Donna G. Blackmond - Publications

Affiliations: 
Imperial College, London, London, England, United Kingdom 
Area:
asymmetric catalysis
Website:
http://www3.imperial.ac.uk/people/d.blackmond

167 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2022 Hao W, Joe CL, Darù A, Ayers S, Ramirez A, Sandhu B, Daley RA, Chen JS, Schmidt MA, Blackmond DG. Kinetic and Thermodynamic Considerations in the Rh-Catalyzed Enantioselective Hydrogenation of 2-Pyridyl-Substituted Alkenes. Acs Catalysis. 12: 5961-5969. PMID 37727697 DOI: 10.1021/acscatal.2c00231  0.332
2022 Wei B, Sharland JC, Blackmond DG, Musaev DG, Davies HML. In-situ Kinetic Studies of Rh(II)-Catalyzed C-H Functionalization to Achieve High Catalyst Turnover Numbers. Acs Catalysis. 12: 13400-13410. PMID 37274060 DOI: 10.1021/acscatal.2c04115  0.349
2022 Hao W, Joe CL, Ayers S, Darù A, Daley RA, Chen JS, Domanski M, Schmidt MA, Blackmond DG. Ru-Catalyzed Enantioselective Hydrogenation of 2-Pyridyl-Substituted Alkenes and Substrate-Mediated H/D Exchange. Acs Catalysis. 12: 1150-1160. PMID 36386561 DOI: 10.1021/acscatal.1c05061  0.781
2022 Ali C, Blackmond DG, Burés J. Kinetic Rationalization of Nonlinear Effects in Asymmetric Catalytic Cascade Reactions under Curtin-Hammett Conditions. Acs Catalysis. 12: 5776-5785. PMID 35633899 DOI: 10.1021/acscatal.2c00783  0.75
2022 Gnaim S, Bauer A, Zhang HJ, Chen L, Gannett C, Malapit CA, Hill DE, Vogt D, Tang T, Daley RA, Hao W, Zeng R, Quertenmont M, Beck WD, Kandahari E, ... ... Blackmond DG, et al. Cobalt-electrocatalytic HAT for functionalization of unsaturated C-C bonds. Nature. 605: 687-695. PMID 35614246 DOI: 10.1038/s41586-022-04595-3  0.719
2021 Huang Y, Knouse KW, Qiu S, Hao W, Padial NM, Vantourout JC, Zheng B, Mercer SE, Lopez-Ogalla J, Narayan R, Olson RE, Blackmond DG, Eastgate MD, Schmidt MA, McDonald IM, et al. A P(V) platform for oligonucleotide synthesis. Science (New York, N.Y.). 373: 1265-1270. PMID 34516793 DOI: 10.1126/science.abi9727  0.389
2021 Barton LM, Chen L, Blackmond DG, Baran PS. Electrochemical borylation of carboxylic acids. Proceedings of the National Academy of Sciences of the United States of America. 118. PMID 34404720 DOI: 10.1073/pnas.2109408118  0.466
2021 Gao Y, Hill DE, Hao W, McNicholas BJ, Vantourout JC, Hadt RG, Reisman SE, Blackmond DG, Baran PS. Electrochemical Nozaki-Hiyama-Kishi Coupling: Scope, Applications, and Mechanism. Journal of the American Chemical Society. PMID 34128671 DOI: 10.1021/jacs.1c03007  0.715
2021 Legnani L, Darù A, Jones AX, Blackmond DG. Mechanistic Insight into the Origin of Stereoselectivity in the Ribose-Mediated Strecker Synthesis of Alanine. Journal of the American Chemical Society. PMID 33979125 DOI: 10.1021/jacs.1c03552  0.784
2020 Hill DE, Yu JQ, Blackmond DG. Insights into the Role of Transient Chiral Mediators and Pyridone Ligands in Asymmetric Pd-Catalyzed C-H Functionalization. The Journal of Organic Chemistry. PMID 32991170 DOI: 10.1021/acs.joc.0c01798  0.407
2020 Murray JI, Sanders JN, Richardson PF, Houk KN, Blackmond DG. Isotopically-Directed Symmetry Breaking and Enantioenrichment in Attrition-Enhanced Deracemization. Journal of the American Chemical Society. PMID 32027134 DOI: 10.1021/Jacs.9B11422  0.333
2020 Schmidt OP, Blackmond DG. Temperature-Scanning Reaction Protocol Offers Insights into Activation Parameters in the Buchwald–Hartwig Pd-Catalyzed Amination of Aryl Halides Acs Catalysis. 10: 8926-8932. DOI: 10.1021/Acscatal.0C01929  0.361
2020 Schmidt OP, Dechert‐Schmitt A, Garnsey MR, Wisniewska HM, Blackmond DG. Corrigendum: Kinetic Analysis of Catalytic Organic Reactions Using a Temperature Scanning Protocol Chemcatchem. DOI: 10.1002/Cctc.202000437  0.399
2019 Blackmond DG. Autocatalytic Models for the Origin of Biological Homochirality. Chemical Reviews. PMID 31797671 DOI: 10.1021/Acs.Chemrev.9B00557  0.418
2019 Hawbaker NA, Blackmond DG. Energy threshold for chiral symmetry breaking in molecular self-replication. Nature Chemistry. 11: 957-962. PMID 31548669 DOI: 10.1038/S41557-019-0321-Y  0.326
2019 Xiang J, Shang M, Kawamata Y, Lundberg H, Reisberg SH, Chen M, Mykhailiuk P, Beutner G, Collins MR, Davies A, Del Bel M, Gallego GM, Spangler JE, Starr J, Yang S, ... Blackmond DG, et al. Hindered dialkyl ether synthesis with electrogenerated carbocations. Nature. PMID 31501569 DOI: 10.1038/S41586-019-1539-Y  0.804
2019 Wisniewski SR, Savage SA, Romero EO, Eastgate MD, Tan Y, Simmons EM, Plata RE, Sowa JR, Blackmond DG. Utilizing Native Directing Groups: Mechanistic Understanding of a Direct Arylation Leads to Formation of Tetracyclic Heterocycles via Tandem Intermolecular, Intramolecular C-H Activation. The Journal of Organic Chemistry. PMID 31117568 DOI: 10.1021/Acs.Joc.9B00823  0.446
2019 Wei B, Sharland JC, Lin P, Wilkerson-Hill SM, Fullilove FA, McKinnon S, Blackmond DG, Davies HML. In Situ Kinetic Studies of Rh(II)-Catalyzed Asymmetric Cyclopropanation with Low Catalyst Loadings Acs Catalysis. 10: 1161-1170. DOI: 10.1021/Acscatal.9B04595  0.419
2019 Dechert-Schmitt A, Garnsey MR, Wisniewska HM, Murray JI, Lee T, Kung DW, Sach N, Blackmond DG. Highly Modular Synthesis of 1,2-Diketones via Multicomponent Coupling Reactions of Isocyanides as CO Equivalents Acs Catalysis. 9: 4508-4515. DOI: 10.1021/Acscatal.9B00581  0.401
2019 Schmidt OP, Dechert‐Schmitt A, Garnsey MR, Wisniewska HM, Blackmond DG. Kinetic Analysis of Catalytic Organic Reactions Using a Temperature Scanning Protocol Chemcatchem. 11: 3808-3813. DOI: 10.1002/Cctc.201900560  0.399
2018 Wang J, Shang M, Lundberg H, Feu KS, Hecker SJ, Qin T, Blackmond DG, Baran PS. Cu-Catalyzed Decarboxylative Borylation. Acs Catalysis. 8: 9537-9542. PMID 30505624 DOI: 10.1021/Acscatal.8B02928  0.784
2018 Hawbaker NA, Blackmond DG. Rationalization of Asymmetric Amplification via Autocatalysis Triggered by Isotopically Chiral Molecules. Acs Central Science. 4: 776-780. PMID 29974074 DOI: 10.1021/Acscentsci.8B00297  0.416
2018 Wang J, Lundberg H, Asai S, Martín-Acosta P, Chen JS, Brown S, Farrell W, Dushin RG, O'Donnell CJ, Ratnayake AS, Richardson P, Liu Z, Qin T, Blackmond DG, Baran PS. Kinetically guided radical-based synthesis of C(sp)-C(sp) linkages on DNA. Proceedings of the National Academy of Sciences of the United States of America. PMID 29946037 DOI: 10.1073/Pnas.1806900115  0.769
2018 Hawbaker N, Blackmond D. Elucidating the Role of Isotopically Chiral Initiators in the Soai Asymmetric Autocatalytic Reaction Chemrxiv. DOI: 10.26434/Chemrxiv.5787984.V1  0.441
2018 Mower MP, Blackmond DG. In-Situ Monitoring of Enantiomeric Excess During a Catalytic Kinetic Resolution Acs Catalysis. 8: 5977-5982. DOI: 10.1021/Acscatal.8B01411  0.442
2018 Hill DE, Pei Q, Zhang E, Gage JR, Yu J, Blackmond DG. A General Protocol for Addressing Speciation of the Active Catalyst Applied to Ligand-Accelerated Enantioselective C(sp3)–H Bond Arylation Acs Catalysis. 8: 1528-1531. DOI: 10.1021/Acscatal.8B00103  0.461
2017 Hill DE, Bay KL, Yang YF, Plata RE, Takise R, Houk KN, Yu JQ, Blackmond DG. Dynamic Ligand Exchange as a Mechanistic Probe in Pd-Catalyzed Enantioselective C-H Functionalization Reactions Using Monoprotected Amino Acid Ligands. Journal of the American Chemical Society. PMID 29215885 DOI: 10.1021/Jacs.7B11962  0.525
2017 Plata RE, Hill DE, Haines BE, Musaev DG, Chu L, Hickey DP, Sigman MS, Yu JQ, Blackmond DG. A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization With Monoprotected Amino Acid Ligands Under Mild Conditions. Journal of the American Chemical Society. PMID 28605190 DOI: 10.1021/Jacs.7B03716  0.542
2017 Wagner AJ, Zubarev DY, Aspuru-Guzik A, Blackmond DG. Chiral Sugars Drive Enantioenrichment in Prebiotic Amino Acid Synthesis. Acs Central Science. 3: 322-328. PMID 28470050 DOI: 10.1021/Acscentsci.7B00085  0.405
2017 Liu WB, Schuman DP, Yang YF, Toutov AA, Liang Y, Klare HF, Nesnas N, Oestreich M, Blackmond DG, Virgil SC, Banerjee S, Zare RN, Grubbs RH, Houk KN, Stoltz BM. KOt-Bu-Catalyzed Dehydrogenative C-H Silylation of Heteroaromatics: A Combined Experimental and Computational Mechanistic Study. Journal of the American Chemical Society. PMID 28403611 DOI: 10.1021/Jacs.6B13031  0.374
2017 Gallagher WP, Soumeillant M, Chen K, Fox RJ, Hsiao Y, Mack B, Iyer V, Fan J, Zhu J, Beutner G, Silverman SM, Fanfair DD, Glace AW, Freitag A, Sweeney J, ... ... Blackmond DG, et al. Preparation of the HIV Attachment Inhibitor BMS-663068. Part 7. Development of a Regioselective Ullmann–Goldberg–Buchwald Reaction Organic Process Research & Development. 21: 1156-1165. DOI: 10.1021/Acs.Oprd.7B00191  0.372
2016 Stich M, Ribó JM, Blackmond DG, Hochberg D. Necessary conditions for the emergence of homochirality via autocatalytic self-replication. The Journal of Chemical Physics. 145: 074111. PMID 27544091 DOI: 10.1063/1.4961021  0.352
2016 Shi Q, Mower MP, Blackmond DG, Rebek J. Water-soluble cavitands promote hydrolyses of long-chain diesters. Proceedings of the National Academy of Sciences of the United States of America. PMID 27482089 DOI: 10.1073/Pnas.1610006113  0.366
2016 Masseroni D, Mosca S, Mower MP, Blackmond DG, Rebek J. Cavitands as Reaction Vessels and Blocking Groups for Selective Reactions in Water. Angewandte Chemie (International Ed. in English). PMID 27254667 DOI: 10.1002/Anie.201602355  0.401
2016 O'Brien AG, Luca OR, Baran PS, Blackmond DG. In Situ FTIR Spectroscopic Monitoring of Electrochemically Controlled Organic Reactions in a Recycle Reactor. Reaction Chemistry & Engineering. 1: 90-95. PMID 27069673 DOI: 10.1039/C5Re00050E  0.78
2016 Burés J, Armstrong A, Blackmond DG. Explaining Anomalies in Enamine Catalysis: "Downstream Species" as a New Paradigm for Stereocontrol. Accounts of Chemical Research. PMID 26830669 DOI: 10.1021/Acs.Accounts.5B00394  0.76
2016 Hawbaker N, Wittgrove E, Christensen B, Sach N, Blackmond DG. Dispersion in Compartmentalized Flow Systems: Influence of Flow Patterns on Reactivity Organic Process Research & Development. 20: 465-473. DOI: 10.1021/Op500360W  0.318
2015 Blackmond DG. Correction to "Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool". Journal of the American Chemical Society. PMID 26703088 DOI: 10.1021/Jacs.5B12722  0.416
2015 Baxter RD, Liang Y, Hong X, Brown TA, Zare RN, Houk KN, Baran PS, Blackmond DG. Mechanistic Insights into Two-Phase Radical C-H Arylations. Acs Central Science. 1: 456-462. PMID 26640819 DOI: 10.1021/Acscentsci.5B00332  0.557
2015 Ji Y, Plata RE, Regens CS, Hay M, Schmidt M, Razler T, Qiu Y, Geng P, Hsiao Y, Rosner T, Eastgate MD, Blackmond DG. Mono-Oxidation of Bidentate Bis-phosphines in Catalyst Activation: Kinetic and Mechanistic Studies of a Pd/Xantphos-Catalyzed C-H Functionalization. Journal of the American Chemical Society. 137: 13272-81. PMID 26461028 DOI: 10.1021/Jacs.5B01913  0.41
2015 Blackmond DG. Kinetic Profiling of Catalytic Organic Reactions as a Mechanistic Tool. Journal of the American Chemical Society. 137: 10852-66. PMID 26285166 DOI: 10.1021/Jacs.5B05841  0.461
2015 Ruiz-Castillo P, Blackmond DG, Buchwald SL. Rational ligand design for the arylation of hindered primary amines guided by reaction progress kinetic analysis. Journal of the American Chemical Society. 137: 3085-92. PMID 25651374 DOI: 10.1021/Ja512903G  0.383
2015 Mower MP, Blackmond DG. Mechanistic rationalization of unusual sigmoidal kinetic profiles in the Machetti-De Sarlo cycloaddition reaction. Journal of the American Chemical Society. 137: 2386-91. PMID 25611219 DOI: 10.1021/Ja512753V  0.467
2015 Ji Y, Benkovics T, Beutner GL, Sfouggatakis C, Eastgate MD, Blackmond DG. Mechanistic insights into the vanadium-catalyzed Achmatowicz rearrangement of furfurol. The Journal of Organic Chemistry. 80: 1696-702. PMID 25562708 DOI: 10.1021/Jo502641D  0.444
2015 Mower MP, Blackmond DG. Mechanistic rationalization of unusual sigmoidal kinetic profiles in the machetti-de sarlo cycloaddition reaction Journal of the American Chemical Society. 137: 2386-2391. DOI: 10.1021/ja512753v  0.326
2014 O'Brien AG, Maruyama A, Inokuma Y, Fujita M, Baran PS, Blackmond DG. Radical C-H functionalization of heteroarenes under electrochemical control. Angewandte Chemie (International Ed. in English). 53: 11868-71. PMID 25209429 DOI: 10.1002/Anie.201407948  0.549
2014 Burés J, Dingwall P, Armstrong A, Blackmond DG. Rationalization of an unusual solvent-induced inversion of enantiomeric excess in organocatalytic selenylation of aldehydes. Angewandte Chemie (International Ed. in English). 53: 8700-4. PMID 25044727 DOI: 10.1002/Anie.201404327  0.749
2014 Ji Y, Blackmond DG. The role of reversibility in the enantioselective conjugate addition of α,α-disubstituted aldehydes to nitro-olefins catalyzed by primary amine thioureas Catalysis Science and Technology. 4: 3505-3509. DOI: 10.1039/C4Cy00648H  0.453
2013 O'Hara F, Blackmond DG, Baran PS. Radical-based regioselective C-H functionalization of electron-deficient heteroarenes: scope, tunability, and predictability. Journal of the American Chemical Society. 135: 12122-34. PMID 23859263 DOI: 10.1021/Ja406223K  0.55
2013 Hein JE, Gherase D, Blackmond DG. Chemical and physical models for the emergence of biological homochirality Topics in Current Chemistry. 333: 83-108. PMID 23271377 DOI: 10.1007/128_2012_397  0.617
2013 Burés J, Armstrong A, Blackmond DG. The interplay of thermodynamics and kinetics in dictating organocatalytic reactivity and selectivity Pure and Applied Chemistry. 85: 1919-1934. DOI: 10.1351/Pac-Con-13-01-14  0.464
2013 Baxter RD, Blackmond DG. In situ kinetic studies of the trifluoromethylation of caffeine with Zn(SO2CF3)2 Tetrahedron. 69: 5604-5608. DOI: 10.1016/J.Tet.2013.04.007  0.369
2012 Hein JE, Cao BH, Viedma C, Kellogg RM, Blackmond DG. Pasteur's tweezers revisited: on the mechanism of attrition-enhanced deracemization and resolution of chiral conglomerate solids. Journal of the American Chemical Society. 134: 12629-36. PMID 22779695 DOI: 10.1021/Ja303566G  0.611
2012 Burés J, Armstrong A, Blackmond DG. Curtin-Hammett paradigm for stereocontrol in organocatalysis by diarylprolinol ether catalysts. Journal of the American Chemical Society. 134: 6741-50. PMID 22452319 DOI: 10.1021/Ja300415T  0.761
2012 Hein JE, Blackmond DG. On the origin of single chirality of amino acids and sugars in biogenesis Accounts of Chemical Research. 45: 2045-2054. PMID 22353168 DOI: 10.1021/Ar200316N  0.658
2012 Baxter RD, Sale D, Engle KM, Yu JQ, Blackmond DG. Mechanistic rationalization of unusual kinetics in Pd-catalyzed C-H olefination. Journal of the American Chemical Society. 134: 4600-6. PMID 22324814 DOI: 10.1021/Ja207634T  0.437
2012 Fujiwara Y, Dixon JA, Rodriguez RA, Baxter RD, Dixon DD, Collins MR, Blackmond DG, Baran PS. A new reagent for direct difluoromethylation. Journal of the American Chemical Society. 134: 1494-7. PMID 22229949 DOI: 10.1021/Ja211422G  0.527
2012 Burés J, Armstrong A, Blackmond DG. Kinetic correlation between aldehyde/enamine stereoisomers in reactions between aldehydes with α -stereocenters and chiral pyrrolidine-based catalysts Chemical Science. 3: 1273-1277. DOI: 10.1039/C2Sc01082H  0.485
2012 Burés J, Armstrong A, Blackmond DG. Correction to Curtin–Hammett Paradigm for Stereocontrol in Organocatalysis by Diarylprolinol Ether Catalysts Journal of the American Chemical Society. 134: 14264-14264. DOI: 10.1021/Ja307209V  0.334
2011 Hein JE, Burés J, Lam YH, Hughes M, Houk KN, Armstrong A, Blackmond DG. Enamine carboxylates as stereodetermining intermediates in prolinate catalysis. Organic Letters. 13: 5644-7. PMID 21958394 DOI: 10.1021/Ol2023533  0.792
2011 Blackmond DG. The origin of biological homochirality Philosophical Transactions of the Royal Society B: Biological Sciences. 366: 2878-2884. PMID 21930578 DOI: 10.1098/Rstb.2011.0130  0.321
2011 Hein JE, Tse E, Blackmond DG. A route to enantiopure RNA precursors from nearly racemic starting materials Nature Chemistry. 3: 704-706. PMID 21860459 DOI: 10.1038/Nchem.1108  0.657
2011 Ji Y, Brueckl T, Baxter RD, Fujiwara Y, Seiple IB, Su S, Blackmond DG, Baran PS. Innate C-H trifluoromethylation of heterocycles. Proceedings of the National Academy of Sciences of the United States of America. 108: 14411-5. PMID 21844378 DOI: 10.1073/Pnas.1109059108  0.531
2011 Hein JE, Armstrong A, Blackmond DG. Kinetic profiling of prolinate-catalyzed α-amination of aldehydes Organic Letters. 13: 4300-4303. PMID 21761822 DOI: 10.1021/Ol201639Z  0.693
2011 Burés J, Armstrong A, Blackmond DG. Mechanistic rationalization of organocatalyzed conjugate addition of linear aldehydes to nitro-olefins. Journal of the American Chemical Society. 133: 8822-5. PMID 21568340 DOI: 10.1021/Ja203660R  0.755
2011 Hein JE, Tse E, Blackmond DG. Enantiopure RNA Precursors from Nearly Racemic Starting Materials Synfacts. 2011: 1361-1361. DOI: 10.1055/S-0031-1289369  0.567
2011 Ferretti AC, Brennan C, Blackmond DG. Reservoir catalysis: Rationalization of anomalous reaction orders in Pd-catalyzed amination of aryl halides Inorganica Chimica Acta. 369: 292-295. DOI: 10.1016/J.Ica.2011.01.018  0.467
2010 Quaranta M, Gehring T, Odell B, Brown JM, Blackmond DG. Unusual inverse temperature dependence on reaction rate in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes. Journal of the American Chemical Society. 132: 15104-7. PMID 20942400 DOI: 10.1021/Ja103204W  0.43
2010 Blackmond DG, Moran A, Hughes M, Armstrong A. Unusual reversal of enantioselectivity in the proline-mediated α-amination of aldehydes induced by tertiary amine additives Journal of the American Chemical Society. 132: 7598-7599. PMID 20465280 DOI: 10.1021/Ja102718X  0.383
2010 Blackmond DG, Moran A, Hughes M, Armstrong A. Inversion of Enantioselectivity in Proline Catalysis by BasicAdditives Synfacts. 2010: 950-950. DOI: 10.1055/S-0030-1257799  0.388
2010 Blackmond DG. Kinetic aspects of non-linear effects in asymmetric synthesis, catalysis, and autocatalysis Tetrahedron Asymmetry. 21: 1630-1634. DOI: 10.1016/J.Tetasy.2010.03.034  0.425
2009 Zotova N, Broadbelt LJ, Armstrong A, Blackmond DG. Kinetic and mechanistic studies of proline-mediated direct intermolecular aldol reactions Bioorganic and Medicinal Chemistry Letters. 19: 3934-3937. PMID 19362473 DOI: 10.1016/J.Bmcl.2009.03.112  0.445
2009 Blackmond DG. "If pigs could fly" chemistry: a tutorial on the principle of microscopic reversibility. Angewandte Chemie (International Ed. in English). 48: 2648-54. PMID 19117002 DOI: 10.1002/Anie.200804566  0.415
2009 Blackmond DG. An examination of the role of autocatalytic cycles in the chemistry of proposed primordial reactions Angewandte Chemie - International Edition. 48: 386-390. PMID 19053125 DOI: 10.1002/Anie.200804565  0.392
2009 Blackmond DG. Challenging the concept of "recycling" as a mechanism for the evolution of homochirality in chemical reactions Chirality. 21: 359-362. PMID 18570293 DOI: 10.1002/Chir.20592  0.41
2009 Klussmann M, Blackmond DG. Origin of homochirality Acs Symposium Series. 1025: 133-145. DOI: 10.1021/bk-2009-1025.ch007  0.552
2009 Zotova N, Moran A, Armstrong A, Blackmond DG. A coherent mechanistic rationale for additive effects and autoinductive behaviour in proline-mediated reactions Advanced Synthesis and Catalysis. 351: 2765-2769. DOI: 10.1002/Adsc.200900665  0.437
2008 Viedma C, Ortiz JE, De Torres T, Izumi T, Blackmond DG. Evolution of solid phase homochirality for a proteinogenic amino acid Journal of the American Chemical Society. 130: 15274-15275. PMID 18954052 DOI: 10.1021/Ja8074506  0.326
2008 Blackmond DG, Matar OK. Re-examination of reversibility in reaction models for the spontaneous emergence of homochirality Journal of Physical Chemistry B. 112: 5098-5104. PMID 18370430 DOI: 10.1021/Jp7118586  0.423
2008 Noorduin WL, Izumi T, Millemaggi A, Leeman M, Meekes H, Van Enckevort WJ, Kellogg RM, Kaptein B, Vlieg E, Blackmond DG. Emergence of a single solid chiral state from a nearly racemic amino acid derivative. Journal of the American Chemical Society. 130: 1158-9. PMID 18173274 DOI: 10.1021/Ja7106349  0.327
2008 Blackmond DG. Response to "comment on 'a Re-examination of reversibility in reaction models for the spontaneous emergence of homochirality"' Journal of Physical Chemistry B. 112: 9553-9555. DOI: 10.1021/Jp8040378  0.36
2007 Zotova N, Franzke A, Armstrong A, Blackmond DG. Clarification of the role of water in proline-mediated aldol reactions Journal of the American Chemical Society. 129: 15100-15101. PMID 18001021 DOI: 10.1021/Ja0738881  0.395
2007 Blackmond DG, Klussmann M. Spoilt for choice: Assessing phase behavior models for the evolution of homochirality Chemical Communications. 3990-3996. PMID 17912393 DOI: 10.1039/B709314B  0.638
2007 Klussmann M, Izumi T, White AJP, Armstrong A, Blackmond DG. Emergence of solution-phase homochirality via crystal engineering of amino acids Journal of the American Chemical Society. 129: 7657-7660. PMID 17530759 DOI: 10.1021/Ja0708870  0.643
2007 Phua PH, Mathew SP, White AJ, de Vries JG, Blackmond DG, Hii KK. Elucidating the mechanism of the asymmetric aza-Michael reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 4602-13. PMID 17352437 DOI: 10.1002/Chem.200601706  0.419
2007 Ferretti AC, Mathew JS, Blackmond DG. Reaction calorimetry as a tool for understanding reaction mechanisms: Application to Pd-catalyzed reactions Industrial and Engineering Chemistry Research. 46: 8584-8589. DOI: 10.1021/Ie070050D  0.478
2007 Blackmond DG, Klussmann M. Investigating the evolution of biomolecular homochirality Aiche Journal. 53: 2-8. DOI: 10.1002/Aic.11024  0.611
2006 Klussmann M, Mathew SP, Iwamura H, Wells DH, Armstrong A, Blackmond DG. Kinetic rationalization of nonlinear effects in asymmetric catalysis based on phase behavior Angewandte Chemie - International Edition. 45: 7989-7992. PMID 17061299 DOI: 10.1002/Anie.200602521  0.627
2006 Mathew SP, Klussmann M, Iwamura H, Wells DH, Armstrong A, Blackmond DG. A mechanistic rationalization of unusual kinetic behavior in proline-mediated C-O and C-N bond-forming reactions. Chemical Communications (Cambridge, England). 4291-3. PMID 17047844 DOI: 10.1039/B609926B  0.701
2006 Klussmann M, White AJP, Armstrong A, Blackmond DG. Rationalization and prediction of solution enantiomeric excess in ternary phase systems Angewandte Chemie - International Edition. 45: 7985-7989. PMID 16986192 DOI: 10.1002/Anie.200602520  0.598
2006 Mathew JS, Klussmann M, Iwamura H, Valera F, Futran A, Emanuelsson EA, Blackmond DG. Investigations of Pd-catalyzed ArX coupling reactions informed by reaction progress kinetic analysis. The Journal of Organic Chemistry. 71: 4711-22. PMID 16776495 DOI: 10.1021/Jo052409I  0.726
2006 Blackmond DG, Hodnett NS, Lloyd-Jones GC. Mechanistic implications of pseudo zero order kinetics in kinetic resolutions Journal of the American Chemical Society. 128: 7450-7451. PMID 16756293 DOI: 10.1021/Ja062173F  0.435
2006 Klussmann M, Iwamura H, Mathew SP, Wells DH, Pandya U, Armstrong A, Blackmond DG. Thermodynamic control of asymmetric amplification in amino acid catalysis Nature. 441: 621-623. PMID 16738656 DOI: 10.1038/Nature04780  0.725
2006 Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. Journal of the American Chemical Society. 128: 3584-91. PMID 16536531 DOI: 10.1021/Ja045533C  0.439
2006 Blackmond DG, Schultz T, Mathew JS, Loew C, Rosner T, Pfaltz A. Comprehensive kinetic screening of palladium catalysts for heck reactions Synlett. 3135-3139. DOI: 10.1055/S-2006-951514  0.421
2006 Mathew SP, Klussmann M, Iwamura H, Wells DH, Armstrong A, Blackmond DG. A mechanistic rationalization of unusual kinetic behavior in proline-mediated C-O and C-N bond-forming reactions Chemical Communications. 4291-4293. DOI: 10.1039/b609926b  0.632
2006 Blackmond DG, Ropic M, Stefinovic M. Kinetic studies of the asymmetric transfer hydrogenation of imines with formic acid catalyzed by Rh-diamine catalysts Organic Process Research and Development. 10: 457-463. DOI: 10.1021/Op060033K  0.49
2006 Mathew JS, Klussmann M, Iwamura H, Valera F, Futran A, Emanuelsson EAC, Blackmond DG. Investigations of Pd-catalyzed ArX coupling reactions informed by reaction progress kinetic analysis Journal of Organic Chemistry. 71: 4711-4722. DOI: 10.1021/jo052409i  0.655
2006 Blackmond DG. Mechanistic study of the Soai autocatalytic reaction informed by kinetic analysis Tetrahedron Asymmetry. 17: 584-589. DOI: 10.1016/J.Tetasy.2006.01.012  0.464
2005 Mathew SP, Gunathilagan S, Roberts SM, Blackmond DG. Mechanistic insights from reaction progress kinetic analysis of the polypeptide-catalyzed epoxidation of chalcone Organic Letters. 7: 4847-4850. PMID 16235904 DOI: 10.1021/Ol051708R  0.472
2005 Reetz MT, Meiswinkel A, Mehler G, Angermund K, Graf M, Thiel W, Mynott R, Blackmond DG. Why are BINOL-based monophosphites such efficient ligands in Rh-catalyzed asymmetric olefin hydrogenation? Journal of the American Chemical Society. 127: 10305-13. PMID 16028942 DOI: 10.1021/Ja052025+  0.419
2005 Blackmond DG. Reaction progress kinetic analysis: A powerful methodology for mechanistic studies of complex catalytic reactions Angewandte Chemie - International Edition. 44: 4302-4320. PMID 15997457 DOI: 10.1002/Anie.200462544  0.447
2005 Arseniyadis S, Subhash PV, Valleix A, Mathew SP, Blackmond DG, Wagner A, Mioskowski C. Tuning the enantioselective N-acetylation of racemic amines: a spectacular salt effect. Journal of the American Chemical Society. 127: 6138-9. PMID 15853296 DOI: 10.1021/Ja051302+  0.357
2005 Strieter ER, Blackmond DG, Buchwald SL. The role of chelating diamine ligands in the goldberg reaction: a kinetic study on the copper-catalyzed amidation of aryl iodides. Journal of the American Chemical Society. 127: 4120-1. PMID 15783164 DOI: 10.1021/Ja050120C  0.391
2005 Blackmond DG. Cover Picture: Reaction Progress Kinetic Analysis: A Powerful Methodology for Mechanistic Studies of Complex Catalytic Reactions (Angew. Chem. Int. Ed. 28/2005) Angewandte Chemie. 44: 4271-4271. DOI: 10.1002/Anie.200590094  0.427
2004 Iwamura H, Wells DH, Mathew SP, Klussmann M, Armstrong A, Blackmond DG. Probing the active catalyst in product-accelerated proline-mediated reactions Journal of the American Chemical Society. 126: 16312-16313. PMID 15600319 DOI: 10.1021/Ja0444177  0.72
2004 Iwamura H, Mathew SP, Blackmond DG. In situ catalyst improvement in the proline-mediated α-amination of aldehydes Journal of the American Chemical Society. 126: 11770-11771. PMID 15382893 DOI: 10.1021/Ja046258X  0.452
2004 Mathew SP, Iwamura H, Blackmond DG. Amplification of enantiomeric excess in a proline-mediated reaction Angewandte Chemie - International Edition. 43: 3317-3321. PMID 15213963 DOI: 10.1002/Anie.200453997  0.436
2004 Buono FG, Iwamura H, Blackmond DG. Physical and chemical rationalization for asymmetric amplification in autocatalytic reactions. Angewandte Chemie (International Ed. in English). 43: 2099-103. PMID 15083455 DOI: 10.1002/Anie.200353086  0.392
2004 Blackmond DG. Asymmetric autocatalysis and its implications for the origin of homochirality. Proceedings of the National Academy of Sciences of the United States of America. 101: 5732-6. PMID 15067112 DOI: 10.1073/Pnas.0308363101  0.478
2004 Nielsen LP, Stevenson CP, Blackmond DG, Jacobsen EN. Mechanistic investigation leads to a synthetic improvement in the hydrolytic kinetic resolution of terminal epoxides. Journal of the American Chemical Society. 126: 1360-2. PMID 14759192 DOI: 10.1021/Ja038590Z  0.436
2004 Richards S, Ropic M, Blackmond D, Walmsley A. Quantitative determination of the catalysed asymmetric transfer hydrogenation of 1-methyl-6,7-dimethoxy-3,4-dihydroisoquinoline using in situ FTIR and multivariate curve resolution Analytica Chimica Acta. 519: 1-9. DOI: 10.1016/J.Aca.2004.05.021  0.399
2004 LeBars J, Dini S, Hawkins JM, Blackmond DG. Mechanistic insights into anomalous kinetic behaviour in the hydrogenation of a substituted nitrobenzene Advanced Synthesis and Catalysis. 346: 943-946. DOI: 10.1002/Adsc.200303202  0.4
2003 Buono FG, Blackmond DG. Kinetic evidence for a tetrameric transition state in the asymmetric autocatalytic alkylation of pyrimidyl aldehydes. Journal of the American Chemical Society. 125: 8978-9. PMID 15369330 DOI: 10.1021/Ja034705N  0.438
2003 Strieter ER, Blackmond DG, Buchwald SL. Insights into the origin of high activity and stability of catalysts derived from bulky, electron-rich monophosphinobiaryl ligands in the Pd-catalyzed C-N bond formation. Journal of the American Chemical Society. 125: 13978-80. PMID 14611232 DOI: 10.1021/Ja037932Y  0.399
2003 Blackmond DG. Erratum: Requiem for the Reaction-Rate Equation? Catalysis Letters. 89: 281-284. DOI: 10.1023/A:1025775015567  0.441
2002 Singh UK, Strieter ER, Blackmond DG, Buchwald SL. Mechanistic insights into the Pd(BINAP)-catalyzed amination of aryl bromides: kinetic studies under synthetically relevant conditions. Journal of the American Chemical Society. 124: 14104-14. PMID 12440909 DOI: 10.1021/Ja026885R  0.421
2002 Buono F, Walsh PJ, Blackmond DG. Rationalization of anomalous nonlinear effects in the alkylation of substituted benzaldehydes Journal of the American Chemical Society. 124: 13652-13653. PMID 12431076 DOI: 10.1021/Ja027406R  0.37
2002 Blackmond DG. Requiem for the reaction rate equation? Catalysis Letters. 83: 133-136. DOI: 10.1023/A:1021041925818  0.425
2002 Blackmond DG. Description of the Condition for Asymmetric Amplification in Autocatalytic Reactions Advanced Synthesis and Catalysis. 344: 156-158. DOI: 10.1002/1615-4169(200202)344:2<156::Aid-Adsc156>3.0.Co;2-1  0.478
2001 Blackmond DG, McMillan CR, Ramdeehul S, Schorm A, Brown JM. Origins of asymmetric amplification in autocatalytic alkylzinc additions [3] Journal of the American Chemical Society. 123: 10103-10104. PMID 11592892 DOI: 10.1021/Ja0165133  0.351
2001 Rosner T, Pfaltz A, Blackmond DG. Observation of unusual kinetics in Heck reactions of aryl halides: The role of non-steady-state catalyst concentration [11] Journal of the American Chemical Society. 123: 4621-4622. PMID 11457257 DOI: 10.1021/Ja005872F  0.434
2001 Rosner T, Le Bars J, Pfaltz A, Blackmond DG. Kinetic studies of heck coupling reactions using palladacycle catalysts: Experimental and kinetic modeling of the role of dimer species Journal of the American Chemical Society. 123: 1848-1855. PMID 11456804 DOI: 10.1021/Ja003191E  0.466
2001 Blackmond DG. Kinetic resolution using enantioimpure catalysts: Mechanistic considerations of complex rate laws Journal of the American Chemical Society. 123: 545-553. PMID 11456566 DOI: 10.1021/Ja002562O  0.44
2001 Le Bars J, Häußner T, Lang J, Pfaltz A, Blackmond DG. A Scale-Transparent Reaction Calorimetric Assay for Rapid Catalyst Selection Advanced Synthesis and Catalysis. 343: 207-214. DOI: 10.1002/1615-4169(20010226)343:2<207::Aid-Adsc207>3.0.Co;2-3  0.44
2001 Blackmond DG. Book Review: Kinetics of Homogeneous Multistep Reactions. By F. G. Helfferich Angewandte Chemie. 40: 4512-4513. DOI: 10.1002/1521-3773(20011203)40:23<4512::Aid-Anie4512>3.0.Co;2-C  0.314
2000 Rosner T, Sears PJ, Nugent WA, Blackmond DG. Kinetic investigations of product inhibition in the amino alcohol-catalyzed asymmetric alkylation of benzaldehyde with diethylzinc Organic Letters. 2: 2511-3. PMID 10956534 DOI: 10.1021/Ol006181R  0.465
2000 Blackmond DG. Kinetic aspects of nonlinear effects in asymmetric catalysis Accounts of Chemical Research. 33: 402-411. PMID 10891058 DOI: 10.1021/Ar990083S  0.433
2000 Blackmond DG, Lightfoot A, Pfaltz A, Rosner T, Schnider P, Zimmermann N. Enantioselective hydrogenation of olefins with phosphinooxazoline-iridium catalysts. Chirality. 12: 442-9. PMID 10824167 DOI: 10.1002/(Sici)1520-636X(2000)12:5/6<442::Aid-Chir25>3.0.Co;2-F  0.416
1999 Blackmond DG, Rosner T, Neugebauer T, Reetz MT. Kinetic Influences on Enantioselectivity for Non-Diastereopure Catalyst Mixtures. Angewandte Chemie (International Ed. in English). 38: 2196-2199. PMID 10425479 DOI: 10.1002/(Sici)1521-3773(19990802)38:15<2196::Aid-Anie2196>3.0.Co;2-9  0.466
1999 Blackmond DG, Rosner T, Pfaltz A. Comprehensive kinetic screening of catalysts using reaction calorimetry Organic Process Research and Development. 3: 275-280. DOI: 10.1021/Op990024U  0.475
1999 Le Bars J, Specht U, Bradley JS, Blackmond DG. Catalytic probe of the surface of colloidal palladium particles using Heck coupling reactions Langmuir. 15: 7621-7625. DOI: 10.1021/La990144V  0.388
1998 Siedlaczek G, Schwickardi M, Kolb U, Bogdanovic B, Blackmond DG. Diastereoselective reductive amination reactions using novel metal-carbon catalysts prepared from inorganic Grignard reagents Catalysis Letters. 55: 67-72. DOI: 10.1023/A:1019026711011  0.444
1998 Blackmond DG. Kinetic implications of nonlinear effects in asymmetric synthesis Journal of the American Chemical Society. 120: 13349-13353. DOI: 10.1021/Ja982448U  0.49
1998 Bohnen FM, Gamez A, Blackmond DG. On the implications of hemiketal formation during ethyl pyruvate hydrogenation in alcohol solvents Journal of Catalysis. 179: 335-338. DOI: 10.1006/Jcat.1998.2247  0.461
1997 Blackmond DG. Mathematical models of nonlinear effects in asymmetric catalysis: New insights based on the role of reaction rate Journal of the American Chemical Society. 119: 12934-12939. DOI: 10.1021/Ja973049M  0.436
1997 Wang J, LeBlond C, Orella CF, Sun Y, Bradley JS, Blackmond DG. Modeling of kinetically coupled selective hydrogenation reactions: Kinetic rationalization of pressure effects on enantioselectivity Studies in Surface Science and Catalysis. 108: 183-190. DOI: 10.1016/S0167-2991(97)80903-2  0.407
1997 Sun Y, Wang J, LeBlond C, Reamer RA, Laquidara J, Sowa JR, Blackmond DG. Kinetic influences on enantioselectivity in asymmetric catalytic hydrogenation Journal of Organometallic Chemistry. 548: 65-72. DOI: 10.1016/S0022-328X(97)00165-4  0.458
1996 Sun Y, Landau RN, Wang J, LeBlond C, Blackmond DG. A re-examination of pressure effects on enantioselectivity in asymmetric catalytic hydrogenation Journal of the American Chemical Society. 118: 1348-1353. DOI: 10.1021/Ja952988G  0.382
1996 LeBlond C, Wang J, Larsen RD, Orella CJ, Forman AL, Landau RN, Laquidara J, Sowa JR, Blackmond DG, Sun YK. Reaction calorimetry as an in-situ kinetic tool for characterizing complex reactions Thermochimica Acta. 289: 189-207. DOI: 10.1016/S0040-6031(96)03072-9  0.461
1996 Sun Y, Wang J, LeBlond C, Landau RN, Blackmond DG. Asymmetric hydrogenation of ethyl pyruvate: Diffusion effects on enantioselectivity Journal of Catalysis. 161: 759-765. DOI: 10.1006/Jcat.1996.0238  0.404
1996 Wang J, Sun Y, LeBlond C, Landau RN, Blackmond DG. Asymmetric hydrogenation of ethyl pyruvate: Relationship between conversion and enantioselectivity Journal of Catalysis. 161: 752-758. DOI: 10.1006/Jcat.1996.0237  0.474
1995 Landau RN, Singh U, Gortsema F, Sun YK, Gomolka SC, Lam T, Futran M, Blackmond DG. A Reaction Calorimetric Investigation of the Hydrogenation of a Substituted Pyrazine Journal of Catalysis. 157: 201-208. DOI: 10.1006/Jcat.1995.1280  0.452
1995 Singh UK, Landau RN, Sun YK, Leblond C, Blackmond DG, Tanielyan SK, Augustine RL. Enantioselective Catalysis: Influence of Conversion and Bulk Diffusion Limitations on Selectivity in the Hydrogenation of Ethyl Pyruvate Journal of Catalysis. 154: 91-97. DOI: 10.1006/Jcat.1995.1150  0.453
1995 Wang J, Oukaci R, Wender I, Blackmond DG. Alcohol Synthesis from Co/H2 over Co/Cu/ZnO/Al2O3: In-Situ Addition of Ch3NO2 Journal of Catalysis. 153: 100-107. DOI: 10.1006/Jcat.1995.1112  0.312
1994 Landau RN, Blackmond DG, Tung HH. Calorimetric investigation of an exothermic reaction: Kinetic and heat flow modeling Industrial & Engineering Chemistry Research. 33: 814-820. DOI: 10.1021/Ie00028A005  0.341
1994 Blackmond DG. 15th Conference on Catalysis of Organic Reactions, 2–5 May, 1994, Phoenix, AZ Applied Catalysis a-General. 115. DOI: 10.1016/0926-860X(94)80394-3  0.35
1993 Waghray A, Blackmond DG. Infrared spectroscopic studies of the adsorption and reaction of 3-methyl-2-butenal over alkali-promoted ruthenium/silica catalysts The Journal of Physical Chemistry. 97: 6002-6006. DOI: 10.1021/J100124A036  0.447
1993 Waghray A, Oukaci R, Blackmond DG. Selective Hydrogenation of α,β-Unsaturated Aldehydes Over Supported Ru Studies in Surface Science and Catalysis. 75: 2479-2482. DOI: 10.1016/S0167-2991(08)64329-3  0.38
1992 Waghray A, Wang J, Oukaci R, Blackmond DG. Influence of alkali promoters in the selective hydrogenation of 3-methyl-2-butenal over Ru/SiO{sub 2} catalysts The Journal of Physical Chemistry. 96: 5954-5959. DOI: 10.1021/J100193A056  0.399
1992 Blackmond DG. Meeting reports 14th international conference on the catalysis of organic reactions, Albuquerque, New Mexico, 27–29 april, 1992 Applied Catalysis a-General. 87. DOI: 10.1016/0926-860X(92)80191-E  0.342
1992 Waghray A, Oukaci R, Blackmond DG. Diffusion effects in the hydrogenation of 3-methyl crotonaldehyde over zeolite-supported Ru Catalysis Letters. 14: 115-122. DOI: 10.1007/Bf00764225  0.392
1991 Blackmond DG, Waghray A, Oukaci R, Blanc B, Gallezot P. Selective Hydrogenation of Unsaturated Aldehydes over Zeolite-Supported Metals Studies in Surface Science and Catalysis. 59: 145-152. DOI: 10.1016/S0167-2991(08)61115-5  0.366
1991 Blackmond DG, Oukaci R, Blanc B, Gallezot P. Geometric and electronic effects in the selective hydrogenation of α, β-unsaturated aldehydes over zeolite-supported metals Journal of Catalysis. 131: 401-411. DOI: 10.1016/0021-9517(91)90275-9  0.31
1990 Cavalcanti FAP, Oukaci R, Wender I, Blackmond DG. Probe molecule studies of CO hydrogenation over Ru/SiO2 Journal of Catalysis. 123: 260-269. DOI: 10.1016/0021-9517(90)90174-I  0.303
1988 Blackmond DG, Kesraoui S. The effects of alkali promoters on the adsorptive properties of supported Rh catalysts Studies in Surface Science and Catalysis. 38: 33-42. DOI: 10.1016/S0167-2991(09)60640-6  0.335
1988 Blackmond DG. 1988 International symposium on C1 reactions Applied Catalysis. 45: 366. DOI: 10.1016/S0166-9834(00)83053-5  0.386
1988 Ciocco MV, Blackmond DG. Support and alkali promotion effects on the surface chemistry of nickel/silica catalysts Applied Catalysis. 44: 105-116. DOI: 10.1016/S0166-9834(00)80047-0  0.339
1988 Cavalcanti FAP, Blackmond DG, Oukaci R, Sayari A, Erdem-Senatalar A, Wender I. In situ chemical trapping of CO H2 surface species Journal of Catalysis. 113: 1-12. DOI: 10.1016/0021-9517(88)90232-1  0.342
1987 Kesraoui S, Oukaci R, Blackmond DG. Adsorption and reaction of CO and H2 on K-promoted Rh SiO2 catalysts Journal of Catalysis. 105: 432-444. DOI: 10.1016/0021-9517(87)90071-6  0.364
1986 Blackmond DG, Williams JA, Kesraoui S, Blazewick DS. The effects of Cs promotion on Rh Al2O3 catalysts Journal of Catalysis. 101: 496-504. DOI: 10.1016/0021-9517(86)90276-9  0.4
1985 Blackmond DG, Ko EI. Structural sensitivity of CO adsorption and H2 CO coadsorption on Ni SiO2 catalysts Journal of Catalysis. 96: 210-221. DOI: 10.1016/0021-9517(85)90374-4  0.602
1985 Blackmond DG, Ko EI. Carbon monoxide adsorption as a chemical probe of supported nickel catalysts: The role of carbonyl formation and support effects Journal of Catalysis. 94: 343-352. DOI: 10.1016/0021-9517(85)90199-X  0.619
1984 Blackmond DG, Ko EI. Preparation and characterization of well-defined Ni/SiO2 catalysts Applied Catalysis. 13: 49-68. DOI: 10.1016/S0166-9834(00)83327-8  0.619
1982 Blackmond DG, Goodwin JG, Lester JE. The effect of hydrogen on the adsorption and reaction of 1-hexene over HY cracking catalysts Journal of Catalysis. 78: 247-252. DOI: 10.1016/0021-9517(82)90304-9  0.418
1982 Blackmond DG, Goodwin JG, Lester JE. In situ Fourier transform infrared spectroscopy study of HY cracking catalysts: Coke formation and the nature of the active sites Journal of Catalysis. 78: 34-43. DOI: 10.1016/0021-9517(82)90283-4  0.362
1981 Blackmond DG, Goodwin JG. Zeolite support effects on CO-Ru interactions Journal of the Chemical Society, Chemical Communications. 125-126. DOI: 10.1039/C39810000125  0.317
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