Klaus H. Theopold, Ph.D. - Publications

Affiliations: 
Chemistry & Biochemistry University of Delaware, Newark, DE, United States 
Area:
Inorganic Chemistry
Website:
http://www.udel.edu/theopold/

156 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Wu P, Yap GPA, Theopold KH. Synthesis, Characterization, and Reactivity of Tris(imido)chromium(VI) Complexes. Inorganic Chemistry. PMID 37953611 DOI: 10.1021/acs.inorgchem.3c03169  0.313
2022 Salisbury BA, Young JF, Theopold KH, Yap GPA. A molecular substitutional disorder case study suitable for instruction: LCr(THF)/L[(trimethylsilyl)methyl]Cr (L is 2,5-bis{[(2,6-diisopropylphenyl)imino]methyl}pyrrol-1-ide). Acta Crystallographica. Section C, Structural Chemistry. 78: 295-298. PMID 35510435 DOI: 10.1107/S2053229622003825  0.708
2019 Wu P, Yap GPA, Theopold KH. Synthesis, Characterization, and Reactivity of Chromium(VI) Alkylidenes Organometallics. 38: 4593-4600. DOI: 10.1021/Acs.Organomet.9B00604  0.362
2019 Hung Y, Yap GP, Theopold KH. Unexpected reactions of chromium hydrides with a diazoalkane Polyhedron. 157: 381-388. DOI: 10.1016/J.Poly.2018.10.030  0.351
2018 Wu P, Yap GPA, Theopold KH. Structure and Reactivity of Chromium(VI) Alkylidenes. Journal of the American Chemical Society. PMID 29847922 DOI: 10.1021/Jacs.8B04882  0.464
2016 Sirianni ER, Cummins DC, Yap GP, Theopold KH. FcTp(R) (R = (i)Pr or (t)Bu): third-generation ferrocenyl scorpionates. Acta Crystallographica. Section C, Structural Chemistry. 72: 813-818. PMID 27811417 DOI: 10.1107/S205322961601202X  0.791
2016 Cummins DC, Yap GPA, Theopold KH. Scorpionates of the "Tetrahedral Enforcer" Variety as Ancillary Ligands for Dinitrogen Complexes of First Row Transition Metals (Cr-Co) European Journal of Inorganic Chemistry. DOI: 10.1002/Ejic.201501326  0.814
2015 Falceto A, Theopold KH, Alvarez S. Cr-Cr Quintuple Bonds: Ligand Topology and Interplay Between Metal-Metal and Metal-Ligand Bonding. Inorganic Chemistry. 54: 10966-77. PMID 26502158 DOI: 10.1021/Acs.Inorgchem.5B02059  0.4
2015 Akturk ES, Yap GP, Theopold KH. Dioxygen Activation by Non-Adiabatic Oxidative Addition to a Single Metal Center. Angewandte Chemie (International Ed. in English). PMID 26473394 DOI: 10.1002/Anie.201508777  0.392
2015 Akturk ES, Yap GP, Theopold KH. Mechanism-based design of labile precursors for chromium(i) chemistry. Chemical Communications (Cambridge, England). 51: 15402-5. PMID 26344782 DOI: 10.1039/C5Cc05993C  0.388
2014 Sirianni ER, Yap GP, Theopold KH. Ferrocenyl-substituted tris(pyrazolyl)borates--a new ligand type combining redox activity with resistance to hydrogen atom abstraction. Inorganic Chemistry. 53: 9424-30. PMID 25144913 DOI: 10.1021/Ic5015658  0.782
2014 Theopold KH. Deprotonation of coordinated ethylene may start Phillips catalysis. Proceedings of the National Academy of Sciences of the United States of America. 111: 11578-9. PMID 25082894 DOI: 10.1073/Pnas.1411822111  0.314
2014 Shen J, Yap GP, Barker WE, Geiger WE, Theopold KH. An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand. Chemical Communications (Cambridge, England). 50: 10626-9. PMID 25073609 DOI: 10.1039/C4Cc03332A  0.566
2014 Shen J, Yap GP, Theopold KH. Chromium mediated reductive coupling of isonitrile forms unusual heterocycles. Journal of the American Chemical Society. 136: 3382-4. PMID 24552240 DOI: 10.1021/Ja501291P  0.548
2014 Shen J, Yap GP, Theopold KH. Binding and activation of small molecules by a quintuply bonded chromium dimer. Chemical Communications (Cambridge, England). 50: 2579-81. PMID 24463485 DOI: 10.1039/C3Cc48746F  0.543
2014 Shen J, Yap GPA, Barker Iv WE, Geiger WE, Theopold KH. An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand Chemical Communications. 50: 10626-10629. DOI: 10.1039/c4cc03332a  0.514
2014 Shen J, Yap GPA, Theopold KH. Binding and activation of small molecules by a quintuply bonded chromium dimer Chemical Communications. 50: 2579-2581. DOI: 10.1039/c3cc48746f  0.423
2014 Shen J, Yap GPA, Theopold KH. Chromium mediated reductive coupling of isonitrile forms unusual heterocycles Journal of the American Chemical Society. 136: 3382-3384. DOI: 10.1021/ja501291p  0.425
2014 Sirianni ER, Yap GPA, Theopold KH. Ferrocenyl-substituted tris(pyrazolyl)borates-A new ligand type combining redox activity with resistance to hydrogen atom abstraction Inorganic Chemistry. 53: 9424-9430. DOI: 10.1021/ic5015658  0.752
2013 Dai F, Yap GP, Theopold KH. The direct oxidative addition of O2 to a mononuclear Cr(I) complex is spin forbidden. Journal of the American Chemical Society. 135: 16774-6. PMID 24171595 DOI: 10.1021/Ja408357X  0.578
2013 Sirianni ER, Yap GP, Akturk ES, Theopold KH. Improved syntheses, and structural and electronic characterization of carboxamide-substituted Tp(CONHPh,Me) and Tp(CONHt-Bu,Me) ligands. Acta Crystallographica. Section C, Crystal Structure Communications. 69: 947-53. PMID 24005497 DOI: 10.1107/S0108270113015898  0.788
2013 Wang M, England J, Weyhermüller T, Kokatam SL, Pollock CJ, DeBeer S, Shen J, Yap GP, Theopold KH, Wieghardt K. New complexes of chromium(III) containing organic π-radical ligands: an experimental and density functional theory study. Inorganic Chemistry. 52: 4472-87. PMID 23531224 DOI: 10.1021/Ic302743S  0.612
2013 Monillas WH, Young JF, Yap GPA, Theopold KH. A well-defined model system for the chromium-catalyzed selective oligomerization of ethylene Dalton Transactions. 42: 9198-9210. PMID 23493916 DOI: 10.1039/C3Dt00109A  0.787
2013 Sirianni ER, Yap GPA, Akturk ES, Theopold KH. Improved syntheses, and structural and electronic characterization of carboxamide-substituted TpCONHPh,Me and TpCONHt-Bu,Me ligands Acta Crystallographica Section C: Crystal Structure Communications. 69: 947-953. DOI: 10.1107/S0108270113015898  0.768
2013 Dai F, Yap GPA, Theopold KH. The direct oxidative addition of O2 to a mononuclear Cr(I) complex is spin forbidden Journal of the American Chemical Society. 135: 16774-16776. DOI: 10.1021/ja408357x  0.498
2012 Kreisel KA, Yap GPA, Theopold KH. Organochromium complexes bearing noninnocent diimine ligands European Journal of Inorganic Chemistry. 520-529. DOI: 10.1002/Ejic.201100803  0.793
2011 Monillas ES, Monillas WH, Sirianni ER, Yap GP, Theopold KH. Guanidinium 2-(myristoylsulfanyl)ethane-sulfonate. Acta Crystallographica. Section E, Structure Reports Online. 67: o3257. PMID 22199766 DOI: 10.1107/S1600536811046472  0.769
2011 Shen J, Yap GP, Werner JP, Theopold KH. Reactions of a quintuply bonded chromium dimer with alkynes. Chemical Communications (Cambridge, England). 47: 12191-3. PMID 21986955 DOI: 10.1039/C1Cc15218A  0.584
2011 Jové FA, Pariya C, Scoblete M, Yap GPA, Theopold KH. A family of four-coordinate iron(II) complexes bearing the sterically hindered tris(pyrazolyl)borato ligand TptBu,Me Chemistry - a European Journal. 17: 1310-1318. PMID 21243699 DOI: 10.1002/Chem.201001792  0.815
2011 Monillas ES, Monillas WH, Sirianni ER, Yap GPA, Theopold KH. Guanidinium 2-(myristoylsulfanyl)ethanesulfonate Acta Crystallographica Section E: Structure Reports Online. 67: o3257. DOI: 10.1107/S1600536811046472  0.738
2011 Shen J, Yap GPA, Werner JP, Theopold KH. Reactions of a quintuply bonded chromium dimer with alkynes Chemical Communications. 47: 12191-12193. DOI: 10.1039/c1cc15218a  0.451
2011 Monillas WH, Yap GPA, Theopold KH. Reactivity of a low-valent chromium dinitrogen complex Inorganica Chimica Acta. 369: 103-119. DOI: 10.1016/J.Ica.2010.11.024  0.793
2011 Monillas WH, Yap GPA, Theopold KH. Synthesis and structure of a chromium(III) complex supported by a β-diketiminate and an enediolate ligand Journal of Chemical Crystallography. 41: 415-418. DOI: 10.1007/S10870-010-9943-Z  0.787
2010 Gunay A, Theopold KH. C-H bond activations by metal oxo compounds. Chemical Reviews. 110: 1060-81. PMID 20143877 DOI: 10.1021/Cr900269X  0.318
2010 Young JF, MacAdams LA, Yap GPA, Theopold KH. The synthesis, characterization, and alkylation of nacnac chromium triflate derivatives Inorganica Chimica Acta. 364: 138-143. DOI: 10.1016/J.Ica.2010.08.010  0.819
2010 Monillas WH, Bazzoli TC, Yap GPA, Theopold KH. Synthesis and structure of bis(β-diketiminate) chromium(II) complexes Journal of Chemical Crystallography. 40: 67-71. DOI: 10.1007/S10870-009-9627-8  0.78
2009 King WA, Yap GPA, Incarvito CD, Rheingold AL, Theopold KH. Metal complexes of the perfluoroalkyl substituted Tpn - C3 F7,Me ligand Inorganica Chimica Acta. 362: 4493-4499. DOI: 10.1016/J.Ica.2009.04.013  0.386
2009 Young JF, Yap GPA, Theopold KH. Erratum to: 2,4-Pentane N,N′-Bis(2,6-Diisopropylphenyl) ketiminato cobalt (II) (trimethylsilyl)methylene Journal of Chemical Crystallography. 40: 85-85. DOI: 10.1007/S10870-009-9665-2  0.334
2009 Monillas WH, Yap GPA, Theopold KH. Synthesis and structure of chromium(II) complexes supported by both a β-Diketiminate and an amidinate ligand Journal of Chemical Crystallography. 39: 849-852. DOI: 10.1007/S10870-009-9621-1  0.785
2009 Young JF, Yap GPA, Theopold KH. 2,4-Pentane N,N-Bis(2,6-Diisopropylphenyl) ketiminato cobalt (II) (trimethylsilyl)methylene Journal of Chemical Crystallography. 39: 846-848. DOI: 10.1007/S10870-009-9618-9  0.448
2009 Monillas WH, Yap GPA, Theopold KH. Synthesis and structure of (TMEDA)Cr(I)2(THF) and [(N,N-DMEDA)2CrI] i Journal of Chemical Crystallography. 39: 842-845. DOI: 10.1007/S10870-009-9617-X  0.778
2009 Monillas WH, Yap GPA, Theopold KH. Phenylamido and diphenylamido complexes of chromium(II) Journal of Chemical Crystallography. 39: 535-538. DOI: 10.1007/S10870-009-9571-7  0.791
2009 Monillas WH, Yap GPA, Theopold KH. Synthesis and Structural Characterization of Bis(μ2-Iodo)- Bis(Diethyl Ether)-(N-N′-(Bis(2,6-Diisopropylphenyl)Pentane-2,4- Diketiminato)-Lithium-Chromium, a Cr(II) (β-Diketiminato) Complex with a Coordinated LiI Salt Journal of Chemical Crystallography. 39: 377-379. DOI: 10.1007/S10870-009-9561-9  0.805
2009 Monillas WH, Yap GPA, Theopold KH. Synthesis and structural characterization of bis[(cyclohexylamino)pent-2- en-4-onato]-chromium(II) Journal of Chemical Crystallography. 39: 380-383. DOI: 10.1007/S10870-009-9526-Z  0.762
2009 Monillas WH, Yap GPA, Theopold KH. Synthesis and structural comparison for a series of Cr(II) (iodo) NacNac complexes Journal of Chemical Crystallography. 39: 73-77. DOI: 10.1007/S10870-008-9492-X  0.769
2008 Bénard M, Rohmer MM, López X, Theopold KH. A tale of two isomers (continued): is the phenyl hydride complex of chromium more stable than its benzene-bridged isomer? Angewandte Chemie (International Ed. in English). 47: 5597-9. PMID 18563763 DOI: 10.1002/Anie.200801032  0.463
2008 Kreisel KA, Yap GP, Theopold KH. Synthesis, characterization, and electronic structure of diimine complexes of chromium. Inorganic Chemistry. 47: 5293-303. PMID 18442232 DOI: 10.1021/Ic800302W  0.799
2008 Kreisel KA, Yap GPA, Theopold KH. Synthesis, characterization, and electronic structure of diimine complexes of chromium Inorganic Chemistry. 47: 5293-5303. DOI: 10.1021/ic800302w  0.752
2008 Bénard M, Rohmer MM, López X, Theopold KH. A tale of two isomers (continued): Is the phenyl hydride complex of chromium more stable than its benzene-bridged isomer? Angewandte Chemie - International Edition. 47: 5597-5599. DOI: 10.1002/anie.200801032  0.357
2007 Kreisel KA, Yap GP, Dmitrenko O, Landis CR, Theopold KH. The shortest metal-metal bond yet: molecular and electronic structure of a dinuclear chromium diazadiene complex. Journal of the American Chemical Society. 129: 14162-3. PMID 17967028 DOI: 10.1021/Ja076356T  0.784
2007 Monillas WH, Yap GP, Theopold KH. A tale of two isomers: a stable phenyl hydride and a high-spin (S=3) benzene complex of chromium. Angewandte Chemie (International Ed. in English). 46: 6692-4. PMID 17668893 DOI: 10.1002/Anie.200701933  0.753
2007 Monillas WH, Yap GP, MacAdams LA, Theopold KH. Binding and activation of small molecules by three-coordinate Cr(I). Journal of the American Chemical Society. 129: 8090-1. PMID 17567016 DOI: 10.1021/Ja0725549  0.813
2007 Kreisel KA, Yap GP, Theopold KH. A bimetallic N-heterocyclic carbene complex featuring a short Cr-Cr distance. Chemical Communications (Cambridge, England). 1510-1. PMID 17406690 DOI: 10.1039/B616685G  0.796
2007 Salisbury BA, Young JF, Yap GPA, Theopold KH. Synthesis and reactivity of pyrrolide-diimine complexes of chromium Collection of Czechoslovak Chemical Communications. 72: 637-648. DOI: 10.1135/Cccc20070637  0.768
2007 Kreisel KA, Yap GPA, Theopold KH. A bimetallic N-heterocyclic carbene complex featuring a short Cr-Cr distance Chemical Communications. 1510-1511. DOI: 10.1039/b616685g  0.753
2007 Monillas WH, Yap GPA, MacAdams LA, Theopold KH. Binding and activation of small molecules by three-coordinate Cr(I) Journal of the American Chemical Society. 129: 8090-8091. DOI: 10.1021/ja0725549  0.769
2007 Monillas WH, Yap GPA, Theopold KH. A tale of two isomers: A stable phenyl hydride and a high-spin (S = 3) benzene complex of chromium Angewandte Chemie - International Edition. 46: 6692-6694. DOI: 10.1002/anie.200701933  0.739
2006 Kreisel KA, Yap GP, Theopold KH. Tetra-mu-chloro-1:2kappa4Cl;1:3kappa4Cl-dimethyl-2kappaC,3kappaC-tetrakis(tetrahydrofuran)-1kappa2O,2kappaO,3kappaO-chromium(II)dizinc(II). Acta Crystallographica. Section C, Crystal Structure Communications. 62: m569-70. PMID 17148886 DOI: 10.1107/S0108270106041783  0.789
2006 Kreisel KA, Yap GPA, Theopold KH. Tetra-μ-chloro-1:2κ4Cl;1:3κ4Cl-di- methyl-2κC,3κC-tetrakis(tetrahydrofuran)-1κ2O, 2κO,3κO-chromium(II)-dizinc(II) Acta Crystallographica Section C: Crystal Structure Communications. 62: m569-m570. DOI: 10.1107/S0108270106041783  0.721
2006 Kreisel KA, Yap GPA, Theopold KH. A chelating N-heterocyclic carbene ligand in organochromium chemistry Organometallics. 25: 4670-4679. DOI: 10.1021/Om060514S  0.796
2006 Theopold KH, Holmes SJ, Schrock RR. Alkin-Komplexe von Wolfram(IV) Angewandte Chemie. 95: 1012-1013. DOI: 10.1002/Ange.19830951218  0.398
2005 Shay DT, Yap GP, Zakharov LN, Rheingold AL, Theopold KH. Intramolecular C-H activation by an open-shell cobalt(III) imido complex. Angewandte Chemie (International Ed. in English). 44: 1508-10. PMID 15693038 DOI: 10.1002/Anie.200462529  0.8
2005 MacAdams LA, Buffone GP, Incarvito CD, Rheingold AL, Theopold KH. A chromium catalyst for the polymerization of ethylene as a homogeneous model for the phillips catalyst. Journal of the American Chemical Society. 127: 1082-3. PMID 15669830 DOI: 10.1021/Ja043877X  0.766
2005 MacAdams LA, Buffone GP, Incarvito CD, Rheingold AL, Theopold KH. A chromium catalyst for the polymerization of ethylene as a homogeneous model for the Phillips catalyst Journal of the American Chemical Society. 127: 1082-1083. DOI: 10.1021/ja043877x  0.745
2005 Shay DT, Yap GPA, Zakharov LN, Rheingold AL, Theopold KH. Intramolecular C-H activation by an open-shell cobalt(III) imido complex Angewandte Chemie - International Edition. 44: 1508-1510. DOI: 10.1002/anie.200462529  0.8
2004 Hoganson CW, Doren DJ, Theopold KH. Selectivity in the polymerization of olefins with cyclopentadienyl chromium catalysts: A density functional study Macromolecules. 37: 566-572. DOI: 10.1021/Ma035080G  0.337
2004 Höcher T, Salisbury BA, Theopold KH, Hey-Hawkins E. Phosphanylalkylcyclopentadienyl ligands: Synthesis, molecular structures and catalytic properties of [{(η5-C5H 4)CMe2PHR}CrCl2(PMe2Ph)] (R=Ph, tBu) Polyhedron. 23: 1393-1399. DOI: 10.1016/J.Poly.2004.02.011  0.747
2004 Pariya C, Incarvito CD, Rheingold AL, Theopold KH. Preparation and ligand substitution reactions of TpMsRu(COD)H including intramolecular ligand metalation Polyhedron. 23: 439-444. DOI: 10.1016/J.Poly.2003.11.031  0.396
2004 Van Kirk CC, Qin K, Theopold KH, Evans DH. Studies of the oxidation of a hydroxychromium(III)-[hydrotrispyrazoylborate]pyrazolyl complex Journal of Electroanalytical Chemistry. 565: 185-190. DOI: 10.1016/J.Jelechem.2003.10.007  0.6
2004 Theopold KH, Mommertz A, Salisbury BA. π-Complexes of Chromium, Molybdenum, and Tungsten Excluding Arenes Cheminform. 35. DOI: 10.1002/chin.200411226  0.325
2003 MacAdams LA, Buffone GP, Incarvito CD, Golen JA, Rheingold AL, Theopold KH. A stable alkyl hydride of a first row transition metal. Chemical Communications (Cambridge, England). 1164-5. PMID 12778716 DOI: 10.1039/B301943H  0.803
2003 Thyagarajan S, Shay DT, Incarvito CD, Rheingold AL, Theopold KH. Intramolecular C-H activation by inferred terminal cobalt imido intermediates. Journal of the American Chemical Society. 125: 4440-1. PMID 12683812 DOI: 10.1021/Ja028267G  0.796
2003 Varkey SP, Lobo RF, Theopold KH. Zeolite MCM-22 supported heterogeneous chromium catalyst for ethylene polymerization Catalysis Letters. 88: 227-229. DOI: 10.1023/A:1024030326621  0.36
2003 Thyagarajan S, Incarvito CD, Rheingold AL, Theopold KH. In pursuit of a stable peroxynitrite complex - NOx (x=1-3) derivatives of Tpt-Bu,MeCo Inorganica Chimica Acta. 345: 333-339. DOI: 10.1016/S0020-1693(02)01275-6  0.655
2003 MacAdams LA, Buffone GP, Incarvito CD, Golen JA, Rheingold AL, Theopold KH. A stable alkyl hydride of a first row transition metal Chemical Communications. 9: 1164-1165.  0.75
2002 Qin K, Incarvito CD, Rheingold AL, Theopold KH. Hydrogen atom abstraction by a chromium(IV) oxo complex derived from O2 Journal of the American Chemical Society. 124: 14008-14009. PMID 12440895 DOI: 10.1021/Ja028382R  0.575
2002 Qin K, Incarvito CD, Rheingold AL, Theopold KH. A structurally characterized chromium(III) superoxide complex features "side-on" bonding Angewandte Chemie - International Edition. 41: 2333-2335. PMID 12203583 DOI: 10.1002/1521-3773(20020703)41:13<2333::Aid-Anie2333>3.0.Co;2-F  0.6
2002 Hess JS, Leelasubcharoen S, Rheingold AL, Doren DJ, Theopold KH. Spin surface crossing in chromium-mediated olefin epoxidation with O(2). Journal of the American Chemical Society. 124: 2454-5. PMID 11890791 DOI: 10.1021/Ja0167553  0.774
2002 MacAdams LA, Kim WK, Liable-Sands LM, Guzei IA, Rheingold AL, Theopold KH. The (PH)2nacnac ligand in organochromium chemistry Organometallics. 21: 952-960. DOI: 10.1021/Om010857K  0.794
2002 Theopold KH, Reinaud OM, Blanchard S, Leelasubcharoen S, Hess A, Thyagarajan S. Toward Benign Synthesis via Catalytic Oxidations Using Dioxygen or Nitrous Oxide Acs Symposium Series. 823: 75-85.  0.755
2001 Thyagarajan S, Incarvito CD, Rheingold AL, Theopold KH. Formation and reactivity of a cobalt (II) hydroperoxide intermediate. Chemical Communications (Cambridge, England). 2198-9. PMID 12240109 DOI: 10.1039/B107080K  0.596
2001 Leelasubcharoen S, Lehmann MW, Theopold KH, Evans DH. Voltammetric study of an unusual dimer/monomer redox system involving a chromium(III) complex of a tridentate CNN ligand Journal of the Electrochemical Society. 148: E118-E120. DOI: 10.1149/1.1346612  0.819
2001 Leelasubcharoen S, Lam KC, Concolino TE, Rheingold AL, Theopold KH. Unusual transformations of a bipyridine ligand in attempts to trap a terminal chromium (III) alkylidene Organometallics. 20: 182-187. DOI: 10.1021/Om0007421  0.811
1999 Jewson JD, Liable-Sands LM, Yap GPA, Rheingold AL, Theopold KH. Paramagnetic alkyl, hydride, and alkene complexes of the Tpt-Bu,MeCo moiety Organometallics. 18: 300-305. DOI: 10.1021/Om980844F  0.417
1999 Doren DJ, Konecny R, Theopold KH. Insights into homogeneous catalysis from first-principles theory: Density functional studies of inorganic cobalt complexes Catalysis Today. 50: 669-675. DOI: 10.1016/S0920-5861(98)00501-X  0.392
1998 Heintz RA, Leelasubcharoen S, Liable-Sands LM, Rheingold AL, Theopold KH. Structure and Reactivity of Trimethylsilylmethyl Complexes of Chromium, Including the 13-Electron Alkyl Cp*Cr(CH2SiMe3)2 Organometallics. 17: 5477-5485. DOI: 10.1021/Om980796Z  0.807
1998 Kim WK, Fevola MJ, Liable-Sands LM, Rheingold AL, Theopold KH. [(Ph)2nacnac]MCl2(THF)2 (M = Ti, V, Cr): A new class of homogeneous olefin polymerization catalysts featuring β-diiminate ligands Organometallics. 17: 4541-4543. DOI: 10.1021/Om9806545  0.367
1998 Theopold KH. Homogeneous chromium catalysts for olefin polymerization European Journal of Inorganic Chemistry. 15-24. DOI: 10.1002/(Sici)1099-0682(199801)1998:1<15::Aid-Ejic15>3.0.Co;2-M  0.34
1998 Abernethy CD, Bottomley F, Chen J, Kemp MF, Mallais TC, Womiloju OO, Thyagarajar S, Theopold KH. High-valent mono-(η5-pentamethylcyclo-pentadienyl)vanadium and molybdenum complexes Inorganic Syntheses. 32: 207-214.  0.312
1997 Theopold KH, Reinaud OM, Doren D, Konecny R. Dioxygen activation with sterically hindered tris(pyrazolyl)borate cobalt complexes Studies in Surface Science and Catalysis. 110: 1081-1088. DOI: 10.1016/S0167-2991(97)81074-9  0.467
1997 Kersten JL, Kucharczyk RR, Yap GPA, Rheingold AL, Theopold KH. [(TptBu, Me)CrR]: A New Class of Mononuclear, Coordinatively Unsaturated Chromium(II) Alkyls with cis-Divacant Octahedral Structure Chemistry: a European Journal. 3: 1668-1674. DOI: 10.1002/Chem.19970031016  0.401
1996 Liang Y, Yap GPA, Rheingold AL, Theopold KH. Constrained geometry chromium catalysts for olefin polymerization Organometallics. 15: 5284-5286. DOI: 10.1021/Om960774H  0.429
1996 White PA, Calabrese J, Theopold KH. α-olefin polymerization with ether-coordinated chromium(III) alkyls Organometallics. 15: 5473-5475. DOI: 10.1021/Om960697Q  0.416
1996 Detrich JL, Konečný R, Vetter WM, Doren D, Rheingold AL, Theopold KH. Structural distortion of the TpCo-L fragment (Tp = tris(pyrazolyl)borate). Analysis by X-ray diffraction and density functional theory Journal of the American Chemical Society. 118: 1703-1712. DOI: 10.1021/Ja9523101  0.339
1996 Bhandari G, Kersten JL, Kucharczyk RR, White PA, Liang Y, Theopold KH. Organochromium complexes in homogeneous olefin polymerization Studies in Surface Science and Catalysis. 101: 153-160. DOI: 10.1016/S0167-2991(96)80225-4  0.379
1995 Bhandari G, Kim Y, McFarland JM, Rheingold AL, Theopold KH. Paramagnetic (Benzyl)chromium Complexes as Homogeneous Ethylene Polymerization Catalysts Organometallics. 14: 738-745. DOI: 10.1021/Om00002A023  0.376
1995 Bhandari G, Rheingold AL, Theopold KH. Correlations Between Structure, Magnetism, and Polymerization Activity of Paramagnetic Benzylchromium Complexes Chemistry - a European Journal. 1: 199-203. DOI: 10.1002/Chem.19950010309  0.489
1995 Reinaud OM, Yap GPA, Rheingold AL, Theopold KH. Novel Binuclear Cobalt Dioxygen Complex : A Step On The Path To Dioxygen Activation Angewandte Chemie. 34: 2051-2052. DOI: 10.1002/Anie.199520511  0.389
1994 Heintz RA, Ostrander RL, Rheingold AL, Theopold KH. [(.eta.5-C5R5)CrR]n: A New Class of Paramagnetic Alkyls and Hydrides of Divalent Chromium Journal of the American Chemical Society. 116: 11387-11396. DOI: 10.1021/Ja00104A019  0.336
1994 Reinaudt OM, Theopold KH. Hydrogen tunneling in the activation of dioxygen by a tris(pyrazolyl)borate cobalt complex Journal of the American Chemical Society. 116: 6979-6980. DOI: 10.1021/Ja00094A080  0.382
1994 Reinaud OM, Rheingold AL, Theopold KH. [Hydrotris(3-isopropyl-5-methylpyrazolyl)borato]iodocobalt(II): Unusual Purification by "Inverse Recrystallization" Inorganic Chemistry. 33: 2306-2308. DOI: 10.1021/Ic00088A038  0.403
1993 Protasiewicz JD, Theopold KH. A direct comparison of the rates of degenerate transfer of electrons, protons, and hydrogen atoms between metal complexes Journal of the American Chemical Society. 115: 5559-5569. DOI: 10.1021/Ja00066A025  0.61
1993 Janiak C, Silvestre J, Theopold KH. Metal-Metal Bonding in Paramagnetic Chromium(III) Complexes – An MO-Theoretical Case Study Chemische Berichte. 126: 631-643. DOI: 10.1002/Cber.19931260313  0.404
1992 Noh SK, Heintz RA, Haggerty BS, Rheingold AL, Theopold KH. Oxo-alkyls of chromium(V) and chromium(VI) Journal of the American Chemical Society. 114: 1892-1893. DOI: 10.1021/Ja00031A060  0.318
1992 Heintz RA, Haggerty BS, Rheingold AL, Theopold KH, Wan H. [{Cp*Cr(?3-H)}4]?a Paramagnetic Chromium Hydride with a Cubane Structure Angewandte Chemie International Edition in English. 31: 1077-1079. DOI: 10.1002/Anie.199210771  0.342
1992 Heintz RA, Haggerty BS, Wan H, Rheingold AL, Theopold KH. [{Cp*Cr(μ3-H)}4] - ein paramagnetisches Chromhydrid mit Cubanstruktur Angewandte Chemie. 104: 1100-1102. DOI: 10.1002/Ange.19921040841  0.323
1991 Douglas T, Theopold KH. Molecular precursors for indium phosphide and synthesis of small III-V semiconductor clusters in solution Inorganic Chemistry. 30: 594-596. DOI: 10.1021/Ic00004A002  0.465
1991 Douglas T, Theopold KH. Molecular precursors for indium phosphide and synthesis of small III-V semiconductor clusters in solution Inorganic Chemistry. 30: 594-596. DOI: 10.1021/ic00004a002  0.394
1991 Sendlinger SC, Haggerty BS, Rbeingold AL, Theopold KH. Synthesis and Crystal Structure of an Arsolyl Anion and Preparation of an Arsinogallate Chemische Berichte. 124: 2453-2456. DOI: 10.1002/Cber.19911241114  0.315
1990 Egan JW, Theopold KH. trans-Tetrakis(3-tert-butyl-5-methylpyrazole)bis(tetrafluoroborato)cobalt(II), a complex with two coordinated tetrafluoroborate anions Acta Crystallographica Section C Crystal Structure Communications. 46: 1013-1015. DOI: 10.1107/S0108270189010462  0.332
1990 Egan JW, Haggerty BS, Rheingold AL, Sendlinger SC, Theopold KH. Crystal structure of a side-on superoxo complex of cobalt and hydrogen abstraction by a reactive terminal oxo ligand Journal of the American Chemical Society. 112: 2445-2446. DOI: 10.1021/Ja00162A069  0.428
1990 Douglas T, Theopold KH, Haggerty BS, Rheingold AL. A phospholyl complex of indium Polyhedron. 9: 329-333. DOI: 10.1016/S0277-5387(00)80587-2  0.531
1990 NOH SK, HEINTZ RA, JANIAK C, SENDLINGER SC, THEOPOLD KH. ChemInform Abstract: A Paramagnetic μ-Methylene Complex with a Short Cr(III)-Cr(III) Bond. Cheminform. 21. DOI: 10.1002/CHIN.199040256  0.312
1990 DOUGLAS T, THEOPOLD KH, HAGGERTY BS, RHEINGOLD AL. ChemInform Abstract: A Phospholyl Complexes of Indium. Cheminform. 21. DOI: 10.1002/chin.199023251  0.512
1990 DOUGLAS T, THEOPOLD KH. ChemInform Abstract: Synthesis and Crystal Structure of a Phospholyl Anion. Cheminform. 21. DOI: 10.1002/chin.199002250  0.438
1990 Noh SK, Heintz RA, Janiak C, Sendlinger SC, Theopold KH. A paramagnetic μ-methylene complex with a short CrIII-CrIII bond Angewandte Chemie (International Edition in English). 29: 775-X. DOI: 10.1002/Anie.199007751  0.396
1990 Noh SK, Heintz RA, Janiak C, Sendlinger SC, Theopold KH. Ein paramagnetischer μ-Methylenkomplex mit kurzer CrIII-CrIII-Bindung Angewandte Chemie. 102: 805-807. DOI: 10.1002/Ange.19901020714  0.325
1990 Egan JW, Haggerty BS, Rheingold AL, Sendlinger SC, Theopold KH. Crystal structure of a side-on superoxo complex of cobalt and hydrogen abstraction by a reactive terminal oxo ligand Journal of the American Chemical Society. 112: 2445-2446.  0.315
1989 Richeson DS, Mitchell JF, Theopold KH. Synthesis and reaction chemistry of a new class of paramagnetic chromium(III) alkyls. Characterization of complexes formed by insertion of nitriles into the chromium-carbon bond Organometallics. 8: 2570-2577. DOI: 10.1021/Om00113A009  0.64
1989 Noh SK, Heintz RA, Theopold KH. Deprotonation of bis(dimethylphosphino)ethane ligand of a cationic chromium alkyl Organometallics. 8: 2071-2073. DOI: 10.1021/Om00110A043  0.414
1989 Theopold KH, Silvestre J, Byrne EK, Richeson DS. Homoleptic mesityl complexes of cobalt(II). Synthesis, crystal structure, and theoretical description of bis(.mu.-mesityl)dimesityldicobalt Organometallics. 8: 2001-2009. DOI: 10.1021/Om00110A027  0.655
1989 Noh SK, Sendlinger SC, Janiak C, Theopold KH. [Cp*(Me)Cr(.mu.-Me)]2, an electron-deficient chromium(III) alkyl with bridging methyl groups and a chromium-chromium bond Journal of the American Chemical Society. 111: 9127-9129. DOI: 10.1021/Ja00207A034  0.378
1989 Byrne EK, Theopold KH. Synthesis, characterization, and electron-transfer reactivity of norbornyl complexes of cobalt in unusually high oxidation states Journal of the American Chemical Society. 111: 3887-3896. DOI: 10.1021/Ja00193A021  0.344
1989 Douglas T, Theopold KH. Synthesis and Crystal Structure of a Phospholyl Anion Angewandte Chemie International Edition in English. 28: 1367-1368. DOI: 10.1002/Anie.198913671  0.499
1989 Douglas T, Theopold KH. Synthese und Kristallstruktur eines Phospholylanions Angewandte Chemie. 101: 1394-1395. DOI: 10.1002/Ange.19891011017  0.488
1988 Byrne EK, Douglas T, Theopold KH. Organometallic Precursors for III-V Semiconductors Mrs Proceedings. 131. DOI: 10.1557/Proc-131-59  0.516
1988 Thomas BJ, Theopold KH. Cationic chromium(III) alkyls as olefin polymerization catalysts Journal of the American Chemical Society. 110: 5902-5903. DOI: 10.1021/Ja00225A053  0.444
1988 Protasiewicz JD, Schulte G, Theopold KH. Electron transfer rates of a cobalt(1-)/cobalt(0) couple and crystal structure of the tetrakis(trimethylphosphite)cobaltate(1-) ion Inorganic Chemistry. 27: 1133-1136. DOI: 10.1021/Ic00280A007  0.558
1988 Thomas BJ, Mitchell JF, Theopold KH, Leafy JA. Synthesis and structure determination of [Cp*4Cr4(μ-F)5Cl2]PF6. A tetranuclear chromium complex formed by fluoride abstraction from hexafluorophosphate Journal of Organometallic Chemistry. 348: 333-342. DOI: 10.1016/0022-328X(88)80414-5  0.436
1988 Protasiewicz JD, Theopold KH, Schulte G. Electron-transfer rates of a Co(-I)/Co(0) couple and crystal structure of the tetrakis(trimethyl phosphite)cobaltate(-I) ion [8] Inorganic Chemistry. 27: 1133-1136.  0.499
1987 Richeson DS, Mitchell JF, Theopold KH. Facile insertion of nitriles into paramagnetic chromium(III) alkyls. Crystal structure of a μ2-ketimino complex Journal of the American Chemical Society. 109: 5868-5870. DOI: 10.1021/Ja00253A059  0.668
1986 Byrne EK, Richeson DS, Theopold KH. Tetrakis(1-norbornyl)cobalt, a low spin tetrahedral complex of a first row transition metal Journal of the Chemical Society, Chemical Communications. 1491-1492. DOI: 10.1039/C39860001491  0.639
1986 Richeson DS, Hsu SW, Fredd NH, Van Duyne G, Theopold KH. Synthesis and characterization of polynuclear chromium(III) alkyls. Crystal structure of a paramagnetic .mu.3-methylidyne complex with short nonbonded chromium-chromium contacts Journal of the American Chemical Society. 108: 8273-8274. DOI: 10.1021/Ja00286A033  0.673
1986 Richeson DS, Hsu SW, Fredd NH, Van Duyne G, Theopold KH. Synthesis and characterization of polynuclear chromium(III) alkyls. Crystal structure of a paramagnetic μ3-methylidyne complex with short nonbonded Cr-Cr contacts Journal of the American Chemical Society. 108: 8273-8274.  0.635
1985 CHURCHILL MR, LI Y, THEOPOLD KH, SCHROCK RR. ChemInform Abstract: HIGH OXIDATION STATE DINITROGEN COMPLEXES. SYNTHESIS AND CRYSTAL STRUCTURE OF (W(C6H5CCC6H5)(CH3OCH2CH2OCH3)CL2)2(μ-N2).0.5CH3OCH2CH2OCH3 Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520277  0.542
1984 Churchill MR, Li YJ, Theopold KH, Schrock RR. High oxidation state dinitrogen complexes. Synthesis and crystal structure of [W(C6H5C.tplbond.CC6H5)(CH3OCH2CH2OCH3)Cl2]2(.mu.-N2).0.5CH3OCH2CH2OCH3 Inorganic Chemistry. 23: 4472-4476. DOI: 10.1021/Ic00194A015  0.532
1984 Belmonte PA, Cloke FGN, Theopold KH, Schrock RR. Preparation of [Nb(.eta.5-C5Me5)Cl2]2 and Nb(.eta.5-C5Me5)(3-hexyne)Cl2 Inorganic Chemistry. 23: 2365-2367. DOI: 10.1021/Ic00183A033  0.33
1984 BELMONTE PA, CLOKE FGN, THEOPOLD KH, SCHROCK RR. ChemInform Abstract: PREPARATION OF (NB(η5-C5ME5)CL2)2 AND NB(η5-C5ME5)(3-HEXYNE)CL2 Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198443286  0.443
1984 THEOPOLD KH, HOLMES SJ, SCHROCK RR. ChemInform Abstract: TUNGSTEN(IV) ALKYNE COMPLEXES Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198412282  0.558
1983 Theopold KH, Bergman RG. Synthesis and reaction chemistry of a new class of .mu.-alkylidene dicobalt complexes. Crystal and molecular structure of (.mu.-methylene)bis[.eta.5-(methylcyclopentadienyl)carbonylcobalt] Journal of the American Chemical Society. 105: 464-475. DOI: 10.1021/Ja00341A028  0.522
1983 THEOPOLD KH, BERGMAN RG. ChemInform Abstract: SYNTHESIS, CRYSTAL AND MOLECULAR STRUCTURE, AND CHEMISTRY OF (μ-(TRIMETHYLENE)BIS(η-CYCLOPENTADIENYL)BIS(μ-CARBONYL)DICOBALT, A FIVE-MEMBERED DICOBALTACYCLE Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198311272  0.527
1983 Theopold KH, Holmes SJ, Schrock RR. Some Chemistry of Tungsten(IV) Alkyne Complexes Angewandte Chemie International Edition in English. 22: 1409-1423. DOI: 10.1002/Anie.198314090  0.565
1983 Theopold KH, Holmes SJ, Schrock RR. Alkyne Complexes of Tungsten(IV) Angewandte Chemie International Edition in English. 22: 1010-1010. DOI: 10.1002/Anie.198310101  0.491
1983 Theopold KH, Bergman RG. Synthesis and reaction chemistry of a new class of μ-alkylidene dicobalt complexes. Crystal and molecular structure of (μ-methylene)bis[η5-(methylcyclopentadienyl)carbonyl-cobalt] Journal of the American Chemical Society. 105: 464-475.  0.321
1982 Xiang SF, Chen HW, Eyermann CJ, Jolly WL, Smit SP, Theopold KH, Bergman RG, Herrmann WA, Pettit R. An x-ray photoelectron spectroscopic study of transition metal .mu.-methylene complexes and related compounds Organometallics. 1: 1200-1203. DOI: 10.1021/Om00069A017  0.468
1982 Theopold KH, Bergman RG. Carbon-to-carbon migration of the dimetallic group in dinuclear cobalt alkylidene complexes Organometallics. 1: 219-222. DOI: 10.1021/Om00061A040  0.419
1982 Theopold KH, Becker PN, Bergman RG. Asymmetric induction in reactions employing enolates generated from cyclic organo transition metal acyl complexes Journal of the American Chemical Society. 104: 5250-5252. DOI: 10.1021/Ja00383A054  0.499
1982 Theopold KH, Hersh WH, Bergman RG. Binuclear Metallacycles: Organometallic Ring Systems Containing Two Metal Centers Israel Journal of Chemistry. 22: 27-29. DOI: 10.1002/Ijch.198200006  0.436
1982 THEOPOLD KH, BECKER PN, BERGMAN RG. ChemInform Abstract: ASYMMETRIC INDUCTION IN REACTIONS EMPLOYING ENOLATES GENERATED FROM CYCLIC ORGANO TRANSITION METAL ACYL COMPLEXES Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198252297  0.427
1981 Theopold K, Bergman R. Additions and Corrections - Synthesis and Reactions of a Binuclear Cobalt Bridging Methylene (μ-CH2) Complex. Conversion to μ-CH2Rh/Co and Rh/Rh Complexes and Methylene Transfer to Ethylene Involving Activation by a Second Metal Complex Journal of the American Chemical Society. 103: 5624-5624. DOI: 10.1021/Ja00408A609  0.574
1981 Theopold KH, Bergman RG. Synthesis and reactions of a binuclear cobalt bridging methylene (.mu.-CH2) complex. Conversion to .mu.-CH2 rhodium/cobalt and rhodium/rhodium complexes and methylene transfer to ethylene involving activation by a second metal complex Journal of the American Chemical Society. 103: 2489-2491. DOI: 10.1021/Ja00399A092  0.551
1981 THEOPOLD KH, BERGMAN RG. ChemInform Abstract: SYNTHESIS AND REACTIONS OF A BINUCLEAR COBALT BRIDGING METHYLENE (μ-CH2) COMPLEX. CONVERSION TO μ-CH2 RHODIUM/COBALT AND RHODIUM/RHODIUM COMPLEXES AND METHYLENE TRANSFER TO ETHYLENE INVOLVING ACTIVATION BY A SECOND METAL COMPLEX Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198132276  0.492
1981 Theopold KH, Bergman RG. Synthesis and reactions of a binuclear cobalt bridging methylene (μ-CH2) complex. Conversion to μ-CH2 Rh/Co and Rh/Rh complexes and methylene transfer to ethylene involving activation by a second metal complex Journal of the American Chemical Society. 103: 2489-2491.  0.322
1980 Theopold KH, Bergman RG. Synthesis of metallacyclopentanes containing two metals in the ring. Thermal decomposition to cyclopropane and ligand-induced conversion to stable mononuclear metallacyclopentanones Journal of the American Chemical Society. 102: 5694-5695. DOI: 10.1021/Ja00537A056  0.497
1980 THEOPOLD KH, BERGMAN RG. ChemInform Abstract: SYNTHESIS OF METALLACYCLOPENTANES CONTAINING TWO METALS IN THE RING. THERMAL DECOMPOSITION TO CYCLOPROPANE AND LIGAND-INDUCED CONVERSION TO STABLE MONONUCLEAR METALLACYCLOPENTANONES Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198047263  0.425
1978 Roose WRW, Rehder D, Lüders H, Theopold KH. The coordinative properties of bifunctional arsenic ligands in carbonylvanadium compounds Journal of Organometallic Chemistry. 157: 311-319. DOI: 10.1016/S0022-328X(00)91714-5  0.38
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