924 DOI: 10.1039/C2Dt30846K  0.646
2012 Ehret F, Bubrin M, Hübner R, Schweinfurth D, Hartenbach I, Záliš S, Kaim W. Filling gaps in the series of noninnocent hetero-1,3-diene chelate ligands: ruthenium complexes of redox-active α-azocarbonyl and α-azothiocarbonyl ligands RNNC(R')E, E = O or S. Inorganic Chemistry. 51: 6237-44. PMID 22594925 DOI: 10.1021/Ic300439H  0.469
2012 Das A, Scherer TM, Mobin SM, Kaim W, Lahiri GK. 9-Oxidophenalenone: a noninnocent β-diketonate ligand? Inorganic Chemistry. 51: 4390-7. PMID 22435485 DOI: 10.1021/Ic300207D  0.424
2012 Agarwala H, Scherer TM, Maji S, Mondal TK, Mobin SM, Fiedler J, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. Correspondence of Ru(III) Ru(II) and Ru(IV) Ru(III) mixed valent states in a small dinuclear complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 5667-75. PMID 22434480 DOI: 10.1002/Chem.201103618  0.473
2012 Kämper S, Paretzki A, Fiedler J, Záliš S, Kaim W. Solar cell sensitizer models [Ru(bpy-R)2(NCS)2] probed by spectroelectrochemistry. Inorganic Chemistry. 51: 2097-104. PMID 22320128 DOI: 10.1021/Ic201825H  0.501
2012 Das A, Scherer TM, Chowdhury AD, Mobin SM, Kaim W, Lahiri GK. Asymmetrical diruthenium complex bridged by a redox-active ligand. Inorganic Chemistry. 51: 1675-84. PMID 22251030 DOI: 10.1021/Ic201975H  0.503
2012 Roeser S, Ertem MZ, Cady C, Lomoth R, Benet-Buchholz J, Hammarström L, Sarkar B, Kaim W, Cramer CJ, Llobet A. Synthesis, structure, and electronic properties of RuN6 dinuclear Ru-Hbpp complexes. Inorganic Chemistry. 51: 320-7. PMID 22221281 DOI: 10.1021/Ic201668R  0.65
2012 Naklicki ML, Gorelsky SI, Kaim W, Sarkar B, Crutchley RJ. 1H NMR, electron paramagnetic resonance, and density functional theory study of dinuclear pentaammineruthenium dicyanamidobenzene complexes. Inorganic Chemistry. 51: 1400-7. PMID 22220947 DOI: 10.1021/Ic2016403  0.633
2012 Drozdz A, Bubrin M, Fiedler J, Záliš S, Kaim W. (α-Diimine)tricarbonylhalorhenium complexes: the oxidation side. Dalton Transactions (Cambridge, England : 2003). 41: 1013-9. PMID 22105557 DOI: 10.1039/C1Dt11449B  0.407
2012 Bubrin M, Krafft MJ, Steudle L, Hübner R, Field JS, Záliš S, Kaim W. Structural Reassessment of [W(CO)5(TCNE)]: N (σ) Coordination Instead of an Olefin (π) Complex Organometallics. 31: 6305-6311. DOI: 10.1021/Om300565Q  0.446
2012 Jana R, Schwederski B, Fiedler J, Kaim W. Facilitated reduction and oxidation of {[Ru(NH 3) 5] 4(μ 4-TCNX)} 8+ by changing from TCNX = TCNQ to TCNQF 4 Polyhedron. 44: 174-178. DOI: 10.1016/J.Poly.2012.06.066  0.478
2012 Hübner R, Sarkar B, Fiedler J, Záliš S, Kaim W. Metal(IV) complexes [M(L N,O,S) 2] n (M = Ru, Os) of a redox-active o-amidophenolate ligand (L N,O,S) 2- with coordinating thioether appendix European Journal of Inorganic Chemistry. 3569-3576. DOI: 10.1002/Ejic.201200225  0.62
2012 Kaim W. The Shrinking World of Innocent Ligands: Conventionaland Non-Conventional Redox-Active Ligands European Journal of Inorganic Chemistry. 2012: 343-348. DOI: 10.1002/Ejic.201101359  0.405
2012 Roduner E, Kaim W, Sarkar B, Urlacher VB, Pleiss J, Gläser R, Einicke W, Sprenger GA, Beifuß U, Klemm E, Liebner C, Hieronymus H, Hsu S, Plietker B, Laschat S. Selective Catalytic Oxidation of CH Bonds with Molecular Oxygen Chemcatchem. 5: 82-112. DOI: 10.1002/Cctc.201200266  0.517
2012 Wang D, Unold J, Bubrin M, Frey W, Kaim W, Buchmeiser MR. Ruthenium(IV)-Bis(methallyl) Complexes as UV-Latent Initiators for Ring-Opening Metathesis Polymerization Chemcatchem. 4: 1808-1812. DOI: 10.1002/Cctc.201200183  0.386
2011 Fekl U, Sarkar B, Kaim W, Zimmer-De Iuliis M, Nguyen N. Tuning of the spin distribution between ligand- and metal-based spin: electron paramagnetic resonance of mixed-ligand molybdenum tris(dithiolene) complex anions. Inorganic Chemistry. 50: 8685-7. PMID 21853970 DOI: 10.1021/Ic201047K  0.597
2011 Das D, Sarkar B, Kumbhakar D, Mondal TK, Mobin SM, Fiedler J, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. Bis(acetylacetonato)ruthenium complexes of noninnocent 1,2-dioxolene ligands: qualitatively different bonding in relation to monoimino and diimino analogues. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 11030-40. PMID 21853485 DOI: 10.1002/Chem.201101009  0.575
2011 Kaim W. Manifestations of noninnocent ligand behavior. Inorganic Chemistry. 50: 9752-65. PMID 21744793 DOI: 10.1021/Ic2003832  0.472
2011 Das A, Scherer T, Maji S, Mondal TK, Mobin SM, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. Reductive approach to mixed valency (n = 1-) in the pyrazine ligand-bridged [(acac)2Ru(μ-L(2-))Ru(acac)2](n) (L(2-) = 2,5-pyrazine-dicarboxylate) through experiment and theory. Inorganic Chemistry. 50: 7040-9. PMID 21714492 DOI: 10.1021/Ic200530U  0.489
2011 Das D, Sarkar B, Mondal TK, Mobin SM, Fiedler J, Kaim W, Lahiri GK. Oxidation state analysis of a four-component redox series [Os(pap)2(Q)]n involving two different non-innocent ligands on a redox-active transition metal. Inorganic Chemistry. 50: 7090-8. PMID 21699145 DOI: 10.1021/Ic200615S  0.595
2011 Pellegrino J, Hübner R, Doctorovich F, Kaim W. Spectroelectrochemical evidence for the nitrosyl redox siblings NO+, NO*, and NO- coordinated to a strongly electron-accepting Fe(II) porphyrin: DFT calculations suggest the presence of high-spin states after reduction of the Fe(II)-NO- complex. Chemistry (Weinheim An Der Bergstrasse, Germany). 17: 7868-74. PMID 21626580 DOI: 10.1002/Chem.201003516  0.451
2011 Kundu T, Sarkar B, Mondal TK, Mobin SM, Urbanos FA, Fiedler J, Jiménez-Aparicio R, Kaim W, Lahiri GK. Redox-rich spin-spin-coupled semiquinoneruthenium dimers with intense near-IR absorption. Inorganic Chemistry. 50: 4753-63. PMID 21517015 DOI: 10.1021/Ic102280Q  0.647
2011 Bulak E, Varnali T, Schwederski B, Sarkar B, Hartenbach I, Fiedler J, Kaim W. 2,3-Bis(1-methylimidazol-2-yl)quinoxaline (bmiq), a new ligand with decoupled electron transfer and metal coordination sites: the very different redox behaviour of isoelectronic complexes with [PtCl2] and [AuCl2]+. Dalton Transactions (Cambridge, England : 2003). 40: 2757-63. PMID 21298196 DOI: 10.1039/C0Dt01282C  0.659
2011 Schmidt R, Moya SA, Aguirre P, Fuentealba M, Leboschka M, Sieger M, Niemeyer M, Kaim W. Synthesis, Characterization and Structure of Tribromo(2-phenyl- 1,8-naphthyridine)gold(III) Zeitschrift FüR Naturforschung B. 66: 677-680. DOI: 10.5560/Znb.2011.66B0677  0.402
2011 Zhang F, Götz G, Mena-Osteritz E, Weil M, Sarkar B, Kaim W, Bäuerle P. Molecular and electronic structure of cyclo[10]thiophene in various oxidation states: polaron pair vs. bipolaron Chemical Science. 2: 781. DOI: 10.1039/C0Sc00560F  0.515
2011 Bulak E, Varnali T, Schwederski B, Bubrin D, Fiedler J, Kaim W. Separation of metal binding and electron transfer sites as a strategy to stabilize the ligand-reduced and metal-oxidized form of [Mo(CO)4L] Organometallics. 30: 6441-6445. DOI: 10.1021/Om2007858  0.458
2011 Hübner R, Weber S, Strobel S, Sarkar B, Záliš S, Kaim W. Reversible Intramolecular Single-Electron Oxidative Addition Involving a Hemilabile Noninnocent Ligand Organometallics. 30: 1414-1418. DOI: 10.1021/Om100969Q  0.618
2011 Prabhakaran R, Palaniappan K, Huang R, Sieger M, Kaim W, Viswanathamurthi P, Dallemer F, Natarajan K. Can geometry control the coordination behaviour of 2-hydroxy-1- naphthaldehyde-N(4)-phenylthiosemicarbazone? A study towards its origin Inorganica Chimica Acta. 376: 317-324. DOI: 10.1016/J.Ica.2011.06.045  0.395
2011 Mahmoud L, Gorelsky SI, Kaim W, Sarkar B, Crutchley RJ. EPR and 1H NMR spectroscopy and DFT study of pentaammineruthenium(III)phenylcyanamide complexes Inorganica Chimica Acta. 374: 147-151. DOI: 10.1016/J.Ica.2011.01.105  0.592
2011 Kaim W. Concepts for metal complex chromophores absorbing in the near infrared Coordination Chemistry Reviews. 255: 2503-2513. DOI: 10.1016/J.Ccr.2011.01.014  0.439
2011 Schnödt J, Sieger M, Sarkar B, Fiedler J, Manzur JS, Su CY, Kaim W. Copper(I) Chelation by Tetradentate NSSN Donor Ligands: Reversible Oxidation but no Oxygenation Zeitschrift Fur Anorganische Und Allgemeine Chemie. 637: 930-934. DOI: 10.1002/Zaac.201100026  0.705
2011 Schnödt J, Manzur J, García A, Hartenbach I, Su C, Fiedler J, Kaim W. Coordination of a Hemilabile N,N,S Donor Ligand in the Redox System [CuL2]+/2+, L = 2-Pyridyl-N-(2′-alkylthio­phenyl)methyleneimine European Journal of Inorganic Chemistry. 2011: 1436-1441. DOI: 10.1002/Ejic.201001183  0.563
2010 Van N, Tiritiris I, Winter RF, Sarkar B, Singh P, Duboc C, Muñoz-Castro A, Arratia-Pérez R, Kaim W, Schleid T. Oxidative perhydroxylation of [closo-B12H12]2- to the stable inorganic cluster redox system [B12(OH)12](2-/*-): experiment and theory. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 11242-5. PMID 20726020 DOI: 10.1002/Chem.201001374  0.477
2010 Kundu T, Sarkar B, Mondal TK, Fiedler J, Mobin SM, Kaim W, Lahiri GK. Carboxylate tolerance of the redox-active platform [Ru(mu-tppz)Ru](n), where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine, in the electron-transfer series [(L)ClRu(mu-tppz)RuCl(L)](n), n = 2+, +, 0, -, 2-, with 2-picolinato, quinaldato, and 8-quinolinecarboxylato ligands (L(-)). Inorganic Chemistry. 49: 6565-74. PMID 20557093 DOI: 10.1021/Ic100500P  0.653
2010 Mansell SM, Adams CJ, Bramham G, Haddow MF, Kaim W, Norman NC, McGrady JE, Russell CA, Udeen SJ. Synthesis and characterisation of the persistent radical [BCl2(bipy)]*. Chemical Communications (Cambridge, England). 46: 5070-2. PMID 20552129 DOI: 10.1039/C0Cc00187B  0.354
2010 Lahiri GK, Kaim W. Electronic structure alternatives in nitrosylruthenium complexes. Dalton Transactions (Cambridge, England : 2003). 39: 4471-8. PMID 20449468 DOI: 10.1039/C002173C  0.485
2010 Chauhan RS, Kedarnath G, Wadawale A, Muñoz-Castro A, Arratia-Perez R, Jain VK, Kaim W. Tellurium(0) as a ligand: synthesis and characterization of 2-pyridyltellurolates of platinum(II) and structures of [Pt{2-Te-3-(R)C5H3N}2Te(PR'3)] (R = H or Me). Inorganic Chemistry. 49: 4179-85. PMID 20369824 DOI: 10.1021/Ic902347S  0.382
2010 Sixt T, Sieger M, Krafft MJ, Bubrin D, Fiedler J, Kaim W. Ambi-Valence Taken Literally: Ruthenium vs Iron Oxidation in (1,1′-Diphosphinoferrocene)ruthenium(II) Hydride and Chloride Complexes as Deduced from Spectroelectrochemistry of the Heterodimetallic “Mixed-Valent” Intermediates† Organometallics. 29: 5511-5516. DOI: 10.1021/Om1004258  0.467
2010 Zhang J, Pan M, Yang R, She Z, Kaim W, Fan Z, Su C. Structure, biological and electrochemical studies of transition metal complexes from N,S,N′ donor ligand 8-(2-pyridinylmethylthio)quinoline Polyhedron. 29: 581-591. DOI: 10.1016/J.Poly.2009.07.024  0.589
2010 Kaim W, Sieger M, Greulich S, Sarkar B, Fiedler J, Záliš S. The 1,4-diazabutadiene/1,2-enediamido non-innocent ligand system in the formation of iridaheteroaromatic compounds: Spectroelectrochemistry and electronic structure Journal of Organometallic Chemistry. 695: 1052-1058. DOI: 10.1016/J.Jorganchem.2009.11.042  0.66
2010 Jana R, Sarkar B, Bubrin D, Fiedler J, Kaim W. Structure, electrochemistry and spectroscopy of a new diacylhydrazido-bridged diruthenium complex with a strongly near-infrared absorbing RuIIIRuII intermediate Inorganic Chemistry Communications. 13: 1160-1162. DOI: 10.1016/J.Inoche.2010.06.038  0.603
2010 Kumbhare LB, Wadawale AP, Jain VK, Sieger M, Kaim W. Binuclear rhodium(III) and iridium(III) monoselenocarboxylates: Synthesis, spectroscopy and structure of an ortho-metallated iridium complex featuring an IrCCC(μ-Se) chelate ring Inorganic Chemistry Communications. 13: 475-478. DOI: 10.1016/J.Inoche.2010.01.012  0.445
2010 Sarper O, Sarkar B, Fiedler J, Lissner F, Kaim W. Organoosmium complexes of imidazole-containing chelate acceptor ligands Inorganica Chimica Acta. 363: 3070-3077. DOI: 10.1016/J.Ica.2010.04.007  0.636
2010 Vergara MM, Posse MEG, Fagalde F, Katz NE, Fiedler J, Sarkar B, Sieger M, Kaim W. Mixed-valency with cyanides as terminal ligands: Diruthenium(III,II) complexes with the 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine bridge and variable co-ligands (CN− vs. bpy or NH3) Inorganica Chimica Acta. 363: 163-167. DOI: 10.1016/J.Ica.2009.09.018  0.63
2010 Záliš S, Winter RF, Kaim W. Quantum chemical interpretation of redox properties of ruthenium complexes with vinyl and TCNX type non-innocent ligands Coordination Chemistry Reviews. 254: 1383-1396. DOI: 10.1016/J.Ccr.2010.02.020  0.447
2010 Kaim W, Schwederski B. Non-innocent ligands in bioinorganic chemistry—An overview Coordination Chemistry Reviews. 254: 1580-1588. DOI: 10.1016/J.Ccr.2010.01.009  0.37
2010 Kaim W, Hosmane NS. Multidimensional potential of boron-containing molecules in functional materials Journal of Chemical Sciences. 122: 7-18. DOI: 10.1007/S12039-010-0008-9  0.3
2010 Rivas BL, Maureira A, Guzmán C, Contreras D, Kaim W, Geckeler KE. Poly(l-lysine) as a polychelatogen to remove toxic metals using ultrafiltration and bactericide properties of poly(l-lysine)–Cu2+ complexes Polymer Bulletin. 67: 763-774. DOI: 10.1007/S00289-010-0418-3  0.357
2010 Kavakli C, Schwederski B, Fiedler J, Gudat D, Kaim W. Ligand-based reduction in a molecular rectangle with four organplatinum(IV) vertices Zeitschrift Fur Anorganische Und Allgemeine Chemie. 636: 114-120. DOI: 10.1002/Zaac.200900445  0.431
2010 Schnödt J, Sieger M, Schleid T, Hartenbach I, Kaim W. Chelation and Bridging of Zinc(II) by Tetradentate N2S2Donor Ligands: Similarities and Differences to Copper(I) and Copper(II) Systems Zeitschrift FüR Anorganische Und Allgemeine Chemie. 636: 385-388. DOI: 10.1002/Zaac.200900373  0.474
2010 Hartenbach I, Strobel S, Schleid T, Sarkar B, Kaim W, Nockemann P, Binnemans K, Dorhout PK. Synthesis, structure, and spectroscopic properties of the new lanthanum(III) fluoride oxomolybdate(VI) la3FMo4O 16 European Journal of Inorganic Chemistry. 1626-1632. DOI: 10.1002/Ejic.200901052  0.547
2009 Kaim W, Fiedler J. Spectroelectrochemistry: the best of two worlds. Chemical Society Reviews. 38: 3373-82. PMID 20449056 DOI: 10.1039/B504286K  0.33
2009 Das D, Das AK, Sarkar B, Mondal TK, Mobin SM, Fiedler J, Zális S, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. The semiquinone-ruthenium combination as a remarkably invariant feature in the redox and substitution series [Ru(Q)(n)(acac)(3-n)](m), n = 1-3; m = (-2), -1, 0, +1, (+2); Q = 4,6-Di-tert-butyl-N-phenyl-o-iminobenzoquinone. Inorganic Chemistry. 48: 11853-64. PMID 19928984 DOI: 10.1021/Ic901900G  0.627
2009 Kaim W, Sarkar B. N(2) (.3-): filling a gap in the N(2) (n-) series. Angewandte Chemie (International Ed. in English). 48: 9409-11. PMID 19899178 DOI: 10.1002/Anie.200904968  0.497
2009 Kumbhakar D, Sarkar B, Das A, Das AK, Mobin SM, Fiedler J, Kaim W, Lahiri GK. Valence structures of the diastereomeric complexes meso- and rac-[Ru(2)(acac)(4)(mu-Q)](n) (n = 2-, 1-, 0, 1+, 2+) with the multiple quinonoid bridging ligand Q = 1,2,4,5-tetraimino-3,6-diketocyclohexane. Dalton Transactions (Cambridge, England : 2003). 9645-52. PMID 19859620 DOI: 10.1039/B906900C  0.63
2009 Chatterjee S, Singh P, Fiedler J, Baková R, Zális S, Kaim W, Goswami S. Effect of metal exchange (Os vs. Ru) and co-ligand variation (Cl(-)vs. acac(-)) on the oxidation state distribution in complexes of an o-phenylenediamido(2(-))/o-quinonediimine redox system. Dalton Transactions (Cambridge, England : 2003). 7778-85. PMID 19759953 DOI: 10.1039/B906913E  0.482
2009 Das AK, Sarkar B, Fiedler J, Zális S, Hartenbach I, Strobel S, Lahiri GK, Kaim W. A five-center redox system: molecular coupling of two noninnocent imino-o-benzoquinonato-ruthenium functions through a pi acceptor bridge. Journal of the American Chemical Society. 131: 8895-902. PMID 19505079 DOI: 10.1021/Ja901746X  0.636
2009 Roy S, Sarkar B, Duboc C, Fiedler J, Sarper O, Lissner F, Mobin SM, Lahiri GK, Kaim W. Heterohexanuclear (Cu3Fe3) complexes of substituted hexaazatrinaphthylene (HATN) ligands: twofold BF4(-) association in the solid and stepwise oxidation (3e) or reduction (2e) to spectroelectrochemically characterized species. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 6932-6939. PMID 19499557 DOI: 10.1002/Chem.200802655  0.641
2009 Das AK, Sarkar B, Duboc C, Strobel S, Fiedler J, Zális S, Lahiri GK, Kaim W. An odd-electron complex [Ru(k)(NO(m))(Q(n))(terpy)]2+ with two prototypical non-innocent ligands. Angewandte Chemie (International Ed. in English). 48: 4242-5. PMID 19431179 DOI: 10.1002/Anie.200900767  0.596
2009 Kaim W, Hosmane NS, Zális S, Maguire JA, Lipscomb WN. Boron atoms as spin carriers in two- and three-dimensional systems. Angewandte Chemie (International Ed. in English). 48: 5082-91. PMID 19338002 DOI: 10.1002/Anie.200803493  0.331
2009 De Candia AG, Singh P, Kaim W, Slep LD. All-trans-[ClRu(II)(py)4(NC)Ru(II)(py)4(CN)Ru(II)(py)4(NO)](PF6)4: a redox-active 2-donor/1-acceptor system based on the electrophilic {RuNO}6 motif. Inorganic Chemistry. 48: 565-73. PMID 19093847 DOI: 10.1021/Ic801347D  0.487
2009 Kowalski K, Linseis M, Winter RF, Zabel M, Záliš S, Kelm H, Krüger H, Sarkar B, Kaim W. Charge Delocalization in a Heterobimetallic Ferrocene−(Vinyl)Ru(CO)Cl(PiPr3)2System†† Dedicated to Prof. Dr. Helmut Werner on the occasion of his 75th birthday Organometallics. 28: 4196-4209. DOI: 10.1021/Om9002945  0.597
2009 Hosmane NS, Yinghuai Z, Maguire JA, Kaim W, Takagaki M. Nano and dendritic structured carboranes and metallacarboranes: From materials to cancer therapy Journal of Organometallic Chemistry. 694: 1690-1697. DOI: 10.1016/J.Jorganchem.2008.11.059  0.313
2009 Frantz S, Sieger M, Hartenbach I, Lissner F, Schleid T, Fiedler J, Duboc C, Kaim W. Structure, electrochemistry, spectroscopy, and magnetic resonance, including high-field EPR, of {(μ-abpy)[Re(CO)3X]2}o/•-, where abpy = 2,2′-azobispyridine and X = F, Cl, Br, I Journal of Organometallic Chemistry. 694: 1122-1133. DOI: 10.1016/J.Jorganchem.2008.09.034  0.397
2009 Záliš S, Sarkar B, Duboc C, Kaim W. Evidence for the dimer-of-(mixed-valent dimers) configuration in tetranuclear {(μ4-TCNX)[Ru(NH3)5] 4}8+, TCNX = TCNE and TCNQ, from DFT calculations Monatshefte Fur Chemie. 140: 765-773. DOI: 10.1007/S00706-009-0129-3  0.66
2009 Leboschka M, Sieger M, Sarkar B, Heck J, Niemeyer M, Bubrin D, Lissner F, Schleid T, Záliš S, Su C, Kaim W. 2-Organoselenomethyl-1H-benzimidazole Complexes of Copper(II) and Copper(I) Zeitschrift FüR Anorganische Und Allgemeine Chemie. 635: 2177-2184. DOI: 10.1002/Zaac.200900265  0.657
2009 Leboschka M, Sieger M, Sarkar B, Niemeyer M, Schurr T, Fiedler J, Záliš S, Kaim W. Silver(I), Copper(I) and Copper(II) Complex of the New N,Se-Chelate Ligand 2-Phenylselenomethyl-1H-benzimidazole: Electrochemistry and Structure Zeitschrift FüR Anorganische Und Allgemeine Chemie. 635: 1001-1007. DOI: 10.1002/Zaac.200900098  0.613
2009 De P, Sarkar B, Maji S, Das AK, Bulak E, Mobin SM, Kaim W, Lahiri GK. Stabilization of {RuNO}6 and {RuNO}7 States in [RuII(trpy)(bik)(NO)]n + {trpy = 2,2':6',2''-terpyridine, bik = 2,2'-bis(1-methylimidazolyl) ketone} - Formation, Reactivity, and Photorelease of Metal-Bound Nitrosyl European Journal of Inorganic Chemistry. 2009: 2702-2710. DOI: 10.1002/Ejic.200900021  0.606
2009 Das AK, Sarkar B, Duboc C, Strobel S, Fiedler J, Záliš S, Lahiri GK, Kaim W. An odd-electron complex [Ruk(NOm)(Q n)(terpy)]2+ with two prototypical non-innocent ligands Angewandte Chemie - International Edition. 48: 4242-4245. DOI: 10.1002/anie.200900767  0.315
2009 Kaim W, Sarkar B. N2.3−: eine Lücke in der N2n−-Reihe gefüllt Angewandte Chemie. 121: 9573-9575. DOI: 10.1002/Ange.200904968  0.491
2009 Das A, Sarkar B, Duboc C, Strobel S, Fiedler J, Záliš S, Lahiri G, Kaim W. Das ungeradzahlig elektronenkonfigurierte Komplexion [Ruk(NOm)(Qn)(terpy)]2+mit zwei idealtypischen “nicht-unschuldigen” Liganden Angewandte Chemie. 121: 4306-4309. DOI: 10.1002/Ange.200900767  0.434
2008 Kumbhakar D, Sarkar B, Maji S, Mobin SM, Fiedler J, Urbanos FA, Jiménez-Aparicio R, Kaim W, Lahiri GK. Intramolecular valence and spin interaction in meso and rac diastereomers of a p-quinonoid-bridged diruthenium complex. Journal of the American Chemical Society. 130: 17575-83. PMID 19053401 DOI: 10.1021/Ja807043S  0.614
2008 Roy S, Sarkar B, Bubrin D, Niemeyer M, Zális S, Lahiri GK, Kaim W. Stabilizing the elusive ortho-quinone/copper(I) oxidation state combination through pi/pi interaction in an isolated complex. Journal of the American Chemical Society. 130: 15230-1. PMID 18954055 DOI: 10.1021/Ja804429V  0.578
2008 Maity AN, Sarkar B, Niemeyer M, Sieger M, Duboc C, Zalis S, Kaim W. A tetranuclear organorhenium(i) complex of the 2,3,5,6-tetrafluoro-7,7,8,8-tetracyano-p-quinodimethane radical anion, TCNQF4 (-). Dalton Transactions (Cambridge, England : 2003). 5749-53. PMID 18941662 DOI: 10.1039/B807977C  0.656
2008 Ghumaan S, Sarkar B, Maji S, Puranik VG, Fiedler J, Urbanos FA, Jimenez-Aparicio R, Kaim W, Lahiri GK. Valence-state analysis through spectroelectrochemistry in a series of quinonoid-bridged diruthenium complexes [(acac)(2)Ru(mu-L)Ru(acac)(2)](n) (n=+2, +1, 0, -1, -2). Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 10816-28. PMID 18924186 DOI: 10.1002/Chem.200800976  0.68
2008 Singh P, Das AK, Sarkar B, Niemeyer M, Roncaroli F, Olabe JA, Fiedler J, Zális S, Kaim W. Redox properties of ruthenium nitrosyl porphyrin complexes with different axial ligation: structural, spectroelectrochemical (IR, UV-visible, and EPR), and theoretical studies. Inorganic Chemistry. 47: 7106-13. PMID 18646846 DOI: 10.1021/Ic702371T  0.637
2008 Roy S, Sieger M, Sarkar B, Schwederski B, Lissner F, Schleid T, Fiedler J, Kaim W. Establishing the chelating alpha-azocarbonyl function in pi-acceptor ligands. Angewandte Chemie (International Ed. in English). 47: 6192-4. PMID 18613190 DOI: 10.1002/Anie.200801328  0.512
2008 Maji S, Sarkar B, Mobin SM, Fiedler J, Urbanos FA, Jimenez-Aparicio R, Kaim W, Lahiri GK. Valence-state alternatives in diastereoisomeric complexes [(acac)2Ru(mu-QL)Ru(acac)2]n (QL2- = 1,4-dioxido-9,10-anthraquinone,n = +2, +1, 0, -1, -2). Inorganic Chemistry. 47: 5204-11. PMID 18491893 DOI: 10.1021/Ic800115Q  0.657
2008 Subat M, Woinaroschy K, Gerstl C, Sarkar B, Kaim W, König B. 1,4,7,10-tetraazacyclododecane metal complexes as potent promoters of phosphodiester hydrolysis under physiological conditions. Inorganic Chemistry. 47: 4661-8. PMID 18461925 DOI: 10.1021/ic702413q  0.534
2008 Maji S, Sarkar B, Patra M, Das AK, Mobin SM, Kaim W, Lahiri GK. Formation, reactivity, and photorelease of metal bound nitrosyl in [Ru(trpy)(L)(NO)](n+) (trpy = 2,2':6',2''-terpyridine, L = 2-phenylimidazo[4,5-f]1,10-phenanthroline). Inorganic Chemistry. 47: 3218-27. PMID 18311917 DOI: 10.1021/Ic702160W  0.613
2008 Khusniyarov MM, Harms K, Burghaus O, Sundermeyer J, Sarkar B, Kaim W, van Slageren J, Duboc C, Fiedler J. A series of metal complexes with the non-innocent N,N'-bis(pentafluorophenyl)-o-phenylenediamido ligand: twisted geometry for tuning the electronic structure. Dalton Transactions (Cambridge, England : 2003). 1355-65. PMID 18305848 DOI: 10.1039/B714974C  0.646
2008 Sarkar B, Patra S, Fiedler J, Sunoj RB, Janardanan D, Lahiri GK, Kaim W. Mixed-valent metals bridged by a radical ligand: Fact or fiction based on structure-oxidation state correlations Journal of the American Chemical Society. 130: 3532-3542. PMID 18290644 DOI: 10.1021/Ja077676F  0.681
2008 Singh P, Sieger M, Fiedler J, Su CY, Kaim W. Pseudo-base formation in the attempted synthesis of a conjugatively coupled bis(nitrosylruthenium) complex and spectroelectrochemistry of bipyrimidine-bridged dinuclear Ru(terpy)X precursor compounds (X = Cl, NO2). Dalton Transactions (Cambridge, England : 2003). 868-73. PMID 18259618 DOI: 10.1039/B716307J  0.63
2008 Samanta S, Singh P, Fiedler J, Zális S, Kaim W, Goswami S. Singlet diradical complexes of ruthenium and osmium: geometrical and electronic structures and their unexpected changes on oxidation. Inorganic Chemistry. 47: 1625-33. PMID 18247559 DOI: 10.1021/Ic702301A  0.512
2008 Maurer J, Linseis M, Sarkar B, Schwederski B, Niemeyer M, Kaim W, Zalis S, Anson C, Zabel M, Winter RF. Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: a case of non-innocence in organometallic chemistry. Journal of the American Chemical Society. 130: 259-68. PMID 18072771 DOI: 10.1021/Ja075547T  0.627
2008 KAIM W. METAL COMPOUNDS OF THE TCNX REDOX SYSTEMS -FROM ELECTRON TRANSFER TO SPIN DISTRIBUTION AND MAGNETISM Journal of the Chilean Chemical Society. 53. DOI: 10.4067/S0717-97072008000100002  0.439
2008 Khusniyarov MM, Harms K, Burghaus O, Sundermeyer J, Sarkar B, Kaim W, Van Slageren J, Duboc C, Fiedler J. A series of metal complexes with the non-innocent N,N′- bis(pentafluorophenyl)-o-phenylenediamido ligand: Twisted geometry for tuning the electronic structure Dalton Transactions. 1355-1365. DOI: 10.1039/b714974c  0.362
2008 Linseis M, Winter RF, Sarkar B, Kaim W, Záliš S. Ligand-Centered Oxidations and Electron Delocalization in a Tetranuclear Complex of a Tetradonor-Substituted Olefin Organometallics. 27: 3321-3324. DOI: 10.1021/Om8003338  0.624
2008 Das AK, Bulak E, Sarkar B, Lissner F, Schleid T, Niemeyer M, Fiedler J, Kaim W. Structures and Redox Properties of Metal Complexes of the Electron-Deficient Diphosphine Chelate LigandR,R-QuinoxP Organometallics. 27: 218-223. DOI: 10.1021/Om700755Y  0.625
2008 Sarkar B, Frantz S, Roy S, Sieger M, Duboc C, Denninger G, Kümmerer HJ, Kaim W. High-frequency EPR and structural data as complementary information on stable radical complexes containing the semi-reduced azo function Journal of Molecular Structure. 890: 133-138. DOI: 10.1016/J.Molstruc.2008.04.048  0.668
2008 Sarkar B, Schurr T, Hartenbach I, Schleid T, Fiedler J, Kaim W. Double cyclometallation of bridging 3,6-bis(2-thienyl)-1,2,4,5-tetrazine in a dinuclear mesityl(dimethylsulfoxide)platinum(II) complex: Structure and properties Journal of Organometallic Chemistry. 693: 1703-1706. DOI: 10.1016/J.Jorganchem.2007.10.045  0.609
2008 Roy S, Sieger M, Singh P, Niemeyer M, Fiedler J, Duboc C, Kaim W. A radical-bridged bis(ferrocenylcopper(I)) complex: Structural identity, multifrequency EPR, and spectroelectrochemistry Inorganica Chimica Acta. 361: 1699-1704. DOI: 10.1016/J.Ica.2007.02.006  0.46
2008 Dogan A, Kavakli C, Sieger M, Niemeyer M, Sarkar B, Kaim W. Structural and Spectroscopic Evidence for Marginal Metal-to-Ligand Charge Transfer in Complexes Pt(abpy)Me3X, abpy = 2,2′-Azobispyridine, X = Cl, Br, I Zeitschrift FüR Anorganische Und Allgemeine Chemie. 634: 2527-2531. DOI: 10.1002/Zaac.200800353  0.586
2008 Leboschka M, Sieger M, Niemeyer M, Záliš S, Kaim W. Dimerization of the 2-(Methylselenomethyl)benzimidazole-silver(I) Cation Involving a AgI-AgIInteraction Zeitschrift FüR Anorganische Und Allgemeine Chemie. 634: 2343-2346. DOI: 10.1002/Zaac.200800283  0.304
2008 Roy S, Sieger M, Sarkar B, Schwederski B, Lissner F, Schleid T, Fiedler J, Kaim W. Etablierung der chelatbildenden α-Azocarbonyl-Funktion in π-Akzeptor-Liganden Angewandte Chemie. 120: 6287-6289. DOI: 10.1002/Ange.200801328  0.455
2007 Maurer J, Sarkar B, Kaim W, Winter RF, Zális S. Towards new organometallic wires: tetraruthenium complexes bridged by phenylenevinylene and vinylpyridine ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 10257-72. PMID 17937381 DOI: 10.1002/Chem.200700459  0.553
2007 Singh P, Fiedler J, Záliš S, Duboc C, Niemeyer M, Lissner F, Schleid T, Kaim W. Spectroelectrochemistry and DFT analysis of a new {RuNO}n redox system with multifrequency EPR suggesting conformational isomerism in the {RuNO}7 state Inorganic Chemistry. 46: 9254-9261. PMID 17900185 DOI: 10.1021/Ic701206A  0.511
2007 Sanyal A, Chatterjee S, Castiñeiras A, Sarkar B, Singh P, Fiedler J, Zális S, Kaim W, Goswami S. Singlet diradical complexes of chromium, molybdenum, and tungsten with azo anion radical ligands from M(CO)6 precursors. Inorganic Chemistry. 46: 8584-93. PMID 17887746 DOI: 10.1021/Ic700584X  0.57
2007 Maji S, Sarkar B, Mobin SM, Fiedler J, Kaim W, Lahiri GK. Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A2Ru(mu-L)RuA2]n, A = 2,4-pentanedionato or 2-phenylazopyridine, L(2-) = 2,5-bis(2-oxidophenyl)pyrazine. Dalton Transactions (Cambridge, England : 2003). 2411-8. PMID 17844663 DOI: 10.1039/B701511A  0.676
2007 Kar S, Sarkar B, Ghumaan S, Leboschka M, Fiedler J, Kaim W, Lahiri GK. Ancillary ligand determination of the spin location in both oxidised and reduced forms of diruthenium complexes bridged by bis-bidentate 1,4-bis(2-phenolato)-1,4-diazabutadiene. Dalton Transactions (Cambridge, England : 2003). 1934-8. PMID 17702173 DOI: 10.1039/B617468J  0.785
2007 Maity AN, Schwederski B, Sarkar B, Zális S, Fiedler J, Kar S, Lahiri GK, Duboc C, Grunert M, Gütlich P, Kaim W. Tetranuclear complexes of [Fe(CO)2(C5H5)]+ with TCNX ligands (TCNX=TCNE, TCNQ, TCNB): intramolecular electron transfer alternatives in compounds (mu4-TCNX)[MLn]4. Inorganic Chemistry. 46: 7312-20. PMID 17691765 DOI: 10.1021/Ic062253K  0.776
2007 Contreras D, Rodríguez J, Freer J, Schwederski B, Kaim W. Enhanced hydroxyl radical production by dihydroxybenzene-driven Fenton reactions: implications for wood biodegradation. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 12: 1055-61. PMID 17636352 DOI: 10.1007/S00775-007-0274-2  0.351
2007 Bulak E, Leboschka M, Schwederski B, Sarper O, Varnali T, Fiedler J, Lissner F, Schleid T, Kaim W. Reversibly reducible cis-dichloroplatinum(II) and cis-dichloropalladium(II) complexes of bis(1-methylimidazol-2-yl)glyoxal. Inorganic Chemistry. 46: 5562-6. PMID 17571882 DOI: 10.1021/Ic070185B  0.486
2007 Koley M, Sarkar B, Ghumaan S, Bulak E, Fiedler J, Kaim W, Lahiri GK. Probing mixed valence in a new tppz-bridged diruthenium(III,II) complex {(mu-tppz)[Ru(bik)Cl]2}3+ (tppz=2,3,5,6-tetrakis(2-pyridyl)pyrazine, bik=2,2'-bis(1-methylimidazolyl)ketone): EPR silence, intervalence absorption, and nu(CO) line broadening. Inorganic Chemistry. 46: 3736-42. PMID 17388585 DOI: 10.1021/Ic0700102  0.642
2007 Kaim W, Lahiri GK. Unconventional mixed-valent complexes of ruthenium and osmium. Angewandte Chemie (International Ed. in English). 46: 1778-96. PMID 17323423 DOI: 10.1002/Anie.200602737  0.464
2007 Videla M, Jacinto JS, Baggio R, Garland MT, Singh P, Kaim W, Slep LD, Olabe JA. New ruthenium nitrosyl complexes with tris(1-pyrazolyl)methane (tpm) and 2,2'-bipyridine (bpy) coligands. Structure, spectroscopy, and electrophilic and nucleophilic reactivities of bound nitrosyl. Inorganic Chemistry. 45: 8608-17. PMID 17029371 DOI: 10.1021/Ic061062E  0.536
2007 Singh P, Sarkar B, Sieger M, Niemeyer M, Fiedler J, Zális S, Kaim W. The metal-NO interaction in the redox systems [Cl5Os(NO)]n-, n = 1-3, and cis-[(bpy)2ClOs(NO)]2+/+: calculations, structural, electrochemical, and spectroscopic results. Inorganic Chemistry. 45: 4602-9. PMID 16749822 DOI: 10.1021/Ic0517669  0.628
2007 Záliš S, Kaim W. Electronic structures of two kinds of oligoborane radical anions: mixed-valence description of a reducedp-phenylenediborane and spin density distributions in distorted octahedral clusters [B6Hal6]•−, Hal = Cl, Br, I Main Group Chemistry. 5: 267-276. DOI: 10.1080/10241220701562169  0.371
2007 Maji S, Sarkar B, Mobin SM, Fiedler J, Kaim W, Lahiri GK. Non-innocent behaviour of ancillary and bridging ligands in homovalent and mixed-valent ruthenium complexes [A2Ru(-L)RuA2] n, A = 2,4-pentanedionato or 2-phenylazopyridine, L2- = 2,5-bis(2-oxidophenyl)pyrazine Dalton Transactions. 2411-2418. DOI: 10.1039/b701511a  0.434
2007 Ghumaan S, Sarkar B, Patil MP, Fiedler J, Sunoj RB, Kaim W, Lahiri GK. Multiple one-electron oxidation and reduction of trinuclear bis(2,4-pentanedionato)ruthenium complexes with substituted diquinoxalino[2,3-a:2′,3′-c]phenazine ligands Polyhedron. 26: 3409-3418. DOI: 10.1016/J.Poly.2007.03.030  0.632
2007 Kavakli C, Gabrielsson A, Sieger M, Schwederski B, Niemeyer M, Kaim W. Reversible radical complex formation of an organometallic diplatinum(IV) compound Journal of Organometallic Chemistry. 692: 3151-3155. DOI: 10.1016/J.Jorganchem.2007.01.017  0.492
2007 Kaim W, Sarkar B. Mixed valency in ruthenium complexes—Coordinative aspects Coordination Chemistry Reviews. 251: 584-594. DOI: 10.1016/J.Ccr.2006.06.003  0.623
2007 Manzur J, Vega A, García AM, Acuña C, Sieger M, Sarkar B, Niemeyer M, Lissner F, Schleid T, Kaim W. Coordination Alternatives in Dinuclear Bis(pyridin-2-ylalkyl)benzylaminecopper(II) Complexes with OH–, RO–, F–, or Cl– Bridges: Experimental Structures and DFT Preferences European Journal of Inorganic Chemistry. 2007: 5500-5510. DOI: 10.1002/Ejic.200700637  0.593
2006 Gabrielsson A, van Leeuwen P, Kaim W. Acidic iridium hydrides: implications for aerobic and Oppenauer oxidation of alcohols. Chemical Communications (Cambridge, England). 4926-7. PMID 17136249 DOI: 10.1039/B610857A  0.324
2006 Ghumaan S, Sarkar B, Chanda N, Sieger M, Fiedler J, Kaim W, Lahiri GK. 2,2'-Dipyridylketone (dpk) as ancillary acceptor and reporter ligand in complexes [(dpk)(Cl)Ru(mu-tppz)Ru(Cl)(dpk)]n+ where tppz = 2,3,5,6-tetrakis(2-pyridyl)pyrazine. Inorganic Chemistry. 45: 7955-61. PMID 16961390 DOI: 10.1021/Ic060887L  0.656
2006 Moorlag C, Sarkar B, Sanrame CN, Bäuerle P, Kaim W, Wolf MO. Conjugation length dependent ground and excited state electronic behavior in oligothienyl Ru complexes Inorganic Chemistry. 45: 7044-7046. PMID 16933899 DOI: 10.1021/Ic060912N  0.641
2006 Maji S, Sarkar B, Patra S, Fiedler J, Mobin SM, Puranik VG, Kaim W, Lahiri GK. Metal-induced reductive ring opening of 1,2,4,5-tetrazines: three resulting coordination alternatives, including the new non-innocent 1,2-diiminohydrazido(2-) bridging ligand system. Inorganic Chemistry. 45: 1316-25. PMID 16441144 DOI: 10.1021/Ic051532P  0.588
2006 Sarper O, Bulak E, Kaim W, Varnali T. Modelling bis-(1-methylimidazol-2-yl)glyoxal, ‘big’, in complex ions [M(big)2]+n, M=Au, Pt, Cu, Re, Zn: a DFT study Molecular Physics. 104: 833-838. DOI: 10.1080/00268970500417432  0.382
2006 Maurer J, Sarkar B, Schwederski B, Kaim W, Winter RF, Záliš S. Divinylphenylene-Bridged Diruthenium Complexes Bearing Ru(CO)Cl(PiPr3)2Entities† Organometallics. 25: 3701-3712. DOI: 10.1021/Om0602660  0.641
2006 Sarper O, Bulak E, Kaim W, Varnali T. A DFT based assessment of coordination modes of the bis(1-methyl-2-imidazolyl)glyoxal ligand in mononuclear and dinuclear complexes Journal of Molecular Structure: Theochem. 773: 35-42. DOI: 10.1016/J.Theochem.2006.06.039  0.477
2006 Bulak E, Sarper O, Dogan A, Lissner F, Schleid T, Kaim W. Dichlorogold(III) complexes of bis(1-methyl-2-imidazolyl)ketone and related ligands: Geometrical and electronic structures Polyhedron. 25: 2577-2582. DOI: 10.1016/J.Poly.2006.03.008  0.474
2006 Dey S, Jain VK, Varghese B, Schurr T, Niemeyer M, Kaim W, Butcher RJ. 3-Dimethylaminopropyl chalcogenolate complexes of palladium(II): Syntheses and characterization, including the crystal structures of [Pd(OAc)(ECH2CH2CH2NMe2)]2·H2O (E=S, Se) and [PdCl(TeCH2CH2CH2NMe2)]2 Inorganica Chimica Acta. 359: 1449-1457. DOI: 10.1016/J.Ica.2005.09.019  0.353
2006 Heilmann M, Frantz S, Kaim W, Fiedler J, Duboc C. Mixed-valent and radical states of complexes [(bpy)2M(μ-abpy) M′(bpy)2]n+, M,M′ = Ru or Os, abpy = 2,2′-azobispyridine: Electron transfer vs. hole transfer mechanism in azo ligand-bridged complexes Inorganica Chimica Acta. 359: 821-829. DOI: 10.1016/J.Ica.2005.04.044  0.496
2005 Kar S, Sarkar B, Ghumaan S, Roy D, Urbanos FA, Fiedler J, Sunoj RB, Jimenez-Aparicio R, Kaim W, Lahiri GK. A new coordination mode of the photometric reagent glyoxalbis(2-hydroxyanil) (H2gbha): bis-bidentate bridging by gbha2- in the redox series [(mu-gbha)[Ru(acac)2]2]n (n = -2, -1, 0, +1, +2), including a radical-bridged diruthenium(III) and a Ru(III)/Ru(IV) intermediate. Inorganic Chemistry. 44: 8715-22. PMID 16296825 DOI: 10.1021/Ic050950R  0.795
2005 Patra S, Sarkar B, Maji S, Fiedler J, Urbanos FA, Jimenez-Aparicio R, Kaim W, Lahiri GK. Controlling metal-ligand-metal oxidation state combinations by ancillary ligand (L) variation in the redox systems [L2Ru(mu-boptz)RuL2]n, boptz = 3,6-bis(2-oxidophenyl)-1,2,4,5-tetrazine, and L = acetylacetonate, 2,2'-bipyridine, or 2-phenylazopyridine. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 489-98. PMID 16134203 DOI: 10.1002/Chem.200500295  0.669
2005 Sarkar S, Sarkar B, Chanda N, Kar S, Mobin SM, Fiedler J, Kaim W, Lahiri GK. Complex series [Ru(tpy)(dpk)(X)]n+ (tpy = 2,2':6',2''-terpyridine; dpk = 2,2'-dipyridyl ketone; X = Cl-, CH3CN, NO2(-), NO+, NO*, NO-): substitution and electron transfer, structure, and spectroscopy. Inorganic Chemistry. 44: 6092-9. PMID 16097830 DOI: 10.1021/Ic050533E  0.796
2005 Sarkar B, Patra S, Fiedler J, Sunoj RB, Janardanan D, Mobin SM, Niemeyer M, Lahiri GK, Kaim W. Theoretical and experimental evidence for a new kind of spin-coupled singlet species: isomeric mixed-valent complexes bridged by a radical anion ligand. Angewandte Chemie (International Ed. in English). 44: 5655-8. PMID 16078282 DOI: 10.1002/Anie.200501075  0.646
2005 Das N, Arif AM, Stang PJ, Sieger M, Sarkar B, Kaim W, Fiedler J. Self-assembly of heterobimetallic neutral macrocycles incorporating ferrocene spacer groups: spectroelectrochemical analysis of the double two-electron oxidation of a molecular rectangle. Inorganic Chemistry. 44: 5798-804. PMID 16060632 DOI: 10.1021/Ic0481834  0.582
2005 Sieger M, Vogler C, Klein A, Knödler A, Wanner M, Fiedler J, Zális S, Snoeck TL, Kaim W. Geometrical and electronic structures of dinuclear complex ions {(mu-bpym)[Cu(EAr3)2]2}2+ with intramolecular "organic sandwich" formation (E = P or As; Ar = Aryl; bpym = 2,2'-bipyrimidine). Inorganic Chemistry. 44: 4637-43. PMID 15962972 DOI: 10.1021/Ic050207Z  0.708
2005 Kar S, Sarkar B, Ghumaan S, Janardanan D, van Slageren J, Fiedler J, Puranik VG, Sunoj RB, Kaim W, Lahiri GK. 2,5-Dioxido-1,4-benzoquinonediimine (H2L2-), a hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: different oxidation state distributions in complexes [{(bpy)2Ru}2(mu-H2L)]n (n=0,+,2+,3+,4+) and [{(acac)2Ru}2(mu-H2L)]m (m=2-,-,0,+,2+). Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 4901-11. PMID 15954152 DOI: 10.1002/Chem.200500202  0.792
2005 Ghumaan S, Sarkar B, Patra S, van Slageren J, Fiedler J, Kaim W, Lahiri GK. Sensitive oxidation state ambivalence in unsymmetrical three-center (M/Q/M) systems [(acac)2 Ru(mu-Q)Ru(acac)2](n), Q = 1,10-phenanthroline-5,6-dione or 1,10-phenanthroline-5,6-diimine (n = +, 0, -, 2-). Inorganic Chemistry. 44: 3210-4. PMID 15847429 DOI: 10.1021/Ic048309X  0.592
2005 Ye S, Sarkar B, Duboc C, Fiedler J, Kaim W. The redox series [M(bpy)2(q)]n+, M = Ru or Os, Q = 3,5-di-tert-butyl-n-phenyl-1,2-benzoquinonemonoimine. Isolation and a complete X and W band EPR study of the semiquinone states (n = 1). Inorganic Chemistry. 44: 2843-7. PMID 15819573 DOI: 10.1021/Ic048407I  0.755
2005 Patra S, Sarkar B, Ghumaan S, Patil MP, Mobin SM, Sunoj RB, Kaim W, Lahiri GK. Isomeric ruthenium terpyridine complexes [Ru(trpy)(L)Cl]n+ containing the unsymmetrically bidentate acceptor L=3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine. Synthesis, structures, electrochemistry, spectroscopy and DFT calculations. Dalton Transactions (Cambridge, England : 2003). 1188-94. PMID 15782253 DOI: 10.1039/B500152H  0.647
2005 Ye S, Sarkar B, Lissner F, Schleid T, van Slageren J, Fiedler J, Kaim W. Three-spin system with a twist: a bis(semiquinonato)copper complex with a nonplanar configuration at the copper(II) center. Angewandte Chemie (International Ed. in English). 44: 2103-6. PMID 15723422 DOI: 10.1002/Anie.200462339  0.719
2005 Ghumaan S, Sarkar B, Patra S, Parimal K, van Slageren J, Fiedler J, Kaim W, Lahiri GK. 3,6-bis(2'-pyridyl)pyridazine (L) and its deprotonated form (L - H+)- as ligands for {(acac)2Ru(n+)} or {(bpy)2Ru(m+)}: investigation of mixed valency in [{(acac)2Ru}2(mu-L - H+)]0 and [{(bpy)2Ru}2(mu-L - H+)]4+ by spectroelectrochemistry and EPR. Dalton Transactions (Cambridge, England : 2003). 706-12. PMID 15702181 DOI: 10.1039/B417530A  0.64
2005 Kaim W. Chemistry. Odd electron on nitrogen: a metal-stabilized aminyl radical. Science (New York, N.Y.). 307: 216-7. PMID 15653492 DOI: 10.1126/Science.1107345  0.398
2005 Klein A, Schurr T, Knödler A, Gudat D, Klinkhammer KW, Jain VK, Záliš S, Kaim W. Multiple isomerism (cis/trans; syn/anti) in [(dmso) 2Pt(aryl)2] complexes: A combined structural, spectroscopic, and theoretical investigation Organometallics. 24: 4125-4131. DOI: 10.1021/Om050076+  0.44
2005 Ye S, Kaim W, Niemeyer M, Hosmane NS. Stereospecific intramolecular S→Pt transmethylation from 8-(Methylthio)quinoline to coordinated PtMe 2: Formation of 8yn-[fac-Pt IVMe 3(μ-8-quinolinethiolato)] 2 with stacked quinoline rings Organometallics. 24: 794-796. DOI: 10.1021/Om049247L  0.367
2005 Baumann F, Kaim W, Denninger G, Kümmerer H, Fiedler J. Widely Separated Reduction Processes of abpy-Coupled Areneosmium(II) Reaction Centers (abpy = 2,2‘-Azobispyridine):  Stabilization of the Radical Intermediate and of the Os0OsIIState Organometallics. 24: 1966-1973. DOI: 10.1021/Om049085T  0.375
2005 Tomlinson S, Zheng C, Hosmane NS, Yang J, Wang Y, Zhang H, Gray TG, Demissie T, Maguire JA, Baumann F, Klein A, Sarkar B, Kaim W, Lipscomb WN. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 31. New insights into reaction pathways of carborane ligand systems: Synthetic, structural, spectroscopic, and electrochemical studies on sandwich and half-sandwich metallacarboranes of iron, cobalt, and nickel Organometallics. 24: 2177-2187. DOI: 10.1021/Om048982U  0.564
2005 Nayak A, Patra S, Sarkar B, Ghumaan S, Puranik VG, Kaim W, Lahiri GK. Tetrazine derived mononuclear RuII(acac)2(L) (1), [RuII(bpy)2(L)](ClO4)2 (2) and [RuII(bpy)(L)2](ClO4)2 (3) (L = 3-amino-6-(3,5-dimethylpyrazol-1-yl)-1,2,4,5-tetrazine, acac = acetylacetonate, bpy = 2,2′-bipyridine): Syntheses, structures, spectra and redox properties Polyhedron. 24: 333-342. DOI: 10.1016/J.Poly.2004.11.019  0.563
2005 Maity AN, Schwederski B, Kaim W. The redox pair {(μ4-TCNE)[Fe(CO)2(C5H5)]4}4+/3+: Surprisingly small metal–ligand interaction and the first resolved EPR hyperfine structure (13C,14N,57Fe) of a tetranuclear complex with TCNE− Inorganic Chemistry Communications. 8: 600-602. DOI: 10.1016/J.Inoche.2005.03.026  0.383
2005 Phadnis PP, Jain VK, Schurr T, Klein A, Lissner F, Schleid T, Kaim W. Synthesis, spectroscopy, structure and photophysical properties of dinaphthylmethylarsine complexes of palladium(II) and platinum(II) Inorganica Chimica Acta. 358: 2609-2617. DOI: 10.1016/J.Ica.2005.03.026  0.412
2005 Kaim W, Titze C, Schurr T, Sieger M, Lawson M, Jordanov J, Rojas D, García AM, Manzur J. Reactivity of Copper(I) Complexes with Tripodal Ligands towards O2: Structures of a Precursor [L3CuI(NCCH3)](BF4), L3 = Tris(3-isopropyl-4,5-trimethylenepyrazolyl)methane and of its Oxidation Product [L3CuII(μ-OH)2CuIIL3](BF4)2 with Strong Antiferromagnetic Spin-Spin Coupling Zeitschrift FüR Anorganische Und Allgemeine Chemie. 631: 2568-2574. DOI: 10.1002/Zaac.200500053  0.419
2005 Kaim W, Dogan A, Klein A, Záliš S. Complexes of 1,3-Bis(diphenylphosphano)propane (dppp) with Dichloroplatinum(II) and Bis(chlorogold(I)): Intramolecular versus Intermolecular AuI-AuI Association of [(μ-dppp)(AuCl)2] incatena andcyclo Forms Zeitschrift FüR Anorganische Und Allgemeine Chemie. 631: 1355-1358. DOI: 10.1002/Zaac.200400514  0.388
2005 Stange A, Schurr T, Klein A, Kaim W. Kupferkomplexe des neuen Chelatliganden 1-Methyl-2-(2-thiophenolato)-1H-benzimidazol (mtpb) und dessen Oxidationsprodukten Zeitschrift F�R Anorganische Und Allgemeine Chemie. 631: 663-671. DOI: 10.1002/Zaac.200400343  0.339
2005 Kn�dler A, Kaim W. Cis/trans-Isomerie von [RuCl2(S-dmso)(tpy)] Komplexen, tpy = Terpyridin-Ligand Zeitschrift F�R Anorganische Und Allgemeine Chemie. 631: 491-495. DOI: 10.1002/Zaac.200400330  0.427
2005 Ye S, Sarkar B, Niemeyer M, Kaim W. Mixed-Ligand Copper Complexes with 8-Methylthioquinoline and Triphenylphosphane or theo-Semiquinone/Catecholate Redox System European Journal of Inorganic Chemistry. 2005: 4735-4738. DOI: 10.1002/Ejic.200500567  0.622
2005 Kar S, Sarkar B, Ghumaan S, Janardanan D, Van Slageren J, Fiedler J, Puranik VG, Sunoj RB, Kaim W, Lahiri GK. 2,5-dioxido-1,4-benzoquinonediimine (H2L2 ), A hydrogen-bonding noninnocent bridging ligand related to aminated topaquinone: Different oxidation state distributions in complexes [{(bpy)2Ru} 2(μ-H2L)]n (n = 0, + ,2 + ,3 + ,4+) and [{(acac)2Ru}2(μ-H2L)]m (m = 2-, -,0, + ,2 + ) Chemistry - a European Journal. 11: 4901-4911. DOI: 10.1002/chem.200500202  0.685
2005 Sarkar B, Patra S, Fiedler J, Sunoj RB, Janardanan D, Mobin SM, Niemeyer M, Lahiri GK, Kaim W. Theoretische und experimentelle Hinweise auf einen neuen Typ spingekoppelter Singulett-Spezies: isomere gemischtvalente Komplexe mit verbrückendem Radikalanion-Liganden Angewandte Chemie. 117: 5800-5803. DOI: 10.1002/Ange.200501075  0.486
2005 Ye S, Sarkar B, Lissner F, Schleid T, Slageren Jv, Fiedler J, Kaim W. Dreispinsystem mit neuer Wendung: ein Bis(semichinonato)kupfer‐Komplex mit nichtplanarer Konfiguration am Kupfer(II)‐Zentrum Angewandte Chemie. 117: 2140-2143. DOI: 10.1002/Ange.200462339  0.526
2004 Sieger M, Kaim W, Stufkens DJ, Snoeck TL, Stoll H, Zalis S. Reduced and excited states of the intermediates (alpha-diimine)(C5R5)Rh in hydride transfer catalysis schemes: EPR and resonance Raman spectroscopy, and comparative DFT calculations of Co, Rh and Ir analogues. Dalton Transactions (Cambridge, England : 2003). 3815-21. PMID 15540123 DOI: 10.1039/B411892H  0.606
2004 Sarkar B, Kaim W, Fiedler J, Duboc C. Molecule-bridged mixed-valent intermediates involving the Ru I oxidation state. Journal of the American Chemical Society. 126: 14706-7. PMID 15535680 DOI: 10.1021/Ja046397E  0.641
2004 Sarkar B, Frantz S, Kaim W, Duboc C. High-frequency EPR study of reduced diruthenium and dirhenium polypyridine complexes based on the 1,2,4,5-tetrazine radical bridge. Dalton Transactions (Cambridge, England : 2003). 3727-31. PMID 15510299 DOI: 10.1039/B407611G  0.65
2004 Sieger M, Sarkar B, Zalis S, Fiedler J, Escola N, Doctorovich F, Olabe JA, Kaim W. Establishing the NO oxidation state in complexes [Cl(5)(NO)M](n-), M = Ru or Ir, through experiments and DFT calculations. Dalton Transactions (Cambridge, England : 2003). 1797-800. PMID 15381982 DOI: 10.1039/B404121F  0.62
2004 Patra S, Sarkar B, Ghumaan S, Fiedler J, Kaim W, Lahiri GK. Isovalent and mixed-valent diruthenium complexes [(acac)2RuII (-bpytz)RuII(acac)2] and [(acac)2RuII(-bpytz)RuIII(acac)2](ClO4) (acac = acetylacetonate and bpytz = 3,6-bis(3,5-dimethylpyrazolyl)-1,2,4,5-tetrazine): synthesis, spectroelectrochemical, and epr investigation . Inorganic Chemistry. 43: 6108-13. PMID 15360263 DOI: 10.1021/Ic049346R  0.656
2004 Dogan A, Sarkar B, Klein A, Lissner F, Schleid T, Fiedler J, Zális S, Jain VK, Kaim W. Complex reduction chemistry of (abpy)PtCl2, abpy = 2,2'-azobispyridine: formation of cyclic [(micro,eta2:eta1-abpy)PtCl]2(2+) with a new coordination mode for abpy and a near-infrared ligand-to-ligand intervalence charge transfer absorption of the one-electron reduced state. Inorganic Chemistry. 43: 5973-80. PMID 15360246 DOI: 10.1021/Ic049941T  0.778
2004 Gudat D, Dogan A, Kaim W, Klein A. Multinuclear NMR study of some organoplatinum complexes containing multifunctional azines as chelating ligands. Magnetic Resonance in Chemistry : Mrc. 42: 781-7. PMID 15307061 DOI: 10.1002/Mrc.1407  0.704
2004 Chanda N, Sarkar B, Kar S, Fiedler J, Kaim W, Lahiri GK. Mixed valence aspects of diruthenium complexes [((L)ClRu)2(mu-tppz)]n+ incorporating 2-(2-pyridyl)azoles (L) as ancillary functions and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (Tppz) as bis-tridentate bridging ligand. Inorganic Chemistry. 43: 5128-33. PMID 15285690 DOI: 10.1021/Ic049605C  0.751
2004 Patra S, Sarkar B, Ghumaan S, Fiedler J, Kaim W, Lahiri GK. The triruthenium complex [[(acac)2Ru(II)]3(L)] containing a conjugated diquinoxaline[2,3-a:2',3'-c]phenazine (L) bridge and acetylacetonate (acac) as ancillary ligands. Synthesis, spectroelectrochemical and EPR investigation. Dalton Transactions (Cambridge, England : 2003). 754-8. PMID 15252496 DOI: 10.1039/B316007F  0.628
2004 Patra S, Sarkar B, Ghumaan S, Fiedler J, Zális S, Kaim W, Kumar Lahiri G. [(mu-L)[RuII(acac)2]2]n, n= 2+, +, 0, -, 2-, with L = 3,3',4,4'-tetraimino-3,3',4,4'-tetrahydrobiphenyl. EPR-supported assignment of NIR absorptions for the paramagnetic intermediates. Dalton Transactions (Cambridge, England : 2003). 750-3. PMID 15252495 DOI: 10.1039/B315927M  0.612
2004 Berger S, Fiedler J, Reinhardt R, Kaim W. Metal vs ligand reduction in complexes of dipyrido[3,2-a:2',3'-c]phenazine and related ligands with [(C5Me5)ClM]+ (M = Rh or Ir): evidence for potential rather than orbital control in the reductive cleavage of the metal-chloride bond. Inorganic Chemistry. 43: 1530-8. PMID 14966991 DOI: 10.1021/Ic0351388  0.511
2004 Frantz S, Rall J, Hartenbach I, Schleid T, Zális S, Kaim W. Metal-induced tautomerization of p- to o-quinone compounds: experimental evidence from CuI and ReI complexes of azophenine and DFT studies. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 149-54. PMID 14695560 DOI: 10.1002/Chem.200305369  0.478
2004 Hartmann H, Kaim W, Wanner M, Klein A, Frantz S, Duboc-Toia C, Fiedler J, Zális S. Proof of innocence for the quintessential noninnocent ligand TCNQ in its tetranuclear complex with four [fac-Re(CO)3(bpy)]+ groups: unusually different reactivity of the TCNX ligands (TCNX = TCNE, TCNQ, TCNB). Inorganic Chemistry. 42: 7018-25. PMID 14577767 DOI: 10.1021/Ic034232L  0.74
2004 Zális S, Sieger M, Greulich S, Stoll H, Kaim W. Replacement of 2,2'-bipyridine by 1,4-diazabutadiene acceptor ligands: why the bathochromic shift for [(N empty set N)IrCl(C5Me5)]+ complexes but the hypsochromic shift for (N empty set N)Ir(C5Me5)? Inorganic Chemistry. 42: 5185-91. PMID 12924889 DOI: 10.1021/Ic034464K  0.449
2004 DEY S, JAIN VK, KNOEDLER A, KAIM W. Synthesis and Crystal Structure of cis-Dichloro{bis-(N,N-dimethylaminoethyl)tellurium-κ2N,Te}palladium(II) Analytical Sciences: X-Ray Structure Analysis Online. 20: x127-x128. DOI: 10.2116/Analscix.20.X127  0.382
2004 Kaim W, Schwederski B. Cooperation of metals with electroactive ligands of biochemical relevance: Beyond metalloporphyrins Pure and Applied Chemistry. 76: 351-364. DOI: 10.1351/Pac200476020351  0.432
2004 Wang J, Li S, Zheng C, Li A, Hosmane NS, Maguire JA, Roesky HW, Cummins CC, Kaim W. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 30. Synthetic and structural studies on oxide ion encapsulating tetralanthanide tetrahedra surrounded by "carbons apart" C 2B 4-carborane ligands (Ln(III) = La, Nd, Gd, Tb, Ho, Lu) Organometallics. 23: 4621-4629. DOI: 10.1021/Om0496176  0.427
2004 Knödler A, Fiedler J, Kaim W. Characterization of the mixed-valent intermediate (n=3) of the complex series {(μ,η3:η3-L)[(Ru(terpy)]2}n+ with the unsaturated bridging ligand N,N′-bis(α-picolinoyl)hydrazido(2−)=L2− Polyhedron. 23: 701-707. DOI: 10.1016/J.Poly.2003.11.043  0.474
2004 Frantz S, Fiedler J, Hartenbach I, Schleid T, Kaim W. A complete series of tricarbonylhalidorhenium(I) complexes (abpy)Re(CO)3(Hal), Hal=F, Cl, Br, I; abpy=2,2′-azobispyridine: Structures, spectroelectrochemistry and EPR of reduced forms Journal of Organometallic Chemistry. 689: 3031-3039. DOI: 10.1016/J.Jorganchem.2004.06.047  0.387
2004 Dey S, Jain VK, Klein A, Kaim W. Interconversion of structurally characterised complexes [PdCl(Se  ̂ N)] 2 and [Pd(Se  ̂ N) 2 ] 6 with the hemi-labile ligand Se  ̂ N=Me 2 NCH 2 CH 2 CH 2 Se − Inorganic Chemistry Communications. 7: 601-603. DOI: 10.1016/J.Inoche.2004.02.005  0.331
2004 Dogan A, Schwederski B, Schleid T, Lissner F, Fiedler J, Kaim W. The complex (μ,η2:η2-L)[AuCl2]2, L2−=N,N′-bis(α-picolinoyl)hydrazido(2−), as obtained directly or through ring-opening reaction of 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine Inorganic Chemistry Communications. 7: 220-223. DOI: 10.1016/J.Inoche.2003.11.006  0.463
2004 Frantz S, Kaim W, Fiedler J, Duboc C. Complexes of [Re(CO)3Cl] with different oxidation states of the polyfunctional bmtz/H2bmtz ligand system (bmtz = 3,6-bis(2-pyrimidyl) -1,2,4,5-tetrazine) Inorganica Chimica Acta. 357: 3657-3665. DOI: 10.1016/J.Ica.2004.03.056  0.442
2004 Ye S, Kaim W, Albrecht M, Lissner F, Schleid T. Complexes of the imine/thioether mixed-donor ligand 8-methylthioquinoline with d6-configurated transition metal centers: synthesis, structures and comparison with complexes of 1-methyl-2-(methylthiomethyl)-1H-benzimidazole Inorganica Chimica Acta. 357: 3325-3330. DOI: 10.1016/J.Ica.2004.03.040  0.498
2004 Frantz S, Weber M, Scheiring T, Fiedler J, Duboc C, Kaim W. Mechanism and product characterization from the electroreduction of heterodinuclear complexes [(C5Me5)ClM(μ-L)Re(CO) 3X](PF6), M=Rh or Ir, L=2,2′- azobispyridine or 2,2′-azobis(5-chloropyrimidine), X=halide Inorganica Chimica Acta. 357: 2905-2914. DOI: 10.1016/J.Ica.2004.02.031  0.407
2004 Singhal A, Jain VK, Klein A, Niemeyer M, Kaim W. Thiolato-bridged “Linear” trinuclear platinum complexes [Pt3(μ-SR)4(dppm)2]2+ Inorganica Chimica Acta. 357: 2134-2142. DOI: 10.1016/J.Ica.2003.12.024  0.388
2004 Kaim W, Scheiring T, Weber M, Fiedler J. Die konjugative Verbr�ckung metallorganischer Reaktionszentren in Heterozweikernkomplexen [(OC)3ClRe(?-L)MCl(C5Me5)]+, M = Rh oder Ir - Spektroskopische Konsequenzen reduktiver Aktivierung Zeitschrift F�R Anorganische Und Allgemeine Chemie. 630: 1883-1893. DOI: 10.1002/Zaac.200400174  0.425
2004 Berger S, Scheiring T, Fiedler J, Kaim W. Kopplung metallorganischer Reaktionszentren durch den nichtplanaren Brückenliganden 2, 3‐Bis(2‐pyridyl)pyrazin Zeitschrift FüR Anorganische Und Allgemeine Chemie. 630: 2409-2417. DOI: 10.1002/Zaac.200400133  0.482
2004 Dey S, Kumbhare L, Jain V, Schurr T, Kaim W, Klein A, Belaj F. Structural Variety and Multiple Isomerism in 1-(Dimethylamino)propyl-2-chalcogenolate and 2-(Dimethylamino)propyl-1-chalcogenolate Complexes of Palladium(II) and Platinum(II): Synthesis, Spectroscopy and Structures European Journal of Inorganic Chemistry. 2004: 4510-4520. DOI: 10.1002/Ejic.200400524  0.4
2004 Frantz S, Sarkar B, Sieger M, Kaim W, Roncaroli F, Olabe J, Záliš S. EPR Insensitivity of the Metal-Nitrosyl Spin-Bearing Moiety in Complexes [LnRuII-NO·]k European Journal of Inorganic Chemistry. 2004: 2902-2907. DOI: 10.1002/Ejic.200400042  0.528
2003 Patra S, Sarkar B, Mobin SM, Kaim W, Lahiri GK. Separating innocence and non-innocence of ligands and metals in complexes [(L)Ru(acac)2](n) (n = -1, 0, +1; L = o-iminoquinone or o-iminothioquinone). Inorganic Chemistry. 42: 6469-73. PMID 14514323 DOI: 10.1021/Ic034469H  0.651
2003 Sarkar B, Kaim W, Klein A, Schwederski B, Fiedler J, Duboc-Toia C, Lahiri GK. What a difference ancillary thienyl makes: unexpected additional stabilization of the diruthenium(III,II) but not the diosmium(III,II) mixed-valent state in tetrazine ligand-bridged complexes. Inorganic Chemistry. 42: 6172-4. PMID 14514292 DOI: 10.1021/Ic034105P  0.754
2003 Su CY, Cai YP, Chen CL, Smith MD, Kaim W, zur Loye HC. Ligand-directed molecular architectures: self-assembly of two-dimensional rectangular metallacycles and three-dimensional trigonal or tetragonal prisms. Journal of the American Chemical Society. 125: 8595-613. PMID 12848568 DOI: 10.1021/Ja034267K  0.532
2003 Sieger M, Wanner M, Kaim W, Stufkens DJ, Snoeck TL, Zális S. Low-valent cobalt complexes with three different pi acceptor ligands: experimental and DFT studies of the reduced and the low-lying excited states of (R-DAB)Co(NO)(CO), R-DAB = substituted 1,4-diaza-1,4-butadiene. Inorganic Chemistry. 42: 3340-6. PMID 12739976 DOI: 10.1021/Ic026078T  0.59
2003 Hoshino Y, Higuchi S, Fiedler J, Su CY, Knödler A, Schwederski B, Sarkar B, Hartmann H, Kaim W. Long-range electronic coupling in various oxidation states of a C4-linked tris(beta-diketonato)ruthenium dimer. Angewandte Chemie (International Ed. in English). 42: 674-7. PMID 12575003 DOI: 10.1002/Anie.200390186  0.611
2003 Cai YP, Su CY, Chen CL, Li YM, Kang BS, Chan AS, Kaim W. Formation of racemate and mesocate complexes from an achiral tripodal ligand containing three benzimidazole groups. Inorganic Chemistry. 42: 163-8. PMID 12513091 DOI: 10.1021/Ic025934Y  0.574
2003 Fujino T, Hoshino Y, Eto M, Yukawa Y, Fiedler J, Kaim W. Synthesis and Spectroelectrochemical Characterization of a Novel Oxalate-Bridged Binuclear Ruthenium(III) Complex Chemistry Letters. 32: 274-275. DOI: 10.1246/Cl.2003.274  0.436
2003 Chanda N, Sarkar B, Fiedler J, Kaim W, Lahiri GK. Synthesis and mixed valence aspects of [{(L)ClRu} 2(μ-tppz)]n+ incorporating 2, 2′-dipyridylamine (L) as ancillary and 2,3,5,6-tetrakis(2-pyridyl)pyrazine (tppz) as bridging ligand Journal of the Chemical Society. Dalton Transactions. 3550-3555. DOI: 10.1039/B306065A  0.606
2003 Frantz S, Reinhardt R, Greulich S, Wanner M, Fiedler J, Duboc-Toia C, Kaim W. Multistep redox sequences of azopyridyl (L) bridged reaction centres in stable radical complex ions {(μ-L)[MCl(η5-C5Me5)]2}˙+, M = Rh or Ir: spectroelectrochemistry and high-frequency EPR spectroscopy Dalton Transactions. 3370-3375. DOI: 10.1039/B305311C  0.465
2003 Phadnis PP, Jain VK, Klein A, Schurr T, Kaim W. Tri(allyl)- and tri(methylallyl)arsine complexes of palladium(ii) and platinum(ii): synthesis, spectroscopy, photochemistry and structures New Journal of Chemistry. 27: 1584. DOI: 10.1039/B303990K  0.432
2003 Kaim W. The chemistry and biochemistry of the copper–radical interaction Dalton Transactions. 761-768. DOI: 10.1039/B210193A  0.35
2003 Su C, Liao S, Wanner M, Fiedler J, Zhang C, Kang B, Kaim W. The copper(I)/copper(II) transition in complexes with 8-alkylthioquinoline based multidentate ligands Dalton Transactions. 189-202. DOI: 10.1039/B208120M  0.581
2003 Wang J, Li S, Zheng C, Hosmane NS, Maguire JA, Roesky HW, Cummins CC, Kaim W. An oxide ion encapsulating tetraholmium tetrahedron stabilized by complexation with the "carbons aparts" C2B4-carborane ligands Organometallics. 22: 4390-4392. DOI: 10.1021/Om034019X  0.373
2003 Wang J, Li S, Zheng C, Maguire JA, Sarkar B, Kaim W, Hosmane NS. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 29. Synthetic and structural studies on lanthanacarboranes with two and three "Carbons apart" carborane cages bonding to Ln(III) metal (Ln(III) = Nd, Gd, Dy, Ho, Er, Tb, Lu) Organometallics. 22: 4334-4342. DOI: 10.1021/Om030426X  0.577
2003 Kaim W, Reinhardt R, Greulich S, Fiedler J. Resolving the Two-Electron Process for the Couple [(C5Me5)M(N∧N)Cl]+/[(C5Me5)M(N∧N)] (M = Rh, Ir) into Two One-Electron Steps Using the 2,2‘-Azobis(pyridine) N∧N Ligand, Fast Scan Cyclovoltammetry, and Spectroelectrochemistry:  Detection of Radicals instead of MIIIntermediates Organometallics. 22: 2240-2244. DOI: 10.1021/Om020860J  0.382
2003 Wang J, Li S, Zheng C, Maguire JA, Kaim W, Hosmane NS. Unsolvated "carbons apart" neodymacarborane sandwich stabilized by bis(η6-benzene)potassium cation: A unique dimeric mixed-metal sandwiched ion-pair Inorganic Chemistry Communications. 6: 1220-1223. DOI: 10.1016/S1387-7003(03)00227-2  0.376
2003 Ye S, Kaim W, Sarkar B, Schwederski B, Lissner F, Schleid T, Duboc-Toia C, Fiedler J. First crystal structure determination and high-frequency EPR study of an organoarsanecopper radical complex Inorganic Chemistry Communications. 6: 1196-1200. DOI: 10.1016/S1387-7003(03)00216-8  0.594
2003 Dey S, Jain VK, Chaudhury S, Knoedler A, Kaim W. Synthesis and structure of bis(2-N,N-dimethylamioethyl-selenolato)zinc and its transformation to ZnSe Polyhedron. 22: 489-491. DOI: 10.1016/S0277-5387(02)01379-7  0.35
2003 Kaim W, Doslik N, Frantz S, Sixt T, Wanner M, Baumann F, Denninger G, Kümmerer H, Duboc-Toia C, Fiedler J, Zališ S. Azo compounds as electron acceptor or radical ligands in transition metal species: spectroelectrochemistry and high-field EPR studies of ruthenium, rhodium and copper complexes of 2,2′-azobis(5-chloropyrimidine) Journal of Molecular Structure. 656: 183-194. DOI: 10.1016/S0022-2860(03)00339-9  0.519
2003 Dey S, Jain VK, Knoedler A, Kaim W. Synthesis and characterization of 3-dimethylaminopropyl selenolate complexes of palladium(II) and platinum(II) Inorganica Chimica Acta. 349: 104-110. DOI: 10.1016/S0020-1693(03)00080-X  0.403
2003 Phadnis PP, Jain VK, Klein A, Weber M, Kaim W. Configurational selectivity in benzyldimethylarsine complexes of palladium(II) and platinum(II): synthesis, spectroscopy and structures Inorganica Chimica Acta. 346: 119-128. DOI: 10.1016/S0020-1693(02)01375-0  0.42
2003 Hartmann H, Sarkar B, Kaim W, Fiedler J. Electron transfer reactions of (C5R5)2(CO)2Ti (R=H or Me) with TCNE or TCNQ Journal of Organometallic Chemistry. 687: 100-107. DOI: 10.1016/J.Jorganchem.2003.07.014  0.586
2003 Sarkar B, Kaim W, Schleid T, Hartenbach I, Fiedler J. 3, 6-Bis(2-pyrazinyl)-1, 2, 4, 5-tetrazin: Ein neuer mehrfunktioneller Ligand und sein syn, fac-konfigurierter Bis(tricarbonylchlororhenium)-Komplex Zeitschrift FüR Anorganische Und Allgemeine Chemie. 629: 1353-1357. DOI: 10.1002/Zaac.200300076  0.637
2003 Hoshino Y, Higuchi S, Fiedler J, Su C, Knödler A, Schwederski B, Sarkar B, Hartmann H, Kaim W. Weitreichende elektronische Kopplung in unterschiedlichen Oxidationszuständen eines C4‐verknüpften Tris(β‐diketonato)ruthenium‐Dimers Angewandte Chemie. 115: 698-701. DOI: 10.1002/Ange.200390154  0.625
2002 Su CY, Cai YP, Chen CL, Lissner F, Kang BS, Kaim W. Self-assembly of trigonal-prismatic metallocages encapsulating BF4- or CuI32- as anionic guests: structures and mechanism of formation. Angewandte Chemie (International Ed. in English). 41: 3371-5. PMID 12298035 DOI: 10.1002/1521-3773(20020916)41:18<3371::Aid-Anie3371>3.0.Co;2-4  0.443
2002 Frantz S, Hartmann H, Doslik N, Wanner M, Kaim W, Kümmerer HJ, Denninger G, Barra AL, Duboc-Toia C, Fiedler J, Ciofini I, Urban C, Kaupp M. Multifrequency EPR study and density functional g-tensor calculations of persistent organorhenium radical complexes. Journal of the American Chemical Society. 124: 10563-71. PMID 12197758 DOI: 10.1021/Ja025829N  0.428
2002 Kaim W, Dogan A, Wanner M, Klein A, Tiritiris I, Schleid T, Stufkens DJ, Snoeck TL, McInnes EJ, Fiedler J, Zális S. Reduced and excited states of (bpym)[PtCl(2)](n)() (bpym = 2,2'-bipyrimidine; n = 1, 2): experiments and DFT calculations. Inorganic Chemistry. 41: 4139-48. PMID 12160401 DOI: 10.1021/Ic020158F  0.773
2002 Kaim W, Schwederski B, Dogan A, Fiedler J, Kuehl CJ, Stang PJ. Metalla-supramolecular rectangles as electron reservoirs for multielectron reduction and oxidation Inorganic Chemistry. 41: 4025-4028. PMID 12132929 DOI: 10.1021/Ic020122N  0.434
2002 Dey S, Jain VK, Knödler A, Klein A, Kaim W, Zális S. Structural basis for unusually long wavelength charge transfer transitions in complexes [MCl(ECH(2)CH(2)NMe(2))(PR(3))] (E = Te, Se; M = Pt, Pd): experimental results and TD-DFT calculations. Inorganic Chemistry. 41: 2864-70. PMID 12033893 DOI: 10.1021/Ic011210V  0.694
2002 Knödler A, Wanner M, Fiedler J, Kaim W. Coordination ambivalence of the electroactive bis-chelate ligand bis(1-methyl-2-imidazolyl)glyoxal (BIG) in mononuclear and dinuclear complexes with Re(CO)3Cl Journal of the Chemical Society-Dalton Transactions. 3079-3084. DOI: 10.1039/B202636H  0.466
2002 Klein A, McInnes EJL, Kaim W. Organometallic platinum(II) complexes of methyl-substituted phenanthrolines Journal of the Chemical Society-Dalton Transactions. 2371-2378. DOI: 10.1039/B201419J  0.473
2002 Pott T, Jutzi P, Kaim W, Schoeller WW, Neumann B, Stammler A, Stammler H, Wanner M. Reactivity of “GaI” TowardN-Substituted 1,4-Diazabuta-1,3-dienes:  Synthesis and Characterization of Gallium Heterocycles Containing Paramagnetic Diazabutadiene Monoanions Organometallics. 21: 3169-3172. DOI: 10.1021/Om0200510  0.367
2002 Greulich S, Klein A, Knödler A, Kaim W. Qualitatively Different Reactivities of Hydride Reagents toward [(α-diimine)(η5-C5Me5)ClIr]+Cations:  Substitution, Electron Transfer (Reduction), or Stepwise Hydrogenation Organometallics. 21: 765-769. DOI: 10.1021/Om010529K  0.427
2002 Dutta DP, Jain VK, Knoedler A, Kaim W. Dithiocarbamates of gallium(III) and indium(III): syntheses, spectroscopy, and structures Polyhedron. 21: 239-246. DOI: 10.1016/S0277-5387(01)00990-1  0.328
2002 Knödler A, Kaim W, Jain VK, Záliš S. Dimethylplatinum(II) and tetramethylplatinum(IV) complexes of 1-methyl-(2-alkylthiomethyl)-1H-benzimidazoles: experimental and DFT-calculated structures and NMR spectra Journal of Organometallic Chemistry. 655: 218-226. DOI: 10.1016/S0022-328X(02)01564-4  0.428
2002 Kaim W, Wanner M, Knödler A, Záliš S. Copper complexes with non-innocent ligands: probing CuII/catecholato-CuI/o-semiquinonato redox isomer equilibria with EPR spectroscopy Inorganica Chimica Acta. 337: 163-172. DOI: 10.1016/S0020-1693(02)01081-2  0.45
2002 Glöckle M, Katz NE, Ketterle M, Kaim W. Qualitatively and quantitatively different solvatochromism of the MLCT and MMCT absorption bands of centrosymmetric acceptor-bridged diiron(II,II) and diiron(III,II) cyanide complexes Inorganica Chimica Acta. 336: 55-60. DOI: 10.1016/S0020-1693(02)00846-0  0.332
2002 Kaim W. The coordination chemistry of 1,2,4,5-tetrazines Coordination Chemistry Reviews. 230: 127-139. DOI: 10.1016/S0010-8545(02)00044-9  0.467
2002 Su C, Cai Y, Chen C, Lissner F, Kang B, Kaim W. Selbstorganisation trigonal‐prismatischer Metallakäfige mit eingeschlossenen BF4−‐ oder CuI32−‐Gast‐Ionen: Strukturen und Bildungsmechanismen Angewandte Chemie. 114: 3519-3523. DOI: 10.1002/1521-3757(20020916)114:18<3519::Aid-Ange3519>3.0.Co;2-Q  0.408
2002 Sieger M, Hübler K, Scheiring T, Sixt T, Zalis S, Kaim W. Geometrical and Ground State Electronic Structures of Nitrosylcobalt Complexes [(RNCHCHNR)Co(NO)(CO)] (R = Isopropyl, 2,6-Diisopropylphenyl orp-Tolyl) from Experiment and DFT-Calculations Zeitschrift FüR Anorganische Und Allgemeine Chemie. 628: 2360-2364. DOI: 10.1002/1521-3749(200211)628:11<2360::Aid-Zaac2360>3.0.Co;2-L  0.363
2002 Phadnis PP, Jain VK, Knödler A, Kaim W. Tripropylarsane Complexes of Palladium(II) and Platinum(II) — Syntheses, Spectroscopy, and Structures Zeitschrift FüR Anorganische Und Allgemeine Chemie. 628: 1332. DOI: 10.1002/1521-3749(200206)628:6<1332::Aid-Zaac1332>3.0.Co;2-T  0.4
2001 Uhl W, Cuypers L, Harms K, Kaim W, Wanner M, Winter R, Koch R, Saak W. Ga (CMe ) , an Important New Building Block in the Structural Chemistry of the Alkylelement(I) Compounds E R (E=B-In). Angewandte Chemie (International Ed. in English). 40: 566-568. PMID 29712028 DOI: 10.1002/1521-3773(20010202)40:3<566::Aid-Anie566>3.0.Co;2-T  0.33
2001 Hartmann H, Kaim W, Hartenbach I, Schleid T, Wanner M, Fiedler J. A Fully Characterized Complex Ion with Unreduced TCNQ as Fourfold Bridging Ligand: [(μ -TCNQ){fac-Re(CO) (bpy)} ]. Angewandte Chemie (International Ed. in English). 40: 2842-2844. PMID 29711978 DOI: 10.1002/1521-3773(20010803)40:15<2842::Aid-Anie2842>3.0.Co;2-R  0.479
2001 Wanner M, Scheiring T, Kaim W, Slep LD, Baraldo LM, Olabe JA, Zális S, Baerends EJ. EPR characteristics of the [(NC)(5)M(NO)](3-) ions (M = Fe, Ru, Os). Experimental and DFT study establishing NO* as a ligand. Inorganic Chemistry. 40: 5704-7. PMID 11599974 DOI: 10.1021/Ic010452S  0.33
2001 Glöckle M, Hübler K, Kümmerer HJ, Denninger G, Kaim W. Dicopper(I) complexes with reduced states of 3,6-bis(2'-pyrimidyl)-1,2,4,5-tetrazine: crystal structures and spectroscopic properties of the free ligand, a radical species, and a complex of the 1,4-dihydro form. Inorganic Chemistry. 40: 2263-9. PMID 11327900 DOI: 10.1021/Ic001228Q  0.426
2001 Glöckle M, Kaim W, Klein A, Roduner E, Hübner G, Zalis S, van Slageren J, Renz F, Gütlich P. The stable diiron(2.5) complex ion [(NC)(5)Fe(mu-tz)Fe(CN)5](5-), tz = 1,2,4,5-tetrazine, and its neighboring oxidation states. Inorganic Chemistry. 40: 2256-62. PMID 11327899 DOI: 10.1021/Ic001229I  0.337
2001 Hornung FM, Heilmann O, Kaim W, Zalis S, Fiedler J. Metal vs ligand reduction in complexes of 1,3-dimethylalloxazine (DMA) with copper(I), ruthenium(II), and tungsten(VI). Crystal structures of (DMA)WO2Cl2 and (bis(1-methylimidazol-2-yl)ketone)WO2Cl2. Inorganic Chemistry. 39: 4052-8. PMID 11198860 DOI: 10.1021/Ic0001816  0.531
2001 Berger S, Klein A, Wanner M, Kaim W, Fiedler J. Electron paramagnetic resonance and spectroscopic characteristics of electrogenerated mixed-valent systems [(eta 5-C5Me5)M(mu-L)M(eta 5-C5Me5)]+ (M = Rh, Ir; L = 2,5-diiminopyrazines) in relation to the radicals [(eta 5-C5Me5)ClM(mu-L)MCl(eta 5-C5Me5)]+ and [(eta 5-C5Me5)M(mu-L)MCl(eta 5-C5Me5)]2+. Inorganic Chemistry. 39: 2516-21. PMID 11197004 DOI: 10.1021/Ic991110D  0.385
2001 Hartmann H, Berger S, Winter R, Fiedler J, Kaim W. Reversible and site-specific reduction of the ligand sides in a molecular rectangle with up to eight electrons. Inorganic Chemistry. 39: 4977-80. PMID 11196979 DOI: 10.1021/Ic0001006  0.385
2001 Albrecht M, Hübler K, Zalis S, Kaim W. Crucial role of Cu-S bonding for structural changes accompanying the reversible CuI/CuII transition in an unrestrained Cu(N[symbol: see text]S)2 coordination arrangement. An experimental and DFT study. Inorganic Chemistry. 39: 4731-4. PMID 11196947 DOI: 10.1021/Ic000021U  0.429
2001 Kaim W, Klein A, Glöckle M. Exploration of mixed-valence chemistry: inventing new analogues of the Creutz-Taube ion. Accounts of Chemical Research. 33: 755-63. PMID 11087312 DOI: 10.1021/Ar960067K  0.373
2001 Kaim W, Titze C, Klein A, Knödler A, Zalis S. Experimental and DFT calculated structure of the diruthenium(2.5) complex [(Me3TACN)Ru(μ-Cl)3Ru(Me3TACN)](PF6)2 Israel Journal of Chemistry. 41: 145-148. DOI: 10.1560/J8Q3-0De1-A30K-Xbgl  0.461
2001 Wanner M, Hartenbach I, Fiedler J, Schleid T, Kaim W. Zwei- und dreikemige Organometallkomplexe (ReS4)[MCl(C5Me5)], M = Rh, Ir, und (μ-WS4)[IrCl(C5Me5)]2 / Dinuclear and Trinuclear Organometallic Complexes (ReS4)[MCl(C5Me5)], M = Rh, Ir, and (μ-WS4)[IrCl(C5Me5)]2 Zeitschrift FüR Naturforschung B. 56: 940-946. DOI: 10.1515/Znb-2001-0913  0.439
2001 Kaim W, Reinhardt R, Greulich S, Sieger M, Klein A, Fiedler J. Coupling of Electron Transfer and Bond Dissociation Processes in Dinuclear Complexes with Rhodium and Iridium Reaction Centres Bridged by 2,2'-Bipyrimidine Collection of Czechoslovak Chemical Communications. 66: 291-306. DOI: 10.1135/Cccc20010291  0.473
2001 Dey S, Jain VK, Chaudhury S, Knoedler A, Lissner F, Kaim W. 2-(Dimethylamino)ethaneselenolates of palladium(II): synthesis, structure, spectroscopy and transformation into palladium selenide Journal of the Chemical Society-Dalton Transactions. 723-728. DOI: 10.1039/B008310K  0.394
2001 Scheiring T, Fiedler J, Kaim W. Structure and Spectroelectrochemistry (UV/Vis, IR, EPR) of the Acceptor-Bridged Heterodinuclear Complex [(η5-C5Me5)ClRh(μ-bptz)Re(CO)3Cl](PF6), bptz = 3,6-Bis(2-pyridyl)-1,2,4,5-tetrazine Organometallics. 20: 1437-1441. DOI: 10.1021/Om000892B  0.507
2001 Kaim W, Sixt T, Weber M, Fiedler J. Iron(II) versus osmium(II) oxidation in 1,1′-bis(diorganophosphino)ferrocene–osmium(II) complexes Journal of Organometallic Chemistry. 637: 167-171. DOI: 10.1016/S0022-328X(01)00898-1  0.438
2001 Jiménez-Pulido SB, Sieger M, Knödler A, Heilmann O, Wanner M, Schwederski B, Fiedler J, Moreno-Carretero MN, Kaim W. Rhenium(I) coordinated lumazine and pterin derivatives: structure and spectroelectrochemistry of reversibly reducible (6-ATML)Re(CO)3Cl (6-ATML=6-acetyl-1,3,7-trimethyllumazine) Inorganica Chimica Acta. 325: 65-72. DOI: 10.1016/S0020-1693(01)00646-6  0.446
2001 Stange AF, Klein A, Klinkhammer K, Kaim W. Aggregation control of copper(I) thiolates through substituent size and ancillary chelate ligands: closely related mono-, di-, tri- and tetranuclear complexes Inorganica Chimica Acta. 324: 336-341. DOI: 10.1016/S0020-1693(01)00535-7  0.334
2001 Farrell IR, Hartl F, Záliš S, Wanner M, Kaim W, Vlček A. Electrochemical oxidation of [Cr(CO)4(tmp)] to the low-spin Cr(I) species [Cr(CO)4(tmp)]+ (tmp=3,4,7,8-tetramethyl-1,10-phenanthroline): an IR, UV–Vis, and EPR spectroelectrochemical and DFT computational study of the accompanying changes in molecular and electronic structure Inorganica Chimica Acta. 318: 143-151. DOI: 10.1016/S0020-1693(01)00421-2  0.425
2001 Berger S, Hartmann H, Wanner M, Fiedler J, Kaim W. Tetranuclear complexes {(μ4-TCNX)[Cu(Me3TACN)]4}(BF4)4 with TCNX=TCNE, TCNQ or TCNB (1,2,4,5-tetracyanobenzene) and Me3TACN=1,4,7-trimethyl-1,4,7-triazacyclononane Inorganica Chimica Acta. 314: 22-26. DOI: 10.1016/S0020-1693(00)00368-6  0.505
2001 Kaim W. Complexes with 2,2â²-azobispyridine and related 'S-frame' bridging ligands containing the azo function Coordination Chemistry Reviews. 219: 463-488. DOI: 10.1016/S0010-8545(01)00347-2  0.514
2001 Glöckle M, Kaim W, Fiedler J. Stufenweise und chemisch reversible Reduktion von Zweikernkomplexen {(μ-bmtz)[MCl(η6-Cym)]2}[PF6]2 (M = Ru, Os; bmtz = 3,6-Bis(2′-pyrimidyl)1,2,4,5-tetrazin) mit bis zu sechs Elektronen Zeitschrift FüR Anorganische Und Allgemeine Chemie. 627: 1441-1453. DOI: 10.1002/1521-3749(200107)627:7<1441::Aid-Zaac1441>3.0.Co;2-R  0.392
2001 Berger S, Baumann F, Scheiring T, Kaim W. Metallorganische Komplexkationen [(ηn-CnR′n M(RN=CH-CH=NR)Cl]+ von 1,4-Diazabutadienen (M = Os und n = 6 oder M = Rh, Ir und n = 5, R = 2,6-Dialkylphenyl). Strukturen und Reduktion zu den Neutralverbindungen [(ηn-CnR′n)M(RN-CH=CH-NR)] Zeitschrift FüR Anorganische Und Allgemeine Chemie. 627: 620-630. DOI: 10.1002/1521-3749(200104)627:4<620::Aid-Zaac620>3.0.Co;2-K  0.365
2001 Dey S, Jain V, Knoedler A, Kaim W, Zalis S. Platinum(II) Complexes of 2-(Dimethylamino)ethylselenolate − Donor−Acceptor Inter-Ligand Interactions as Evident from Experimental and TD-DFT Computational Analysis European Journal of Inorganic Chemistry. 2001: 2965. DOI: 10.1002/1099-0682(200111)2001:11<2965::Aid-Ejic2965>3.0.Co;2-7  0.477
2000 Sixta T, Kaim W, Preetz W. Characterization of the Inorganic/Organometallic Osmium(IV) Compound [Cp2 OsIVCl]2 [OsIVCl6] as Formed by the Reaction of OSCI3 with Pentamethylcyclopentadiene in Air Zeitschrift FüR Naturforschung B. 55: 235-237. DOI: 10.1515/Znb-2000-3-401  0.334
2000 Uhl W, Spies T, Haase D, Winter R, Kaim W. Synthesis of a Large Organometallic Macrocycle Comprising Four Ga−Ga Bonds and Four Bridging Ferrocene Dicarboxylato Ligands† Organometallics. 19: 1128-1131. DOI: 10.1021/Om990875Q  0.375
2000 Knödler A, Hübler K, Sixt T, Kaim W. A copper(I) dimer [Cu(L)(CH3CN)]2(BF4)2 with the new chelating and bridging tridentate ligand 1-(2-pyridylmethyl)-2-(2-pyridyl)benzimidazole (L) Inorganic Chemistry Communications. 3: 182-184. DOI: 10.1016/S1387-7003(00)00042-3  0.408
2000 Sixt T, Fiedler J, Kaim W. Iron versus ruthenium oxidation in 1,1′-bis(diphenylphosphino)ferrocene–ruthenium(II) complexes: EPR and spectroelectrochemical evidence Inorganic Chemistry Communications. 3: 80-82. DOI: 10.1016/S1387-7003(00)00009-5  0.413
2000 Scheiring T, Kaim W, Fiedler J. Geometrical and electronic structures of the acetyl complex Re(bpy)(CO)3(COCH3) and of [M(bpy)(CO)4](OTf), M=Mn,Re Journal of Organometallic Chemistry. 598: 136-141. DOI: 10.1016/S0022-328X(99)00691-9  0.49
2000 Albrecht M, Scheiring T, Sixt T, Kaim W. Structures and properties of complexes [MCl(C5Me5)(N∧S)](PF6), M=Rh, Ir, with N∧S=1-methyl-2-(alkylthiomethyl)-1H-benzimidazole ligands Journal of Organometallic Chemistry. 596: 84-89. DOI: 10.1016/S0022-328X(99)00544-6  0.437
2000 Hartmann H, Scheiring T, Fiedler J, Kaim W. Structures and spectroelectrochemistry (UV–vis, IR, EPR) of complexes [(OC)3ClRe]n(abpy), n=1, 2; abpy=2,2′-azobispyridine Journal of Organometallic Chemistry. 604: 267-272. DOI: 10.1016/S0022-328X(00)00282-5  0.527
2000 Sixt T, Kaim W. Copper(I) complexes with N,O-donor Schiff base ligands related to intermediate forms of the TPQ cofactor in amine oxidases Inorganica Chimica Acta. 300: 762-768. DOI: 10.1016/S0020-1693(99)00612-X  0.476
2000 Scheiring T, Kaim W, Olabe JA, Parise AR, Fiedler J. The valence-localized decacyanodiruthenium(III,II) analogue of the Creutz–Taube ion. Completing the full d5/d6 triad [(NC)5M(μ-pz)M(CN)5]5−, M=Fe,Ru,Os; pz=pyrazine Inorganica Chimica Acta. 300: 125-130. DOI: 10.1016/S0020-1693(99)00456-9  0.409
2000 Albrecht M, Kaim W. Koordination von Rhodium(III), Iridium(III) und Kupfer(II) mit dem potentiell vierzähnigen Akzeptorliganden Bis(1‐methylimidazol‐2‐yl)glyoxal (big) Zeitschrift FüR Anorganische Und Allgemeine Chemie. 626: 1341-1348. DOI: 10.1002/(Sici)1521-3749(200006)626:6<1341::Aid-Zaac1341>3.0.Co;2-0  0.328
2000 Albrecht M, Hübler K, Kaim W. Syntheses, Structures, and Properties of the Complexes [Ag(N∧S)n](X), N∧S = 1-Methyl-2-(alkylthiomethyl)-1H-benzimidazoles, X = PF6 (n = 2) or PO2F2 (n = 1) Zeitschrift FüR Anorganische Und Allgemeine Chemie. 626: 1033-1037. DOI: 10.1002/(Sici)1521-3749(200005)626:5<1033::Aid-Zaac1033>3.0.Co;2-A  0.4
1999 Zális S, Stoll H, Baerends EJ, Kaim W. The d(0), d(1) and d(2) Configurations in Known and Unknown Tetrathiometal Compounds MS(4)(n)()(-) (M = Mo, Tc, Ru; W, Re, Os). A Quantum Chemical Study. Inorganic Chemistry. 38: 6101-6105. PMID 11671319 DOI: 10.1021/Ic990891F  0.308
1999 Glöckle M, Kaim W. An Exceedingly Stable Diiron(II,III) Complex Ion [(tz){Fe(CN)5}2]5− with Comproportionation Constants between 108 (in H2O) and 1019 (in CH3CN) Angewandte Chemie. 38: 3072-3074. PMID 10540426 DOI: 10.1002/(Sici)1521-3773(19991018)38:20<3072::Aid-Anie3072>3.0.Co;2-2  0.39
1999 Albrecht M, Hiibler K, Kaim W. Coordination of the Hetero(N,S)- bidentate Ligand 1-Methyl-2- (methylthiomethyl)-1H-benzimidazole to [(Ph3P)Au)]+ Exclusively through the Imine Nitrogen Donor Zeitschrift FüR Naturforschung B. 54: 1606-1608. DOI: 10.1515/Znb-1999-1221  0.395
1999 Wanner M, Kaim W, Lorenzen V, Preetz W. Hexaborate Cluster Radical Anions [B6Haln Hal'6-n].- and [B6Hal5R].-(Hai, Hal' = CI, Br, I; R = H, alkyl). Chemical or Electrochemical Generation, Vibrational, UV-Vis and EPR Spectroscopy Zeitschrift FüR Naturforschung B. 54: 1103-1108. DOI: 10.1515/Znb-1999-0902  0.39
1999 Barra A, Brunel L, Baumann F, Schwach M, Moscherosch M, Kaim W. High-frequency (245 GHz) and X-band EPR study of stable dicopper radical complexes Journal of the Chemical Society-Dalton Transactions. 3855-3857. DOI: 10.1039/A903419F  0.422
1999 Fees J, Ketterle M, Klein A, Fiedler J, Kaim W. Electrochemical, spectroscopic and EPR study of transition metal complexes of dipyrido[3,2- a :2′,3′- c ]phenazine Journal of the Chemical Society-Dalton Transactions. 2595-2600. DOI: 10.1039/A903417J  0.533
1999 Klein A, Kasack V, Reinhardt R, Sixt T, Scheiring T, Zalis S, Fiedler J, Kaim W. 2,5-Bis(1-phenyliminoethyl)pyrazine (bpip): a conjugated metal–metal bridging acceptor ligand and its homodinuclear complexes with low-valent metal centres Journal of the Chemical Society-Dalton Transactions. 575-582. DOI: 10.1039/A808293F  0.492
1999 Schwach M, Hausen H, Kaim W. The First Crystal Structure of a Metal-Stabilized Tetrazine Anion Radical:  Formation of a Dicopper Complex through Self-Assembly in a Comproportionation Reaction Inorganic Chemistry. 38: 2242-2243. DOI: 10.1021/Ic9814625  0.357
1999 Wanner M, Sixt T, Klinkhammer K, Kaim W. First Experimental Structure of a 1:1 Metal Complex with a PQQ Cofactor Derivative outside Dehydrogenase Enzymes Inorganic Chemistry. 38: 2753-2755. DOI: 10.1021/Ic981390H  0.383
1999 Baumann F, Dormann E, Ehleiter Y, Kaim W, Kärcher J, Kelemen M, Krammer R, Saurenz D, Stalke D, Wachter C, Wolmershäuser G, Sitzmann H. Structure and reactivity of paramagnetic cyclopentadienyl cobalt complexes with bulky alkyl substituents Journal of Organometallic Chemistry. 587: 267-283. DOI: 10.1016/S0022-328X(99)00332-0  0.319
1999 Heilmann O, Hornung FM, Fiedler J, Kaim W. Organometallic iridium(III) and rhenium(I) complexes with lumazine, alloxazine and pterin derivatives Journal of Organometallic Chemistry. 589: 2-10. DOI: 10.1016/S0022-328X(99)00294-6  0.521
1999 Kaim W, Berger S, Greulich S, Reinhardt R, Fiedler J. Electronic coupling of two [Cp*ClM]+/[Cp*M] reaction centers via π conjugated bridging ligands: similarities and differences between rhodium and iridium analogues Journal of Organometallic Chemistry. 582: 153-159. DOI: 10.1016/S0022-328X(98)01027-4  0.476
1999 Ketterle M, Kaim W, Olabe JA, Parise AR, Fiedler J. Widely differing stabilities of molecule-bridged cyanodiiron(III,II) species in non-aqueous solvents Inorganica Chimica Acta. 291: 66-73. DOI: 10.1016/S0020-1693(99)00039-0  0.368
1999 Albrecht M, Hübler K, Scheiring T, Kaim W. Copper(I) and copper(II) complexes of the bidentate imidazole/thioether ligand 1-methyl-2-(methylthiomethyl)-1H-benzimidazole Inorganica Chimica Acta. 287: 204-208. DOI: 10.1016/S0020-1693(99)00018-3  0.496
1999 Baumann F, Kaim W, M. Baraldo L, Slep LD, Olabe JA, Fiedler J. Reduction of the NO+ ligand in the pentacyanonitrosylosmate(II) ion Inorganica Chimica Acta. 285: 129-133. DOI: 10.1016/S0020-1693(98)00254-0  0.371
1999 Kaim W, Schwederski B, Heilmann O, Hornung FM. Coordination compounds of pteridine, alloxazine and flavin ligands: structures and properties Coordination Chemistry Reviews. 182: 323-342. DOI: 10.1016/S0010-8545(98)00193-3  0.415
1999 Rall J, Wanner M, Albrecht M, Hornung FM, Kaim W. Sensitive Valence Tautomer Equilibrium of Paramagnetic Complexes [(L)Cun+(Qn−)] (n=1 or 2; Q=Quinones) Related to Amine Oxidase Enzymes Chemistry - a European Journal. 5: 2802-2809. DOI: 10.1002/(Sici)1521-3765(19991001)5:10<2802::Aid-Chem2802>3.0.Co;2-5  0.353
1999 Binder H, Kellner R, Vaas K, Hein M, Baumann F, Wanner M, Kaim W, Wedig U, Hönle W, von Schnering HG, Groeger O, Engelhardt G. HB9X9˙ and H2B9X9 (X = Cl, Br, I): Neutralcloso-Nonaboranes in the Novel Series BnHn+1, and BnHn+2 - Syntheses, Ab Initio Calculations, and Electronic Structures Zeitschrift FüR Anorganische Und Allgemeine Chemie. 625: 1638-1646. DOI: 10.1002/(Sici)1521-3749(199910)625:10<1638::Aid-Zaac1638>3.0.Co;2-V  0.352
1999 Klein A, Scheiring T, Kaim W. Molecular and Crystal Structure of an Organoplatinum(II) Complex with Dipyrido[3,2-a : 2′,3′-c]phenazine (dppz) Zeitschrift FüR Anorganische Und Allgemeine Chemie. 625: 1177-1180. DOI: 10.1002/(Sici)1521-3749(199907)625:7<1177::Aid-Zaac1177>3.0.Co;2-1  0.377
1999 Binder H, Kellner R, Vaas K, Hein M, Baumann F, Wanner M, Winter R, Kaim W, Hönle W, Grin Y, Wedig U, Schultheiss M, Kremer RK, Schnering HGv, Groeger O, et al. The closo-Cluster Triad: B9X9, [B9X9]· –, and [B9X9]2– with Tricapped Trigonal Prisms (X = Cl, Br, I). Syntheses, Crystal and Electronic Structures Zeitschrift FüR Anorganische Und Allgemeine Chemie. 625: 1059-1072. DOI: 10.1002/(Sici)1521-3749(199907)625:7<1059::Aid-Zaac1059>3.0.Co;2-#  0.364
1998 Rall J, Stange AF, Hübler K, Kaim W. A Coordination-Induced 1,4→1,2-Quinonediimine Isomerization. Angewandte Chemie (International Ed. in English). 37: 2681-2682. PMID 29711603 DOI: 10.1002/(Sici)1521-3773(19981016)37:19<2681::Aid-Anie2681>3.0.Co;2-9  0.424
1998 Doslik N, Sixt T, Kaim W. The First Structural Characterization of an Azoaromatic Radical Anion Stabilized by Dicopper(I) Coordination. Angewandte Chemie (International Ed. in English). 37: 2403-2404. PMID 29710941 DOI: 10.1002/(Sici)1521-3773(19980918)37:17<2403::Aid-Anie2403>3.0.Co;2-J  0.45
1998 Lorenzen V, Preetz W, Baumann F, Kaim W. Paramagnetic Cluster Ions [B(6)Hal(n)()Hal'(6)(-)(n)()](*)(-) (Hal, Hal' = Cl, Br, I). EPR Evidence for Radical Stabilization through Electronic Effects of the Halogen Substituents. Inorganic Chemistry. 37: 4011-4014. PMID 11670517 DOI: 10.1021/Ic9802698  0.378
1998 Hornung FM, Klinkhammer KW, Kaim W. New sulfide-bridged heterocubanes [MVI(S)ReI3(CO)9(µ3-S)4]–, M = Mo or W, with transition metals in very different oxidation states Chemical Communications. 2055-2056. DOI: 10.1039/A805295F  0.346
1998 Ketterle M, Kaim W, Fiedler J. Valence delocalisation in a strongly coupled (Kc = 1014) molecule-bridged cyanodiiron(III,II) species Chemical Communications. 1701-1702. DOI: 10.1039/A804279I  0.391
1998 Stange AF, Kaim W. Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR) Chemical Communications. 469-470. DOI: 10.1039/A708867A  0.413
1998 Vlček A, Baumann F, Kaim W, Grevels F, Hartl F. Electron distribution in the Cr(CO)4(bpy)>·>>–>> (bpy = 2,2′-bipyridine) radical anion as revealed by EPR spectroscopy and IR spectroelectrochemistry of 13CO-enriched species Journal of the Chemical Society-Dalton Transactions. 215-220. DOI: 10.1039/A705819E  0.436
1998 Glöckle M, Kaim W, Fiedler J. Valence Delocalization Despite Weak Metal-Metal Coupling In A Bis(Organoosmium(Iii,Ii)) Complex With A Pyrazine Bridge Organometallics. 17: 4923-4925. DOI: 10.1021/Om980586M  0.434
1998 Klein A, Hasenzahl S, Kaim W, Fiedler J. On the Question of Mixed-Valent States in Ligand-Bridged Dinuclear Organoplatinum Compounds [RkPt(μ-L)PtRk]n,k= 2 or 4† Organometallics. 17: 3532-3538. DOI: 10.1021/Om980107J  0.512
1998 Hosmane NS, Demissie T, Zhang H, Maguire JA, Lipscomb WN, Baumann F, Kaim W. Synthesis and crystal structure of the first polymeric cesium compound of a carborane ligand system Organometallics. 17: 293-295. DOI: 10.1021/Om970938+  0.398
1998 Kaim W, Klein A, Hasenzahl S, Stoll H, Záliš S, Fiedler J. Reactions of New Organoplatinum(II) and -(IV) Complexes of 1,4-Diaza-1,3-butadienes with Light and Electrons. Emission vs Photochemistry and the Electronic Structures of Ground, Reduced, Oxidized, and Low-Lying Charge-Transfer Excited States† Organometallics. 17: 237-247. DOI: 10.1021/Om970736D  0.473
1998 Baumann F, Kaim W, García Posse M, Katz NE. Spectroelectrochemistry of the Multistep Redox System {(μ-bpym)[Ru(NH3)4]2}n+,n= 2−6, in a Nonaqueous Medium Inorganic Chemistry. 37: 658-660. DOI: 10.1021/Ic971143Y  0.467
1998 Hornung FM, Baumann F, Kaim W, Olabe JA, Slep LD, Fiedler J. Spectroelectrochemical Characterization of the Two-Step Redox System {(μ-pz)[Os(CN)5]2}n-(n= 4, 5, 6; pz = Pyrazine). Similarities and Differences in Relation to the Creutz−Taube System Inorganic Chemistry. 37: 311-316. DOI: 10.1021/Ic970804O  0.431
1998 Baumann F, Stange A, Kaim W. Interaction of two equivalent electron transfer/atom transfer centers via 2,2′-bipyrimidine as bridging ligand Inorganic Chemistry Communications. 1: 305-308. DOI: 10.1016/S1387-7003(98)00082-3  0.413
1998 Pfitzner A, Baumann F, Kaim W. TeS2.− Radical Anions in CuBrCu1.2TeS2 Angewandte Chemie International Edition. 37: 1955-1957. DOI: 10.1002/(Sici)1521-3773(19980803)37:13/14<1955::Aid-Anie1955>3.0.Co;2-C  0.344
1998 Rall J, Stange AF, Hübler K, Kaim W. Eine Koordinationsinduzierte 1,4 1,2-Chinondiimin-Isomerisierung Angewandte Chemie. 110: 2827-2829. DOI: 10.1002/(Sici)1521-3757(19981002)110:19<2827::Aid-Ange2827>3.0.Co;2-H  0.357
1997 Baumann F, Kaim W, Olabe JA, Parise AR, Jordanov J. Tetranuclear osmium complexes of tetracyanoquinodimethane [TCNQ, 2,2′-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile)] and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism† Journal of the Chemical Society-Dalton Transactions. 4455-4460. DOI: 10.1039/A703824K  0.467
1997 Scheiring T, Klein A, Kaim W. EPR study of paramagnetic rhenium(I) complexes (bpy>>·>>–>>)Re(CO)3X relevant to the mechanism of electrocatalytic CO2 reduction† Journal of the Chemical Society-Perkin Transactions 1. 2569-2572. DOI: 10.1039/A702467C  0.388
1997 Klein A, Hasenzahl S, Kaim W. EPR study of electron transfer and group transfer in organoplatinum(II) and (IV) compounds Journal of the Chemical Society-Perkin Transactions 1. 2573-2578. DOI: 10.1039/A702466E  0.495
1997 Baumann F, Livoreil A, Kaim W, Sauvage J. Changeover in a multimodal copper(ii) catenate as monitored by EPRspectroscopy Chemical Communications. 35-36. DOI: 10.1039/A606282B  0.367
1997 Hosmane NS, Wang Y, Zhang H, Lu KJ, Maguire JA, Gray TG, Brooks KA, Waldhör E, Kaim W, Kremer RK. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 21. Syntheses, structures, EPR spectra, and reactivities of bent-sandwich and half-sandwich titanacarboranes. Full analysis of spin-spin coupling in two structurally characterized titanium(III)-carborane dimers Organometallics. 16: 1365-1377. DOI: 10.1021/Om960890K  0.366
1997 Titze C, Kaim W, Zalis S. Structural Flexibility of the Hydrogen-Free Acceptor Ligand Octachloro-1,10-phenanthroline in Its Complexes with d10Metal Ions Inorganic Chemistry. 36: 2505-2510. DOI: 10.1021/Ic960837O  0.404
1997 Klein A, Kaim W, Hornung FM, Fiedler J, Zalis S. Electronic and molecular structure of 2,2′-bipyrimidine-bridged bis(organoplatinum) complexes in various oxidation states. Radical-bridged diplatinum species and the absence of a Pt(III)/Pt(II) mixed-valent intermediate Inorganica Chimica Acta. 264: 269-278. DOI: 10.1016/S0020-1693(97)05704-6  0.466
1997 Kaim W, Reinhardt R, Fiedler J. Ligand-Mediated Coupling of Organometallic Reaction Centers Angewandte Chemie International Edition in English. 36: 2493-2495. DOI: 10.1002/Anie.199724931  0.33
1996 Titze C, Kaim W. Polychlorinated Biaryl Heterocycles as Potential Ligands. Reactions between Octachloro-1,10-phenanthroline and -2,2′-bipyridine with Copper(I) and Other Metal Ions Zeitschrift FüR Naturforschung B. 51: 981-988. DOI: 10.1515/Znb-1996-0713  0.473
1996 Waldhör E, Zulu MM, Zalis S, Kaim W. Coordination-induced switch between the singly occupied and the lowest unoccupied molecular orbitals in two methylviologen-derived chromophores Journal of the Chemical Society-Perkin Transactions 1. 1197-1204. DOI: 10.1039/P29960001197  0.459
1996 Heilmann O, Hornung FM, Kaim W, Fiedler J. Structure, EPR and UV–VIS and IR spectroelectrochemistry of reversibly reducible compounds [(C5Me5)IrCl(L)](PF6), L = 1,3-dimethyllumazine or 1,3-dimethylalloxazine J. Chem. Soc., Faraday Trans.. 92: 4233-4238. DOI: 10.1039/Ft9969204233  0.465
1996 Heilmann M, Baumann F, Kaim W, Fiedler J. Configuration-dependent electron hopping between equivalent ligands in isomeric ruthenium(II) complexes Journal of the Chemical Society, Faraday Transactions. 92: 4227. DOI: 10.1039/Ft9969204227  0.454
1996 Hosmane NS, Zhang H, Wang Y, Lu K, Thomas CJ, Ezhova MB, Helfert SC, Collins JD, Maguire JA, Gray TG, Baumann F, Kaim W. Electron-Acceptor Behavior Of 2,4,7,9-Tetracarba-Nido-Dodecaborane(12) With Group 1 And Group 2 Metals : Syntheses And Crystal Structures Of (Thf)4Li( Sime3)4C4B8H9 And (Thf)2Mg(Sime3)4C4B8H8 Organometallics. 15: 2425-2427. DOI: 10.1021/Om9509249  0.365
1996 Hosmane NS, Wang Y, Zhang H, Maguire JA, Mclnnis M, Gray TG, Collins JD, Kremer RK, Binder H, Waldhör E, Kaim W. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 20. Synthetic and structural studies on sandwich Ln(III) carborane clusters. II (Ln(III) = Sm, Gd, Dy, Ho, Er) Organometallics. 15: 1006-1013. DOI: 10.1021/Om950780Y  0.328
1996 Klein A, Vogler C, Kaim W. The δ in 18 + δ Electron Complexes:  Importance of the Metal/Ligand Interface for the Substitutional Reactivity of “Re(0)” Complexes (α-diimine-)ReI(CO)3(X) Organometallics. 15: 236-244. DOI: 10.1021/Om950500E  0.469
1996 Fiedler J, Zališ S, Klein A, Hornung FM, Kaim W. Electronic Structure of π-Conjugated Redox Systems with Borane/Borataalkene End Groups Inorganic Chemistry. 35: 3039-3043. DOI: 10.1021/Ic951482W  0.391
1996 Binder H, Riegel B, Heckmann G, Moscherosch M, Kaim W, von Schnering H, Hönle W, Flad H, Savin A. Generation and Characterization of Diphosphene and Triphosphene Radical Anions. Computational Studies on the Structure and Stability of P3H3•- † Inorganic Chemistry. 35: 2119-2126. DOI: 10.1021/Ic950661A  0.404
1996 Kaim W, Reinhardt R, Waldho¨r E, Fiedler J. Electron transfer and chloride ligand dissociation in complexes [(C5Me5)ClM(bpy)]+/[(C5Me5)M(bpy)]n (M=Co, Rh, Ir;n = 2+, +, 0, −): A combined electrochemical and spectroscopic investigation Journal of Organometallic Chemistry. 524: 195-202. DOI: 10.1016/S0022-328X(96)06426-1  0.46
1996 Baumann F, Heilmann M, Matheis W, Schulz A, Kaim W, Jordanov J. Ground state electron transfer between TCNE and one or more 16-electron species containing vanadium, osmium, ruthenium or cobalt Inorganica Chimica Acta. 251: 239-248. DOI: 10.1016/S0020-1693(96)05276-0  0.447
1996 Hilgers F, Bruns W, Fiedler J, Kaim W. UV-vis, IR and EPR spectroelectrochemical study of the EC redox transition [(PR3)n(CO)3(R′-pz)M]+/0; M = Mo, W; R′-pz = N-alkylpyrazinium; R = isopropyl, cyclohexyl; n = 1 or 2 Journal of Organometallic Chemistry. 511: 273-280. DOI: 10.1016/0022-328X(95)05933-G  0.485
1996 Stange AF, Kaim W. Bis(homoleptische) vs. heteroleptische Kupfer(I)-Komplexe: Elektrosynthese, Spektroskopie und Kristallstruktur von {[Cu(BIK)2]+}2{[Cu4(SR)6]2?} � 3(CH3CN) � (RSH); BIK = Bis(N-methylimidazol-2-yl)keton, R = o-Tolyl Zeitschrift F�R Anorganische Und Allgemeine Chemie. 622: 1118-1124. DOI: 10.1002/Zaac.19966220703  0.397
1996 Schwach M, Hausen H, Kaim W. Pulled Molecular Strings and Stacked Molecular Decks: Chelate-Ring Formation vs. Metal–Metal Bridging in Dicopper(I) Complexes of 2,2′-Bipyrimidine with Diphosphine Ligands of Variable Polymethylene Chain Length Chemistry - a European Journal. 2: 446-451. DOI: 10.1002/Chem.19960020414  0.456
1996 Kaim W, Rall J. Copper—A“Modern” Bioelement Angewandte Chemie International Edition in English. 35: 43-60. DOI: 10.1002/Anie.199600431  0.355
1995 Kaim W, Fees J. The New Tetrafunctional π Acceptor Ligand 3,6-Bis(2′-pyrimidyl)-1,2,4,5-tetrazine (bmtz): Diruthenium Complexes of bmtz and of its 1,4-Dihydro Form Zeitschrift FüR Naturforschung B. 50: 123-127. DOI: 10.1515/Znb-1995-0123  0.499
1995 Stange AF, Waldhör E, Moscherosch M, Kaim W. Variable Structure of the Cu2S2 Core in Doubly Thiolate-Bridged Dicopper(I) Complexes. An X-Ray Crystallographic, Electrochemical and EPR Study of (dmp)2(o-CH3C6H4S)2Cu2, dmp = 2,9-Dimethyl-1,10-phenanthroline, and a Comment on the Nature of Phenanthroline-Containing “Cu(0)” Complexes Zeitschrift FüR Naturforschung B. 50: 115-122. DOI: 10.1515/Znb-1995-0122  0.393
1995 Fees J, Hausen H, Kaim W. Molekül- und Kristallstrukturen zweier einkerniger Ruthenium(II)-Komplexe mit dem starken π·Akzeptorliganden 2,2'-Azobis(pyridin) (abpy): [mer-Ru(abpy)3](PF6)2 und Ru(abpy)2Cl2 (ctc-Isomer) / Molecular and Crystal Structures of Two Mononuclear Ruthenium(II) Complexes with the Strongly π Accepting Ligand 2,2'-Azobis(pyridine) (abpy): [mer-Ru(abpy)3](PF6)2 and Ru(abpy)2Cl2 (ctc Isomer) Zeitschrift FüR Naturforschung B. 50: 15-22. DOI: 10.1515/Znb-1995-0104  0.505
1995 Stahl T, Kasack V, Kaim W. Conformational equilibria of 2,5-bis(1-phenyliminoethyl)pyrazine anion radical, bpip˙–. An electron paramagnetic resonance/electron–nuclear double resonance study of bpip˙–, (bpip˙–)(RMg+)2, and of the related anion radical of N-tert-butylpyridine-2-carbaldimine (But-pyca) Journal of the Chemical Society-Perkin Transactions 1. 2127-2131. DOI: 10.1039/P29950002127  0.424
1995 Klein A, Kaim W, Waldhör E, Hausen H. Different orbital occupation by an added single electron in 1,10-phenanthroline and its 3,4,7,8-tetramethyl derivative. Evidence from electron paramagnetic resonance spectroscopy of the anion radicals and of their dimesitylplatinum(II) complexes. X-Ray molecular structure of dimesityl(1,10-phenanthroline)platinum(II) Journal of the Chemical Society-Perkin Transactions 1. 2121-2126. DOI: 10.1039/P29950002121  0.53
1995 Klein A, Kaim W. Axial Shielding of 5d8 and 5d7 Metal Centers in Dimesitylplatinum Complexes with Unsaturated Chelate Ligands: Spectroscopic and Spectroelectrochemical Studies of Four Different Oxidation States Organometallics. 14: 1176-1186. DOI: 10.1021/Om00003A019  0.384
1995 Hosmane NS, Wang Y, Zhang H, Oki AR, Maguire JA, Waldhör E, Kaim W, Binder H, Kremer RK. A systematic synthetic approach to a novel, mixed 2,3-C2B4- and 2,4-C2B4-erbium(III) carborane bent-sandwich complex Organometallics. 14: 1101-1103. DOI: 10.1021/Om00003A009  0.356
1995 Moscherosch M, Waldhoer E, Binder H, Kaim W, Fiedler J. Tetranuclear Pentaammineruthenium Complexes Bridged by .pi.-Conjugated Tetracyano Ligands Related to TCNE: Syntheses and Spectroscopy of Different Oxidation States Inorganic Chemistry. 34: 4326-4335. DOI: 10.1021/Ic00121A010  0.392
1995 Waldhoer E, Poppe J, Kaim W, Cutin EH, Garcia Posse ME, Katz NE. EPR Evidence for Low-Lying MLCT States in Tetracyanoiron and -ruthenium Complexes with Strongly .pi.-Accepting Chelate Ligands. Comparison with Isoelectronic Tetracarbonylmetal Species Inorganic Chemistry. 34: 3093-3096. DOI: 10.1021/Ic00115A042  0.415
1995 Kasack V, Kaim W, Binder H, Jordanov J, Roth E. When Is an Odd-Electron Dinuclear Complex a Mixed-Valent Species? Tuning of Ligand-to-Metal Spin Shifts in Diruthenium(III,II) Complexes of Noninnocent Bridging Ligands OC(R)NNC(R)O Inorganic Chemistry. 34: 1924-1933. DOI: 10.1021/Ic00111A045  0.414
1995 Bruns W, Kaim W, Waldhoer E, Krejcik M. Electronic Structure of the 16 Valence Electron Fragments M(CO)3(PR3)2 (M = Mo, W; R = iPr, Cy) in Their Complexes with H2, THF, and Three .pi.-Conjugated Dinucleating Ligands: Electrochemistry and Spectroscopy of Different Oxidation States Inorganic Chemistry. 34: 663-672. DOI: 10.1021/Ic00107A021  0.43
1995 Ehlend A, Hausen H, Kaim W, Lichtblau A, Schwarz W. Insertion von CO2, COS and CS2 in die NSi-Bindung des extrem elektronenreichen 1,4-Bis(trimethylsilyl) -1,4-dihydropyrazins und Bildung eines neuen poly(N,S-) heterocyclischen Systems durch mehrfache Cycloaddition Journal of Organometallic Chemistry. 501: 283-292. DOI: 10.1016/0022-328X(95)05673-D  0.365
1995 Uhl W, Schütz U, Kaim W, Waldhör E. Das tetraalkyldigallan-radikalanion [R2Ga−GaR2]− [R CH(SiMe3)2] mit langer einelektron-π-bindung Journal of Organometallic Chemistry. 501: 79-85. DOI: 10.1016/0022-328X(95)05618-Y  0.333
1995 Kaim W, Bruns W, Kohlmann S, Krejčik M. Metal—metal interaction in ligand-bridged dimolybdenum(0,0) and -(I,0) complexes with very small frontier orbital gaps: electrochemistry and spectroscopic properties of three neighboring oxidation states Inorganica Chimica Acta. 229: 143-151. DOI: 10.1016/0020-1693(94)04239-R  0.512
1995 Hasenzahl S, Hausen H, Kaim W. A Tale of Two Complexes, [PtMen(RNCHCHNR)] (n = 2 andn = 4, R = Cyclohexyl): Why do PtII and PtIV Complexes Exhibit Virtually Identical Redox Behavior and Colors? Chemistry - a European Journal. 1: 95-99. DOI: 10.1002/Chem.19950010114  0.507
1995 Lichtblau A, Ehlend A, Hausen H, Kaim W. N,N′ -Disilylated 1,4-Dihydropyrazines: Organosilyl Substitution Reactions, Structural Effects of Steric Hindrance, and Electron Exchange with C60 Chemische Berichte. 128: 745-750. DOI: 10.1002/Cber.19951280802  0.439
1995 Bertagnolli H, Kaim W. The Dinuclear CuA Center in Cytochromec Oxidase and N2O Reductase—A Metal–Metal Bond in Biology? Angewandte Chemie International Edition in English. 34: 771-773. DOI: 10.1002/Anie.199507711  0.301
1994 Heilmann O, Hausen H, Kaim W. Organometallic Rhodium(III) and -(I) Complexes with 1,3-Diniethyllumazine(DML). The Crystal Structure of [(η2- (O4,N5)DML)(η5-C5Me5)ClRh](PF6) Zeitschrift FüR Naturforschung B. 49: 1554-1560. DOI: 10.1515/Znb-1994-1117  0.482
1994 Matheis W, Poppe J, Kaim W, Záliš S. Diquaternized heterocycles with strong electronic coupling between a metal-chelating site and a methylviologen-type redox function: EPR/ENDOR detected coordination of metal ions and complexes by radical cation intermediates Journal of the Chemical Society-Perkin Transactions 1. 1923-1928. DOI: 10.1039/P29940001923  0.524
1994 Hilgers F, Kaim W, Schulz A, Záliš S. Electronic absorption spectroscopy of some exceptionally stable 1,4-dialkyl-1,4-dihydro-1,4-diazinium radical cations: assignment of transitions, vibrational structure and effects of π–π dimerization Journal of the Chemical Society-Perkin Transactions 1. 135-138. DOI: 10.1039/P29940000135  0.383
1994 Hornung FM, Kaim W. Oxotungsten(V) and (VI) complexes of 1,3-dimethyllumazine as models for the tungstopterin cofactor Journal of the Chemical Society, Faraday Transactions. 90: 2909. DOI: 10.1039/Ft9949002909  0.42
1994 Rall J, Kaim W. Ligand-controlled oxidation state ambivalence in copper–quinone complexes. Replacement of N-donor by S-donor ligands favours the copper(I)–semiquinone over the copper(II)–catecholate form J. Chem. Soc., Faraday Trans.. 90: 2905-2908. DOI: 10.1039/Ft9949002905  0.485
1994 Hosmane NS, Wang Y, Zhang H, Maguire JA, Waldhör E, Kaim W, Binder H, Kremer RK. Novel bent-sandwich titanium (III) and titanium(IV) organometallics Organometallics. 13: 4156-4158. DOI: 10.1021/Om00023A012  0.317
1994 Kaim W, Reinhardt R, Sieger M. Chemical and Electrochemical Generation of Hydride-Forming Catalytic Intermediates (bpy)M(CnRn): M = Rh, Ir (n = 5); M = Ru, Os (n = 6). Coordinatively Unsaturated Ground State Models of MLCT Excited States? Inorganic Chemistry. 33: 4453-4459. DOI: 10.1021/Ic00098A009  0.336
1994 Hasenzahl S, Kaim W, Stahl T. Charge and electron transfer from metal-to-carbon bonds of main group organometallics MRn (M = Al, Ga, Zn) to aromatic N-heterocycles: colored precursor compounds and radical complex formation Inorganica Chimica Acta. 225: 23-34. DOI: 10.1016/0020-1693(94)04025-7  0.528
1994 Kaim W, Moscherosch M. The coordination chemistry of TCNE, TCNQ and related polynitrileπ acceptors Coordination Chemistry Reviews. 129: 157-193. DOI: 10.1016/0010-8545(94)85020-8  0.493
1994 Kaim W. Thermal and light induced electron transfer reactions of main group metal hydrides and organometallics Topics in Current Chemistry. 169: 231-251. DOI: 10.1007/3-540-57565-0_77  0.385
1993 Vogler C, Kaim W. Dinuclear Bis(phosphane)copper(I) Complexes with 2,2’-Bipyrimidine as Bridging Ligand: Structural Analogy to “Blue” Copper Centers and Reduction to Paramagnetic Species Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 48: 1470-1480. DOI: 10.1515/Znb-1993-1104  0.462
1993 Hausen H, Kaim W, Schulz A, Moscherosch M, Jordanov J. Erstmaliger Nachweis von π–π Dimerenbildung bei stabilen 1,4-Dialkylchinoxalinium-Radikalkationen. Struktur, Spektroskopie und Magnetismus / First Evidence for π-π-Dimerization of the Stable 1,4-Dialkylquinoxalinium Radical Cations. Structure, Spectroscopy and Magnetism Zeitschrift FüR Naturforschung B. 48: 1181-1186. DOI: 10.1515/Znb-1993-0905  0.389
1993 Kaim W, Schulz A, Hilgers F, Hausen HD, Moscherosch M, Lichtblau A, Jordanov J, Roth E, Zalis S. Structure, spectroscopy and magnetism of 1,4-dihydro-1,4-diazine radical cations: Exceptionally stable intermediates related to methylviologen and flavosemiquinone radicals Research On Chemical Intermediates. 19: 603-615. DOI: 10.1163/156856793X00253  0.415
1993 Waldhör E, Schwederski B, Kaim W. Ruthenium(II) coordination to a model for the topasemiquinone cofactor of amine oxidases. Resolution of 1H and 99,101Ru EPR hyperfine structure Journal of the Chemical Society-Perkin Transactions 1. 2109-2111. DOI: 10.1039/P29930002109  0.47
1993 Poppe J, Kaim W, Altabef AB, Katz NE. EPR characteristics of radical complexes with coordinated ammineruthenium(II) fragments. Evidence for the metal-to-ligand charge transfer (MLCT) nature of the low-lying excited states in precursor complexes Journal of the Chemical Society-Perkin Transactions 1. 2105-2108. DOI: 10.1039/P29930002105  0.549
1993 Hausen H, Schulz A, Kaim W. Flavosemiquinone model systems. Part 3. Molecular and crystal structure of the cation radical salt 1,4,6,7-tetramethylquinoxalinium triiodide Journal of the Chemical Society-Perkin Transactions 1. 343-345. DOI: 10.1039/P29930000343  0.354
1993 Moscherosch M, Field JS, Kaim W, Kohlmann S, Krejcik M. ‘Inverse cryptate’ structure of an exceptionally stable dicopper(I) semiquinonoid intermediate Journal of the Chemical Society-Dalton Transactions. 211-216. DOI: 10.1039/Dt9930000211  0.481
1993 Bruns W, Kaim W, Waldhör E, Krejčik M. Spectroelectrochemical characterization of a pyrazine-bridged mixed-valent (4d5/4d6) organometallic analogue of the Creutz–Taube ion Journal of the Chemical Society, Chemical Communications. 1868-1869. DOI: 10.1039/C39930001868  0.382
1993 Schäfer R, Fiedler J, Moscherosch M, Kaim W. First characterization of a tetrathiomolybdate(V) derivative by EPR, UV–VIS and IR spectroelectrochemistry Journal of the Chemical Society, Chemical Communications. 896-897. DOI: 10.1039/C39930000896  0.372
1993 Hosmane NS, Wang Y, Zhang H, Maguire JA, Waldhör E, Kaim W. Synthesis and crystal structure of a novel, TMEDA-stabilized closo-cobalt(II) carborane: An intermediate for anionic, commo-cobalt(III) carborane complexes Organometallics. 12: 3785-3787. DOI: 10.1021/Om00034A001  0.396
1993 Sitzmann H, Bock H, Boese R, Dezember T, Havlas Z, Kaim W, Moscherosch M, Zanathy L. Pentaisopropylcyclopentadienyl: singlet anion, doublet radical, and triplet cation of a carbocyclic .pi. system Journal of the American Chemical Society. 115: 12003-12009. DOI: 10.1021/Ja00078A043  0.528
1993 Krejcik M, Zalis S, Klima J, Sykora D, Matheis W, Klein A, Kaim W. 2,2'-Azobis(pyridine) (abpy) as a multiply reducible tetradentate ligand. EPR evidence for the configurational dependence of intramolecular electron transfer in the stereoisomeric tris-chelate ruthenium complexes [Ru(abpy)n(bpy)3-n]m (n = 2, 3; m = 2+ to 3-) Inorganic Chemistry. 32: 3362-3368. DOI: 10.1021/Ic00067A029  0.504
1993 Poppe J, Moscherosch M, Kaim W. An unusually weak intervalence transition in a very stable bis chelate analog of the ruthenium mixed-valent Creutz-Taube ion. UV/visible/near-IR and EPR spectroelectrochemistry of [(NH3)4Ru(.mu.-bptz)Ru(NH3)4]n+ (bptz = 3,6-bis(2-pyridyl)-1,2,4,5-tetrazine; n = 3 - 5) Inorganic Chemistry. 32: 2640-2643. DOI: 10.1021/Ic00064A012  0.496
1993 Fees J, Kaim W, Moscherosch M, Matheis W, Klima J, Krejcik M, Zalis S. Electronic structure of the "molecular light switch" bis(bipyridine)dipyrido[3,2-a:2',3'-c]phenazineruthenium(2+). Cyclic voltammetric, UV/visible and EPR/ENDOR study of multiply reduced complexes and ligands Inorganic Chemistry. 32: 166-174. DOI: 10.1021/Ic00054A009  0.434
1993 Lichtblau A, Hausen HD, Schwarz W, Kaim W. Inorganic hybrid analogs of Thiele's and Chichibabin's hydrocarbons. Spectroscopy, electrochemistry, and structure Inorganic Chemistry. 32: 73-78. DOI: 10.1021/Ic00053A012  0.372
1993 Kaim W, Kohlmann S, Lees AJ, Snoeck TL, Stufkens DJ, Zulu MM. Reinvestigation of the visible absorption bands of the 2,2′-bipyrimidine complexes W(CO)4(bpym) and (μ-bpym)[M(CO)4]2 (M=Mo, W) with resonance Raman spectroscopy; the emission spectrum of (μ-bpym)[Mo(CO)4]2 Inorganica Chimica Acta. 210: 159-165. DOI: 10.1016/S0020-1693(00)83322-8  0.589
1993 Moscherosch M, Kaim W. A first robust complex of tetradentate TCNQ. Evidence for two weakly coupled diruthenium(II,III) subsystems in symmetrical tetranuclear complexes {(μ4-TCNX)[Ru(NH3)5]4}8+ (TCNX=TCNE, TCNQ) Inorganica Chimica Acta. 206: 229-230. DOI: 10.1016/S0020-1693(00)82872-8  0.499
1993 Bruns W, Hausen H, Kaim W, Schulz A. Wolfram(0)-komplexe des π-aciden N-methylpyrazinium-kations und des N-methylpyrazinium-radikals. Kristall- und molekülstruktur von [(C4H4N2-Me)W(CO)3(PCy3)2] (PF6), Cy  cyclohexyl Journal of Organometallic Chemistry. 444: 121-130. DOI: 10.1016/0022-328X(93)83064-3  0.531
1993 Kaim W, Lichtblau A, Hausen H. Korrelation zwischen struktur und elektronentransferverhalten metallorganischer modellverbindungen für flavine mit “butterfly”-konformation Journal of Organometallic Chemistry. 456: 167-173. DOI: 10.1016/0022-328X(93)80422-8  0.432
1993 Kaim W, Bruns W, Poppe J, Kasack V. Spectroscopy of mixed valent states in dinuclear ions and metalloproteins Journal of Molecular Structure. 292: 221-228. DOI: 10.1016/0022-2860(93)80102-2  0.346
1993 Reinhardt R, Kaim W. α-Diimin-Komplexe des Pentamethylcyclopentadienylrhodiums in verschiedenen Oxidationsstufen Zeitschrift FüR Anorganische Und Allgemeine Chemie. 619: 1998-2005. DOI: 10.1002/Zaac.19936191207  0.357
1992 Vogler C, Kaim W. Mononuclear Bis(triphenylphosphine)copper(I) Complexes of the Bidiazines Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 47: 1057-1062. DOI: 10.1515/Znb-1992-0801  0.393
1992 Wolmershäuser G, Kaim W, Heckmann G, Lichtblau A. Benzo-1,3,2-diselenazol-2-ylium-Salze – Synthese und Reaktivität / Benzo-1,3,2-diselenazolylium Salts – Synthesis and Reactivity Zeitschrift FüR Naturforschung B. 47: 675-679. DOI: 10.1515/Znb-1992-0511  0.371
1992 Krejčík M, Záliš S, Ladwig M, Matheis W, Kaim W. A study of the reduced states of four isomeric bidiazines (diaza-2,2′-bipyridines) by UV–VIS/NIR-spectroelectrochemistry Journal of the Chemical Society-Perkin Transactions 1. 2007-2010. DOI: 10.1039/P29920002007  0.388
1992 Lichtblau A, Kaim W, Schulz A, Stahl T. Organoboron substituent effects in EPR/ENDOR spectroscopy. Radical ions with B–C and B–N bonds Journal of the Chemical Society-Perkin Transactions 1. 1497-1501. DOI: 10.1039/P29920001497  0.436
1992 Moscherosch M, Kaim W. EPR/ENDOR detection of stable TiIII and TiIV radical products generated by single electron transfer from (PriO)3TiCH3 Journal of the Chemical Society-Perkin Transactions 1. 1493-1496. DOI: 10.1039/P29920001493  0.407
1992 Schäfer R, Kaim W, Moscherosch M, Krejčik M. Tetrathiorhenate(VI), ReS42–. Spectroelectrochemical characterization (UV–VIS–IR) of a small new d1 system and of its tetrakis(2,2′-bipyridine)diruthenium(II) complex (EPR) Journal of the Chemical Society, Chemical Communications. 834-835. DOI: 10.1039/C39920000834  0.43
1992 Oki AR, Zhang H, Maguire JA, Hosmane NS, Ro H, Hatfield WE, Moscherosch M, Kaim W. Chemistry of C-trimethylsilyl-substituted heterocarboranes. 10. Syntheses, structures, and properties of anionic chromium(III) and neutral chromium(IV) sandwiched metallacarborane complexes {1,1'-commo-Cr[2-(SiMe3)-3-(R)-2,3-C2B4H4]2}- and 1,1'-commo-Cr[2,3-(SiMe3)2-2,3-C2B4H4]2 (R = SiMe3, Me, and H) Organometallics. 11: 4202-4213. DOI: 10.1021/Om00060A043  0.342
1992 Kaim W, Roth T, Olbrich-Deussner B, Gross-Lannert R, Jordanov J, Roth EKH. Unexpected paramagnetism of mono- and polynuclear 18 valence electron metal carbonyl complexes [(CnRn)(CO)2M]k(L), M = chromium, manganese; k = 1, 2, 4. Implications for photoreactivity Journal of the American Chemical Society. 114: 5693-5697. DOI: 10.1021/Ja00040A031  0.434
1992 Braterman PS, Song JI, Wimmer FM, Wimmer S, Kaim W, Klein A, Peacock RD. Electrochemistry and spectroelectrochemistry (EPR, UV-vis-near-IR) of platinum(II) 2,2′-bipyridine and ring-metalated bipyridine complexes: PtII(L-) and PtI(L-) but not PtI(L) Inorganic Chemistry. 31: 5084-5088. DOI: 10.1021/Ic00050A030  0.472
1992 Bell SE, Field JS, Haines RJ, Moscherosch M, Matheis W, Kaim W. Novel and stable metal-metal-bonded diruthenium(I) complexes containing TCNX0/.bul.- in both the inner and the outer coordination sphere (TCNX = TCNE, TCNQ). A combined EPR/ENDOR-, UV/visible/near-IR-, and IR-spectroscopic and electrochemical investigation Inorganic Chemistry. 31: 3269-3276. DOI: 10.1021/Ic00041A020  0.464
1992 Roth T, Kaim W. Electron-transfer-induced isomerization .eta.2(C:C) .fwdarw. .eta.1(N) of the tetracyanoethylene complex, pentacarbonyl(tetracyanoethylene)tungsten (0/1-) Inorganic Chemistry. 31: 1930-1933. DOI: 10.1021/Ic00036A038  0.479
1992 Braterman PS, Song JI, Vogler C, Kaim W. EPR and absorption spectra of singly reduced mono- and dinuclear diorganoplatinum complexes of heterocyclic .alpha.-diimines Inorganic Chemistry. 31: 222-224. DOI: 10.1021/Ic00028A018  0.328
1992 Schwederski B, Kaim W. Complexes of folic acid, lumiflavin and riboflavin with bis(2, 2′-bipyridine)ruthenium(II). Facilitated formation of flavosemiquinone complexes and substantial decrease of pKa(NH) Inorganica Chimica Acta. 195: 123-126. DOI: 10.1016/S0020-1693(00)83859-1  0.48
1992 Vogler C, Schwederski B, Klein A, Kaim W. Electrochemistry, electron spin resonance, optical spectroscope, and reactivity of organometallic platinum(II) complexes containing strongly π-accepting aromatic α-diimine ligands Journal of Organometallic Chemistry. 436: 367-378. DOI: 10.1016/0022-328X(92)85067-7  0.488
1992 Klein A, Hausen H, Kaim W. Axiale abschirmung des quadratisch-planar konfigurierten platin(II) in strukturell charakterisiertem (bpy)PtMes2: Lumineszenz und elektrochemisch reversible Bildung von Platin(III) Journal of Organometallic Chemistry. 440: 207-217. DOI: 10.1016/0022-328X(92)83497-6  0.436
1992 Schwederski B, Kaim W, Olbrich-Deussner B, Roth T. Electron transfer catalyzed substitution in carbonyl complexes Journal of Organometallic Chemistry. 440: 145-152. DOI: 10.1016/0022-328X(92)83491-Y  0.454
1992 Ladwig M, Kaim W. Electronic structure of catalytic intermediates for production of H2: (C5Me5)Ir(bpy) and its conjugated acid Journal of Organometallic Chemistry. 439: 79-90. DOI: 10.1016/0022-328X(92)80055-3  0.44
1991 Kaim W, Matheis W. Bis(1,4-di-tert-butyl-1,4-diazabutadiene)gallium is not a gallium(II) compound Journal of the Chemical Society, Chemical Communications. 597-598. DOI: 10.1039/C39910000597  0.414
1991 Kaim W, Olbrich-Deussner B, Roth T. Specific solvatochromism of the prototypical olefin complexes (.eta.2-TCNE)M(CO)5 (M = chromium, tungsten) resulting from n and .pi. donation of aprotic solvents toward the .pi.-acceptor ligand Organometallics. 10: 410-415. DOI: 10.1021/Om00048A015  0.389
1991 Kaupp M, Stoll H, Preuss H, Kaim W, Stahl T, Van Koten G, Wissing E, Smeets WJJ, Spek AL. Theoretical and experimental study of diamagnetic and paramagnetic products from thermal and light-induced alkyl transfer between zinc or magnesium dialkyls and 1,4-diaza-1,3-butadiene substrates Journal of the American Chemical Society. 113: 5606-5618. DOI: 10.1021/Ja00015A014  0.44
1991 Matheis W, Kaim W. Electronic structure of heterodinuclear complexes (bpy)2RuII-(μ-bpym)MLn; bpy=2,2′-bipyridine; bpym=2,2′-bipyrimidine; MLn=+Cu(PPh3)2, Mo(CO)4, Re(CO)3Cl Inorganica Chimica Acta. 181: 15-21. DOI: 10.1016/S0020-1693(00)85254-8  0.428
1991 Ladwig M, Kaim W. Spectroscopic and electrochemical properties of the isomeric bidiazine complexes [(C5Me5)CiRh(bdz)]+ and (C5Me5)Rh(bdz) and their relevance to the catalysis of the 2 H+ → H2 reaction by 2,2′-bipyridine analogues Journal of Organometallic Chemistry. 419: 233-243. DOI: 10.1016/0022-328X(91)86178-S  0.473
1991 Stufkens DJ, Snoeck TL, Kaim W, Roth T, Olbrich-Deussner B. Resonance raman study of (η2-TCNE)M(CO)5 (M = Cr, W; TCNE = tetracyanoethene). Evidence for an olefin-complex → metallacyclopropane transition upon low-energy metal-to-ligand charge-transfer excitation Journal of Organometallic Chemistry. 409: 189-195. DOI: 10.1016/0022-328X(91)86144-F  0.624
1991 Braterman PS, Song JI, Kohlmann S, Vogler C, Kaim W. Spectroelectrochemistry of aromatic ligands and their derivatives. III. Binuclear transition metal complexes of CuI, Mo0, and ReI with 2,2′-bipyrimidine Journal of Organometallic Chemistry. 411: 207-213. DOI: 10.1016/0022-328X(91)86019-M  0.479
1991 Kaim W, Kohlmann S, Jordanov J, Fenske D. Kantenverkn�pfung zweier Metallchelat-F�nfringe: Strukturen und Magnetismus von Mo0-, CuI- und CoII- Komplexen mit dem ?S-Frame?-Liganden Azo-2,2?-pyridin Zeitschrift F�R Anorganische Und Allgemeine Chemie. 598: 217-234. DOI: 10.1002/Zaac.19915980120  0.469
1991 Schulz A, Kaim W. Elektrochemische und spektroskopische Charakterisierung von N,N′‐Dialkylchinoxalinium‐Redoxsystemen Chemische Berichte. 124: 129-139. DOI: 10.1002/Cber.19911240121  0.406
1991 Kaim W. Book Review: Metals and Ligand Reactivity. By E. C. Constable Angewandte Chemie. 30: 1384-1385. DOI: 10.1002/Anie.199113842  0.327
1991 Kaim W. Metals and Ligand Reactivity. Von E. C. Constable. Ellis Horwood, New York 1990. XII, 246 S., geb. $ 54.50. ‐ ISBN 0‐13‐577222‐2 Angewandte Chemie. 103: 624-625. DOI: 10.1002/Ange.19911030544  0.335
1990 Matheis W, Kaim W. A first radical cation chelate ligand: electron paramagnetic resonance spectra of singly reduced 3,3′-diazamethylviologen, DAMV˙+and the rhenium(I) complex [(DAMV˙+)Re+(CO)3(PPh3)]2+ J. Chem. Soc., Faraday Trans.. 86: 3337-3339. DOI: 10.1039/Ft9908603337  0.479
1990 Kaim W, Ernst S, Kasack V. ESR of homo- and heteroleptic mono- and dinuclear tris(.alpha.-diimine)ruthenium radical complexes Journal of the American Chemical Society. 112: 173-178. DOI: 10.1021/Ja00157A028  0.442
1990 Gross-Lannert R, Kaim W, Olbrich-Deussner B. Electron delocalization in molecule-bridged polymetallic systems. Unique neutral complexes of TCNE or TCNQ and up to four organometallic fragments (C5R5)(CO)2Mn Inorganic Chemistry. 29: 5046-5053. DOI: 10.1021/Ic00350A009  0.48
1990 Kaim W, Kasack V. Stability rules for d5/d6 mixed-valent dimers. Effects from the donor/acceptor capability of the metal (ruthenium vs osmium) and from the occupancy of the mediating ligand orbital (LUMO vs HOMO) Inorganic Chemistry. 29: 4696-4699. DOI: 10.1021/Ic00348A022  0.414
1990 Kaim W, Kohlmann S. The nature of reduced and excited states of .pi.-electron-deficient complexes between tricarbonylhalorhenium and diimine ligands Inorganic Chemistry. 29: 2909-2914. DOI: 10.1021/Ic00341A010  0.416
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