Year |
Citation |
Score |
2023 |
Neisius NA, MacHale LT, Snyder ER, Finke RG, Prieto AL. Copper Selenophosphate, CuPSe, Nanoparticle Synthesis: Octadecane Is the Key to a Simplified, Atom-Economical Reaction. Nano Letters. 23: 11430-11437. PMID 38085913 DOI: 10.1021/acs.nanolett.3c02620 |
0.77 |
|
2021 |
Long DK, Bangerth W, Handwerk DR, Whitehead CB, Shipman PD, Finke RG. Estimating reaction parameters in mechanism-enabled population balance models of nanoparticle size distributions: A Bayesian inverse problem approach. Journal of Computational Chemistry. PMID 34672375 DOI: 10.1002/jcc.26770 |
0.663 |
|
2020 |
Tuttle RR, Folkman SJ, Rubin HN, Finke RG, Reynolds MM. Copper Metal-Organic Framework Surface Catalysis: Catalyst Poisoning, IR Spectroscopic, and Kinetic Evidence Addressing the Nature and Number of the Catalytically Active Sites En Route to Improved Applications. Acs Applied Materials & Interfaces. PMID 32805891 DOI: 10.1021/Acsami.0C08961 |
0.781 |
|
2020 |
Handwerk DR, Shipman PD, Özkar S, Finke RG. Dust Effects on Ir(0) Nanoparticle Formation Nucleation and Growth Kinetics and Particle Size-Distributions: Analysis by and Insights from Mechanism-Enabled Population Balance Modeling. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 32011887 DOI: 10.1021/Acs.Langmuir.9B03193 |
0.339 |
|
2020 |
Handwerk DR, Shipman PD, Whitehead CB, Özkar S, Finke RG. Particle Size Distributions via Mechanism-Enabled Population Balance Modeling The Journal of Physical Chemistry C. 124: 4852-4880. DOI: 10.1021/Acs.Jpcc.9B11239 |
0.671 |
|
2020 |
Finke RG, Watzky MA, Whitehead CB. Response to “Particle Size Is a Primary Determinant for Sigmoidal Kinetics of Nanoparticle Formation: A “Disproof” of the Finke–Watzky (F-W) Nanoparticle Nucleation and Growth Mechanism” Chemistry of Materials. 32: 3657-3672. DOI: 10.1021/Acs.Chemmater.0C00780 |
0.69 |
|
2019 |
Handwerk DR, Shipman PD, Whitehead CB, Özkar S, Finke RG. Mechanism-Enabled Population Balance Modeling of Particle Formation en Route to Particle Average Size and Size Distribution Understanding and Control. Journal of the American Chemical Society. PMID 31556606 DOI: 10.1021/Jacs.9B06364 |
0.705 |
|
2019 |
Tuttle RR, Rubin HN, Rithner CD, Finke RG, Reynolds MM. Copper ion vs copper metal-organic framework catalyzed NO release from bioavailable S-Nitrosoglutathione en route to biomedical applications: Direct H NMR monitoring in water allowing identification of the distinct, true reaction stoichiometries and thiol dependencies. Journal of Inorganic Biochemistry. 199: 110760. PMID 31349071 DOI: 10.1016/J.Jinorgbio.2019.110760 |
0.362 |
|
2019 |
Özkar S, Finke RG. Nanoparticle Formation Kinetics and Mechanistic Studies Important to Mechanism-Based Particle-Size Control: Evidence for Ligand-Based Slowing of the Autocatalytic Surface Growth Step Plus Postulated Mechanisms The Journal of Physical Chemistry C. 123: 14047-14057. DOI: 10.1021/Acs.Jpcc.9B03220 |
0.38 |
|
2019 |
Whitehead CB, Özkar S, Finke RG. LaMer’s 1950 Model for Particle Formation of Instantaneous Nucleation and Diffusion-Controlled Growth: A Historical Look at the Model’s Origins, Assumptions, Equations, and Underlying Sulfur Sol Formation Kinetics Data Chemistry of Materials. 31: 7116-7132. DOI: 10.1021/Acs.Chemmater.9B01273 |
0.693 |
|
2019 |
Whitehead CB, Finke RG. Nucleation Kinetics and Molecular Mechanism in Transition-Metal Nanoparticle Formation: The Intriguing, Informative Case of a Bimetallic Precursor, {[(1,5-COD)IrI·HPO4]2}2– Chemistry of Materials. 31: 2848-2862. DOI: 10.1021/Acs.Chemmater.8B05335 |
0.728 |
|
2018 |
Mondloch JE, Özkar S, Finke RG. "Weakly Ligated, Labile Ligand" Nanoparticles: The Case of Ir(0) ·(HCl) . Acs Omega. 3: 14538-14550. PMID 31458138 DOI: 10.1021/acsomega.8b01569 |
0.678 |
|
2018 |
Folkman SJ, Soriano-Lopez J, Galán-Mascarós JR, Finke RG. Electrochemically Driven Water-Oxidation Catalysis Beginning with Six Exemplary Cobalt Polyoxometalates: Is It Molecular, Homogeneous Catalysis or Electrode-Bound, Heterogeneous CoO Catalysis? Journal of the American Chemical Society. PMID 30204436 DOI: 10.1021/Jacs.8B06303 |
0.782 |
|
2018 |
Folkman SJ, Zhou M, Nicki M, Finke RG. Correction to "Alcohol Solvent Effects in the Synthesis of CoO Metal-Oxide Nanoparticles: Disproof of a Surface-Ligand Thermodynamic Effect en Route to Alternative Kinetic and Thermodynamic Explanations". Inorganic Chemistry. PMID 30058332 DOI: 10.1021/acs.inorgchem.8b01888 |
0.796 |
|
2018 |
Folkman SJ, Zhou M, Nicki M, Finke RG. Alcohol Solvent Effects in the Synthesis of Co3O4 Metal-Oxide Nanoparticles: Disproof of a Surface-Ligand Thermodynamic Effect en Route to Alternative Kinetic and Thermodynamic Explanations. Inorganic Chemistry. PMID 29363962 DOI: 10.1021/Acs.Inorgchem.7B02831 |
0.8 |
|
2017 |
Kirner JT, Finke RG. Sensitization of Nanocrystalline Metal Oxides with a Phosphonate-Functionalized Perylene Diimide for Photoelectrochemical Water Oxidation with a CoOₓ Catalyst. Acs Applied Materials & Interfaces. PMID 28727440 DOI: 10.1021/Acsami.7B05874 |
0.779 |
|
2017 |
Özkar S, Finke RG. Dust Effects on Nucleation Kinetics and Nanoparticle Product Size Distributions: Illustrative Case Study of a Prototype Ir(0)n Transition-Metal Nanoparticle Formation System. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 28640625 DOI: 10.1021/Acs.Langmuir.7B01219 |
0.351 |
|
2017 |
Özkar S, Finke RG. Nanoparticle Nucleation Is Termolecular in Metal and Involves Hydrogen: Evidence for a Kinetically Effective Nucleus of Three {Ir3H2x·P2W15Nb3O62}(6-) in Ir(0)n Nanoparticle Formation From [(1,5-COD)Ir(I)·P2W15Nb3O62](8-) Plus Dihydrogen. Journal of the American Chemical Society. PMID 28379002 DOI: 10.1021/Jacs.7B00958 |
0.401 |
|
2017 |
Kirner JT, Finke RG. Water-oxidation photoanodes using organic light-harvesting materials: a review Journal of Materials Chemistry A. 5: 19560-19592. DOI: 10.1039/C7Ta05709A |
0.747 |
|
2017 |
Özkar S, Finke RG. Silver Nanoparticles Synthesized by Microwave Heating: A Kinetic and Mechanistic Re-Analysis and Re-Interpretation The Journal of Physical Chemistry C. 121: 27643-27654. DOI: 10.1021/Acs.Jpcc.7B06323 |
0.326 |
|
2017 |
Finney EE, Finke RG. Catalyst Sintering Kinetics Data: Is There a Minimal Chemical Mechanism Underlying Kinetics Previously Fit by Empirical Power-Law Expressions—and if So, What Are Its Implications? Industrial & Engineering Chemistry Research. 56: 10271-10286. DOI: 10.1021/Acs.Iecr.7B02633 |
0.758 |
|
2016 |
Folkman SJ, Kirner JT, Finke RG. Cobalt Polyoxometalate Co4V2W18O68(10-): A Critical Investigation of Its Synthesis, Purity, and Observed (51)V Quadrupolar NMR. Inorganic Chemistry. PMID 27159211 DOI: 10.1021/Acs.Inorgchem.6B00324 |
0.798 |
|
2016 |
Özkar S, Finke RG. Palladium(0) Nanoparticle Formation, Stabilization, and Mechanistic Studies: Pd(acac)2 as a Preferred Precursor, [Bu4N]2HPO4 Stabilizer, plus the Stoichiometry, Kinetics, and Minimal, Four-Step Mechanism of the Palladium Nanoparticle Formation and Subsequent Agglomeration Reactions. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 27046305 DOI: 10.1021/Acs.Langmuir.6B00013 |
0.325 |
|
2016 |
Folkman SJ, Finke RG. Electrochemical Water Oxidation Catalysis Beginning with Co(II) Polyoxometalates: The Case of the Precatalyst Co4V2W18O6810– Acs Catalysis. 7: 7-16. DOI: 10.1021/Acscatal.6B02244 |
0.801 |
|
2016 |
Kent P, Mondloch JE, Finke RG. Synthesis of Heterogeneous Ir0∼600-900/γ-Al2O3 in One Pot from the Precatalyst Ir(1,5-COD)Cl/γ-Al2O3: Discovery of Two Competing Trace "ethyl Acetate Effects" on the Nucleation Step and Resultant Product Acs Catalysis. 6: 5449-5461. DOI: 10.1021/Acscatal.6B00265 |
0.733 |
|
2015 |
Crooks AB, Yih KH, Li L, Yang JC, Özkar S, Finke RG. Unintuitive inverse dependence of the apparent turnover frequency on precatalyst concentration: A quantitative explanation in the case of ziegler-type nanoparticle catalysts made from [(1,5-COD)Ir(μ-O2C8H15)]2 and AlEt3 Acs Catalysis. 5: 3342-3353. DOI: 10.1021/Acscatal.5B00347 |
0.388 |
|
2015 |
Bayram E, Lu J, Aydin C, Browning ND, Özkar S, Finney E, Gates BC, Finke RG. Agglomerative sintering of an atomically dispersed ir1/zeolite y catalyst: Compelling evidence against ostwald ripening but for bimolecular and autocatalytic agglomeration catalyst sintering steps Acs Catalysis. 5: 3514-3527. DOI: 10.1021/Acscatal.5B00321 |
0.802 |
|
2015 |
Bayram E, Linehan JC, Fulton JL, Szymczak NK, Finke RG. Determination of the dominant catalyst derived from the classic [RhCp∗Cl2]2 precatalyst system: Is it single-metal Rh1Cp∗-based, subnanometer Rh4 cluster-based, or Rh(0) n nanoparticle-based cyclohexene hydrogenation catalysis at room temperature and mild pressures? Acs Catalysis. 5: 3876-3886. DOI: 10.1021/Acscatal.5B00315 |
0.635 |
|
2015 |
Laxson WW, Özkar S, Folkman S, Finke RG. The story of a mechanism-based solution to an irreproducible synthesis resulting in an unexpected closed-system requirement for the LiBEt3H-based reduction: The case of the novel subnanometer cluster, [Ir(1,5-COD)(μ-H)]4, and the resulting improved, independently repeatable, reliable synthesis Inorganica Chimica Acta. 432: 250-257. DOI: 10.1016/J.Ica.2015.04.015 |
0.79 |
|
2014 |
Laxson WW, Finke RG. Nucleation is second order: an apparent kinetically effective nucleus of two for Ir(0)n nanoparticle formation from [(1,5-COD)Ir(I)·P2W15Nb3O62]8- plus hydrogen. Journal of the American Chemical Society. 136: 17601-15. PMID 25479070 DOI: 10.1021/Ja510263S |
0.374 |
|
2014 |
Kirner JT, Stracke JJ, Gregg BA, Finke RG. Visible-light-assisted photoelectrochemical water oxidation by thin films of a phosphonate-functionalized perylene diimide plus CoOx cocatalyst. Acs Applied Materials & Interfaces. 6: 13367-77. PMID 24654796 DOI: 10.1021/Am405598W |
0.781 |
|
2014 |
Kent PD, Mondloch JE, Finke RG. A four-step mechanism for the formation of supported-nanoparticle heterogenous catalysts in contact with solution: the conversion of Ir(1,5-COD)Cl/γ-Al2O3 to Ir(0)(∼170)/γ-Al2O3. Journal of the American Chemical Society. 136: 1930-41. PMID 24444431 DOI: 10.1021/Ja410194R |
0.73 |
|
2014 |
Stracke JJ, Finke RG. Distinguishing homogeneous from heterogeneous water oxidation catalysis when beginning with polyoxometalates Acs Catalysis. 4: 909-933. DOI: 10.1021/Cs4011716 |
0.793 |
|
2014 |
Stracke JJ, Finke RG. Water oxidation catalysis beginning with Co4(H 2O)2(PW9O34)2 10- when driven by the chemical oxidant ruthenium(III)tris(2, 2′-bipyridine): Stoichiometry, kinetic, and mechanistic studies en route to identifying the true catalyst Acs Catalysis. 4: 79-89. DOI: 10.1021/Cs4006925 |
0.778 |
|
2013 |
Stracke JJ, Finke RG. Water oxidation catalysis beginning with 2.5 μm [Co4(H 2O)2(PW9O34)2] 10-: Investigation of the true electrochemically driven catalyst at ≥600 mV overpotential at a glassy carbon electrode Acs Catalysis. 3: 1209-1219. DOI: 10.1021/Cs400141T |
0.769 |
|
2013 |
Hamdemir IK, Özkar S, Finke RG. Exceptionally thermally stable, hydrocarbon soluble Ziegler-type Ir(0) n nanoparticle catalysts made from [Ir(1,5-COD)(μ-O 2C8H15)]2 plus AlEt3: Tests of key hypotheses for their unusual stabilization Journal of Molecular Catalysis a: Chemical. 378: 333-343. DOI: 10.1016/J.Molcata.2013.07.005 |
0.39 |
|
2012 |
Yih KH, Hamdemir IK, Mondloch JE, Bayram E, Özkar S, Vasi? R, Frenkel AI, Anderson OP, Finke RG. Synthesis and characterization of [Ir(1,5-cyclooctadiene)(μ-H)]4: a tetrametallic Ir4H4-core, coordinatively unsaturated cluster. Inorganic Chemistry. 51: 3186-93. PMID 22356560 DOI: 10.1021/Ic2026494 |
0.755 |
|
2012 |
Bayram E, Lu J, Aydin C, Uzun A, Browning ND, Gates BC, Finke RG. Mononuclear zeolite-supported iridium: Kinetic, spectroscopic, electron microscopic, and size-selective poisoning evidence for an atomically dispersed true catalyst at 22 °c Acs Catalysis. 2: 1947-1957. DOI: 10.1021/Cs300366W |
0.633 |
|
2012 |
Bayram E, Finke RG. Quantitative 1,10-phenanthroline catalyst-poisoning kinetic studies of Rh(0) nanoparticle and Rh 4 cluster benzene hydrogenation catalysts: Estimates of the poison K association binding constants, of the equivalents of poison bound and of the number of catalytically active sites for each catalyst Acs Catalysis. 2: 1967-1975. DOI: 10.1021/Cs300330C |
0.641 |
|
2012 |
Hamdemir IK, Özkar S, Yih KH, Mondloch JE, Finke RG. Hydrocarbon-soluble, isolable ziegler-type Ir(0) n nanoparticle catalysts made from [(1,5-COD)Ir(μ-O 2C 8H 15)] 2 and 2-5 equivalents of AlEt 3: Their high catalytic activity, long lifetime, and AlEt 3-dependent, exceptional, 200 °c thermal stability Acs Catalysis. 2: 632-641. DOI: 10.1021/Cs200688G |
0.745 |
|
2012 |
Mondloch JE, Finke RG. Kinetic evidence for bimolecular nucleation in supported-transition-metal- nanoparticle catalyst formation in contact with solution: The prototype Ir(1,5-COD)Cl/γ-Al 2O 3 to Ir(0) ∼900/ γ-Al 2O 3 System Acs Catalysis. 2: 298-305. DOI: 10.1021/Cs2006422 |
0.746 |
|
2012 |
Finney EE, Shields SP, Buhro WE, Finke RG. Gold nanocluster agglomeration kinetic studies: Evidence for parallel bimolecular plus autocatalytic agglomeration pathways as a mechanism-based alternative to an Avrami-based analysis Chemistry of Materials. 24: 1718-1725. DOI: 10.1021/Cm203186Y |
0.728 |
|
2012 |
Mondloch JE, Bayram E, Finke RG. A review of the kinetics and mechanisms of formation of supported-nanoparticle heterogeneous catalysts Journal of Molecular Catalysis a: Chemical. 355: 1-38. DOI: 10.1016/J.Molcata.2011.11.011 |
0.78 |
|
2011 |
Bayram E, Linehan JC, Fulton JL, Roberts JA, Szymczak NK, Smurthwaite TD, Özkar S, Balasubramanian M, Finke RG. Is it homogeneous or heterogeneous catalysis derived from [RhCp*Cl2]2? In operando XAFS, kinetic, and crucial kinetic poisoning evidence for subnanometer Rh4 cluster-based benzene hydrogenation catalysis. Journal of the American Chemical Society. 133: 18889-902. PMID 22035197 DOI: 10.1021/Ja2073438 |
0.664 |
|
2011 |
Stracke JJ, Finke RG. Electrocatalytic water oxidation beginning with the cobalt polyoxometalate [Co4(H2O)2(PW9O34)2]10-: identification of heterogeneous CoOx as the dominant catalyst. Journal of the American Chemical Society. 133: 14872-5. PMID 21894961 DOI: 10.1021/Ja205569J |
0.774 |
|
2011 |
Mondloch JE, Finke RG. Supported-nanoparticle heterogeneous catalyst formation in contact with solution: kinetics and proposed mechanism for the conversion of Ir(1,5-COD)Cl/γ-Al2O3 to Ir(0)(~900)/γ-Al2O3. Journal of the American Chemical Society. 133: 7744-56. PMID 21526773 DOI: 10.1021/Ja110550H |
0.733 |
|
2011 |
Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Özkar S, Yih KH, Johnson KA, Finke RG. Industrial Ziegler-type hydrogenation catalysts made from Co(neodecanoate)2 or Ni(2-ethylhexanoate)2 and AlEt3: evidence for nanoclusters and sub-nanocluster or larger Ziegler-nanocluster based catalysis. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 6279-94. PMID 21480617 DOI: 10.1021/La200053F |
0.785 |
|
2011 |
Yih KH, Alley WM, Finke RG. Improved syntheses for the compounds [(1,5-COD)M(μ-O 2C 8H 15) 2 (M = Ir, Rh) Organometallics. 30: 5068-5070. DOI: 10.1021/Om2003249 |
0.744 |
|
2011 |
Bayram E, Linehan JC, Finke RG, Fulton J, Roberts JAS, Smurthwaite TD, Ozkar S, Szymczak NK. Is it single-metal homogeneous or polymetallic heterogeneous catalysis? Further investigation of the catalytically active species in benzene hydrogenation beginning with [RhCp*Cl 2] 2 via operando-XAFS, kinetic and poisoning studies Acs National Meeting Book of Abstracts. |
0.56 |
|
2010 |
Alley WM, Hamdemir IK, Wang Q, Frenkel AI, Li L, Yang JC, Menard LD, Nuzzo RG, Ozkar S, Johnson KA, Finke RG. Iridium Ziegler-type hydrogenation catalysts made from [(1,5-COD)Ir(mu-O2C8H15)](2) and AlEt3: spectroscopic and kinetic evidence for the Ir(n) species present and for nanoparticles as the fastest catalyst. Inorganic Chemistry. 49: 8131-47. PMID 20681520 DOI: 10.1021/Ic101237C |
0.789 |
|
2010 |
Mondloch JE, Wang Q, Frenkel AI, Finke RG. Development plus kinetic and mechanistic studies of a prototype supported-nanoparticle heterogeneous catalyst formation system in contact with solution: Ir(1,5-COD)Cl/gamma-Al2O3 and its reduction by H2 to Ir(0)n/gamma-Al2O3. Journal of the American Chemical Society. 132: 9701-14. PMID 20575521 DOI: 10.1021/Ja1030062 |
0.751 |
|
2010 |
Bayram E, Zahmakiran M, Ozkar S, Finke RG. In situ formed "weakly ligated/labile ligand" iridium(0) nanoparticles and aggregates as catalysts for the complete hydrogenation of neat benzene at room temperature and mild pressures. Langmuir : the Acs Journal of Surfaces and Colloids. 26: 12455-64. PMID 20536218 DOI: 10.1021/La101390E |
0.648 |
|
2010 |
Miyake GM, DiRocco DA, Liu Q, Oberg KM, Bayram E, Finke RG, Rovis T, Chen EYX. Stereospecific polymerization of chiral oxazolidinone-functionalized alkenes Macromolecules. 43: 7504-7514. DOI: 10.1021/Ma101310N |
0.701 |
|
2010 |
Finney EE, Finke RG. Reply to comment on "fitting and interpreting transition-metal nanocluster formation and other sigmoidal-appearing kinetic data: A more thorough testing of dispersive kinetic vs chemical-mechanism-based equations and treatments for 4-step type kinetic data" Chemistry of Materials. 22: 2687-2688. DOI: 10.1021/cm903884p |
0.719 |
|
2010 |
Alley WM, Hamdemir IK, Johnson KA, Finke RG. Ziegler-type hydrogenation catalysts made from group 8-10 transition metal precatalysts and AlR3 cocatalysts: A critical review of the literature Journal of Molecular Catalysis a: Chemical. 315: 1-27. DOI: 10.1016/J.Molcata.2009.07.007 |
0.778 |
|
2009 |
Mondloch JE, Yan X, Finke RG. Monitoring supported-nanocluster heterogeneous catalyst formation: product and kinetic evidence for a 2-step, nucleation and autocatalytic growth mechanism of Pt(0)n formation from H2PtCl6 on Al2O3 or TiO2. Journal of the American Chemical Society. 131: 6389-96. PMID 19379011 DOI: 10.1021/Ja808980A |
0.758 |
|
2009 |
Morris AM, Anderson OP, Finke RG. Reinvestigation of a Ru(2)-incorporated polyoxometalate dioxygenase precatalyst, "[WZnRu(2)(III)(H(2)O)(OH)(ZnW(9)O(34))(2)](11-)": evidence for marginal, Inorganic Chemistry. 48: 4411-20. PMID 19351133 DOI: 10.1021/Ic9000363 |
0.609 |
|
2009 |
Morris AM, Pierpont CG, Finke RG. Synthesis and characterization of V(V)(3,6-DBSQ)(3,6-DBCat)2, a d(0) metal complex with dioxygenase catalytic activity. Inorganic Chemistry. 48: 3496-8. PMID 19317407 DOI: 10.1021/Ic802122Q |
0.627 |
|
2009 |
Graham CR, Ott LS, Finke RG. Ranking the lacunary (Bu4N)9[H[alpha2-P2W17O61]] polyoxometalate's stabilizing ability for Ir(0)(n) nanocluster formation and stabilization using the five-criteria method plus necessary control experiments. Langmuir : the Acs Journal of Surfaces and Colloids. 25: 1327-36. PMID 19133735 DOI: 10.1021/La8025254 |
0.673 |
|
2009 |
Alley WM, Girard CW, Ozkar S, Finke RG. Model Ziegler-type hydrogenation catalyst precursors, [(1,5-COD)M(mu-O2C8H15)]2 (M = Ir and Rh): synthesis, characterization, and demonstration of catalytic activity en route to identifying the true industrial hydrogenation catalysts. Inorganic Chemistry. 48: 1114-21. PMID 19127998 DOI: 10.1021/Ic801933B |
0.783 |
|
2009 |
Morris AM, Finke RG. Alpha-synuclein aggregation variable temperature and variable pH kinetic data: a re-analysis using the Finke-Watzky 2-step model of nucleation and autocatalytic growth. Biophysical Chemistry. 140: 9-15. PMID 19101068 DOI: 10.1016/J.Bpc.2008.11.003 |
0.584 |
|
2009 |
Morris AM, Watzky MA, Finke RG. Protein aggregation kinetics, mechanism, and curve-fitting: a review of the literature. Biochimica Et Biophysica Acta. 1794: 375-97. PMID 19071235 DOI: 10.1016/J.Bbapap.2008.10.016 |
0.581 |
|
2009 |
Finney EE, Finke RG. Is there a minimal chemical mechanism underlying classical avrami-Erofe'ev treatments of phase-transformation kinetic data Chemistry of Materials. 21: 4692-4705. DOI: 10.1021/Cm9018716 |
0.737 |
|
2009 |
Finney EE, Finke RG. Fitting and interpreting transition-metal nanocluster formation and other sigmoidal-appearing kinetic data: A more thorough testing of dispersive kinetic vs chemical-mechanism-based equations and treatments for 4-step type kinetic data Chemistry of Materials. 21: 4468-4479. DOI: 10.1021/Cm901142P |
0.752 |
|
2009 |
Morris AM, Pierpont CG, Finke RG. Dioxygenase catalysis by d0 metal-catecholate complexes containing vanadium and molybdenum with H2(3,5-DTBC) and H2(3,6-DTBC) substrates Journal of Molecular Catalysis a: Chemical. 309: 137-145. DOI: 10.1016/J.Molcata.2009.05.008 |
0.642 |
|
2008 |
Watzky MA, Morris AM, Ross ED, Finke RG. Fitting yeast and mammalian prion aggregation kinetic data with the Finke-Watzky two-step model of nucleation and autocatalytic growth. Biochemistry. 47: 10790-800. PMID 18785757 DOI: 10.1021/Bi800726M |
0.588 |
|
2008 |
Watzky MA, Finney EE, Finke RG. Transition-metal nanocluster size vs formation time and the catalytically effective nucleus number: a mechanism-based treatment. Journal of the American Chemical Society. 130: 11959-69. PMID 18707099 DOI: 10.1021/Ja8017412 |
0.755 |
|
2008 |
Ott LS, Finke RG. Supersensitivity of transition-metal nanoparticle formation to initial precursor concentration and reaction temperature: understanding its origins. Journal of Nanoscience and Nanotechnology. 8: 1551-6. PMID 18468189 DOI: 10.1166/Jnn.2008.089 |
0.71 |
|
2008 |
Morris AM, Watzky MA, Agar JN, Finke RG. Fitting neurological protein aggregation kinetic data via a 2-step, minimal/"Ockham's razor" model: the Finke-Watzky mechanism of nucleation followed by autocatalytic surface growth. Biochemistry. 47: 2413-27. PMID 18247636 DOI: 10.1021/Bi701899Y |
0.591 |
|
2008 |
Smith SE, Sasaki JM, Bergman RG, Mondloch JE, Finke RG. Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer. Journal of the American Chemical Society. 130: 1839-41. PMID 18198879 DOI: 10.1021/Ja710365X |
0.684 |
|
2008 |
Finney EE, Finke RG. Nanocluster nucleation and growth kinetic and mechanistic studies: a review emphasizing transition-metal nanoclusters. Journal of Colloid and Interface Science. 317: 351-74. PMID 18028940 DOI: 10.1016/J.Jcis.2007.05.092 |
0.75 |
|
2008 |
Ott LS, Finke RG. Supersensitivity of transition-metal nanoparticle formation to initial precursor concentration and reaction temperature*: Understanding its origins Journal of Nanoscience and Nanotechnology. 8: 1551-1556. DOI: 10.1166/jnn.2008.089 |
0.652 |
|
2008 |
Finney EE, Finke RG. The four-step, double-autocatalytic mechanism for transition-metal nanocluster nucleation, growth, and then agglomeration: Metal, ligand, concentration, temperature, and solvent dependency studies Chemistry of Materials. 20: 1956-1970. DOI: 10.1021/Cm071088J |
0.753 |
|
2008 |
Ott LS, Finke RG. Transition-metal nanocluster stabilization versus agglomeration fundamental studies: Measurement of the two types of rate constants for agglomeration plus their activation parameters under catalytic conditions Chemistry of Materials. 20: 2592-2601. DOI: 10.1021/Cm062001H |
0.691 |
|
2007 |
Ott LS, Campbell S, Seddon KR, Finke RG. Evidence that imidazolium-based ionic ligands can be metal(0)/nanocluster catalyst poisons in at least the test case of iridium(0)-catalyzed acetone hydrogenation. Inorganic Chemistry. 46: 10335-44. PMID 17975891 DOI: 10.1021/Ic700976Z |
0.719 |
|
2007 |
Ott LS, Cline ML, Finke RG. Nanocluster formation and stabilization fundamental studies: ranking the nanocluster stabilizing ability of halides. Journal of Nanoscience and Nanotechnology. 7: 2400-10. PMID 17663259 DOI: 10.1166/Jnn.2007.426 |
0.68 |
|
2007 |
Ott LS, Finke RG. Transition-metal nanocluster stabilization for catalysis: A critical review of ranking methods and putative stabilizers Coordination Chemistry Reviews. 251: 1075-1100. DOI: 10.1016/J.Ccr.2006.08.016 |
0.664 |
|
2006 |
Ott LS, Hornstein BJ, Finke RG. A test of the transition-metal nanocluster formation and stabilization ability of the most common polymeric stabilizer, poly(vinylpyrrolidone), as well as four other polymeric protectants. Langmuir : the Acs Journal of Surfaces and Colloids. 22: 9357-67. PMID 17042554 DOI: 10.1021/La060934M |
0.68 |
|
2006 |
Ott LS, Finke RG. Nanocluster formation and stabilization fundamental studies: investigating "solvent-only" stabilization en route to discovering stabilization by the traditionally weakly coordinating anion BF4- plus high dielectric constant solvents. Inorganic Chemistry. 45: 8382-93. PMID 16999438 DOI: 10.1021/Ic060876S |
0.677 |
|
2006 |
Finney EE, Finke RG. Is it homogeneous Pt(II) or heterogeneous Pt(0)n catalysis? Evidence that Pt(1,5-COD)Cl2 and Pt(1,5-COD)(CH3)2 plus H2 form heterogeneous, nanocluster plus bulk-metal Pt(0) hydrogenation catalysts Inorganica Chimica Acta. 359: 2879-2887. DOI: 10.1016/J.Ica.2005.11.023 |
0.762 |
|
2006 |
Woehrle GH, Hutchison JE, Özkar S, Finke RG. Analysis of nanoparticle transmission electron microscopy data using a public- domain image-processing program, Image Turkish Journal of Chemistry. 30: 1-13. |
0.614 |
|
2005 |
Yin CX, Sasaki Y, Finke RG. Autoxidation-product-initiated dioxygenases: vanadium-based, record catalytic lifetime catechol dioxygenase catalysis. Inorganic Chemistry. 44: 8521-30. PMID 16270992 DOI: 10.1021/Ic050717T |
0.622 |
|
2005 |
Yin CX, Finke RG. Kinetic and mechanistic studies of vanadium-based, extended catalytic lifetime catechol dioxygenases. Journal of the American Chemical Society. 127: 13988-96. PMID 16201821 DOI: 10.1021/Ja052998+ |
0.615 |
|
2005 |
Yin CX, Finke RG. Vanadium-based, extended catalytic lifetime catechol dioxygenases: evidence for a common catalyst. Journal of the American Chemical Society. 127: 9003-13. PMID 15969577 DOI: 10.1021/Ja051594E |
0.599 |
|
2005 |
Yin CX, Finke RG. Is it true dioxygenase or classic autoxidation catalysis? Re-investigation of a claimed dioxygenase catalyst based on a Ru(2)-incorporated, polyoxometalate precatalyst. Inorganic Chemistry. 44: 4175-88. PMID 15934747 DOI: 10.1021/Ic050090E |
0.578 |
|
2005 |
Besson C, Finney EE, Finke RG. A mechanism for transition-metal nanoparticle self-assembly. Journal of the American Chemical Society. 127: 8179-84. PMID 15926847 DOI: 10.1021/Ja0504439 |
0.751 |
|
2005 |
Ott LS, Cline ML, Deetlefs M, Seddon KR, Finke RG. Nanoclusters in ionic liquids: evidence for N-heterocyclic carbene formation from imidazolium-based ionic liquids detected by (2)H NMR. Journal of the American Chemical Society. 127: 5758-9. PMID 15839652 DOI: 10.1021/Ja0423320 |
0.673 |
|
2005 |
Ozkar S, Finke RG. Iridium(0) nanocluster, acid-assisted catalysis of neat acetone hydrogenation at room temperature: exceptional activity, catalyst lifetime, and selectivity at complete conversion. Journal of the American Chemical Society. 127: 4800-8. PMID 15796546 DOI: 10.1021/Ja0437813 |
0.402 |
|
2005 |
Hagen CM, Widegren JA, Maitlis PM, Finke RG. Is it homogeneous or heterogeneous catalysis? Compelling evidence for both types of catalysts derived from [Rh(eta5-C5Me5)Cl2]2 as a function of temperature and hydrogen pressure. Journal of the American Chemical Society. 127: 4423-32. PMID 15783225 DOI: 10.1021/Ja044154G |
0.736 |
|
2005 |
Hagen CM, Vieille-Petit L, Laurenczy G, Süss-Fink G, Finke RG. Supramolecular triruthenium cluster-based benzene hydrogenation catalysis: Fact or fiction? Organometallics. 24: 1819-1831. DOI: 10.1021/Om048976Y |
0.466 |
|
2005 |
Besson C, Finney EE, Finke RG. Nanocluster nucleation, growth, and then agglomeration kinetic and mechanistic studies: A more general, four-step mechanism involving double autocatalysis Chemistry of Materials. 17: 4925-4938. DOI: 10.1021/Cm050207X |
0.771 |
|
2005 |
Vieille-Petit L, Tschan MJL, Süss-Fink G, Laurenczy G, Hagen CM, Finke RG, Geneste F, Moinet C. The water-soluble cluster cation [H3Ru3(C 6H6)(C6Me6)2(O)] +: Improved synthesis, aerobic oxidation, electrochemical properties and ligand exchange studies Polyhedron. 24: 1961-1967. DOI: 10.1016/J.Poly.2005.06.006 |
0.348 |
|
2004 |
Doll KM, Finke RG. Adenosylcobinamide plus exogenous, sterically hindered, putative axial bases: a reinvestigation into the cause of record levels of Co-C heterolysis. Inorganic Chemistry. 43: 2611-23. PMID 15074980 DOI: 10.1021/Ic030141C |
0.646 |
|
2004 |
Hornstein BJ, Finke RG. Transition-Metal Nanocluster Kinetic and Mechanistic Studies Emphasizing Nanocluster Agglomeration: Demonstration of a Kinetic Method That Allows Monitoring of All Three Phases of Nanocluster Formation and Aging Chemistry of Materials. 16: 139-150. DOI: 10.1021/Cm034585I |
0.406 |
|
2004 |
Özkar S, Finke RG. The hydrogenphosphate complex of (1,5-cyclooctadiene)iridium(I), {[Bu4N][(1,5-COD)Ir·HPO4]}n: Synthesis, spectroscopic characterization, and ES-MS of a new, preferred precursor to HPO4 2- and Bu4 N+ stabilized Ir(0)n nanoclusters Journal of Organometallic Chemistry. 689: 493-501. DOI: 10.1016/J.Jorganchem.2003.10.038 |
0.336 |
|
2004 |
Finke RG, Özkar S. Molecular insights for how preferred oxoanions bind to and stabilize transition-metal nanoclusters: A tridentate, C3 symmetry, lattice size-matching binding model Coordination Chemistry Reviews. 248: 135-146. DOI: 10.1016/J.Cct.2003.08.003 |
0.359 |
|
2003 |
Doll KM, Bender BR, Finke RG. The first experimental test of the hypothesis that enzymes have evolved to enhance hydrogen tunneling. Journal of the American Chemical Society. 125: 10877-84. PMID 12952467 DOI: 10.1021/Ja030120H |
0.633 |
|
2003 |
Widegren JA, Bennett MA, Finke RG. Is it homogeneous or heterogeneous catalysis? Identification of bulk ruthenium metal as the true catalyst in benzene hydrogenations starting with the monometallic precursor, Ru(II)(eta 6-C6Me6)(OAc)2, plus kinetic characterization of the heterogeneous nucleation, then autocatalytic surface-growth mechanism of metal film formation. Journal of the American Chemical Society. 125: 10301-10. PMID 12926954 DOI: 10.1021/Ja021436C |
0.731 |
|
2003 |
Doll KM, Finke RG. A compelling experimental test of the hypothesis that enzymes have evolved to enhance quantum mechanical tunneling in hydrogen transfer reactions: the beta-neopentylcobalamin system combined with prior adocobalamin data. Inorganic Chemistry. 42: 4849-56. PMID 12895106 DOI: 10.1021/Ic0300722 |
0.627 |
|
2003 |
Özkar S, Finke RG. Transition-metal nanocluster stabilization fundamental studies: Hydrogen phosphate as a simple, effective, readily available, robust, and previously unappreciated stabilizer for well-formed, isolable, and redissolvable Ir(0) and other transition-metal nanoclusters Langmuir. 19: 6247-6260. DOI: 10.1021/La0207522 |
0.445 |
|
2003 |
Hornstein BJ, Finke RG. Transition-metal nanocluster catalysts: Scaled-up synthesis, characterization, storage conditions, stability, and catalytic activity before and after storage of polyoxoanion- and tetrabutylammonium-stabilized Ir(0) nanoclusters Chemistry of Materials. 15: 899-909. DOI: 10.1021/Cm020856Y |
0.402 |
|
2003 |
Widegren JA, Finke RG. A review of the problem of distinguishing true homogeneous catalysis from soluble or other metal-particle heterogeneous catalysis under reducing conditions Journal of Molecular Catalysis a: Chemical. 198: 317-341. DOI: 10.1016/S1381-1169(02)00728-8 |
0.741 |
|
2003 |
Weiner H, Trovarelli A, Finke RG. Expanded product, plus kinetic and mechanistic, studies of polyoxoanion-based cyclohexene oxidation catalysis: The detection of ∼70 products at higher conversion leading to a simple, product-based test for the presence of olefin autoxidation Journal of Molecular Catalysis a: Chemical. 191: 217-252. DOI: 10.1016/S1381-1169(02)00344-8 |
0.367 |
|
2003 |
Weiner H, Trovarelli A, Finke RG. Polyoxoanion-supported catalysis: Evidence for a P2W15Nb3O62 9-- supported iridium cyclohexene oxidation catalyst starting from [n-Bu4N]5Na3[(1,5-COD)Ir ·P2W15Nb3O62] Journal of Molecular Catalysis a: Chemical. 191: 253-279. DOI: 10.1016/S1381-1169(02)00343-6 |
0.421 |
|
2003 |
Widegren JA, Finke RG. A review of soluble transition-metal nanoclusters as arene hydrogenation catalysts Journal of Molecular Catalysis a: Chemical. 191: 187-207. DOI: 10.1016/S1381-1169(02)00125-5 |
0.729 |
|
2002 |
Doll KM, Fleming PE, Finke RG. The synthesis and characterization of 8-methoxy-5'-deoxyadenosylcobalamin: a coenzyme B(12) analog which, following Co-C bond homolysis, avoids cyclization of the 8-methoxy-5'-deoxyadenosyl radical. Journal of Inorganic Biochemistry. 91: 388-97. PMID 12161308 DOI: 10.1016/S0162-0134(02)00401-4 |
0.657 |
|
2002 |
White WT, Finke RG. Synthesis of adenosylcobinamide 2-chlorophenyl phosphate, a zwitterionic cobinamide phosphate analog of adenosylcobalamin en route to crystallizable cobinamides. Journal of Inorganic Biochemistry. 91: 371-87. PMID 12161307 DOI: 10.1016/S0162-0134(02)00402-6 |
0.323 |
|
2002 |
Ozkar S, Finke RG. Nanocluster formation and stabilization fundamental studies: ranking commonly employed anionic stabilizers via the development, then application, of five comparative criteria. Journal of the American Chemical Society. 124: 5796-810. PMID 12010055 DOI: 10.1021/Ja012749V |
0.337 |
|
2002 |
Hornstein BJ, Aiken JD, Finke RG. Nanoclusters in catalysis: a comparison of CS(2) catalyst poisoning of polyoxoanion- and tetrabutylammonium-stabilized 40 +/- 6 A Rh(0) nanoclusters to 5 Rh/Al(2)O(3), including an analysis of the literature related to the CS(2) to metal stoichiometry issue. Inorganic Chemistry. 41: 1625-38. PMID 11896733 DOI: 10.1021/Ic010920Y |
0.43 |
|
2002 |
Widegren JA, Finke RG. Anisole hydrogenation with well-characterized polyoxoanion- and tetrabutylammonium-stabilized Rh(0) nanoclusters: effects of added water and acid, plus enhanced catalytic rate, lifetime, and partial hydrogenation selectivity. Inorganic Chemistry. 41: 1558-72. PMID 11896725 DOI: 10.1021/Ic0109750 |
0.744 |
|
2002 |
Özkar S, Finke RG. Nanocluster formation and stabilization fundamental studies: 2. Proton sponge as an effective H+ scavenger and expansion of the anion stabilization ability series Langmuir. 18: 7653-7662. DOI: 10.1021/La020225I |
0.39 |
|
2001 |
Suto RK, Brasch NE, Anderson OP, Finke RG. Synthesis, characterization, solution stability, and X-ray crystal structure of the thiolatocobalamin gamma-glutamylcysteinylcobalamin, a dipeptide analogue of glutathionylcobalamin: insights into the enhanced Co-S bond stability of the natural product glutathionylcobalamin. Inorganic Chemistry. 40: 2686-92. PMID 11375680 DOI: 10.1021/Ic001365N |
0.305 |
|
2001 |
Widegren JA, Aiken JD, Özkar S, Finke RG. Additional investigations of a new kinetic method to follow transition-metal nanocluster formation, including the discovery of heterolytic hydrogen activation in nanocluster nucleation reactions Chemistry of Materials. 13: 312-324. DOI: 10.1021/Cm0006852 |
0.72 |
|
2000 |
Sirovatka JM, Finke RG. Hydrogen abstraction from thiols by adenosyl radicals: chemical precedent for thiyl radical formation, the first catalytic step in ribonucleoside triphosphate reductase from Lactobacillus leichmannii. Journal of Inorganic Biochemistry. 78: 149-60. PMID 10766338 DOI: 10.1016/S0162-0134(99)00224-X |
0.329 |
|
2000 |
Widegren JA, Weiner H, Miller SM, Finke RG. Improved synthesis and crystal structure of tetrakis(acetonitrile)(η4-1,5-cyclooctadiene)ruthenium(II) bis[tetrafluoroborate(1 - )] Journal of Organometallic Chemistry. 610: 112-117. DOI: 10.1016/S0022-328X(00)00462-9 |
0.702 |
|
2000 |
Nomiya K, Arai Y, Shimizu Y, Takahashi M, Takayama T, Weiner H, Nagata T, Widegren JA, Finke RG. Synthesis and characterization of the tetrameric, tri-titanium(IV)-substituted Wells-Dawson-substructure polyoxotungstate, [(P2W15Ti3O60.5)4]36- Inorganica Chimica Acta. 300: 285-304. DOI: 10.1016/S0020-1693(99)00603-9 |
0.681 |
|
1999 |
Sirovatka JM, Finke RG. Coenzyme B(12) Axial-Base Chemical Precedent Studies. Adenosylcobinamide Plus Sterically Hindered Axial-Base Co-C Bond Cleavage Product and Kinetic Studies: Evidence for the Dominance of Axial-Base Transition-State Effects and for Co-N(Axial-Base) Distance-Dependent, Competing sigma and pi Effects. Inorganic Chemistry. 38: 1697-1707. PMID 11670936 DOI: 10.1021/Ic980608X |
0.312 |
|
1999 |
Brasch NE, Hsu TL, Doll KM, Finke RG. Synthesis and characterization of isolable thiolatocobalamin complexes relevant to coenzyme B12-dependent ribonucleoside triphosphate reductase. Journal of Inorganic Biochemistry. 76: 197-209. PMID 10605837 DOI: 10.1016/S0162-0134(99)00128-2 |
0.64 |
|
1999 |
Suto RK, Whalen MA, Finke RG. Adenosylcobalamin-dependent ribonucleoside triphosphate reductase from Lactobacillus leichmannii. Rapid, improved purification involving dGTP-based affinity chromatography plus biophysical characterization studies demonstrating enhanced, "crystallographic level" purity. Preparative Biochemistry & Biotechnology. 29: 273-309. PMID 10431931 DOI: 10.1080/10826069908544929 |
0.324 |
|
1999 |
Weiner H, Finke RG. An all-inorganic, polyoxometalate-based catechol dioxygenase that exhibits > 100 000 catalytic turnovers Journal of the American Chemical Society. 121: 9831-9842. DOI: 10.1021/Ja991503B |
0.358 |
|
1999 |
Aiken JD, Finke RG. Polyoxoanion- and tetrabutylammonium-stabilized Rh(0)(n) nanoclusters: Unprecedented nanocluster catalytic lifetime in solution Journal of the American Chemical Society. 121: 8803-8810. DOI: 10.1021/Ja991034D |
0.422 |
|
1999 |
Weiner H, Hayashi Y, Finke RG. Oxygenation Catalysis by All-Inorganic, Oxidation-Resistant, Dawson-Type Polyoxoanion-Supported Transition Metal Precatalysts, [(CH3CN)xM]n+Plus P2W15Nb3O629-(M = MnII, FeII, CoII, NiII, CuI, CuII, ZnII) Inorganic Chemistry. 38: 2579-2591. DOI: 10.1021/Ic990078K |
0.425 |
|
1999 |
Aiken JD, Finke RG. Polyoxoanion- and tetrabutylammonium-stabilized, near-monodisperse, 40 ± 6 Å Rh(0)∼1500 to Rh(0)∼3700 nanoclusters: Synthesis, characterization, and hydrogenation catalysis Chemistry of Materials. 11: 1035-1047. DOI: 10.1021/Cm980699W |
0.39 |
|
1999 |
Aiken JD, Finke RG. A review of modern transition-metal nanoclusters: Their synthesis, characterization, and applications in catalysis Journal of Molecular Catalysis a: Chemical. 145: 1-44. DOI: 10.1016/S1381-1169(99)00098-9 |
0.34 |
|
1999 |
Weiner H, Hayashi Y, Finke RG. A polyoxoanion-based iron(II) catechol extradiol dioxygenase: Oxygenation of 3,5-di-tert-butylcatechol by the polyoxoanion-supported iron(II) complex (n-Bu4N)7[(CH3CN)xFe II·P2W15Nb3O62] Inorganica Chimica Acta. 291: 426-437. DOI: 10.1016/S0020-1693(99)00161-9 |
0.339 |
|
1998 |
Fleming PE, Daikh BE, Finke RG. The coenzyme B12 derivative N1-methyl-5'-deoxyadenosylcobalamin: synthesis, characterization, stability towards dimroth rearrangement, and Co-C thermolysis product and kinetic studies. Journal of Inorganic Biochemistry. 69: 45-57. PMID 9606937 DOI: 10.1016/S0162-0134(97)10008-3 |
0.306 |
|
1998 |
Weddle KS, Aiken JD, Finke RG. Rh(0) nanoclusters in benzene hydrogenation catalysis: Kinetic and mechanistic evidence that a putative [(C8H17)3NCH3]+[RhCl4]- ion- pair catalyst is actually a distribution of Cl- and [(C8H17)3NCH3]+ stabilized Rh(0) nanoclusters Journal of the American Chemical Society. 120: 5653-5666. DOI: 10.1021/Ja973045H |
0.427 |
|
1998 |
Aiken JD, Finke RG. Nanocluster formation synthetic, kinetic, and mechanistic studies. The detection of, and the methods to avoid, hydrogen mass-transfer limitations in the synthesis of polyoxoanion- and tetrabutylammonium-stabilized, near- monodisperse 40 ± 6 Å Rh(0) nanoclusters Journal of the American Chemical Society. 120: 9545-9554. DOI: 10.1021/Ja9719485 |
0.42 |
|
1998 |
Hsu TLC, Brasch NE, Finke RG. The Second Isolable B12-Thiolate Complex, (Pentafluorophenylthiolato)cobalamin: Synthesis and Characterization Inorganic Chemistry. 37: 5109-5116. DOI: 10.1021/Ic9704750 |
0.317 |
|
1997 |
Nagata T, Pohl M, Weiner H, Finke RG. Polyoxoanion-Supported Organometallic Complexes: Carbonyls of Rhenium(I), Iridium(I), and Rhodium(I) That Are Soluble Analogs of Solid-Oxide-Supported M(CO)(n)()(+) and That Exhibit Novel M(CO)(n)()(+) Mobility. Inorganic Chemistry. 36: 1366-1377. PMID 11669714 DOI: 10.1021/Ic960910A |
0.367 |
|
1997 |
Watzky MA, Finke RG. Transition metal nanocluster formation kinetic and mechanistic studies. A new mechanism when hydrogen is the reductant: Slow, continuous nucleation and fast autocatalytic surface growth Journal of the American Chemical Society. 119: 10382-10400. DOI: 10.1021/Ja9705102 |
0.397 |
|
1997 |
Hayashi Y, Müller F, Lin Y, Miller SM, Anderson OP, Finke RG. 2CH3CNC(n-Bu4N)2[{Ir(1,5-COD)}6W4O16]·2CH3CN: A hybrid inorganic-organometallic, flexible cavity host, acetonitrile-guest complex composed of a [W4O4](n+) tetratungstate cube and six polyoxoanion-supported (1,5-COD)Ir+ organometallic groups Journal of the American Chemical Society. 119: 11401-11407. DOI: 10.1021/Ja970336H |
0.309 |
|
1997 |
Sirovatka JM, Finke RG. Coenzyme B12 chemical precedent studies: Probing the role of the imidazole base-on motif found in B12-dependent methylmalonyl-CoA mutase Journal of the American Chemical Society. 119: 3057-3067. DOI: 10.1021/Ja963380Q |
0.304 |
|
1997 |
Watzky MA, Finke RG. Nanocluster Size-Control and "Magic Number" Investigations. Experimental Tests of the "Living-Metal Polymer" Concept and of Mechanism-Based Size-Control Predictions Leading to the Syntheses of Iridium (0) Nanoclusters Centering about Four Sequential Magic Numbers Chemistry of Materials. 9: 3083-3095. DOI: 10.1021/Cm9704387 |
0.366 |
|
1996 |
Garr CD, Sirovatka JM, Finke RG. Adocobinamide, the base-off analog of coenzyme 612 (adocobalamin). 2.1 probing the "base-on" effect in coenzyme B12 via cobalt-carbon bond thermolysis product and kinetic studies as a function of exogenous pyridine bases Journal of the American Chemical Society. 118: 11142-11154. DOI: 10.1021/Ja954110V |
0.31 |
|
1996 |
Welner H, Aiken JD, Finke RG. Polyoxometalate Catalyst Precursors. Improved Synthesis, H+-Titration Procedure, and Evidence for 31P NMR as a Highly Sensitive Support-Site Indicator for the Prototype Polyoxoanion - Organometallic-Support System [(n-C4H9)4N]9P2W 15Nb3O62 Inorganic Chemistry. 35: 7905-7913. DOI: 10.1021/Ic960681S |
0.303 |
|
1996 |
Aiken JD, Lin Y, Finke RG. A perspective on nonocluster catalysis: Polyoxoanion and (n- C4H9)4N+ stabilized Ir(0)(~300) nanocluster 'soluble heterogeneous catalysts' Journal of Molecular Catalysis a: Chemical. 114: 29-51. DOI: 10.1016/S1381-1169(96)00302-0 |
0.441 |
|
1996 |
Mizuno N, Weiner H, Finke RG. Co-oxidative epoxidation of cyclohexene with molecular oxygen, isobutraldehyde reductant, and the polyoxoanino-supported catalyst precursor [(n-C4H9)4N]5Na3[(1,5-COD)Ir · P2W15Nb3O62] Journal of Molecular Catalysis a: Chemical. 114: 15-28. DOI: 10.1016/S1381-1169(96)00301-9 |
0.398 |
|
1996 |
Cavani F, Comuzzi C, Dolcetti G, Etienne E, Finke RG, Selleri G, Trifirò F, Trovarelli A. Oxidative dehydrogenation of isobutane to isobutene: Dawson-type heteropolyoxoanions as stable and selective heterogeneous catalysts Journal of Catalysis. 160: 317-321. DOI: 10.1006/Jcat.1996.0151 |
0.364 |
|
1995 |
Pohl M, Lin Y, Weakley TJR, Nomiya K, Kaneko M, Weiner H, Finke RG. Trisubstituted Heteropolytungstates as Soluble Metal-Oxide Analogs. Isolation and Characterization of [(C5Me5)Rh.cntdot.P2W15Nb3O62]7- and [(C6H6)Ru.cntdot.P2W15Nb3O62]7-, Including the First Crystal Structure of a Dawson-Type Polyoxoanion-Supported Organometallic Complex Inorganic Chemistry. 34: 767-777. DOI: 10.1021/Ic00108A005 |
0.327 |
|
1995 |
Nomiya K, Nozaki C, Kaneko M, Finke RG, Pohl M. The all-sodium salt of a polyoxoanion-supported organometallic complex: synthesis and characterization of Na7[(ν5-C5Me5) Rh·PW2W15Nb3O62] · 7DMSO · 5H2O Journal of Organometallic Chemistry. 505: 23-28. DOI: 10.1016/0022-328X(95)05573-2 |
0.352 |
|
1995 |
Comuzzi C, Dolcetti G, Trovarelli A, Cavani F, Trifirò F, Llorca J, Finke RG. The solid-state rearrangement of the Wells-Dawson K6P2W18O62·10H2O to a stable Keggin-type heteropolyanion phase: A catalyst for the selective oxidation of isobutane to isobutene Catalysis Letters. 36: 75-79. DOI: 10.1007/Bf00807208 |
0.331 |
|
1994 |
Lin Y, Finke RG. A more general approach to distinguishing "homogeneous" from "heterogeneous" Catalysis: Discovery of polyoxoanion- and Bu4N+-stabilized, isolable and redissolvable, high-reactivity Ir∼190-450 nanocluster catalysts Inorganic Chemistry. 33: 4891-4910. DOI: 10.1021/Ic00100A012 |
0.353 |
|
1993 |
Waddington MD, Finke RG. Neopentylcobalamin (neopentyl B12) cobalt-carbon bond thermolysis products, kinetics, activation parameters, and bond dissociation energy: A chemical model exhibiting 106 of the 1012 enzymic activation of coenzyme B12's cobalt-carbon bond Journal of the American Chemical Society. 115: 4629-4640. DOI: 10.1021/Ja00064A026 |
0.324 |
|
1993 |
Lin Y, Nomiya K, Finke RG. Polyoxoanions as soluble metal oxide analogs. Synthesis and characterization of the polyoxoanion-supported iridium(I) complex (1,5-COD)Ir.cntdot.SiW9Nb3O406- Inorganic Chemistry. 32: 6040-6045. DOI: 10.1021/Ic00078A023 |
0.372 |
|
1993 |
Randall WJ, Weakley TJR, Finke RG. Oxidation resistant inorganic-porphyrin analog polyoxometalates. 3. Synthesis and x-ray crystallographic characterization of a new heteropolyoxoanion structural type, the diruthenium-oxo-bridged bimetallic inorganic-porphyrin analog KLi15[O{RuIVCl(.alpha.2-P2W17O61)}2].2KCl.60H2O Inorganic Chemistry. 32: 1068-1071. DOI: 10.1021/Ic00059A005 |
0.323 |
|
1992 |
Martin BD, Finke RG. Methylcobalamin's full- vs. "half"-strength cobalt-carbon sigma bonds and bond dissociation enthalpies: A >10(15) Co-CH3 homolysis rate enhancement following one-antibonding-electron reduction of methlycobalamin. Journal of the American Chemical Society. 114: 585-92. PMID 20000783 DOI: 10.1021/Ja00028A027 |
0.311 |
|
1991 |
Mansuy D, Bartoli JF, Battioni P, Lyon DK, Finke RG. Highly oxidation resistant inorganic-porphyrin analog polyoxometalate oxidation catalysts. 2. Catalysis of olefin epoxidation and aliphatic and aromatic hydroxylations starting from .alpha.2-P2W17O61(Mn+.cntdot.Br)(n-11) (Mn+ = Mn3+,Fe3+,Co2+,Ni2+,Cu2+), including quantitative comparisons to metalloporphyrin catalysts Journal of the American Chemical Society. 113: 7222-7226. DOI: 10.1021/Ja00019A019 |
0.35 |
|
1991 |
Lyon DK, Miller WK, Novet T, Domaille PJ, Evitt E, Johnson DC, Finke RG. Highly oxidation resistant inorganic-porphyrin analog polyoxometalate oxidation catalysts. 1. The synthesis and characterization of aqueous-soluble potassium salts of .alpha.2-P2W17O61(Mn+.cntdot.OH2)(n-10) and organic solvent soluble tetra-n-butylammonium salts of .alpha.2-P2W17O61(Mn+.cntdot.Br)(n-11) (M = Mn3+,Fe3+,Co2+,Ni2+,Cu2+) Journal of the American Chemical Society. 113: 7209-7221. DOI: 10.1021/Ja00019A018 |
0.324 |
|
1991 |
Daikh BE, Finke RG. Unprecedented and Reversible Cobalt-to-Carbon Alkyl Bond Rearrangement in the Coenzyme B12 Model Complex C6H5CH2CoIII[C 2(DO)(DOH)pn]I: Synthesis, Structural Characterization, and Mechanistic Studies Journal of the American Chemical Society. 113: 4160-4172. DOI: 10.1021/Ja00011A018 |
0.344 |
|
1990 |
Daikh BE, Hutchison JE, Gray NE, Smith BL, Weakley TJR, Finke RG. An unprecedented and reversible cobalt-to-carbon alkyl bond rearrangement in the coenzyme B12 model complex C6H5CH2CoIII[C2(DO)(DOH)pn]I Journal of the American Chemical Society. 112: 7830-7832. DOI: 10.1021/Ja00177A073 |
0.669 |
|
1990 |
Lyon DK, Finke RG. Polyoxoanions as soluble metal oxide analogues. 6. Catalytic activity and initial kinetic and mechanistic studies of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir·P2W15Nb3O62 8- Inorganic Chemistry. 29: 1787-1789. DOI: 10.1021/Ic00335A003 |
0.408 |
|
1990 |
Finke RG, Lyon DK, Nomiya K, Sur S, Mizuno N. Polyoxoanions as soluble metal oxide analogs. 5. Synthesis and characterization of polyoxoanion-supported, atomically dispersed iridium(I), (1,5-COD)Ir.cntdot.P2W15Nb3O628- Inorganic Chemistry. 29: 1784-1787. DOI: 10.1021/Ic00335A002 |
0.372 |
|
1988 |
Edlund DJ, Saxton RJ, Lyon DK, Finke RG. Trisubstituted heteropolytungstates as soluble metal oxide analogues. 4. The synthesis and characterization of organic solvent-soluble (Bu4N)12H4P4W30Nb6O123 and (Bu4N)9P2W15Nb3O62 and solution spectroscopic and other evidence for the supported organometallic derivatives (Bu4N)7[(C5Me5)Rh.cntdot.P2W15Nb3O62] and (Bu4N)7[(C6H6)Ru.cntdot.P2W15Nb3O62] Organometallics. 7: 1692-1704. DOI: 10.1021/Om00098A003 |
0.356 |
|
1987 |
Finke RG, Keenan SR, Schiraldi DA, Watson PL. Organolanthanide and organoactinide oxidative additions exhibiting enhanced reactivity. 4. Products, stoichiometry, and preliminary kinetic studies of the reaction of (C5Me5)2SmII·OEt2 and (C5Me5)2EuII·OEt2 with alkyl and aryl halides. Evidence .. Organometallics. 6: 1356-1358. |
0.518 |
|
1986 |
Finke RG, Rapko B, Domaille PJ. Trisubstituted heteropolytungstates as soluble metal oxide analog. 2. 1,2,3-.beta.-SiW9V3O407- supported CpTi3-, (Bu4N)4[CpTi.cntdot.SiW9V3O40] Organometallics. 5: 175-178. DOI: 10.1021/Om00132A032 |
0.3 |
|
1986 |
Finke RG, Rapko B, Saxton RJ, Domaille PJ. Trisubstituted heteropolytungstates as soluble metal oxide analogs. III. Synthesis, characterization, phosphorus-31, silicon-29, vanadium-51, and 1- and 2-D tungsten-183 NMR, deprotonation, and proton mobility studies of organic solvent solute forms of HxSiW9V3O40x-7 and HxP2W15V3O62x-9 Journal of the American Chemical Society. 108: 2947-2960. DOI: 10.1021/Ja00271A025 |
0.347 |
|
1986 |
Finke RG, Keenan SR, Schiraldi DA, Watson PL. Organolanthanide and organoactinide oxidative additions exhibiting enhanced reactivity. 3. Products and stoichiometries for the addition of alkyl and aryl halides to (C5Me5)2YbII·OEt2 and evidence for facile, inner-sphere (C5Me5)2YbIIIR and (C .. Organometallics. 5: 598-601. |
0.505 |
|
1984 |
Finke RG, Droege MW. Trisubstituted heteropolytungstates as soluble metal oxide analogs. 1. The preparation, characterization, and reactions of organic solvent soluble forms of the silicon-niobium heteropolytungstates Si2W18Nb6O778-, SiW9Nb3O407-, and the SiW9Nb3O407- supported organometallic complex [(C5Me5)Rh.cntdot.SiW9Nb3O40]5- Journal of the American Chemical Society. 106: 7274-7277. DOI: 10.1021/Ja00335A086 |
0.381 |
|
1984 |
Finke RG, Schiraldi DA, Mayer BJ. Towards the unification of coenzyme B12-dependent diol dehydratase stereochemical and model studies: The bound radical mechanism Coordination Chemistry Reviews. 54: 1-22. DOI: 10.1016/0010-8545(84)85016-X |
0.457 |
|
1983 |
Finke RG, Schiraldi DA. Model studies of coenzyme B12 dependent diol dehydratase. 2. A kinetic and mechanistic study focusing upon the cobalt participation or nonparticipation question Journal of the American Chemical Society. 105: 7605-7617. DOI: 10.1021/Ja00364A023 |
0.533 |
|
1983 |
Finke RG, McKenna WP, Schiraldi DA, Smith BL, Pierpont C. Model studies of coenzyme B12 dependent diol dehydratase. 1. Synthetic, physical property, and product studies of two key, cobalt-bound, putative diol dehydratase intermediates Journal of the American Chemical Society. 105: 7592-7604. DOI: 10.1021/Ja00364A022 |
0.526 |
|
1983 |
Finke R, Keenan S, Schiraldi D, Watson P. Organolanthanide and organoactinide oxidative addition reactions: a mechanistic comparison Journal of the Less Common Metals. 94: 401-402. DOI: 10.1016/0022-5088(83)90045-0 |
0.495 |
|
1982 |
Collman JP, Rothrock RK, Finke RG, Moore EJ, Rose-Munch F. Role of the metal-metal bond in transition-metal clusters. Phosphido-bridged diiron carbonyl complexes Inorganic Chemistry. 21: 146-156. DOI: 10.1021/Ic00131A029 |
0.526 |
|
1981 |
Laganis ED, Finke RG, Boekelheide V. Multilayered iron complexes of [2.2]paracyclophane. Proceedings of the National Academy of Sciences of the United States of America. 78: 2657-8. PMID 16593011 DOI: 10.1073/Pnas.78.5.2657 |
0.305 |
|
1981 |
Finke RG, Hirose Y, Gaughan G. (C5Me5)2UCl·tetrahydrofuran. Oxidative-addition and related reactions Journal of the Chemical Society, Chemical Communications. 232-234. DOI: 10.1039/C39810000232 |
0.344 |
|
1981 |
Finke RG, Schiraldi DA, Hirose Y. Bis(pentamethylcyclopentadienyl)chlorouranium.tetrahydrofuran oxidative-addition reaction. 2. A kinetic and mechanistic study Journal of the American Chemical Society. 103: 1875-1876. DOI: 10.1021/Ja00397A065 |
0.563 |
|
1979 |
Ginsburg RE, Rothrock RK, Finke RG, Collman JP, Dahl LF. The (metal-metal)-nonbonding[Fe2(CO)6(.mu.2-PPh2)2]2- dianion. Synthesis, structural analysis of its unusual dimeric geometry, and stereochemical-bonding implications Journal of the American Chemical Society. 101: 6550-6562. DOI: 10.1021/Ja00516A013 |
0.501 |
|
1978 |
Collman JP, Finke RG, Cawse JN, Brauman JI. Lewis acid catalyzed [RFe(CO)4]- alkyl migration reactions. A mechanistic investigation Journal of the American Chemical Society. 100: 4766-4772. DOI: 10.1021/Ja00483A022 |
0.585 |
|
1978 |
Collman JP, Finke RG, Matlock PL, Wahren R, Komoto RG, Brauman JI. Synthetic and mechanistic studies of the reduction of .alpha.,.beta.-unsaturated carbonyl compounds by the binuclear cluster, sodium hydrogen octacarbonyldiferrate Journal of the American Chemical Society. 100: 1119-1140. DOI: 10.1021/Ja00472A016 |
0.57 |
|
1978 |
COLLMAN JP, FINKE RG, CAWSE JN, BRAUMAN JI. ChemInform Abstract: LEWIS ACID CATALYZED (RFE(CO)4)- ALKYL MIGRATION REACTIONS. A MECHANISTIC INVESTIGATION Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197845138 |
0.546 |
|
1978 |
COLLMAN JP, FINKE RG, MATLOCK PL, WAHREN R, KOMOTO RG, BRAUMAN JI. ChemInform Abstract: SYNTHETIC AND MECHANISTIC STUDIES OF THE REDUCTION OF α,β-UNSATURATED CARBONYL COMPOUNDS BY THE BINUCLEAR CLUSTER, SODIUM HYDROGEN OCTACARBONYLDIFERRATE Chemischer Informationsdienst. 9. DOI: 10.1002/Chin.197823279 |
0.578 |
|
1977 |
Collman JP, Rothrock RK, Finke RG, Rose-Munch F. Metal promoted alkyl migration in a bimetallic complex Journal of the American Chemical Society. 99: 7381-7383. DOI: 10.1021/Ja00464A061 |
0.496 |
|
1977 |
Collman JP, Finke RG, Cawse JN, Brauman JI. Oxidative-addition reactions of the disodium tetracarbonylferrate supernucleophile Journal of the American Chemical Society. 99: 2515-2526. DOI: 10.1021/Ja00450A019 |
0.599 |
|
1977 |
Teller RG, Finke RG, Collman JP, Chin HB, Bau R. Dependence of the tetracarbonylferrate(2-) geometry on counterion: crystal structures of dipotassium tetracarbonylferrate and bis(sodium crypt) tetracarbonylferrate [crypt = N(CH2CH2OCH2CH2OCH2CH2)3N] Journal of the American Chemical Society. 99: 1104-1111. DOI: 10.1021/Ja00446A022 |
0.436 |
|
1977 |
TELLER RG, FINKE RG, COLLMAN JP, CHIN HB, BAU R. ChemInform Abstract: DEPENDENCE OF THE TETRACARBONYLFERRATE(2-) GEOMETRY ON COUNTERION- CRYSTAL STRUCTURES OF DIPOTASSIUM TETRACARBONYLFERRATE AND BIS(SODIUM CRYPT) TETRACARBONYLFERRATE (CRYPT = N(CH2CH2OCH2CH2OCH2CH2)3N) Chemischer Informationsdienst. 8: no-no. DOI: 10.1002/chin.197718082 |
0.365 |
|
1976 |
Collman JP, Finke RG, Matlock PL, Wahren R, Brauman JI. Binuclear clusters in organic synthesis. Synthetic and mechanistic studies of the reduction of .alpha.,.beta.-unsaturated carbonyl compounds by sodium hydrogen octacarbonyldiferrate Journal of the American Chemical Society. 98: 4685-4687. DOI: 10.1021/Ja00431A078 |
0.579 |
|
1976 |
COLLMAN JP, FINKE RG, MATLICK PL, WAHREN R, BRAUMAN JI. ChemInform Abstract: BINUCLEAR CLUSTERS IN ORGANIC SYNTHESIS. SYNTHETIC AND MECHANISTIC STUDIES OF THE REDUCTION OF α,β-UNSATURATED CARBONYL COMPOUNDS BY SODIUM HYDROGEN OCTACARBONYLDIFERRATE Chemischer Informationsdienst. 7: no-no. DOI: 10.1002/Chin.197642137 |
0.583 |
|
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